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'BPAIG-68- Construction of South Site Central Plant 5{CPS) xc12100100 “rage Engineering jae Covers tecivr RUNS STRUCTURAL STE, 203.2017 As per attached DLR “1888GATRG-MT- IAErER (0387-0008 ‘STRUCTURAL STEEL MATERIAL, HEMPEL PAINT ‘QATAR FOUNDATION, CPS 0 Mezwaxsuisunparam/ate | QA/QCEngineer HavipRajamari Site QA/QC Manager Condition of Delivered Material/Equipment: PHOTO {Refer attached) dais! Dit tnt sbi whtin 23 hours of matealeaiimant ary ose ‘he Ispecton soley covers the vise, aecesibla ane exposed Here er components, major defects and damages atthe time of the Inspection ant. Ary ems or Components major defects and domoges Haden cameutlage, conceled intntenalyo intentionally o otherwise ot vibe or aesible the tine of he nspeion ‘remot tobe considered patof hs Inspection, = Inspection andsianaf hs DIR does ot by ny aan eevee Cordier rom he crtracual tons 2 Thecentactris si responsible forsafguering nd protecting the meter equipment or pt tare ake sing of sR Document Ref No, ASTAD-SEP-ADE.605, Rev. 4 42.0, 2046 age Loft Delivery No. |FME 150071 - D099. Date: 20/03/2037 ship to: [GULE CONTRACING CO.W.LL i Job no: fate to: IMR. Dx 155037390 _ DUM DUM - 77318996 [Location: Driver: FOUNDATION: CPS,NEAR GATE 15 ary. DESCRIPTION tenor | WEIGHT REMARKS (wm_| te Gece 4 Herpadur 15570 acon 80 1 Gan =20 er Herpathane enamel : 5 ons Scan 300 1 Gan =20 iter a Thinner 8450 ican 20 1 Can =201ier a “Thinner 8080 Can 20 “an =20liter FRUNS STRUCTURAL STEEL HASOLE EAST WiLL DISPATCHED BY RECEIVED BY Name ee Name Paget of 2/3 /201F- Signature FRINS STRUCTURAL STEEL id MIDDLE EAST W.LL. = DOCUMENT INDEX SINo: ae DESCRIPTIONS ae 1. | HEMPATHANE ENAMEL 55109 2. | HEMPEL'S CURING AGENT 95370 3. | HEMPADUR 15579 “| 4. | HEMPEL'S CURING AGENT 95570 HEMPEL'S THINNER 08450 HEMPEL'S THINNERO8080 HEMPATHANE ENAMEL 55109 safety Data < HEMPATHANE ENAMEL 591: © HEMPE. Conforms to ANSI 2400.1-2010 Standard - HCS 2012 & Proveative Clothing General Hazard See hte OOD SECTION 4: Identification of the substance/mixture and of the company/undertaking 44 Productidentitier Product name HEMPATHANE ENAMEL 55109, Product identity 5510900010 Product ype polyurethane paint (base for mult-component product) 41.2 Relevant identified uses of the substance or mixture and uses advised against Field of application ‘metal industry yacht. ships and shipyards, Reaay-foruse mixture 195100 = 55109 7 vol. /96370 1 vol, §10E = 86109 7 vol / 97080 1 vol Identified uses IndustialProfessional use TSCA Unless otherwise stated All compunents are listed or exempted. 4.8 Details of the supplier ofthe safety data sheet Company details HEMPEL (USA), Inc. {600 Conroe Park Narth Drive Conroe, Texas 77303 Tol ree: (800) 678-6641, itoutside area codes 713,281, 400, 936, Regular pnene number: (836) 623-8000, E-mail Hempel@Hempel.com 1.4 Emergency telephone number (with hours of operation) For Transportation Emergencies; CHEMTREC: 1-200-424-9800 (Tolle in the U.S., Canada and the U.S. Virgin Islands) 703-627-3887 (24 hours) For calls ofginating elsewhere (Collect catls are accepted), Contract number, CCN10384 ‘To preserve ths effectiveness of arrangements for providing accurate end timely emergency respanse information. tne basic entfying information (shipper name or contract number) must be included an shipping papers, Ifthe purchaser of this products going to be shipping this product to other locations, the purchaser _must arrange for its own Emergency Information Provider to respond to transpon incidents. Hempel's 24 hour response contract does not cover non-Hempel shipments. For all other information In USA tol free caling available: 1-800- 678-6641 or (036}-522-6000 (@AM-5PMCST) See Section 4 ofthe safety data chee! (first aid measures) SECTION 2: Hazards identification 2. Classification of the substance or mixture OSHNHCS status This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910, 1200), ‘GHS Classification FLAMMABLE LIQUIDS - Category 3 SKIN SENSITIZATION - Category 4 CARCINOGENICITY - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSUPE} (Respiratory tract irittion) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic fects) - Category 3 2.2 Label elements Hazard pictograms fety Data Sheet HEMPATHANE ENAMEL 55109 SECTION 2: Hazards identification Signal word Hazard statements Waring 1226 - Flammable liquid and vapor. ©HEMPEL 14317 - May cause an allergic skin reaction ¥ = Suspected of causing cancer. H335 - May cause respiratory irritation 11336 - Nay cause drowsiness or cizziness. Precautionary statements: Read label before use, Keep out af reach ufchidron. If medical advice is needed, have product (Obtain special instructions before use, Do not handle Until all safety precautions have been read and understood. Wear protective doves, Wear eye or face protection. Wear protective clothing, Keep ‘away from heat, hot surfaces, sparks, gpen flames and other ignition sources. No smoking, Use explosion-proof electrical, ventilating, lighting and all material-handling equipment. Use only non- sparking tools. Take precautionary measures against stalic cischarge. Keep container tighty closed. Use only outdoors or in a well-ventilated area. Avoid breathing vapor. Contaminated work clothing IF exposed or concemed: Gel medical attention. IF INHALED: Remove person to fresh air and keep ‘comfortable for breathing. Calla POISON CENTER or physician if you feel urwell. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin vith water or shower. IF ON SKIN: ‘Wash wih plenty of soap and water. Wash contaminated clothing before reuse. If skin initation or Disposs of contents and container in accordance with al locsi, regional, national and international General Container or label at han, Prevention ‘must not be allowed out of te workplace. Response rash occurs: Get medical attention. Storage Store locked up. Store in a wellventiated place. Keep cost Disprset regulations. Supplemental label elements: None known. 2.3 Other hazards Hazards not otherwise classified : None known, SECTION omposition/information on ingredients Product defrition Mixture Physical sate Liquia Productingredient name leentifiors % GHS Classification solvent naphiva(petrieum),lightarom, | 64742.95-6 | 228-50 Stanium dioxide buy acetate 913463.87-7 123-80-4 210-325 25-510 1,24-timethylbenzone 95635 21-3 vylere 4300-207 atesd ethylbonzons roots 2000 maiko : s-pperidyp sebacate 050 Ora Rat 22000 mag z n-butyl acrylate {L060 Inhalation Gas. Rat 2730 ppm Shous 060 Dermal Rabbit 2mukg : UD50 Oral Rat 00 mekg hydroxyprepyimethacryate LD50 Oral Rat *1200 maha Cumen LCBO ination Venor Rat 39000 mgimn* 4 hours 150 Dermal Rabbit 72300 ug : Safety Data She: HEMPATHANE ENAMEL 55109 ©HEMPEL SECTION 11: Toxicological information [1050 Ont Rat [400 mars Acute toxicity estimates Rove ATE value Oral 1980.5 mgikg Doral sra0amone Inhaon (gases) 90839.) pom Inhaon Wapors) 2545 mat Initation/Corrosion Productingredient name Result Species] Seore Fxposure elven naphtha (pavalour) ight | Eyee Wid Talat FabeH MW Yea. Bese iaaas enmancescnedles as IATA Code uni263 Code : Classification FG: Pecking grou nuts Environmental hazards PAINT 148 Special precautions for user ‘Transport within user's premises: always transport in closed containers that are upright and szcure, Ensure thal persons transporting the ‘product know what to do in the event of an accident or spilage. e 44,7 Transport in bulk according to Annex Il of MARPOL and the IBC Code Not applicable ‘SECTION 15: Regulatory information 416.1 Safety, health and environmental rogulationsilogistation specific for the substance or mixture |All components are listed or exempted, TSCA 8{a) PAIR: 2snethylpropan-2-o U.S. Federal regulations ‘TSCA 8{a) CDR ExomptiPartial exemption: Not deterriied United States inventory (TSCA 8b): All components are sted or exempted Clean Water Act (CWA) 307 ethylbenzene; toluene Clean Water Act (CWA) 311. xylene; ethylbenzene; styrene; methyl methacrylate, -bulyl acetate: Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPo) Listed Safety b ©OHEwi HEMPATHANE ENAME: 55:09 ree SECTION 15: Regulatory information Proseainaniet nae CaS nanber oncetason aaa cd Tes tre Bae ae ee jonas ‘aniats Fenecgenca ace Scere once eon sae | lean Air Act Section 602 Class I Substances : Notlsted Clean Air Act Section 602 Class I Substances + fot fisted DEA List Chemicals (Procursor Chemicals}: Not listed DEA List l Chemicals (Essential Chomicals}_: Not listed “SARA 102/304 - SARA 211312: SARA 313: Form R - Reporting requirements, Supplier notification State regulations : Version: bud ‘SARA 302/304: No products were found SARA 311/312 Hazards Identification: Flee hazard, tmmvediate (acute) health hazard, Delayed (Chronic) health hazard relense oh ceca | hoi) Tetchiebsreens ny [ke te te ve te ene uo [ve te he ve fe Sherer f te i Ne ‘S Yee Heinz zssoeraninytapraian |Ot-os | ne te ts oe No Ph soytte ler-os | Yes he i. ve Ne psewmronieescyae feazos | Ne de fe Ye S Sone feito | Me i he ye See ‘SARA 313 natifeations must not be detached from the MSDS and any copying and reaistibution ofthe MSDS Shall inchude copying and registrioution of he netice attached to copies ofthe MSDS suhsequenty Re Sana | aan a aes = ae oo a 4 Connecticut Carcinogen Reporting: None of the components are Isted Connecticut Hazardous Material Survey: None of the components are listed Florida substances: None of the components ara ised, Mlinois Chemical Safety Act: None of the components are sted Mlinois Toxie Substances Disclosure to Employee Act: None of the components are liste. Louisiana Reporting: None of the components are listed, Louisiana Spill None of the components are listed ‘Massachusetts Spill: None of the componenis are listed. Massachusetts Substances: The folowing components are listed: XYLENE; DIMETHYLBENZENE; TITANIUM DIOXIDE; TIN DIOXIDE DUST; BUTYL ACETATE, N-BUTYL ACETATE, PSEUDOCUMENE Michigan Critical Material: None of the components are isted Minnesota Hazardous Substances: Nore of tha components are listed. New Jersey Hazardous Substances: The fllowing components are isted: XYLENES; BENZENE, DIMETHYL: TITANIUM DIOXIDE; TITANIUM OXIDE (1102); n-BUTYL. ACETATE, ACETIC ACID, BUTYL ESTER; CUMENE; BENZENE, (\-METHYLETHYL}. PSEUDOCUMENE, 1.2,4-TRIMETHYL BENZENE New Jersey Spill: None of the components are listed. New Jersey Toxic Catastrophe Prevention Act: None of the components are listed. New York Acutely Hazardous Substances: The follwing components are listed: Xylene mixed Buty| ‘acatzta; Cumens; Benzene, t-methylethy!- ‘Now York Toxic Chemical Release Reporting: None of the components 2re Iisted Pennsylvania RTK Hazardous Substances: The following components are listed: BENZENE, DIMETHYL= TITANIUM OXIDE; SILICA; ACETIC ACID, BUTYL ESTER, BENZENE, (-METHYLETHYL}: PSEUDOCUMENE e114 HEMPATHANE ENAMEL 55109 H SECTION 15: Regulatory information Rhode Island Hazardous Substances: None of the components are fisted. California Prop. 65 PFF = WARNING: This product contains a chemical known to the State of California to cause cancer WARNING: This product cantains lass than 1% of a chemical known tothe State of California to cause birih defects or other reproductive harm, eoeresne ve Ke Higgs een +t 2menybarzane Ne ex ts ue Con vee te Ss Ne hans o be R00 vaca trae SECTION 16: Other information Remarks Note: In USA, consult Code of Federal Regulations, Tile 29, Labor, Parts 1910 and 1915 concerning ‘occtpational safety and health standards and regulations, as well ¢s any olher applicable Federal, State or local regulations that apply to safe practices in coating operations. ‘Warning! Ifyou scrape, sand, er remove old paint, you may release lead dust. LEAD is TOXIC. Validation Validated by US - HSE Products Coordinator on 21 September 2016 GHS Classification Procedure used to derive the classification. ‘Classification “Justification FLANIMABL= [QUIDS - Category 3 ‘On basis af teat data SKIN SENSITIZATION - Category 1 Calculation method ICARCINOGENICITY - Catagory ‘Calculation metnod SPECIFIC TARGET ORGAN TOXIGITY (SINGLE EXPOSURE) (Respiratory ttt inition) Cstegory 3 | Calculation method SPECIFIC TARGET ORGAN TOXIGITY (SINGLE EXPOSURE) (Nercoti effects) - Category 3 Galeulation method azardous Meal tbmaton System [USA sional Fie Protection Aeon (USA) | Spel fan PPE) am sect gpeton Sioa ensan ey ay ne tno eater ail lay & Pash guaran. Cs and i wre epoca ate Sina aplson and cristina spyapia PPE sab srs bap ey ose fice. tsecns CormaneatonSyscn Ser doctanaren rece TSCA Tn Satan Cora (Bria ne enmeen 2 Tpation GFR cae eral Rogictons [Re = ageey Renna ace Se eet ance enseral Mame Omg Groot CGI = Araican oneness sjoenss latk=tasateon Ar ape Assoston IER ron ny te Reman Soni Sigutnd terme Rnuanon SHES Ai Tacey earns Notice to reader 7 Inaicats information tnat has changed trom previously issued version TTothe best cf our knowledge, the information contained herein ls accurate. Howevar_neiiher the above named supplier nor any afte subaitares ‘assumes any Kebilty whatsoever fr the accuracy oF completeness of the information contained herein. Final determination of suitably of ary ‘meters the sole responsibly of he user. All materials may present unknown hazards end should be used with caution. Alibough certain hazards are described horoin, we cannot guarantee that these are the only hazards that exist HEMPATHANE TOPGOAT 55219 Conforms te ANS! 2400.1-2010 Standard -HCS 2012 Protective Clothing ‘General Hazard Se th ite OSD SECTION 1: Identification of the substance/mixture and of the company/undertaking 4.4 Product identifier Product name HEMPATHANE TOPCOAT 85218 Product entity 18521803040 Product type: polyurethane paint (base fer mul-companent product) 4.2 Relevant identified uses of the substance or mixture and uses advised against Field of aplication metal industry, ships and shipyards. Ready-forse mixture 55210 = 552197 vol./9b370 1 vol $5212 = $6219 7 vol. £95370 1 vol Ieentiied uses IndusrialProfessional use TSCA Unless otherwise stated All components are listed or exomptod, 4.3 Details of the supplier of the safety data sheet Company details HEMPEL (USA), Inc. {800 Conroe Park North Drive Conroe, Texas 77303 “Tol trae: (600) 878-£641, Ioutside area codes 713, 281, 409, 926 Regular phone number: (236) 623-6000, E-mail Hempel@Hempel com 44 Emergency telephone number (with hours of operation) For Transportation Emergencies: CHEMTREC: 1-800-424-0300 (Toll-ee in the U.S... Canada and the U.S. Virgin [slands) 703-627-3887 (24 hous) Forcalls originating elsewhere (Collact calls are accepted). Contract number: CCN10284 To preserve the effectiveness of arrangements for previding accurate and timely emergency response information, the basic identtying information (snipper name or contract number) must be included on shipping papers. Ii the pulehaser ofthis product is going to be shipping thie product to othe! lovatione, the purchaser ‘must arrange for iis own Emergency Information Provider to respond fo transport incidents. Hempel s 24 hour response contract does not cover non-Hempel shipments, For all other information In USA toll ree calling avaiable: 1-800-678-8841 ar (@36)-523-6000 (8 AM-5 PM CST) See Section 4 of the safety data sheet (rst aid measures) SECTION 2: Hazards identification 2A Classification of the substance or mixture OSHaWHCS status ‘This material is considered hacardous by the OSHA Hazard Communication Standard (29 CFR 1910. 1200) GHS Classification FLAMMABLE LIQUIDS - Category 3 SKIN IRRITATION - Category 2 ‘SKIN SENSITIZATION - Category 1 CARCINOGENICITY - Category 2 ‘SPECIFIC TARGET ORGAN TOXICITY (GINGLE EXPOSURE} (Respiratory tract initation) - Cotogory 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 SPEGIRG TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs and lungs) - Sategory 1 2.2 Label elements Safety D ee HEMPATHANE TOPCOAT 98213 © HEMPeEL ‘SECTION 2: Hazards identification Hazard pictoorams ‘Signal werd Danger Hazard statements 1226 - Flammable fiquid anc vapor. H315 - Causes skinirtation, H317 - May cause an allergic skin reaction. H351 - Suspected of causing cancer. 136 - May cause respiratory initation. 1336 - May cause drowsiness or dizziness, 1372 Causes damage to argans through prolonged or repeated exposure, hearing ois, lungs} Precautionary statements General Read label before use, Keep out of reach of children. It medical advice is needed, have product container or label at hand, Prevention (Obtain special instructions before use. Do not handle until al safely precautions have been read ard Understood. Wear protective gloves. Wear eye er face protection, Wear protective clothing, Keep ‘nay from heat, hat surfaoes, sparks, open flames and other ignition sources. No smokiig. Use explosionproof electrical, ventilating, lighting and all material-handling equipment. Use only non- sparking tools. Take precautionary measures against static discharge. Keep container tighlly closed. Use only eutdooes or in a well-ventilated area. Do not breathe vapor. Do not eat, drink or smoke when Using this product. Wash hancs thoroughly after handling, Cantarninated work clothing must not be allowed out of tne workplace. Response Get medical attention if you feel unwell. IF exposed oy eoncamed: Get medical attention. IF INHALED; Remove person to fresh sir and keep comfortable for breathing. Call a POISON CENTER or physician Ifyou feel unwel, IF ON SKIN (or hain Take off immediately all cantaminated clothing, Rinse skin ‘wth water of shower. IF ON SKIN: Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin iiiation or rash ocours; Get medical altention, Storage ‘Store locked up. Store ina well-ventilated place. Keep cool Disposal Dispose of vontents end container in accordance with alloca, regional, national and international equations, ‘Supplemental label elements: Nore knowns 23 Omer hazards Hazerds not etherwige classified: None known. SECTION 3: Composition/information on ingredients Product definition Mixture Physical state : Liqui. Productingredient name ‘entiiors % ‘GHS Classification solvent naghtha (petroleum, ightarom. | 64742-05-6 | =10-225 | FLAMMABLELIQUIDS - Category 3 ‘SPELIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory wact irtation) - Galegary 3 ‘SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Nstootc effects) - Category 3 ASPIRATION HAZARD = Calegory 1 lxytene 1330207 210-220 | FLAMMABLE LIQUIDS - Category 3 AGUTE TOXICITY (dermal) - Category 4 ‘ACUTE TOXICITY inhalation) - Category 4 SKIN IRRITATION - Category 2 etryibenzene 100-414 28s4§ | FLAMMABLE LIQUIDS - Category 2 AQUTE TOXICITY (inhelation) - Category 4 CARCINOGENICITY - Catagory 2 ‘SPECIFIC TARGET ORGAN TOXICITY (REPEATED | EXPOSURE) (hearing organs) - Category 2 | ASPIRATION HAZARD - Category t pigmentohve 15:4, 74160 (copper saree aiess | Notclassied Phinalocyanine ble, beta-nod.ploment) | Page, 2/13 a oicet HEMPATHANE TOPCOAT 55219 & aewiPeL SECTION 3: Compositionfinformation on ingredients respirable quartz 14806607 Jt CARCINOGENICITY - Catagory 1, SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (lungs) (inhalation) « Category 1 bis (1.2.266-pentamethy-tpipercy) — | 41856-2897 — | xt SKIN SENSITIZATION - Categary 4 jsebacate butyl acrylata 141322 03 FLAMMABLE LIQUIDS - Category 3 hydronyprooyimethacrylate SKIN IRRITATION - Category 2 EYE IRRITATION Category 28 SKIN SENSITIZATION - Category 1 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract inition) - Category 3 aretsoz1 | 203 EYE IRRITATION - Catagory 28 SKIN SENSITIZATION - Category 1 ‘Any concentration shown as a range isto protect confidentially or due to batch variation, (Occupational exposure ims, i avallable, ae ste in Section 8. “There are no additonal ingredients present which, within the current knowledge ofthe supplier and in the concentrations applicable, are classifed as hazardous fo health or the environment and hence require reporting inthis section, SECTION irst aid measures 441 Description of first aid measures General Eye contact: Inhalation Skin contact: Angestion Protecion of frst-aiders In all casos of doubt, or when eymptoms persist, seck medical attention. Never give anything by mouth te an unconscious person, Itbreathing is regular, drowsiness, loss of consciousness or cramps: Call 911 and give immediate leeatment (rst as. Check for and remove any contact lenses. Immediately ush eyes with plenty of water or at least 15 minutes, occasionally liting the upper and lower eyelids, Seek immediate medical attention, Remove to fesh air. Keep person warm an at rest If not breathing, breathing is regular or iF respiratory atest occurs, provide arfifcial respiration or oxygen by trained personnel, Give nothing by ‘mouth, unconscious, place in recovery postion and get medical attention mmediately. Remove contaminated clothing and shoes. Wash skin thoreughly with Soap and wiater of use recognized skin cleanser, Do NOT use solvents or thinners, If swallowed, seek mecical advice immediately and show this container or lael. Keep person warm ‘and at rest. Do not induce vomiting unless directed to do so by medicel personnel. Lower the head 30 ‘het vomit will net re-enter the mouth and throat No action shall be taken involving any personal risk or wthout suitable taining. If iis suspected that fumes are sil present, the rescuer should wear an appropriate mask of seltcontained breathing apparatus. It may be dangerous to the person providing ad to give mouth-4o-mouth resuscitation, 4.2 Most important symptoms and effects, both acute and delayed Potential acute hoalth effects Eye contact Inhalation: Skin-contect Ingestion Over-exposure signs/symptoms Eye contact Inhalation [No known significant effects ur cxtoal hazards. Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May. cause respiratory iitation. ‘Causes skin itation, Can cause central nervous system (CNS) depression, ‘Adverse symptoms may include the following: pain er iitation watering redness ‘Adverse symptoms may include the flowing: respiratory tract itation coughing rausea or vomiting eadache crowsiness/fatique izzinessiveriga unconsciousness, Page: 3/13 Safety : i HEMPATHANE TOrGUA; 55219 Heli WW ‘SECTION 4: First aid measures ‘Skin contact ‘Adverse symptoms may inetude the fallowing: irtation redness Tigestion No specific data 43 Indication of any immediate medical attention and special treatment needed Notes to physieran If gasses have been inhaled, from the decompasiion of the product, symptoms may be delayed Specific treatments No specttic treatment SECTION 5: Firefighting measures 5.1 Extinguishing media Extinguishing media Recommended alcohol resistant foam, COs, powsirs, water spray. Not to be used: waterjet 6.2 Special hazards arising from the substance or mixture Mazards from the substance or Flammable quid and vepor. In a fire ori heated, a pressure increase will cour and the container may mixture burst, with the risk of @ subsequent explosion. Runoff to sewer may create fire or explosion hazard. This material is toxic te aquatic lite with long lasting effects. Fire water contaminated with this material ‘must be contained and prevented from being discharged to ary waterway, sewer or drain, Hazardous combustion products ; Decomposition products may include the following materials: carbon oxides nitragen oxides metal oxide! oxides 6.3 Advice for firefighters Promplly isolate the scene by removing all persons from the vicinity of tha incident if there isa fire. No action shall bs taken involving any personal isk or withoUr suitable training. Fire will produce dense black smoke. Exposure to decomposition products may cauce a health hnazerd, Cool closed containers exposed to fre with water. Do not release runoff from fire fo uraine of watercourses, Fire-Aighters should ‘wear appropriate protective equipment and self-contained bresthing apparatus (SCBA) witha full face-pioce operated in postive pressure mode. SECTION 6: Accidental release measures 6.4 Personal precautions, protective equipment and emergency procedures ‘Avoid all direct contact with the splled material. Exclude sources of ignition and be aware of explosion hazard. Ventilate the area, Avoid ‘breathing vapor or mist. Refer to protective measures listed m sections 7 and 8. No action shall be taken invelving any personal isk or ‘without suitable training Ifthe product contaminates lakes, rivers, ot sewers, inform the appropriate authoriies In accordance wih local regulations. 6.2 Envitonmeniat precautions, Avoid dispersal of spilled material and 1unoff and contact wih soll, waterways, drains and sewers. Inform the relevant authorities ithe product has caused environmental pollution (Sewers, walerways, soll or ai), Weler polluting mateiial. May/be harmful fo the environment it Teleased in large quanties. 8.3 Methods and materials for containment and cleaning up ‘Stop leak if without risk. Move containers trom spill area. Approach release fram upwind. Prevent entry into sewers, water courses, Dasemenis or confined areas, Wash spillages into an effuent treatment plant or proceed as follows, Contain and collect spillage with no Combustible, absorbent material e.g. sand, earth, vermiculita ar diatomaceous earth and place in container for disposal acrording to local regulations (eee Section 13). Use spark-proaf tools and explosion-groof equipment. Contaminated sbsorbent material may pose the same hazard as the spilled product, 6.4 Roference to other sections. See Section 1 or emergency contact information ‘See Section 8 for Information on apprcpriate personal protective equipment. Soo Section 13 for addtional waste treatment information. Safety Data Si : ; HEMPATHANE TOPCOAT 55219 © HEMPEL SECTION 7: Handling and storage 7.4 Precautions for safe handling Vapors are heavier than air and may spiced along floors. Vapors may form explosive mixtures wit alr. Prevent the creation of flammable or explosive concentrations of vapors im ir and avoid vapor concentrations higher then the occupational exposure limits. In adation, the product should be used only in areas from which all naked lights and other sources ofigniion have been excluded, Elecirical equipment Should be protected ta the appropriate standard, To desipate static electricty during transfer, ground drum and connect te receiving Container with bonding strap. No sparking tools should be vsed. ‘Avoid inhalation of vapour, dust and spray mist, Avoid contact with skin and eyes. Eating, drinking and smoking should be prohibited in area ‘where this mateviale handled, stored and processed. Appropriate personal protective equipment: see Section 8, Always keep in containers ‘made from the same material as the original one, 7.2 Conditions for safe storage, including any incompatibilites Store in 2ocordance with focal regulations, Store in a cool, well-ventilated area away from incompatible materials and ignition sources, Keep out of the reach of children. Keep away from: Oxiizing agents, strong alkalis, song aciés. No smoking. Prevent unauthorized ‘access. Containars that are opened must be carefully fesealed and kept upright to prevent leakage. 7.3 Specific end use(s) ‘Soo separate Preduct Data Sheet for seccrmmendations or industrial sector specific solutions. “This product may be applied using several application techniques and methods of handling may be different for each. Apnlication tectiiques include [but are not limited to} brusting, rolling, and Spray application [canventional, HPLY, aries, pleural componeyit ‘aerosol can. Avoid the breathing of vapors and, f spraying, do not breath spray mist or serosal SECTION 8: Exposure controls!personat protection 844 Control parameters Productiingrediont name Exposure limit values solvent naphtha (petroleum), light arom, ‘ACGIH TLY (United States). TWA Tentative: 25 ppm 8 hours. poten ACGIH TLY (United States, 3/2016). STEL: 651 mgm? 15 minutes. STEL: 150 ppm 18 minues. TWA’ 434 main 8 hours. TWA: 100 pom 8 hours. OSHA PEL (United States, 22013) “TW: 435 mgine B hours. | ‘TWA: 100 ppm 8 hours, ethybencens ACGIH TLV (Untied States, 22016) ‘WIA: 25 ppm 8 hours ‘MOSH REL (United States, 10/2012). SSTEL: 545 moi? 1 minutes SSTEL: 125 porn 15 minutes “TWA; 438 moi 10 hours. JTW: 109 ppm 10 hours. OSHA PEL (United States, 22013) ‘TW: 435 maim? 8 hours. TWA $00 ppm 8 hours. reeprable quattz OSHA PEL 23 (United States, 2/2019). “TWA: 230 mppe! J (91Si02+5) 8 hours, Form: Respcable TWA: 10 maim? (%Si02#2) 8 hours, Form: Resprable ACGIH TLV (Unitod States, 372016) TWA: 0.025 main? B hours, Feri: Respirable fraction NIOSH REL (United States, 10/2018). TIA? 0.05 maim 10 hours, Fora: respirable dust butyl aarlate ACGIM TLV (United States, 3/2018). Skin sensitizer. WIA: 2 ppm B hours MOSH REL (United States, 10/2013), “TWA: 35 mgin? 10 hous, I TWA: 10 ppm 10 hours pee EEE lh Recommended monitoring procedures ion 0:02 Page: 5/13 HEMPATHANE :UPCUAi 55219 SECTION 8: Exposure controls/personal protection If this product contains ingredients with expesare mits, personal, workplace atmosphere or bislogioal monitoring may be required 19 determine the effectiveness ofthe ventlation or other control measures and/or the necessity to use zespiratory protective equipment, Reference should be made to aprvopriate monitoring standarde, Reference fo national guidance documents fer methods for tre ‘determination of hazardous substances wil also be required 8.2 Exposure cantrols Appropriate engineering controls Provide locel exhaust and general ventlation systerts to maintain aifoome concentrations below OSHA, ACGIA, and manufacturer recommanded exposure limits. Local exhaust ventilation is prefarred because it prevents contaminant dispersion into work ereas by controling it at its source, Use local and general exhaust ventlation to effectively remove and prevent buildup of mists/vapors/iumes generated from the handling ofthis product. Note: Local exhaust ventilation is designed to capture an emitted contaminant at or near its source, before the contaminant has a chance ts leperse into the workplace air. General exhaust ventilation, also called dilution ventilation i fferent from local exhaust ventilation because instead of capturing emissions at their source and -emoving thems from the air, génaral exhaust ventilation allows the contaminant ‘o_be emitted into the workplace air and then dilutes the concentration af the contaminant to an acceptable leva (eto the PEL or bela), Individual protection measures General: Gloves must be wor for all work that may result in solling. Apton/coveralls/protzctive Clothing must be ‘worn when selling Is 69 great that reguiar work clothes do pot adequately protect skin against contact withthe product, Safety eyewear should be used when there is @fkellnoed of expasure, Hygiene measures Wash hands, forearms, and face theroughly after handling compounds and before eating, smoking, using lavatory, and at the end of day. Eyelface protection Safety eyewear complying with an approved standard should be used when a risk assessment indicates tis is necessary to avoid exposure to iquid splashes, mists, gases or dusts. If contact iz [Possible the following protection should be worn, unless the assessment indicates a highes degree of protection: chemical splash goggles. Hand protection ‘Wear chemicabresistant gloves in combination with ‘basic’ employee tring. The quality of the chemical-esistant protevive aloves must be ctosen as a function ofthe specitic workplace ‘concentistions and quantity of hazardous substances, Since the actual work situation Is unknown, Supplier of gloves should be contacted in order to find the ‘Bppropriate type. Below listed gleve(s) should be regardad as generic advice Recommended: Silver Shield /4H gloves, polyvinyl alcohol (PVA, Vitont> ‘May be used: nile rubber Short term exposure: neoprene rubber, butyl uber, natural rubber (latex), polyvinyl chloride (PVC) oy protection Personal prctectve equipment forthe body shouldbe selected based onthe task being performed and the take nvaled handing ths precuct, Wear sitable protective ceting.Alvays weer protective elotina when spraying Respirctoryortection tf working areas have insufficient venttin, woar hallo ftally coven mask eauippod with oas fier of ype Orgenic Vapor, whan grinding vee pal iter of tye PSS, P34 or P100. When spraying use a ombined ite (oxgane vapor! HEPA or agane vapor | PYOO pe). Be sre fo use approvediceniea respirator or equivalent Alvays wear en aifed espiatr whe spraying na coninvous ard prolonged work situation e.g. hood wth SupPy ct tlh or eampressed a oa al lace, powered et Doniyra tte Protective clothing (pictogram) a ae & ee Note: Application of paint preducts by spraying requires adtionel safety precautions: Full boy su. Full face respirator wih ar supped. Environmental exposure controls Emisions from ventilation or work process equipment should be checked to ensure they comply wit the requirements of envisenmental ‘protection lecislation. In some cases, fume scrubbes, fers or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. fersion: 0.02 Safety Data < Eade TOPCOAT 55219 © HEMPEL SECTION 9: Physical and chemical properties 8.1 Information on basic physical an chemical properties Physical state gui. Osor Solventike pH Testing nat elevator not possible due to nature of the produ, Meling poittteezing point: Testing not relevant or not possible due to nature of the product. Boiling point/baing range : Testing not relevan) oy not possible due to nature of the product, Flash point Closed cup: 33°C (91.4°F) Evaporation rate Testing not relevant ar not possible dus fo nature of the product, Flammabitiy ighty dammable in the presence of the folowing materiale or cenditiae; open fames, tratks and static discharge and heat. Uppedioner lammabilty or 08-76 vol % explosive lis ‘vapor pressure : ‘Testing not relevant or not possible due to nature of the product, Vapor density “Testing not relevant or not possible due to nature ofthe product. Relative density 1.054 glenn? Sotubility{ies) Very slighily soluble inthe fellowing materials: cold water and hot wator Partition coefficient (Logkom): Testing not relevant or not possible due to nature of the product, Autoignition temperature Testing not relevant or not passible due io native of the product Decomposition temperature “Testing not rafevant or not possible due to nature ofthe product, Viscosity ‘Testing not relevant or not possible due to nature of the product, Explosive properties Not avaliable, Oxidizing properties ‘Testing not relevant or not possible dus to nature of the product 8.2 other information Solvents) % by weight 46.9 % (wi) {Included excematsolvenifsy Wator % by weight Weighted average: 0% VOC content (Coatings) 4.13tbsigal (4948 6!) YOG somtent (Regulatory) 413 lolgal (494.8 TOC Content (Volatile) Weighted average: 443 gi Solvent Gas ‘Weighted average: 0.109 a SECTION 10: Stability and roactivity 10.1 Reactivity No speciictost data related te reactivity available for this product arts ingredients, 40,2 Chomicat stability ‘The product is stable. 19.3 Possibility of hazardous roactions Under normat conditions of storage and use, hazardous reactions Will not octur 10.4 Conditions to avoid Avoid all possible sources of ignition (spark or flame), Do not pressurize, cut, wold, braze, solder, dil, erind or expose containers ta heal ‘9r Sairces of ignition. 10.5 Incompatible materials Version: 00% Page HEMPATHANE TOPCOAT 55219 a Bow SECTION 10: Stability and reactivity Hight reactive os incompatible with the following materials: oxidizing materials. Reactive or incompatible with the following materials: reducing materials, 10.6 Hazardous decomposition products When exposed to high temperatures (Le, in case offre) hermfu! decomposition products may be formed Decomposition products may include the following materials: carbon oxides nitrogen oxides metal oxide bxides SECTION 11: Toxicological information 11.4 Information on toxicological effects Exposure to component solvent vapor concentrations may result in adveree health effects such as mucous membrane and respiratory ‘system ination and adverse effects on the kidneys, Iver and central nervous system, Solvents may cause some of the above effects by absorption through the skin. Symptoms and signs include headaches, dizziness, fatigue, muscular weakness, drowsiness and, in exiteme ‘eases, loss of consciousness. Regectad oF prolonged contact with the preparation may cause removal of natural fat from the skin, resulting in non-allergie contact dermatitis and absorption through the skin. If splased in the eyes, the quid may cause iitation and reversible damage. Accidental swallowing may cause stomach pain, Chemical lung inflammation may occur the pracuc is takon ino the lungs via vomiting, Acute toxicity Productingredient name i Result Species, Dose Exposure Solvent naphtha (pavaeum), ant | LOSO Wnhalaion Vapor Rat S193 mg ‘thous ero, L950 Dermat Rabbit 3160 mtg Hl LD50 Oral Bat 3492 mak ‘ rvlene C50 Innaletion Gas. Rat 5000 ppm ‘Shows C50 inhalation Vapor Ral 6350 ppm ‘hours 1050 Oral Fat 4300 make . ethyfoenzene LD50 Dermal Rabbit 5000 mgikg S 1080 Oral Rat ‘3500 mai fs pigment blue 15:4, 74160 (copper | LDSO Dermal at 22000 egikg : phthalocyanine blue, bets-mod, pigment) bis (122.6.6-pentamethyt- [L050 Dermal Rat >2000 moka - 4-piperai) acbacate L050 oral Rat 72000 mgikg : rebut acre LLCS0 Inhalation Ges, Rat 2730 pom hours (L050 Dermal Rabbit 2m 7 11950 Oral Rat 200 mai 7 hydronypropyimethacryate 1050 Oral Rat 111200 ms : Acute toxicity estimates Route 7 ATE value Oral 2605.3 maka Dermat 42520 mgikg Inziation (gases) '21037-3 ppm Inhalation (vapors) 49.23 mil Inritation/Gorrosion| Productiingredient narme Result 3p Score Exposure [Savant naphtha (pevoleomp, ight | Eyes = Wid Welant Rabb : 24 ours 700 microliters Respiratory - Mid intant Rabbit : . lene Eyes - Severe irtant Rabbi [24 ours § miligrams ‘Skin Moderate ritant Rabbit . 24 hours 500 mitigrams ethytbenzene Shan = pliant Rabbit 7 24 houts 15 miligrams Respiratory - Mi jetant Rabbit 7 - Eyes - Mid intent Rappit é - uly acrylate jes - Mi intant Rabbt : [24 hours 600 mitigrams Skin is ira Rabbit 2 24 hours 10 milgrame Sensitizer Safety Uaiz HEMPATHANE TOPCOAT 95219. SECTION 11: Toxicological information OQHEWi-e ethybenzena Information on the likely routes of exposure Routes of enty anticipated: Oral, Dermal, Inhalation, Potential chronic health effects, Sensitization Contains 6 INNNNN (Other information SECTION 12: Ecological information 124 Toxicity lacgedentvane | Roe oropoare Spas Ta ease epaneine em Tinea seat ‘Shai asa a Carchogen Ghssiteaton roalngovane ro a Bronee : : fea ae ; iwomtoes | nse : : : Spat rel ran toric ne FoR) Feicngninane Saige [Roasters | Toa oame RRS aT a Fekense ee es tacit cassoys tapas. [Rano ie Pe ee Fauctnanerinane age | Raat [Taner sais Saupoy? feared — [rare oe ee ge emetic? [isar sspteion tara Praia wae Fea ap ATO A SEATON RES Soe JASPIRATION HAZARD - Category ¢ Do not alow to enter drains or watercourses. Toxic fo aquatic ffs with long lasting effects, ‘When spilled, this product may act as en ol, causing a fl, sheen, emulsion, or sludge at or beneath the sutface of a body of water: ils of any kind ean cause: (a) drowning af waterfowd due to lack of buoyancy, loss of insulating capasiy of feathars, starvation and vulnerability t0 predators due fo lack of mobility; (b) fetal effect on fish by coating gil surtaoes, prevonting respiration: (c) potential ish kils resulting fromm alteration in biochemical oxygen demand; 8) asphyxiation of benthic life forms whon floating masses become engaged with surface debts and Settle on the Dottom: and (e) adverse aesthetic effects af fouled shoreline and beaches, 2,8.6-pentamethyl-4-piperidy!) sobacate, n-butyl acrylate, hydraxypronyimethacrylate hexaethyl-29H 31H -onthalocyaninetrimethylaminato(2-)N29,N30,N31,N32|eopper. May produce an allergic reaction, No addtional known significant effects or critical hazards, Productingredient ame Result Species Exposure | [solvent naphia (patioleun, ight | AauleEO502.6 mah "Algae -Psevckrehnerels subcapiata [S6houS rom, (green algae) outs £060 6.18 mg Baphnis = Daphnia magna 48 hours Saevte LCS0 9.22 mig Fish - Oncornynehus mykiss (rainbow —/98 hours teow) ethybenzene {chronic NOEC =1000 yt Fresh water Algae -Pseusckirchneriella subesoiata. [6 hours pigment biue 16:4, 74160 (copper | Chronic NOEC >1 ml Daphnia 2t days phthalocyanine blue, bete-mod, pigment bis (1.2.26 epentametiyt Acuie E050 1.88 maf Aquatic plante 72hows A-ppsridy) sebacale | ‘cule L050 0.97 mai Fresh water Fish -Lepomis macrochius 96 hours ver oz Page. $13 Safeiy Das. sz ne i: HEMPATHANE TOPCOAT 58219 w riEMPEL SECTION 12: Ecological information 12.2 Persistence and degradability Productingredient name Test Result Dose Troculum Scivent naphina (petoleum), lant | = 370% Roaally-28 days - E 210 Lylene : 360% - Readily-28 days - - ethybenzene : >10-% Readily 28 days ‘ - Productingrediont name ‘Aquatic halite Photolysis [ Biodearadablty solvent naphtha (peteur) ght] = Readily vylene © : Readily ettybenzene : . Resaily 123 Bloaccumufative potential Producingredien name Tear aor] Potent ser rapa Pavol Tae qi a0 ign ne x0 ar s8 oe ehyensane Be ; E omen blue 18:4, 74160 (copper phhuleoyaine bo, bene, [68 E ss igre ato 38 ear low oeeenpropinatceyta oar : ioe 12.4 Mobility in soil ‘Seilwater partition coeficient No known.data avaliable in our database. (Koc) Mobily: No known data avaliable in our database. 12.5 Other adverse affects No known significant effects o citical hazards. SECTION 13: Disposal considerations 13:1 Waste treatment methods Disposal should be in accordance with applicable tegional, natlonal and local aws 2nd regulations, Loval regulations may be move stringent {han regional or national requirements. ‘The information presented nelow arly applies fo the materia as supplied. The identifcation based on characteristi(s) or Hsting may not ‘apply fe riaterial has been used or otherwise contaminated, Its the cesponsibilty of the waste generatar to determine the toxicity and physical properties of the material generated to determina the proper waste identification and dispassl msthods in compliance with applicable regulations. eter to Section 7 and Section & for akitional nandling information end protection of employees “The generation of waste should be avoided or minimized wherever possible, Disposal of this product, solutions and any by-products should at al times comply with the requirements of envirormental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-reeyclable products via a licensed waste dlsposal contractor, Waste should not be disposed of Lniteated fo the sewer unless fully compliant withthe requirements ofall authorities with jurisdiction. Waste packaging should be recycle. Incineration ar landfil should only be considered when recycling is not feasibie. This material and its contsiner must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned cr ringed out. Empty containers or liners ‘may retsin some product residues. Vapor from product residues may create a highly lammable or explosive aimosphere inside the container, Do not cut, weld or grind used containers unless they have been cleaned thoraughly internally. Avoid dispersal of set material and runoff and contact with sol, waterways, drains and sewers. United States = RORA Toxic hazardous waste "U" List ingredient cas # ‘Status Reference number [eone = [seat | Uses Was | l Bee = version: 0.02 Safe i I HEMPATHANE TOPGOAi 55219 YQ Freie. Co SECTION 14: Transport information Transport may take place according fo national regulation or DOT for transport by road and by train, IMDG for transport by sea, VATA for Air shipment, Refer to specific Dangerous Goods Transport requirements under 4SCFR, ICAO and IATA, 141 a. 143 (aa 148 UNno. Proper shipping name Transport hazard clase(es) PG" Env Additional information Sor cinae jaw acne : ire ee forte i) ‘Oe eect ‘separa quntiy Eyre chert Eipesiee/ S094 [60.307 geld Brau Patago tet gpoé usnicn leo innne nescence ‘erm Ro UN1263. PAINT. {saivent naphtha (petoleum), igh atom) is Yes. Corecl ie terepsttan at ea ‘Gonporue Goods Reasons 2, ¢ “Thematiepldsnions ‘eure on arabes ce UNI265 PAINT. Ne, UNI263 PAINT. (solvent naphtha (petioleum), ight arom) Yes. Therm pander rake ‘ee wares nase ‘pazonncscbaules mee UNT263 PAINT No. Rasp cis ‘Code = Classification PG": Pecking group Eng": Enviconmental hazards 14.8 Special precautions for user ‘Transport within user's premises: ahvays transport in closed containers that ara upright and secure, Ensure that persons transporting the Droduct know wwhat to do a the event of an accident or spillage 14,7 Transport in bulk according to Annex I of MARPOL and the IBC Code Not applicable. SECTION 45: Regulatory information 416.1 Satety, heath and environmental regulationsilegislation specific forthe substance or mixture U.S. Federal regulations ‘All companents are sted or exempted, ‘TSCA 4a final test rules: ronane ‘TSCA Bla) PAIR: 2-nethylpropan-2-ol poly(simethyfsoxane); nonane: naphthalene TSCA Bla) CDR ExomptPartal exemption: Not determined United States inventory (F5CA Bb): Al components ae sted or exempted Coan Water Act (CWA) 307: ethylbenzene, pigment green 7, 74260 {ovpper phthalocyanine green pigment); [N.NIW.N.N'N'-exaethy-26r,31H-phthalocyeninatnmetnylarnato(2+)-N20,N20,N34,NS2] Eopoer. pigment bive 18:4, 74160 (copper anhalocyanine blue, Betamod. pigment), naphthalens ‘Clean Water Act (CWA) 31: xylene: ethylbenzene; styrene; meth methacrylate; nepivhalene Ha HEMr Ais Sheet TOPCOAT 55219 SECTION 15: Regulatory information Clean Ai Act Sesion #126 Hazardous hr Pallant (HAPS) = Ue orale aa = Ee = See oe co epee a Ee ‘lean A Ae Seton 692 Gass Suetances + Nested Clean A Ae econ 6B2 Chis Substances: NotIsed DEA List I Chemicals {Precursor Cher DEA List Il Chemicals (Essontial Chemicals} cals): Not listed Not feted SARA 302/304 - SARA 311/812: SARA 313 Form R-Reporting requirements Supplier notification: State regulations : California Prop. 65 PFF : version: 0.02 SARA 302/304: chlorine SARA 311/312 Hazards identification; Fica hazard, Immediate (acute) health hazard, Delayed (chronic) health nazard a = ae] Ss SE =e eee = = (© E le & oe er iF if 12 fs Fee msseenn en Sern x [eis [ef ‘hall inclucs copying and redstibution of the notos attached fo copies cf the MSDS. fadisirbuted ‘SARA 318 nolilations must not be delsched from the MSDS and any copying and redistrbution ofthe MSDS subsequently Connecticut Carcinogen Reporting: None of the components are lise. Connecticut Hazardous Matertal Survey. None of the components are listed. Florida substances: None ofthe components are listed Winols Chemical Safety Act: None of the components are Isted. ‘roduenrsent nae | Gisnanter[—Cencenon | eerane ioe a Mlinois Toxic Substances Disclosure to Employee Act None ofthe components are listed. Louisiana Reporting: None of the components are listed Louisiana Spill: None of t2e components are ised. Massachusetts Spill: None of the components are Iisted Massachusetts Substances: The following components are listed: XYLENE; DIMETHYLBENZENE: ETHYL BENZENE, ETHYLBENZENE Michigan Critical Material: Nono of the comoonents are listed. Minnesota Hazardous Substances: None of the components areisted, New Jers: Hazardous Substances: The folloving comocnents are listed: XYLENES; BENZENE, DIMETHYt- ETHYL BENZENE; BENZENE, ETHYL; CARBON BLACK; COPPER compounds: TITANIUM DIOXIDE; TIFANIUM OXIDE (Ti02} New Jersey Spill; Nono of the components are list, New Jersey Toxic Catastrophe Prevention Act: None of the components are listed New York Acutoly Hazardous Substances: The following components are list Ethylbenzene Now York Toxic Chemical Release Reporting: None of the components are ted: Xylene mixed, Isted, Pennsytvania RTK Hazardous Substances: The following comaonents are listed: BENZENE, BIMETHYL Rhode Island Hazardous Substances: None of the components are listed |ENZENE, ETHYL-: CARBON BLACK, COPPER COMPOUNDS; TITANIUM OXIDE WARNING: This product contains a chemical known tothe Stata of California to cause cancer, Page: 1201 HEMPATHANE TOPCOAS 962s SECTION 15: Regulatory information | Protctinareint nme = | a Tene v= cr E as Slee ve i [ee Ne } SECTION 16: Other information Remarks » Note: In USA, consult Code of Federal Regulations, Title 29, Labor, Pasts #94@ and 1915 concaming ‘occupational safety and health standards and regulations, 2s Well a3 any other applicable Federal, State o¢ local regulations that apply to safe practi in coating operations. ‘Weetning! I you scrape, sand, or remove old paint, you may release lead dust. LEAD is TOXIC, Validation ‘Validated by US - HSE Products Coordinator on 21 September 2016 GHS Classification Procedure used to derive the classification, tassiication ‘Justification FLAMMABLE TIQUIOS - Category 5 On basis oftest data SKIN IRRITATION - Category 2 Calculation methoo SKIN SENSITIZATION - Category 1 Calcuation method CARCINOGENICITY - Category 2 Caleulation mathad SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE} (Respiratory tract inittion)~Catogory3 | Caleviation method /SPEGIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effecis) - Category 3 Calculation metnod | SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing ofgans and lungs) - Category 1| Calculation method aa ‘Natal Fr roton Aran (USA) Ser ea cme eee ea ara ec seeps See or om htm seme ree et se et bres an eons B19te Aran Noe! Sze ea geo: Hee = dears commuriston Sy [GF =Ssuincanaton race ‘Ses one Sastre Cone A {0G =n Ss Depa Tanouroon ies case tuo Reiman ERG Emergency Repone Sage [Si = Guna arenes Spt of Chien at abet ef emis YG = ever of Drgeous Goes, Cras United ts Gesuwioa aime Soy Aameston Sere Tarmpenaens bonmuntaters sty, Masco pera tenant Reoaraaien ht pera Enereny Pama ans Caan Pi Rae Rt ee Notice to roedor PF incicates information that hae changod from previously issued version To the best of cur Knowledge, the infarmation contained herein is accurate. However, neither te above named supplier nav any offs subsiciories assumes any ablty whatsoever for the accuracy or completeness ofthe infermation cantalned Prein Final determination of Sutebity of any materialist sole responsibilty ofthe user. All materials may present unsinown hazards and should be used with caution, Allhough cersin hazards ae deserited herein. we cannot guarantee that these are the only hazerds that exit Description: Recommended uss Service temperature: Availabi PHYSICAL CONSTANTS: ‘Shade nesiColows: Finish: Volume solids, % ‘Theoretical spreading rate: Flash point Specific gravity: Surface dry: Dry to touch: Fully cured VOC content: APPLICATION DETAILS: Version, mixed produc Mixing rao Application method: ‘Thinner (maxvol} Pot ite: Nozzle orice: Nozzle pressure: Cleaning of tools Indicated film thickness, dry: Indicated fm tnickness, wet Recoat interval, mi: Recost interval, max Safety: HEMPAT# i. di 2 SAMEL S57uu 85100: BASE 55109: CURING AGEN 95370 HEMPATHANE ENAMEL 55100 is a two-component, high-gloss acrylic polyurethane enamel, cured with aliphatic isocyanate, with good gloss and colour retention, {As a glossy decorative finishing coat on a variety of substrates such as steel, aluminium, glassfibre, reinforced polyester, phwood, hardwood etc. in severely corrosive atmospheric environment. Minimum temperature for curing is -10°CI14"F. Maximum, dry exposure only: 120°CI248°F see REMARKS overleaf Part of Group Assortment, Local availablity subject to confirmation, 19000" Write, High-gloss s2et 14.9 mii (597.5 69.8 gallon] to 95 miont 4 mils 35°C (95 °F] 4.3 kgltre [10.4 bbslUS gallor} 2 approx. hour(s) 20°C/88"F 410 5 hour(s) 20°C/8a'F T day(s) 20°C/68"F 433 gi [2.6 Ibs/US gallon] “Wide range of colours available via Hempel MULTI-TINT systern. ‘he pty contants ted av ori a acag the MEWS Grup on emul 55100 BASE 85109; CURING AGENT 95370 7.4 by volume Airless spray / Air spray! Brush ‘see REMARKS overleaf see REMARKS overleaf 018080 (5%) 2hourls) 20°C/68"F 0.017 to0.019" 75 to 100 bar [1087.5 to 1450 psi] (Airless spray dais ace indicative and subject to sdustment) HEMPEL'S THINNER 08000 9" 08510 35 micron (1.4 mis] 75 micron (3 mits} ‘According to Specification According to specication Handle with care, Bsfore and during uso, observe all safely tsbels on packaging and paint containers, ‘consult HEMPEL Safety Data Sheets and follow all local or national safely regulatans, —_________HEMPEL _ Date of issue" November 2012 Page: 172 Product Data Sheet 2 \ANE ENAMEL $5100, SURFACE PREPARATION: According to specification, APPLICATION CONDITIONS: Apply only on a dry and clean surface with a temperature above the dew point to avoid condensation. ‘Minimum temperature for curingis: ~10°C/14"F, [Av the freezing point and >elow be aware of the risk of ice cn the surface, which will hinder adhesion, The fm formation may be adversely afecied by light rain, high humidity and/or condensation during application and the following interval etter application: 16 hours at 20°C/66"F In confined spaces provice adequate ventilation during application and drying PRECEDING COAT ‘According to specification. Recommended systems are: HEMPADUR 45141/45143, HEMPADUR MASTIC 45680745881 SUBSEQUENT COAT: None. REMARKS: Colours{Colaur stability: Criain lead-free red and yellow colours may discolour when exposed to chlorine-containing atmoseiere. Leaded coloure may become discoloured when exposed to eulphide-containing mosphere. To obtain full opacity, an estra coal may be necessary, especially for certain lead-free InduatriauProfessional use TSCA Unless otherwise stated All components are listed or exempted. 4.3 Details of the supplier of the safety data shoot Company details HENPEI, (USA), Inc. "800 Conroe Park North Drive Gonroe, Texas 77303 Tol free: (800) 678-6641, ifoutside area codes 713, 281, 409, 936 Regular phone number: (836) 523-6000 E-mail Hempel@Hempel com 1.4 Emergency telephone number (with hours of operation) For Transportation Emergencies: CHEMTREC: 1-800-424-9300 (Toll-tea ia the U.S,, Canada and the U.S, Virgin Islands) 708-827-2887 (24 hours) For calls originating elsewhere (Collect cals are accepted). Contract number. CCN10384 ‘To preserve the effectiveness of arrangements for providing accurate and timely emeigency response information, the basic klentifying information (shipper name or contract mumber) must be included on shipping papers the purchaser ofthis produc is going to be shipping this product to other locations, the purchaser ‘must arrange for ts own Emergency Information Provider to respond to transport incidents, Hempel's 24 hour response contract does not cover non-Hemoel shipments. For all other information In USA tall ee caling available: 1-800. 678-8641 or (936)-523-8000, {8 AM-5 PMCST) See Section 4 of the safety data shest (fst aid measures) SECTION 2: Hazards identification 2.4 Classification of the substance or mixture OSHAVHCS status “This material's considered hazardous by ths OSHA Hazare Connunication Standard (28 CFR 4940. 4200) GHS Classification FLAMMABLE LIQUIDS - Category 3 ACUTE TOXICITY (Inhalation) - Category 4 SKIN IRRITATION - Catagory’ 2 SKIN SENSITIZATION - Category 4 CARCINOGENICITY - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE} (Respiratory tract iritation) - Category 3 SPECIFIG TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) ~ 2.2 Label elements Version 0.06 Page: 13 ty Data Si riEMPEL'S CURING AGENT 9937 HEMPE-L SECTION 2: Hazards identification Hazard plotograms Signal word Waring Hazard statements : He26 - Flammable tquid and vapor. 1332 Harmfulif inhaled. 1315 - Causes skin irtafon HB17 - May cause an alergic skin reaction. HB5t - Suspected of causing cancer, 335 - May cause respiratory Imitation. 1373 - May cause damage fo organs through prolonged or repeated exposure. (hearing organs) Precautiorary stateinents Prevertion (Obtain special instructions before use. Do not handle unt all safely precautions have been read and ‘understood, Wear protactive gloves. Wear eye or face protection. Wear protective cothing. Keep ‘away from heat, hot surfaces, sparks, open flames and otter ignition sources. No smoking. Use ‘xplasion-proof electrical, ventating, lighting and all material-handling equipment. Use only non- sparking tools. Take precautionary measures against static discharge, Keep container tightly closed. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Wash hands thoroughly ater handling. Contaminated work clothing must not be allowed out of the workplace, Response Get medical attention if you fos? unwell. IF exposed or concerned: Get medical attention. IF INHALED: Remove person to fresh ait and keep comfortable for breathing. Call a POISON CENTER or physician if you feelurwell, FON SKIN (or hair Take aff immediately all contaminated clothing, Rinse skin ‘wath water or shower. IF ON SKIN: Wash wit plenty of soap and water. Wash contaminated clothing before reuse. If skin inftaion of rash occurs: Get mexical attention Storage ‘Steve lacked up. Store in a well-ventilated place. Keep cool Disposal Dispase of contents and container in accardancs with all local, regional, national and international regulations. ‘Supplemental label elements: None known 2.3 Other hazards Hazards not otherwise classified : None known, ‘SECTION 3: Composition/information on ingredients Product defrition Modure Physical state: Liquid Produetingredient name Identifiers % GHS Classification hexamethylene-1 @disacyanate 76182812 | 250-575 | ACUTE TOXICITY (inhalation) ~Category 4 homopolymer SKIN SENSITIZATION Category 1 [SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irtaton}- Category 2methory-t-methyletiyl acetate 108-65.5. 219-225 | FLAMMABLE LIQUIDS Categor3 oene 1330-20-7 | 210-229 | FLAMMABLE LIQUIDS - Calogory 3 ACUTE TOXICITY (denral) Category 4 ‘ACUTE TOXICITY (italation)~ Category 4 ‘SKIN IRRITATION -Catogory 2 etiytenzene pote) 33 FLAMMABLE LIQUIDS - Catogory 2 ACUTE TOXICITY (inhalation) ~ Category 4 EARCINOGENICITY ~ Category 2 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE} (hearing organs) - Category 2 ASPIRATION HAZARD - Category 1 hexamethylene-di-isocyanete 22.060 05 [ACUTE TOXICITY (orl) - Category 4 ‘ACUTE TOXICITY (inhalation) - Category 4 SKIN IRRITATION - Category 2 EYE IRRITATION - Category 2 RESPIRATORY SENSITIZATION - Category 1 SKIN SENSITIZATION - Catagory 1 v Data Sheet HEWPEL'S CURING AGENT 95370 ) HEMPEL SECTION 3: Composition/information on ingredients SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respirsor tractittaton - Category 3 “Any concentration shown as a range isto preci confidentiality ors due to bach variation Occupational exposure ite, i avilable, are ted in Section 8 “There are nc additional ingredients present which, within the current knowledge of the supplier and inthe concentrations applicable, re classified as hazardous to health er the environment and hence require reperiing in this section SECTION 4: First aid measures 441 Description of irs aid measures General Inall cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth fo an unconscious person, Ifbreathing is regular, drowsiness, loss of conscicusnasa or cramps: Call 911 and give immediate treatment (frst aid). Eye contact ‘Check for and remove any contact lenses. Immediately fush eyes with plenty of water for at east 15. ‘minutes, Cccasionally iting the upper and lower eyelids. In all cases of doubt, or when symptoms persist, seck medical attention Inhalation Remove to fresh alr. Keep person warm and at rest. If not breathing, if breathing is itregular or if respiratory arest accurs, provide artifcial respiration or oxygen by trained personnel, Give nothing by mouth. f unconscious, plate in tecovery position and get medical attention immediately Skin contact Remove contaminated clothing and shoss. Wash skin thoroughly with soap and water or use recognized skin cleanser. De NOT use solvents or thinners, Ingestion + sf swallowed, seek medical advice immediately and show this container or label, Keep person warm and at rest. Do not induce vomiting unless directed fo do so by medical personnel, Lower the head so that vomit will not re-enter the moutts and throat Protection offistaiders No action shall be taken involving any personal risk or without suitable training. Iit is suspected that ‘ures are stll present the rescuer should wear an appropriate mask of self-contained breathing apparatus, 1! may be dangerous to the person providing aid to give moutn-tc-mouth resuscitation. ‘Wash contaminated clothing thoroughly with water before cemoving I, or wear alewes. 4.2 Most important symptoms and effects, both acute and delayed Potential acute health effects Eye contact [No known significant effects or citical hazards. Iohalation Harmful if inhaled. May cause respiratory initation, Skin contact Causes skin iritation, May cause an allergic skin reaction. Ingestion [No keawn significant effects or ertical hazards. Over-exposure signsisymptoms Eye contact: Adverse symptoms may include the folowing: pain or initaion ‘watering redness Inhalation ‘Adverse symptoms may include the folfowing: respiratory tract imitation coughing ‘Skin eortact Adverse symptoms may include the following: tritation esinecs Ingestion No specific data, 43 Indication of any immediate medical attention and special treatment needed {Notes to physician: If gasses have been inhaled, (rom the decomposition ofthe produc Specific treatments No specific treatmert 0.08 HEMPEL'S CURING AGEix: 385 /0 © HEMP: SECTION 5: Firefighting measures, 6.1 Extinguishing media Extinguishing media Recommended: afcohol resistant foam, COs, powders, water spray. Not to be used: wateret 45.2 Special hazards arising from the substance or mixture Hazards from the substance er Flammable liquid and vapor, Jn 2 fire cr if heated, a pressure increase will occur and the container may mixture burs, with the nak of @ subsequent explosion, Runoff to sewer may create fre ar explesion haze Hazardous combustion products : Decomposition producte may include the fellowing meterials: carbon exides rrogen oxides 5.8 Advice for firefighters, Promptly isolate the scene by removing all persons from the vicinity ofthe incident here is fre, No action shall be taken involving any personal risk or without sutable training, Fire wil produce dense black smoke. Exposure to decomposition products may cause a health hazard. Cool closed containers exposed to fre with water. Do not release runoff from fire to drains or watercourses. Firevighters should Wear appropriate protective equipment arc self-contained breathing aoparatus (SCBA) with a full foe-piece operated in positive presse mode. SECTION 6: Accitiental release measures 6.1 Personal precautions, protective equipment and emergency procedures ‘Avoid al direct contact with the spilled material. Exclude sources of ignition and ue aware of explosion hazard. Ventilate the area. Avid breathing vapor or mist, Refer to protective moasures listed in sections 7 and B. No ection shell be taken involving any personal risk or Without suitable raining, Ifthe predict contaminates lakes. rivers, o* Sewers, infarm the appropriate authoriles in accordance wih local regulations, ‘Avoid dispel of epiled material and runoff and contact wim soll, waterways, drains and zowers, Inform the relevant authorities it tha [product has caused environmental potlution (sewers, waterways, sol or air. 6.3 Methods and materials for containment and cleaning up Stop leak if without rk. Move containers from spl area. Approach release from upwind, Prevent entry into sewers, water coursos, basements or confined areas. Wash spilages into an effuent treatment plant or proceed as fellows. Contain an calect spillage with nen- ombuetible, absorbent material e.g. sand, eurih, vermiculite or diatomaceous earth and place in container for disposal according to local regulations {see Section 13). Use Spark-proof tools and explosion-proof equipment. Contaminated absorbent material may pase the same hazard as the spilled product, 4.4 Reference to other sections ‘See Section 1 for emergency contact information, ‘See Section 8 fo: information on appropriate personal protective equipment ‘See Section 13 for addtional waste treatment information SECTION 7: Handling and storage 7.4 Precautions for safe handling \Vagors are heavier than air and may spread along floors. Vapors may form explosive mixtures with ar. Prevent he creation of flammable oF ‘explosive concentrations of vapors in air and avoid vapor concentrations higher than the occupatinnal exposure limits. tn addition, tha [product should be used only i areas from which all naked ghis and other sources of ignition have been excluded, Electrical equipment ‘should be protected to the aporopriate standard. To dissipate stall electricity during transfer, ground drama and connect to receiving container with bonding strap. No spacking tools should be used. Contains isocyanates, Exposure ty isocyanate may result in acute iitation andlor sensitisation when breathing. Care should be taken when re-opening partly-used containers. ‘Avoid inhalation of vapour, dust and spray mis. Avoid contact with skin and eyes. Eating, drinking and smoking should be probibited in area ‘where this motorial is handled, stored and processes. Appropriate personal protective equipment: sae Section 8. Aways keep in containers made from the same material as the original oe. 7.2.Conditions for safe storage, including any Incompatibilities Poge: 4/18 ety Data Sheet 4 HiEMPEL'S CURING AGENT 95370 oO HEMPEL SECTION 7: Handling and storage Store in accordance with local regulations for flammable liquids. Store in a coot, well-ventilated area avray from incompatible materials and ignition sources. Keep out of the teach of children, Keep away from: Oxidizing agents, strong slkalis, strong acids 2s well ss of aminas, slcohols and water, No smoking. Prevent unauthorized access. Containers that ars opened must be carefully rescaled and kept uprighi to prevent leakage. 7.3 Specific end use(s) ‘Seo separate Product Data Sheet for recommentiations or industrial sector specific solutions, ‘This product may be spplied using several application techniques ard methods of handling may be diferent for each. Application techniques include (but are not limited to] brushing, roling, and spray application [convertional, HPLY, airless, pleural component or ‘aerosel can], Avoid tha breathing of vapors and, if spraying, da nat breath spray mist ar aerosols, ‘SECTION 8: Exposure controls/personal protection 84 Control parameters Productiingredient name “Exposure limit values: 2-mettiony-t-methylethyl acetate ‘AIA WEEL (United States, 10/2011). TWA:50 ppm 8 hours. lene ACGIH TLV (Unitod States, 32016). STEL: 651 mg/r 15 minutes. STEL: 150 ppm 15 ininutes TWA 434 man’ 8 hours. TWA: 100 ppm 8 hours ‘OSHA PEL (United States, 2/2013}, “TWA: 435 maim? 8 hours. TWA: 100 ppm 8 hours ethybanzene ‘ACGIH TLY (United Stat “TWA: 20 pp 8 hours NIOSH REL (United States, 1012013). STEL: 545 mgm? 15 minutes. STEL: 125 ppm 15 minutes. “TWA: 435 magi? 10 hours. “TWA: 100 ppm 10 hours, ‘OSHA PEL (United States, 2/2012) “TWA: 435 mg/m? Bhours. TWA 100 ppm 8 hours hevamethylane-diisocyanale ACGIH TLV (United States, 12018). TWA: 0.03 mgin® 8 hours ‘TWA. 0.005 ppm 8 hours. NIOSH REL (United States, 1012013). ‘GEIL: 0,02 ppm 10 minutes. CCEIL: 0.14 main 10 minutes. ‘TWA: 0.005 ppm 10 hours. TWA: 0.035 mgin* 10 hours, OSHA PEL United States, 22013), Abcorbed through skin. ‘TWA: § mp/m, (as CN} 8 hours. 312016). L Recommended monitoring procedures If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological montoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessily 1o use respiratory protective equipment Reference should b= made fo appropriate monitoring standards. Raference to national guidance documents for methods fer the ‘determination of hazardous substances will also be tequired. 8.2 Exposure controls Appropriate engineering controts Provide local exhaust and general ventilation systems to maintain irorne concentrations below OSHA, ACGIH, and marufacturer recommended exposure limits, Local exhaust ventistion is preferred because it prevents contaminant dispersion into work areas by ‘controlling tat is Source. Use local and general exhaust ventlation fo effectively remave and prevent buildup of rists/vaporsifunies generated from the handling of this product. Note: Local exhaust ventilation is designed to capture an emitted contaminant at or near its source, before the contaminant has a chance ta tienerse into the workplace ait. General exhaust ventilation also called dilution ventilation, ie diferent fram local exhaust ventilation because instead of capturing emissions at their source end removing them ffom the air, general exnaust venation allows the contaminant {0 be emitted into the workplace air and then diltes the concertration ofthe contaminant to an eccepiable level (e.g, to the PEL or below), 2: 5/13 HEMPEL'S CURING AGENT 95370 Quem: —: SECTION 8: Exposure controls/personal protection Individual protection measures General: Gloves must be worn forall wark that may result in soling. Apron/coveralls/protective lothing must be worn when soiling is so great that regular work clothes do nol adequately protect skin against contact with the product, Safety eyewear should be used when there is a likelihood of exposure. Hygiene measures: ‘Wash hands, forearms, and face thoroughly after handling compounds and before esting, smoking using lavatory, and at the end of day. Eyerface protection ‘Safety eyewear complying with an approved standard should be used when a risk assessment Indicates this is necessary to avokl excosure to guid splashes, mists, gases or dusts. If contacts possible, the following protection should be wom, unless the assessment incicales a highs degree of protection: chemical splash goggles. Hand protection ‘Wear chemica-resistant gloves in combination wth ‘basic’ employee training. The quality of the chemical resistant protective gloves must be chosen as a function ofthe specific workplace concentrations and quantity of hazardous substances, Since the actual work situation is unknown. Supplier of gloves should be contacted in order to find the ‘aporopriate typa, Belaw listed glove(s) should be regarded as genaric advice: Recommended: Siver Shield / 4H gloves, polyvinyl alcohol (PVA), Viton) ‘May be used: nitrile rubber, butyl rubber ‘Shor term exposure: neoprene rubber, natural rubber (latex), polyvinyl chloride (PVC) Body protection Personal protective equipment for the body should be selected based on the task being performed ang the risks involved handling this product. ‘Wear suitable protective clothing. Aways wear protective clothing when spraying, Respiratory protection working areas have insufficient ventilation, wear half or totally covering evask equipped with gas fiter cof type Organic Vapor, when grinding use particle fiter of type P95, P99 or P100, When spraying use a ‘combined fiter (organic vapar / HEPA or erganie vaper / P100 tyea). Ber ure to use approvedieertiied Tespirator of equivalent. Always wear an aired respirator when spraying ina continuous and prolonged wark situation (e.9, hood with supply of flesh or compressed air or a fll faoe, powered air purfying fter. Ee RS SRST S 4 ee We ‘Note: Application of paint products by spraying cequres edltional safety precautions: Full body suit respirator wih ar supplied Environmental exposure controls Emissions from vention or work process equipment should be checked to ensure they comply withthe requirements of environmental protection legislation, In some cases, fume scrubbers, fers or engineering medications to the process equipment will ba necessary to reduce emissions to acceptable levels. SECTION 9: Physical and chemical properties 9.4 Information on basie physical and chemical properties Physical stato: Liquid Oder Solventike oH “Testing nol relevant or not possibte due to nature ofthe product Meling pomntireezing point: Testing not selevant or not possible due to nature ofthe product. Boiling poinubotiny range ‘Testing nol relevant or nol possible due to nature of the product Flash point: Closed cup: 40°C (104°F) Evaporation rate Testing not relevant or not possible due to nature ofthe product Flammatilty ‘Highly flammable in the presence of the folowing materials or conditions: open famos, sparks and static discrerge and heat Upparflower flammability oF 08-7 v0l%, explosive its spor pressure 10.01 kPa This is based on data for the following ingredient: hexamethylene-,6-cisocyanate hamopolyner Vapor density Testing not relevant or aot possible due to nature ofthe product, Relative densiy 127 glen? Version: 0.05 ifety Data Shec HEMPEL'S CURING AGENT 95370 © HEMPEL SECTION 9: Physical and chemical properties ‘Sotubilty(es) ‘Very slightly soluble in the fotowing materials: cold water and hot water. Parition coefficient (LogKow}: Testing nat relevant or not passible due to nature af he product, ‘Autoigntion temperature ‘Testing not relevant or not possible due to nature ofthe product Decomposition temperature Testing not relevant or not possible due to nature ofthe product Viscosity: ‘esting nol relevant or nol possible due to nature ofthe product. Explosive properties Not available. Ovigizing properties, Testing not relevant or not possible due to nature of the produc Solvents) % by welght 25 % (ww) (Incteded excampt solvents) Water % by weight Weighted average: 0% ‘YOC content (Coatings) 2.23 losfoal (267.5 gi) VOC content (Regulatory) 2.23 Ioslgal (267.5 98 TOC Content (Vetatley Weighted average: 194 9 Solvent Gas Weighted average: 0.055 mn SECTION 10: Stability and reactivity 10.1 Reactivity [No specific test data related to reactivity available for this product or its inaredients 40.2 Chemical sta “The products stable, ity 10.3 Possibility of hazardous reactions ‘Under normal conditions of storegs and use, hazardous reactions will not occur. 1 Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do wl pressurize, cut, weld, braze, solder, dil, grind ar expuse containore to heat ‘sources of igniin. 10.5 Incompatible materials, Hight reacive or incompatible with the following materials: oxidizing materia Reactive or incompatible wit the following materals: reducing matarials, 10.6 Hazardous decomposition products When exposed to high temperatures (i. in case of fie} harmful decomposition products may be formed. Decomposition products may include the folowing materials: carbon oxides ritrogen oxides SECTION 11: Toxicological information 11.1 Information on toxicological effects Exposure to component solvent vapor concentrations may result mn adverse healt effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, live and central nervous system. Solvents may cause tame of the above affects by absorption hough the skin. Symptoms and sighe include heavachos, dizziness, fatigue, muscular weakness. drowsiness and, in extreme ‘cases, oss of consciousness. Repeated or pralor ged contact withthe preparation may cause removal of natural fat from the skin, resulting In non-sllergic contact dermatitis and absorption tirough the skin. If splashed in the eyes, the liquid may cause initaton and reversible damage. Accidental swallowing may cause stomach pain. Chemical lung inflammation may occur ifthe product is taken ino the lungs via vomiting. Isouyanate containing products have characteristics that include producing acute trtation andlor sensitisation when breathing, subsequent asthmatic problems end lung contractions. Sensitised people can, as a result from this, show asthmatic aymptoms with exposure to atmospheric concentrations far below the TLV, Repeated exposures will lead to permanent damege to the respiratory system. sion: 0.08 13 ty Data Sine 7 ; ; HiWPEL'S CURING AGENT 95370 ww HEMmrec SECTION 11: Toxicological information Acute toxicity Produclingredient ame Result Species Dose Bipesue Tevandtiiene-1Saisoeanaia | [CPO ntalaion ass ands a ar nom=poimer Lesotinaision owisendmits —— [rar 18 gt ‘hows {580 berm fal “zoo0 rats LDS0 Oral Rat 22500 mghkg avehon- tative acetate |LD80 Deal ra Sons tos ot fal seeps pone {Ese ion Gas, Fat 50 ppm ‘nous {G80 inaaion Vapor fat sso pon ‘hous {80 or fat #200 ota erenzene tee Demal Rabo zo00 maa {360 ot fat Ssromaha hexametyenediisceyancte |LOSO taton Cure andinste | Rat Sanger ren {so lnaaton vapor ral ciaengt aout tse Goma Ravbit Soa {bso or ran raomang Acute tonicity estates Route TE vaio ora Taina Tal Berna esi omg Inttaton gate) eaten en Inelton (por) S80 mgt Inston (sani) 2278 mat Intation/Corrosion Feat TSpevies | Score Eiposure Rexamatiyanes -lsocjarais | Stin= Wd lan abe ——- fomeroher joshi ra abt ; Rovian fant abot SHEER ametony-tmetyetyaceaio | Revbtay Mi tat rat Hel Eyer dita fate SHEL re fee Sores ant abot 2 fee houesmitgrams Ske Modesto rant rato [Bb pouts 500 maigrs tienzone Sen stat abot 2 enous 13 mibgans Fespiratoy “Mi tant abet uel Eyes diane Rabbi ee exanetivenetsccyarate | Stn Gove ant Rabe StH jes Severe Intent evo ae Respiatoy Sever intent ated SHEE sonaiteer Prosaageaertnene | Roadlaponwe Spacies esait, TeamatnjeneiBaisccyanate |r Guinea wa Sara remeromer nevanetyened-sccyanalo_fskn Guinea pa | sensing Carcinogen Classification A Productingredient name 1ARC NTP ‘OSHA rye z : Ptiteenzone : ‘Specific target organ toxicity (single exposure) Praductingredient name Category Route of exposure | Target organs hoxamethyiene-1 6-disocyanats hemopohmer lCaeguys Not applicable. Respiratory tract tration hexamethylene-diisocyanate [Category 3 Not applicable. Respiratory tract inition ‘Specific target organ toxicity (repeated exposura) Version: 0.08 Page: 813 safety Data S en HEMPEL'S CURING AGENT 95370 © HEMPEL SECTION 11; Toxicological information Productiingredient name Category | Routeofexposure | Target organs atiyibanzene [Caegoy2 Not daiciained | Reating organs Aspiration hazard Productingredient name Result 7 fahyiberzene ASPIRATION HAZARD - Category 7 Information on the likely routes of exposure Routes of entry anticipated; Oral, Dermal, Inhalation Potential chronic health effects ‘Sensttzation Contains hexamethylene-1,6-clisocyanate femopalymer, hexamethylene-1000 mgh Fahour homepalymer ethyboenzene Chronic NOEC <1000 pai Fresh water Pseudckirehneriella subesptata_|96 hours 12.2 Porsistence and degradability Productlingredient name Test Result tr Dose Inoculum Texenethylane-1e-disowyanate | ORCD301G Ready | 0%-Noleadiy-28 days IE omapalymes Blodegradabily- Modified MITI Test) lene 760 % -Rendly - 28 days | |. thytenzene - 270 % = Readily -28 days L heKamethylene-di-socyanate 42.54-Net readily -28 days E 5 Productingrodient name ‘Aquatic haltiite Photolysis Biodogradablliy Revameliyiene 1 Sdieeojanale |= > ~~ Tratreadiiy homopolymer Zametoxy-T-metbyethylacelate | - : Readily a/ene E - Readily ethylbenzene E : Readily examothylene-diisocyanate | : Notreadily 12.3 Bioaccumulative potential Productingredient name [__tesPee Bor Potential hexamethylene-t,6-disccynate homopolymer fats ser7 Tow 2smetnoxy-t-methyeiryl acetate 52. 7 tow Seyler 312 fa1-259 low ethylbenzene 36 - tow heyameshylene-tiisocyanate oc. 5783 ow | 124 Mobility in soil sion: 0.05 fety Data Shee ‘MPEL'S CURING AGENT 95370 © HEMPEL SECTION 12: Ecological information Sollwater partition coefticiant No known data avalabie in our database, (ee) Mobitty: No kaw data avaliable in our database, 126 Other adverse affects No known significant effects or eftical hazards, SECTION 13: Disposal considerations 13.4 Waste treatmont methods Disposal should be in accordance with applicable regional, national and local laws and regulations. Local regulations may be more stngent than regional or national requirements. ‘The information presented below only apples tothe material as supplied. The Identifcation based on characterstic(s) or listing may not poly if the material has been used or ollerwise contaminated. Its the responsiblity of the waste generator to determine the toxicity and ‘Physical propertes of the material generated to determine the proper waste identification and disposal methods in compliance with applicable regulations. Refer to Section 7 and Section 6 for addtional tandiing information and protection of employees. ‘The generation of waste should be avaided or minimized wherever possible. Disposel cf this product, solutions and any by-products should atalltimes comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements, Dispose of surplus and nor-recyciable products via @ licensed waste disposal contraotor. Waste should not be disposed of Untreated tothe sawer unless fully compliant withthe requirements ofall authorities with jurisdiction. Waste packaging should be racycled. Incineration or lanafil should only be considered when recycling isnot feasible. This material and ite container must be disposed atin a safe way. Care should be taken when handling erigtied containers that have not been cleaned or rinsed out. Empty containers of liners may retain some product residues. ‘Vapor from product residues may create a highly flammable of explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dishersal of spilled materiak and runoff and contact witn sol, waterways, drains and sewers. United States - RCRA Toxic hazardous waste "U" List, Ingredient cas # States Reference ‘number iene [Reezo7 fetes ae SECTION 14: Transport information Transport may take place according to national regulation or DOT for transport by road and by train, IMOG for transport by sea, IATA for Alt shipment. Refer to speoiic Dangerous Goods Transport requirements under 49CFR, ICAO and IATA. i °} a CERI en Pasge aces pod nani Ieee manne passe ‘only a reieuaove RO epee ai toneten tos UNI283.PAINT 3 No. Peis den pour |code {sslonsatne Teegarden IDG UNI263. PAINT 3 Code No. azesneracstces Ser untae PANT 5 Whe Cote . 2 HEMPEL'S CURING AGENT 95370 © HE iviai- SECTION 14: Transport information ark vt PAINT 3 WN code g ‘Code : Oassiication PG" Packing group Env"! Environmental hazards 14.6 Special precautions for user Transport within user's premises: always transport in closed containers thal are upright and secure, Ensure that porsons trarsporting the product know wnat io do in the event of an accident or spilage, 414.7 Transportn bulk according t> Annex ll of MARPOL and the IBC Code Not applicable SECTION 18: Regulatory information 16.1 Safety, health and environmental regulations/legislation specific for the substance or mixture U.S. Federal regulations [All components are listed or exempted TSCA 8(a) PAIR: 2-methoxy-1-methylethyl acetate TSCA 8{a) CDR ExempUPartial exemption, Not determined United States inventory (TSCA 8b): All components are listed or exempted. ‘TSCA 8{e) calls for record of SAR: hexemethylene-diisocyanate ‘Clean Water Act (CWA) 307: ethylbenzene, nexametnylene-desocyanate Clean Water Act (OWA) 311: xylene; ethylbenzene Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs) Listed os Himba ao ayer Tae Ta ~ ea a By lar isinpne Be ile lean Air Act Section 602 Class | Substances Not listed Clean Air Act Section 602 Clase Ii Substances: Notlisted DEA List | Chemicals (Precursor Chemicals) : Not listed DEA List U Chemicals (Essential Chemicals) + Nol listed SARA 302/904 SARA 211/312: SARA 302/304: No procucts wore found. SARA 311/312 Hazards identification: Fire hazard, Immediate (acute) health hazard, Detayad) (chron) health hazard Procter nae % | Fatwa | sodden | passive | tomes ayes renee ot facta neatn | ehrone) pressure ‘azteca a =e Te co = 1 into ow ae woz | ves bs te ta, he ‘ane wie | ve te t ts te Specie na [se te ts vee es Fetineryane sco Bios [te he ts ve te SARA 313: ‘SARA 313 natiieatons musi nol be detached from the MSDS and any copying and redisirbution of the MSDS shall include copying and redistribution ef the notice attache to copes of tne MSDS subsequently redistnbutes, Form R - Reporting roquirements : ‘Pralucnareieatrane Svar Coneenan Supplier notification : Prousctingreent oe CAS ramber cone hens ose ny safety Data Sh HiEMPEL'S CURING AGENT 95/0 © HEMPEL SECTION 18: Regulatory information State regulations = Connecticut Carcinogen Reporting: None of tre components ar listed. Connecticut Hazardous Materia! Survey. None of the components are liste. Florida substances: Nane of the components are listed Ilinois Chemieai Safety Act: None of the components are sted. Minot Toxic Substances Disclosure to Employee Act: None of the components are listed. Louisiana Reporting: Nana of the components are listed, Louisiana Spill None of the components are listed. ‘Massachusetts Spill: None of the components ae listed. Massachusetts Substances: The follwing components are sted: XYLENE, DIMETHYLBENZENE: ETHYL BENZENE: ETHYLEENZENE. Michigan Critical Material: None of the components are sted, Minnesota Hazardous Substances: None of the components are listed, New Jersey Hazardous Substances: The following components are listed: XYLENES; BENZENE. DIMETHYL ETHYL BENZENE; BENZENE, ETHYL Now Jersey Spill: Nave cf the components are listed. Now Jersey Toxic Catastrophe Prevention Act None of the components are listed. Now York Acutely Hazardous Substances: The following commpanents are sted: Xylene moeed: Ethyibenzene New York Toxic Chemical Release Reporting: None of the components are fisted. Pennsylvania RTK Hazardous Substances: The folowing components are listed: BENZENE, DIMETHYL: BENZENE, ETHYL~ Rhode Island Hazardous Substances: None of the components ar listed California Prop, 65 PFF : WARNING: This product contains & chemical known ts the State of Caillenia to cause cancer, ve © Tae ieee [Re Liar tate SECTION 16: Other information Remarks Note: in USA, consult Code of Faderal Regulations, Title 29, Labor, Paris 1910 and 1815 conceming ‘occupational safety and health standards and regulations, as well as arty other applicable Federal, ‘State or local regulations that apply o safe practices in coating operations. Warning! If you scrape, sand, or remove old pave, you may release lead dust, LEAD is TOXIC. Validation Validated by US - HSE Products Coordinator on 21 September 2018 Procadure used to derive the classification, | ‘Siassification | Justification FLAMMABLE LIQUIDS - Category 3 ‘Ga basis ofest data JAGUTE TOXICITY (inhalation) Category 4 Calculation method SKIN IRRITATION - Category 2 Calculation mathod SKIN SENSITIZATION - Category 4 Galewation method CARCINOGENICITY - Cafegary 2 SPECIFIC TARGCT ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract iitation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (Rearing organs) - Calenary 2 Calculation method Cateulaion method Calculation method azedous Matera formation System (USA) ‘loca Fr Protection Anocition USA = “O= rel Pini erat Pc nh min enon, ce nay rw en nao crt iy fey ath pen Com tant ‘Na1=Anacan tional ier ate 60» orprention to EcoromieCo-perato an Delp FROG =Aaznrdus Corman Spa BoE bicomntin Fe {estes bts Corl Borie Site eparer ramperten ous ener Hea ‘arapor Dargo oath, Canada et taraporaion¢Carmurcetore eer, en inane er Grapevorst Sey ses island sins Bae Ses tage ex Reaatn on Cea ‘Sta "Sigers eras Rosabren ct Nihal Torey Popa Ebb ea > Ehergeey Pang etcammanty HOR Row ion. 0.08 ty Data Sheet aa HEWPEL'S CURING AGENT 95370 ini iL ‘SECTION 16: Other information Notice to reader 7 ndicates iforration that has changed from previously issued version To the best oF eur knowledge, the information contained herein is accurate ‘However, neither the above named supplier nor any af is subsidiaries assumes ary ltilty whatsoever for tke accuracy or completeness ofthe information contained herein. Final determination of sutebity of ary material isthe sole responsibilty of tho user, All materials mey present unknewn hazards and shouldbe Used with caution, Altyough oerain hazards are Gescribed herein, we cannot guarantee thet these are the only hazards that exist Yarsion: 0.08 Page 13/73 HEMPADUR 15579 HEMPADUR 15579 oO HEMPEL Conforms to ANSI 2400.1-2010 Standard - HES 2012 Prleche Cin Cereal oF See hte GOSH oe ‘SECTION 1: Identification of the substance/mixture and of the company/undertaking 4.4 Producten Produc name HEMPADUR 19679 Product dnty tesrett203 Prodi pe enor ime [bse or masons oil 4.2 Relevant identified uses of the substance or mixture and uses advised against Field of application buildings and metal industry. ships and shipyards. Ready-foruse mixture : 115570 = 18579 3 vol / 955701 vol 15571 = 18579 4-vol / 95040 1 yok entified uses IndustiauProtessional use TSCA Unlese otherwise stated All components are listed or exempted, 4.3 Details of the supplier of the safety data sheet Company details HEMPEL (USA), Ins, 80) Corvae Park North Drive Conroe, Texas 77303 Toll free: (800) 678-6641, ifoutside area codes 713, 261, 409, 996 Regular phone number: (825) 523-6000 E-mail Hempel@Hempel.com 4.4 Emergency telephone number (with hours of operation} For Transportation Emergencies: CHEMTREC: 1-800-424-9300 (Toll-free in the U.S., Canada and the U.S. Virgin Islands} 703-627-2867 (24 hours} For calls originating elsewhere (Collect sas are acceptad). Contract number, CCN10384 To preserve the effectiveness of arrangements for providing accurate and timely emergency response Information, the basie dentitying information (shipper name or contrast number) must be included on shipping papers. Ir the purchaser ofthis produet 2s gaing to be shipping this product to other locations, the purchaser ‘must arrange for its on Emergency Information Provider to respont to transport incidents, Hempels 24 hour response contract does not cover nan-Hempel shipments. For all other information Jn USA tol free calling available: 1-800-878-5641 or (936)-523-6000 (GAM-SPMCST) See Section 4 of the Safely deta sheet (frst aid measures). ‘SECTION 2: Hazards identification 2.4 Classification of the substance or mixture OSHAIHCS status “This material is consiaared hazardous by the OSHA Hazard Communication Standard (29 GFR 1940, 1200), GHS Classification FLAMMABLE LIQUIDS - Category 3 ACUTE TOXICITY finhalaton) ~ Category 4 SKIN IRRITATION - Category 2 ‘SERIOUS EVE DAMAGE - Category 1 SKIN SENSITIZATION - Category 1 CARCINOGENICITY ~ Categary 1A SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs and lunge) Category 1 2.2 Label elements ata Sheet , EW. ADUR 15579 Ww HEMPEL SECTION 2: Hazards identification Hazard pictograms Signal word Mazard statements: Precautionary statements : General Prevention Response Storage Disposal ‘Supplemental label elements 2.3 Other hazards Hazards not otherwise classified > OOOH Danger 14226 - Flammable liquid and vapor 352- Harmful ifinhaled. 318 - Causes erious eye damage. 315 - Causes skin iitation, H317 - May cause an allergic akin reaction H350- May cause cancer, 1372. Causes damage to organs through prolonged or repeated exposure. (hearing organs, lungs) Read late’ before use, Keep out of reach of children. If madical advice is needed, have product Container or label af hand. CObiain special nsructons before use, Do not hancle untl ail safety precautions have beon read and Understood. Wear protective gloves, Wear eye er face protection. Wear protective clothing, Keep away from heay, Nol surfaces, sparks, open flames and other ignion sources, No smoking. Use ‘explosion-proof electrical, ventilating, lighting and all materal-hanaling equipment, Use only non- ‘parking tools. Take preceutionary measures against static discharge. Keep container tightly closed. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Do nat eat, drink or smoke wien Using th product. Wash hands thoroughly after handling. Contaminated work clothing must not be allowed out ofthe workplace, Get madical attention ifyou feel unwell, IF expased or concerned: Get medical attention, IF INHALED: Remove person to fresh air anc keep comfortable for breathing. Call a POISON CENTER or physician ityou feel unwell. IF ON SKIN (or nal): Take off immediately all contaminated cbrhing. Rinse skin with water or shower. IF CN SKIN: Wash with plenty of soep and water, Wash contaminated clothing before reuse, If skin irteton or rash occurs: Get mecical attention. IFN EYES: Rinse cautiously vith water for several minutes. Remove contact lenses, if present and easy to do, Gentinue rinsing, Immediately call a POISON CENTER or physician Store locked up, Store in a wel Iventilated place. Keep cool, Dispose of contents and container in accordance with all local, regional, national and international regulations. None known, None known, SECTION 3; Composition/information on ingredients Product definition inture Physical state: Liquid, Productingredient name Identifiers eat GHS Classification yene 1380-207 210-525 | FLAVMABLE LIQUIDS - Catogory 3 midale molecutar epoxy resin MMW 7001200 Tale ethylbenzene butanol on: 0.02 ‘ACUTE TOXICITY (dermal) Category & ACUTE TOXIGITY inhalation) - Category 4 SKIN IRRITATION = Category 2 -zs068-26-6 [210-225 | SKINIPRITATION - Category 2 EYE IRRITATION Category 24 SKIN SENSITIZATION - Category 4 sas07-9¢-8 — | 210-325 | Netcast. 100-414 23.25 FLAMMABLE LIQUIDS - Category 2 ‘ACUTE TOXICITY (inhalation) = Category 4 CARCINOGENICITY - Cateuery 2 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (heating organs) - Category 2 ASPIRATION HAZARD - Category 1 FLAMMABLE LIQUIDS - Category 3 ACUTE TOXICITY (oral - Category 4 71363 Page 2114 HEMPEL HEMPADUK «22.9 SECTION 3; Composition/information on ingre ‘SKIN IRRITATION - Category 2 SERIOUS EVE DAMAGE - Category 1 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE} (Respiratory tract inftaion) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) Blarcotc effects) - Category 3 titanium siecle 13463-877 Not easafed n-butylacetate 123-864 FLAMIMBBLE LIQUIDS - Catagory 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic efects|= Catagory 3 respirable quartz 44808-60-7 CARCINOGENICITY - Category 1A, SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE} llungs) (intalation) - Category 1 Sbie{12hydroryoctadecanamiéen- | 126554529 | st SKIN SENSITIZATION Gatevory 4 ethyle)benzene ‘Any concentration shown ag a range 0 protect confidentialiy cri due to batch variation “There are no ingredients present whict, within the current knowledge ofthe supplier and in the concentrations applicable, are classified as hazardous fo health or the environment and hance require reporting in this section, SECTION 4: First aid measures 44 Description of firet ald measures General: In a¥ cases of doubt, or wnen symptoms persist, seek medial attention, Never give anything by mauth to an anconsciows person breathing is regular, drowsiness, loss of consciousness or cramps: Catt 011 and give immediate treatment (frst id). Eye contact Check for and remove any Contact lenses. immediately Nush eyes with plenty of water for a feast 15 ‘minutes, occesionallyliting the upper and lower eyelids. Seek inimediate medical alletion, Inhaiation Remove to fresh air, Keep person warm and at rest, Ifnat breathing, If breathing is rregutar or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Give noting by ‘mouth, If unconscious, place in recovery position and yet medical attention immediately Skin contact Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recagrized skin cleanser. Do NOT use solvents or thinners, Ingestion I swallowed, seek medical advice immediatoly and show this container or label. Keep person warm anat est Do not induce vamiing unless directed to do so by medical personnel Lower the head so ‘that vowit will not re-enter the mouth and throat. Protection of frst-aiders 'No action shall be taken involving any personal risk or without suitable training, Ifit is suspected that ‘fumes are stil present, the rescuer should wear an appropriate mask or sell-contained breathing ‘apparatus. It may be dangerous to the person providing aid to give mouth-to-moulh resuscitation, ‘Wash contaminated clothing thoroughly with watar before removing it, or wear gloves, 4.2 Most important symptoms and effects, both acute and delayed Potential acute health effects Eye contact Causes serious eye damage Inhalation: Harn ifn Skin contac Causce hin tation. May cause an argc shin reaction, Ingestion Ne known scant effects or ctica hazards Overexposure signstsymptoms Eye contac ‘Adverse symptoms may includ the falling vratering rodnese inition No specie data Skin ont Adverse sympioms mey include the following pan niaton bistering may occur sata Sheet isEMPADUR 15579 HEMPEL SECTION 4; First aid measures, Ingestion Adverse symptoms may include the folowing: stomach pins 43 Indication of any immestate medical attention and special treatment needed Notas o physician Not applicable Speciic reetmens No specif treatment SECTION §: Firefighting measures 5. Extinguishing media Extinguishing media Recommended: alatiol resistant foarn, CO2, powders, Not to bo vsed! watoret. 8.2 Special hazards arising from the substance or mixture Hazards from the substance or Flammable quid and vapor, In a fie or heated, a pressure increase will ccur and the container may site Durst, with the risk of a subsequent explosion, Runoff to newer may create fia or explosion hazard, ‘This material is toxic to aquatic Ifa with long lasting effects, Fire water contaminated with this material ‘ust be Contained and prevented from being discharged to any watentay, cewer or drain. Hazardous combustion products: Decomposition products may include the following materials: carton oxides halogenated compounds metal cxide/oxides. 5.3 Advice for firefighters Promptly isolate the scene by removing all persone Iam the vicinity ofthe Incident i there is fie. No action shall be taken involving any ‘personal isk or without sultabe training. Fre will produce dense black amake. Exposure fo decompasiton praducts may cause a healty hhazard, Coo! closed containers expased to f¥e with water. Do not release sunoff fom fre (0 drains or watercourses, Fite-fighters shold ‘wear appropriate protective equip ent and self-contained brenthing apperetus (SCBA) with a ful face-piece operated in postive pressure mode, SECTION 6: Accidental release measures 6.4 Personal precautions, protective equipment aid emergency procedures ‘Avoid all diet contact with the spied material. Exclude sources of ignition and be aware ef explosion hazerd. Ventlate the area, Avoid breathing vepor or mist, Refer to protective measures isted in sections 7 and 8, Na action shall be taken involving any personal sk ce ‘without suitable training, Ifthe product contaminates lakes, rivers, or sewers, inform the appropriate authorities in accordance with local regulations, 6.2 Environmental precautions Avoid dispersal of spilled material and runoff and contact with sel, waterways, drains and sewers. Infarm the relevant authorities if the product has caused environmental polluion (cewers, watorways, Sol or alr). Water pouting tmateral. May be harmful tothe environment if refzased inlerge quantities. 6.3 Methods and materials for containment and cleaning up ‘Stop leak: without risk. Move containers from spil area, Approach release from upwind, Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effuent treatment plant oF proceed as follows, Contain and collect spilage with non- ‘combustible, absorbent material e.g, sand, earth, vemmiculte or diatomaceous eath and place in container for dispasal according to local rogulations (see Section 13). Use spark-proof tools and explosionproof equipment, Contaminated absorbent material may pose the same hhazatd as the spiled product 6.4 Reference to other sections ‘See Section 1 for emergency contac! information See Section § for inforration on apsropriate personal protective equipment See Section 13 ‘or addtional waste treatment information. Jata Sheet HEMrADUR 15879 © HEMPEL SECTION 7: Handling and storage 7A Precautions for safe handling \Vapors are heavier than air and may spread along loors. Vapors may form explosive mixtures with ai, Prevent the creation of flammable ot explosive concentrations of vapors in and avoid vapor concentrations higher than the occupational exposure mits. In addition, the raduct should be used only in aes from which all naked lights and cther sources of ignition have been excluded. Electrical equipment Should be protected tothe appropriate standard, To dissipate static electricity during transfer, eround drum and connect to receiving ‘container with bonding strap. No sparking tools should be used. Contains epoxy constituents, Avoid all possible skin contact with epoxy and amine containing products, they may cause allergic reactions. Avoid inhalation of vapour, dust and spray mist, Avoid contact with skin ard eyes. Eating, drinking and smoking should be pronibited In area ‘Where this material is handled, stored and processed, Approp‘ate personel protectve equipment. see Section 8, Alaays keep in containers Trade from the same material as the original one. 7.2 Conditions for safe storage, including any incompatibilities Store In accordance with local cegulations, Store in a cool, well-ventilated area away from incompatibla materials and ignition sources. Koop out of the reach of children. Keep away fram: Oxidizing agents, strong akalis, song acids. No smoking. Prevent unauthorized ‘access. Corfainers that are opens must be carefully reseafed and Kept upright to prevent leakage. 7.3 Specific end use(s) ‘See separate Product Data Steet for recommendations or industrial sector epecific solutions. Tihs prockict may 2e applied using several application techniques and methods of hanaling may be differant for each. Application ‘techniques include [but are not limited to] brushing, olin, and spray application [eonventonal, HPLV, airless, pleural component or ‘aerosol can], Avo the breathing of vapors and, if spraying, do not breath spray mist or aeresols. SECTION 8: Exposure controls/personal protection 81 Control parameters I ona ans leven "ACGIH TLV (United States, 3/2016). STEL: 651 mgm? 15 minutes. STEL: 150 ppm 15 minutes. TWA. 434 mgin® 8 hours. TWA: 100 ppm 8 hours. OSHA PEL (United States, 612016) TWA: 436 mali? & hours. TWA: 100 ppm 8 hours, ACGIH TLY (United States, 3/2018)- TWA: 0.1 fle 8 houre. Form: Respicable fibers: length greater than § uM: aspact ‘allo equal oor greater than 3:1 as determined by the membrane fter methed at 400-450X magnification (4-mim shjective) chase contrast lluranation. MOSH REL (United States, 1072019) “TWA: 2 main 10 hours. Farm: Respirable fraction ‘OSHA PEL 23 (Unltad States, 6/2016). “TWA: 0.1 Vee 8 hours. Form: containing asbestos SSTEL: | fee 30 minutes, Form: containng asbesios ACGIN TLV (United States, 3/2016}, TWA: 20 ppm 8 hours. NIOSH REL (United Siates, 1012043), ‘STEL: 545 mgtnt 15 minutes, STEL: 125 ppm 15 minutes. “TWA: 435 maim? 40 hours. “TWA: 109 ppm $0 hours, OSHA PEL (United States, 6/2016), “TWA; 435 mgim® 8 hours. “TWA: 100 ppm 8 hours. ACGIH TLV (United States, 3/2016) “Twa: 20 ppm & hours. NIOSH REL (United States, 10/2013). Absorbed though skin, CCEIL: 160 main? CEIL: 50 9pm OSHA PEL (United States, 6/2016), TW: 300 mgm? 8 hours. TWA. 100 ppm & hours, (OSHA PEL (United States, 6/2016) rate thyibonzene utanat titanium dioxide age: S14 HEMPEL HEMPADUR 15579 SECTION 8: Exposure controls/personal protection TWA: 15 magin® 8 hours. Ferm: Totat dust ACGIH TLV (United States, 32016). ] TWA 10 mgin® 8 hours. NIOSH REL (United States, 1072013). STEL: 950 mai 15 minutes, STEL: 200 ppm 15 minutes, "TWA 710 main? 19 hours. “TWA. 150 ppm 10 hours. OSHA PEL (United States, 8/2016), TWA 716 main? & hours. TWA: 150 ppm 8 hours. ACGIH TLY (United States, 32016), STEL: 159 ppm 15 minutes. ‘TWA’ 50 ppm 8 hours. respirable quart OSHA PEL 23 (United States, 6/2016). TWA: 250 mppet | (10245) 8 hours. Form: Resplrabie TWA: 10 mglmn'/ (%sSi0242)8 hours. Farm, Resprable OSHA PEL (United States, c'2016). “TWA 50 jg’ & hours, Form: Respirable dust ACGIH TLV (United States, 12076). TWA 0.025 mgim®& hour. Foon: Reapirable fraction NIOSH REL (United States, 10/2013). TWA: 0.05 mgin* 10 hours. Form: respirable dust n-butyl acetate Recommended monitoring procedures IF this product containe ingredients with exposure limits, 2ersonal, workptace atmosphere or biological monitoring may be required ta determine the effectiveness ofthe ventilation or other conirol measures andior the necessity to use respiratory protective equipment. Reference shauld be made to appropriate monitoring stzndards, Reference to national guidance documents fer methods for the determination of hazardous substances will also be required. 8.2 Exposure controls Appropriate engineering controls Provide local exhaust and ganeral ventilation sysiems to maintain airborne concentrations below OSHA, AGGIN, and manufacturer recommended exposure limits, Local exhaust ventilation is preferred because t prevents contaminant dispersion into work areas by controling tat its source. Use local and general exhaust vectiation to effectively remave and prevent buildup of mists/vaporssiumes ‘generated from the handling ofthis produ. Note: Local exhaust ventilation is designed to capture an emitted contaminant ator near its source, before the contaminant has a chance to disperse into the workplace air, General exhaust ventlation, also called dition ventilation, 1s diferent from focal exhaust ventlation because instead of capturing missions al tair source and removing them from the air, general exhaust ventiation allows the contaminant to be emitted into the workplace air and then dilules the Concentration of the contaminant to an acceptable lavel e.g, to the PEL ur below). Individual protection measures General Gloves must be worn for al work that may result in ailing. Apronicaveralsfprotectve clothing must be ‘worn when soiling is so great that regular work clothes do not adequately protect skin against contact vith the product. Sfety eyewear should be used wher there is likelincad of exposure. Hygiene measures: Wash hands, forearms, and face thoroughly ater handling compounds and before watiny, sinoking, using lavatory, and al the end of day. Eyeltace protection Selety eyevrear complying with an approved standard should be used when e risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the folowing protection should be wom, unless the assessment indicates a higher degree of protection: chemical splash wagoles andlor face’shield. 1f inhalation hazards exis, a ful-face Tespirator may be required instead, Hand protection Wear chemicalesistant gloves in combination with ‘basic’ employee training, The quality of tha ’hemical-resistant protective gloves must be chosen as a function ofthe spacsfic workplace ‘concentrations and quantty of hazardous substances. Since the actual work situation is unknown. Supplier of glaves should be contacted in order to find the appropriate type, Below listed glove(s) should be regarded as generic advice: Recommended: Silver Shield J 4H gloves, polyviny alcohol (PVA), Viton® May be used: nitrile subber, neoprene rubber, butyl rubber ‘Short term exposure: natural rubber (ltex), plwinyl chloride (PVC) Data Sheet HEMPADUR 18579 HEMPEL ‘SECTION 8: Exposure controls/personal protection Body protection Fersonal protective equipment for the body should be selected based on the task being performed and the risks involved handling this pradtct Wear suitable pratectve dothiig, Always wear protective clothing when spraying. Respiratory protection working areas have insufficient ventilation, wear half or totally covering mask equipped with gas flter ‘of type Organic Vapor, when grinding use particle fier of type Pa5, P99 or P100. When spraying use & combined fer (organic vapor / HEPA or otganic vapor / P100 type). Be sure to use approvedicertitied respirator or equivalent, Always wear an ait-fe¢ respirator when spraying in @ continuous and. prolonged work situstion fe 9 hond with cupply of fresh or carspressed air of a ful ana, powered air purifying fits revved de ie Note: Apolication of paint products by spraying requires additional safely precautions: Ful booy sui ul face respirator wth ar supplied Environmental oxposice controls Emiesios form ventlaton or work process equipment should be checkos to ensure they comply wit he requtements of environ pictacion logiaton. Insome cases, fume seruters, lcs or engneerng modcetansf0 he process equipment al be neceneay 12 ‘edice emissions to acceptable aves SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties Physical state Ligui. (Oder: Solventsike pH: “Testing not relevant or not possible due to nature of the product, Melting pointtreezing point “Testing no! elevant ar not possihle due to nature of the product Bolling polnuboling range “Testing not relevant or not possible due to ature of the product. Flash point Closed cup: 25°C (77°F) Evaporation rate Testing not relevant or not possible due to natura of the product. Flammabiliy Highly lammabie in the prosence ofthe fllowing materials or conditions: open flames, sparke and static discharge and heat. Flammable in the presence of the folowing materials or conditions: oxidizing matertas. Upparilower fammatilty or 08-11.3901 % explosive limits “apor pressure “Testing not relevant or not possible due to natura of the product, ‘Vapor density ‘Testing not relevant or nol poesible due to nature of the product Relative density 1.381 giem* Solsbiy(les) Parially soluble in the following materials: cold water and hot water Patttion coefficient (LogKow): Testing not relevant oF not possible due to nature of the product. Auio-gnitin tomperature esting not relevant or not possible due to nature ofthe product. Decomposition temperature ‘Testing nat relevant or not possible due to nature of the product. Viscosiy “Testing nat relevant or not possible due {0 nature ofthe product. Explosive properties : Explosive in the presence of the following materials or conditions; opon flames, sparks and stave discharge and heat. Oxicizing propertios, “Testing not relevant or nat possible due to nature of the product. 9.2 Other information Solvent(s) % by weight 31.3 % (ww) Uncluded excempt solvents): Water % by weight Weighted average: 0 ‘VOC enntent (Coatings) 3.61 Iosigal (432.6 af) Ve content (Regulatory) 3.61 bbsigal (432.6 gM) TOC Content (Volatile) Weighted average: 372 gl Version 0.02 P t a sr«ma: HEMPADUR 15879 Ode ee SECTION 8: Physical and chemical properties, Solvent Gas Weighted average: 0.102. SECTION 40: Stability and reactivity 10.1 Reactivity [No shecifc test data related to reactivity availabe for this product o ts ingredients, 410.2 Chemical stability ‘The products stable. 10.3 Possibility of hazerdous reactions Under normal conditions of storage and use, hazardous reactions wil not occur 410.4 Conditions to avoid ‘Avoid all possible sourcas of gniian (snark or lame). Do not pressurize, cut, weld, braze, aoe, dil, grind or wxpose containers to eal ‘or sources cf ignition. 10.5 Incompatible materials Highly reactive or incompatible ith the following materials: oxicizing materials. Reactive or incompatible with the folawing materials: reducing materials. 10.6 Hazardous decomposition products ‘When exposed to high temperatures (Le. in case offre) harmful decomposition products may be formed: Decomposition products may Include the following materials: carbon oxides halogenated vompounds metal oxidelaxides SECTION 11: Toxicological information 11.4 Jofermation on toxicotagical effects Exposure te component sclvent vapor concentrations may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, ver and central nervous system, Solvents may cause some of the above effects by absorption through the skin, Symptoms and signs include headaches, dizziness, fatigue, muscular weakness, drowsiness and, in exreme cases, toss of consciousness. Repeated or prolonged contact with the preparation may cause removal of natural fat from the ski, resuling in non-allergic contact dermatitis and absorption through the skin. I splashed in the eyes, the quid may cause iron and reversible damage, Accidental swallowing may cause etomach pain, Chemical lung inflammation may occur If he product is taken into lhe lungs via vomiting, Epox and amine containing products can cause skin disorders such as allergic eczema. The allergy may arise after only a short exposure period. Acute toxlity Prodictingediont name Result I Dose Exposure Ssfere TESb nkaaton Gas Tat DORI Trou 180 Inslaion Vapor Rat 6350 pr ‘hours LBg0 Dermal abi saaoimgts | Dep Oral Rat 3523 malta : tigate molecular epoxy rosin MMW | LEO Derm at Seo00meka | 70-1260 stnibenzons £080 Dermat abst ssooomgng | = {DEO Ora fat 3600 moka : butanol 1050 lnalaion Vapor at 2aooomamn? | hous LDg0 Dem Rabbi hod mag ‘ LDs0 Or Rat eomat : anim dioxide esc innate Dustsandmiste {Rat Semon ‘hous Ube Dem Rabbi 3so00mona |: {bse Oral fat ssnoomerg |= rot aoetate 160 ination Vapor Rat 221 mh ‘bourse 1550 Sermat Rabo Xaremoks | bs Ora Rat iarsamaro | 132a(12nerooct- {B50 Derma Rat rooms | dbcanamiceNcnetiylejanzere Uso rat at 2000 make f= Version: 0.02 ‘ety Data Sheet i1EWMPADUR 15579 © HEMPEL SECTION 11: Toxicological information Acute toxicity estimates Route ATE value Oral Base matg Dermal 4948.8 mola Inhalation (gases) 191538 ppm Inhalation vapors) 42.95 mol Iritation(Corrosion Produetingredient name Result Species | Score Exposure ane Eyes Severe ivtant Rabbi fat hours 5 miligrame SSkin= Moderate intant Rabbit 4 [24 hours 500 mnitigrams Tae ‘Skin Midian Human H }72 hours 300 Micrograms intermitient ethylbenzene ‘Skin = Mid iitant Rabbit a [24 hours 15 miligrams Respiratory - Mid iritant Rabbit : i Eyes Mid intent Rapbit ‘ n-butanol Eyes - Severe irtant Rapbit 2 [24 hours 2 miigrams ‘Skin Moderate iritant Rapbit e !24 hours 20 miligras ttanium dioxide ‘Skin= Mild intant Human z 72 hours 300 Micrograms Intermittent -buty! acetate ‘Skin - Moderate iritant Rabbit H 24 hours 500 miligrams Eyes - Mi intent Rabbt 4 | Respiratory - Mid iritant Rabbit z [ Sensitizor Productiingredient name | Route of exposure ‘Species Result middle molecular epoxy resin MMW [ski Guinea pa ‘Sensing 700-1200, Carcinogen Classification Productingredient name TARE NTP ‘OSHA yen 7 = 7 Tale 1 : 7 ethytbenzene 2B : 7 tain dioxide 2B - 7 respirable quartz 4 Known tobe a human carcinogen ‘Specific target organ toxicity (single exposure) Productingredient name Category _| Route ofexposure | __ Target organs butanol (Category Not applicable! Respratoy vac iritation and Nareatic fects n-butyl acetate [Category 3 Not applicable. Nareolic effects ‘Sporilie target organ toxlelty (repeated exposure) a Productiingredient name Category Route of exposure | Target argans thyfoenzene (Category 2 Not detemined [hearing organs respirable quartz Category 1 Inhalation lungs Aspiration hazard Productiingredient name Result ethylbenzene [ASPIRATION HAZARD - Categary 7 Information on the likely routes of exposure Routes of entry anipated: Oral, Dermal, Inhelaton. Potential chronic health effects Sensitization Contains middle molecular epoxy resin MMW 700-1200, 1,5-bis(12-hydroxyocta-decanemide-N- methyle)benzene, May preduce an allergic reaction, ‘Other information No additional known significant effects or erica hazards, Page oft ata Shee HEMPADUK 15579 SECTION 12: Ecological information 424 Toxicity De not allow fo enter drains or watercourses. Toxic to aqua ffe with long lasting effects ‘When spilled, tis product may act as an oi, causing a film, sheen, emulsion, or sluxge at or beneath the surface of a body of water. Oils of ‘ny kind can cause: (a) drowning of waterfowl due to lack ef buoyancy, loss of insulating capaciy of feathers, starvation end vulnerability to predators due to lack of mobility fo) lethal effect an fsh by coating ail auriaces, preventing respiration; () potential fish kill Tesulting from alteration in biochemical oxygen demand; (d) asphyxaton of berthic life forms when floating masses become engaged wth surface debvis, and settle on the bottom, and (e) adverse aesthetic effects of fouled shoreline and beaches. Productlingredient name Result Species riddle molecular epoxy resin MMW | Acute ECHO 100 mgi Daphne ‘roo-t200 Acute L050 >100 ment Fish os hours ethylbenzene Chronic NOEG «1000 ugil Fresh water Algae -Pseudckirchneriella subcapitata.|5 hours p-butanol ‘Route ECO 1828 mal Daphnia 98 hours ‘Route LC5D 1.976 mgt Fish 98 hours tanium dioxide ‘Route LSD >100 mah Daphnia 48 hours ‘Asuto LCSD >100 mg Fish [e6 hours bat acetate Acute ECSO 648 mt Algae 72 hous Acute EG50.44 mg Daphnia a8 hows 1. 2bis(12-hydroxyocta- ‘Acute LC¥O > 100 mail igae 172 roves Jdccanamide-A-mathyle)benzene cule LOE0>109 mg Fish 96 hours 12.2 Persistence and degradability Productiingrediont name Test Result Suse Troculum ene = 360% Readily-28 dave etyibenzene " 270% -Readily-28 days, ' 7 n-butanol ‘OECD 3010 Ready | 62 %- 20 days i 5 Biodegradatity = Closed Bottle Test n-butyl acetate i“ 80% - Readily-28 days yi - 4 3bis(12-hydroxyocta- : 5% 28 days 5 : decanamide-N-mathyo}benzona Productfingredient name ‘Aquatic halt-lte Photolysis Biodegraaability "iene 7 Roady ethylbenzene : Readily n-butanol < Realy butyl acotate EB z Readiy 1,Sbis(12-Nydroxyocts- : Not readily | decanamide-Nsmethye}benzene {8 Bioaccumnulative potential Producvingredient name LogPa= ‘cr Potential ‘wfene fat jaro Tow riddle molecular epoxy resin MANNY 700-1200, 264-378 31 ow ettyibenzene FE : ow butanol fl 3.16 low but acetate za 34 low 12.4 Mobility in soil ‘Sollwater partion coefficient (Kee) Mobitiy 126 Other adverse effects No known data avaiable in our database, No known data avaliable in our database. [No known significant affects or ertical hazards, Version: 0.02 fety Data She riEMPADUR 15879 Oo HEMPEL SECTION 13: Disposal considerations 13.1 Waste treatment methods Disposal should be in accordance with applicable regional, national and local laws and regulations. Local regulations may be more stfingent than regional or national requirements, The information presented below only apples to the material as supplied, The identification based on charactetistic(s) or sting may not ‘apply ifthe material has been used or otherw/se contaminated, Iti the responsibilty af the waste generator to determine the foxily and physical properties of the material generated to determine the proper waste identification and disposal methods in compliance with ‘applicable regulations, Refer to Section 7 and Section 8 for additional handing information and protection of employees. “The generation of waste should be avoided or minimized wherever possible, Drain all material fram containers to maximize use and ‘minimize waste dispose, Disposal ofthis product, solutions and any by-products should at all imes comply wih the requirements of environmental protection and waste disposal legisation and any regional local authority requirements, Dispose of surplus and non recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreatad to the sewer unless fully ‘compliant with the requirements ofall autharies with jrisdicion, Waste packaging shoukt 9e recycled. Incineration or landfll should only bee considered when recycling is not feasible, This matenal and its container must be disposed of ina safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product restdues. ‘Vapor from product residues may creste a highly flamimable er explosive atmosphere inside the container. Do not cut, weld or grind used Containers umlass they have been cleaned thoroughly intemally, Avoid dispersal of spiled material and runoff and contact with soll, waterways, crains arc sewes. United States - RCRA Toxic hazardous waste "U" List Ingredient cas Status Reference umber Xylene aoa07 | Usted Use *-Butano ) -Buylaleohol (0) 74-36-3 Usted 0st SECTION 14: Transport information “Transport may take place according to natonal regulation or DOT for transport by road and by tain, MDG or transport by se9, IATA for Ale shipment, Refer to specie Dangerous Goods Transport requirements under 49CFR, ICAO and IATA 74a 142 743 44 145 UNno, Proper shipping name ‘Transport hazard classes) PG" Env Additonal information TM Yes. eG: aa requres wean anepsed on and tyre a ered rina DoT UNTZ63 PAINT. (tzincbisforhophosphatey) 3 Code 7 & Z uote aun Blaze ater reat ate tenn besianne nea ote forty rete the RO Eaten, foe wnrase PANT. Gidnebotorteshamey 2 W Ws Seueereneeagne feciorgane enweonston Code Brrpeeue Gee Aopen fez sic) otustman Ser una6s PANT 3 WN Code } IDG _UN1263.PAINT, (rine bis(orthophasphate)) 3 ‘ ‘Yes, Meat pan main mie Eoarasncsthadules ea Fes Version: Data Sheet HEWir AGUR 15579 )HEMPEL ‘SECTION 14: Transport information IATA —UNI263.— PART 5 No, Teena neaceys | Code & ence mst ry ope Gade: Classifeation PG": Packing group Env. : Environmental hszerde 14.6 Special precautions for user ‘Transport within user's promises: always transyor in closed containers thet are upright and secure, Ensure that persons transporting the product know what 0 do in the event of en accident or spillage. 44,7 Transport in bulk according to Annex ll of MARPOL and the IBC Code Not applicable, SECTION 15: Regulatory information 15-4 Safety, hoalth and environmental regulationsslegislation specific for the substance or mixture USS. Federal regulations Allcomponents are listed or exempted, ‘TSCA 8(a) PAIR: poly(dimethylsloxane) TSCA 8{a) CDR ExemptPartial exemption: Not determined United States inventory (TSCA 8b). All components are listed or exeripted. Clean Water Act (CWA) 307; ethylbenzene; tizincbis(orthophosphate): Zinc lean Water Act (CWA) 311; xylene; ethylbenzene; epichlorohytirin; n-butyl acetate Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPS): Listed f Freatingedertnane om commiveion | coor Sin Spear Clean Air Act Section 802 Class | Substances: Not listed Clean Air Act Section 802 Class ll Substances: Notlisted DEA List Chemicals (Precursor Chemicals) : Not sted DEA List l Chemicals (Essential Chemicals} : Not fisted ‘SARA 202/904 - SARA 311/912: SARA 302/904: chlorine; epichlorohydsir ‘SARA 341/342 Hazards identification: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard a aE = os T= wine oa EOE HE a Pega raion Se [ee re Steen ms = fe tre ze 2 {Ste onvatdeanaien Ne Ne Ne. ves te SARA 313: ‘SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS Stubs cpg ue enon ates seed aps be eos cee) waa Form R= Reporting requirements : Prodvctinredient tone [eas nmtar Comin = 5 Supper nataton ae | sea Version: 0.02 Page. 12/18 HEMPADUR 15579 © HEMFci SECTION 15: Regulatory information State regulations : Califomia Prop. 66 PF Connecticut Carcinogen Reporting: None of the components are liste, Connecticut Hazardous Material Survey: None of tne components ate listed. Florida substances: None of the components are listed linols Chemical Safety Act: None of the components are Isted, linois Toxic Substances Disclosure to Employee Act: None of the components are iste, Louisiana Reporting: None of the components ae listed Louisiana Spill: None of the components are listed. Massachusetts Spill: None of the components are listed Massachusetts Substances: The following components are listed: XYLENE; DIMETHYLBENZENE, ETHYL BENZENE; ETHYLBENZENE; SILICA, CRYSTALLINE, QUARTZ: TALC; SOAPSTONE: BUTYLACETATE: N-BUTYL ACETATE: N-BUTYL ALCOHOL; 1-BUTANOL; TITANIUM DIOXIDE; TIN DIOXIDE DUST Michigan Critical Material: None of the components are fisted. Minnesota Hazardous Substances: None af the components aré listed, Now Jersey Hazardous Substances: The fallowing components are listed: XYLENES, BENZENE, DIMETHYL», ETHYL BENZENE: BENZENE, ETHYL-; SILICA, QUARTZ; QUARTZ (Si02); ‘SOAPSTONE, n-BUTVL ACETATE; ACETIC ACID, BUTYL ESTER: n-BUTYL ALCOHOL, 4 BUTANOL; TITANIUM DIOXIDE; TITANIUM OXIDE (1102) New Jersey Spill: None of the components ara ited. New Jersey Toxic Catastrophe Prevention Act: None of the companents are sted. New York Acutely Hazardous Substances: Ths folowing components ars lstec: Xylene mixed! Ethylbenzere, Butyl acetate: Butyl alcoho}, 1-Butenol New York Toxic Chemical Release Reporting None ofthe components are isted RTK Hazardous Substances: The falowing components are Isted: BENZENE BENZENE, ETHYL+| QUARTZ DUST; QUARTZ; TALC; SOAPSTONE DUST; ACETIC ACID, BUTYL ESTER; 1-BUTANOL, TITANIUM OXIDE Rhode Island Hazardous Substances: None of the components are Isted, WARNING: This product contains a chemical known tothe State of California to cause cancer. WARNING: This product contains less than 1% of 2 chemical knovn to the State of Califomia to cause birth defects or other reproductive harm. ehrtensne Ns Trot rowan (Re eenrn ve Ye Ne. SECTION 16: Othor information Remarks Validation GHS Classification Note: In USA, consult Code of Federal Regulations, Title 29, Labor, Parts 1910 and 1915 concerning ‘gccupational safety and health standards and regulations, as well as any other epplicable Federal, State or local regulations that apply to safe practices in coating operations. Warning! If you scrape, sand, or rernove old paint, you may release lead dust. LEAD Is TOXIC, Validated by US - HSE Products Coordinator on 17 February 2017 Procedura used to derive the classification, FLANMABIE IGUIBS -Calegory > ACUTE TOXICITY {inhalatan) - Category & ‘Onbasis oftest dala cassication “stfeaion = [SKIN IRRITATION Category 2 [SERIOUS EYE DAMAGE - Catagory 1 [SKIN SENSITIZATION - Category 1 CARCINOGENICITY - Category 14 SPECIFIC TARGET ORGAN TOXICITY (REPCATED EXPOSURE) (heating organs and lungs) - Category 1 Calculation method Calculation method Calculation method Calculation method Caleuiaion method ccous Moti inormaen System US.) ‘atonal Fre Protection Resin (USA) Page ‘ Data Shee* ini ADUR 15879 9 HEMPEL SECTION 16: Other information Pencat Froicive Equant (PPE| sown in hi sen a ugzsion, ies cnn any am ew nt ane cy ae 8 heath ro Catone or end ‘Carirepunete ovate otter spomasralene alte glean oe emia eagle PPE mae ir wrt pra aly or eae ANSI Fea Nana Senet EGS sirius Cormunean Som (Gre Co acral Rendon ERS gu Response Ge (GAS Geely Harmensed a i ‘1oG= Irreport Ganges Case Caran (4 = Unto Site Orpen eal Scr Terpotaen& Canmunestirs Wty. Masco lOG = teal iets’ esa IMDG* nara! Marie Ungar Comet AGM “aver Contes nara gene {ites mater Ar aap cca {AP ~htraanal geey tr eesea on eves Sheds Sipetars Angra Retreat Neihart Gecster bor Seas Bnet Bang ond Gonmanty Rt ow Ae Notice to reader 7 Incicates information tat has changed from previously issued version. Ta the tas! of our mawiedge, the information contained herein is accurate, However neler the above named suppler nor any of ks subsicianes assumes any lial whatsoever for ihe accuracy or campeteness ofthe information conisined herein. Final determination of suitability af any. materials the sole responsiblity ofthe user, Al materials may present unknown hazerds and should be used with oautun. Although certain azarde arb described herein, we cannot guarantee tat these are the only hazards that one. on: 0.02 Page: 14 HEMPEL’S CURING AGENT 95570 sheet : HEMPEL'S CURING AGENT 95570 Gin MIPEL coe to ANSI 24001-2010 Standard - HCS 2012 Pratecive Clothing ‘General Hazard DoT See We COD Aa SECTION 4: Identification of the substance/mixture and of the company/undertaking 4.4 Productidentiior Produst name HEMPEL'S CURING AGENT @5570 Product iasty 9857000000 Product iype ‘Curing agent 4.2 Relevant identified uses of the substance or mixture and uses advised against Field of apptication used only a8 par of two- or multicomponent predusts Ready-fonuse mixture (020 base component} Ientified uses IndustiavProfessional use TSCA Unless otherwise stated All components are listed 0} 41.3 Details ofthe supplier of the safety data sheet Company details HEMPEL (USA), Ina. 800 Conroe Park Not Ove Conroe, Texas 77303 Tall treo: (800} 678-6641, ifoutside area codes 713, 281, 409, 936 Regular phons number: (835) 523-6000 E-mail Hempel@Hempel.car 1.4 Emergency telephone number (with hours of operation) For Transportation Emergencies; CHEMTREC: 1-900-424-8300 (Toles in the U.S., Canada and the U.S. Virgin Islande) 703-827-3887 [24 pours} For calls originating elsewhere (Collect calls are accepted), Contract nursber: CCN10384 ‘To preserve ths effectiveness of arrangements for providing accurate and timely emergency response information, the basic idenitying informatinn (shipper name or contract number) must be included on shipping papers, ithe purchaser of this product is going to be shipping this praduct to other locations, the purchaser must arrange for its own Emorgency Informaticn Provider to respond ta transport incidents. Hempel's 24 hour response contract does not corer non-Hempel shipments. For all other information : In USA toll ee paling aveilebte: 1-800- 678-8641 oF (936)-523-5000 (8 AM-SPMCST) See Section 4 orthe safely data sheet (frst ald measures), SECTION 2: Hazards identification 2.1 Classification 6f the substance or mixture OSHAMHCS status This material js considered hazardous by the OSHA Hazard Communication Standerd (29 CFR 1910. 1200), GHS Classification FLAMMABLE LIQUIDS - Category 3 SKIN IRRITATION - Category 2 SERIOUS EVE DAMAGE - Category 1 SKIN SENSITIZATION - Category 1 CARCINOGENICITY - Category 2 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE} (hearing organs) - Category 2 2.2 Label elements Version: 0.05 Page 113 hoe HEMPEL'S CURING AGENT 95570 J WEMPEL SECTION 2: Hazards identification ‘Signal word. Danger Hazard statements +228 - Flammable qui and vapor. HOt - Causes serious aye damage. #315 - Causes skin iritation, H317 - May cause an allergic skin reaction, H351 - Suspectes of causing cancer. 1373 - May cause damage fo organs through prolonged or repeated exnosure. {hearing araans) Precautionary statements General Read label before use. Keep out of reach of children, If medical advice is needed, have product Container or label at hand, Prevention ‘Obtain special instructions before use. Oo not hancle unl all safety precautions have been read and understood. Wear protective gloves. Wear eye or face protection. Wear protective clothing. Keep ‘away from heat, hot Surfaces, sparks, open flames and other ignition sources. No smoking, Use exptbsion-proof electrical, venllating, lighting and all materiaLhandling equipment. Use only non- ‘sparking tools. Take precautionary measures against static discharge. Keep container tightly closed, Do nat breathe vapor. Wash hands thoroughly after handling, Contaminated work clothing must nat be allowed out ofthe workplace Response Get medical attention ifyou feel unwell. IF exposed or concemed: Get medical attention, (F ON SKIN fer ait, Teke off immediately all contaminated clothing. Rinse skin with water or shower. IF ON 'SKIN: Wash with pismy of soap and water. Wash contaminated clothing before reuse, If skin imitation for rash occurs: Get medical attention. IF IN EYES; Rinse cautiously with water for several minutes, Remove contact lenses, if present and easy to do. Continue rinsing, Immediately call a POISON CENTER cr physician. Storage ‘Store locked up. Store ina well-ventilated place, Keep cool Disposat : Dispose of contents and container in accordance with all local, regional, national and internationat regulations, Supplemental/abel elements: None knovi, 2.3 Other hazards Hazards nat otherwise classified: None known SECTION 3: Compositionlinformation on ingredients Product definition Mivture Physical state guid [ Producvingredient name Identifiers % GHS Classification ‘Methyistyrenated phenol eesiza01 [210-328 | SKINIRRITATION Cateyory2 SKIN SENSITIZATION - Category 1 -butanol 71963 vio-sts | FLAMMABLE LIQUIDS - Category 3 ACUTE TOXICITY (oral - Category 4 ‘SKIN IRRITATION - Category 2 ‘SERIOUS EYE DAMAGE - Category 1 SPECIFIC TARGET ORGAN TOXIGITY (SINGLE EXPOSURE) (Respiratory tract tation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Natcatic efees) - Catagory 3 lene 1330-207 | xto-<20 | FLAYMABLE LIQUIDS = Category 3 ‘ACUTE TOXICITY (dermal) - Category 4 ‘ACUTE TOXICITY (inhalation)- Category 4 SKIN IRRITATION - Category 2 ethybenzene ronstt-t 23-285 | FLAMMABLE LIQUIDS - Category 2 ‘AQUTE TOXICITY (intafation) - Category 4 ‘CARCINOGENICITY - Category 2 [SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) - Category 2 ASPIRATION HAZARD - Category ? ‘2s(dimethyaminemethybohenst — | 80-722 SKIN CORROSION - Category 1 SERIOUS EYE DAMAGE -Catezory + SKIN SENSITIZATION Category 18. Fatty acl, ta Fol, compds. wih @-N- | 91645-13.5 ACUTE TOXICITY (ral) - Category & ‘SKIN IRRITATION = ‘aeladesenyl-t 3 propanediamine (2:1) Category 2 @ Sheet HEWFEL J CURING AGENT 95570 SECTION 3: Compositioniinformation on ingredients } SERIOUS EYE DAMAGE - Category 4 SKIN IRRITATION - Category 2 S-propanediamine EYE IRRITATION - Category 24 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (oral) -Catogary 2 solvert naphthe (petroleum), light arom. 6a7arasg — | et FLAMMABLE LIQUIDS - Catagory 3 ‘SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory trac iritation) ~ Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE} (Narcotic eects) - Category 3 ASPIRATION HAZARD - Catagory 1 riethylenetetramine 112.243 1 ACUTE TOXICITY (dermal) - Category 4 ‘SKIN CORROSION - Category 18 ‘SERIOUS EYE DAMAGE - Category 1 SKIN SENSITIZATION Category 1 2-phenyieropene se039 503 FLAMMABLE LIQUIDS - Category 3 EYE IRRITATION Catagory 24, CARCINOGENICITY - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (espiraiory tract itaton) «Category 3 ‘Any concentration shown a8 a range is fo protect confidentially ors due t Daten variation. ‘Sccupational exposure fits, if avaliable, are isied in Section 8. S-oxtadcoanoie act (2-comod. with a}.n- | 40027-38-4 Sectadecany “There ara no aekstional ingredients present which, within the current Knowiedge of the supplier and n the concentrations arpicable, are slassifed as hazardaus to health or the environment and hence cequire reporting inthis section. SECTION. : First ald measures 4:1 Description of first Generat In all cases of doubt, or when symptoms persist, seek medical atention. Never give anything by mouth to.an unconscious person, 11 breathing is iregular, drowsiness, loss of consciousness or cramps: Call 9¢1 and give immediate treatment (first aid) Eye contact ‘Check for and remove any contact lansee. Immediately fush eyes with plenty of water for atleast 15, ‘minutes, eccasionallyliting the upper and lower eyelids. Seek immediate medical altention Inhalation Remove to fresh ai. Keep person warm and at rest. I not broathitg, if broathing is irogular or if respiretory arrest occurs, provide artifical respiraion or nxygen oy trained personnel. Give nothing by ‘mouth. tf unconscious, place in recovery position and get mecical attention immediately Skin contact Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners, Ingestion swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest, Do not induce vomiting unless otectec to do so by medical personnel. Lower the head so that vorit will not re-enter the mouth and throat Protection offstsiders 'No action shall be taken involving any personal risk or without suitable training, If itis suspocted that fumes are stil present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-io-mouth resuscitation, ‘Wash contaminated clothing thoroughly with water before removing it, or wear gloves 4.2 Most important symptoms and offects, both acufe and delayed Potential acute health effects Eye contac Causes seus eye damage Inhatton No knonn sigieant fects or etical nears Skin contac Cause skin ination. May cause an stbgic sin eeton Ingestion No know sgnicant eects or crcl hazards Overexposure signtaymptoms ye contac Adverse symptoms may ince th Slowing watering rooness Inhalation No specie deta Version: 0.05 HEMPEL'S CURING AGENT s55v0 SECTION 4: First aid measures ‘Skin contact Adverse symptoms may include the folowing: pain or iitason redness biistering may occur Ingestion Advarse symptoms may include the folowing: stomach pains 433 Indication of any immectate medical attention and special treatment needed Notes fo physician IM gasses have been inhaled, from the decomposition ofthe product, symptome may be delayed Specific treatments: No specific treatment. SECTION 5: Firefighting measures 5.4 Extinguishing media Extinguishing media Recommended: alcaho! resistant foam, COs, powders, water spray. Not to be used: wateret. 6.2 Special hazards arising from the substance or mixture Hazards from the substance or Flammable liquid and vapor, in a fre or heated, a pressure increase will cour and the container may mibture bust, wih the isk of@ subsequent explosion. Runoff to sewer may create fire or explosion hazerd. ‘Tris matarial is harmful to aquatic life with long lasting effects, Fire water contaminated wi this material must be contained and prevented froin ing discharged to any waterway, sewer or drain Hazardous combustion products : Detomposition products may include the following materials: carbon oxides nitrogen oxides 5.3 Advice for firefighters romplly isolate the scene by removing al persons from the vicinity ofthe incident if there isa fre. No action shall be taken involving ang personal isk er without suitable training. Fire will praduce dense biack smoke, Exposure to decomposition products may cause 2 health hazard. Cool closed containers exposed to fe with water. Do nol release runof ftom fre fo drains ar watercourses. Fire-fighers should “wear appropriate protective equipment and self-contained breathing apparatus (SCBA) wih afl fce-piece operated in postive pressure mode. SECTION 6: Accidental release measures. 6.1 Personal precautions, pratective equipment and emergency procedures Avoid all direct contact with the spilled material, Exclude sources of ignition and be aware of explosion hazard. Ventlate the ares. Avoid breathing vapor or mist. Refer to protective measures listed in sections 7 and 8. No action shat he taken involving any personal isk or without suitable training. Ifthe product contaminates lakes, rivers, or sewers, inform tha appropriate authorities in accordance with local regulations, 6.2 Environmental precautions Avoid dispersal of spilled maforial and runoff and contact with soll, waterways, diains and sewers. Infor the relevant authorities ifthe produc las caused environmental polluion (sewers, waterways, coil or air). Water poltting materia, 6.3 Methods and materials for containment and cleaning up ‘Stop leak if without risk. Move containers from spill area. Approach release from upwind, Prevent enty info sewers, water courses, asements or confined areas. Wash spilages into an efuent treatment plant or proceed as follows. Contain and collect spillage with non- ‘combustible, absorben! material e.g. sand, earth, vermiculite or diatomaceo.s earth and glace in container for disposal accarding to local regulations (zee Section 13), Use spark-proof tools and explosionpraof equipment. Contaminated absorbent materisl may pose the seme hazard as the spilled product. 6.4 Reference to other sections ‘See Section 1 for emergency contact information ‘See Section 8 for information on appropriate personal protective equipment. ‘Bee Section 13 for addtional waste treatment information, iata Sheet “u:L'S CURING AGENT 95570 SECTION 7: Handling and storage 7.4 Precautions for safe handling \Yapors are heavier than sir and mey spread along loots. Vapors may form explosive mixtures with alr. Prevent the creation of flammable of icaiva concentrations of vapors in aif and avoid vapor concentrations higher than the accupational exposure lita In addition, the product should ie used only in areas from which all naked lights and other Sources ofigntion have bean excluded. Electrical equipment ‘should be protected fo the appropriate standard, To dissipate static electricity during transfer, ground druni and connect to receiving Container with bonding strap. No'sparking tools should be used. ‘Avoid inhalation of vepour, dust and spray mist. Avoid contact with skin and ayes. Eating, drinking and smoking should be prohibted in area ‘where this material is handled, stored and provesscd. Annropriate personel protective equipment see Section 8. Always keep in containers, ‘made from the same material as the anginal one. 7.2 Conditions for safe storage, including any incompatibilities Store in accordance with tocal regulations. Store in @ Coot, welLventlated area away ftom incompatible materials and ignition sources. Keep out ofthe reach of children. Keep away from: Oxidizing agents, strong alkalis, song acids. No smoking. Prevent unauthorized ‘acoass, Coniainers that are opened must be carefully resealad and kept upright to pravent leakage, 1.8 Specie end use(s) ‘See separate Product Data Sheet for recommendations or industrial wecior specific elution ‘This product may be applied using several application techniques and methods of handling may be diferent for each. Appicaton techniques include [but are not limited to} busting, rolling, and spray aplication [conventional, HPLY, airless, pleural component or ‘aerosol can], Avoid the breathing of vapors and, f spraying, do not breath spray mist or aerosols SECTION Exposure controls/personal protection 8.1 Control parameters Producvingredient neme Expoaure limit values Jr-butanct ‘ACGIH TLV (United States, 312016) TWA: 20 9pm Ehouts, NIOSH REL (Unitod States, 10/2013), Aasorbed through skin, ‘CEI: 150 mgm* GEIL: 50 ppm (OSHA PEL (United States, 6/2016). “TWA: 200 mg? & hours TWA: 100 ppm 8 hours. sylene ACGIH TLV (United States, 312018), SSTEL: 651 mglin’ 15 minutes, STEL: 160 ppm 15 minutes, TWA: 424 gin & hours. TWA: 120 pom 8 hour. ‘OSHA PEL (United States, 6/2016). FAVA: 435 mlm 8 hours. “DWA: 100 ppin 8 hours. etiylbenzene ‘ACGIH TLY (United States, 3/2018), “TWA: 20 ppm 8 hours. NIOSH REL (United States, 0/2013). STEL: 545 mg/m” 16 minus. STEL: 125 ppm 15 minutes TWA: 435 magi? 10 hours. TWA: 100 ppm 10 hours. OSHA PEL (United States, 6/2016), TWA: 435 mgin® 8 hours. TWA: 100 ppm 8 hours. solvent naphtna (neroleum), ight arom ACGIH TLV (United States} TWA Tentative: 25 ppm 8 hours. rithylonetetarine [AIHA WEL (United States, 10/2011), Absorbed through skin ‘TWA: 1 pom & hours. 2phenvipropane ACGIN TLV (United States, 3/2016). ‘TWA 10 ppm 8 hours. NIOSH REL (United Siates, 1012043). STEL: 485 mg/m? 16 minutes. STEL: 100 ppm 16 minutos. TWA: 240 maint 0 hours. TWA: 60 ppm 10 neurs, (OSHA PEL (United States, 612018). Version’ 0.08 Page: §/13 Sheet HEMPEL S UGi.'NG AGENT 95570 SECTION 8: Exposure controls/personal protection ‘CEIL: 480 matt CEIL 100 ppm Recommended monitoring procedures I this product contains ingredients wit exposure limits, personal, workplaoa atmosphere or biological monitaring may be required to detennine the effectiveness of the ventilation or other control measures and/or the necessity o use respiratory protective equipment. Reference should be made to appropriate moritoring standards. Reference to national guidance documents fer methods for the determination of hazardous substances wil also be required, 8.2 Exposure controls, Appropriate engineering controls Provide local exhaust and general ventiltion systems to maintain aifbome concentrations below OSHA, ACGIH, and manufacturer Fecommended expozure lms. Local exhaust ventilation is preferred because it prevents Contaminant dispersion fato work areas by controling iat its source, Use local and general exhaust ventilation fo effectively remove end prevent buildup of mistelveporsifumess generated fom the handling of tis product Note: Local exhaust ventlation ip designed to capture an emitted contaminant at or near its source, before the contaminant has a chance to disperse info the werkplace ai Goneral exhaust ventilation, also called dilution ventilation, i aifferent from local exhaust ventilation because instead of raptucing emissions at the'r source and removing them fror the air, general exhaust ventilation allows the contaminant {be envied into the workplace air and hen dilutes the concentration of the contaminant fo an aoceptable level (e.9., to the PEL or below) Individual protection measures General ‘Gloves must be wor forall work that may result in song, Apronvcaverallsiprotective dathing must be ‘orn whan soling is so great that reguiar work clothes do not adequately protect skin against contact with the product, Safely eyewear should be used when thete is kellhaad of exposure. Hygiene measures Wash hands. forearms, and face thoroughly efter handling compounds and before eating, smoking, using lavatory, and at the end of day. Eyetface pretection ‘Safety eyewear complying with an spproved standard should be used when a risk assessment Indicates this is necessary to evoid exposure to liquid splashes, micts, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degres of protection: chemical splash goggles andior face shisld. Inhalation hazards exist, a full-face Fespirator may 02 required instead, Hand protection: Wear chemical-resistant gloves in combination with ‘basic’ employee training, The quality ofthe Cchemical-resistant protective gloves must be chosen as a function ofthe specific workplace concentrations and quantity of hazardous substances. Since the actual work situations unknown. Supplier of cloves should be contacted in order to fins the appropriate type. Below Fated glove(s) should be regarded as generic advice Recommended! Silver Shield / 4H cloves, polyvinyl alcohel (PVA), Viton® May be used nitrile rubber, neoprene rubber, butyl rubber ‘Short term exoosure! natural rubber latex), polyvinyl chloride (PVC) Body protectin Personal protective equipment forthe body should be selacted Lased on the task being performed and the risks involved handling this product Wear sultabla protective clothing, Always wear protective clothing when spraying, Respiratory protection If working areas have insusfcient ventiation, west half or totally covering mask equipped with gas filer of type Organic Vapor, when grinding use particle flter af type P85, P89 or P100. When soraying use @ combined fier (organic vapor / HEPA or organic vapor /P100 type). Be sure to use approvedicerified respirator or equivalent Always Wear an aic-fod respirator when spraying in a continuous and prolongad work situation (e.g. hood with supply of fresh or compressed air ora ful face, powered air purifying iter. Pratsetve clothing (pictograme} & ge S 56 Note: Application of paint proicts by spraying requires addtional safely precautions: Full body uit, Fuk face respirator wih alr supplies. Environmental exposure controls [Emissions from vertlation or work process equiporent should be checked to ensure they comply win the requirements of environmental protection legislation. In same cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduoe emissions to acceptable levels. Version: 0.05 98 B13 ta Sheet HEMPEL'S CURING AGENT 95570 wy HEMPEL SECTION 9: Physical and chemical properties. 9.4 Information on basic physical and chemical properties Physical state cor: eH ‘Melting pointtraezing point Bolting poimtooiing range Flash point Evaporation ate Flammebity Upperiower flammabilty oF explosive limits Vapor pressure \Vepor density Relative density Solubilyies) Partiion coefficient (LogKow) ‘Aute-ignition temperature Decompesition tamperature Viscosity Explosive properties Oxidizing properties 9.2 Other information Solventis) % by weight {included excempt solvent(s) Water % by welght ‘YOC content (Coatings) VOC content (Regulatory) TOC Content (Volatis): Solvent Gas qui. Solventike Testing not relevant or not possible due to nature of the product, Testing not relevant cr not possible due to nature of the product, ‘Testing nat relovamt or not possible due to nature ofthe product Closed cup: 26°C (78.8°F) “Testing nat relevant or not possible cue to nature of the product Highly flammable in the presence of the folowing materials or condti's. apen Names, sparks and static discharge and heat, oa-11.3v0I% Testing not celevant or not possible due to nature ofthe product ‘Testing not relevant or not possible due to nature ofthe product 0.849 gfom? Partially soluble inthe folowing materials: cold watar and hot water Testing not relevant or not possible due to nature ofthe product. Testing not relevant or not possible due to nature ofthe product “Testing not ealevant or not possibie due to nature of the product “Testing not relevant or not possible due to nature of the product. Explosive in the presence of fhe following materials or conditions: open tames, sparks end static discharge and heat. “Testing not relevant or not possible due to nature of the product. 26.3.% {win} Weighted average: 0% 2.87 losieal (3442 61) 287 lbsiget (2442 gf) Weighted average: 270 0 Weighted average: 0.093 mn SECTION 10: Stability and reactivity 10.1 Reactivity No specific test data related to reactivity available for this product or its ingredionts, 40.2 Chemical stability “The product is stable, 40.3 Possibility of hazardous reactions Under nena conditions of storage and use, hazardous rettions will not occur 410.4 Conditions to avoid Avoid all possible sourcos af gntion (spark or flame}. Do net pressurize, cut, weld, braze, sokier drill grind or expose containers to heat (0 sources of ignition 10.5 Incompatible materials ta Sheet se cu'S CURING AGENT 95570 <> “EMPEL salle He SECTION 10: Stability and reactivity Highly reavtve or Incompatible wit the following materials: oxdizing materials Reactive ar iPeompatibie wit the following materiale: reducing materials, 10.6 Hazardous decomposition products When exposed to high temperatures (ie, in cage of fre) harmful decomposition products may be formed Decomposition products mey include the following materials: carbon oxides nitrogen oxides ‘SECTION 11: Toxicological information 14.4 Information on toxicological effects Exposure to component solvent vapor concentrations may result in adverse health effects such as mucous membrane and respiratory system iritation and adverse effects on the kidneys, ver and central nervous system. Solvents may cause some of the abave effects by absorption through the skin, Symptoms and signs include headaches, dizziness, fetigue, muscular weakness, drowsiness and, in extreme casas, loss of consciousness. Repeated or prolonged contact with tha preparation may cause removal of natural fat ffomn the skin, resulting in non-allergic contact dermaiitis and absorption through the skin. If splashed in the eyes, he liquid may cause irtation and reversible damage, Accidental swallowing may cause stomach pain, Chemical |ung inflammation may occur if he products taken inte the lungs via ‘vomiting, Direct contact with te eyes can cause irreversible damage, including blindness. Acute toxicity Productingredient name Result ‘Species Dose Exposure | Tieyisirenatea phenol Toso ihalaton Busts and mite Rat Penal sows L050 Dermal Rat 22000 mghkg 7 rebut C60 Inhalation Vapor Rat 24000 gin ‘hours 1LD80 Dermat Rabbit ‘3400 mata : £50 Oral Rat 790 maka : lene {L650 inhalation Gas. Rat 3000 ppm ‘4nours G50 Inhalation Vapor Rat 6950 ppm abou LD50 Oral Rat 4900 maria ethylbenzene. LLDS0 Dermal Rabbit >5000 mgikg : L050 oral Rat 3500 mngkg 3 2.4.6crs\cimetyaminomelnyh} | LDS0 Bermal Rat 1280 mpg : Phenol L050 Oral Ra 4200 maikg - 1080 Oral Rat 2469 mgikg 2 solvent naphtha (petroloum), ight | LCS nnalalln Vapor Rat 6193 maint hours 1.059 Dermal Rebtit 3160 maka : 1.060 Oral Rat 3892 maka z riethylenetetaming {L050 Dermal Rabbit 550 mohka 7 1050 Oral Ret 4716 moka = | 2-phenyipropene L050 Ova? Rat aenometg | Acute toxicity estimates i Route i ‘ATE value Sral BreTmanG Dermal 5507-3 mig Inhalation gases) 281385 e0m lehalation (vapors) 63:14 mah InvitationiCorrosion| Productingredient name Result [species [score 7 Exposure, Weibyshrensted phenal Eyes Mid tant Rabon = E butanol Eyes -Severe tant Rabbit - [24 hours 2 miligrams ‘Skin - Moderate ittant Rabbit x "24 hours 20 miligrams lene Eyes - Severe iitant Rabb 7 [24 hours Smears ‘Skin - Moderate itant Rabbit - 124 havrs 500 miligrams ethyibenzene ‘Skin - Mid tant Rabbit : 24 hours 15 miligrams. Respiratory - ia tant Rabbit S - Eyes Mil ant Rabbit z 5 24 6nsidimathyaminometyt | Eyes Severs initant Rabe - 24 hours 50 Micrograms pheno} ‘Skin - Sever tant Rabbit 124 nours 2miligrems solvent raphiha (petroloum), ht | Eyes Mild irtant Rabbit s [24 nours 109 microitere HEMPEL'S CURING AGENT 99570 ©jHEMPE: SECTION 11: Toxicological information Respiratory - Mid intent Rabbit . |. Wethyienetetramine Eyes - Moderate irritant Rabbit : 24 hours 20 riigrams Skin - Severe itant Rabbit - 24 hours § mibgrams Zphanylpropens Eyes - Mi itant Rabbit - 91 miligrams ‘Skin - Moderate itant Rabbit : [100 Percent Sen: Produetfingredientname | Route of expoasre Species Result viethylenetetramine hin Ganea pig Sensitzing Carcinogen Classification Productiingredient name ARC NTP osHa | hyene 3 5 = etnyibenzene 28 : 2 2-phenylpropene Ey . s ‘Specific target organ toxicity (single exposure) Productingredient name Category Route of exposure | Target organs: -butanat (Gategorys | Netappicable. Respiratory wack tration and Narcotic effects solvent naphtha (petroleurn), light arom, Category 3 Nt appicabie. Respiratory tract Inttation and Narcotic effects 2-phenytpropene Category 9 Not applicable, Respiratory tract iertation ‘Spesific target organ toxicity (repeated exposure) Productiingredient name Category Route of exposure | Target organs eihybenzene (Cateyory2 Not determined [heating owgans S-cctadecenoic acid (2)-compd. with (2}-n-S-octadecenyH1 Category2 Oral Not determined 3:propanediaraine L Aspiration hazard Productiingredient name Result ethybenzene [ASPIRATION HAZARD - Calegory 1 Solvent naphtha (petroleum), light arom, ASPIRATION HAZARD - Category 1 Information on the likely routes of exposure Routes of entry anticipated: Oral, Dermal, Inhalation. Potential chronic health effects Sensitization Contains Methylstyrenated phencl, tiethylenetetramine. May produce an allergic reaction. Other information: No adiltional known significant effects er eitcal hazards. SECTION 12: Ecological information 42.4 Toxicity Do not allow to enter drains or watercourses. Harmful fo aquatic fe with long lasting effects, When spile, this product may act as an cil, causing «fim, sheen, emulsion, or sludge at or beneath the surface of a body of water. Oils of any kind can cause: (s) drowning of waterfow! due to lack or buoyancy, loss of insulating capacity of feathers, starvation and vulnerabilly to predators due to lack of mobility: (tj lethal effect on fish by coating gill surfaces, preventing respwration; (c} potential fsh kills resulting from alteration in biochemical oxygen demana; (d) asphyxiation of benthic ife forme whan floating masses become engaged with surface Gebris ‘and settlo on the bottom: end (e} adverse aesthetic effects cf fouled shoreline and beaches. ta Sheet fy vic. e's CURING AGENT 95570 MEMPEL SECTION 12: Ecological information Productlingrediont name asa Species Exposure Wetigletyenated phonol Foal £050 15 mgih algae FZhows cute ECS 14-51 ma Daphnia 48 hours ‘Acute EC50 25.8 malt Fish 96 hours rebutancl ‘Acute £C50 1328 mall Daptnia 98 hours Route LCBO 1376 mal Fish 98 hours ethyoenzene CChronie NOEC <1000 ygt Fresh water Algae Pseudckrchnerilla subeaptata [96 hours 2,4,6e(dimethytaminomethy) | Acute EC50 84 mgl algae 72 haus phenol ‘Acute L050 175 malt Fish [98 hows solvent naptina (petroleum), ligne | Acute ECS0 2.6 mal ‘lgae -Pssudkirchneriella subeapitata /95 hours arom. (green algae) Acute EC5D6.14 mgt Daphnia Daphnia magna 48 hous ‘Acute 0509.22 mg Fish- Oncothynchus mykiss [rainbow [5 hours ous rietmeneteramine ‘cute £050 20 malt Algae 72 hours ‘Acute EG59 31.4 mail Daphnia 48 hours Acute £50 330 mal Fish ephows 12.2 Persistence and degradabllity Productlingredient name Test Result Dose Toeulum -butanal ‘OECD 3010 Ready | 92 %-20 days rE F Biodegradabily Closed Bottle Test pylene 80% -Readlly- 28 days . L ethylbenzene 970 % - Readily -28 days | | 246tia(denethylaminometty) — F OECD 301 31D | 454-Nol readily ~ 28 days [ 7 pheno Ready Biodegradabilty Closed Botte Test Solvent naphika (petroleum), ight | - 270% Readlly-28 days |. ' ator. Productiingredient name ‘Aquatic halflife Photaiysis Biodegradability ‘ebulanal - - Ready syne - - Ready ethybenzene : E Readily 2.4.6-ieldimethyaminometnyy — | Ee Not readily phenol ‘Solvent nacintha (petrcleum). ght | = - Reselly 12.3 Bloaccumulative potential Productingredient name LogP er BCr Potontiat Methistyrenatea pnanl 827 r Tow labutanok 4 316 low peylene 312 81-259 low ethylbenzene 36 - low 2.4.6-is(dimethyaminomethy)phenat p29 7 low solvent naphtha (petroleum), ight arom, - 40-2500 ign rithylonetetramine 16-14 - ow 2-phenylpropen 3.48 5-140 low 12.4 Mobiniy in soit Soilister partion coefficient No known data avalible in our database. Kee) Mobitty [No known data avaliable in our database. 125 Other adverse affects ‘No known significant efects or erict hazards. 1013 : heet HEMPEL'S LURING AGENT 95570 SECTION 13: Disposal considerations 43.1 Waste treatment methods Disposal should be in eosardance with applicable regional, national and local laws and regulations. Local regulations may be more stringent than regional or national requirements, ‘The information presonted below only applies to the material as supplied. The isentication based on characteristic(s} or isting may not apply ithe materal has been used cr otherwise contaminated. It is ihe responsibiliy ofthe weste generator to determine the tonicity and physical properties of the material generated to determine the proper waste entiation ad disposal methods in compfance with ‘Applicable regulations. Refer to Section 7 and Section 8 for addtional handling information and protection of employees. “The generation of waste should be avoided or miaimized wherever possible. Disposal ofthis product, oltions and eny by-products should tall times comply wih the requirements of environmental protection and waste disposal legislation ard any regional local authority requirements, Dispose of surplus and non-recyclable products via 9 licensed waste dieposal contractor, Waste ehould not be disposed of ‘untreated to the sewer unless fully compliant with the requirements ofall authortias with juiagictian. Waste packaging should be recycled, Incinaration or lanefil should only be considered when recycling is not feasible, This material and ts container must be disposed of in a ‘safo way. Care should be isken when handling emptied containers that hava not been cleaned or rinsed out. Empty containers or liners may cetain Some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the Container. Do not cut, weld ar grind used containers unless they have been cleaned thoreughly internally, Avoid cispersal of spilled ‘material and runoff and contact with sol, waterways, drains and sewers. United States - RCRA Toxic hazardous waste "U" List, Ingredient cAS# | Status number 1-Bulaol Gy, n-Bulyl alcohol 1) 74-36-3 Usted Wost xylene 4330-207 Listed 239 SECTION 14: Transport information ‘Transport may take place accatding te national regulation oF DOT for transport by road and by train, IMG for transport by sea, IATA for Air shipment, Refer lo specif Dangerous Gcods Transport requirements under 49CER, ICAO and |ATA eames j oe ana pa 3 Tee oer eae F Berges Coote Regione nee °® = en e ‘Code Classification Po"; Packing group Env." : Environmental hazards 14.6 Spocial precautions for user Transport within user's premises: slweys tranepor in closed containers that are upright and secure, Ensure thal persons traneperting the product knew what 6 do inthe event of an sosident or spillage Version: 0.08 Poge: 1113 Data Sheet fic MIPEL'S CURING AGENT 95570 HEMPEL SECTION 14: Transport information 414.7 Transport in bulk according to Annex of MARPOL and the IBC Code Not applicable. SECTION 15: Regulatory information 45.1 Safety, health and environmental regulationsilegislation specific for the substance or mixture US. Federal regulations SARA 302/304 - SARA 311/512: SARA3I3: Form R - Reporting requirements: ‘Supplier notification : State regulations : Not determined. TSCA 8{a) CDR Exempt/Partial exemption: Not determined United States inventory (TSCA 8b): Not determined. Clean Water Act (CWA) 307: ethylbenzene; phenol Clean Water Act (CWA) 311: xylene; ethylbenzene: phenol Clean Alr Act Section 112(b) Hazardous Air Pollutants (HAPs): Listed aan Toe ae tenn frou Shaan Pron teas? PoE) lean Air Act Section 602 Class | Substances: Not listed Clean Air Act Section 602 Class ll Substances: Notlisted DEA List | Chemicals (Precursor Chemicals) : Not Iistod DEA List ll Chemicals (Essential Chemicals) : Not Isted SARA 302/304: phenol, chlorine SARA 311/312 Hazards identification: Fie hazard, Immediate facute] health hazard, Delayed (chronic) health hazard Proscingreient mane % | fnbacwa | Sutien [ects | tmmatian | —Oaaped silsee ot cetinein | hy Tenaya cs = % Rs ane Yea t te: ve fe ne we we te ve te itencene te ts vs ve ha Perce einonatyngenct = te te. s his Fy st nl cme S he fe S ne ection ad hoe wt tw. i ro yen Ceemancontt Spepanousrn ‘Sie api pteeom) r70% ves No We. he enters is hs te. te erences s_| Yee te ne te ‘SARA 319 natifcation must nol be detached from the MSDS and ary copying and vedistibution ofthe MSDS ‘shall include copying and resistibution ofthe notice attached fo copies af the MSDS subsequently redistrbutes, term {250207 19-20 Cheacare too : Prostngreaint name ‘AS ume ‘oneanrston ra0207 10-20 Connecticut Carcinogen Reporting: None of the components are listed. Connecticut Hazardous Material Survey: None of the components are listed Florida substances: Nana of tha components are iste, Minos Chemical Safety Act: None of the components are listed lMinots Toxic Substances Disclosure to Employee Act: None af the components are listed Louisiana Reporting: None of the components are sted. Louisiana Spill None of the components are listed Massachusetts Spill: None of the components are liste. Massachusetts Substances: The folloving components are fisted: N-BUTYL ALCOHOL; 1-BUTANOL; XYLENE; DIMETHYLBENZENE: ETHYL SENZENE; ETHYLBENZENE Michigan Critical Material: None of the components are listed ‘Minnesota Hazardous Substances: None of the components are sted. ta Sheet HEMPEL'S CURING AGENT 95570 1 HEMPEL SECTION 15: Regulatory information New Jersey Hazardous Substances: Ths fllowing components are listed: n-BUTYL ALCOHOL; 1-BUTANOL; XYLENES: BENZENE, DIMETHYL” ETHY], BENZENE, BENZENE, ETHYL: ISOPROPENYL BENZENE. alpha-METHYLSTYRENE. Now Jersey Spill: None of the components are listed, New Jersey Toxic Catastrophe Prevention Act: None of te components are listed. Now York Acutely Hazardous Substances: The following components are listed: Butyl alcchel; 4-Butanol Xylene med: Ethylbenzena Now Yerk Toxic Chomical Release Reporting: None of the components are listed Pennsylvania RTK Hazardous Substances: The folowing components are listed: 1-SUTANOL: BENZENE, DIMETHYL-; BENZENE, ETHYL- Rhode Island Hazardous Substances: None of the components are listed Prop. 65°F: WARNING: Thie product contains a chemical known t9 the State of Califomia 6 cause cancer, WARNING: This product contains lass than 1% af a chemical known te the State of California to cause birth defects or ether reproductive harm, Califor Prowutingreset nae meer | Repioaucive | Wosigifeasiskiowt | Woxmmanaareni iy aene ve E Team Pe eneniene ve Ye is he SECTION 16: Other information Remarks, Note: In USA, consult Code of Federal Regulations, Tite 29, Labor, Parts 1910 and 1915 conceming ‘occupational safety and health etandards ail regulations, as well as any other applicable Federal State or local regulations thet apply to safe practices in coating operations. \Waming! If you scrape, sand, or remove old paint, you may release lead dust. LEAD is TOXIC, Validation Validated by US HSE Products Coordinator on 21 December 2016 GHS Classification Procedure used to derive the elassification. Classification “Justification FLAMMABLE LIQUIDS - Catagory On basis oftest dala SKIN IRRITATION - Category 2 Calculation method SERIOUS EYE DAWAGE - Category 1 Calculation method ‘SKIN SENSITIZATION Calegory 1 Calculation method CARCINOGENICITY - Category 2 Calculation method SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) - Category 2 Calculation metnod Hazardous tal atormationBys0m (V5.8) Nona Fre Protection Rsosinon (UA) ny | > aity ee pia eal Prarie Cupar PE) shown sting 8 sugeazen. Ses cnns vay ton ee atlas Wo afer he cy ely & math etn Cuomo en COIR Speic i acs weet mpoare cocion @ he Oe apron and daa te pooioe PPE wataon ewok st ht rc ely a beso ANDI arian sin Snaud e ‘OECD = orate fo rami Co pen eis Deere [EER code af eee! Repdstons ergney Repara Gal {= Gana Hamenas yom fClesean bet of Chai {TOG= Transat Dango Coes, Cans sti =tiod thes Ocnpana ears Salety Aan Sets Tpetstans Commuter ery, Waxca 7 NO3- ticrateralMrtne Boman Greos cots henoan Curacao fue Hype {Rtas neem acer NTP tatona Teo Beye A [EPCRA Eireserey Planning ard Conmunty fight to Krom Ac Notice to reader PF tedicatos information that has changed fem previously issued version. To the bast of our knowledge, the Ilormalion contained herein ls accurate, However, nether the above named eupalior nav any of le subsidiaries ‘assum any labitty whatsoever forthe accuracy or comartoness ofthe information contained herein. Final determination of suitably of ary fnetena isthe sole esponsibility of te user. All materals may present unknown hazards and shoule be used with caution. Athough ceriain Inazarde are described herein, we cannot guarsntee tat theze are the only hazers that exis Page: 13/13 HEMPEL’S THINNER 08450 Safety Data Siieci HEMPEL'S THINNER 08450 © HEMPEL Conforms to ANSI Z400.1-20109 Stendard - HES 2012 Proiecive Clothing ‘General Hacard bor See th ite SOSH A SECTION 4: Identification of the substance/mixture and of the company/undertaking 41.4 Productidentitier Product name: HEMPEL'S THINNER 08460 Product identity : 85000000 Product ype thinner 112 Relevant identified uses of the substance or mixture and uses advised ayainst Fiold of application yacht, ships end shioyard. buildings and metal industy. Identified uses, IndustialiProfessional uss TSCA Unless otherwise stated All components are listed or exempted. 2.3 Detalls of the supplier of the safety data sheet Company details HEMPEL (USA), Inc. {800 Conroe Parc North Drive Conroe, Texas 77303 ‘Tol iree: (800) 078-6641, if ouiside area codes 713, 261, 409, 996 Regular phone number: (836) 623-8000 E-mail Hompel@Hempel.com 1.4 Emergency telephone number (with hours of operation) For Transportation Emergencies: CHEMTREC: 1-800-424-9300 (Tol-ftee in the US., Canada and the U.S, Vegi fslands) 703-527-3867 (24 pours) For calls onginating elsewhere (Collect cals are accepted), Contract nuriber. CCN10364 ‘To preserve the effectiveness of arrangements for provicing accurate and tly emergency response information, the basic denting infomation (shipper name or conract number) must be included on shipsing papers IF tho purchaser ofthis product is Going fo be shipping this prosuctto other locations, the purcraser ist arrange fr is ovn Emergency information Provider respond to transport Indes, Hempet's 24 nour response contract does not cover noa-Hempel shprrents, For al other information. In. USA toll fee caling availabe: 1-800-678-6641 or (838)-528-6000 (@AM-5 PM CST) ‘See Section 4 of the safety data sheot (ist aid measures). SECTION 2: Hazards identification 24 Classitication of the substance or mixture OSHAVHCS status ‘This material ie considered hazardous by the OSHA Hazard Communication Standard 79 CFR 1910. 1200}, GHS Ciassification FLAMMABLE LIQUIDS - Category 3 ACUTE TOXICITY (dermal) - Category 4 ACUTE TOXICITY (inhlation)= Category 4 SKIN IRRITATION - Category 2 SERIOUS EYE DANAGE - Category 1 CARCINOGENICITY - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory ract tation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (heusing organs} ~ Category 2 ASPIRATION HAZARD - Category 1 2.2 Label eloments Poge: 14 ve J set HEMPEL'S THINNER 08450 SECTION 2: Hazards identification Hazard pictograms : Signal word: Danger Hazard statements Ho12 4 H3a2 H315 - Causes skin irtation H351 - Suspected of causing cancer. © reWiPEL OOD #226 - Flammable tguid and vapor, Harmful in contact with skin er if inhaled, H318- Causes serious eye damage. H204- May be fate if swallowed and enters sinvays. 1335 - May cause respiratory iritation. 1HS36 - May cause drowsiness or dizziness H379- May cause damage to organs through prolongec or repeated exposure. (hearing o1gans} Precautonary statements General Read label betore use, Keep out of reach of children. If medical advice is needed, have product container or label at hand Prevention ‘Obtain special instructions before use. Do not handle unt all safety precautions have been ead and Understood. Wesr protective gloves. Wear eye or face protection. Wear protective clotting. Keep away from heat, hot surfaces, sparks, open flames end other ignition sources. No smoking. Use ‘explosion-proof electrical, ventilating lighting and all material-handling equipment. Use only non- ‘sparking tools. Take precaulionery measures against static discharge. Keep container tightly closed Use only outdoors orin @ well-ventilated area, Do not breathe vapor. Wash hands thoroughly after handling. Response ‘Get medical attention if you feet unwell, IF exposed or concemed: Get medical attention. IF INHALED: Remove person to frach ai and keep comfortable for breathing. Call a POISON CENTER or physician ifyou feel unwell IF SWALLOWED: Immediately cal a POISON CENTER or physician. Do NOT. induea vomiting, IF ON SKIN (orhai): Tako off immediately all contamineted clothing. Rinse skin with water or shower. F ON SKIN: Wash with plenty of scap and water. Call a POISON CENTER or Physician you feel unwvel, Take off contaminated clothing and wash it before reuse, If skin itation ‘occurs: Gel medical atention, IF IH EYES: Rinse cautiously wih water for several minutes, Remove contact lenses, if present and easy iodo, Continue rinsing. Immediately call s POISON CENTER or physician, Storage ‘Store locked up, Store ina well-ventlated place. Keep cool Disposal ispoze of contenis and container in accordance with al local, regional, national and international regulations, ‘Supplemenial label elements: None known, 2.3 Other hazards Hazards not etherwise classified ; None known, SECTION 3: Compositioniinformation on ingredients Product definition : Mivture Physical state Liquid Productingredient name Identifiers GHS Classification ene 1390-207 250-560 | FLAMMABLE LIQUIDS - Category ACUTE TOXICITY (dermal) - Category 4 ‘ACUTE TOXICITY ‘nnaltion)- Category 4 ‘SKIN IRRITATION - Catagory 2 etutanel 1463 zio-s20 | FLAMMABLE LIQUIDS - Catagory 3 ersion: 0.08 ‘ACUTE TOXICITY (oral) - Category 4 ‘SKIN IRRITATION - Cazgory 2 SERIOUS EYE DAMAGE - Category 1 ‘SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract ation) -Categary 3 | SPECIFIC TARGET ORGAN TOXICITY (SING! | (larcote effects) - Categons XPOSURE) Safety wus rennin HEMPEL'S THINNER 08450 © HEF ow SECTION 3: Composition/information on ingredients Jetrytbenzene 100-414 210-514 | FLAMMABLE LIQUIDS - Category 2 ACUTE TOXICITY (inhalation) - Category 4 CARCINOGENICITY -Category 2 ‘SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) ~ Category 2 ASPIRATION HAZARD - Category t solvent naphia (petroleum), light arom. | 64742056 | 29-5 FLAMMABLE LIQUIDS - Catagory 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tac! tation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 [ASPIRATION HAZARD - Catogory 1 :24-4imethybenzons 25536 21-535 | FLAMMABLE LIQUIDS - Category 3 ACUTE TOXICITY (inhalation) ~ Catagory 4 SKIN IRRITATION - Catagory 2 EYE IRRITATION Category 24 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE} (Respiratory trac tation) - Category 3 41,23-trimethylbenzene 528.73-8 zs FLANIMABLE LIQUIDS - Category 3 Comer 96-82-5 50 FLAMMABLE LIQUIDS - Category 3 GARCINOGENICITY -Cetegory 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSLIRE) (Respirtor tract ation) - Category 3 ASPIRATION HAZARD - Calegory 1 “Any concentrallon shown as a range isto protect confidentiality ori due to batch variation, ‘Occupational exposure limits, avaliable, ae listed in Section 8 “There are no additional ingredients present wivch, within the current knawledge ofthe supplist and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting inthis section, SECTION 4: First aid measures 44 Description of first aid measures General In ll cases of doubt, or when symptoms persist, seek medical attention, Never give anything by mouth toan unconscious person, If breathing is inegular, drowsiness, foss of consclousness or cramps: Call 911 and give immediate ‘restment ist ai Eye contact ‘Chack for and remove any contact lenses. immadiately fish eyes with plenty of water for at least 5 minutes, occasionally liting the upper and lower ayelids, Seek immediate medicel attention Inhalation Renove tofresh ar. Keap person warm and at rest not breathing, f breathing is irregular ori respiratory arrast occurs, provide artificial respiration or oxygen by ained personnel, Give nothing by reauth. If unconscious, place in recovery position and get medical atterion immediately Skin contact Revove contaminated clothing and shoes. Wash skin thoroughiy wth soap and waler or use recognized skin cleanser. Do NOT use solvents or thinners, Ingestion If swallowed, soek medical advice immodiately and show this container or label. Keep person warm ‘and at rest, Do not induce vomiting unless directed to do sa by medical personnel. Lower the head so that vomit will nol re-enter the mouth and throat Protection af frst-aiders : No actiunt shall be taken involving any personal risk or without suitable kaining, If itis suspected that fumes are stil present, the rescuer chould wear an eppropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid te give mouth-to-mouth resuscitation, ‘Wash contaminated clothing thoroughly with water before removing it, or wear gloves. 4.2 Most important symptoms and effects, oth acute and delayed Potential acute health effects Eye contact Causes serious eye damage. Inhalation Harmfufifinhaled. Can cause cen‘sal nervous system (CNS) depression. May cause drowsiness or Gizzinass, May cause respiratory Yritaton, ‘Skin contact: Harmful in contact with skin. Causes skin iitation Ingestion Can cause central nervous system (CNS) depression. Bay be fatal if swallowed and enters airways, COver-exposure signsisymptoms Page’ 8/14 HEMPEL'S THINNER 08450 © HEMPEL SECTION 4; First aid measures Eye contact: ‘Adverse symptoms may include the fofowing: pain watering redness Inhalation Adverse symptoms may include the flowing: respiratory tract iittion eoughing ‘nausea or vomiting headache drowsinessatigue dizzinessivertigo Unconsciousness ‘Skin contact Adverse symptoms pain or irtation redness blistering may occur Ingestion ‘Adverse symptoms may include the folowing stomach pains nausea of vomiting ay include the fllowing 43 Indication of any immediate medical attention and special treatment needed Notes to physician Not epplicable. Specific treatments : No specific treatment SECTION 5: Firefighting measures 54 Extinguishing media Extinguishing media Recommended: alcohol resistant foam, CO: powers, water spray. Not to be used. wateret 3.2 Special hazards arising from the substance or mixture Hazards from the substance o Flammable quid and vance. In a fre or if heated, a pressure increase will occur and the container may mixture : burst, with the risk of a subsequent explosion. Runoff to sewer may create fre or explosion hazard. ‘This material is harmful to aquatic bfe with long lasting effects. Fire water contaminated with this ‘material must be contained and prevested from being discharged to any waterway, sewer oF drain, Hazardous combustion products: Decomposition products may include the following materials: carvon oxides 53 Advice for firefighters PPromplly isolate the scene by removing all persons from the viinty of the incident if there is a fre, No action shall be taken involving any personel sk or without suitable taining. Fire will produce dense biack smoke. Exposure to decomposition products may cause a health hazard. Cool closed containers exposed to fre with water. Do not release runaff ftom fre to drains or watercourses, Fire-ighters should ‘wear appropriate protective equipment and seltcontained breatring apparatus (SCBA) witha full fare piove operate! in postive pressure mode. ‘SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures ‘Avoid all direct contact with the spilled material, Exclude sources of ignition and be aware of explosion hazard. Ventilate the area, Avoid breathing vapor or mist. Refer to protective measures listed in sections 7 and 8. No action shall be taken involving any personal risk oF vitheut suitable training. If the product contaminates lakes, rivers, or sewers, Inform the appropriate authorities in accordance with local regulations. 6.2 Environmental precautions ‘Avoid dispersal of spilled material and runoff and contact with sail, waterways, draiss and sewers, Inform the relevant authories ifthe product has caused environmental pollution (sewers, waterways. sol or ai). Water poluting materia. 6.5 Methods and materials for containment and cleaning up Version 0.05 HEMPEL'S THINNER 08450 © hew. EL SECTION 6: Accidental release measures Stop leak if without risk, Move containers from spill area. Approach release from upwind. Prevent enty into sewers, water courses, basements or confined areas. Wash spillages inta an effuent treatment plant or proceed as follows, Contain and colect spilage with non: ‘combustible, absorbent mataral e.g, sand, earth, vermiculta ar diatomaceous earth and place in container for disposal according to local regulations (See Section 13). Use spark-praaf todls and explosion-proof equipment. Contaminsted absorhert material may pose the same hazard as the spilled product, 8.4 Reference to other sections ‘Bee Section 1 for emergency contact information. 'Bee Section 8 for infarmstion on appropriate personal protecve equiprnem. See Section 13 for axttional waste treatment information. SECTION 7: Handling and storage 7 Precautions for safe handling ‘Vapors are heavier than air and may spread along floors. Vapors may form explosive mixtures with ait. Prevent the croation of flammable or ‘explosive Concentrations of vapors in air and avoid vapor concontrattans higher than the occupational exposure limits. In addition, the product should be used only in areas from which al naked lights and other sources of ignition have been excluded. Electical equipment Should be protected to the appropriate standard, To cissipate static electity during transfer, graund drum and contect to receiving ‘container with bonding strap. No sparking tools should be used, ‘Avoid inhalation of vapour, sust and spray mist. Avoid contect with skin and eyes. Eating, drinking and smoking should be prohibited in area ‘where this material is handled, stored and processed, Appropriate personal protecive equipment: see Section 8. Always keep in containers ‘made from the same material asthe original one. 7.2 Conditions for safe storage, including any incompatibiities Store in accordanca wit local regulations. Store in a cy, well-ventilated area away from incompatible materials and ignition sources, Keep out af the reach of children, Keep away Jlom: Oxidizing agents, strong alkali, strong acids. No smoking. Prevent unauthorized ‘access, Containers that are opened must be carefully resealed and kept upright to prevent leekage, 7.3 Specific ond uso(s) See separate Product Data Sheet for recommendations or industial sector specific solutions. This product may be applied using several application fechniquas arid methods of handing may be diferent for each. Apptcation techniques include [but are not limited fo] brushing, rolling, and spray application (conventional, HPLV, airless, pleural component or ‘aerosol car], Avoid the breathing of vapors ans, if spraying, do not breath spray mist or aerosol. SECTION 8: Exposure controls/personal protection 84 Control parameters Protea naa Sanaa a rae Aci Tov ied Ss, 01) Seto mom orcs Srek Snob oe dss Ta 1 Sona bret me, 019 Tis ng as ‘TWA: 100 ppm hours. ' our cout aS, 32098) ‘nk poms na Moot Re Cat Ss, 09)-Asotes ou shi ei so St: Se Cini PEP Ones, 201. Tw wor a TWh amas etree AcOH TL ed Ses, 2016) Tia pongo wee Td Ss, 00 Se rae tomar Sie ts Osos ik one coe Tie freon | ober ane Ses, aor, Safety Data © : : HEMPEL'S THINNER 08450 © HEMPEL SECTION 8: Exposure controls/personal prctection TWA 435 mgin® 8 hours. TWA: 100 ppm 8 hours. salvent naphtha (petaleum), light aram, ACGIH TLY (United States). "TWA Tentative: 25 pom 8 hours 4.24stimethyoenzene ACGIH TLY (United States, 3/20). TWA: 129 mgin*8 hours. TWA: 25 ppm 8 hour. NIOSH REL (United States, 102013}. ‘TWA: 125 migim* 10 hours “FWA: 25 por Onous. 1,2.3timetiyibenzene ACGIH TLV (United States, 32016), TWA 123 mgim 8 hours. TWA: 25 pom 8 hours NIOSH REL (United Statee, 10/2012). TWA: 126 mgin® 10 hours, ‘3WA: 25 ppm 10 hours. cunen ACGIH TLV (United States, 32016). TWA: 50 ppm & hours. NIOSH REL (United States, 10/2013), Absorbed through skin, TWA: 246 magi #0 hous TWA: 50 pom 10 nous, ‘OSHA PEL (United States, 22043). absorbed through skin. TWA: 246 maim? & hous. TWA: 50 ppm & hours Recommended monitering procedures: Iv this product cantains ingredients with expasura limits, personal, workplace atmosphere or biological monitoring may be required ta etermine the effectiveness of the ventilation or ather control measures ardor the necessity to use respizatory protective equipment, Reference shuld be made to appropriate monitoring standards. Reference to national guidance documents for methods forthe Cetermination of hazardous substances will also be require. 8.2 Exposure controls Appropriate engineering controls Provide‘ocal exhaust and ganeral ventilation systems to maintain srborne concentrations below OSHA, ACGIH, and manufacturer recommended exposure limits, Local exhaust ventlation is preferred because t prevents canta-ninant dispereion into work areas by ‘controling tat ts source, Use local and general exhaust ventilation to effectively remove and frevent buildup af mists/vepars/fumes: ‘gonerated from the handling ofthis product. Note: Local exhaust ventilation is designed to capture an emittea contaminant at or near its source, before the contemirant has a elisneo to disperse ino the workplace air. General exhaust ventilation, also called dilstion ventilation, is diferent from local exhaust ventilation ‘becaulsa instead of capturing emissions at ther source and removing them from the air, enerel exhaust ventilation allows the contaminant {0 be emitted into the workplace air and then dilules the concentration of the contaminant to an acceptable level (@., to the PEL or below Individual protection measures General Gloves must be wor fo" all work that may result in sollng. Apron/coverelisiprotective clothing must be worn when soling is so grest that regular work clothes do sal adequately protect kin against contact with the product. Safety eyewear should be used when there is a likelihood of expasure, Hygiene measures, ‘Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking, Using lavatory, and at the end of day. Eyelface protection Safely eyewear complying with an approved standard should be used when a rik assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts, Ifcontactis possible, the following proteeton should be worn, unless the assessment indicates a higher degree ol protection; chemical splash goggles and/or face shield. If inhalation hazards exis, a full-face respirator may be required instead, Hand prtection ‘Wear chemicat-resistantaloves in combination with ‘basic! employee training, The quality of the chemicalcesistant protective gloves must be chosen as a function ofthe specific workplace ‘concentrations and quentty of hazerdous substances. Since the actual work situation is unknown. Supplier of gloves should be contacted in order to find the ‘appropriate type. Below listed glove(s) should be regarded as generic advice: Recommended: Siver Shield / 4H gloves, polyvinyl alcohol (PVA), Viton® May be used: nitrile rubber ‘Short teem exposure: naoprene rubber, butyl rubber, natural rubber ('stex), polyvinyl chloride (VO) age 6a HEMPEL'S THINNER 08450 Ww oie VIPEL SECTION 8: Exposure controls/personal protection Body protection Personal protective equipment for the body should be selacted based on the task being peifermed and ‘he sisks involved handing this product Wear suitable protective clothing, Always wear protective clothing when spraying, Respiratory protection It working areas have insufficient ventilation, wear half or totally covering mask equipped wih gas filter Df type Organic Vapor, when grinding use particle fite of type P95, P99 or P100, When spraying use 2 combined fer (organic vapor! HEPA or organic vapor! P100 type). Be sure to use aporovedieerified respirator or equivalent. Aways wear an al-fed respirator when spraying in & continuous and prolonged work situation (2.9. hood with wipply of fresh ar compressed air ora ful face, powered air purifying iter, Protective dothing (pictograms) @ 7 ® See Note Applicaton of paint products by spraying requltes additonal safety precautions: Full body su, Full face respraterwith ai supplied. Environmental exposure controls Emissions from ventilation or werk process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. in some cases, furne scrubber, ters Cr engireecing modiicators to the process eauipment will be necessary to Teduce emissions to acceptable levels, SECTION 9: Physical and chemical properties 8.4 Information on basic physical and chemicat properties Physical state Liquid Odor Solventike pH ‘Testing not relevant or not possible due to nature of the product, Metting pointtreezing point -84.96°C This is based on data for the following ingredient xylene Boling point/boting range Testing not relevant or not possible due to nature of the product, Flash point ‘Closed cup: 26°C (78.8°F} Evaporation rate ‘Testing not relevant or not possible due to natwe of the product Flammabilly Highly lammable in the presence of the folowing meterials or conditions: open flames, sparks and satis discharge and heat Flammable in the presence ofthe following materials or conditions: oxidizing materia, ‘Stahtly flammable in the prosence of the fellowing materials or coneions: reducing materials. Upperilower Nlammabifty or 08-11.3401% explosive its ‘Vapor pressure 10.89 KPa This is based on data for the folowing ingredient xylone ‘Vapor density ‘Testing not relevant or not possivie due to nature ofthe product, Relative density : 0.857 ole? Solubitiyies) Partially soluble in the following materials: cold water and hat water. Parition coefficient Lagkow): Testing not relevant or not possible due to nature ofthe product. ‘Auto-gnition temperature : Testing not relevant or not possible due to nature ofthe product Decomposition tempersiure: Testing nat ralevant or not possible due to nature of the produc. Viscosity <7 x 10% mls Kinematic viscosity at 40°C. Explosive properties Explosive in the presence of the folowing materials or conuitions: open flares, sparks and static sdischarge and heat (Oxidizing properties, “Testing not relevant or not possibie due to nature ofthe product. 9.2 other information, Solvents) % by weight 100 % (win (included excempt solvents) Water % by weight Weighted average: 0% VOC content (Coatings) 7.45 tostaal (857 of) VOC content (Regulatory) 7.18 lbsigal (887 of) Page 7114 Safety Gaia a HEMPEL'S THINNER 08450 © HEMFci SECTION 9: Physical and chemical properties TOC Content (Volaile) Weighted average? 720.01 Solvent Gas Weighted average: 0.209 ms SECTION 10; Stability and reactivity 10.1 Reactivity No specific est data related to reactivity avsilable for this product orits ingredients, 10.2 Chemical stability “The product is stable 10.3 Possibility of hazardous reactions Under normat conditions of storage and use, hazardous reactions will not cour 10.4 Conditions to avetd ‘Avoid all possible sources ofignition (spark er flame}. Do not pressurize, cut, wel, braze, solder, dil grind or expose containers to heat fr Scurces of gation. 10.5 Incompatible materials Highty reactive or incompaticie with the folloiing materials: oxidizing materials, Reactive or incompatiole withthe following materials: reducing materials, 410.8 Hazardous decomposition products ‘When exposed to high fernperatures (ein case offre) harmful decomposition produats may be formed: Decompesition products may include the following materiale: carbon oxides SECTION 11: Toxicological information 111.4 Information on toxicological effects Exposure fo component solvent vapor concentrations may resuit in adverse health effects such as mucous membrane and respratory system iitaion and adverse effects on the kidneys, Iver and central nervous system, Scivents may cause some ofthe above effects by absorption through the skin. Symptoms and signs include headaches, dizziness, fatigue, muscular weakness, cronsiness and, in extreme cases, loss of consciousness. Repeated or prolonged contact withthe preparation may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. If splashed in the eyes, the quid may cause irtaton and reversible damaye. Accidental ewallowing may cause stomach pain. Chemical lung infammetion riay occur ifthe product is taken into ths lunge vie vomiting Aspiration hazard if swatowed. Can enter lungs and cause damage. Direct contact with the eyes can cause irravarsible damage, including blindness. ‘Acute toxtetty Productiingredient name Result Species Bose Exposure “jena OSD halation Gas. Fat 000 ppm hours {C50 Inhalation Vapor Fal 6350 ppm 4 hours LD800ral Rat 4209 maka e sebutanal {68% Inhalation Vapor Rat 24000 mghn® hours {050 Dermal Rabbit £3400 mara 7 L050 Oral Ret 790 mag : ethylbenzene (550 Bermat Rabbit 35009 mgike e 050 Oral Rat 3500 marc : solvent naphtha (petroleum), ight | L250 Inhalation Vapor Ret 6193 mghn* 4 howe L050 Dermal Rabbit 3160 mag z L050 Oral Rat 3482 mol 7 1 2/trimethyibenzene 1LC50 Inhalation Vapor Rat 418000 magi 4 hours 1350 Oral Rat Saka 7 [cumen LLG50 Inhalation Vapor Rat 38000 mgimn* 4 hours 1LD50 Dermal Rabbit 12300 ug 7 L950 Oral Rat +400 mgikg ‘Acute toxicity estimates s Page: 8/14 HEMPEL'S THINNER 08450 SECTION 11: Toxicological information (\y-cMPEL Route ATE value Oral 22528 mag Dermal 16658 mag Inhalation (gases) 6644.8 opm Inhalation (vapors) 1522 mah Ieritation!Corrosion Productlingrediant name Result Species | Score Exposure bayer Eyes Severe iftant Rabbit (aa hours & miigrams ‘Skin = Moderate iritant Rabbit 7 24 houre 500 millorams s-butanol Eyes - Severe urtant Rabbit : [24 hours 2 mligrams Skin = Madeateiritant Rabhit 7 24 eure 20 miligrams ethyvenzene Shin = Mig itant Rabbi 7 24 houre 18 riligrams Respiratory - Md intant Rabbit 7 i Eyes - Mid intent Rabbit 2 E solvent naphtha (petroleum), light | Eyes Mid itant Rabbit 7 [24 hours 109 microfters Respirator - Md initant Rabbit 7 . Jcumen Eyes - Mle lrtent Rabbit 7 24 hours 500 milfgrams Skin = Moderate iritant Rebbit - [ea nours 100 miigrams Carcinogen Classification Productlingredient name TaRe NTP ‘OSHA payers a : = ethyibenzena a . /cumen a Reasonably 7 anticipated to be a Fruman eareinogen. ‘Specific target organ toxicity (single exposure) Productlingredient name Category _| Route of exposure | Target organs racbutanol eategoys Not apphicable. Respiratory Fact jirtaton and Narcotic etiects solvent naphtha (petroleum), light arom. Jeategon 3 Not appticable. Respiratory tract inition and Narcotic etiects 1,24-vimetrybenzene category3 Not appticable Respiratory tract iretation Cumen category 3 hot apptcable Respiratory tract istation Specific target organ toxicity (repeated exposure) Produatlingredient name Category | Rous of exposure | Target organs etiyibenaene: (Category? Netasiomined [hearing organs a Aspiration hazard Productingredient name Result fethyibenzene [ASPIRATION HAZARE - Category 7 solvent naphtha (petroleum), Tight arom. JASPIRATION HAZARC - Category 1 ‘Cumen |ASPIRATION HAZARC - Category 1 Information on the likely routes of exposure Routes of enity anticipated: Oral, Dermal, Inhalation, Potential chronic health effects (Other information Version: 095 No oxtional known significant effects or cxtical hazards, SECTION 12: Ecological information 42.4 Toxicity Do not allow to enter drains or watercourses. Harmful to aquatic life with ong lasting affects. ‘When spilled, this praduct may act as an of, causing a fi, sheen, emulsion, ur sludge at or beneath the suttace of a body of water. Oils of any kind can cause: (a) drowning of waterfowl due to lack of buoyancy. '0s8 of insulating capacity of feathers, starvation and vulnerability 1o predators dus to lack of mobility; (b) lethal effect on fish by coatiig gil surfaces, preventing respiration: {c) potential ish kil zesuling from alteration in biochemical oxygen demand: (d) asphyxiation of benthic life forms when floating masses become engaged with surface debris ‘and Settle On the bottom; and (2) adverse aesthetis effects of fouled shoreline and beaches: Productiingrodiont name Result Species Exposure | ‘butanol ‘eute EEO 1928 mah Daghaia Sheu Rete L050 1.376 maa Fish 96 hours etnyibenzene Chronic NOEC «1000 gl Fresh water Algae -Pseusckichnerclia subcapiiata |96 hours Solvent naphtha (petiieum). ich | Acute EC502.6 ml [Algae -Pseudokichneriela subcaprata (96 hours arom (green s1o30) ‘culo EOSC6.14 mot apnnia - Daphnia magna 48 hours ‘eote L050 922 mail Fish - Oncorhynchus mytiss (rainbow |86 hours rout) 1,2.4imetiyibenzene ‘Acute LC50 4910 pt Marine water Crustaceans -Elasmopus pectinious = |48 hours duit ‘Acute LE50 7720 yt Fresh water Fish -Pimophales promelas 98 hours cumen ‘Route E050 2.5 moh Algae “2 hours Acute EC5O 7400-11290 ugh Fresh water | Crustaceans Artemia p.-Nauplii | 48 hours ‘Acute EC50 0600-14100 ugi Fresh water | Daphnia-Dephnia magna -Neonate | 48 hours ‘Acute LG50 2700 ug Fresh water Fish - Oncorhynchus mykiss 6 hours ‘Acute NOEC 0:35 mg Algae 21 days 412.2 Persistence and degradability Productiingredient name Test Result Dose | __Inoculum rayne - 0 % -Reaclly -28 days F FS butanol (OECD 3010 Rosey | 92%. 20 days [ : Blodegradablity Closed Bolte Test ethylbenzene 2 370 % -Readily-28 days L . solvent naphtha (petroleum), ght |= >70 % -Readily-28 days, [ " Productlingredient name ‘Aquatic hat-fe Photelysis Biodegradabilty sien. - ° Ready nebula} . 2 Realy ethyloenzene : : Readily solvent naphtna (petroleum). ght . Readily 12.3 Bioaccumulative potential Preductingredient name LogP BOF Potential ‘iene saa a1-288 Tow ebutanol i 3.16 low athylbenzane 36 - low solvent naphtha (petroleum), fight arom, : 10-2500 high 1.2.4rmethylbenzene 36a 243 iow 1.23-rimethybereene 3.88 19498 low Cumen 3.55 36.48 iow 12.4 Mobility in soil Solltwater partion coefficient No Ksiown date avaliable in our database. (Kee) Mobily No known data avaliable in our databace. 12.5 Other adverse effects Version: 0.05 aici HEMPEL'S THINNER 08450 YQ HEMPEL SECTION 12: Ecological information No known significant effects orcitical hazards, SECTION 13: Disposal considerations 13.4 Waste troatment methods. LLispasal should be in accordance with applicable regional, national and local laws and regulations, Local regulations may be more stringent than regionaf ar national requirements, ‘The information presented below only applies to the material as supplied. The identifcation based on characteristio(s} or listing may not apaly if the materal has been used o¢ otherwise contaminated. Its Le responsibly of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste identification and dispasal methods in compliance with applicable regulations, Refer to Section T and Section 8 for acitional handling information and protection of employees. ‘The generation of waste should be avoided or minimized wherever possible. Disposal cf this product, Solutions and any by-products should atalltimes comply wth the requirements of environmental protection and waste disposal legislation and any regional local authonty raquirements. Dispose of surplus and non-recyclabla products via a licensed waste dispasal contractof. Waste should not be disposed of ‘untreated to the sewer unloss fully compliant with the requirements ofall authoriies wit jurisdiction. Waste packeging should be recycled Incineration or landfill should only be considered when recycing isnot feasible. This material and ite container must be disposed of in a ‘safe way, Care should be taken when handling emptied containers that have not been cleaned er rinsed out. Empty containers or liners ‘may retain sore product residues. Vapor from product residues may create a highly lammable or explosive stmosphera inside the ‘container. Do no: cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spllod ‘material and runoff and contact with sol, waterways, drains and sewers, RCRA classification 004 ilgnitable) United States -RCRA Toxic hazardous waste "U" List Ingredient cas # ‘Status Reference umber Diylene ie nT | Led 238 {-Butanol Buy aleohot 71-383 Usted 031 SECTION 14; Transport information Transport may take place according to national regulation or DOT for transport. by road and by train, IMDG for transport by sea, IATA for Alr shipment. Refer to specific Dangerous Goods Transport requirements under 49CFR, ICAO and IATA a ees as oa Sito. Poe cigng mae Tetepetnemed dete! FOE Addon womaton DoT OME FANTRELATEDATENAE 9 ieatioat eat 2 —— a Pecan neti gaan {Teponae qty anon IE UNTZS PAINT RELATED MATERIAL 3 code No. Prgutcneasn 98 oars [set _UN1263._-PAINT RELATED MATERIAL 3 feode mM Re E Code = z IATA —UNI263._—-PAINT RELATED MATERIAL a We. Code : IMDG UNT263._ PAINT RELATED MATERIAL 3 g TH No, mecaancuechesleg Code : Classification PG": Packing group

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