Beruflich Dokumente
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Presentation Outline
Process Basics
Membrane applications
Supply model
UOP experience
Integration with PSA
Integration with UOP licensed technology
Q&A
UOP 7804I-1
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Non-Permeate
High Pressure
P 1.5 bar
FEED GAS
H2 + Impurities
High Pressure
Permeate
High Purity H2
H2 Purity 90 95 % Low Pressure
H2 Recovery 70 98 %
H2 Feed pressure 15-180 bar g
H2 Product pressure 5-80 bar g
All streams at constant flow, pressure, and temperature
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UOP 6196-2
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High Pressure M
P
(Feed) e Qx = A p x
m t
b H2
H2 r Permeability (P) for different components
a Relative permeability: selectivity ()
n Low Pressure
Permeability and selectivity are strongly T-dependent
e (Permeate)
Membrane design parameters : thickness (t), area (A)
H2O, H2, He
Soluble in membrane
Fastest Small molecule
M
FAST e
m
SLOW b H2S, CO2,
r O2
a
n CO, CH4, N2, Ar, C2+
e Insoluble in membrane
Slowest
Large molecule
UOP 7804I-3
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UOP 7804I-4
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UOP 7804I-5
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Exceptional UOP technology delivered fast and with the highest quality
7
Small systems
Large systems
Limited plot space compact design
PSA/Membrane Integration
UOP 7804I-7
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UOP 7804I-8
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UOP 7804I-9
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* includes Hydrotreating/Hydrocracking
** includes Oxo-alcohols, syngas and IGCC
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UOP 7804I-11
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UOP 7804I-12
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Conventional Integrated
PSA Recycle PSA PSA/Membrane
Design Hydrogen Recovery 90% 95% 98%
Incremental Fuel Gas lost, $/yr (1) -- (~ $1.5 MM/yr) (~ $2.2 MM/yr)
Incremental OPEX
-- $1.1 MM/yr $0.5 MM/yr
(Compression Power)
UOP 7804I-14
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Hydrogen
H2 Purity 99.9 %
H2 Recovery 88 %
Net Gas
Recontact
Section
Tail Gas
LPG Reformate
UOP 7804I-15
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Hydrogen
H2 Purity 99.9 %
H2 Recovery 94 %
Net Gas
Recontact
Section
Tail Gas
LPG Reformate
Recycle
UOP 7804I-16
H2 Purification Integrated in UOP Licensed 17
Hydrogen
H2 Purity 99.9 %
H2 Recovery 98 %
Tail Gas
LPG Reformate
Recycle
Fuel Gas
UOP 7804I-18
Platforming Case Study Improved Recycle 19
Hydrogen
H2 Purity 99.9 %
H2 Recovery 98 %
Tail Gas
Recovery
Max
Non-permeate
LPG Reformate
Recycle
UOP 7804I-19
Product Recovery Comparison 20
Value (MM$/yr)
Recov
Base Max Delta [USGC] [NEA] [ME] [India]
LPG (C3+C4), KMTA 89 174 85 55.8 71.0 67.5 58.0
Recovery (LPG Product), Wt-% 45.3 88.5 --- --- --- --- ---
Reformate, KMTA 2483 2489 6 6.3 6.6 6.4 5.8
H2, KMTA 96 105 9 10.0 24.1 4.8 23.0
Recovery (PSA Product), % 89.0 97.7 --- --- --- --- ---
Fuel Gas, KMTA 211 113 -98 -28.5 -76.2 -8.7 -60.3
Net Product Value 43.5 25.5 70.0 26.5
UOP 7804I-20
Evaluation Summary 21
All Region
USGC NEA ME India
CAPEX Investment (EEC*), MM$ 15.2
Delta 10 yr NPV (10% rate of return), MM$ 235.2 94.5 406.0 132.2
* EEC factor = 3
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