D. Gevaa/ Chemistry 26.

1 Page | 1
(2017)

APPENDIX

Standardization of EDTA Solution

Standard CaCO3 solution

Weight of pure CaCO3: 0.50 g

Formula mass of 1 standard: 100.09 g/mol

% Purity of pure CaCO3: 99.9%

Volume of final solution: 100.0 mL

Working standard CaCO3 solution

Volume of standard CaCO3 solution: 5.0 mL

Volume of final solution: 50.0 mL

Trial 1 2 3
Volume of working Ca(II) standard, mL 10.0 10.0 10.0
Net volume of EDTA, mL 6.8 6.7 6.7
M EDTA 7.34 10-3 M 7 .45 10-3 M 7 .45 10-3 M
Average M EDTA 0.007412007858 M or 7.41 103 M
Titer 0.7418678665 mg/mL or 0.74 mg/mL

Sample Analysis
Brand of mineral water used: Viva!
mg
Mineral Water content: 54 Ca
L
mg
10 Mg
L

ppm CaCO3 from ppm Ca 134.86 ppm

ppm CaCO3 from ppm Mg 41.18 ppm
Total water hardness: 176.04 ppm

Trial 1 2 3
Volume of water sample, mL 50.0 50.0 50.0
Net volume of EDTA, mL 7.3 7.3 7.2
Total Hardness 108.31 ppm 108.31 ppm 106.83 ppm
Average 107.82 ppm
RSD 7.93 ppt
Confidence Interval 107. 82 2.11
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Calculations

1 mol CaC O3
g CaC O3 %purity
M stock CaC O 3 = 100.09 g CaC O3 =
L solution
1 mol CaC O3 99.9
0.50 g CaC O3
100.09 g CaC O3 100 = 0.04990508542 M
0.100 L

M working standard CaC O3

M stock V stock ( 0.04990508542 M ) (5 mL)
= =0.004990508542 M
V w . std. 50 mL

Standardization of EDTA Solution

1mol EDTA
M w .std . soln V w . std. soln .
M EDTA 1 mol CaC O3

V EDTA

Trial 1
1 mol EDTA
0.004990508542 M 10 mL
1 mol CaC O3
M EDTA =
6.8 mL

= 0.00733898315 M or 7.34 10-3 M

Trial 2
1 mol EDTA
0.004990508542 M 10 mL
1 mol CaC O3
M EDTA =
6.7 mL
= 0.007448520212 M or 7 .45 10-3 M

Trial 3
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1 mol EDTA
0.004990508542 M 10 mL
1 mol CaC O3
M EDTA =
6.7 mL

= 0.007448520212 M or 7 .45 10-3 M

Average M EDTA

0.00733898315 M + 0.007448520212 M +0.007448520212 M

M EDTA ave =
3

= 0.007412007858 M or 7.41 103 M

1 mmolCa CO3
Titer = M EDTA ave EW of CaC O3
1 mmol EDTA
mg 1 mmol Ca CO3
(
= ( 0.007412007858 M ) 100.09
mmol )

1 mmol EDTA
= 0.7418678665 mg/mL or 0.74 mg/mL

Sample Analysis
1 mol CaC O 100.09g
( 140.078 Ca )( )(1 mol CaC O )
mol 3
ppm CaC O3 from ppm Ca = (54 ppm )
g 1 mol Ca 3
= 134.8585259 ppm or 134.86 ppm CaC O3

1 mol CaCO 100.09g

(124.305 Mg )( )(1 mol CaCO )
mol 3
ppm CaCO 3 from ppm Mg = ( 10 ppm )
g 1 mol Mg 3
= 41.18082699 ppm or 41.18 ppm CaC O3

Total Water Hardness (theoretical) = 134.8585259+ 41.18082699 = 176.0393529 ppm or 176.04 ppm CaC

Titer Net Volume of EDTA

Total Hardness =
Volume of Water Sample

Trial 1
(0.7418678665 mg/mL) (7.3 mL)
Total Hardness = = 108.3127085 ppm or 108.31 ppm
0.0 50 L

Trial 2
(0.7418678665 mg/mL) (7.3 mL)
Total Hardness = = 108.3127085 ppm or 108.31 ppm
0.0 50 L

Trial 3
(0.7418678665 mg/mL) (7.2 mL)
Total Hardness = = 106.8289728 ppm or 106.83 ppm
0.0 50 L
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108.3127085 + 108.3127085 + 106.8289728

Average Total Hardness = =107.8181299 ppm or 107.82 ppm
3

106.83 107.82 2

31
2
Standard Deviation, s = 108.31 107.82 + .8544783984
108.31 107.82 2+

s 0.8544783984
Relative Standard Deviation = = 1000 ppt = 7.925182891 ppt
X 107.8181299

ts (4.30)(0 .8544783984)
CL= x = 107.8181299 = 107.8181299
n 3
2.121333333 = 107. 82 2.11

Interval: 105.71109.93