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Revision Date 13/12/2012

Revision 8
Supersedes date 19/10/2010

SAFETY DATA SHEET


Ultraseal PC504/66
According to Regulation (EC) No 1907/2006

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1. Product identifier

Product name Ultraseal PC504/66


1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses Sealant.


1.3. Details of the supplier of the safety data sheet

Supplier Ultraseal International


Godiva Place
Coventry
CV1 5PN
UK
+44 (0)24 7625 8444
+44 (0)24 7655 1402
MSDS@ultraseal.co.uk
1.4. Emergency telephone number

+44 (0)20 8911 2530

SECTION 2: HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture

Classification (1999/45/EEC) Xi;R36. R43.


2.2. Label elements

Contains HYDROXYPROPYL METHACRYLATE


Labelling

Irritant

Risk Phrases
R36 Irritating to eyes.
R43 May cause sensitisation by skin contact.
Safety Phrases
S24/25 Avoid contact with skin and eyes.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
S37 Wear suitable gloves.
S51 Use only in well-ventilated areas.
S47/49A Keep only in original container at temperatures not exceeding 25C.
SU1 Protect from sunlight
2.3. Other hazards

This product does not contain any PBT or vPvB substances.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.2. Mixtures

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HYDROXYPROPYL METHACRYLATE 50 - 100%

CAS-No.: Proprietary EC No.: 248-666-3

Classification (EC 1272/2008) Classification (67/548/EEC)


Eye Irrit. 2 - H319 Xi;R36.
Skin Sens. 1 - H317 R43.

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: FIRST AID MEASURES

4.1. Description of first aid measures

Inhalation
Remove victim immediately from source of exposure. Provide rest, warmth and fresh air. Get medical attention if any discomfort
continues.
Ingestion
DO NOT INDUCE VOMITING! NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! Rinse mouth thoroughly. Get
medical attention.
Skin contact
Remove affected person from source of contamination. Remove contaminated clothing. Wash the skin immediately with soap and water.
Get medical attention if any discomfort continues.
Eye contact
Remove victim immediately from source of exposure. Make sure to remove any contact lenses from the eyes before rinsing. Promptly
wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention.
4.2. Most important symptoms and effects, both acute and delayed

General information
The severity of the symptoms described will vary dependant of the concentration and the length of exposure.
Inhalation.
Irritation of nose, throat and airway.
Ingestion
No specific symptoms noted.
Skin contact
Prolonged skin contact may cause redness and irritation.
Eye contact
Irritation of eyes and mucous membranes.
4.3. Indication of any immediate medical attention and special treatment needed

Treat Symptomatically.

SECTION 5: FIREFIGHTING MEASURES

5.1. Extinguishing media

Extinguishing media
Fire can be extinguished using: Water spray. Foam, carbon dioxide or dry powder.
Unsuitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire.
5.2. Special hazards arising from the substance or mixture

Hazardous combustion products


Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours.
Specific hazards
Carbon dioxide (CO2). Carbon monoxide (CO).
5.3. Advice for firefighters

Special Fire Fighting Procedures


Containers close to fire should be removed immediately or cooled with water. Be aware of danger of explosion.
Protective equipment for fire-fighters
Self contained breathing apparatus and full protective clothing must be worn in case of fire.

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

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For personal protection, see section 8.
6.2. Environmental precautions

Do not discharge into drains, water courses or onto the ground.


6.3. Methods and material for containment and cleaning up

Ventilate well. Wear necessary protective equipment. Absorb in vermiculite, dry sand or earth and place into containers. Do not
contaminate water sources or sewer. Inform Authorities if large amounts are involved.
6.4. Reference to other sections

For personal protection, see section 8. See section 11 for additional information on health hazards. Collect and dispose of spillage as
indicated in section 13.

SECTION 7: HANDLING AND STORAGE

7.1. Precautions for safe handling

Avoid spilling, skin and eye contact.


7.2. Conditions for safe storage, including any incompatibilities

Store in tightly closed original container in a dry, cool and well-ventilated place. Keep in original container. Store below 25C. Protect from
freezing and direct sunlight.
7.3. Specific end use(s)

The identified uses for this product are detailed in Section 1.2.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

Ingredient Comments
No exposure limits noted for ingredient(s).

8.2. Exposure controls

Protective equipment

Process conditions
Provide eyewash station.
Engineering measures
Well-ventilated area.
Respiratory equipment
No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air
contamination exists. In case of inadequate ventilation or when the product is heated, use suitable respiratory equipment with gas filter
(type A2).
Hand protection
Nitrile gloves are recommended. Be aware that the liquid may penetrate the gloves. Frequent change is advisable.
Eye protection
Use approved safety goggles or face shield.
Other Protection
Wear appropriate clothing to prevent any possibility of skin contact.
Hygiene measures
DO NOT SMOKE IN WORK AREA! Wash hands at the end of each work shift and before eating, smoking and using the toilet. Wash
promptly if skin becomes wet or contaminated. Promptly remove any clothing that becomes contaminated. When using do not eat, drink
or smoke.
Environmental Exposure Controls
Keep container tightly sealed when not in use.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Appearance Liquid
Colour Light (or pale). Straw.

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Odour Mild (or faint).
Solubility Forms an emulsion.
Initial boiling point and boiling range
Not available.
Melting point (C)
Not available.
Relative density 1.005 - 1.015 @ 20 c
Vapour density (air=1)
Not available.
Evaporation rate
Not available.
pH-Value, Conc. Solution
Not available.
Viscosity 32 - 34 s @ 20 c
Solubility Value (G/100G H2O@20C)
Not available.
Decomposition temperature (C)
Not available.
Odour Threshold, Lower
Not available.
Odour Threshold, Upper
Not available.
Flash point 96 C
Auto Ignition Temperature (C)
Not available.
Flammability Limit - Lower(%)
Not available.
Flammability Limit - Upper(%)
Not available.
Partition Coefficient
(N-Octanol/Water)
Not available.
Explosive properties
Not available.
Oxidising properties
Not available.
9.2. Other information

Not available.

SECTION 10: STABILITY AND REACTIVITY

10.1. Reactivity

10.2. Chemical stability

Stable under normal temperature conditions.


10.3. Possibility of hazardous reactions

Hazardous Polymerisation
May polymerize violently.
Polymerisation Description
Store in original container to avoid contamination. Polymerises easily with evolution of heat. Keep cool. Avoid heat. Avoid light.
10.4. Conditions to avoid

Polymerises when heated. Avoid heat, flames and other sources of ignition. Avoid exposure to high temperatures or direct sunlight. Avoid
contact with acids and oxidising substances.
10.5. Incompatible materials

Materials To Avoid
Strong oxidising substances. Strong reducing agents. Inorganic peroxides. Organic peroxides/hydroperoxides. Strong acids. Strong
alkalis.
10.6. Hazardous decomposition products

Fire creates: Carbon monoxide (CO). Carbon dioxide (CO2).

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SECTION 11: TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects

Toxicological information
No information available.

Germ cell mutagenicity:


This substance has no evidence of mutagenic properties.

Carcinogenicity:
This substance has no evidence of carcinogenic properties.

Reproductive Toxicity:
This substance has no evidence of toxicity to reproduction.

Inhalation
May cause irritation to the respiratory system.

Skin contact
Irritating to skin. May cause sensitisation by skin contact.

Eye contact
Irritating to eyes.

Route of entry
Skin and/or eye contact.

Target Organs
Skin Eyes
Medical Symptoms
Skin irritation. Irritation of eyes and mucous membranes.

Toxicological information on ingredients.

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HYDROXYPROPYL METHACRYLATE
Toxic Dose 1 - LD 50
> 2000 mg/kg (oral rat)

Acute toxicity:

Acute Toxicity (Dermal LD50)


> 5000 mg/kg Rat

Respiratory or skin sensitisation:


Sensitising.

Germ cell mutagenicity:


Based on available data the classification criteria are not met.

Carcinogenicity:
Estimated Value
This substance has no evidence of carcinogenic properties.

Reproductive Toxicity:
No evidence of reproductive toxicity in animal studies

Specific target organ toxicity - single exposure:


Not classified as a specific target organ toxicant after a single exposure.

Specific target organ toxicity - repeated exposure:


STOT - Repeated exposure
NOAEL 300 mg/kg Oral Rat
Not classified as a specific target organ toxicant after repeated exposure.

Aspiration hazard:
Not anticipated to present an aspiration hazard based on chemical structure.
Inhalation
No specific health warnings noted.
Ingestion
No specific health warnings noted.
Skin contact
May cause sensitisation by skin contact.
Eye contact
Irritating to eyes.
Route of entry
Skin and/or eye contact.
Target Organs
Skin Eyes
Irritation of eyes and mucous membranes.

SECTION 12: ECOLOGICAL INFORMATION

12.1. Toxicity

Acute Toxicity - Fish


Not available.
Acute Toxicity - Aquatic Invertebrates
Not available.
Acute Toxicity - Aquatic Plants
Not available.
Acute Toxicity - Microorganisms
Not available.
Chronic Toxicity - Fish Early life Stage
Not available.

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Chronic Toxicity - Aquatic Invertebrates
Not available.
Acute Toxicity - Terrestrial
Not available.

Ecological information on ingredients.

HYDROXYPROPYL METHACRYLATE
Acute Toxicity - Fish
LC50 48 hours 493 mg/l Leuciscus idus (Golden orfe)
Acute Toxicity - Aquatic Invertebrates
EC50 48 hours 380 mg/l Daphnia magna
NOEC 48 hours 24.1 mg/l Daphnia magna
Acute Toxicity - Aquatic Plants
EC50 72 hours > 97.2 mg/l Freshwater algae
NOEC 72 hours 97.2 mg/l Freshwater algae
12.2. Persistence and degradability

Degradability
The product is expected to be biodegradable.

Ecological information on ingredients.

HYDROXYPROPYL METHACRYLATE
Degradability
Biodegradable according to the appropriate OECD test. This product is expected to be removed in a wastewater treatment plant. Oxides rapidly
by photochemical reactions in air
12.3. Bioaccumulative potential

Bioaccumulative potential
Bioaccumulation is unlikely to be significant because of the low water solubility of this product.
Partition coefficient
Not available.

Ecological information on ingredients.

HYDROXYPROPYL METHACRYLATE
Bioaccumulative potential
Bioaccumulation is unlikely to be significant because of the low water solubility of this product.
Partition coefficient
Pow 0.97
12.4. Mobility in soil

Mobility:
The product has poor water-solubility.

Ecological information on ingredients.

HYDROXYPROPYL METHACRYLATE
Mobility:
Mobile.
12.5. Results of PBT and vPvB assessment

Not relevant

Ecological information on ingredients.

HYDROXYPROPYL METHACRYLATE
This product does not contain any PBT or vPvB substances.
12.6. Other adverse effects

Not known.

Ecological information on ingredients.

HYDROXYPROPYL METHACRYLATE
Not available.

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SECTION 13: DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods

Dispose of waste and residues in accordance with local authority requirements.

SECTION 14: TRANSPORT INFORMATION

General The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA,
ADR/RID).
14.1. UN number

Not applicable.

14.2. UN proper shipping name

Not applicable.

14.3. Transport hazard class(es)

Not applicable.
Transport Labels
No transport warning sign required.

14.4. Packing group

Not applicable.

14.5. Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant


No.

14.6. Special precautions for user

Not applicable.

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

Not applicable.

SECTION 15: REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Statutory Instruments
The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716).
Approved Code Of Practice
Classification and Labelling of Substances and Preparations Dangerous for Supply.
Guidance Notes
CHIP for everyone HSG(108).
EU Legislation
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive
1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive
76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.
15.2. Chemical Safety Assessment

No chemical safety assessment has been carried out.

SECTION 16: OTHER INFORMATION

Revision Date 13/12/2012


Revision 8
Supersedes date 19/10/2010
Risk Phrases In Full
R36 Irritating to eyes.
R43 May cause sensitisation by skin contact.

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Ultraseal PC504/66
Hazard Statements In Full
H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.

Disclaimer
The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. Ultraseal International shall not
be held liable for any damage resulting from contact with or handling of the above product.
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