Alexander Yurchuk Owner, Institute geophysics and problems of the
Earth
Applications of nuclear magnetic resonance for oil gas prospecting and
exploration gives unique results. Company Halliburton and Schlumberger used NMR in logging surveys in the wells (only to a distance of 20-30 meters). We use NMR properties from ground surface (without drilling) and see the hydrocarbons directly to a depth of 5 km and possibly deeper. This is our big advantage over the Schlumberger and Halliburton. Our technology provides a direct detection of hydrocarbons and shows the effectiveness of exploratory surveys to 98% and significantly exceeds the aeromagnetic and aerogravity and seismic surveys. (These surveys provide the anomalies). Our technology is based on effect of Nuclear Magnetic Resonance (NMR, in medicine is called MRI), http://en.wikipedia.org/wiki/Nuclear_magnetic_resonance Video of NMR, look: http://www.youtube.com/watch?v=7aRKAXD4dAg Kirlian effect, http://en.wikipedia.org/wiki/Kirlian_photography Kirlian effect is widely used around the world to visualize the images invisible to the eye, is what we use when a transfer the image from the infrared range to the visible eye image. And the property of radio waves at terahertz range, THz (1012 - 1015 Hz) http://en.wikipedia.org/wiki/Terahertz_radiation Terahertz range of radio waves used in airports to detect explosives in passengers baggage and passengers inside at distance of tens of meters. MRI sees the human body through (no matter how body was- thick or thin), and NMR in geophysics allows technology to see to great depth. Nuclear magnetic resonance From Wikipedia, the free encyclopedia
Nuclear magnetic resonance (NMR) is a physical phenomenon in which nuclei
in a magnetic field absorb and re-emit electromagnetic radiation. This energy is at a specific resonance frequency which depends on the strength of the magnetic field and the magnetic properties of the isotope of the atoms;
In practical applications, the frequency is similar to VHF and UHF television
broadcasts (601000 MHz). NMR allows the observation of specific quantum mechanical magnetic properties of the atomic nucleus. Many scientific techniques exploit NMR phenomena to study molecular physics, crystals, and non-crystalline materials through NMR spectroscopy. NMR is also routinely used in advanced medical imaging techniques, such as in magnetic resonance imaging (MRI). All isotopes that contain an odd number of protons and/or of neutrons (see Isotope) have an intrinsic magnetic moment and angular momentum, in other words a nonzero spin, while all nuclides with even numbers of both have a total spin of zero. The most commonly studied nuclei are 1H and 13C, although nuclei from isotopes of many other elements (e.g. 2H, 6Li, 10B, 11B, 14N, 15N, 17O, 19F, 23Na, 29Si, 31P, 35Cl, 113Cd, 129Xe, 195Pt) have been studied by high- field NMR spectroscopy as well. A key feature of NMR is that the resonance frequency of a particular substance is directly proportional to the strength of the applied magnetic field. It is this feature that is exploited in imaging techniques; if a sample is placed in a non-uniform magnetic field then the resonance frequencies of the sample's nuclei depend on where in the field they are located. Since the resolution of the imaging technique depends on the magnitude of magnetic field gradient, many efforts are made to develop increased field strength, often using superconductors. The effectiveness of NMR can also be improved using hyperpolarization, and/or using two-dimensional, three-dimensional and higher- dimensional multi-frequency techniques. The principle of NMR usually involves two sequential steps: The alignment (polarization) of the magnetic nuclear spins in an applied, constant magnetic field H0. The perturbation of this alignment of the nuclear spins by employing an electro- magnetic, usually radio frequency (RF) pulse. The required perturbing frequency is dependent upon the static magnetic field (H0) and the nuclei of observation. The two fields are usually chosen to be perpendicular to each other as this maximizes the NMR signal strength. The resulting response by the total magnetization (M) of the nuclear spins is the phenomenon that is exploited in NMR spectroscopy and magnetic resonance imaging. Both use intense applied magnetic fields (H0) in order to achieve dispersion and very high stability to deliver spectral resolution, the details of which are described by chemical shifts, the Zeeman effect, and Knight shifts (in metals). NMR phenomena are also utilized in low-field NMR, NMR spectroscopy and MRI in the Earth's magnetic field (referred to as Earth's field NMR), and in several types of magnetometers. Data acquisition in the petroleum industry
Main article: NMR in porous media
Another use for nuclear magnetic resonance is data acquisition in the petroleum industry for petroleum and natural gas exploration and recovery. A borehole is drilled into rock and sedimentary strata into which nuclear magnetic resonance logging equipment is lowered.
Nuclear magnetic resonance analysis of these boreholes is used to measure rock
porosity, estimate permeability from pore size distribution and identify pore fluids (water, oil and gas). These instruments are typically low field NMR spectrometers. Low field NMR spans a range of different nuclear magnetic resonance (NMR) modalities, going from NMR conducted in permanent magnets, supporting magnetic fields of a few T, all the way down to zero field NMR, where the Earth's field is carefully shielded such that magnetic fields of nT are achieved where nuclear spin precession is close to zero. In a broad sense, "Low-field NMR" is the branch of nuclear magnetic resonance that is NOT conducted in superconducting high-field magnets. Low field NMR also includes Earth's field NMR where simply the Earth's field is exploited to cause nuclear spin-precession which is detected. With magnetic fields on the order of T and below magnetometers such as SQUIDs or atomic magnetometers (among others) are used as detectors. "Normal" high field NMR relies on the detection of spin-precession with inductive detection with a simple coil. However, this detection modality becomes less sensitive as the magnetic field and the associated frequencies decrease. Hence the push toward alternative detection methods at very low fields. When a sample is placed in a constant magnetic field and stimulated (perturbed) by a pulsed or alternating magnetic field, NMR active nuclei resonate at characteristic frequencies. Examples of such nuclei are the isotopes carbon-13, and hydrogen-1 also referred to as protons. The resonant frequency of each isotope is directly proportional to the strength of the applied magnetic field, and the magnetogyric or gyromagnetic ratio of that isotope. The signal strength is proportional both to the stimulating magnetic field and the number of nuclei of that isotope in the sample. Thus in the 21 tesla magnetic field that may be found in high resolution laboratory NMR spectrometers, protons resonate at 900 MHz. However in the Earth's magnetic field the same nuclei resonate at audio frequencies of around 2 kHz and generate very weak signals. The location of a nucleus within a complex molecule affects the 'chemical environment' (i.e. the rotating magnetic fields generated by the other nuclei) experienced by the nucleus. Thus different hydrocarbon molecules containing NMR active nuclei in different positions within the molecules produce slightly different patterns of resonant frequencies. EFNMR signals can be affected by both magnetically noisy laboratory environments and natural variations in the Earth's field, which originally compromised its usefulness. However this disadvantage has been overcome by the introduction of electronic equipment which compensates changes in ambient magnetic fields. Whereas chemical shifts are important in NMR, they are insignificant in the Earth's field. The absence of chemical shifts causes features such as spin-spin multiplets (that are separated by high fields) to be superimposed in EFNMR. Instead, EFNMR spectra are dominated by spin-spin coupling (J-coupling) effects. Software optimised for analysing these spectra can provide useful information about the structure of the molecules in the sample.