Beruflich Dokumente
Kultur Dokumente
Revision 8
Supersedes date 19/10/2010
Irritant
Risk Phrases
R36 Irritating to eyes.
R43 May cause sensitisation by skin contact.
Safety Phrases
S24/25 Avoid contact with skin and eyes.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
S37 Wear suitable gloves.
S51 Use only in well-ventilated areas.
S47/49A Keep only in original container at temperatures not exceeding 25C.
SU1 Protect from sunlight
2.3. Other hazards
3.2. Mixtures
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The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Inhalation
Remove victim immediately from source of exposure. Provide rest, warmth and fresh air. Get medical attention if any discomfort
continues.
Ingestion
DO NOT INDUCE VOMITING! NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! Rinse mouth thoroughly. Get
medical attention.
Skin contact
Remove affected person from source of contamination. Remove contaminated clothing. Wash the skin immediately with soap and water.
Get medical attention if any discomfort continues.
Eye contact
Remove victim immediately from source of exposure. Make sure to remove any contact lenses from the eyes before rinsing. Promptly
wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
General information
The severity of the symptoms described will vary dependant of the concentration and the length of exposure.
Inhalation.
Irritation of nose, throat and airway.
Ingestion
No specific symptoms noted.
Skin contact
Prolonged skin contact may cause redness and irritation.
Eye contact
Irritation of eyes and mucous membranes.
4.3. Indication of any immediate medical attention and special treatment needed
Treat Symptomatically.
Extinguishing media
Fire can be extinguished using: Water spray. Foam, carbon dioxide or dry powder.
Unsuitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire.
5.2. Special hazards arising from the substance or mixture
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For personal protection, see section 8.
6.2. Environmental precautions
Ventilate well. Wear necessary protective equipment. Absorb in vermiculite, dry sand or earth and place into containers. Do not
contaminate water sources or sewer. Inform Authorities if large amounts are involved.
6.4. Reference to other sections
For personal protection, see section 8. See section 11 for additional information on health hazards. Collect and dispose of spillage as
indicated in section 13.
Store in tightly closed original container in a dry, cool and well-ventilated place. Keep in original container. Store below 25C. Protect from
freezing and direct sunlight.
7.3. Specific end use(s)
The identified uses for this product are detailed in Section 1.2.
Ingredient Comments
No exposure limits noted for ingredient(s).
Protective equipment
Process conditions
Provide eyewash station.
Engineering measures
Well-ventilated area.
Respiratory equipment
No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air
contamination exists. In case of inadequate ventilation or when the product is heated, use suitable respiratory equipment with gas filter
(type A2).
Hand protection
Nitrile gloves are recommended. Be aware that the liquid may penetrate the gloves. Frequent change is advisable.
Eye protection
Use approved safety goggles or face shield.
Other Protection
Wear appropriate clothing to prevent any possibility of skin contact.
Hygiene measures
DO NOT SMOKE IN WORK AREA! Wash hands at the end of each work shift and before eating, smoking and using the toilet. Wash
promptly if skin becomes wet or contaminated. Promptly remove any clothing that becomes contaminated. When using do not eat, drink
or smoke.
Environmental Exposure Controls
Keep container tightly sealed when not in use.
Appearance Liquid
Colour Light (or pale). Straw.
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Odour Mild (or faint).
Solubility Forms an emulsion.
Initial boiling point and boiling range
Not available.
Melting point (C)
Not available.
Relative density 1.005 - 1.015 @ 20 c
Vapour density (air=1)
Not available.
Evaporation rate
Not available.
pH-Value, Conc. Solution
Not available.
Viscosity 32 - 34 s @ 20 c
Solubility Value (G/100G H2O@20C)
Not available.
Decomposition temperature (C)
Not available.
Odour Threshold, Lower
Not available.
Odour Threshold, Upper
Not available.
Flash point 96 C
Auto Ignition Temperature (C)
Not available.
Flammability Limit - Lower(%)
Not available.
Flammability Limit - Upper(%)
Not available.
Partition Coefficient
(N-Octanol/Water)
Not available.
Explosive properties
Not available.
Oxidising properties
Not available.
9.2. Other information
Not available.
10.1. Reactivity
Hazardous Polymerisation
May polymerize violently.
Polymerisation Description
Store in original container to avoid contamination. Polymerises easily with evolution of heat. Keep cool. Avoid heat. Avoid light.
10.4. Conditions to avoid
Polymerises when heated. Avoid heat, flames and other sources of ignition. Avoid exposure to high temperatures or direct sunlight. Avoid
contact with acids and oxidising substances.
10.5. Incompatible materials
Materials To Avoid
Strong oxidising substances. Strong reducing agents. Inorganic peroxides. Organic peroxides/hydroperoxides. Strong acids. Strong
alkalis.
10.6. Hazardous decomposition products
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SECTION 11: TOXICOLOGICAL INFORMATION
Toxicological information
No information available.
Carcinogenicity:
This substance has no evidence of carcinogenic properties.
Reproductive Toxicity:
This substance has no evidence of toxicity to reproduction.
Inhalation
May cause irritation to the respiratory system.
Skin contact
Irritating to skin. May cause sensitisation by skin contact.
Eye contact
Irritating to eyes.
Route of entry
Skin and/or eye contact.
Target Organs
Skin Eyes
Medical Symptoms
Skin irritation. Irritation of eyes and mucous membranes.
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HYDROXYPROPYL METHACRYLATE
Toxic Dose 1 - LD 50
> 2000 mg/kg (oral rat)
Acute toxicity:
Carcinogenicity:
Estimated Value
This substance has no evidence of carcinogenic properties.
Reproductive Toxicity:
No evidence of reproductive toxicity in animal studies
Aspiration hazard:
Not anticipated to present an aspiration hazard based on chemical structure.
Inhalation
No specific health warnings noted.
Ingestion
No specific health warnings noted.
Skin contact
May cause sensitisation by skin contact.
Eye contact
Irritating to eyes.
Route of entry
Skin and/or eye contact.
Target Organs
Skin Eyes
Irritation of eyes and mucous membranes.
12.1. Toxicity
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Chronic Toxicity - Aquatic Invertebrates
Not available.
Acute Toxicity - Terrestrial
Not available.
HYDROXYPROPYL METHACRYLATE
Acute Toxicity - Fish
LC50 48 hours 493 mg/l Leuciscus idus (Golden orfe)
Acute Toxicity - Aquatic Invertebrates
EC50 48 hours 380 mg/l Daphnia magna
NOEC 48 hours 24.1 mg/l Daphnia magna
Acute Toxicity - Aquatic Plants
EC50 72 hours > 97.2 mg/l Freshwater algae
NOEC 72 hours 97.2 mg/l Freshwater algae
12.2. Persistence and degradability
Degradability
The product is expected to be biodegradable.
HYDROXYPROPYL METHACRYLATE
Degradability
Biodegradable according to the appropriate OECD test. This product is expected to be removed in a wastewater treatment plant. Oxides rapidly
by photochemical reactions in air
12.3. Bioaccumulative potential
Bioaccumulative potential
Bioaccumulation is unlikely to be significant because of the low water solubility of this product.
Partition coefficient
Not available.
HYDROXYPROPYL METHACRYLATE
Bioaccumulative potential
Bioaccumulation is unlikely to be significant because of the low water solubility of this product.
Partition coefficient
Pow 0.97
12.4. Mobility in soil
Mobility:
The product has poor water-solubility.
HYDROXYPROPYL METHACRYLATE
Mobility:
Mobile.
12.5. Results of PBT and vPvB assessment
Not relevant
HYDROXYPROPYL METHACRYLATE
This product does not contain any PBT or vPvB substances.
12.6. Other adverse effects
Not known.
HYDROXYPROPYL METHACRYLATE
Not available.
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SECTION 13: DISPOSAL CONSIDERATIONS
General The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA,
ADR/RID).
14.1. UN number
Not applicable.
Not applicable.
Not applicable.
Transport Labels
No transport warning sign required.
Not applicable.
Not applicable.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable.
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Statutory Instruments
The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716).
Approved Code Of Practice
Classification and Labelling of Substances and Preparations Dangerous for Supply.
Guidance Notes
CHIP for everyone HSG(108).
EU Legislation
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive
1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive
76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.
15.2. Chemical Safety Assessment
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Hazard Statements In Full
H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
Disclaimer
The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. Ultraseal International shall not
be held liable for any damage resulting from contact with or handling of the above product.
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