Beruflich Dokumente
Kultur Dokumente
Vander Voort
Buehler Ltd.
Lake Bluff, Illinois USA
Contemporary Procedure for Ni-Based Superalloys
Surface Abrasive/Size Load Platen Time
Lb (N) Speed (min.)
CarbiMet 180-240 (P180-P280)
6 240-300 Until
waterproof grit SiC
(27) Comp. Plane
discs (psa) water cooled
Ultra-Pol Silk 9-m MetaDi
6 100-150 5
Cloth (psa) Supreme Diamond
(27) Comp.
Suspension
3-m MetaDi
TriDent cloth 6 100-150 5
Supreme Diamond
(psa) (27) Comp.
Suspension
1-m MetaDi
TriDent cloth 6 100-150 3
Supreme Diamond
(psa) (27) Comp.
Suspension
MicroCloth 0.05-m
6 80-150 3
pad (psa) MasterPrep
(27) Contra
alumina slurry
Common Etchants
15 mL HCl Glyceregia. Mix fresh; do not store. Good for
10 mL glycerol about 20 minutes. Use by swabbing. General
5 mL HNO3 purpose etch.
15 mL HCl Acetic glyceregia, stronger than glyceregia. Mix
10 mL Acetic acid fresh; do not store. Good for about 20 minutes.
5 mL HNO3 General purpose etch.
1 - 2 drops glycerol
15 mL HCl Mixed acids, for the most corrosion-resistance
10 mL Acetic acid grades; e.g., Alloy 625. Mix fresh; do not store.
10 mL HNO3 Good for 30 minutes. General purpose etch.
5 g CuCl2 Waterless Kallings reagent (number 2). This
100 mL HCl reagent can be made as a stock solution. Good
100 mL ethanol grain boundary etch.
Lucas Reagent
Lucas Reagent
2 V dc, 10s
Dendritic structure of cast IN-738 alloy (Ni 0.17C 16Cr 8.5Co 2.6W
1.75 Mo 0.9Nb 1.75Ta 3.4Al 0.01B 0.1Zr).
Glyceregia Lucas Reagent
2 V dc, 10 s
Lucas Reagent
2 V dc, 10s
The microstructure of hot worked, annealed and cold drawn Monel 400 (Ni 32% Cu - <0.3% C -
<2% Mn - <0.5% Si) revealed using Berahas selenic acid etch for copper (longitudinal axis is
horizontal). Monel alloys are very difficult to color etch, especially wrought alloys (as-cast alloys are
easier). Bright field revealed a weak image as the interference film produce is thin (inclusions,
arrows, can be seen). When this occurs, polarized light will often enhance the image quality
dramatically (the sensitive tint filter enhances coloration), as shown. Note the deformed, twinned
FCC alpha grain structure. The magnification bars are 50 m long.
Martensitic structure (335 HV) of Greek Ascoloy (Fe
0.17C 13Cr 2Ni 3W) revealed using Vilellas
reagent.
Martensitic (345 HV) grain structure of Moly Ascoloy (Fe 0.11C
0.7Mn 11.75Cr 2.5Ni 1.75Mo 0.32V 0.03N) etched with Vilellas
reagent.
Glyceregia Berahas Tint Etch
Coarse grains
near surface
Grain structure of A286 (Fe 0.05C 26Ni 15Cr 1.25Mo 0.3V 2.15Ti 0.2Al
0.003B) solution annealed at 1650 F/899 C.
1825 F/996 C 1875 F 1024 C
1900 F 1038 C
Nomarski DIC
As-rolled alloy 330 solution annealed at 1975 F/1079 C (10% Oxalic acid, 6 V dc, 10 s).
15 HCl - 10 Acetic
Glyceregia
Acid - 10 HNO3
Lucas Reagent
2 V dc, 10 s
Grain structure of solution annealed and aged non-rotating quality alloy 718
with a fine grain size, considerable delta and large primary MC carbides.
Glyceregia 15 HCl - 10 Acetic Acid -
10 HNO3
Lucas Reagent
2 V dc, 10 s
Grain structure of premium quality alloy 718 in the forged and aged condition.
Note that glyceregia did not reveal the grain structure, only primary MC carbides.
Austenitic grain structure of fine grained alloy 718 in the solution annealed
and aged condition etched with glyceregia revealing delta phase pinning the
boundaries. The magnification bar is 10 m long.
954 C/1750 F 1066 C/1950 F
Microstructure of alloy 718 solution annealed at 954 and 1066 C and double
aged; etched with glyceregia. Note differences in magnification. The low solution
annealing temperature does not dissolve the delta phase, as happens with the high
solution annealing temperature. Delta is used to control the grain size for best
cryogenic properties. MC type carbides are observed in both specimens. The
strengthening phase is much too fine to be seen with light microscopy. Note that
the structure looks the same before or after aging (although the hardnesses are
different).
Delta phase in Alloy 718 solution annealed at 954 C (1750 F) and aged 100 h
at 1600 F/871 C (etched with glyceregia)
100X 200X
500X
Austenitic grain structure of alloy X-750 (Ni 0.04C 7Fe 15.5Cr 2.5Ti
0.95Nb+Ta 0.7Al) in the solution annealed and aged condition revealed
using glyceregia (left) and 15 mL HCl-10 mL acetic acid-10 mL nitric acid
(right). The magnification bars are 100 and 50 m, left and right,
respectively.
Microstructure of as-forged Waspaloy (Ni 0.07C 13.5Co 19.5Cr
4.3Mo 3Ti 1.4Al 0.07Zr 0.006B) etched with 15 mL HCl-10 mL
acetic acid-10 mL HNO3, magnification bar is 50 m long.
1010 C (1850 F) 1038 C (1900 F)
All magnification
Influence of bars are 100 m long
solution
annealing
temperature on
grain growth in
1066 C (1950 F)
Waspaloy
Microstructure of wrought, solution annealed and double aged (about 42 HRC)
Waspaloy, a nickel-based superalloy tint etched with Berahas BIV reagent
revealing twinned austenitic grains. Viewed in bright field. The magnification
bar is 100 m long.
Glyceregia 15-10-10
Lucas Reagent, 2 V
dc, 20 s
Microstructure of forged, rotating grade Waspaloy in the solution annealed and
aged condition. A necklace-type bimodal grain size distribution was observed.
Microstructure of an as-forged bar of an experimental composition similar to
alloy 625 revealing a necklace type bimodal grain size distribution due to
partial recrystallization. The specimen was etched with acetic glyceregia. The
magnification bar is 100 m long.
As-Polished Acetic Glyceregia
Microstructure of hot rolled Custom Age 625 PLUS alloy with finish rolling
temperatures of 1680 F/916 C (left, partially recrystallized) and at 1845
F/1007 C (right, fully recrystallized) revealed using 15 mL HCl 10 mL
acetic acid 10 mL HNO3.
Finish Roll at 1680 F/916 C + SA and DA Finish Roll at 1845 F/1007 C + SA and DA
Grain structure of the Custom Age 625 PLUS alloy specimens finish rolled at
1680 (left) and 1845 F (right) after solution annealing and double aging
revealed using 15 mL HCl 10 mL acetic acid 10 mL HNO3.
Austenitic grain structure of Carpenters Custom Age 625 Plus alloy in
the solution annealed and aged condition after etching with acetic
glyceregia. The magnification bar is 100 m long.
Bright Field Dark Field
Microstructure of Russian P/M turbine blade alloy EP741NP (Ni 0.04C 9Cr
15.8Co 3.9Mo 5.5W 1.8Ti 2.6Nb 0.25Hf) revealing the coarse grain
structure in grain contrast (other etchants simply darkened the matrix
uniformly). The specimen was Hiped and heat treated (2210 F 8 h, furnace
cool to 2120 F, air cool; age at 1600 F for 32 h, air cool).
15 mL HCl 10 mL acetic acid Molybdic Acid Reagent
10 mL HNO3
200m
200m
Base Metal
Berahas Reagent