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Relative Motion
Determining whether something changes position requires a point of reference. An object
changes position if it moves relative to a reference point. To vi sualize this, picture
yourself competing in a 100-m dash. You begin just behind the start line. When you pass
the finish line, you are 100 m from the start line. If the start line is your reference point,
then your position has changed by 100 m relative to the start line, and motion has
occurred.
Distance and Displacement Suppose you are to meet your friends at the park in
five minutes. Can you get there on time by walki ng, or should you ride your bike? To
help you decide, you need to know the distance you will travel to get to the park. This
distance is the length of the route you will travel from your house to the park.
Suppose the distance you traveled from your house to the park was 200 m. When you get
to the park, how would you describe your location? You could say that your location was
200 m from your house. However, your final position depends on both the distance you
travel and the direction. Did you go 200 m east or west? To describe your final position
exactly, you also would have to tell the direction from your starting point. To do this, you
would specify your displacement. Displacement includes the distance between the
starting and ending points and the direction in which you travel.
The unit for speed is the unit of distance divi ded by the unit of time. In SI units, speed is
measured in units of m/smeters per second. However, speed can be calculated using
other units such as ki lometers for distance and hours for time.
Average Speed A car traveling in city traffic might have to speed up and slow down
many times. How could you describe the speed of an object whose speed is changing?
One way is to determine the object s average speed between where it starts and
stops. The speed equation written above can be used to calculate the average speed.
Aver age speed is found by divi ding the total distance traveled by the total time taken.
Velocity
The motion of an object also depends on the direction in which the object is movi ng. The
direction of an object s motion can be described with its velocity. The velocity of an
object is the speed of the object and the direction of its motion. For example, if a car is
movi ng west with a speed of 80 km/h, the car s velocity is 80 km/h west. The velocity of
an object is sometimes represented by an arrow. The arrow points in the direction in
which the object is movi ng. The velocity of an object can change if the object s speed
changes, its direction of motion changes, or they both change. For example, suppose a car
is traveling at a speed of 40 km/h north and then turns left at an intersection and
continues on with a speed of 40 km/h. The speed of the car is constant at 40 km/h, but the
velocity changes from 40 km/h north to 40 km/h west.
Constant speed means steady speed, neither speeding up nor slowing down. Constant
velocity, on the other hand, means both constant speed and constant direction. Constant
direction is a straight line-the object's path doesn't curve. So constant velocity means
motion in a straight line at a constant speed-motion with no acceleration.
Figure : 7
Figure : 8
Slowing Down Now suppose you are biki ng at a speed of 4 m/s and you apply the
brakes. This causes you to slow down. When you slow down, your velocity changes
because your speed decreases. This means that acceleration occurs when an object
slows down, as well as when it speeds up. The car in Figure 8 is slowing down. During
each time interval, the car travels a smaller distance, so its speed is decreasing.
Changing Direction The velocity of an object also changes if the direction of motion
changes. Then the object doesn t move in a straight line, but instead moves in a curved
Calculating Acceleration
If an object is moving in only one direction, its acceleration can be calculated using this
equation.
In this equation, time is the length of time over which the motion changes. In SI units,
acceleration has units of meters per second squared (m/s2).
Figure: A particle moving along the x axis with constant acceleration ax; (a) the position time graph, (b) the
velocitytime graph, and (c) the accelerationtime graph.
Worked-out Problems:
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Problems:
Changing Motion What happens to the motion of an object when you exert a force on
it? A force can cause the motion of an object to change. If you have played billiards, you
know that you can cause a ball at rest to roll into a pocket by striki ng it with another ball.
The force applied by the movi ng ball causes the ball at rest to move in the direction of the
force.
Balanced Forces Force does not always change velocity. In Figure 12A, two
students are pushing on opposite sides of a box. Both students are pushing with an equal
force but in opposite directions. When two or more forces act on an object at the
same time, the forces combine to form the net for ce. The net force on the box in Figure
12A is zero because the two forces cancel each other. Forces on an object that are equal
in size and opposite in direction are called balanced for ces.
Unbalanced Forces Change Velocity When the forces acting on an object are
balanced, the velocity of an object doesn t change. If you and a friend push on a door
from opposite sides with the same size force, the door doesn t move. The net force is zero
and the forces are balanced. But if you push harder, the door moves in the direction of
your push. The velocity the door, or any object, changes only when the forces on it are
unbalanced.
Friction
Suppose you give a skateboard a push with your hand. The skateboard speeds up as you
push it and then keeps movi ng after it leaves your hand. What happens to the
skateboard s speed if it is movi ng on a flat, level surface? You know the answer. The
skateboard slows down and finally stops. After it left your hand, the skateboard s velocity
changed because the forces acting on it were unbalanced. The unbalanced force that
slowed the skateboard was friction. Fr iction is the force that opposes the sliding motion
of two surfaces that are in contact.
What causes friction? The size of the frictional force exerted by one surface on
another depends on the materials the surfaces are made from and the roughness of the
surfaces. All surfaces have bumps and dips, including highly-polished metal surfaces that
seem very smooth. When two surfaces are in contact, sticki ng occurs where the bumps
and dips touch each other. This causes microwelds to form between the two surface.
These microwelds tend to make the surfaces stick together and cause friction to occur.
The frictional force between two surfaces increases when the force pushing the surfaces
together increases, as shown in Figure 13. When the surfaces are pushed together with
more force, more of the bumps and dips come into contact. This increases the strength of
the microwelds.
Figure 13
General Science and Environment Page 12
Static Friction Suppose you push
on a heavy box, like the one in the
figure left, and it doesn t budge. The
velocity of the box didn t change, so
another force is acting on the box that
balances your push. This force is a
frictional force called static friction that
is due to the microwelds that have
formed between the box and the floor.
Static fr iction is the frictional force
that prevents two surfaces in contact
from sliding past each other. In this
case, the box didn t move because your
push is not large enough to break the microwelds between the two surfaces.
Sliding Friction You and a friend push together on the box and the box slides along the
floor, as shown in Figure below. As the box slides on the floor, another frictional
forcesliding friction opposes the motion of the box. Sliding fr iction is the force that
acts in the opposite direction to the motion of a surface sliding on another surface. If you
stop pushing, sliding friction causes the box to slow down and stop. The force due to
sliding friction between two surfaces is smaller than the force due to static friction.
Rolling Friction When an object rolls over a
surface, a frictional force due to rolling friction
slows the object down. Rolling friction usually is
much less than sliding friction. This is why it is
easier to move a heavy object if it is on wheels.
Air Resistance
When an object falls toward Earth, it is pulled downward by the force due to gravi ty.
However, a type of frictional force called air r esistance opposes the motion of objects
that move through the air. Air resistance causes objects to fall with different accelerations
and different speeds. If there were no air resistance, then all objects, like the apple and
feather would fall with the same acceleration.
Air resistance acts in the direction opposite to the velocity of an object movi ng in air. If
an object is falling downward, air resistance acts upward on the object. The size of the air
resistance force depends on the size and shape of an object. Imagine dropping two
identical plastic bags. One is crumpled into a ball and the other is spread out. When the
bags are dropped, the crumpled bag falls faster than the spread-out bag.
Air r esistance incr eases with incr easing velocity of the falling obj ect.
Inertia and the First Law of Motion According to the first law of motion, the
velocity of an object doesn t change unless the forces acting on the object are
unbalanced. In other words, if you observe a change in an object s velocity, you know
an unbalanced force acted on it. This is similar to the definition of inertiaan object
resists a change in its motion. As a result, the first law of motion sometimes is called the
law of inertia. Inertia and the first law of motion explain why the boxes in the Figure
below slide off the cart when the cart comes to a sudden stop. The student applies an
unbalanced force to the cart that makes it stop. However, the inertia of the boxes causes
them to keep moving even after the cart stops.
or
Acceleration equals the net force divi ded by the mass. If the net force acting on an object
is doubled, the object's acceleration will be doubled. Suppose instead that the mass is
doubled. Then the acceleration will be halved. If both the net force and the mass are
doubled, then the acceleration will be unchanged.
We can call one force the action force, and we can call the other the reaction force. The
important thing is that they are coequal parts of a single interaction and that neither force
exi sts without the other. Action and reaction forces are equal in strength and opposite in
direction. They occur in pairs, and they make up a single interaction between two things.
There is a simple rule for identifying action and reaction forces. First, identify the
interaction-one thing (object A) interacts with another (object B). Then, action and
reaction forces can be stated in the following form:
Action: Object A exerts a force on object B.
Reaction: Object B exerts a force on object A.
Same principle applies to a rocket, which continually "recoils" from the ejected exhaust
gas. Each molecule of exhaust gas is like a tiny cannonball shot from the rocket.
We see Newton's third law in action everywhere. A fish propels water backward with its
fins, and the water propels the fish forward. The wind caresses the branches of a tree, and
the branches caress back on the wind to produce whistling sounds. Forces are interactions
between different things. Every contact requires at least a two-ness; there is no way that
an object can exert a force on nothing. Forces, whether large shoves or slight nudges,
always occur in pairs, each opposite to the other.
SOLVED PROBLEMS
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Problems
We can see from the definition that a movi ng object can have a large momentum if either
its mass or its velocity is large or both its mass and its velocity are large. A truck has
more momentum than a car movi ng at the same velocity because it has a greater mass.
We can see that a huge ship movi ng at a small velocity can have a large momentum, as
can a small bullet movi ng at a high velocity.
I mpulse
Changes in momentum may occur when there is a change in the mass of an object, or a
change in its velocity, or both. If momentum changes while the mass remains unchanged,
as is most often the case, then the velocity changes. Acceleration occurs. And what
produces acceleration? The answer is force. The greater the force acting on an object, the
greater will be the change in velocity and, hence, the change in momentum.
But something else is important also: time-how long the force acts. Apply a force briefly
to a stalled automobile and you produce a small change in its momentum. Apply the same
force over an extended period of time, and a greater momentum change results. A long
sustained force produces more change in momentum than the same force applied briefly.
So, for changing an object's momentum, both force and the time interval during which
the force acts are important.
The quantity " for ce X time inter val" is called impulse.
The gr eater the impulse exer ted on something, the gr eater will be its change in
momentum. This is known as the impulse-momentum r elationship. M athematically,
the exact r elationship is
Consider a cannon being fired. Both the force that drives the cannonball and the force
that makes the cannon recoil are equal and opposite (Newton's third law). To the system
consisting of the cannon and the cannonball, they are internal forces.
Collisions
The conservation of momentum is especially useful in collisions, where the forces
involved are internal forces. In any collision, we can say that
Net momentum befor e collision = net momentum after collision.
When a movi ng billiard ball hits another billiard ball at rest head-on, the first ball comes
to rest and the second ball moves with the initial velocity of the first ball. We call this an
elastic collision; the colliding objects rebound without lasting deformation or the
generation of heat. In this collision, momentum is transferred from the first ball to the
second. Momentum is conserved.
A car movi ng along a road has ki netic energy. A car that is twice as heavy moving at the
same speed has twice the ki netic energy. That's because a car that is twice as heavy has
twice the mass. Kinetic energy depends on mass. But note that it also depends on speed-
not just plain speed, but speed multiplied by itself speed squared. If you double the speed
of a car, you'll increase its ki netic energy by four (2x 2 = 4). Or, if you drive three times
as fast, you will have nine times the kinetic energy (3x 3 = 9). The fact that kinetic
energy depends on the square of the speed means that small changes in speed can
produce large changes in ki netic energy. The squaring of speed means that ki netic energy
can only be zero or positive-never negative.
Whenever energy is transformed or transferred, none is lost and none is gained. In the
absence of work input or output, the total energy of a system before some process or
event is equal to the total energy after.
SOLVED PROBLEMS
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Problems:
CHECK YOURSELF
1. According to the equation for gravi ty, what happens to the force between two bodies if
the mass of only one body is doubled?
2. What happens if the masses of both bodies are doubled?
3. What happens if the mass of one body is doubled and the other is tripled?
4. Gravi tational force acts on all bodies in proportion to their masses. Why, then, doesn't
a heavy body fall faster than a light body?
The greater the distance from Earth's center, the less the
gravitational force on an object. In Newton's equation for gravi ty,
the distance term d is the distance between the centers of the masses
of objects attracted to each other. Note that the girl at the top of the
ladder weighs only 1/4th as much as she weighs at the Earth's
surface. That's because she is twice the distance from Earth's center.
We know, weight is the force due to gravi ty on a body, mg. Your weight does have the
value of mg if you're not accelerating. To generalize, we now refine this definition by
The center of gravi ty (CG) of an object is the point located at the object's average
position of weight. For a symmetrical object, this point is at the geometric center.
But an irregularly shaped object, such as a baseball bat, has more weight at one
end, so its CG is toward the heavi er end. A piece of tile cut into the shape of a tri-
angle has its CG one third of the way up from its base. The position of an object's CG
relative to its base of support determines the object's stability. The rule for stability is
this: If the CG of an object is above the area of support, the object will remain upright. If
the CG extends outside the area of support, the object will topple.
If you whirl an empty tin can on the end of a string, you find that you must keep
pulling on the string . You pull inward on the string to keep the can revolvi ng over your
head in a circular path. A force of some ki nd is required for any circular motion,
including the nearly circular motions of the planets around the Sun.
Any force that causes an object to follow a circular path is called a centripetal force.
Centripetal means "center-seeki ng," or "toward the center." Centripetal force is not a new
ki nd of force. It is simply a name given to any force that is directed at right angles to the
path of a movi ng object and that tends to produce circular motion. The gravi tational force
acting across space is a centripetal force that keeps the Moon in Earth's orbit. Likewise,
electrons that revolve about the nucleus of an atom are held by an electrical force that is
directed toward the central nucleus.
Without gravi ty, you could toss a rock upward at an angle and it would follow a straight-
line path. But, due to gravi ty, the path curves. A tossed rock, a cannon- ball, or any object
that is projected by some means and continues in motion by its own inertia is called a
projectile.
A very simple projectile is a falling stone, as shown in Figure 5.22. The stone gains speed
as it falls straight down, as indicated by a speedometer. Remember that a freely falling
object gains 10 meters/second during each second of fall. This is the acceleration due to
gravity, 10 m/s-2 . If it begins its fall from rest, 0 m/s, then at the end of the first second of
fall its speed is 10 m/s. At the end of 2 seconds, its speed is 20 m/s-and so on. It keeps
gaining 10 m/s each second it falls.
Although the change in speed is the same each second, the distance of fall keeps
increasing. That's because the average speed of fall increases each second. Let's apply
this to a new situation-throwing the stone horizontally off the cliff. First, imagine that
gravi ty doesn't act on the stone. In Figure 5.23 we see the positions the stone would have
if there were no gravity. Note that the positions each second are the same distance apart.
That's because there's no force acting on the stone.
In the real world, there is gravi ty. The thrown stone falls beneath the straight
line it would follow with no gravi ty (Figure 5.24). The stone curves as it falls.
Interestingly, this familiar curve is the result of two ki nds of motion occurring at
the same time. One ki nd is the straight -down vertical motion of Figure 5.22. The
other is the horizontal motion of constant velocity, as imagined in Figure 5.23.
Both occur simultaneously. As the stone moves horizontally, it also falls straight
Fast-Movi ng Projectiles-Satellites
At this speed, atmospheric friction would incinerate the projectile. This happens to grains
of sand and other small meteors that graze the Earth's atmosphere, burn up, and appear as
"falling stars." That is why satellites like the space shuttles are launched to altitudes
higher than 150 ki lometers-to be above the atmosphere.
Solved Problems:
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Problems:
Satellites are payloads carried above the atmosphere by rockets. Putting a payload into
orbit requires control over the speed and direction of the rocket. A rocket initially fired
vertically is intentionally tipped from the vertical course as it rises. Then, once above the
drag of the atmosphere, it is aimed horizontally, whereupon the payload is given a final
thrust to orbital speed.
For a satellite dose to Earth, the period (the time for a complete orbit about the Earth) is
about 90 minutes. For higher altitudes, gravi tation is less and the orbital speed is less, so
the period is longer. For example, communication satellites located at an altitude of 5.5
Earth radii have a period of 24 hours. This period matches the period of daily Earth
rotation. For an orbit around the equator, such a satellite stays above the same point on
the ground. That is, it is in geo-synchronous orbit.
Molecules A particle consisting of two or more atoms that are bonded together is called
a molecule. Oxygen in the air, as an example, is a diatomic (two-atom) molecule. A
molecule is a basic unit of a molecular compound. The simple sugars you eat; the
proteins in your body; and the wool and cotton fibers in your clothes all consist of
molecules formed from bonded atoms.
States of Matter
Gases, liquids and solids are all made up of microscopic particles, but the behaviors of these
particles differ in the three phases.
Particles in a:
o gas are well separated with no regular arrangement.
o liquid are close together with no regular arrangement.
o solid are tightly packed, usually in a regular pattern.
Particles in a:
o gas vibrate and move freely at high speeds.
o liquid vibrate, move about, and slide past each other.
o solid vibrate (jiggle) but generally do not move from place to place.
Liquids and solids are often referred to as condensed phases because the particles are very close
together.
The following table summarizes properties of gases, liquids, and solids and identifies the
microscopic behavior responsible for each property.
The following table summarizes properties of gases, liquids, and solids and identifies the
microscopic behavior responsible for each property.
assumes the shape and assumes the shape of the retains a fixed volume and
volume of its container part of the container which shape
particles can move past it occupies rigid - particles locked into
one another particles can move/slide place
past one another
Properties of Matter
Just as you use several adjectives to describe someone (color of hair or
eyes, how tall or short, etc.) several properties, or characteristics, must be
used in combination to adequately describe a kind of matter. Simply saying
that something is a colorless liquid isn't enough to identify it as water. The
following chart shows the differences between the two kinds of properties,
chemical and physical, as well as how the two kinds of physical properties,
intensive and extensive, differ.
Futher experiments by Brown and others showed that the motion became more rapid and the
particles moved farther in a given time interval when the temperature of the water was raised,
when the viscosity of the fluid was lowered, or when the size of the particles was reduced.
This motion makes sense if you imagine the pollen grain or dust mote being bombarded on
all sides by particles too tiny to see, that are in constant motion.
The atoms or molecules that make up a liquid or gas are in constant thermal motion, and their
velocity distribution is determined by the temperature of the system. The motion of the
molecules of the fluid, due to the fact that the fluid contains heat, causes the molecules to strike
the suspended particles at random. The impact makes the particles move ... the net effect is an
erratic, random motion of the particle through the fluid.
The most commonly used temperature scale in the US today is the Fahrenheit scale, abbreviated F. In
this scale, water freezes at 32 degrees and boils at 212 degrees Another common scale is the Celsius
(also called Centigrade) scale. In this scale, water freezes at 0 degrees and boils at 100 degrees.
There are also temperature scales in which zero is absolute zero, the lowest possible temperature.
Absolute zero is at -273.15 Celsius, or -459.67 Fahrenheit.The Kelvin temperature scale uses the same
size degree as Celsius, but has its zero set to absolute zero. To convert from Celsius to Kelvin, add
273.15 to the Celsius reading.
Imagine that you cut something in half. Then, you cut each half in half and continue doing so.
Could you keep cutting the pieces in half forever? Around 440 BC, a Greek philosopher named
Democritus (di MAHK ruh tuhs) thought that you would eventually end up with a particle that
could not be cut. He called this particle an atom. The word atom is from the Greek
word atomos, which means not able to be divided. We now know that matter is made of
particles that we call atoms. An atom is the smallest particle into which an element can be
divided and still have the properties of that element.
Figure 3
The Parts of
an Atom
Almost all kinds of
atoms are made of
the same three
particles. These
particles are
protons, neutrons,
and electrons, as
the model in Figure
1 shows. The
particles in the
pictures are not
shown in their
correct proportions.
Mass Number The mass number of an atom is the sum of the number of protons and
the number of neutrons in the nucleus of the atom. Look at Table 3 to see that this is
true. If you know the mass number and the atomic number of an atom, you can calculate
the number of neutrons. The number of neutrons is equal to the atomic number subtracted
from the mass number.
Atoms of the same element with different numbers of neutrons can have different
properties. For example, carbon with a mass number equal to 12, or carbon-12, is the
most common form of carbon. Carbon-14 is present on Earth in much smaller quantities.
Carbon-14 is radioactive, while carbon-12 is not.
Isotopes
Models of two kinds of
hydrogen atoms are shown
in Figure 4. They are both
hydrogen atoms because
they each have one proton.
But one of the atoms also
has a neutron in its nucleus.
The two hydrogen atoms are
isotopes of each other.
Isotopes are atoms that have
the same number of protons but have different numbers of neutrons. Atoms that are isotopes of
each other are always the same element, because isotopes of the same element always have
the same number of protons. They have different numbers of neutrons, however, which gives
them different masses.
Discovering a Pattern
In the late 1800s, Dmitri Mendeleev, a Russian chemist, searched for a way to
organize the elements. When he arranged all the elements known at that
time in order of increasing atomic masses, he discovered a pattern. Chemical properties
found in lighter elements could be shown to repeat in heavi er elements. Because the
pattern repeated, it was considered to be periodic. Today, this arrangement is called the
periodic table of elements. In the per iodic table, the elements are arranged by increasing
atomic number and by changes in physical and chemical properties.
Mendeleevs Predictions Mendeleev had to leave blank spaces in his periodic table
to keep the elements properly lined up according to their chemical properties. He looked
at the properties and atomic masses of
the elements surrounding these blank
spaces. From this information, he was
able to predict the properties and the
mass numbers of new elements that had
not yet been discovered. Table 4
shows Mendeleev s predicted
properties for germanium, which he
called ekasilicon. His predictions
proved to be accurate. Scientists later
discovered these missing elements and
found that their properties were
ext remely close to what Mendeleev had
predicted.
Rows on the Table Remember that an atomic number found on the periodic table is
equal to the number of electrons in an atom. Look at Figure 10. The first row has
hydrogen with one electron and helium with two electrons both in energy level one.
Because energy level one is the outermost level containing an electron, hydrogen has one
outer electron. Helium has two outer electrons. Recall from Figure 9 that energy level
one can hold only two electrons. Therefore, helium has a full or complete outer energy
level.
The second row begins with lithium, which has three electrons, two in energy level one
and one in energy level two. Lithium has one outer electron. Lithium is followed by
beryllium, with two outer electrons, boron with three, and so on until you reach neon,
with eight outer electrons. Again, looki ng at Figure 9, energy level two can hold only
eight electrons. Therefore, neon has a complete outer energy level. Do you notice how
the row in the periodic table ends when an outer energy level is filled? In the third row of
elements, the electrons begin filling energy level three. The row ends with argon, which
has a full outer energy level of eight electrons.
Figure 10
Electron Dot Diagrams Did you notice that hydrogen, lithium, and sodium
each have one electron in their outer energy levels? Elements that are in the
same group have the same number of electrons in their outer energy levels. An
electr on dot diagr am uses the symbol of the element and dots to represent the
electrons in the outer energy level. Figure shows the electron dot diagram for
four of the Group 1 elements.
Same Group, Similar Properties The elements in Group 17, the
halogens, have electron dot diagrams similar to chlorine, shown in Figure 12.
All halogens have seven electrons in their outer energy levels.
Fig: 12
Regions on the
Periodic Table
The periodic table has several
regions with specific names. The
horizontal rows of elements on the
periodic table are called per iods.
The elements incr ease by one
pr oton and one electr on as you
go fr om left to r ight in a per iod.
All of the elements in the blue
squares in Figure are metals.
Iron, zinc, and copper are
examples of metals. Most metals
exi st as solids at room temperature. They are shiny, can be drawn into wires, can be
pounded into sheets, and are good conductors of heat and electricity.
Those elements on the right side of the periodic table, in yellow, are classified as
nonmetals. Oxygen, bromine, and carbon are examples of nonmetals. Most nonmetals are
gases, are brittle, and are poor conductors of heat and electricity at room temperature.
The elements in green are metalloids or semimetals. They have some properties of both
metals and nonmetals. Boron and silicon are examples of metalloids.
How do you suppose protons and neutrons are held together so tightly in the nucleus?
Positive electric charges repel each other, so why don t the protons in a nucleus push
each other away? Another force, called the str ong for ce, causes protons and
neutrons to be attracted to each other, as shown in Figure. The strong force is one of the
four basic forces in nature and is about 100 times stronger than the electric force. The
attractive forces between all the protons and neutrons in a nucleus keep the nucleus
together. However, protons and neutrons have to be close together, like they are in the
nucleus, to be attracted by the strong force. The strong force is a short-range force that
quickl y becomes extremely weak as protons and neutrons get farther apart. The electric
force is a long-range force, so protons that are far apart still are repelled by the electric
force.
Radioactivity
Many types of nuclei are held together permanently and are stable. However, there are
many other types of nuclei that are unstable. These nuclei break apart, or decay, by
emitting particles and energy. This process of nuclear decay is called r adioactivity.
A nucleus that decays is called a radioactive nucleus.
Nuclei that contain large numbers of protons and neutrons tend to be unstable. In fact, all
nuclei that contain more than 83protons are radioactive. However, many other nuclei that
contain fewer than 83 protons also are radioactive. Even some nuclei with only one or a
few protons are radioactive.
Almost all elements with more than 92 protons don t exi st naturally on Earth. They have
been produced only in laboratories and are called synthetic elements. These synthetic
elements are unstable and decay soon after they are created.
Nuclear Numbers A nucleus can be described by the number of protons and neutrons
it contains. A nucleus can be represented by a symbol that includes its atomic number,
mass number, and the symbol of the element it belongs to. The symbol for the nucleus of
the stable isotope of carbon is shown below as an example.
This isotope is called carbon-12. The number of neutrons in the nucleus is the mass
number minus the atomic number. So the number of neutrons in the carbon-12 nucleus is
12 - 6 = 6. Carbon-12 has six protons and six neutrons. Now, compare the isotope
carbon-12 to this radioactive isotope of carbon:
Nuclear Radiation
When an unstable nucleus decays, particles and energy called nuclear radiation are
emitted from it. The three types of nuclear radiation are alpha, beta (BAY tuh), and
gamma radiation. Alpha and beta radiation are particles. Gamma radiation is an
electromagnetic wave.
Alpha Particles
When alpha radiation occurs, an alpha par ticlemade of two protons and two neutrons,
is emitted from the decaying nucleus. An alpha particle is the same as the nucleus of a
helium atom. It has a charge of +2 and an atomic mass of 4.Its symbol is the same as the
symbol of a helium nucleus,42
Compared to beta and gamma radiation, alpha particles are much more massive. They
also have the most electric charge. As a result, alpha particles lose energy more quickl y
when they interact with matter than the other types of nuclear radiation do. When alpha
particles pass through matter, they exert an electric force on the electrons in atoms in
their path. This force pulls electrons away from atoms and leaves behind charged ions.
Alpha particles lose energy quickl y during this process. As a result, alpha particles are the
least penetrating form of nuclear radiation. Alpha particles can be stopped by a sheet of
paper.
Transmutation When an atom emits an alpha particle, it has two fewer protons, so it is
a different element. Tr ansmutation is the process of changing one element to another
through nuclear decay. In alpha decay, two protons and two neutrons are lost from the
nucleus. The new element has an atomic number two less than that of the original
element. The mass number of the new element is four less than the original element.
Beta Particles
A second type of radioactive decay is called beta decay. Sometimes in an unstable
nucleus a neutron decays into a proton and emits an electron. The electron is emitted
from the nucleus and is called a beta par ticle. Because the atom now has one more
proton, it becomes the element with an atomic number one greater than that of the
original element. Atoms that lose beta particles undergo transmutation. However, because
the total number of protons and neutrons does not change during beta decay, the mass
number of the new element is the same as that of the original element.
Figure 9 shows a transmutation caused by beta decay.
Damage from Beta Particles Beta particles are much faster and more penetrating
than alpha particles. They can pass through paper but are stopped by a sheet of aluminum
foil. Just like alpha particles, beta particles can damage cells when they are emitted by
radioactive nuclei inside the human body.
Radioactive Half-Life
If an element is radioactive, how can you tell when its atoms are going to decay? Some
radioisotopes decay to stable atoms in less than a second. However, the nuclei of certain
radioactive isotopes require millions of years to decay. A
measure of the time required by the nuclei of an isotope to decay
is called the half-life. The half-life of a radioactive isotope is the
amount of time it takes for half the nuclei in a sample of the
isotope to decay. The nucleus left after the isotope decays is
called the daughter nucleus. For example, radium-226 has a half-
life of 1620 years, which means that half of a pure radium-226
sample will be converted to other elements by the end of 1620
years. In the next 1620 years, half of the remaining radium
will decay, leaving only one-fourth the original amount of
radium. (After 20 half-lives, the initial quantity of radium-226
will be diminished by a factor of about 1 million; Figur e 11)
The half-life of an element is remarkably constant and not
affected by external conditions. Some radioactive isotopes have half-lives that are less
than a millionth of a second, while others have half-lives of more than a billion years.
Figure 10 shows how the number of decaying nuclei decreases after each half-life.
Half-lives vary widely among the radioactive isotopes. For example, polonium-214 has a
half-life of less than a thousandth of a second, but uranium-238 has a half-life of 4.5
billion years. The half-lives of some other radioactive elements are listed in Table 4.
Carbon Dating The radioactive isotope carbon-14 often is used to estimate the ages of
plant and animal remains. Carbon-14 has a half-life of 5,730 years and is found in
molecules such as carbon dioxi de. Plants use carbon dioxi de when they make food, so all
plants contain carbon-14.When animals eat plants, carbon-14 is added to their bodies.
Nuclear Fission
In the 1930s, physicist Enrico Fermi thought that by bombarding nuclei with neutrons,
nuclei would absorb neutrons and heavi er nuclei would be produced. However, in 1938,
Otto Hahn and Fritz Strassmann found that when a neutron strikes a uranium-235
nucleus, the nucleus splits apart into smaller nuclei. In 1939 Lise Meitner was the first to
offer a theory to explain these results. She proposed that the uranium-235 nucleus is so
distorted when the neutron strikes it that it divi des into two smaller nuclei, as shown in
Figure 16. The process of splitting a nucleus into several smaller nuclei is nuclear
fission. The word fission means to divide.
Mass and Energy Albert Einstein proposed that mass and energy were related in his
special theory of relativi ty. According to this theory, mass can be converted to energy and
energy can be converted to mass. The relation between mass and energy is given by this
equation:
A small amount of mass can be converted into an enormous amount of energy. For
example, if one gram of mass is converted to energy, about 100 trillion joules of energy
are released.
Nuclear Fusion
Even though nuclear fission reactions release tremendous amounts of energy, even more
energy can be released by nuclear fusion reactions. In a nuclear fusion reaction, two
nuclei with small masses combine to form a nucleus of larger mass. Nuclear fission
reactions release millions of times more energy than can be released by chemical
reactions.
Temperature and Fusion For nuclear fusion to occur, positively charged nuclei
must get close to each other. However, nuclei repel each other because they have the
same positive electric charge. If nuclei are movi ng fast, they can have enough
ki netic energy to overcome the repulsive electrical force between them and get close to
each other. Remember that the ki netic energy of atoms or molecules increases as their
temperature increases. Only at temperatures of millions of degrees Celsius are nuclei
movi ng so fast that they can get close enough for fusion to occur. These extremely high
temperatures are found in the center of stars, such as the Sun.
2.
3.
4.
6.
Atomic Stability
Why do atoms form compounds? The electric forces between electrons and protons,
which are oppositely charged, hold atoms and molecules together, and thus they are the
forces that cause compounds to form. The periodic table on the inside back cover of your
book lists the known elements. However, the six noble gases in Group 18 do not form
compounds, or do so with difficulty. Atoms of noble gases are unusually stable.
Compounds of these atoms rarely form because they are almost always less stable than
the original atoms.
Energy Levels and Other Elements How do the dot diagrams represent other
elements, and how does this relate to their ability to make compounds? Hydrogen and
helium, the elements in period 1 of the periodic table, can hold a maximum of two
electrons in their outer energy levels. Hydrogen contains one electron in its lone energy
level. A dot diagram for hydrogen has a single dot next to its symbol. This means that
hydrogen s outer energy level is not full. It is more stable when it is part of a compound.
Outer LevelsGetting Their Fill As you just learned, hydrogen is an element that
does not have a full outer energy level. How does hydrogen, or any other element,
become stable? Atoms with partially stable outer energy levels can lose, gain, or share
electrons to obtain stable outer energy levels. They do this by combining with other
atoms that also have partially complete outer energy levels. As a result, each becomes
stable. Figure 5 shows electron dot diagrams for sodium and chlorine. When they
combine, sodium loses one electron and chlorine gains one electron. You can see from
the electron dot diagram that chlorine now has a stable outer energy level, similar to a
noble gas. But what about sodium?
Stability Is Reached Sodium had only one electron in its outer energy level, which it
lost when it combined with chlorine to form sodium chloride. However, look back to the
next, outermost energy level of sodium. This is now the new outer energy level, and it is
stable with eight electrons. When the outer electron of sodium is removed, a complete
inner energy level becomes the new outer energy level. Sodium and chlorine are
stable now because of the exchange of an electron. In the compound water, each
hydrogen atom needs one electron to have a stable outer energy level. The oxygen atom
needs two electrons for its outer level to be stable with eight electrons. Hydrogen and
oxygen become stable and form bonds in a different way from sodium and chlorine.
Instead of gaining or losing electrons, they share them. Figure 6 shows how hydrogen
A Bond Forms What happens when potassium and iodine atoms collide? A neutral
atom of potassium has one electron in its outer level. This is not a stable outer energy
level. When potassium forms a compound with iodine, potassium loses one electron from
its fourth level, and the third level becomes the complete outer level. However, the atom
is no longer neutral. The potassium atom has become an ion. When a potassium atom
loses an electron, the atom becomes positively charged because there is one electron less
in the atom than there are protons in the nucleus. The 1+charge is shown as a superscript
written after the element s symbol, K + , to indicate its charge. Superscript means
written above. The iodine atom in this reaction undergoes change as well. An iodine
Sharing Electrons
Some atoms of nonmetals are unlikely to lose or gain electrons. For example, the
elements in Group 14 of the periodic table have four electrons in their outer levels. They
would have to either gain or lose four electrons to have a stable outer level.
Losing four electrons takes a great deal of energy. Each time an electron is removed, the
nucleus holds the remaining electrons even more tightly. These atoms become more
chemically stable by sharing electrons, rather than by losing or gaining electrons.
The attraction that forms between atoms when they share electrons is known as a
covalent bond. A neutral particle that forms as a result of electron sharing is called a
molecule, as shown in Figure 11.
Single Covalent Bonds A single covalent bond is made up of two shared electrons.
Usually, one of the shared electrons comes from one atom in the bond and the other
comes from the other atom in the bond. A water molecule contains two single bonds. In
each bond, a hydrogen atom contributes one electron to the bond, and the oxygen atom
contributes the other. The two electrons are shared, forming a single bond. The result of
this type of bonding is a stable outer energy level for each atom in the molecule.
Figure 12
Covalent
Compounds
and
Molecules
An atom is the
smallest particle into
which an element can
be divided and still be
the same element.
Likewise, a molecule
is the smallest particle
into which a covalently
bonded compound
can be divided and
still be the same
compound. The
models in Figure 4
show how a sample of
water is made up of many individual molecules of water. Imagine dividing water again and
again. You would finally end up with a single molecule of water. What would happen if you
separated the hydrogen and oxygen atoms that make up a water molecule? Then, you would no
longer have water.
Unequal Sharing Electrons are not always shared equally between atoms in a
covalent bond. The strength of the attraction of each atom to its electrons is related to the
size of the atom, the charge of the nucleus, and the total number of electrons the atom
contains. Part of the strength of attraction has to do with how far the electron being
shared is from the nucleus. For example, a magnet has a stronger pull when it is right
next to a piece of metal rather than several centimeters away. The other part of the
strength of attraction has to do with the size of the positive charge in the nucleus. Using a
Tug-of-War You might think of a covalent bond as the rope in a tug-of-war, and the
shared electrons as the knot in the center of the rope. Each atom in the molecule attracts
the electrons that they share. However, sometimes the atoms aren t the same size.
The same thing happens in tug-of-war. Sometimes one team has more people or stronger
participants than the other. When this is true, the knot in the middle of the rope ends up
closer to the stronger team. Similarly, the electrons being shared in a molecule are held
more closely to the atoms with the stronger pull or larger nucleus.
Properties:
Ionic Compounds
The ions that make up an ionic compound are bonded in a repeating three-dimensional pattern
called a crystal lattice. In ionic compounds such as table salt, the crystal lattice is built up so that
the positive ions are nearest to the negative ions, forming a solid. The model in Figure 5 shows
a small part of a crystal lattice. The shape of the crystals of an ionic compound depends on the
pattern of ions in its crystal lattice.
Covalent Compounds The covalent bonds between atoms in molecules are strong.
However, the attraction between indivi dual molecules is weak. It is the weak forces
between indivi dual molecules that are responsible for the properties of covalent
compounds. Melting and boiling points of covalent compounds are relatively lower when
compared to ionic compounds. Sugar will melt at approxi mately 185C, whereas table
Metallic Bonds
Think about a metal sculpture. Some metal pieces can be flattened, and others can be shaped
into wires. How could the artist change the shape of the metal into all of these different forms
without breaking the metal into pieces? Metal can be shaped because of the presence of
metallic bonds, a special kind of chemical bond. A metallic bond is a bond formed by the
attraction between positively charged metal ions and the electrons around the ions. Positively
charged metal ions form when metal atoms lose electrons.
Properties of Metals
Metallic bonding gives metals their particular properties. These properties include electrical
conductivity, malleability, and ductility.
Conducting Electric Current
Metallic bonding allows metals to conduct electric current. For example, when you turn on a
lamp, electrons move within the copper wire that connects the lamp to the outlet. The electrons
that move are the valence electrons in the copper atoms. These electrons are free to move
because the electrons are not connected to any one atom.
Reshaping Metals
Because the electrons move freely around the metal ions, the atoms in metals can be
rearranged. As a result, metals can be reshaped. The properties of ductility (the ability to be
drawn into wires) and malleability (the ability to be rolled or pounded) describe a metals ability
to be reshaped. For example, copper is made into wires for use in electrical cords. Aluminum
can be pounded into thin sheets and made into aluminum foil.
Bending Without Breaking
When a piece of metal is bent, some of the metal ions are forced closer together. You may
Ionization Energy
Q& A
Oxidation Numbers You need to know which elements are involved and what
number of electrons they lose, gain, or share to become stable. Section 1 discussed the
relationship between an element s position on the periodic table and the number of
electrons it gains or loses. Because all elements in a given group have the same number
of electrons in their outer energy levels, they must gain or lose the same number of
electrons. Metals always lose electrons and nonmetals always gain electrons when
they form ions. The charge on the ion is known as the oxidation number of the atom.
For ionic compounds, the oxi dation number is the same as the charge on the ion. For
example, a sodium ion has a charge of 1+ and an oxi dation number of 1+ . A chloride ion
has a charge of 1- and an oxi dation number of 1-.
Oxidation Numbers and the Periodic Table The numbers with positive or
negative signs in above Fig are the oxi dation numbers for the elements in the columns
below them. Notice how they fit with the periodic-table groupings. The elements in
Table 3 can have more than one oxi dation number. When naming these compounds, the
oxi dation number is expressed in the name with a roman numeral. For example,
the oxi dation number of iron in iron(III) oxi de is 3+.
Writing Formulas After you ve learned how to find the oxi dation numbers and their
least common multiple, you can write formulas for ionic compounds. Write the formula
for an ionic compound containing sodium and oxygen by using the following
rules in this order.
1. Write the symbol of the element that has the positive oxi dation number or charge.
Sodium, a Group 1 element, has an oxi dation number of 1+.
2. Write the symbol of the element with the negative number. Nonmetals other than
hydrogen have negative oxi dation numbers. Oxygen has an oxi dation number of 2-.
3. To have a neutral compound, the positive charges have to balance the negative
charges. It takes two sodium ions to balance the one oxygen ion. Thus, the formula
becomes Na2O.
Writing Equations
Consider the reaction:
Nickel(I I ) chlor ide, dissolved in water , plus sodium hydr oxide, dissolved in water ,
pr oduces solid nickel(I I ) hydr oxide plus sodium chlor ide, dissolved in water .
This series of words is rather cumbersome, but all of the information is important. The
same is true of descriptions of most chemical reactions.
Unit Managers
What do the numbers to the left of the formulas for
reactants and products mean? Remember that according
to the law of conservation of mass, matter is neither
made nor lost during chemical reactions. Atoms are
rearranged but never lost or destroyed. These numbers,
called coefficients, represent the number of units of each substance taking part in a
reaction. Coefficients can be thought of as unit managers.
Knowing the number of units of reactants enables chemists to add the correct amounts of
reactants to a reaction. Also, these units, or coefficients, tell them exactly how much
product will form. An example of this is the reaction of one unit of NiCl 2 with two units
of NaOH to produce one unit of Ni(OH)2 and two units of NaCl. You can see these units
in Figure 5.
Notice that the number of mercury atoms is the same on both sides of the equation but
that the number of oxygen atoms is not the same. One oxygen atom appears on the
reactant side of the equation and two appear on the product side.
But according to the law of conservation of mass, one oxygen atom cannot just become
two. Nor can you simply add the subscript 2 and write HgO2 instead of HgO. The
formulas HgO2 and HgO do not represent the same compound. In fact, HgO2 does not
exist. The formulas in a chemical equation must accurately represent the compounds that
react. Fixi ng this equation requires a process called balancing. Balancing an equation
doesn t change what happens in a reaction t simply changes the way the reaction is
represented. The balancing process involves changing coefficients in a reaction to
achieve a balanced chemical equation, which has the same number of atoms of each
element on both sides of the equation.
Balancing Equations Magnesium burns with such a brilliant white light that it is
often used in emergency flares. Burning leaves a white powder called magnesium
oxi de. To write a balanced chemical equation for this and most other reactions, follow
these four steps.
Step 1 Write a chemical equation for the reaction using formulas and symbols. Recall
that oxygen is a diatomic molecule.
Step 4 Recheck the numbers of each atom on each side of the equation and adjust
coefficients again if necessary. Now two Mg atoms are on the right side and only one is
on the left side. So a coefficient of 2 is needed for Mg to balance the equation.
Types of Reactions
Chemists have defined five main categories of chemical reactions: combustion, synthesis,
decomposition, single displacement, and double displacement.
Combustion Reactions If you have ever observed something burning, you have
observed a combustion reaction. A combustion r eaction occurs when a substance reacts
with oxygen to produce energy in the form of heat and light. Combustion reactions also
produce one or more products that contain the elements in the reactants. For example, the
reaction between carbon and oxygen produces carbon dioxi de.
Many combustion reactions also will fit into other categories of reactions. For example,
the reaction between carbon and oxygen also is a synthesis reaction.
Another synthesis reaction is the combination of oxygen with iron in the presence of
water to form hydrated iron(II) oxide or rust.
Activation Energy
As you learned earlier, atoms and molecules have to bump into each other before a
product can be formed. In order to form new bonds, atoms have to be close together. In
addition to being close, the reactants require a certain amount of energy in order to allow
the reaction to start. This minimum amount of energy needed to start a reaction is called
activation ener gy.
Heat Absorption When the energy needed is in the form of heat, the reaction is called
an endother mic r eaction. The term endothermic is not just related to chemical
reactions. It also can describe physical changes. The process of dissolvi ng a salt in water
is a physical change. If you ever had to soak a swollen ankl e in an Epsom salt solution,
you probably noticed that when you mixed the Epsom salt in water, the solution became
cold. The dissolvi ng of Epsom salt absorbs heat. Thus, it is a physical change that is
endothermic. Some reactions are so endothermic that they can cause water to freeze.
Exothermic
Reactions When the
energy given off in a
reaction is primarily in
the form of heat, the
reaction is called an
exother mic r eaction.
The burning of wood and
the explosion of
dynamite are exothermic
reactions. Exothermic
reactions provi de most of
the power used in homes
and industries. Fossil
fuels that contain carbon, such as coal, petroleum, and natural gas, combine with oxygen
to yield carbon dioxi de gas and energy. Unfortunately impurities in these fuels, such as
sulfur, burn as well, producing pollutants such as sulfur dioxi de. Sulfur dioxi de combines
with water in the atmosphere, producing acid rain.
Energy Release The energy diagram for an exothermic reaction is the reverse of an
endothermic reaction. With an exothermic reaction, the products have less stored energy
than the reactants. As shown in Figure 21, the reactants, carbon monoxi de (CO) and
nitrogen dioxi de (NO2) have a higher energy level than the products. The molecules have
enough energy to overcome the activation energy barrier.
What conditions control the reaction rate, and how can the rate be changed?
Temperature Energy is needed by atoms and molecules to break old bonds and to
form new ones. One way to increase the activation energy is to add heat or increase the
temperature. With an increase in temperature, atoms and molecules move faster and
ki netic energy increases. With faster moving atoms and molecules, more molecules
have ki netic energy greater than activation energy. The atoms and molecules now will
have enough energy to break old bonds at higher temperature, which will increase the
reaction rate.
Concentration When you walk through the hallways at school, you are more likely to
bump into another student if the hallways are crowded. The closer atoms and molecules
are to each other, the greater the chance of collision. The amount of substance present
in a certain volume is called its concentration. Increasing the concentration of a substance
increases the reaction rate.
Surface Area Only atoms or molecules in the outer layer of a substance can collide
with other reactants. When a substance is finely divi ded, it has a larger surface area than
when it was whole. Increasing the surface area increases the chance for collisions,
which will increase the reaction rate.
Agitation If you are maki ng lemonade, the water, sugar, and lemon juice are mixed in
order to get the product. Agitation or stirring is a physical process that allows reactants to
mix. A low stirring rate will slow the reaction due to fewer collisions. Chemical reactions
can be controlled by agitation.
Pressure Another way to influence the reaction rate is with pressure. By increasing the
pressure of gases, molecules have less room to move about and the concentration of the
reactants increases. This will boost the chance of collisions, which means the reaction
rate increases. Decreasing the pressure means fewer collisions, and lower reaction rate.
A solution in which water is the solvent is called an aqueous (A kwee us) solution.
How It Happens Molecules of sugar dissolvi ng in water are shown in Figure in the
next page. First, water molecules cluster around sugar molecules with their negative
ends attracted to the positive ends of the sugar. Then, the water molecules pull the sugar
molecules into solution. Finally, the water molecules and the sugar molecules mix
evenly, forming a solution.
The process described in Figure repeats as layer after layer of sugar molecules move
away from the crystal, until all the molecules are evenly spread out. The same three steps
occur for most solid solutes dissolvi ng in a liquid solvent.
Rate of Dissolving
When two substances form a solution, the
dissolvi ng occurs at different rates. Sometimes
the rate at which a solute dissolves into a solvent
is fast, while other times it is slow. There are
several things you can do to speed up the rate of
dissolvi ngstirring, reducing crystal size, and
increasing temperature.
Stirring How does stirring speed up the
dissolving process? Think about how you make a
drink from a powdered mix. After you add the
mix to water, you stir it. Stirring a solution
speeds up the dissolvi ng process because it
brings more fresh solvent into contact with more
solute. The fresh solvent attracts the particles
of solute, causing the solid solute to dissolve
faster.
Crystal Size Another way to speed the
dissolvi ng of a solid in a liquid is to grind large
crystals into smaller ones. Suppose you
want to use a 5-g crystal of rock candy to
sweeten your water. If you put the whole crystal into a glass of water, it might take
several minutes to dissolve, even with stirring. However, if you first grind the crystal of
rock candy into a powder, it will dissolve in the same amount of water in a few seconds.
Solubility of Gases
When you shake an opened bottle of soda, it bubbles up and may squirt out. Shaki ng or
pouring a solution of a gas in a liquid causes gas to come out of solution. Agitating the
solution exposes more gas molecules to the surface, where they escape from the liquid.
Pressure Effects What might you do if you want to dissolve more gas in a liquid?
One thing you can do is increase the pressure of that gas over the liquid. Soft drinks are
bottled under increased pressure. This increases the amount of carbon dioxi de that
dissolves in the liquid. When the pressure is released, the carbon dioxide bubbles out.
Temperature Effects Another way to increase the amount of gas that dissolves in a
liquid is to cool the liquid. This is just the opposite of what you do to increase the speed
at which most solids dissolve in a liquid. Imagine what happens to the carbon
dioxi de when a bottle of soft drink is opened. Even more carbon dioxide will bubble out
of a soft drink as it gets warmer.
Acids
Properties of Acids When an acid dissolves in water, some of the hydrogen is
released as hydrogen ions, H_. An acid is a substance that produces hydrogen ions in a
water solution. It is the ability to produce these ions that gives acids their characteristic
properties. When an acid dissolves in water, H- ions interact with water molecules to form
H3O_ ions, which are called hydronium ions.
Acids have several common properties. For one thing, all acids taste sour. The familiar,
sour taste of many foods is due to acids. However, taste never should be used to test for
the presence of acids. Some acids can damage tissue by producing painful burns. Acids
are corrosive. Some acids react strongly with certain metals, eating away the metals and
forming metallic compounds and hydrogen gas. Acids also react with indicators
Bases can be defined in two ways. Any substance that for ms hydr oxide ions, OH _, in
a water solution is a base. I n addition, a base is any substance that accepts H _ fr om
acids. The definitions ar e r elated, because the OH _ ions pr oduced by some bases
do accept H _ ions.
Dissociation of Bases Compounds that can form hydroxi de ions (OH) in water are
classified as bases. When bases that contain OH dissolve in water, the negative areas of
nearby water molecules attract the positive ion in the base. The positive areas of nearby
water molecules attract the OH of the base. The base dissociates into a positive ion and
a negative iona hydroxi de ion (OH). This process also is shown in Figure.
Neutralization Advertisements for antacids claim that these products neutralize the
excess stomach acid that causes indigestion. Normally, gastric juice is acidic. Too much
acid can produce discomfort. Antacids contain bases or other compounds containing
sodium, calcium, magnesium, or aluminum that react with acids to lower acid
concentration. What happens when you ingest an antacid tablet containing sodium
bicarbonate, NaHCO3? The acid (HCl) is neutralized by the base (NaHCO3).
Neutralization is a chemical reaction between an acid and a base that takes place in a
water solution. When HCl is neutralized by NaOH, hydronium ions from the acid
combine with hydroxi de ions from the base to produce water.
Salt Formation The acid-base equation accounts for only half of the ions in the
solution. The remaining ions react to form a salt. A salt is a compound formed when the
negative ions from an acid combine with the positive ions from a base. In the reaction
between HCl and NaOH, the salt formed in water solution is sodium chloride.
An Exception Ammonia is a base that does not contain OH. In a water solution,
dissociation takes place when the ammonia molecule attracts a hydrogen ion from a water
molecule, forming an ammonium ion (NH4+). This leaves a hydroxide ion (OH).
Ammonia (NH3) is a colourless pungent gas that is familiar to us as the smell of urine. In fact
probably no other compound can be identified by its smell and correctly named by as many
people as ammonia. It can be detected in the air at a level of only about 50-60 ppm, and at levels
of 100-200 ppm it sharply irritates the eyes and lungs. At even higher concentrations it makes the
lungs fill with fluid and can quickly cause death. Ammonia takes it name from the worshippers
of the Egyptian god Amun - the Ammonians, because they used ammonium chloride (NH4Cl) in
their rites. Ammonium chloride (also known as sal volatile) occurs naturally in cracks near
volcanoes, and when it is warmed it decomposes into the pungent ammonia.
Industrially ammonia is made by the Haber-Bosch process which converts nitrogen gas into the
air into ammonia. This process was discovered by the German chemists Fritz Haber (nobel prize
1918) and Karl Bosch, just in time for the beginning of WW1. This had important consequences
The Haber-Bosch Process - which takes place at 400-500C and about 200 atm pressure, in the
presence of an iron catalyst.
In the mid-1980s, the annual production rate for ammonia was about 16 million tons. About 25%
of this went directly for fertiliser, and the rest was used to make nitric acid (and from there into
explosives), dyes, pharmaceuticals and cleaning agents. It has a relatively high heat of
vaporisation, and so some ammonia is used as the heat-exchanger gas in large refrigeration units
(rather than the ozone-destroying CFCs). With all of these important applications, it is no
surprise that more molecules of ammonia are produced each year than any other industrial
chemical.
Hydrocarbons
Organic compounds that contain only carbon and hydrogen are hydrocarbons. These
differ from one another by the number of carbon and hydrogen atoms they contain. The
simplest hydrocarbon is methane, CH4, with only one carbon per molecule. Methane is
the main component of natural gas. The hydrocarbon octane, C8H18 , has eight carbons
per molecule and is a component of gasoline. The hydrocarbon polyethylene contains
hundreds of carbon and hydrogen atoms per molecule. Polyethylene is a plastic used to
make many items, including milk containers and plastic bags.
Hydrocarbons also differ from one another in the way the carbon atoms connect to each
other. Figure 14.2 shows the three hydrocarbons n-pentane, iso-pentane, and neo-pentane.
These hydrocarbons all have the same molecular formula, C5 H12 , but are structurally
different from one another.
M olecules such as n-pentane, iso-pentane, and neo-pentane, which have the same
molecular for mula but differ ent str uctur es, ar e known as str uctur al isomer s.
Structural isomers have different physical and chemical properties. For example, n-
pentane has a boiling point of 36C, iso-pentane's boiling point is 30C, and neo-
pentane's is l0C. The number of possible structural isomers for a chemical formula
increases rapidly as the number of carbon atoms increases.
There are three structural isomers for compounds havi ng the formula C5 H12, 18
for C8H18 , 75 for C10H22, and a whopping 366,319 for C20 H42.
The hydrocarbons we use are obtained primarily from coal and petroleum. These fossil
fuels are both formed from the remains of organisms that decayed under water in the
absence of oxygen millions of years ago. Coal is a solid material containing many large,
complex hydrocarbon molecules. Most of the coal mined today is used for the production
of steel and for generating electricity at coal-burning power plants. Petroleum, or "cr ude
oil," is a liquid readily separated into its hydrocarbon components through a process
known as fr actional distillation, shown in Figure 14.3. Distillation is a method of
separating mixtures often used in chemistry. During distillation, a liquid is boiled to
produce a vapor that is then condensed again to a liquid. Fractional distillation refers
specifically to the distillation of petroleum.
Petroleum is heated in a pipe still to a temperature high enough to vaporize most of the
components. The hot vapor flows into the bottom of a fractionating towel; which is
warmer at the bottom than at the top. As the vapor rises in the tower and cools, the
various components begin to condense. Hydrocarbons that have high boiling points, such
as tar and lubricating stocks, condense first at warmer temperatures. Hydrocarbons that
have low boiling points, such as gasoline, travel to the cooler regions at the top of the
tower before condensing. Pipes drain the various liquid hydrocarbon fractions from the
tower. Natural gas, which is primarily methane, does not condense. It remains a gas and
is collected at the top of the tower.
Other Uses for Petroleum Not all of the products obtained from petroleum are
burned to produce energy. About 15 percent of the petroleum-based substances that are
used in the United States go toward nonfuel uses. Look around at the materials in
your home or classroom. Do you see any plastics? In addition to fuels, plastics and
synthetic fabrics are made from the hydrocarbons found in crude petroleum. Also,
lubricants such as grease and motor oil, as well as the asphalt used in surfacing roads, are
obtained from petroleum.
Natural Gas
The chemical processes that produce petroleum as ancient organisms decay also produce
gaseous compounds called natural gas. These compounds rise to the top of the petroleum
deposit and are trapped there. Natural gas is composed mostly of methane, CH4, but it
also contains other hydrocarbon gases such as propane, C3H8, and butane, C4H10.Natural
gas is burned to provi de energy for cooki ng, heating, and manufacturing. About one
fourth of the energy consumed in the United States comes from burning natural
gas. There s a good chance that your home has a stove, furnace, hot-water heater, or
clothes drier that uses natural gas. Natural gas contains more energy per ki logram than
petroleum or coal does. It also burns more cleanly than other fossil fuels, produces fewer
pollutants, and leaves no residue such as ash.
Coal
Coal is a solid fossil fuel that is found in mines underground. In the first half of the
twentieth century, most houses in the United States were heated by burning coal. In fact,
during this time, coal provi ded more than half of the energy that was used in the United
States. Now, almost two-thirds of the energy used comes from petroleum and natural gas,
and only about one-fourth comes from coal. About 90 percent of all the coal that is used
in the United States is burned by power plants to generate electricity.
Origin of Coal Coal mines were once the sites of ancient swamps. Coal formed from
the organic material that was deposited as the plants that lived in these swamps died.
Worldwide, the amount of coal that is potentially available is estimated to be 20 to 40
times greater than the supply of petroleum. Coal also is a complex mixture of
hydrocarbons and other chemical compounds. Compared to petroleum and natural gas,
coal contains more impurities, such as sulfur and nitrogen compounds. As a result, more
pollutants, such as sulfur dioxi de and nitrogen oxi des, are produced when coal is burned.
General Science and Environment Page 135
Generating Electricity
How is the chemical energy contained in fossil fuels converted to electrical energy in an
electric power station?
The process is shown in Figure 8. In the first stage, fuel is burned in a boiler or
combustion chamber, and it releases thermal energy. In the second stage, this thermal
energy heats water and produces steam under high pressure. In the third stage, the steam
strikes the blades of a turbine, causing it to spin. The shaft of the turbine is connected to
an electric generator. In the fourth stage, electric current is produced when the spinning
turbine shaft rotates magnets inside the generator. In the final stage, the electric current is
transmitted to homes, schools, and businesses through power lines.
Polymers
Polymers are exceedingly long molecules that consist of repeating molecular units called
monomers, as Figure 14.21 illustrates. Monomers have relatively simple structures
consisting of anywhere from 4 to 100 atoms per molecule. When chained together, they
can form polymers consisting of hundreds of thousands of atoms per molecule. These
large molecules are still too small to be seen with the unaided eye. They are, however,
giants in the world of the submicroscopic-if a typical polymer molecule were as thick as a
ki te string, it would be 1 ki lometer long.
Many of the molecules that make up livi ng organisms are polymers, including DNA,
proteins, the cellulose of plants, and the complex carbohydrates of starchy foods. For
now, we focus on the human-made polymers, also known as synthetic polymers, that
make up the class of materials commonly known as plastics.
We begin by exploring the two major types of synthetic polymers used today-addition
polymers and condensation polymers.
Addition polymers form simply by the joining together of monomer units. For this to
happen, each monomer must contain at least one double bond. As shown in Figure 14.22,
polymerization occurs when two of the electrons from each double bond split away from
each other to form new covalent bonds with neighboring monomer molecules. During
this process, no atoms are lost, meaning that the total mass of the polymer is equal to the
sum of the masses of all the monomers.
Nearly 12 million tons of polyethylene are produced annually in the United States; that's
about 90 pounds per U.S. citizen. The monomer from which it is synthesized, ethylene, is
an unsaturated hydrocarbon produced in large quantities from petroleum.
The addition polymer polyvinylidene chloride (trade name Saran), shown in Figure
14.24, is used as plastic wrap for food.
Condensation Polymers
A condensation polymer forms when the joining of monomer units is accompanied by the
loss of a small molecule, such as water or hydrochloric acid. Any monomer capable of
becoming part of a condensation polymer must have a functional group on each end.
When two such monomers come together to form a condensation polymer, one functional
group of the first monomer links up with one functional group of the other monomer. The
result is a two-monomer unit that has two terminal functional groups, one from each of
the two original monomers. Each of these terminal functional groups in the two-monomer
unit is now free to link up with one of the functional groups of a third monomer, and then
a fourth, and so on. In this way a polymer chain is built.
Figure 14.26 shows this process for the condensation polymer called nylon, created in
1937 by DuPont chemist Wallace Carothers (1896-1937). Because this polymer is
composed of two different monomers, it is classified as a copolymer. One monomer is
adipic acid, which contains two reactive end groups, both carboxyl groups. The second
monomer is hexamethylenediamine, in which two amine groups are the reactive end
groups. One end of an adipic acid molecule and one end of a hexamethylamine molecule
can be made to react with each other, splitting off a water molecule in the process. After
twO monomers have joined, reactive ends still remain for further reactions, which leads
to a growing polymer chain. Aside from its use in hosiery, nylon also finds great use in
the manufacture of ropes, parachutes, clothing, and carpets.
Ecosystems
Although humans are primarily land dwellers, the Earth s surface is largely water. World s
oceans make up 99% of the planet s biosphere and contain the greatest diversity of life. Even the
most biologically rich tropical rain forests cannot match the biodiversity (measured by the
number of species) found in a coral reef community (Coral reefs are underwater structures
made from calcium carbonate secreted by corals).Rain forests, deserts, coral reefs, grasslands,
and a rotting log are all examples of ecosystems.
An ecosystem is a complex community of plants, animals, and micr oor ganisms linked by
ener gy and nutr ient flows that inter act with each other and their envir onment.
Biosphere
The part of the Earth system that directly supports life, including the oceans, atmosphere, land,
and soil, is the biosphere. All the Earth s plants and animals live in this layer, which is measured
from the ocean floor to the top of the atmosphere. All livi ng things, large and small, are grouped
into species,
or separate types. The main compounds that make up the biosphere contain carbon, hydrogen,
and oxygen. These elements interact with other Earth systems.
The vertical range that contains the biosphere is roughly 20,000 meters high. The section most
populated with livi ng species is only a fraction of that. It includes a section measured from just
below the ocean s surface to about 1,000 meters above it. Most livi ng plants and animals live in
this narrow layer of the biosphere. Fig. 2-1 gives an idea of the depth of the biosphere.
Hydrosphere
The global ocean, the Earth s most noticeable feature from space, makes up the largest single
part of the planet s total covering. The Pacific Ocean, the largest ocean, is so big that the land
mass of all the continents could fit into it. The combined water of all of the oceans makes up
nearly 97% of the earth s water. These oceans are much deeper on average than the land is high,
and make up what is known as the hydrosphere.
The hydr ospher e descr ibes the ever -changing total water cycle that is par t of the closed
envir onment of the ear th.
Nitrogen, along with these other three, makes proteins. Phosphorus is the energy elementit
occurs in compounds called ATP and ADP, important in the transfer and use of energy within
cells.
Other macronutrients also play specific roles. Calcium, for example, is the structure element,
occurring in bones and teeth of vertebrates, shells of shellfish, and wood-forming cell walls of
vegetation. Sodium and potassium are important to nerve-signal transmission. Many of the
metals required by living things are necessary for specific enzymes. (An enzyme is a complex
organic compound that acts as a catalystit causes or speeds up chemical reactions, such as
digestion.)
For any form of life to persist, chemical elements must be available at the right times, in the right
amounts, and in the right concentrations. When this does not happen, a chemical can become a
limiting factor, preventing the growth of an individual, a population, or a species, or
even causing its local extinction.
A biogeochemical cycle is the complete path a chemical takes through the four major
components, or reservoirs, of Earths system: atmosphere, hydrosphere (oceans, rivers, lakes,
groundwaters, and glaciers), lithosphere (rocks and soils), and biosphere (plants and animals).
A biogeochemical cycle is chemical because it is chemicals that are cycled, bio- because the
cycle involves life, and geo- because a cycle may include atmosphere, water, rocks, and soils.
The tectonic cycle involves the creation and destruction of Earths solid outer layer, the
lithosphere. The lithosphere is about 100 km (60 mi) thick on average and is broken into several
large segments called plates, which are moving relative to one another (Figure 6.11). The slow
Plate tectonics has important environmental effects. Moving plates change the location and size
of continents, altering atmospheric and ocean circulation and thereby altering climate. Plate
movement has also created ecological islands by breaking up continental areas. When this
happens, closely related life-forms are isolated from one another for millions of years, leading
to the evolution of new species. Finally, boundaries between plates are geologically active
areas, and most volcanic activity and earthquakes occur there. Earthquakes occur when the
brittle upper lithosphere fractures along faults (fractures in rock within the Earths crust).
Movement of several meters between plates can occur within a few seconds or minutes, in
contrast to the slow, deeper plate movement described above.
Three types of plate boundaries occur: divergent, convergent, and transform faults.
Even the world s total amount of rainfall is incredibly large. To give you an idea of the volume of
water we are talki ng about, think of this: If all the rain that falls on the Earth in one year fell on the
A water r eser voir is a place in the atmospher e, ocean, or under gr ound, wher e water is stor ed
for some per iod of time.
Water is constantly circulating between the atmosphere and the Earth and back to the atmosphere
through a cycle involving condensation, precipitation, evaporation, and transpiration. This is called
the hydrologic cycle. Fig. 5-1 illustrates the many ways water is transported through the hydrologic
cycle.
Water vapor is carried by wind and air currents throughout the atmosphere. When an air mass cools
down, its vapor condenses into clouds and eventually falls to the ground as precipitation in the form
of snow, rain, sleet, or hail.
Water takes one route from the atmosphere to the ground, but can take a variety of paths and time
periods to get back up into the atmosphere. These paths include the following:
Absorption by plants;
Evaporation from the sun s heating;
Storage in the upper levels of soil;
Storage as groundwater deep in the earth;
Storage in glaciers and polar regions;
Storage or transport in springs, streams, rivers, lakes; and
As the air gets wetter and wetter (saturated), water droplets accumulating within the cloud get bigger
and bigger. When these droplets get too heavy, gravity wins and they fall as precipitation.
After rain hits the ground, it can evaporate quickly, be absorbed (by the land or the sea), or run off
into storm sewers, streams, or rivers. Even though the hydrologic cycle balances what goes up with
what comes down, one part of the cycle gets stuck in polar regions during the wintertime.
In cold climates, rain is stored as snow or ice on the ground for several months. In glacial areas, the
time period can extend from years to thousands of years. Then, as the temperature climbs in the
spring, the water is released. When this happens in a very short period of time, flooding occurs.
Nitrogen Cycle
Nitrogen (N2) makes up 79% of the atmosphere. All life, like proteins, requires nitrogen compounds
to survive. However, they can t generally use nitrogen in the gaseous form.
To be used by an organism, nitrogen must be combined with hydrogen and oxygen. Nitrogen is taken
out of the atmosphere by lightning or nitrogen-fixi ng bacteria. During storms, large amounts of
nitrogen are oxi dized by lightning and mixed with water (rain). This falls and is converted into
nitrates. Plants take up nitrates to form proteins. Plants are consumed by herbivores(Herbivores are
organisms that are anatomically and physiologically adapted to eat plant-based foods) or
carnivores(meaning 'meat eater' (Latin carne meaning 'flesh' and vorare meaning 'to devour'), is an
organism that derives its energy and nutrient requirements from a diet consisting mainly or exclusively
of animal tissue). When these die (organic matter), the nitrogen compounds are broken down into
ammonia. Ammonia can be taken up by plants again, dissolved by water, or remain in the soil to be
converted to nitrates (nitrification). Nitrates stored in soil can end up in rivers and lakes through
runoff. They can also be changed into free nitrogen and returned to the atmosphere. Fig. gives you an
idea of the nitrogen cycle.
The transport of carbon takes place in the atmosphere, biosphere, oceans, and landmasses. All of
carbon s different lives are described by the carbon cycle. The carbon cycle has many different
storage spots, also known as reservoirs or sinks, where carbon exchanges take place. The carbon
cycle is shown in Fig. 11-3. The global carbon cycle is divided into two types, the geological carbon
cycle, which has been going on for millions of years, and the biological carbon cycle, which stretches
from days to thousands of years.
Carbon dioxide in the atmosphere reacts with water and minerals to form calcium carbonate. Calcium
carbonate rock (limestone) is dissolved by rainwater through erosion and carried to the oceans.
There, it settles out of the ocean water, forming sedimentary layers on the sea floor. Then, through
plate tectonics, these sediments are subducted underneath the continents. With the ext reme heat and
pressure deep beneath the Earth s surface, the limestone melts and reacts with other minerals, freeing
carbon dioxi de. This carbon jumps back into the carbon cycle, returning to the atmosphere as carbon
dioxi de during volcanic eruptions.
We ve seen how photosynthesis and respiration play a big part in the long term geological cycling of
carbon. Land plants pull carbon dioxide from the atmosphere. In the oceans, the calcium carbonate
shells of dead phytoplankton sink to the sea bed and form sediments. When photosynthesis is higher
than respiration, organic matter gradually builds over millions of years and forms coal and oil
deposits. These biologically regulated activities characterize atmospheric carbon dioxi de removal and
the storage of carbon in geologic sediments.
Atmosphere
Next to the ground we walk on, the atmosphere is the easiest to identify. The atmosphere also
provides the air (oxygen) we breathe. Humans can survive for about 28 days without food and 3 days
without waterbut only three to four minutes without air. For this reason, it is the single most
important resource we have. All other environmental concerns must tie into the preservation
of our atmosphere.
Atmospheric variables include temperature, pressure, and water vapor. The gradients and interactions
of these variables and how they change over time are also important.
A meteor ologist is a per son who
studies the weather and its
atmospher ic patter ns.
Composition
The atmospheric gases blanketing the
Earth exist in a mixture. This mixture is
made up (by volume) of about 79%
nitrogen, 20% oxygen, 0.036% carbon
dioxi de, and trace amounts of other
gases.
TROPOSPHERE
The lowest of the atmospheric layers, the troposphere, extends from the earth s surface up to about
14 km in altitude. Virtually all human activities occur in the troposphere. Mt. Everest, the tallest
mountain on the planet, is only about 9 km high.
Nitrogen and oxygen make up the majority of the Earth s gases, even in the higher altitudes. But it s
the atmospheric level closest to the Earth where everything is perfect to support life. At this level,
living organisms are protected from harmful cosmic radiation showers that constantly assault the
earth s atmosphere.
This active layer is called the troposphere. If you have ever survived a hurricane or tornado, you
know that the troposphere is an active place. It is the atmospheric layer where all the weather we
experience takes place. Rising and falling temperatures, as well as circulating masses of air, keep
things lively. Air pressure also adds to the mix.
The warmest portions of the troposphere are found at the lowest altitudes. This is because the earth s
surface absorbs the sun s heat and radiates it back into the atmosphere. Commonly, temperature
decreases as altitude increases
STRATOSPHERE
Above the troposphere is the stratosphere, where air flow is mostly sideways There is a gradual
change from the troposphere to the stratosphere, which starts at around 14 km in altitude. The
stratosphere extends from 14 km to around 50 km. Most commercial aircraft travel takes place in the
lower part of the stratosphere. Military aircraft travel at much higher altitudes: Some classified
stealth aircraft are thought to graze the boundary of the mesosphere and beyond.
NASA s Space Shuttle generally travels to altitudes between 160 and 500 km.
Although the temperature in the lower stratosphere is cold and constant, hovering around at 57C,
there are strong winds in this layer that are part of specific circulation patterns. Extremely high and
wispy clouds can form in the lower stratosphere. In general, there are no major weather formations
that take place regularly in the stratosphere.
Ozone
Ozone is one of our atmospheric bodyguards. Even small amounts have an important role in
protecting planetary life. Concentrated in a thin layer in the upper stratosphere, atmospheric ozone is
an exceptionally reactive form of oxygen. It is found in the stratospheric layer, around 15 to 30 km
above the Earth s surface. The ozone layer is largely responsible for absorbing most of the sun s
ultraviolet (UV) radiation. Most importantly, it absorbs the fraction of ultraviolet light called UVB.
Ultraviolet radiation is a bad, bad thing! It causes breaks in the body s nuclear proteins, leaving the
door open for cancers and other health issues to get a foothold. UVB has been connected with many
serious health problems, like different ki nds of ski n cancer and cataracts. It is also harmful to certain
crops, materials, and marine organisms
Ozone is much less widespread than normal oxygen. The formation of the ozone layer is a tricky
matter. Out of every 10 million air molecules, about 2 million are normal oxygen and only three are
ozone molecules. Instead of two atoms of oxygen like normal oxygen molecules (O2), ozone (O3)
Ozone Depletion
For the past 50 years, chlorofluorocarbons (CFCs) held the answer to lots of material problems. They
were stable, nonflammable, not too toxic, and cheap to produce. They had a variety of uses including
applications as refrigerants, solvents, and foam-blowing agents.
Chlorine has been used for everything from disinfecting water to serving as solvents (methyl
chloroform and carbon tetrachloride) in chemistry labs.
Unfortunately, these compounds are not so good for the atmosphere. They don t just break down and
disappear. They hang around. This lingering characteristic allows them to be carried by winds into
the stratosphere. The net effect is to destroy ozone faster than it is naturally created. Roughly 84% of
stratospheric chlorine comes from manmade sources, while only 16% comes from natural
sources.
Unfortunately, CFCs break down only by exposure to strong UV radiation. When that happens, CFCs
release chlorine. Scientists have found that one atom of chlorine can destroy over 100,000 ozone
molecules. As CFCs decay, they release chlorine and damage the ozone layer.
In 1985, since chlorine compounds were still being used, the policy of the Vienna Convention was
adopted to gather international cooperation and reduce the number of all CFCs by half. It s important
to remember that just because CFCs were banned doesn t mean that long-lived chemicals will
disappear immediately from the atmosphere. Until CFCs degrade to negligible levels, the annual
South Polar ozone hole will keep appearing for many years to come. The annual hole or thinning
of the ozone layer over Antarctica was first noticed in 1985.
In 1992, with new information on the ever-shrinki ng ozone layer, developed countries decided to
totally stop production of halons by 1994 and CFCs by 1996. Halons are compounds in which
hydrogen atoms of a hydrocarbon are replaced by bromine or fluorine. The halons are used as fire-
extinguishing agents, both in built-in systems and in handheld fire extinguishers.
Halons cause ozone depletion because they contain bromine, which is a lot stronger than CFCs in
destroying ozone. Halons are also very stable and break down slowly once formed.
This course of action turned out to be what turned the tide in falling ozone levels. Levels of inorganic
chlorine in the atmosphere stopped increasing in 19971998, and stratospheric chlorine levels peaked
and are no longer rising. If nothing happens to change this trend, natural ozone recovery should mend
the ozone layer in about 50 years.
MESOSPHERE
Above the stratosphere is the mesosphere, a middle layer separating the lower stratosphere from the
inhospitable thermosphere. Extending from 80 to 90 km and with temperatures around 101C, the
mesosphere is the intermediary of the earth s atmosphere layers.
THERMOSPHERE
The changeover from the mesosphere to the thermosphere layer begins at a height of approxi mately
80 km. The thermosphere is named because of the return to rising temperatures that can reach an
amazing 1,982C.
The earth s atmosphere surrounds our planet like a blanket. It protects us from harmful cosmic
radiation, regulates temperature and humidity, and controls the weather. The atmosphere is critical to
life on this planet and provides the air we breathe.
Greenhouse gases are a natural part of the atmosphere. They trap the sun s warmth, and preserve the
earth s surface temperature at a median level needed to support life. Atmospheric greenhouse gases
act like the glass windows of a greenhouse. Sunlight enters the Earth s atmosphere, passing through
greenhouse gases that act like a lens. Then, as it reaches the Earth s surface, the land, water, and
biosphere absorb the sun s energy. Once absorbed, this energy gets recycled into the atmosphere. A
portion of the heat is reflected into space, but a lot of it stays locked in the atmosphere by greenhouse
gases, causing the Earth to heat.
The gr eenhouse effect descr ibes how atmospher ic gases pr event heat fr om being r eleased back
into space, allowing it to build up in the Ear th s atmospher e.
The more gases there are, the more the Earth heats
up. The greenhouse effect is important. Without it,
the Earth would not be warm enough for most
living things to survive. However, if the
greenhouse effect gets too strong, it can make the
Earth warmer than normal. The problem is that
even a little more heat (a few degrees higher)
creates problems for people, plants, and animals.
Greenhouse Gases
We know that the earth is surrounded by a mixture
of gases. The Earth s atmosphere consists of
roughly 79.1% nitrogen, 20.9% oxygen, 0.03%
carbon dioxi de, and trace amounts of other gases.
Greenhouse gases are a natural part of the
atmosphere. Greenhouse gases include water
vapor, carbon dioxi de, methane, nitrous oxi de,
halogenated fluorocarbons, ozone, perfluorinated
CARBON DIOXIDE
Carbon dioxide (CO2) is a natural greenhouse gas and also the biggest human supplied gas to the
greenhouse effect (about 70%). A heavy, colorless gas, carbon dioxi de is the main gas we exhale
during breathing. It dissolves in water to form carbonic acid, is formed in animal respiration, and
comes from the decay or combustion of plant/animal matter. Carbon dioxi de is absorbed from the air
by plants in photosynthesis and is also used to carbonate drinks.
NITROGEN OXIDES
The colorless gas known as nitrous oxi de is an atmospheric pollutant produced by combustion. It is
also one of the greenhouse gases. There are several ways that nitrogen and oxygen team up in the
atmosphere, including nitrogen dioxide, nitric oxide, and nitrous oxide. Nitrogen oxi des are stable
Nitrogen combines with moisture in the atmosphere to form nitric acid. This comes down as rain and
acidifies lakes and soils, ki lling fish, and small animal populations and damaging forests. Acid
particulates are also precipitated, along with the leaching of heavy metals, into water supplies.
Nitrous oxi de is also used in dentistry to put patients to sleep during dental procedures and is
sometimes called laughing gas. The amount of nitrous oxi de in the atmosphere is about 15% higher
now than it was in the 1800s.
At high altitudes, nitrogen oxi des are responsible for some ozone depletion. When ozone is thin or
gone in places, the amount of solar ultraviolet radiation that reaches the ground is increased. This
causes plant damage and injury to animals and humans in the form of ski n cancers and other
problems. As a greenhouse gas, nitrogen oxi des trap heat much more efficiently than
carbon dioxi de.
METHANE
Another greenhouse gas, methane, is a colorless, odorless, flammable hydrocarbon that is released by
the breakdown of organic matter and the carbonization of coal. This gas is the second biggest
additive, after carbon dioxide, to the greenhouse effect at around 20%.
Methane is the main component of natural gas, which is found in deposits, like oil, in the earth s
crust. Methane is a byproduct of the production, transportation, and use of natural gas. Underwater
decaying plants create methane known as marsh or swamp gas.
One of the best known sources of methane in rural populations is that of belching (Belching (also
known as burping, ructus, or eructation) involves the release of gas from the digestive tract (mainly
esophagus and stomach) through the mouth.) farm animals. Cows have complicated digestive
systems, and release large amounts of methane in satisfying belches. It sounds funny, but when you
consider herds of hundreds of animals, it adds up!
The amount of methane in the atmosphere is about 145% higher now than it was in the 1800s. The
major causes of this increase are thought to include:
Digestive gases of sheep and cattle
Growth and cultivation of rice
Geologic release of natural gas
Decomposition of garbage and landfill waste
HALOCARBONS
As we learned earlier, halocarbons levels dropped since being banned in the 1990s. The phasing out
of chlorofluorocarbons has removed a lot of the ozone threat and is allowing the protective ozone
layer to recover.
Climate Change
Climate change includes temperature increases (global warming), rise in sealevels, rainfall pattern
changes, and increased incidence of ext reme weather events. Scientific data discussed at the 2002
AIR POLLUTION
The WHO defines air pollution as the presence of materials in the air in such concentration which are harmful to
man and his environment. A number of ingredients find their way in the air and these are mostly gases, which
rapidly spread over wide areas.
SOURCES OF AIR POLLUTION
Various sources of air pollution are fossil fuels, industries, agricultural activities, wars, natural causes arid emissions
from vehicles.
Effect on Plants
(i ) SO2 causes chlorosis and also results in the death of cells and tissues.
(ii ) Fluorides and PAN damage leafy vegetables such as lettuce and spinach.
(iii ) Oxides of nitrogen and fluorides reduce crop yield.
(iv) Smog bleaches and blaze foliage of important leafy plants.
(v) Hydrocarbons cause premature yellowing, fall of leave and flower buds, discoloration and curling of sepals and
petals.
(vi ) Smoke and dust cover the leaf surface and reduce photosynthetic capacity of plants.
(vii ) Ozone damages cereals, fruits, and cotton crop.
Effect on Man
The effect of pollutants on animals and man are as follows-
(i ) Ozone causes dryness of mucous membranes, changes eye vision, causes headache, pulmonary congestion and
oedema.
(ii ) Ozone has been reported to produce chromosomal aberrations.
(iii ) SO2 causes drying of mouth, scratchy throat, smarting eyes and disorders of respiratory tract.
(iv) SO3, CO and NO2 diffuse into blood stream and reduce oxygen transport. CO damages cardiovascular system.
Hydrocarbons and other pollutants act, as carcinogens and lead to different cancers.
(v) Cotton dust leads to respiratory disorders e.g. bronchitis and asthma.
(vi ) Smoking of tobacco causes cancerous growth in lungs.
Aesthetic Loss
Dust and smoke spoils the beauty of nature. Especially the mountain environments, which serve as a great attraction
for tourists. Foul odours emitted by industries, automobiles, dirty drains and garbage heaps in cities are a great
nuisance.
Radiation
The radiations from the atomic blasts cause several health hazards. The radiations carry high energy and remove
electrons from atoms and attach them to other atoms producing positive and negative ion pairs. Hence, they are
known as ionizing radiations. The ionization property of these radiations proves to be highly injurious to the
protoplasm. The ionizing radiations of ecological concern are classified as follows:
Corpuscular Radiations
These consist of streams of atomic or subatomic particles, which transfer their energy to the matter they strike.
(i) Alpha particles
These particles are large and travel few centimeters in the air. These cause large amount of local ionization.
(ii) Beta particles
These are small particles characterized by having high velocities. They can travel a few meters in space. These are
capable of entering into the tissues for few centimeters. Since alpha and beta particles have low penetration power
they can produce harmful effects only when absorbed, ingested or deposited in or near living tissues.
(iii) Electromagnetic radiations
Electromagnetic radiations include waves of shorter wavelengths. These are capable of traveling long distances and
can readily penetrate the living tissue. These include gamma rays. These can penetrate and produce effect even
without being taken inside.
Other Types of Radiations
Besides radioactive radiations, some other radiations are also present in the atmosphere.
(i) Neutrons
These are large uncharged particles, which do not cause radiation by themselves, but
they produce radioactivity in non-radioactive materials through which they pass.
(ii) X-rays
These are electromagnetic waves very similar to gamma rays, but originate from the
outer electron shell of radioactive substances, which are not dispersed in nature.
(iii) Cosmic rays
These are radiations from the outer space, which contain alpha and beta particles
together with gamma rays.
Sources of Radiations
The radiations are produced from the radioactive elements, which are known as radionuclides or radioactive
isotopes, e.g. Uranium. Radium, Thorium, and Carbon-14. These contribute to background radiation. But isotopes of
certain metabolically important elements like Carbon-14, Cobalt-60, Calcium 45, Iodine-131, Phosphorus-32, etc.
are not ecologically harmful but are used as tracers. The third category of radionuclides comprises of fission
products of uranium and certain other elements. These are cesium, strontium, and plutonium etc.
Biological Effects of Radiation
The effects of radiation have revealed that acute doses are found to be deleterious and may kill the organisms,
whereas the increase in radiation in biological environment leads to different kinds of mutations. The effects of
RADIOACTIVE WASTES
Land, water, and air can be affected by radioactive contamination. Depending on the wind or water
flow, radioactive levels remain in place or are spread over a wide region. Radioactive wastes from
uranium mining, production of energy (land-based power plants and nuclear submarines), or
weapons development (missiles) are hot environmental issues. Public concern wants responsible
longterm storage of radioactive wastes until they are safe.
Radioactive elements eventually decay or break down to form harmless materials, but these elements
have very different decay rates. A few radioactive elements decay in a matter of hours or days, but
there are some elements that take thousands of years to decay.
Radioactive decay is referred to in half-life periods; the time it takes for onehalf of an element s
original mass to decay and become harmless.
Responsible waste processing facilities handle nonhazardous waste as carefully as hazardous waste.
Nonhazardous waste arrives at facilities in a variety of containers including fiber and plastic drums,
original packaging, bags, and shrink-wrapped or steel-strapped pallets, along with steel drums, cubic-
yard boxes, railcars, tank trucks, roll-off boxes, and dump trailers.
Disposal methods depend on the waste type, but commonly include incineration, sludge-dewatering,
wastewater treatment, waste-to-energy, secure landfill, and others.
Making a Difference
Sometimes it seems like the buildup of hazardous waste is beyond our individual efforts. However,
by demanding responsible environmental processing, treatment, and storage, individuals can have a
positive impact.
There are plenty of things we can do about nonhazardous environmental problems. These fall into the
larger category of reuse and recycling.
As individuals, we can buy recycled paper products so that original wood fibers are used again and
again. The same thing can be done with recycled glass and plastics. And it s easy! Many cities have
recycling programs that allow people to recycle right at their door or driveway.
Ink cartridges from computer printers and electronics parts can be recycled.
Used oil from vehicles, paints, and other products can be taken to approved recycling and disposal
sites.
Drive time, peak hour, freeway, take-away delivery, drive through....the introduction of the
automobile has had a huge impact on our lifestyle and environment.
Cars may get us from A to B (and sometimes even C and D) with a minimum of fuss, but they
also cause lots of pollution.
Yes, that's right. In major cities and large towns throughout the world, motor vehicles cause a
wide range of air pollution problems.
Cars!
Fossil fuel combustion, particularly as it occurs in motor vehicles, has been identified as the
LARGEST contributor to air pollution in the WORLD.
In Melbourne, motor vehicles cause most of the air pollution, except during cooler months when
wood fires contribute significantly.
Not all pollution produced by cars is the same. In fact, there are two types of pollution
discharged by petrol vehicles.
1. Exhaust emissions: including dangerous gases such as carbon monoxide, oxides of nitrogen,
hydrocarbons and particulates.
2. Evaporative emissions: vapours of fuel which are released into the atmosphere, without being
burnt.
Smoky vehicles
Under Victorian guidelines, a car is only considered smoky if it emits visible smoke from its
exhaust pipe for a continuous period of more than 10 seconds.
Your car is not classified as smoky if the exhaust emissions are caused by heat or the
condensation of water vapour, which can occur when the car has just been started, particularly on
cold days.
Smoky cars contribute far more to air pollution than well maintained cars. Anyone who has
driven behind or walked near a smoky car will know, smoky car exhausts are very offensive as
well as posing a risk to public health.
In certain circumstances, even well maintained vehicles can sometimes produce smoke from
their exhaust. This can occur during heavy acceleration, climbing steep hills and as engine turbos
and supercharges are building sufficient speed to provide enough air to burn fuel properly.
These chemicals can cause mild to severe irritation to the eyes, nose, throat and lungs. They can
also be absorbed into the body and cause deterioration in general health. The extent of these
detrimental effects on people's health is related to the length of time one is exposed to vehicle
emissions, the concentration of fumes breathed and various other factors such as age and health.
For example, an EPA study into the affects of air pollution found a link between high levels of
fine particles, ozone, nitrogen dioxide and carbon monoxide and an increase in the number of
hospital admissions for respiratory and cardiovascular disease (EPA Publication 789).
There are many reasons why a vehicle might emit continuous smoke:
Remember, this list is just a guide and might not be relevant to both diesel and petrol cars.
Car use is increasing every year, however, Victoria's air quality has actually been improving
because of tighter controls on car emissions.
Hybrid vehicles are now available which get their energy from batteries or petrol. These cars are
still uncommon, but they are pointing the way to a future with cars contributing less to air
pollution.
The battle isn't over! People will need to use their cars responsibly and keep them in tip top
condition so we can continue to improve matters and ensure we have nice clean air.
Population Density is population size in relation to some unit of space and time. It varies with food availability and
climatic conditions. It can be measured as:
Population Age Distr ibution refers to the individuals of different age groups in a population. The natality and
mortality is also different for respective ages. Bodenhelmer (1938) recognized three ecological ages as: (i ) Pre
reproductive, (ii ) Reproductive and (iii ) Post reproductive Fig. 1. Duration of these ages varies in different
organisms e.g. Insects have a very long pre-reproductive period, a very short reproductive period but no
post reproductive period at all. In man all the three stages are equal in length.