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(HELD ON SUNDAY 02nd APRIL, 2017)

PART A PHYSICS

1. A particle is executing simple harmonic motion with

1

a time period T. AT time t = 0, it is at its position K.E. = mA 2 2 cos2 t

2

of equilibrium. The kinetic energy-time graph of

the particle will look like Hence graph of K.E. v/s time is square cos function

KE KE

(1) 0 T/2 T t 0 T

(2) 30 m 3 increases from 17C to 27C due to

0 T/4 T/2 T t sunshine. The atmospheric pressure in the room

remains 1 105 Pa. If ni and nf are the number

(3)

KE

0 T/2 T T t

of molecules in the room before and after heating,

then nf ni will be :-

(1) 2.5 1025

(3) 1.61 1023

(2) 2.5 1025

(4) 1.38 1023

Ans. (2)

KE

Sol. Using ideal gas equation

(4) 0 T t PV = NRT

(N is number of moles)

Ans. (2)

P0V0 = NiR 290 ...... (1)

[Ti = 273 + 17 = 290 K]

Vmax V=0

After heating

P0V0 = NfR 300 ...... (2)

Sol. V=0

from equation (1) and (2)

Equilibrium Extreme

position position P0 V0 PV

Nf Ni = 0 0

R 300 R 290

Time taken to reach the extreme position from

P0 V0 10

difference in number of moles

T R 290 300

equilibrium position is . Velocity is maximum at

4

Hence nf ni is

equilibrium position and zero at extreme position.

V = A cos t P0 V0 10

= 6.023 1023

R 290 300

1 2

K.E. = mv

2 putting P0 = 105 PA and V0 = 30 m3

(m is the mass of particle and v is the velocity of Number of molecules nf ni = 2.5 1025

particle

1

JEE(MAIN)-2017

3. Which of the following statements is false ? 4. The following observations were taken for

(1) A rheostat can be used as a potential divider determining surface tensiton T of water by

(2) Kirchhoff's second law represents energy

capillary method :

conservation

(3) Wheatstone bridge is the most sensitive when Diameter of capilary, D = 1.25 102 m

all the four resistances are of the same order rise of water, h = 1.45 102 m

of magnitude.

(4) In a balanced wheatstone bridge if the cell and Using g = 9.80 m/s2 and the simplified relation

the galvanometer are exchanged, the null point rhg

T= 103 N/m, the possible error in surface

is disturbed. 2

Ans. (4) tension is closest to :

(1) 2.4% (2) 10% (3) 0.15% (4) 1.5%

Ans. (4)

Sol. (1)

rhg

Sol. T 103

On interchanging Cell & Galvanometer. 2

R1 R2

T r h

T

r

h

0

G 100 100

T 1.25 102 1.45 102

R3 R4 = (0.8 + 0.689)

(2)

= (1.489)

T

100 1.489 %

T

On balancing condition 1.5%

R1 R 2 5. In amplitude modulation, sinusoidal carrier

....(1)

R3 R 4 frequency used is denoted by c and the signal

frequency is denoted by m. The bandwidth (m)

R1 R2 of the signal is such that m << c. Which of the

following frequencies is not contained in the

G modulated wave ?

(1) m + c (2) c m

R3 R4 (3) m (4) c

Sol. Refer NCERT Page No. 526

R1 R 3

....(2) Three frequencies are contained

R2 R

m + c, c m & c

As we see both equation (1) & (2) are same. So

4th statement is false.

2

CODE-B

6. A diverging lens with magnitude of focal length

m 2 m

25 cm is placed at a distance of 15 cm from a I

4 3

converging lens of magnitude of focal length

20 cm. A beam of parallel light falls on the diverging For maxima & minima

lens. The final image formed is : dI m 2 m

(1) real and at a distance of 40 cm from the 2 0

d 4 3

divergent lens

(2) real and at a distance of 6 cm from the 2 m 2 R 2

2

convergent lens 3 3 2

(3) real and at a distance of 40 cm from convergent 2 R 2

lens or

3

(4) virtual and at a distance of 40 cm from

2 3

convergent lens.

R2 2

Ans. (3)

Sol. As parallel beam incident on diverging lens if forms 2 3

or

virtual image at v1 = 25 cm from the diverging R 2

lense (f = 20 cm)

lense which works as a object for the converging 8. An electron beam is accelerated by a potential

difference V to hit a metallic target to produce

X-rays. It produces continuous as well as

characteristic X-rays.If min is the smallest

possible wavelength of X-ray in the spectrum, the

variation of log min with log V is correctly

represented in :

f = 25 cm f = 20 cm

log min

15 cm

So for converging lens u = 40 cm, f = 20 cm (1)

log V

Final image

1 1 1 log min

V 40 20

(2)

7. The moment of inertia of a uniform cylinder of

length and radius R about its perpendicular

log min

bisector is I. What is the ratio /R such that the

moment of inertia is minimum ? (3)

3 3 log V

3

(1) 1 (2) (3) (4)

2 2 2

log min

Ans. (3)

m 2 mR 2 (4)

Sol. I log V

12 4

m 2 2 Ans. (3)

or I R ....(1)]

4 3 hc

Sol. eV

Also m = R2 min

m Put in equation (1) 1 eV

R2

min hc

3

JEE(MAIN)-2017

1 e Ans. (1)

n nV n

min hc Sol. So from pE

e

n(min) = nV + n p

hc

e

n min nV n

hc x axis

It is a straight line with ve slope.

A radioactive nucleus A with a half life T, decays

9.

into a nucleus B. At t = 0, there is no nucleus B.

k k p x i p y j Ei 3Ej

At sometime t, the ratio of the number of B to that p 3E k p E k

x y

of A is 0.3. Then, t is given by :

0 Ek 3p p x y

T

(1) t = T log (1.3) (2) t = py

log(1.3) 3

T log 2 log1.3 px

(3) t = 2 log1.3 (4) t = T log 2 tan = 3

Ans. (4)

Sol. At time t

NB

.3 NB = .3 NA

= 60

11. In a common emitter amplifier circuit using an

n-p-n transistor, the phase difference between the

input and the output voltages will be :

NA

(1) 135 (2) 180 (3) 45 (4) 90

also let initially there are total N0 number of nuclei Ans. (2)

NA + NB = N0

Sol. In common emitter amplifier circuit input and out

N

NA 0 put voltage are out of phase. When input voltage

1.3

is increased then ib is increased, ic also increases

Also as we know

so voltage drop across Rc is increased. However

NA = N0et

increase in voltage across RC is in opposite sense.

N0 12. Cp and Cv are specific heats at constant pressure

N 0 e t

1.3

1 n 1.3 that

e t n(1.3) = t or t

1.3 Cp Cv = a for hydrogen gas

Cp Cv = b for nitrogen gas

n 1.3 n 1.3

t T The correct relation between a and b is :

n 2 n 2

T (1) a = 14 b (2) a = 28 b

1

10. An electric dipole has a fixed dipole moment p , (3) a = b (4) a = b

14

which makes angle with respect to x-axis. When Ans. (1)

subjected to an electric field E1 Ei , it Sol. CP CV = R

experiences a torque T1 k . When subjected to where CP and CV are molar specific heat capacities

another electric field E 2 3E1j it experiences As per the question

R R

torque T2 T1 . The angle is : a= b=

2 28

(1) 60 (2) 90 (3) 30 (4) 45 a = 14 b

4

CODE-B

13. A copper ball of mass 100 gm is at a temperature Ans. (3)

T. It is dropped in a copper calorimeter of mass Sol. 10 = (5 103) (15 + R)

16. A slender uniform rod of mass M and length is

temperature. Subsequently, the temperature of the

pivoted at one end so that it can rotate in a vertical

system is found to be 75C. T is given by : plane (see figure). There is negligible friction at

(Given : room temperature = 30 C, specific heat the pivot. The free end is held vertically above the

pivot and then released. The angular acceleration

of copper = 0.1 cal/gmC

of the rod when it makes an angle with the

(1) 1250C (2) 825C vertical is :

(3) 800C (4) 885 C z

Ans. (4)

Sol. Heat given = Heat taken

(100) (0.1)(T 75) = (100)(0.1)(45) + (170)(1)(45)

10(T 75) = 450 + 7650 = 8100 x

T 75 = 810 3g 2g

(1) cos (2) cos

T = 885 C 2 3

14. A body of mass m = 102 kg is moving in a medium 3g 2g

(3) sin (4) sin

2 3

and experiences a frictional force F = kv2. Its intial

Ans. (3)

speed is v0 = 10 ms1. If, after 10 s, its energy is

1 2

mv0 , the value of k will be:-

8

(1) 104 kg m1 (2) 101 kg m1 s1 Sol. mgsin

(3) 103kg m1 (4) 103 kg s1

Ans. (1)

1 2 1 2 mg

Sol. mvf mv0

2 8 Taking torque about pivot = I

v0 m 2

vf = = 5 m/s mgsin =

2 2 3

dv 3g

(102) kv 2 =

2

sin

dt

17. Some energy levels of a molecule are shown in

5 10

dv the figure. The ratio of the wavelengths r = 1/2,

v2 = 100 k dt is given by :

10 0

1 1 E

= 100 k (10) 2

5 10 4

E

k = 104 3

15. When a current of 5 mA is passed through a 1

galvanometer having a coil of resistance 15 , it 2E

shows full scale deflection. The value of the 3E

resistance to be put in series with the galvanometer 3 1

(1) r (2) r

to convert it into to voltmeter of range 0 10 V is: 4 3

(1) 2.535 103 (2) 4.005 103 4 2

(3) r (4) r

(3) 1.985 103 (4) 2.045 103 3 3

5

JEE(MAIN)-2017

hC 10A

Sol. using E = Sol.

hC

for 1 E (2E) =

1

0.5 sec time

hC

1 =

E

hC q=

4E R

for 2 E =

3 2 = change in flux

3hC

2 = q = I dt

E

= Area of current-time graph

1 1

2 = r = 3 1

= 10 0.5 = 2.5 coloumb

18.

A man grows into a giant such that his linear

dimensions increase by a factor of 9. Assuming

that his density remains same, the stress in the leg

will change by a factor of :

q=

2

R

= 2.5 100 = 250 wb

1 1

(1) 81 (2) (3) 9 (4) 20. In a Young's double slit experiment, slits are

81 9

separated by 0.5 mm, and the screen is placed 150

Ans. (3)

cm away. A beam of light consisting of two

Force mg volume density g

Sol. Stress wavelengths, 650 nm and 520 nm, is used to obtain

area A Area

interference fringes on the screen. The least

3

L g distance from the common central maximum to the

Stress =

L2 point where the bright fringes due to both the

Stress L wavelengths coincide is :

(1) 9.75 mm (2) 15.6 mm

by changing the magnetic flux through it as shown

(3) 1.56 mm (4) 7.8 mm

in the figure. The magnitude of change in flux

Ans. (4)

through the coil is :

Sol. For common maxima

n11 = n22

10

n1 650 = n2 520

Current

(amp.) n1 4

n2 5

n

D

(1) 250 Wb (2) 275 Wb 4 650 109 1.5

y

(3) 200 Wb (4) 225 Wb 0.5 103

Ans. (1) y = 7.8 mm

6

CODE-B

21. A magnetic needle of magnetic moment 23. In the above circuit the current in each resistance

6.7 10 2 Am 2 and moment of inertia is :

7.5 106 kg m2 is performing simple harmonic 2V 2V 2V

oscillations in a magnetic field of 0.01 T.

1 1

1

Time taken for 10 complete oscillations is :

(1) 6.98 s (2) 8.76 s 2V 2V 2V

(3) 6.65 s (4) 8.89 s (1) 0.5 A (2) 0 A (3) 1 A (4) 0.25 A

Ans. (3) Ans. (2)

I 4V 2V 0V

Sol. T = 2 6V

MB

I = 7.5 106 kg m2

Sol.

M = 6.7 102 Am2

6V A

By substituting value in the formula 4V 2V 0V

T = .665 sec

for 10 oscillation, time taken will be Taking voltage of point A as = 0

22.

Time = 10 T = 6.65 sec

Answer option 3

The variation of acceleration due to gravity g with

distance d from centre of the earth is best

Then voltage at other points can be written as

shown in figure

Hence voltage across all resistance is zero.

Hence current = 0

represented by (R = Earth's radius): 24. A particle A of mass m and initial velocity v collides

g g m

with a particle B of mass which is at rest. The

2

collision is head on, and elastic. The ratio of the

(1) (2)

d d deBroglie wavelengths A to B after the collision

O R O R is :

g g A 2 A 1

(1) 3 (2) 2

B B

(3) (4) A 1 A

d d (3) (4) 2

O O R B 3 B

Ans. (2) Ans. (4)

Sol. g = inside the Earth (straight line) V M M

R3 Sol. m m V1 V2

2 2

GM rest

g= outside the Earth By conservation of linear momentum

r2

where M is Mass of Earth m

mv = mv1 + v2

g 2

2v = 2v1 + v2 ....(1)

by law of collision

v v1

e 2

u1 u 2

d ....(2)

u = v2 v1

option (2)

7

JEE(MAIN)-2017

By equation (1) and (2) From work energy theorem

v 4v 1

v1 ; v2 WF K.E m v 2 u 2

3 3 2

h h 1

1 ; 2 1 9 0 = 4.5 J

p1 o2 2

1 2 27. An observer is moving with half the speed of light

2 1 towards a stationary microwave source emitting

waves at frequency 10 GHz. What is the frequency

Option (4) of the microwave measured by the observer?

25. An external pressure P is applied on a cube at 0C (speed of light = 3 108 ms1)

so that it is equally compressed from all sides. (1) 17.3 GHz (2) 15.3 GHz

K is the bulk modulus of the material of the cube

(3) 10.1 GHz (4) 12.1 GHz

and is its coefficient of linear expansion. Suppose

we want to bring the cube to its original size by Ans. (1)

heating. The temperature should be raised by : Sol. Doppler effect in light (speed of observer is not

3 very small compare to speed of light)

(1) (2) 3PK

PK 1 V / C 1 1/ 2

f1 f source 10 GHz

(3)

Ans. (3)

P

3K

(4)

P

K

28.

1 V /C

= 17.3 GHz

1 1/ 2

reaches steady state in the circuit, the charge on

the capacitor of capacitance C will be :

v r

3T E

v

r1

Due to External pressure

v P C

v K r2

Equating both w1 get

P r2 r1

3T (1) CE (2) CE

K r r2 r1 r

P r1

T (3) CE (4) CE

3K r2 r

26. A time dependent force F = 6t acts on a particle Ans. (1)

of mass 1 kg. If the particle starts from rest, the

Sol. It steady state, current through AB = 0

work done by the force during the first 1 sec. will

be : E r

(1) 9 J (2) 18 J (3) 4.5 J (4) 22 J r1

Ans. (3) B A

Sol. F = 6t = ma C

D C

a = 6t r2

dv VAB = VCD

6t

dt

VAB r2 VCD

v 1 r r2

dv 6t dt

0 0

QC = CVAB

v = (3t2)10 = 3 m/s r

CE 2

r r2

8

CODE-B

29. A capacitance of 2 F is required in an electrical 30. A body is thrown vertically upwards. Which

one of the following graphs correctly represent

circuit across a potential difference of 1.0 kV. the velocity vs time?

A large number of 1 F capacitors are available

v

which can withstand a potential difference of

not more than 300 V. (1) t

to achieve this is : v

(2) t

(1) 24 (2) 32

(3) 2 (4) 16

v

Ans. (2)

(3) t

Sol. To hold 1 KV potential difference

C1

1

4

for one series.

(4)

Ans. (1)

v

t

Sol. Velocity at any time t is

are required.

given by

8 Parallel V0

v = u + at

v = v0 + (g)t

1 KV

v = v0 gt

9

JEE(MAIN)-2017

PART B MATHEMATICS

31. Let k be an integer such that triangle with Sol. We have

n

vertices (k, 3k), (5, k) and (k, 2) has area 28

sq. units. Then the orthocentre of this triangle

x r 1 (x r) 10n

r 1

is at the point : n

1 1 r 1

(1) 2, (2) 2, On solving, we get

2 2

2

n 2 31

3 3 x + nx + 0

(3) 1, (4) 1, 3

4 4

Ans. (1) (n 1)

(2 + 1) = n ...(1)

Sol. We have 2

n 2 31

k 3k 1 and ( 1) ...(2)

1 3

5 k 1 28

2 n2 = 121 (using (1) in (2))

k 2 1 or n = 11

5k2 + 13k 46 = 0 1 1

33. The function f : R , defined as

or 2 2

5k2 + 13k + 66 = 0 (no real solution exist) x

f(x) = , is :

1 x2

23 (1) neither injective nor surjective.

k= or k = 2

5 (2) invertible.

As k is an integer, so k = 2 (3) injective but not surjective.

(4) surjective but not injective

A(2, 6)

Ans. (4)

1 1

Sol. f : R , ,

H E 2 2

()

x

f(x) = x R

1 x2

B C(2, 2)

D

(5, 2) (1 x 2 ) 1 x 2x (x 1)(x 1)

f (x)

(1 x 2 ) 2 (1 x 2 )2

1

orthocentre is 2, +

2 sign of f(x)

x = 1 x=1

32. If, for a positive integer n, the quadratic

equation, y 1, 1

2

x(x + 1) + (x + 1) (x + 2) + .....

O x

+ (x + n 1 ) (x + n) = 10n (0,0) x = 1

has two consecutive integral solutions, then n

is equal to : 1, 1

2

(1) 11 (2) 12

(3) 9 (4) 10 From above diagram of f(x), f(x) is

Ans. (1) surjective but not injective.

10

CODE-B

34. The following statement

(p q ) [(~p q) q] is :

(1) a fallacy Sol. x+y=3

(2) a tautology

(3) equivalent to ~ p q y = 1 + x

(1,2) 2

(4) equivalent to p ~q 4y = x

Ans. (2) (0,1)

Sol. (p q) [(~p q) q]

(2,1)

p q ~ p p q ~ p q (~ p q) q (p q) ((~ p q) q)

T F F F T F T

T T F T T T T

(0,0) (1,0) (2,0)

F F T T F T T

F T T T T T T

It is tautology

35. If S is the set of distinct values of 'b' for which

1 2 2

the following system of linear equations x2

Area = (1 x) dx (3 x) dx 4

dx

x+y+z=1

x + ay + z = 1

ax + by + z = 0

=

5

2

0 1 0

(1) a singleton 37. For any three positive real numbers a, b and c,

(2) an empty set 9(25a2 + b2) + 25(c2 3ac) = 15b(3a + c).

(3) an infinite set Then :

(4) a finite set containing two or more elements

(1) a, b and c are in G.P.

Ans. (1)

(2) b, c and a are in G.P.

1 1 1 (3) b, c and a are in A.P.

Sol. D 1 a 1 0 a = 1

a b 1

Ans. (3)

and at a = 1 D1 = D2 = D3 =0

Sol. (15a)2 + (3b)2 + (5c)2 (15a) (5c) (15a) (3b)

but at a = 1 and b = 1

(3b) (5c) = 0

First two equationsare x + y + z =1

There is nosolution.

and third equation is x + y + z = 0 1

[(15a 3b)2 + (3b 5c)2 + (5c 15a)2]=0

b = {1} it is a singleton set 2

36. The area (in sq. units) of the region it is possible when 15a = 3b = 5c

{(x, y} : x 0, x + y 3, x2 4y and y 1 + x}

is : 5c c

b= , a=

3 3

5 59 3 7

(1) (2) (3) (4)

2 12 2 3 a + b = 2c

Ans. (1) b, c, a in A.P.

11

JEE(MAIN)-2017

38. A man X has 7 friends, 4 of them are ladies x2 y2

and 3 are men. His wife Y also has 7 friends, Sol. Equation of hyperbola is 1

a 2 b2

3 of them are ladies and 4 are men. Assume foci is (2, 0) hence ae = 2, a2e2 = 4

X and Y have no common friends. Then the b2 = a2(e2 1)

total number of ways in which X and Y a2 + b2 = 4 ...(1)

together can throw a party inviting 3 ladies and

3 men, so that 3 friends of each of X and Y are

Hyperbola passes through 2, 3

in this party, is : 2 3

1 ...(2)

(1) 484 (2) 485 (3) 468 (4) 469 a 2 b2

Ans. (2) On solving (1) and (2)

a2 = 8 (is rejected) and a2 = 1 and b2 = 3

4 Ladies 3 Ladies

x2 y2

Sol. x y 1

1 3

3 Men 4 Men

2x 3y

Total number of ways Equation of tangent is 1

4C 3C 3C 4C 4 3 3 4 1 3

0 3 3 0 + C1 C2 C2 C1

4 3 3 4 4 3 3

+ C2 C1 C1 C2 + C3 C0 C0 C3 4 Hence 2 2,3 3 satisfy it.

= 485 41. Let a, b, c R. If f(x) = ax2 + bx + c is such

39.

1 1 1 1

The normal to the curve y(x 2)(x 3) = x + 6

at the point where the curve intersects the

that a + b + c = 3 and

f(x + y) = f(x) + f(y) + xy, x, y R,

then

10

f(n)

n 1

is equal to :

(1) , (2) ,

2 3 2 2 (1) 255 (2) 330 (3) 165 (4) 190

Ans. (2)

1 1 1 1 Sol. f(x) = ax2 + bx + c

(3) , (4) ,

2 2 2 3 f(1) = a + b + c = 3

Ans. (3) Now f(x + y) = f(x) + f(y) + xy

put y = 1

x6 f(x + 1) = f(x) + f(1) + x

Sol. y = (x 2)(x 3) f(x + 1) = f(x) + x + 3

Now

Point of intersection with yaxis (0, 1) f(2) = 7

f(3) = 12

(x 2 5x 6)(1) (x 6)(2x 5) Now

y

(x 2 5x 6)2 Sn = 3 + 7 + 12 + ..... tn ...(1)

y= 1 at point (0, 1) Sn = 3 + 7 + ......tn 1 + tn ...(2)

Slope of normal is 1 On subtracting (2) from (1)

Hence equation of normal is x + y = 1 tn = 3 + 4 + 5 + ....... upto n terms

1 1

, satisfy it. (n 2 5n)

2 2 tn =

2

40. A hyperbola passes through the point

tangent to this hyperbola at P also passes

Sn = tn = 2

through the point :

(1) 2, 3 (2) 3 2, 2 3 1 n(n 1)(2n 1) 5n(n 1)

Sn

2 6 2

(3) 2 2, 3 3 (4) 3, 2

S10 = 330

Ans. (3)

12

CODE-B

Let a 2i j 2k and b i j . Let c be a

AB 1

42. Sol.

AP 2

vector such that | c a | = 3, (a b) c = 3 and Let APC =

the angle between c and a b be 30. Then ac AC 1 AB 1 1

tan = = = AC AB

is equal to : AP 2 AP 4 2

B

1 25

(1) (2) (3) 2 (4) 5

8 8

C

Ans. (3)

A P

Sol. a 2i j 2k , b i j and | a | 3 Now

tan tan

a b 2i 2j k tan( )

1 tan tan

|ab| 3

Now : ( a b ) c = | a b | | c | sin 30 n

tan tan 1

1 tan tan 2

AB

tan( ) AP

1

tan( )

2

1

|( a b ) c | = 3| c | 2

2 on solving tan =

9

3 = 3| c | off a flower-bed in the form of a circular sector.

2

Then the maximum area (in sq. m) of the flower

-bed, is :-

| c | = 2

(1) 30 (2) 12.5 (3) 10 (4) 25

Now : | c a | = 3

Ans. (4)

c2 + a2 2 ca 9

Sol. Total length = r + r + r = 20

4 + 9 2ac 9

20 2r

r

ac 2

Area = r r

2 2 r

level ground. Let C be the mid-point of AB and r

P be a point on the ground such that AP = 2AB. A = 10r r2

If BPC = , then tan is equal to :-

dA

4 6 1 2 0 10 2r = 0, r = 5

(1) (2) (3) (4) dr

9 7 4 9

Ans. (4) A = 50 25 = 25

13

JEE(MAIN)-2017

3 n

4

47. Let I n tan x dx,(n 1) . I4 + I6 = a tan5x + bx5

dx + C, where C is a constant of integration, then

45. The integral 1 cos x is equal to :-

the ordered pair (a, b) is equal to :-

4

1 1 1 1

(1) 1 (2) 2 (3) 2 (4) 4 (1) ,0 (2) ,1 (3) ,0 (4) , 1

5 5 5 5

Ans. (3)

Ans. (3)

3

4

4

Sol. I4 + I6 = (tan x tan 6 x) dx = tan

4

x sec 2 x dx

dx

I

Sol. 1 cos x ...(1)

1 1

4 = tan5 x + c a= ,b=0

5 5

3

48. Let be a complex number such that

4

dx 2 + 1 = z where z = 3 . If

I

1 cos x ...(2)

1 1 1

4

1 1 2 3k,

2

Adding (1) and (2)

3

1 2 7

4

2 then k is equal to :-

2I 2 dx

sin x (1) 1 (2) z (3) z (4) 1

4 Ans. (2)

3 Sol. Here is complex cube root of unity

4

R1 R1 + R2 + R3

I cosec 2 x dx

4 3 0 0

2 2

= 1 1

3 / 4

I cot x / 4 2

1 2

dy

46. If (2 sin x) (y 1)cos x 0 and y(0) = 1,

dx = 3(1 ) = 3z k = z

49. The value of

then y is equal to :-

4 1 2 1 (21C3 10C3) + (21C4 10C4) + .... +

(1) (2) (3) (4) (21C10 10C10) is :-

3 3 3 3

Ans. (2) (1) 220 210 (2) 221 211

dy (3) 221 210 (4) 220 29

Sol. (2 + sinx) (y 1)cos x 0 Ans. (1)

dx

Sol. (21C1 + 21C2 .........+ 21C10)

d

(2 sin x)(y 1) 0 (10C1 + 10C2 ......... 10C10)

dx

(2 + sinx) (y + 1) = c 1 21 21 C

= [( C1 + ....+ 10 ) + (21C11 +..... 21C20)]

x = 0, y = 1 c = 4 2

4 (210 1)

y 1

2 sin x 1 21

= [2 2] (210 1)

4 1 2

y 1

2 3 3 = (220 1) (210 1) = 220 210

14

CODE-B

cot x cos x x 1 y2 z 3

lim Sol. Line PQ ; = =

50. x

( 2x)3 equals :- 1 4 5

2

Let F( + 1, 4 2, 5 + 3)

1 1 1 1

(1) (2) (3) (4)

4 24 16 8 P(1,2,3)

Ans. (3)

cot x(1 sin x)

lim 3

Sol. x

2

8 x F

2

tan x 1 cos x

2 2 Q

lim 2

= x

2 8 x x

2 2 F lies on the plane

1 1 1 2( + 1) + 3(4 2) 4(5 + 3) + 22 = 0

= 1 =

8 2 16 6 + 6 = 0 =1

51.

of cos4x is :-

(1)

7

(2)

3

(3)

1

If 5(tan2x cos2x) = 2cos 2x + 9, then the value

(4)

2

F (2, 2, 8)

PQ = 2 PF = 2 42 .

9 5 3 9

53. The distantce of the point (1, 3, 7) from the

Ans. (1) plane passing through the point (1, 1, 1),

having normal perpendicular to both the lines

1 t

Sol. 5 t = 2(2t 1) + 9 {Let cos2 x = t}

x 1 y 2 z 4 x 2 y 1 z 7

t and , is :-

1 2 3 2 1 1

5(1 t t2) = t(4t + 7)

9t2 + 12t 5 = 0 10 20

(1) (2)

9t2 + 15t 3t 5 = 0 74 74

(3t 1) (3t + 5) = 0 10 5

(3) (4)

1 5 83 83

t = as t .

3 3

Ans. (3)

1 1

cos 2x = 2 1 = Sol. Normal vector

3 3

2

1 7 i j k

cos 4x = 2 1 =

3 9 1 2 3 = 5i 7j 3k

52. If the image of the point P(1, 2, 3) in the plane, 2 1 1

2x + 3y 4z + 22 = 0 measured parallel to line,

x y z So plane is 5(x 1) + 7(y + 1) + 3(z + 1) = 0

is Q, then PQ is equal to :-

1 4 5

5x + 7y + 3z + 5 = 0

(1) 6 5 (2) 3 5

(3) 2 42 (4) 5 21 21 5 10

42 Distance =

25 49 9 83

Ans. (3)

15

JEE(MAIN)-2017

1 2 2

54. If for x 0, , the derivative of x2 y

4 2

6x x 2 2

tan 1 4 y y

3 is x g(x) , then g(x) equals :- 2

1 9x

2

3 9 3x x 3x y 2 y 2 1 40

(1) 3 (2) 3 (3) 3 (4)

2

1 9x 1 9x 1 9x 1 9x3

2 2

Ans. (2) 2 1 4 4 0

6x x 2

1

Sol. Let y = tan1 3 where x

0,

1 9x 4 42 4 1 22 16 0

2.(3x 3 / 2 ) 22 4 15 0

= tan1 3 / 2 = 2 tan

1 (3x3/2)

1 (3x )

4 16 120 4 2 34

3 4 4

As 3x3/2 0,

8

2 34 34 2

dy 1 3

=2 3 3 x1/2 2 2

dx 1 9x 2

34 2

9 r

= x 2 2

1 9x 3

which is not in options therefore it must be

9 bonus. But according to history of JEE-Mains

g(x) =

1 9x3 it seems they had following line of thinking.

55. The radius of a circle, having minimum area, Given curves are y = 4 x2 and y = |x|

which touches the curve y = 4 x2 and the lines,

y = |x| is :- (0, 4)

(1) 4 2 1 (2) 2 2 1

(0,4r)

(3) 2 2 1 (4) 4 2 1

Ans. (Bonus or 4)

Sol.

4 2 2 4 There are two circles satisfying the given

conditions. The circle shown is of least area.

2

Let radius of circle is 'r'

co-ordinates of centre = (0, 4 r)

4

circle touches the line y = x in first quadrant

0 (4 r)

=r r4=r 2

x2 + (y )2 = r2 2

xy =0 4

r= = 4 ( 2 1)

0 2 1

r r 2 which is given in option 4.

2

16

CODE-B

56. A box contains 15 green and 10 yellow balls. 58. If two different numbers are taken from the set

If 10 balls are randomly drawn, onebyone, {0, 1, 2, 3, ......., 10), then the probability that

with replacement, then the variance of the

number of green balls drawn is :- their sum as well as absolute difference are both

multiple of 4, is :-

6 12

(1) (2) (3) 6 (4) 4

25 5 7 6

Ans. (2) (1) (2)

55 55

Sol. We can apply binomial probability distribution

Variance = npq 12 14

3 2 12 (3) (4)

55 45

= 10 =

5 5 5

Ans. (2)

57. The eccentricity of an ellipse whose centre is

Sol. Let A {0, 1,2 ,3 ,4 ......, 10 }

1

at the origin is . If one of its directices is n(s) = 11C2 (where 'S' denotes sample space)

2

Let E be the given event

x= 4, then the equation of the normal to it at

E {(0, 4), (0, 8), (2, 6), (2, 10), (4, 8), (6, 10)}

3

1, is :- n(E) = 6

2

(1) x + 2y = 4

(3) 4x 2y = 1

Ans. (3)

(2) 2y x = 2

(4) 4x + 2y = 7

1 59.

P(E) =

6

55

For three events A, B and C,

Sol. Eccentricity of ellipse = P(Exactly one of A or B occurs)

2

= P(Exactly one of B or C occurs)

1

= P(Exactly one of C or A occurs) = and

(0, 0) 4

x = 4 x=4 1

P(All the three events occur simultaneously) = .

16

a 1

Now, =4 a=4 =2

e 2 Then the probability that at least one of the

1 events occurs, is :-

b2 = a2(1 e2) = a2 1 = 3

4

Equation of ellipse 3 7 7 7

(1) (2) (3) (4)

16 32 16 64

x2 y2

+ 1

4 3 Ans. (3)

x 2y 3x P(exactly one of A or B occurs)

+ y' = 0 y' =

2 3 4y

1

3 2 1 = P(A) + P(B) 2P(A B) =

y ' |(1,3 / 2) 4

4 3 2

3 P(Exactly one of B or C occurs)

Equation of normal at 1,

2

1

3 = P(B) + P(C) 2P(B C) =

y = 2(x 1) 2y 3 = 4x 4 4

2

4x 2y = 1 P(Exactly one of C or A occurs)

17

JEE(MAIN)-2017

Ans. (3)

1

= P(C) + P(A) 2P(C A) =

4 2 3

Sol. Given A =

Adding all, we get 4 1

3

2P(A) 2P(A B) = 16 9

4 3A2 =

12 13

3

P(A) P(A B) =

8 24 36

12A =

48 12

1

Now, P(A B C) = (Given)

16

72 63

P(A B C) 3A2 + 12A =

84 51

= P(A) P(A B) + P(A B C)

3 1 7 51 63

= + = adj (3A2 + 12A) =

60.

8 16

2 3

If A

16

, then adj (3A 2 + 12A) is equal

4 1

84 72

to :-

72 63 72 84

(1) 84 51

(2) 63 51

51 63 51 84

(3) 84 72 (4) 63 72

18

CODE-B

PART C CHEMISTRY

61. Which of the following compounds will 63. The increasing order of the reactivity of the

significant amont of meta product during following halides for the S N1 reaction is

mono-nitration reaction ? CH3CHCH2CH3 CH3CH2CH2Cl

OH OCOCH 3 Cl

(I) (II)

(1) (2)

p-H3COC6H4CH2Cl

NH2 NHCOCH 3 (III)

(1) (III) < (II) < (I) (2) (II) < (I) < (III)

(3) (4) (3) (I) < (III) < (II) (4) (II) < (III) < (I)

Ans. (2)

Ans. (3) Sol. For any S N1 reaction reactivity is decided by

Sol. (i) Nitration is carried out in presence of ease of dissociation of alkyl halide

concentrated HNO3 + concentrated H2SO4.

R X

R X

(ii) Aniline acts as base. In presence of H2SO4

NH2

+

NH3 HSO4

its protonation takes place and anilinium

ion is formed

Higher the stability of R (carbocation) higher

would be reactivity of S N1 reaction.

Since stability of cation follows order.

+

CH3 CH 2 CH 2

H

H2SO4 CH 3 CH CH 2 CH3

(iii) Anilinium ion is strongly deactivating p H 3CO C 6 H 4 CH 2

group and meta directing in nature so it

Hence correct order is

give meta nitration product in significant

amount. II I III

+

NH2 NH3 HSO4 64. The radius of the second Bohr orbit for

hydrogen atom is :

conc.H2SO4

+ conc. HNO3 (Plank's const. h = 6.6262 1034 Js ; mass of

62. U is equal to e = 1.60210 1019 C ; permittivity of vaccum

(1) Isochoric work (2) Isobaric work

= 8.854185 1012 kg1 m3 A2)

(3) Adiabatic work (4) Isothermal work

Ans. (3) (1) 1.65 (2) 4.76

Sol. From 1st law : (3) 0.529 (4) 212

U = q + w

Ans. (4)

For adiabatic process :

q=0 Sol. Radius of nth Bohr orbit in H-atom

U = w = 0.53 n2

Work involve in adiabatic process is at the

expense of change in internal energy of the Radius of II Bohr orbit = 0.53 (2)2

system. = 2.12

19

JEE(MAIN)-2017

65. pKa of a weak acid (HA) and pKb of a weak Total weight of person = 75 kg

base (BOH) are 3.2 and 3.4, respectively. The

pH of their salt (AB) solution is 10

Mass due to 1H is = 75 7.5kg

(1) 7.2 (2) 6.9 100

(3) 7.0 (4) 1.0 1H atoms are replaced by 2H atoms.

Ans. (2) So mass gain by person =7.5 kg

Sol. Given

68. Which of the following , upon treatment with

pKa (HA) = 3.2 tert-BuONa followed by addition of bromine

pKb (BOH) = 3.4 water, fails to decolourize the colour of

As given salt is of weak acid and weak bas bromine ?

O C6H5

1 1

pH = 7 + pK a pK b (1) (2)

2 2 Br Br

O

1 1 O

=7+ (3.2) (3.4)

2 2 (3) (4)

Br Br

66.

= 6.9

The formation of which of the following

polymers involves hydrolysis reaction ?

(1) Nylon 6 (2) Bakelite

Ans. (1)

68. Ans.(1)

O O

(3) Nylon 6, 6 (4) Terylene tert-BuONa

Br O-tBu

Sol. Formation of Nylon-6 involves hydrolysis of

its monomer (caprolactum) in initial state.

(fails to decolorise the

colour of bromine)

O

NH O

Hydrolysis +

H3NCH2CH2CH2CH2CH2CO C 6H5 C 6H 5

tert-BuONa

Caprolactum

/Polymerization

Br

O (it decolorises

bromine solution)

HN ( CH2 )5 C

n

Nylon-6

O O

67. The most abundant elements by mass in the tert-BuONa

body of a healthy human adult are :

Br

Oxygen (61.4%) ; Carbon (22.9%), Hydrogen (it decolorises bromine

(10.0%) ; and Nitrogen (2.6%). The weight solution due to

which a 75 kg person would gain if all 1H atoms unsaturation)

are replaced by 2H atoms is

(1) 15 kg (2) 37.5 kg

(3) 7.5 kg (4) 10 kg O O

Ans. (3) tert-BuONa

Sol. Mass in the body of a healthy human adult

Br

has :-

(it decolorises bromine

Oxygen = 61.4%, Carbon = 22.9%, solution due to

Hydrogen = 10.0% and Nitrogen = 2.6% unsaturation).

20

CODE-B

69. In the following reactions, ZnO is respectively

CH3

acting as a/an : CH3

(a) ZnO + Na2O Na2ZnO2 Br H

H Br

(b) ZnO + CO2 ZnCO3 H 3C H

H CH3

(1) base and acid (2) base and base Et

(3) acid and acid (4) acid and base Et

(I) (II)

Ans. (4)

Sol. Although ZnO is an amphoteric oxide but in CH3 CH3

given reaction.

Br H H Br

(A) ZnO + Na2O Na2ZnO2 H CH3 H3 C H

acid base salt

Et Et

(B) ZnO + CO2 ZnCO3

(III) (IV)

base acid salt

70. Both lithium and magnesium display several 72. A metal crystallises in a face centred cubic

similar properties due to the diagonal structure. If the edge length of its unit cell is

relationship ; however, the one which is 'a', the closest approach between two atoms in

incorrect is :

(1) Both form basic carbonates

(2) Both form soluble bicarbonates

(3) Both form nitrides

metallic crystal will be :-

(1) 2a (2) 2 2 a

a

(4) Nitrates of both Li and Mg yield NO2 and (3) 2a (4)

2

O2 on heating

Ans. (1) Ans. (4)

Sol. Mg can form basic carbonate like Sol. In FCC unit cell atoms are in contant along face

5Mg + +2

6CO32 + 7H2O diagonal

4MgCO3 . Mg(OH)2 . 5H2O + 2HCO3 So, 2 a 4R

closest distance (2R) =

basic carbonate. 2 2

73. Two reactions R1 and R2 have identical pre-

71. 3-Methyl-pent-2-ene on reaction with HBr in

presence of peroxide forms an addition product.

exceeds that of R2 by 10 kJ mol1. If k1 and k2

The number of possible stereoisomers for the

are rate constants for reactions R 1 and R 2

product is :-

respectively at 300 K, then ln(k2/k1) is equal to :-

(1) Six (2) Zero

(R = 8.314 J mol1K1)

(3) Two (4) Four

(1) 8 (2) 12

Ans. (4)

(3) 6 (4) 4

Sol.

Ans. (4)

2 4 Ea

3 5

1

HBr K A.e RT

+H2 O2

(4 stereo isomers possible E a / RT

due to 2 chiral centre as K 2 A.e 2 .....(2)

molecule is nonsymmetric)

21

JEE(MAIN)-2017

75. The Tyndall effect is observed only when

( Ea 1 Ea 2 )

K following conditions are satisfied :-

so, equation (2)/(1) 2 e RT

K1 (a) The diameter of the dispersed particles is

much smaller than the wavelength of the

(As pre-exponential factors of both reactions

ligh used.

is same)

(b) The diameter of the dispersed particle is not

K E E a2 10,000

ln 2 a1 4 much smaller than the wavelength of the

K1 RT 8.314 300

light used.

74. The correct sequence of reagents for the (c) The refractive indices of the dispersed phase

following conversion will be :- and dispersion medium are almost similar

in magnitude.

(d) The refractive indices of the dispersed phase

and dispersion medium differ greatly in

magnitude.

(1) (a) and (d) (2) (b) and (d)

(3) (a) and (c) (4) (b) and (c)

Ans. (2)

(1) [Ag(NH3)2]+ OH, H+/CH3OH, CH3MgBr As per NCERT book (fact)

(2) CH3MgBr, H+/CH3OH, [Ag(NH3)2]+ OH 76. Which of the following compounds will

(3) CH3MgBr, [Ag(NH3)2]+ OH, H+/CH3OH behave as a reducing sugar in an aqueous KOH

solution ?

(4) [Ag(NH3)2]+ OH, CH3MgBr, H+/CH3OH

Ans. (1)

Sol. (1)

O O

[Ag(NH3)2]OH

Tollens reagent

CHO CO2H

+

H /CH 3OH (2)

(esterification)

C (3)

O OCH3

CH3MgBr

CH3

(4)

H 3CCCH 3

Ans. (1)

OH

22

CODE-B

Sol. (1) Ester in presence of Aqueous KOH solution 78. Which of the following reactions is an example

give SNAE reaction so following reaction takes of a redox reaction ?

place

(1) XeF4 + O2F2 XeF6 + O2

HOCH2 CH2OH HOCH2 CH2OH (2) XeF2 + PF5 [XeF]+PF6

O Aq. KOH O O

O AE

SN + MeCO (3) XeF6 + H2O XeOF4 + 2HF

OCMe O

OH OH

(4) XeF6 + 2H2O XeO2F2 + 4HF

Ring opening

Sol. In the reaction

HOCH 2 O

CH2OH

4 1 6

Tollen's

ve silver Reagent O X eF4 O2 F2 X eF6 O20

mirror

test OH

Xenon undergoes oxidation while oxygen

(2) In above compound in presence of Aq. undergoes reduction.

KOH (SN AE ) reaction takes place & 79. The products obtained when chlorine gas reacts

-Hydroxy carbonyl compound is formed with cold and dilute aqueous NaOH are :-

which give ve Tollen's test So this compound

(1) ClO and ClO3

behave as reducing sugar in an aqueous KOH

solution.

(2) ClO2 and ClO3

77. Given

C(grahite) + O2(g) CO2(g) ; (3) Cl and ClO

rH = 393.5 kJ mol1

(4) Cl and ClO2

1

H 2 (g) O 2 (g) H 2 O(l); Ans. (3)

2

rH = 285.8 kJ mol1 Sol.

CO2(g) + 2H2O(l) CH4(g) + 2O2(g);

rH = +890.3 kJ mol1

Based on the above thermochemical equations, 80. The major product obtained in the following

the value of rH at 298 K for the reaction reaction is :-

C(grahite) + 2H2(g) CH4(g) will be :-

Br

(1) +74.8 kJ mol1 (2) +144.0 kJ mol1 H

C6H 5 BuOK

(3) 74.8 kJ mol1 (4) 144.0 kJ mol1

C6H 5

Ans. (3)

Sol. CO2(g)+2H2O() CH4(g)+2O2(g);rH= 890.3

(1) C6 H5 CH O t Bu CH2 CH 6 H5

fH 393.5 285.8 ? 0

(2) C6H5CH=CHC6H5

rH = ( H)

f products ( f H)Re actan ts

(3) (+)C6H5CH(OtBu)CH2H5

890.3 1 ( f H) CH4 2 0 1 (393.5) 2(285.8)

(4) ()C6H5CH(OtBu)CH2C6H5

( f H)CH 4 890.3 965.1 74.8 kJ / mol Ans. (2)

23

JEE(MAIN)-2017

Sol. Elimination reaction is highly favoured if Sol. NO One unpaired electron is present in *

(a) Bulkier base is used molecular orbital.

(b) Higher temperature is used CO No unpaired electron is present

Hence in given reaction biomolecular O2 Two unpaired electrons are present in *

ellimination reaction provides major product. molecular orbitals.

C6H5 bonding molecular orbitals.

C6 H 5

C6 H 5 +tBuOH +Br

C6H5 83. The freezing point of benzene decreases by

H H 0.45C when 0.2 g of acetic acid is added to

t 20 g of benzene. If acetic acid associates to

O Bu

form a dimer in benzene, percentage

81. Sodium salt of an organic acid 'X' produces association of acetic acid in benzene will be :-

effervescence with conc. H2SO4. 'X' reacts with (Kf for benzene = 5.12 K kg mol1)

the acidified aqueous CaCl2 solution to give a (1) 64.6% (2) 80.4%

white precipitate which decolourises acidic (3) 74.6% (4) 94.6%

solution of KMnO . 'X' is :- Ans. (4)

4

Sol. In benzene

(1) C6H5COONa 2CH3COOH (CH3COOH)2

(2) HCOONa 1

i = 1 1

(3) CH3COONa 2

(4) Na2C2O4

i = 1 Here is degree of association

2

Ans. (4)

Tf iK f m

Sol.

0.2

1 5.12 60

0.45= 2 20

1000

1 0.527

2

= 0.945

% degree of association = 94.5%

84. Which of the following molecules is least

resonance stabilized ?

82. Which of the following species is not

paramagnetic :-

(1) (2)

(1) NO (2) CO O

(3) O2 (4) B2

Ans. (2) (3) (4)

N O

Ans. (4)

24

CODE-B

Number of Cl present in ionization sphere =

O Mole of ion precipitated with exess AgNO3 0.02

2

mole of complex 0.01

Sol. (4) is nonaromatic and hence least It means 2Cl ions present in ionization sphere

complex is [Co(H2O)5Cl]Cl 2.H2O

86. The major product obtained in the following

reasonance stabilized reaction is :-

O

O

(1) Benzene is aromatic

DIBAL H

O

OH

(3)

N

pyridine is aromatic

(1)

COOH

CHO

CoCl 3 . 6H2O with excess AgNO3; 1.2 1022 OH

ions are precipitated. The complex is :-

CHO

(1) [Co(H2O)4 Cl2]Cl.2H2O (2)

CHO

(2) [Co(H2O)3Cl3].3H2O

(3) [Co(H2O)6]Cl 3

(4) [Co(H2O)5Cl]Cl 2.H2O CHO

(3)

Ans. (4)

COOH

Molarity volume(ml)

Sol. Moles of complex =

1000

CHO

100 0.1 (4)

= = 0.01 mole

1000 CHO

1.2 10 22 Sol. DIBAL H is electrophilic reducing agent

AgNO3 = reduces cynide, esters, lactone, amide,

6.02 10 23

carboxylic acid into corresponding Aldehyde

= 0.02 moles (partial reduction)

25

JEE(MAIN)-2017

87. A water sample has ppm level concentration of 89. Given

following anions

E oCl / Cl

o

1.36 V, E Cr 3

/ Cr

0.74 V

2

the anion/anions that make / makes the water E oCr O2 / Cr3 1.33 V, E oMnO / Mn2 1.51V .

2 7 4

Among the following, the strongest reducing

(1) only NO3 (2) both SO24 and NO3 agent is

Sol. NO3: The maximum limit of nitrate in drinking Ans. (1)

water is 50 ppm. Excess nitrate in drinking

water can cause disease. Such as Sol. E oMnO / Mn 2 1.51V ..(i)

4

methemoglobinemia.

2 2

SO4 : above 500 ppm of SO4 ion in drinking E oCl / Cl

1.36 V ..(ii)

2

moderate levels it is harmless

F : Above 2ppm concentration of F in

drinking water cause brown mottling of teeth.

E oCr O 2 / Cr 3 1.33 V

2 7

E oCr 3 / Cr 0.74

..(iii)

..(iv)

2 Since Cr+3 is having least reducing potential,

4

& NO3 in water is suitable for drinking but the so Cr is the best Reducing agent.

concentration of F (i.e 10 ppm) make water 90. The group having isoelectronic species is :-

2 + 2+

unsuitable for drinking purpose : (1) O , F , Na , Mg

+

88. 1 gram of a carbonate (M2CO3) on treatment (2) O , F , Na , Mg

with excess HCl produces 0.01186 mole of

(3) O2 , F , Na , Mg2+

CO2. the molar mass of M2CO3 in g mol1 is :- + 2+

(1) 1186 (2) 84.3 (4) O , F , Na , Mg

(3) 118.6 (4) 11.86 Ans. (1)

Sol. Given chemical eqn 2 + +2

M2CO3 + 2HCl 2MCl + H2O + CO2 ions O F Na Mg

1gm 0.01186mol Atomic number = 8 9 11 12

from the balanced chemical eqn.

No. of e = 10 10 10 10

1 2 + +2

0.01186 therefore O , F , Na , Mg are isoelectronic

M

M 84.3 gm/mol

26

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