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such as Quartz and Tourmaline; they called At temperatures below the Curie tempera-
Pb
this phenomenon the piezoelectric effect. ture, the lattice structure of the PZT crystalli-
Ti, Zr Later they noticed that electrical fields can tes becomes deformed and asymmetric. This
deform piezoelectric materials. This effect is brings about the formation of dipoles and the
Fig. 1. called the inverse piezoelectric effect. The rhombohedral and tetragonal crystallite
(1) Unit cell with symmetrical, industrial breakthrough came with piezo- phases which are of interest for piezo
cubic Perovskite structure, electric ceramics, when scientists discovered technology. The ceramic exhibits spontane-
T >TC
that Barium Titanate assumes piezoelectric ous polarization (see Fig. 1). Above the Curie
(2) Tetragonally distorted unit
cell, T < TC characteristics on a useful scale when an temperature the piezoceramic material loses
electric field is applied. its piezoelectric properties.
W W W. P I C E R A M I C . C O M