Sie sind auf Seite 1von 9

Tap ch Khoa hoc Trng ai hoc C n Th Phn A: Khoa hc T nhin, Cng ngh v Mi trng: 39 (2015): 57-65

TI CH NHA POLYETHYLENE TEREPHTHALATE (PET)


V NG DNG NHA QUA TI CH

Vn Phm an Thy1, Trng H Phng n1 v Nguyn Thanh Vit1


1
Khoa Cng ngh, Trng i hc Cn Th

ABSTRACT
Thng tin chung:
Ngy nhn: 16/04/2015 PET is one of the common types of materials which are widely used in many
Ngy chp nhn: 17/08/2015 fields with a significant growth rate. With a wide range of uses, PET almost
replaces the traditional materials such as wood, ceramic, and glass.
Title: However, due to the increasing assumption of PET and its short life cycle,
Recyclying polyethylene the amount of PET waste thrown into the environment is very large every
terephthalate (PET) and its year. Therefore, recycling or re-use of PET waste is essential to prevent
applications environmental pollution and reduce the natural resources exploration. Study
on PET recycling methods and applications of recycled PET is a matter of
T kha: concern today.
Polyethylene terephthalate
TM TT
(PET), ti ch, ng dng
Polyethylene terephthalate (PET) l mt trong nhng loi vt liu ph bin
Keywords: c ng dng rng ri trong nhiu lnh vc vi tc tng rt nhanh. Vi
Polyethylene terephthalate phm vi s dng rng, PET hu nh dn thay th cc loi vt dng truyn
(PET), recycle, applications thng khc nh g, s, thy tinh... V mc tiu th nha PET ngy cng
nhiu, vng i s dng tng i ngn nn hng nm lng rc thi t
nha PET thi ra mi trng l rt ln. Do vy, vic ng dng cng ngh
ti ch hoc ti s dng nha PET ph thi l ht sc cn thit, gp phn
ngn nga nhim mi trng, ng thi hn ch kh nng khai thc
ngun ti nguyn. Vic tm hiu cc phng php ti ch PET cng nh kh
nng, phm vi ng dng PET ti ch l vn cn quan tm nht hin nay.

1 GII THIU c lm ngui. Trong qu trnh tc ng nhit ca


n ch thay i tnh cht vt l khng c phn ng
Nha (hay cn gi l cht do hoc polymer) l
ha hc xy ra. Vi c tnh m nha nhit do
cc hp cht cao phn t v cha cc n v ti lp
c kh nng ti sinh nhiu ln, chnh v vy m
trong sut chiu di mch, c dng lm vt liu
nhng ph phm pht sinh trong qu trnh sn xut
sn xut nhiu loi vt dng trong i sng
hoc tiu dng u c kh nng ti ch c.
hng ngy cho n nhng sn phm cng nghip.
1.1 Khi nim ti ch
Nha ph thi l sn phm, vt liu nha b loi
ra trong sn xut hoc tiu dng. Mt s loi nha Ti ch l hot ng thu hi li t cht thi cc
ph thi c th lm nguyn liu ngnh ti ch l thnh phn c th s dng ch bin thnh nhng
nha nhit do nh PET, PE, PP, PS... sn phm mi s dng li cho cc hot ng sinh
hot v sn xut (Hong Anh, 2006). C hai qu
Nha nhit do l nhm vt liu Polymer c trnh ti ch chnh l ti ch vt liu bao gm cc
kh nng lp li nhiu ln qu trnh chy mm di hot ng thu gom vt liu c th ti ch t rc
tc dng nhit v tr nn ng rn (nh hnh) khi thi, x l v s dng vt liu ny sn xut cc

57
Tap ch Khoa hoc Trng ai hoc C n Th Phn A: Khoa hc T nhin, Cng ngh v Mi trng: 39 (2015): 57-65

sn phm mi v thu hi nhit bao gm cc hat 1.2.2 Tnh cht ca PET


ng sn xut nng lng t rc thi nha.
PET l mt polyeste mch thng, c nh
1.2 Khi nim nha PET hng ln do c kt cu cht ch, kh b thy
Polyethylene terephtalate (c gi l PET, phn, bn c hc cao, c kh nng chu lc x, chu
PETE hoc PETP hoc PET-P) l nha nhit do mi mn cao, tng i cng rt t gin khi b tc
thuc h polyester c hnh thnh t cc acid ng ca ngoi lc. Khi chy to ngn la mu
trung gian terepthalic (TPA) v ethylene glycol vng v tip tc chy khi cch ly khi ngn la.
(EG). PET c dng trong tng hp x si, vt bn ko ca mng PET tng ng mng nhm
ng ung, thc n v cc loi cht lng. Ngoi v gp ba ln mng polycarbonate v mng
ra, c th dng lm v cng bc vt dng nhm to polyamide. nhit thng n l polyme v
thnh mt mng chng thm kh v m rt tt. nh hnh c nh hng cao, trong sut, nhng
nhit gn 80C th xut hin kt tinh m c.
O O PET c ha tan rt b trong dung mi hu
c v hon ton khng thm nc, thm kh rt
C O CH2 CH2 O C thp. PET kh bn nhit, cu trc ha hc ca
mch PET vn cha b bin i 200 C, tuy nhin
nhit khong 70C c th lm bin dng co rt
terephthalate ester ethylene ester mng PET. Bn ha hc (c HF), H3PO4,
CH3COOH, axit bo... khng bn vi HNO3 v
Hnh 1: Cng thc cu to ca polyethylene H2SO4 m c (do tc dng vi gc este).
terephtalate 1.3 Gii thiu PET ti ch
1.2.1 Cu trc phn t v hnh thi hc PET ti ch l sn phm ca qu trnh sn xut
hoc ch to t nha PET qua s dng. PET sau
Cc c tnh ca PET c quyt nh bi qu khi s dng c thu gom phn loi cc c s ti
trnh x l nhit, n c th tn ti c hai dng: v sinh, lm sch ri ng thnh kin hay ct nh
nh hnh (Amorphous); kt tinh (Crystalline) v thnh dng vy (Das et al., 2007). Thng thng
bn kt tinh (Semi-crystalline). c rt t thng tin v tnh cht ca PET ti ch (R-
PET), do sn phm sau ti ch thng kh xc nh
c tnh cht cng nh thnh phn ca vt liu
1.4 So snh PET nguyn sinh v PET ti ch
So vi PET nguyn sinh, tnh cht ca PET ti
ch thp hn v khi lng phn t trung bnh,
nht, nhit nng chy cng nh dn di.
Nhng khng v th m PET ti ch thiu th
Hnh 2: Cu trc ca PET trng tiu th. PET sau khi ti ch c ng dng
N.S. Murthy et al., 1991 rng ri trong i sng nh s dng thi chai mi,
thng cha, si thm, mng nha (Upasani, et al.,
dng v nh hnh (amorphous), cc phn t 2012) v trong xy dng PET c ng dng
ca PET sp xp khng c trt t, khng theo mt sn xut nha ng v b tng hn hp (Awaja,
quy lut no, hnh thi ngoi quan l trong sut. et al., 2005). Bn cnh , vi cc thnh phn v
dng kt tinh (crystalline), cc phn t sp nguyn liu, nng lng v gi thnh ht nha
xp theo mt trt t nht nh. Ngoi quan c cng nh u ra sn phm tng i thp hn so
(khng trong sut). Tnh chu nhit v bn cao vi PET nguyn sinh. Nhng vic tiu hao t nng
hn so vi dng v nh hnh. Cu trc kt tinh lng cng nh hn ch lu lng kh thi NO2,
c hnh thnh bng hai c ch: Dng nhit hoc SO2, bi, dioxin v cc kh c khc (Ali, et al.,
nh hng bng cch ko c hc. 2005) ra mi trng cho thy gii quyt c vn
lo ngi ca ton cu v c ngha thc tin i
Dng bn kt tinh (Semi-Crystalline). Ngoi vi cc hot ng sn xut ca ngnh nha gip
quan c (khng trong sut), Cu trc tinh th c gim thiu cht thi t chai nha PET, bo v mi
50% kt tinh (crystalline). trng, mang li li ch kinh t cho ngnh nha v
gim chi ph chn lp tit kim nng lng.

58
Tap ch Khoa hoc Trng ai hoc C n Th Phn A: Khoa hc T nhin, Cng ngh v Mi trng: 39 (2015): 57-65

Bng 1: So snh PET nguyn sinh v PET ti ch


TT Tnh cht PET nguyn sinh PET ti ch
1 Khi lng phn t trung bnh Mw (g/mol) 3.2x104 4.2x104 2.9x104 3.8x104
2 nht (dl/g) 0.74 -0.8 0.61 0.69
3 Nhit nng chy Tm (C) 245 250 226 240
4 dn di >200 <10
5 Nguyn liu-Nng lng Tiu tn nhiu Tiu tn t
6 Gi thnh ht nha(VN/tn) 27- 28 triu 13-24 triu
7 Phm vi ng dng Dng cho cc mt hng cao cp Dng cho cc mt hng th cp
2 TNG QUAN TNH HNH NGHIN ti, xy dng, thy sn v bu chnh vin thng.
CU V TI CH PET Tuy nhin, n vn khng p ng c nhu cu s
dng ngy cng cao ca con ngi, do ti ch
Th gii
PET l hng i ang thc s thu ht cc nh
Trong nhng nm gn y, s lng chai nha nghin cu. V vy, vn gii quyt rc thi
PET ti ch tng gp i, chim 30% tng lng nha t chai PET thc s cn thit v mang li
chai PET c tiu th trn th gii. Cc quc gia hiu qu kinh t bi c th tit kim chi ph x l
c nn kinh t pht trin xy dng mt chin rc thi nha.
lc qun l cht thi rn. Trong , chnh sch thu 2.1 Cc phng php ti ch PET
hi v ti sinh cht thi nha ng vai tr tt yu
trong ton b h thng. Hin nay, th gii ang Hin nay, c nhiu phng php khc nhau
phi i mt vi nhiu kh khn nh kinh t ang x l PET thi nh chn lp, ti s dng li hoc
trong thi k suy thoi, mi trng b nhim ti ch. Do hu ht nha PET khng th t phn
nng n, cc ngun ti nguyn ngy cng cn kit, hu sinh hc, khi x l bng cch t hoc chn
c bit l ti nguyn c ngun gc t du m. lp s gy nhim mi trng, thoi ho t, pht
Chnh v vy, gp phn hn ch nhim mi sinh cc kh c hi gy nh hng n sc kho
trng v bo tn ngun ti nguyn ha thch ang con ngi. Do , ti ch PET l phng php kh
ngy cng cn kit, th vn ti ch PET c thi nht cho vic x l PET thi. c bit, y cn
cc nc quan tm t rt lu, nhiu cng trnh l ngun nguyn liu u vo gi r cho mt s
nghin cu v ti ch PET v ang c thc ngnh sn xut khc.
hin nh x l PET bng kim (Wang, et al.), ti Cc phng php ti ch PET chnh l phng
ch PET bng phng php ha hc nh ng php c hc v phng php ho hc. Vi phng
phn, methanol phn, thy phn (Dutta and Soni, php c hc, n thun l thu gom, ra sch, bm
2013) ti ch ha hc PET thnh si ng dng nh, sy kh, ti gia cng. Tuy nhin, nhc im
trong ngnh cng nghip dt (Upasani, et al., ca phng php ny l ht nha ti ch c cht
2012). Nhn chung, trn th gii cng ngh ti ch lng thp, khng xc nh c thnh phn v
PET lin tc i mi theo thi gian. hm lng tp cht nn PET sau ti ch c nht
Vit Nam rt thp. Do , ti ch ho hc ngy cng tr nn
hiu qu x l PET thi (Dutta and Soni, 2013).
Vit Nam, vic nghin cu ti ch PET
2.1.1 Ti ch bng phng php ha hc
c ch trng t lu. c cc ti nghin cu
c bn, cc chng trnh khoa hc cng ngh cp Phng php ti ch ha hc, cn c gi l
Nh nc v ti ch nha truyn thng thu hi ti ch monomer, l phng php phn hy cc
v bo tn sn phm c ngun gc t du m. Hin polyme v a chng tr v cc thnh phn ban
nay, nhiu nh khoa hc n lc nghin cu u (hydrocacbon) sao cho c th s dng lm
nhm tm ra phng php hiu qu v kinh t nht nhin liu hoc nguyn liu cho phn ng polymer
ti ch PET thi. Mt s cng trnh nghin cu ha. Phng php ha hc khng ch to ra ngun
v ti ch PET c cng b nh phn ng ct nguyn liu c tnh cht ging PET ban u m
mch PET bng dietylen glycol (V Th Hai v cn to ra nhng nguyn liu mi c th ng dng
Hong Ngc Cng, 2008), ch to ph gia chng vo cc lnh vc sn xut, nghin cu khc. Ti ch
chy t nha PET thi (Hong Th ng Qu, et bng phng php ha hc c nhng u im nh
al., 2012), nhiu d n cng xy dng thnh cng hiu sut thu hi cao, sn phm khng b gim cp
cng ngh ti ch nha PET ph thi thnh nha sau qu trnh ti ch, thnh phn n nh. Tuy
polyester khng no ch to vt liu composite nhin, phng php ny cn hn ch do s dng
ng dng trong nhiu lnh vc nh: giao thng vn nhiu dung mi dn n tng gi thnh sn phm.

59
Tap ch Khoa hoc Trng ai hoc C n Th Phn A: Khoa hc T nhin, Cng ngh v Mi trng: 39 (2015): 57-65

Phng php ha hc c chia lm 3 loi: Thy phn (hydrolysis), ru phn (methanolysis) v


glycol phn (glycolysis) (Dutta, Soni, 2014).

Hydrolysis Methanolysis Glycolysis

Terephthalic acid Dimetyl Teraphtalat (Bis(2-hydroxyetyl)


(TPA) (DMT) terephtalat
(BHET)

Hnh 3: Cc phng php ti ch ha hc


Thy phn (hydrolysis): Trong phn ng thu khit tng ng vi tinh khit TPA c trn
phn nha PET c th dng xc tc axit v c hoc th trng. Vi phng php ny, phn ng xy ra
kim. Sn phm ca phn ng l terephthalic acid chm, cn nhiu giai on lm sch TPA, gi
(TPA) th c x l bng than hot tnh loi thnh cao, cho nn phng php t c s dng
b tp cht v sau ti kt tinh bng dung mi cho ti ch PET vi quy m cng nghip.
(thng l axit axetic) thu c TPA c tinh
O O
O C C OCH2CH2O + 2n H2O

n
O O
n HO C C OH + (n + 1) HOCH2CH2OH

TPA
Hnh 4: Phng trnh phn ng thy phn
Dutta & Soni (2014)
Ru phn (methanolysis): Tc nhn kh si v chai. Tuy nhin, qu trnh phn tch sn
trng hp l ru methylic nhit khong 200 phm ca phn ng cn chi ph cao, phng php

C, di p sut cao. Phn ng ru phn rt c ny t kinh t.


hiu qu ti ch nha PET dng mng, dng
O O
O C C OCH2CH2O + 2n CH3OH

n
O O
n CH3O C C OCH3 + (n + 1) HOCH2CH2OH

DMT
Hnh 5: Phng trnh phn ng ru phn
Dutta & Soni (2014)

60
Tap ch Khoa hoc Trng ai hoc C n Th Phn A: Khoa hc T nhin, Cng ngh v Mi trng: 39 (2015): 57-65

Glycol phn (glycolysis): Phn ng glycol (BHET) cng vi oligome. Tinh ch BHET bng
phn PET c tin hnh di p sut cao, nhit phng php lc nng di p sut loi cc tp
180-220 C trong mi trng kh tr (N2) cht. Sau lm sch bng than hot tnh kh
trnh oxy ho cc polyol to thnh. Sn phm ca mu v tp cht. Hin nay, y l phng php
phn ng l monome bis(2-hydroxyetyl) terephtalat ang c s dng ph bin nht.
O O
O C C OCH2CH2O + n HOCH2CH2OH

n
O O
n HOCH2CH2O C C OCH2CH2OH

BHET
Hnh 6: Phng trnh phn ng glycol phn
Dutta & Soni (2014)
2.1.2 Ti ch bng phng php c- l PET thi sau qu trnh nghin ra v sy c
np liu lin tc cho my n hai trc vt, ht R-
Chai PET sau khi s dng xong c thu gom,
PET t my n c x l trong thit b kt tinh
ra sch, bm nh, sy kh v ti gia cng. Hin
ha tng kt tinh nhm trnh s to thnh cc
nay, c 2 cng ngh chnh: cng ngh SSP v cng
kt t khi x l bng thit b SSP nhit 200
ngh bin tnh PET.
250 C iu kin khng c oxy v hi m trong
a. Cng ngh SSP khong thi gian xc nh (10 12 gi) nhm t
Vic x l ph liu bng thit b SSP chia ra 2 c I.V mong mun ng thi loi b sn phm
phng php: phng php chn khng v dng ca phn ng (nc, ethylene glycol, acetaldehyde)
kh tr (N2). cng nh cc tp cht d bay hi (dung mi, cht
ty ra, mc in, ...). Kh nit sch v kh c
Cng ngh SSP dng kh N2 lm cht ti nhit dng lm mi trng ti nhit. Qu trnh x l l
mt qu trnh khng lin tc v li im ca n l
to ra sn phm khc nhau ty theo nhu cu s
dng.
Cng ngh SSP dng phng php chn khng
Cng ngh SSP dng phng php chn khng
c vn hnh tng t phng php SSP dng
kh N2. Tuy nhin, phng php ny s xy ra
nhanh hn do hiu qu loi b nc v ethylene
glycol tt hn, chi ph vn hnh thp hn phng
php dng kh N2.
b. Cng ngh bin tnh ph liu
Qu trnh bt u t PET-F sau khi ra c
trn vi cht bin tnh silicone lng trong thit b
trn 140 150 C, thi gian khong 90 pht.
Nguyn liu c np liu cho my n hai trc
Hnh 7: Quy trnh cng ngh SSP dng kh N2 vt. nhit cao, cht bin tnh s to mch PET
lm cht ti nhit ngn v PET phn nhnh c khi lng phn t
Fugen DAVER et al. (2007)
ln. Vi li lc mn c th loi b nhng tp cht
rn khng nng chy. T , cho ra M-PET c th

61
Tap ch Khoa hoc Trng ai hoc C n Th Phn A: Khoa hc T nhin, Cng ngh v Mi trng: 39 (2015): 57-65

khng cao sau qu trnh bin tnh. Tuy nhin, da trn polyeste khng no v nha epoxy, nhng
bn c tnh th tng ng vi nha PET gn y cc vt liu nha nhit do c ng
nguyn sinh. dng chng hn nh poly (ethylene terephthalate)
(PET). Si thy tinh l nhng vt liu gia c s
dng nhiu nht trong nha nhit do vi nhiu c
tnh mong mun nh chi ph thp, cch nhit v
bn ko cao, khng ha cht. Do , vt liu tng
hp da trn nha nhit do v si thy tinh l s
kt hp d dng. Tuy nhin, cc c tnh k nc,
a nc khc nhau gia cc si thy tinh v nha
dn n bm dnh km nh hng n tnh cht
c hc ca vt liu tng hp. V vy, vic s dng
cht ph gia hot tnh nhm ci thin bm dnh
gia cc si v polyme.
3.3 Lnh vc xy dng
PET ti ch c ng dng trong xy dng l
vn ph bin nht hin nay. Vic ng dng PET
ti ch vo xy dng nhm nng cao hiu sut cch
nhit, ci thin tnh cht c hc ca b tng v li
ch kinh t v mi trng. Cc vt liu cch nhit
v in cho ngnh cng nghip xy dng l mt
trong nhng ng dng kh thi ca PET ti ch.
Mt s ng dng ang c quan tm hin nay
Hnh 8: Cng ngh bin tnh PET
nh: Ct vt liu cho b tng polyme, gch, nha
Fugen DAVER et al. (2007) ng, sn, nhm to s thn thin vi mi trng
v trnh lng ph ti nguyn.
3 NG DNG CA PET TI CH
3.1 Trong lnh vc i sng B tng polyme (PC) vi nhiu tnh nng
tt nh: Kh nng chng n mn, chu nhit, chu
Trong cuc sng hin i, vic s dng cc vt nn v c bn ko tt hn so vi b tng
dng nh chai nha, mng nylon bc thc phm, thng thng (spemat.com). V l do ny, b tng
ng nha dn nc tr nn quen thuc vi polyme c s dng trong nhiu cng trnh nh
i sng con ngi. Sn phm nha tr thnh mt cng hp, thng cha cht thi nguy hi, cc
phn khng th thiu trong cuc sng cng nh ng rnh, cng sn v trong vic sa cha lm
trong cng nghip. Nha c ng dng rt ph lp ph ca b mt b tng xi mng nh ng v
bin t bao b cha thc phm n ha cht cng cu b h hng. S kt hp gia nha PET ti ch
nghip v gia dng. vo b tng polyme gip gim chi ph vt liu gii
Trn thc t, nha ti ch c tnh ng dng cao, quyt mt s vn cht thi rn gy ra v tit
mt s ni c tng ch bin nha ph thi thnh kim nng lng. Trong thc t, mt cuc kho st
du th, ti ch thnh thm, ch bin du xanh t gn y xp ng dng nha t tn km l yu t
nha ph thi. Cc nguyn liu si cng nghip quan trng nht cn thit cho vic s dng
lm t nha PET ti ch c dng to ra nhiu trong tng lai ca b tng polyme (Byung-Wan
loi sn phm khc nhau nh qun o, giy, khn Jo, 2008). V iu ny lm cho th trng tiu
tm, chn Nhng hot ng ny gp phn th PET ti ch ng dng vo b tng polyme c
lm gim gi thnh v gip gii quyt vn khan s rng buc. Cht kt dnh c s dng cho b
him nguyn liu sn xut. tng polyme bao gm epoxy, MMA (Methyl
Methacrylate), v polyester khng no,. nhm ci
3.2 Trong lnh vc vt liu
thin ng k hiu sut.
Mt ng dng quan trng ca PET ti ch trong
Hin nay, hn hp nha ng polyme ci tin
lnh vc vt liu l vic s dng cc vt liu
l mt hn hp tng i tn km cho lt
polyme gia c bng si thy tinh pht trin
ng. Mt cch gim chi ph ca cng trnh
nhanh chng trong nhng nm qua. Cc hp cht
xy dng v lm cho chng thun tin hn l s
cao phn t u tin s dng si thy tinh ct nh

62
Tap ch Khoa hoc Trng ai hoc C n Th Phn A: Khoa hc T nhin, Cng ngh v Mi trng: 39 (2015): 57-65

dng polyme r tin, tc l polyme cht thi. V khc nhau, hoc s dng tng hp nhiu phng
vy, vic kt hp gia nha ph thi PET trn php. ng dng PET ti ch vo nhiu lnh vc vi
nhng c tnh k thut ca hn hp nha mc ch a PET ti ch vo qui trnh c th
ng mastic (SMA) gip tng cng ca hn to ra sn phm mong mun p ng c nhu cu
hp, nng cao khng c, chng li s bin dng, ca x hi, m bo PET c u vo v u ra.
tng ng k bn v kh nng chng ln ng thi, c th l mt ng gp ng k cho mi
(Esmaeil Ahmadinia, 2012). S kt hp b tng trng v nn kinh t t cc kha cnh khc nhau,
nha vi cc polyme dng nh c tim nng ln c th nh: Gim vic lm dng ti nguyn thin
nht cho ng dng thnh cng trong vic thit k nhin, gim mc nhim mi trng, gp phn
mt ng mm tng chiu di tui th ca mt tit kim nng lng v tin bc. V vy, gim
ng hoc gim dy lp va h. thiu tc ng tiu cc i vi mi trng v thin
nhin, th vic ng dng PET ti ch l iu cn
Gch mosaic 100% ti ch l s kt hp gia
thit. Bn cnh cc nc ang pht trin th Vit
PET ti ch (85%) v ph gia khong ti ch
Nam cn gp nhiu kh khn, t , vic ti ch v
(15%). Qu trnh sn xut tiu th t nng lng,
ng dng PET cn gp nhiu cn tr cn phi c
khng thi ra cc cht nhim v to ra khng cht
s u t pht trin nghin cu cc d n ti ch
thi. Mi mt vung ca gch mosaic ngn chn
trn quy m cng nghip, vi dy chuyn ti ch
vic pht thi 3 kg CO2 vo bu kh quyn v loi
ph hp vi tnh hnh kinh t t nc. Cc d n
b 66 chai PET t mi trng. Gch Mosaic
ny phi p ng c cc yu cu quan trng
bn cao, p v d vn chuyn. Mt li th l gch
nh: Ti ch nha PET vi sn lng ln v hiu
Mosaic c th c p dng cho nn hoc vch
qu ti ch cao, m bo cht lng mi trng,
c khu vc trong nh v ngoi tri, chng hn nh
cht lng sn phm ti ch, cnh tranh c vi
nh bp, phng tm, mt tin hoc thm ch b bi.
sn phm t nha nguyn liu mi. ng thi to
PET ti ch l mt polymer ngng t gm u ra sn phm t PET ti ch gip x hi c cuc
ethylene glycol (EG) v axit terepththalic (TPA) sng n nh v nn kinh t ngy mt pht trin.
c s dng trong tng hp nha sn. Nha
TI LIU THAM KHO
alkyd c tng hp t PET ti ch nh l mt
cht thay th cho EG v anhydrit phthalic 1. Friston, Karl J, et al., 1991, Plastic
(PA). Sau khi thay i thnh phn monome ca n, transformation of PET images. Journal of
cui cng cho thy nhng c im tng t Computer Assisted Tomography.
nh nha ban u. Vic s dng PET ti ch trong 2. N.S. Murthy, et al., 1991, Structure of the
tng hp nha alkyd cho thi gian kh, cng v amorphous phase in crystallizable polymer:
kh nng chng mi mn tt hn so vi sn ankyd Poly(ethylene terephthalate).
thng (A. Torlakoglu, 2009). Ngoi ra, vic s
3. Trung tm ti nguyn v mi trng, trng
dng PET ti ch trong alkyd gip tiu th khi
i hc Tng hp H Ni (dch v gii
lng ca PET ti ch mt cch ng k.
thiu) (1993), Cu ly Tri t chin lc
3.4 Mt s ng dng khc ca PET ti ch cho cuc sng bn vng, NXB Khoa hc
Ph tng t: tm ph gh, hp ng pin, cnh K thut.
qut v cc tm ca, thm lt khoang hnh l c 4. Scheirs J (1998) Recycling of PET. In:
sn xut bng cht liu PET bn, p, chng thm Polymer recycling: science, technology and
nc, d v sinh (Panda, et al., 2010). Ngoi ra, applications. Wiley Series in
cn c ng dng trong ngnh cng nghip in PolymerScience, Wiley, Chichester, UK.
t (hp cng tc in, v dy cp in, mn hnh 5. K.S Rebeiz., 1995, Time temperature
tivi), h thng lc thot nc properties of polymer concrete using
4 KT LUN recycled PET. Department of Civl and
environmental engineering, Lafavette
Ti ch PET l mt trong nhng vn cp college, Easton, PA 18042, USA.
bch i vi nc ta hin nay. C nhiu phng
6. K.S Rebeiz., 1996, Precast use of polymer
php ti ch PET, mi phng php u c mt
concrete using unsaturated polyesterresin
tch cc v hn ch ca n. Ty iu kin v hon
based on recycled PET waste. Science:
cnh c th ta c th p dng nhng phng php
215-220.

63
Tap ch Khoa hoc Trng ai hoc C n Th Phn A: Khoa hc T nhin, Cng ngh v Mi trng: 39 (2015): 57-65

7. Brandrup, J., E. H. Immergut, E. A. Grulke, phase transfer catalyst. Indian journal of


A. Abe, et al., 1999. Polymer handbook. chemical technology: 173-177.
Wiley New York. 22. Fugen DAVER et al., 2007, Rheological
8. Don Kaufman, G eoff Wright et al., 1999, characterisation of recycled poly (ethylene
Compounds from old plastic: Recycling terephthalate) modified by reactive extrusion.
PET plastic via depolymerization. An 23. Das, J., A. Halgeri, V. Sahu and P. Parikh,
Activity for the Undergraduate Organic 2007. Alkaline hydrolysis of poly
Lab. Department of Chemistry, University (ethylene terephthalate) in presence of a
of Nebraska at Kearney, Kearney, NE 68849. phase transfer catalyst. Indian journal of
9. J.J.Robin et al., 1999, Study of thermal and chemical technology: 173-177.
mechanical properties of virgin and 24. Quang Minh, 2007. Tng hp coban
recycled poly(ethylene terephthalate) before aluminat (CoAl2O4) kch thc ht siu mn
and after injection molding. nhit thp. Science & Technology
10. Andrzej Galeski et al., 2000, Development, Vol 10, No.10-2007.
Characterization of scrap poly(ethylene 25. V Th Hai, Hong Ngc Cng, Phn
terephthalate). ng ct mch poly(ethylen terephthalat)
11. L Incarnato et al., 2000, Structure and (PET) t v chai bng dietylen glycol
rheology of recycled PET modified by (DEG), Science & Technology
reactive extrusion. Development, Vol 11, No.06 2008.
12. Chikara kawamura et al., 2001, Coating r 26. Siddique, R., J. Khatib and I. Kaur, 2008,
es ins synthesized from recycled PET. Use of recycled plastic in concrete: a
Sciencedirect: 185-191. review. Waste management: 1835-1852.
13. Nguyn nh Triu, 2001. Cc phng 27. Phan V Hong Giang, 2008, Cng ngh
php phn tch vt l v ha l. Nh xut ti s dng chai pet.
bn Khoa hc v K thut. H Ni. 28. Peter Schmid et al., 2008, Does the reuse of
14. D.A. Silva et al., 2004, Degradation of PET bottles during solarwater disinfection
recycled PET fibers in Portland cement- posea healthriskdue to the migration of
based materials. Sciencedirect: 1741-1746. plastic isers and other chemicals into the
15. Ali, M. F. and M. N. Siddiqui, 2005. water?. Science: 5054-5060
Thermal and catalytic decomposition 29. Caparanga, A. R., B. A. Basilia, K. B. Dagbay
behavior of PVC mixed plastic waste with and J. W. Salvacion, 2009, Factors affecting
petroleum residue. Journal of Analytical degradation of polyethylene terephthalate
and Applied Pyrolysis: 282-289. (PET) during pre-flotation conditioning.
16. Awaja, F. and D. Pavel., 2005. Recycling of Waste management: 2425-2428.
PET. European Polymer Journal: 1453-1477. 30. Bulent Yesilata et al., 2009, Thermal
17. A.L.F. de Moura Giraldi, R. Cardoso de insulation enhancement inconcretes by adding
Jesus, 2005,The influence of extrusion waste PET and rubber pieces. Construction
variables on the interfacial adhesion and and Building Materials: 1878-1882.
mechanical properties of recycled PET 31. Panda, A. K., R. Singh and D. Mishra,
composites. 2010. Thermolysis of waste plastics to
18. Firas Awaja et al., 2005, Recycling of PET. liquid fuel: A suitable method for plastic
waste management and manufacture of
19. Trn Vnh Diu v Trn L Trung, 2006, Mi
value added productsA world
trng trong gia cng cht do v compozit.
prospective. Renewable and Sustainable
Nh xut bn Bch khoa H Ni.
Energy Reviews: 233-248.
20. Hong Anh, 2006, Lun vn Nghin cu
32. Kinda Hannawi et al., 2010, Kinphysical
v xut cc cng ngh ti ch kh thi
and mechanical properties of mortars
cht thi rn plastic trn a bn TP.HCM.
containing PET and PC waste aggregates.
21. Das, J., A. Halgeri, V. Sahu and P. Parikh, Science: 2312-2320.
2007, Alkaline hydrolysis of poly
33. Waqas Nawaz et al., 2010, PET recycling
(ethylene terephthalate) in presence of a
chemical and mechanical methods.

64
Tap ch Khoa hoc Trng ai hoc C n Th Phn A: Khoa hc T nhin, Cng ngh v Mi trng: 39 (2015): 57-65

34. Upasani, P. S., A. K. Jain, N. Save, U. S. Mechanical Properties of Recycled PET


Agarwal, et al., 2012, Chemical recycling Modified by Reactive Extrusion.
of PET flakes into yarn. Journal of Applied 41. M Victoria Gonz_alez Rodrguez et al,
Polymer. Science: 520-525. 2014 Assessing changes on poly(ethylene
35. Seville and Spain, 2012, End of waste terephthalate) properties after recycling:
criteria for waste plastic for conversion Mechanical recycling in laboratory versus
technical proposals. postconsumer recycled material.
36. Hong Th ng Qu, Phm Hunh Trm 42. V Th Bch Phng, 2014. Kho st qu
Anh, Thim Tr Vin, Nguyn Ngc Nh trnh phn hy Polyetylen t trng cao
Hng, et al., 2012. Ph gia chng chy phi (HDPE) bng xc tc thi FCC Dung Quc
halogen ng dng vo cc loi vt liu Lun vn tt nghip cao hc. Trng i
polyme chng chy trn c s polyeste hc Cn Th.
khng no. Tp ch Pht trin KH&CN. 43. Wang, C.-Q., H. Wang and Y.-N. Liu,
37. Saisinchai et al., 2013, Separation of PVC Separation of polyethylene terephthalate from
from PET/PVC Mixtures Using Flotation by municipal waste plastics by froth flotation for
Calcium Lignosulfonate Depressant. recycling industry. Waste Management.
Engineering Journal: 45-54. 44. Mohammad Abbasi, Mohammad Mehdi
38. Nurul Munirah Abdullah and Ishak Ahmad, Salarirad, and Ismail Ghasemi, Selective
Potential of Using Polyester Reinforced Separation of PVC from PET/PVC Mixture
Coconut Fiber Composites Derived from Using Floatation by Tannic Acid
Recycling Polyethylene Terephthalate Depressant,Iranian Polymer Journal 19 (7),
(PET) Waste, Fibers and Polymers 2013, 2010, 483-489.
Vol.14, No.4, 584-590. 45. Jensen JW, Holman JL, Stephenson JB
39. Dutta and Soni, 2013, A Review on (1974) Recycling and disposal of waste
Synthesis of Value Added Products from plastics. Ann Arbor Science, chap 7
Polyethylene Terephthalate (PET) Waste. 46. Hp phn sn xut sch hn trong cng
Polymer Science, Ser. B. nghip, Trung tm sn xut sch hn Vit
40. Supawee Makkam, Wanlop Nam, Ti liu hng dn sn xut sch hn.
Harnnarongchai, 2014, Rheological and

65

Das könnte Ihnen auch gefallen