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Designation: G 113 05

Standard Terminology
Relating to Natural and Artificial Weathering Tests of
Nonmetallic Materials1
This standard is issued under the fixed designation G 113; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.

1. Scope 3. Significance and Use


1.1 This terminology standard covers terms that relate to the 3.1 This terminology is not intended to supersede the
durability testing of Nonmetallic Materials using natural and requirements of similar definitions in certain other documents,
artificial weathering exposure techniques. but is intended to provide a listing of terms that are in current
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1.2 It is the intent of this terminology standard to include widespread usage, and their context in relation to weathering.
those weathering terms in wide use in ASTM for which
standard definitions appear desirable. 4. Terminology
4.1 Definitions:
2. Referenced Documents
accelerated outdoor weathering , noutdoor weathering
2.1 ASTM Standards:
using the sun as the source of irradiance, and where the rate
D 9 Terminology Relating to Wood
of deterioration is accelerated over that of the in-service
E 41 Terminology Relating to Conditioning
exposure position increasing one or more of the influencing
E 284 Terminology of Appearance
parameters.
E 349 Definitions of Terms Relating to Space Simulation
acceleration factor, nthe ratio of exposure time required to
E 456 Terminology Relating to Quality and Statistics
produce a specified amount of change in a material by one
E 772 Terminology Relating to Solar Energy Conversion
exposure test divided by the exposure time required to
E 973M Practice for the Determination of the Spectral
produce the same change by another exposure test.
Mismatch Parameter between a Photovoltaic Device and a
Photovoltaic Reference Cell [Metric] DISCUSSIONAcceleration factors must be used with great caution
G 84 Practice for Measurement of Time-of-Wetness on because they vary between materials (including different formulations
Surfaces Exposed to Wetting Conditions as in Atmospheric of the same material) and are strongly dependent on the exposure
conditions and variability of both the natural and laboratory accelerated
Corrosion Testing
exposures. Acceleration factors may also vary depending on the level of
G 90 Practice for Performing Accelerated Outdoor Weath- material property change used to determine the acceleration factor. Do
ering of Nonmetallic Materials Using Concentrated Natu- not ratio irradiance in laboratory accelerated tests to irradiance in
ral Sunlight outdoor exposures, or use equivalent radiant exposures to estimate time
2.2 AATCC Method:2 to fail in outdoor exposures. These calculations ignore differences in
16 Colorfastness to Light temperature and moisture between the accelerated test and exterior
2.3 ANSI Standards:3 exposures, and in the spectral power distributions of the laboratory light
source and sunlight.
ANSI/NCSL Z540-2-1997 American National Standard for
Expressing UncertaintyU.S. Guide to the Expression of actinic radiation, nthe spectral region(s) of a light source
Uncertainty in Measurement responsible for the photodegradation of a particular material.
ambient temperature, nthe existing temperature of the air
or of an object in thermal equilibrium with the surrounding
1
This terminology is under the jurisdiction of ASTM Committee G03 on atmosphere.
Weathering and Durability and is the direct responsibility of Subcommittee G03.92
on Terminology. azimuth angle, nan angle of a plane to the horizon mea-
Current edition approved August 15, 2005. Published September 2005. Origi- sured clockwise to the object.
nally approved in 1992. Last previous edition approved in 2003 as G 113 03.
2
backed exposure, na technique of weathering in which the
Available from American Association of Textile Chemists and Colorists, P.O.
Box 12215, Research Triangle Park, NC 27709.
test specimens being exposed are mounted onto a solid
3
Available from National Conference of Standards Laboratories, 1800 30th St., backing material, of sufficient strength to hold the specimen.
Suite 305B, Boulder, CO 80301. When the specimen and the backing are in direct contact the

Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.

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G 113 05
backing material must be of a type that will not contaminate sunlight. It refers to the full spectrum of solar irradiance,
the specimen. When two materials are intimately joined that is, ultraviolet through infrared, and includes both diffuse
together to form one composite, the materials below the top sky and direct solar irradiance.
surface are not considered as a backing. DISCUSSIONThis definition differs from CIE (Commission Interna-
DISCUSSIONThe backing is typically plywood which has the effect tionale de lEclairage) Publication No 17.4 which defines daylight as
of increasing specimen temperature and wet time during exposure, the visible par of global (sun plus sky) radiation.
compared to exposure unbacked.
direct weathering, , na technique of weathering in which
black box, na thin metal box painted flat black on the the test specimens are exposed to all prevailing elements of
outside only exclusive of the bottom surface with an open the atmosphere.
top where the flat test specimens to be exposed constitute the dry-bulb temperature, , nthe temperature of the ambient
top surface of the box; the box is equipped with mounting air; for example, the temperature that is measured by the
strips to hold the test specimens firmly in place; the top dry-bulb thermometer of a psychrometer. D 4023
surface of the box must be completely filled at all times; any durability, , nin weathering, a measure of the retention of
blank spaces on the top surface must be occupied by flat original condition and function of a material after exposure
black dummy panels to maintain correct operating condi- to a specified set of conditions.
tion. enclosed carbon arc, , na light source in which an arc is
black box under glass, na glass covered enclosure or produced across a pair of carbon rods by a high energy
cabinet of any convenient size. It shall be constructed of electrical source, such that a high intensity light is emitted.
corrosion resistant metal and be enclosed to prevent ambient The carbons are enclosed in an inverted glass dome which
air from circulating over the samples. Exterior non-glass acts to prolong the life of the carbons, and to modify the
surfaces shall be painted black. The interior shall remain spectral power distribution received by the specimens.
unpainted. exposure, , nthe act of subjecting the test specimen to the
black panel thermometer, na temperature measuring de- test conditions.
vice consisting of a metal panel, having a black coating exposure angle , nthe tilt from horizontal of the test
which absorbs all wavelengths uniformly, with a thermal specimen or any other exposed material, or both.
sensitive element firmly attached to the center of the exposed fading unit (AATCC) , na specific amount of exposure
surface. The black panel thermometer is used to control an made under the conditions specified in various test methods
artificial weathering device and to provide an estimate of the where one Fading Unit is one-twentieth (120 th) of the
maximum temperature of samples exposed to a radiant exposure required to produce a color change equal to Step
energy source. No. 4 on the Gray Scale for Color Change or 1.7 6 0.3
climatological types, nmajor regions of significantly differ- CIELAB units of color difference on Blue Wool Lightfast-
ent recurring weather patterns. In weathering, several dis- ness Standard L 4 or 20 6 1.7 CIELAB units of color
tinct climatological types are used to evaluate the atmo- difference on the Xenon Reference Fabric or combination
spheric durability of materials. Within any single thereof.
climatological variation, at a specific geographic location, AATCC Technical Manual
short term weather patterns may fluctuate significantly. This file specimen, nportion of the material to be tested which is
may cause variability in short term exposures. Major cli- stored under conditions in which it is stable, and is used for
matic variations that are used for the study of weathering are: comparison between exposed and original state.
warm, moist climatesubtropical climate distinguished as fluorescent ultraviolet lamp, va lamp in which the irradi-
warm and humid year round, with frequent rain showers. ance from a low pressure mercury arc is transformed to a
hot, dry climatedesert climate distinguished as sunny, hot, longer wavelength UV radiation by a phosphor; the spectral
and dry year round, with rare scattered showers. power distribution of a fluorescent lamp is determined by the
control, nin weathering, the term control has three current emission spectrum of the mercury arc light source, the
widespread uses: emission spectrum of the phosphor and the UV transmittance
1. A material which is of similar composition and construc- of the glass tube.
tion to the test material used for comparison, exposed at the fresnel-reflector system, nflat mirrors arranged in an array
same time. such that they reflect onto a target, the illuminated area of
DISCUSSIONA reference material can often be used as the control. which simulates the size and shape of the flat mirror. Such an
2. A portion of the material to be tested which is stored under array simulates the ray-tracing of a parabolic trough of the
conditions in which it is stable, and is used for comparison between same aperture angle. G 90
exposed and original state. gray scale, nthe scale consists of nine pairs of standard gray
DISCUSSIONThis definition is deprecated in favor of File Speci- chips each pair representing a difference in color or contrast
men. (shade and strength) corresponding to a numerical fastness
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3. A portion of the exposed specimen which is protected from light rating. The results of colorfastness tests are rated by visually
exposure by masking.
comparing the difference in color represented by the scale.
DISCUSSIONThis definition is deprecated in favor of Masked
Area.
AATCC Technical Manual
irradiance, nthe radiant power per unit area incident on a
daylight , nas used in weathering, the term equivalent to receiver, typically reported in watts per square metre, W m2

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G 113 05
E 973 DISCUSSIONWhere sample is used as a term for the item to be
masked area, na portion of the exposed specimen which is exposed, the term is deprecated in favor of specimen.
protected from light exposure by masking. (See also con- solar azimuth angle, nthe angular distance measured clock-
trol.) wise from due north to the projection of the beam radiation
DISCUSSIONThe mask area is not protected from heat and moisture. on the horizontal plane (see Fig. 1).
solar irradiance, nas related to natural weathering of
natural weathering, noutdoor exposure of materials to
materials, the irradiance of the sun incident on the earths
unconcentrated sunlight, the purpose of which is to assess
surface, having wavelengths between about 295 nm and
the effects of environmental factors on various functional
4050 nm (4.05 microns). E 772
and decorative parameters of interest.
open flame sunshine carbon arc, na light source in which solar irradiance, global E5(2p), nsolar irradiance received
an arc is produced across a pair of copper coated carbon rods on an upward facing horizontal surface directly transmitted
filled with rare earth elements intended to produce a specific from the solid angle of the suns disk or scattered in
spectral power distribution. The carbons are open to the traversing the atmosphere, measured in watts per square
atmosphere and may be surrounded by a glass lantern metre.
arrangement which acts to modify the spectral power distri- solar irradiance, infraredas related to natural weathering
bution received by the specimens. of materials, terrestrial solar irradiance for which the wave-
operational control point, na set point for equilibrium lengths are longer than those for visible irradiance and
conditions measured at sensor location(s) in an exposure shorter than about 4.05 microns.
device. DISCUSSIONThe limits of the spectral range of infrared radiation are
operational control point tolerance, nthe permissible de- not well defined and may vary according to the user. Committee E-2.1.2
viation from the operational control point including permit- of the CIE distinguishes in the spectral range between 780 nm and 1
ted random deviation during equilibrium conditions in an mm into IR-A, IR-B, and IR-C as shown below.
exposure device. IR-A 780 to 14 m
IR-B 1.4 to 3 m
DISCUSSIONIt is assumed, as with all measurements, that the IR-C 3 m to 1 mm
measurement of tolerance has uncertainty of measurement.
solar irradiance, ultraviolet, nas related to natural weath-
operational uniformity, nthe range around the operational ering of materials, terrestrial solar irradiance for which the
control point for measured parameters within the intended wavelengths are shorter than those for visible irradiance and
exposure area within the limits of intended operational longer than about 295 nm.
range.
DISCUSSIONThe upper limit is not well defined because it is
DISCUSSIONIt is assumed, as with all measurements, that the dependent on eye sensitivity. It has been identified as either 380 nm or
measurement of uniformity has uncertainty of measurement. 400 nm.CIE Committee E-2.1.2 of the CIE divides the spectral range
between 280 and 400 nm into UV-A and UV-B as shown below.
photodegradation, nphotochemically induced changes in
UV-A 315 to 400 nm
the condition of the material. UV-B 280 to 315 nm
pyranometer, na radiometer used to measure the total solar
radiant energy incident upon a surface per unit time per area. solar irradiance, visible, nthe portion of solar radiation
This energy includes the direct radiant energy, diffuse radiant capable of causing a visual sensation.
energy, and reflected radiant energy from the background. DISCUSSIONThe limits of the spectral range of visible radiation are
E 772 not well defined and may vary according to the user. The shorter limit
pyrheliometer, na radiometer used to measure the direct or is generally taken between 380 and 400 nm and the longer limit
beam solar irradiance incident on a surface normal to the between 760 and 780 nm (1 nanometre, nm = 109 m).
suns rays. E 772
solarization, vchange in transmittance, reflectance, or ab-
radiant exposure, ntime integral of irradiance, typically
sorptance property of a material, such as glass, as a result of
reported in joules per square metre, J m2 E 772
exposure to sunlight or other light sources.
radiometer, na general class of instruments designed to
detect and measure radiant energy. spectral power distribution, nthe absolute or relative
reference material, na material with known performance. radiant power emitted by a source, or incident upon a
reference specimen, na portion of the reference material receiver as a function of wavelength.
that is to be exposed. standard weathering reference material (SWRM), na
relative humidity, nthe ratio of the actual pressure of Weathering Reference Material (WRM) whose well docu-
existing water vapor to the maximum possible (saturation) mented weathering degradation properties have been certi-
pressure of water vapor in the atmosphere at the same fied by a recognized standards agency or group and which
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temperature, expressed as a percentage. E 41 are identical when exposed to identical test conditions.
sample, na group of units or portion of material, taken from sunlight , nas used in weathering, the term equivalent to
a larger collection of units or quantity of material, which daylight. It refers to the full spectrum of solar irradiancew,
serves to provide information that can be used as a basis for that is, ultraviolet through infrared, and includes both diffuse
action on the larger quantity. sky and direct solar irradiance.

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G 113 05

FIG. 1 Solar Azimuth Angle and Surface Azimuth Angle

DISCUSSIONThis definition differs from CIE (Commission Interna- under specified geometric and spectral conditions, expressed
tionale de lEclairage) Publication No. 17.4, which defines sunlight as either as a percentage or a decimal fraction.
the visible part of direct solar irradiance. transmittance, spectral, nthe transmittance as a function of
surface azimuth angle, nThe angular distance measured wavelength.
clockwise from due north of a projection of a normal to the unbacked exposure, na technique of weathering in which
surface on the horizontal plane (see Fig. 1). the test specimens are exposed such that the portion of the
specimen being evaluated is open to the effects of the
DISCUSSION For greatest acceleration of outdoor weathering results,
weather on all sides.
the difference between the solar azimuth angle and surface azimuth
angle should be minimized. uncertainty (of measurement), nparameter, associated with
the result of a measurement, that characterizes the dispersion
test specimen, na specific portion of the samples upon of the values that could be reasonably attributed to the
which the testing is to be performed. measurand.
tilt angle, vthe angle between the horizontal and the plane of
DISCUSSION(1) The parameter may be, for example, a standard
the test fixture, glass frame, or sensory instrumentation.
deviation (or a given multiple of it), or the half-width of an interval
time-of-wetness, nthe total amount of time that a surface is having a stated confidence level. (2) Uncertainty of measurement
wet. This is typically reported in hours. comprises, in general, many components. Some of these components
DISCUSSIONAt this time, the sensing element described in Practice may be evaluated from statistical distribution of the results of series of
G 84 is the only recognized device for the measurement of time-of- measurements and can be characterized by experimental standard
wetness. deviations. The other components, which can also be characterized by
standard deviations, are evaluated from assumed probability distribu-
total solar ultraviolet, adjsolar energy above the solar cut tions based on experience or other information. (3) It is understood that
on and below the visible, when received after transmittance the result of the measurement is the best estimate of the value of the
through the atmosphere. measurand, and that all components of uncertainty, including those
arising from systematic effects, such as components associated with
DISCUSSIONThe total UV radiometer commonly used has a sensi- corrections and reference standards, contribute to the dispersion.
tive range of 290 to 385 nm. GUM 2.2.3
transmittance, nthe ratio of transmitted flux to incident flux weathering behind glass, va technique of weathering in

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G 113 05
which the test specimens are exposed in a glass covered wet-bulb temperature, nthe equilibrium temperature of a
frame constructed of wood, metal, or other satisfactory liquid vaporising into a gas. With water and air, wet-bulb and
material which protects the specimen from the effects of rain dry-bulb temperatures can be used to calculate the relative
and weather. The frame shall be open at the back or sides to humidity. D9
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allow ambient air to circulate over the specimens. xenon arc, nan excited state xenon-plasma that emits UV,
weathering reference material (WRM), na reference ma- visible, and IR radiation and is producd by passing a high
terial having well documented and repeatable degradation intensity electric current through a quartz tube containing
properties when exposed to identical test conditions.
xenon gas.
DISCUSSIONA WRM is used to monitor exposures in order to
establish consistency among tests run under nominally the same DISCUSSIONFor accelerated weathering, the spectral power distri-
conditions. Some WRMs, for example, blue wool, are also used to bution of the xenon-arc is typically modified by specific types of filters
define periods of exposure. A WRM is not used for performance in order to simulate terrestrial solar radiation or solar radiation
comparison with the test material. A control material is used for the transmitted through window or automotive glass.
latter purpose.

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