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1. Let f x 9x 3 x 1 x ,1 , then range of f(x) is ([.] denotes the greatest integer function)
(A) {0, 1, 2, 3, 4, 5, 6} (B) {0, 1, 2, 3, 4, 5, 6, 7}
(C) {1, 2, 3, 4, 5, 6} (D) {1, 2, 3, 4, 5, 6, 7}
2. If f(2x + 3y, 2x 7y) = 20x, then f(x, y) equals
(A) 7x 3y (B) 7x + 3y (C) 3x 7y (D) 3x + 7y
cos x 1 cos x ex
3. The integer n for which lim is a finite non-zero number is
x 0 xn
(A) 1 (B) 2 (C) 3 (D) 4

4. If lim
x 4

x 2 1 ax 2 b 0, then

(A) a = 1, b = 2 (B) a = 1, b = 1 (C) a = 1, b = 1/2 (D) none of these

x y f x f y
5. Let f:R R be a function such that f , f 0 3 and f 0 3, then
3 3
f x
(A) is differentiable in R (B) f(x) is continuous but not differentiable in R
(C) f(x) is continuous in R (D) f(x) is bounded in R

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cos x , x 1
6. If f x ([.] denotes the greatest integer function), then f(x) is
x 2 , 1 x 2
(A) continuous and non-differentiable at x = 1 and x = 1
(B) continuous and differentiable at x = 0
(C) discontinuous at x = 1/2
(D) continuous but not differentiable at x = 2
7. The value of m for which the area of the triangle included between the axes and any tangent to the
curve xmy = bm is constant, is
(A) 1 (B) 2 (C) 3 (D) 4
3 2 2
8. Let f(x) = x + ax + bx + 5sin x be an increasing function in the set of real numbers R. Then, a and
b satisfy the condition
(A) a2 3b 15 > 0 (B) a2 3b + 15 > 0
(C) a2 3b + 15 < 0 (D) a > 0 and b > 0
9. The coordinate of the point on y = 8x, which is closest from x2 + (y + 6)2 = 1 is/are

(A) (2, 4) (B) (18, 12) (C) (2, 4) (D) none of these
10. 3/ 4
dx is equal to

x2 x4 1
1/ 4 1/ 4 1/4
1 1/ 4 1 1
(A) 1 4
(B) x 4 1 c (C) 1 4
c (D) 1 4

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sin n x
11. The value of the integral 0 dx n N is
sin x / 2
(A) (B) 2 (C) 3 (D) none of these
12. If [x] denotes the greatest integer less than or equal to x, then 0 e x dx is equal to

(A) loge2 (B) e2 (C) 0 (D)
13. If z = rei, then |eiz| is equal to
(A) er sin (B) rer sin (C) er cos (D) rer cos
14. If |z1 1| < 1, |z2 2| < 2, |z3 3| < 3, then |z1 + z2 + z3|
(A) is less than 6 (B) is more than 3 (C) is less than 12 (D) lies between 6 and 12
15. If xy = 2(x + y), x y and x, y N, the number of solutions of the equation
(A) two (B) three (C) no solution (D) infinitely many solutions
16. The system of equation |x 1| + 3y = 4, x |y 1| = 2 has
(A) no solution (B) a unique solution (C) two solution (D) more than two solutions
17. Three positive numbers form an increasing GP. If the middle term in this GP is doubled, then new
numbers are in AP. Then, the common ratio of the GP is
(A) 2 3 (B) 3 2 (C) 2 3 (D) 2 3

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18. If a1, a2, ..., an are positive real numbers whose product is a fixed number c, then the minimum value
of a1 + a2 + ... + an1 + 2an is
(A) n(2c)1/n (B) (n + 1)c1/n (C) 2nc1/n (D) (n + 1) (2c)1/n
Hence, minimum value of a1 + a2 + ... + an1 +2an is n(2c)1/n.
19. The remainder obtained, when 1! + 2! + 3! + ... + 175! is divided by 15 is
(A) 5 (B) 0 (C) 3 (D) 8
20. Let A = {x1, x2, x3, x4, x5, x6}, B = {y1, y2, y3, y4, y5, y6}. Then the number of one-one mappings from A
to B such that f(xi) yi, i = 1, 2, 3, 4, 5, 6 is
(A) 720 (B) 265 (C) 360 (D) 145
30 30 30 30 30 30 30 30 n
21. The value of , where n Cr ,
0 10 1 11 2 12 20 30 r
30 30 60 31
(A) (B) (C) (D)
10 15 30 10
22. The equations x y = 2, 2x 3y = , 3x 2y = 1 are consistent for
(A) = 4 (B) = 1, 4 (C) = 1 (D) = 1, 4
1 0
23. If A and A2 = 8A + kl2, then k is equal to
1 7
(A) 1 (B) 1 (C) 7 (D) 7
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24. Two small squares on a chess board are chosen at random. Probability that they have a common
side is
1 1 1 5
(A) (B) (C) (D)
3 9 18 18
25. The number of integral values of m for which the x coordinate of the point of intersection of the lines
3x + 4y = 9 and y = mx + 1 is also an integer is
(A) 2 (B) 0 (C) 4 (D) 1
2 2 2
26. Let AB be a chord of the circle x + y = r subtending a right angle at the centre, then the locus of
the centroid of the triangle PAB as p moves on the circle is
(A) a parabola (B) a circle (C) an ellipse (D) a pair of straight line
27. PQ is any focal chord of the parabola y = 32x. The length of PQ can never be less than
(A) 8 unit (B) 16 unit (C) 32 unit (D) 48 unit
x2 y3 z5
28. The point on the line at a distance of 6 from the point (2, 3, 5) is
1 2 2
(A) (3, 5, 3) (B) (4, 7, 9) (C) (0, 2, 1) (D) (3, 2, 1)
2 4
29. If x y cos z cos , then xy + yz + zx is equal to
3 3
(A) 1 (B) 0 (C) 1 (D) 2

30. The number of real solutions of tan1 x x 1 sin1 x2 x 1 2 is

(A) zero (B) one (C) two (D) infinite

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31. In a U-tube in which the cross sectional area of the limb on the left is one quarter of
that on the right. The limb on the right contains mercury (density 13.6 g/cm3), and
the level of mercury in the narrow limb is at a distance of 36 cm from the upper end
of the tube. What will be the rise in the level of mercury in the right limb if the left
limb is filled to the top with water?
(A) 1.2 cm (B) 2.35 cm (C) 0.56 cm (D) 0.8 cm
32. A cube is compressed at 0C equally from all sides by an external pressure P. By what amount
should its temperature be raised to bring it back to the size it had before the external pressure was
applied? (Given: K is bulk modulus of elasticity of the material of the cube and is the coefficient of
linear expansion; =12 106/K)
P P 3 K
(A) (B) (C) (D)
K 3K P 3P
33. Water rises to a height h in a capillary tube of cross sectional area A, the height to which water will
rise in a capillary tube of cross-sectional area 4A will be
(A) h (B) h/2 (C) h/4 (D) 4h
34. The energy spectrum of a black body exhibits a maximum around a wavelength 0. The temperature
of the black body is now changed such that the energy is maximum around a wavelength 3 0/4. The
power radiated by the black body will now increase by a factor of
(A) 256/81 (B) 64/27 (C) 16/9 (D) 4/3

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35. Two moles of an ideal monoatomic gas undergoes a cyclic process as shown
in the figure. The temperatures in different states are given as
6T1 = 3T2 = 2T4 = T3 = 1800 K. Determine the work done by the gas during
the cycle.
(A) 10 kJ
(B) 20 kJ
(C) 15 kJ
(D) 30 kJ
36. A pendulum of length L and bob of mass M has a spring of force constant k
connected horizontally to it at a distance h below its point of suspension. The
rod is in equilibrium in vertical position. The rod of length L used for vertical
suspension is rigid and massless. The frequency of vibration of the system
for small values of is

1 kh 1 mgL k mL2 1 kh2

(A) gL (B) (C) 2 (D) gL
2L m 2 L m mgL kh 2L m
37. A boy is walking away from a wall at a speed of 1.0 m/s in a direction
at right angles to the wall. The boy blows a whistle steadily. An
observer towards whom the boy is moving hears 4 beats/s. If the
speed of sound is 340 m/s, the frequency of whistle is
(A) 480 Hz (B) 680 Hz (C) 840 Hz (D) 1000 Hz

38. An electric field is expressed as E 2i 3j. Find the potential difference (VA VB) between two
points A and B whose position vectors are given by rA i 2j and rB 2i j 3k.

(A) 1 V (B) 1 V (C) 2 V (D) 3 V
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39. A parallel plate air capacitor is charged to 100 V and is then connected to an identical capacitor in
parallel. The second capacitor has some dielectric medium between its plates. If the common
potential is 20 V, the dielectric constant of the medium is
(A) 2.5 (B) 4 (C) 5 (D) 8
40. In a series RC circuit a steady state charge of 10C is established in time of 10 ms. If 1 ms is the
time constant of the circuit and 3C is the charge at any instant for the growth part then the decay
charge in the circuit is
(A) qd = 3C (B) qd = 7C (C) qd = 3C (D) qd = 7C
41. A current in a coil of self-inductance 2.0 H is increasing as i = 2 sin t2. The amount of energy spend
during the period when the current changes from 0 to 2 A is
(A) 1 J (B) 2 J (C) 3 J (D) 4 J
42. A particle of charge q and mass m starts moving from the origin under the action of an electric

field E E i and B B i with a velocity v v j. The speed of the particle will become 2v0 after a
0 0 0

2mv 0 2Bq 3Bq 3mv 0
(A) t (B) t (C) t (D) t
qE mv 0 mv 0 qE
43. An ideal choke takes a current of 10 A when connected to an ac supply of 125 V and 50 Hz. A pure
resistor under the same conditions takes a current of 12.5 A. If the two are connected to an ac
supply of 100 V and 40 Hz, then the current in series combination of above resistor and inductor is
(A) 10 A (B) 12.5 A (C) 20 A (D) 25 A
44. A stone of mass 1 kg tied to a light inextensible string of length L = 10/3 m is whirling in a circular
path of radius L in a vertical plane. If the ratio of the maximum tension in the string to the minimum
tension is 4 and if g is taken to be 10 m/s2, the speed of the stone at the highest point of the circle is
(A) 10 m/s (B) 5 3 m/ s (C) 10 3 m/s (D) 20 m/s

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45. Two blocks of masses m1 = 2 kg and m2 = 4 kg are moving in the same direction with speeds
v 1 = 6 m/s and v2 = 3 m/s, respectively on a frictionless surface as shown in figure. An ideal spring
with spring constant k = 30000 N/m is attached to the back side of m2. Then the maximum
compression of the spring after collision will be

(A) 0.06 m (B) 0.04 m (C) 0.02 m (D) none of these

46. A smooth sphere is moving on a horizontal surface with velocity vector 2i 2j immediately before it
hits a vertical wall. The wall is parallel to j vector and the coefficient of restitution between the
sphere and the wall is e = 1/2. The velocity vector of the sphere after it hits the wall is
(A) i j (B) i 2j (C) i j (D) 2i j
47. A solid sphere rests on a horizontal surface. A horizontal impulse is
applied at height h from centre. The sphere starts rotating just after the
application of impulse. The ratio h/r will be
1 2 1 2
(A) (B) (C) (D)
2 5 5 3
48. A uniform circular disc of radius r is placed on a rough horizontal
surface and given a linear velocity v0 and angular velocity 0 as
shown. The disc comes to rest after moving some distance to the
right. It follows that
(A) 3v 0 20r (B) 2v 0 0r
(C) v 0 0r (D) 2v 0 30r

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49. The radii of two plantes are respectively R1 and R2 and their densities are respectively 1 and 2.
The ratio of the acceleration due to gravity at their surfaces is

(A) g1 : g2 12 : 22 (B) g1 : g2 R1R2 : 12
R1 R 2
(C) g1 : g2 R12 : R21 (D) g1 : g2 R11 : R22
50. A student performs an experiment to determine the Young's modulus of a wire, exactly 2 m long, by
Searle's method. In a particular reading, the student measures the extension in the length of the
wire to be 0.8 mm with an uncertainty of 0.05 mm at a load of exactly 1.0 kg. The student also
measures the diameter of the wire to be 0.4 mm with an uncertainty of 0.01 mm. Take g = 9.8 m/s2
(exact). The Young's modulus obtained from the reading is
(A) 2.0 0.3 1011Nm 2 (B) 2.0 0.2 1011Nm 2
(C) 2.0 0.1 1011Nm 2 (D) 2.0 0.05 1011Nm 2
51. A 2 m wide truck is moving with a uniform speed 0 = 8 m/s along a straight horizontal road. A
pedestrian starts to cross the road with a uniform speed when the truck is 4 m away from him. The
minimum value of so that he can cross the road safely is
(A) 2.62 m/s (B) 4.6 m/s (C) 3.57 m/s (D) 1.414 m/s
A projectile is given an initial velocity of i 2j. The cartesian equation of its path is (g = 10 m/s2).
(A) y = 2x 5x2 (B) y = x 5x2 (C) 4y = 2x 5x2 (D) y = 2x 25x2
53. A small block of mass m rests on a smooth wedge of angle . With what
horizontal acceleration a should the wedge be pulley, as shown in the figure,
so that the block falls freely.
(A) g cos (B) g sin (C) g cot (D) g tan
54. In the figure if f1, f2, and T be the frictional forces on 2 kg block, 3 kg block and the tension in string,
respectively, then their values are

(A) 2 N, 6 N, 3.2 N (B) 2 N, 6 N, 0 N

(C) 1 N, 6 N, 2 N (D) Data insufficient to calculate the required value
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55. Refractive index of a prism is and the angle of prism is 60. The minimum angle of incidence of
a ray that will be transmitted through the prism is
(A) 30 (B) 45 (C) 15 (D) 50
56. A luminous object and a screen are at a fixed distance D apart. A converging lens of focal length f is
placed between the object and screen. A real image of the object is formed on the screen for two
lens positions if they are separated by a distance d equal to
(A) D D 4f (B) D D 4f (C) 2D D 4f (D) D 2
lmax lmin
57. Two coherent sources of intensity ratio interfere. Find the ratio in the interference
lmax lmin
2 2 1
(A) (B) (C) (D)
1 1 1 1
58. Representing the stopping potential V along y-axis and (1/) along x-axis for a given photocathode,
the curve is a straight line, the slope of which is equal to
e hc ec he
(A) (B) (C) (D)
hc e h c
59. The ratio of the speed of the electron in the first Bohr orbit of hydrogen and the speed of light is
equal to (where e, h, and c have their usual meanings in cgs system)
2hc er 2h e2c 2e 2
(A) (B) (C) (D)
e2 2c 2 h hc
60. The half-life of radium is 1620 years and its atomic weight is 226. The number of atoms that will
decay from its 1 g sample per second will be
(A) 3.6 1010 (B) 3.6 1012 (C) 3.1 1015 (D) 31.1 1015
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61. The possible number of isomers for the complex [MCl2Br2]SO4 is
(A) 1 (B) 2 (C) 4 (D) 5
62. Which of the following metallic sols cannot be prepared by Bredig's arc method?
(A) Gold (B) Silver (C) Platinum (D) Sodium
63. Which of the following statements is wrong?
(A) Among halogens, oxidising behaviour increases down the group
(B) Among alkali metals, reducing character increases down the group
(C) Fluorine is the most electronegative atom.
(D) Lithium is the hardest metal among alkali metals.
64. During the electrolysis of water, 4 mol of electrons were transferred from anode to cathode. The
total volume of the gases produced at STP will be approximately
(A) 67.2 L (B) 22.4 L (C) 44.8 L (D) 89.4 L
65. Which of the following mixtures of solutions can function as a buffer solution?
(A) 50 mol of 0.2 M NH3 + 50 ml of 0.1 M HCl
(B) 50 ml of 0.2 M NH3 + 50 ml of 0.2 M HCl
(C) 50 ml of 0.2 M HCl + 05 ml of 0.2 M NaOH
(D) 50 ml of 0.1 CH3COOH + 50 ml of 0.1 M HCl
66. Standard electrode potential of reactions are given below:
(i) Sn4 2e Sn2 ,E 0.15 V
(ii) 2Hg2 2e Hg22 , E 0.92 V
(iii) PbO2 4H 2e Pb2 2H2O,E 1.45 V
For these which statement is correct.
(A) Pb2+ is more powerful reducing agent than Sn2+
(B) Sn4+ is more powerful oxidising agent than Pb4+
(C) Hg2+ is more powerful oxidising agent than Pb4+
(D) Sn2+ is more powerful reducing agent than Hg22

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67. The activation energy of reaction I is 80 kJ mol1 and that of reaction II is 60 kJ mol1. Which of the
following statements is correct?
(A) The rate constant of reaction I is greater than that of II
(B) The rate constant of reaction II is greater than that of I
(C) The order of reaction I is greater than that of II
(D) The molecularity of reaction II is less than that of I
68. The Lassaigne's extract is boiled with dil. HNO3 before testing for halogens because
(A) Na2S and NaCN are precipitated by HNO3
(B) Na2S and NaCN are decomposed by HNO3
(C) Ag2S is soluble in HNO3
(D) AgCN is soluble is HNO3
69. Which of the following carbides, on hydrolysis, yields methane?
(A) Be2C (B) MgC2 (C) CaC2 (D) Mg2C3
70. Chlorine gas is dried over
(A) CaO (B) NaOH (C) KOH (D) Conc. H2SO4
71. In analytical chemistry, solid K2Cr2O7 is used to detect the presence of which acid radicals
(A) F (B) Cl (C) Br (D) I
72. When a large amount of KMnO4 is added to concentrated H2SO4, then explosive compound formed
(A) Mn2O7 (B) Mn3O4 (C) MnO3 (D) MnO3

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73. The degree of dissociation of PCl 5 at one atmosphere is 0.3. The pressure at which PCl 5 is
dissociated to 50% is
(A) 2.73 atm (B) 0.3 atm (C) 0.273 atm (D) 1.67 atm
74. 2 moles of a perfect gas at 27C is compressed reversibly and isothermally from a pressure of
1.01 105 Nm2 to 5.05 106 Nm2. Maximum work done on the gas in this process is
[log 5 = 0.6990]
(A) 1.95 104 Joule (B) + 1.95 104 Joule
(C) 1.95 103 Joule (D) + 1.95 103 Joule
75. S will be the highest for the reaction
(A) Ca s O 2 g CaO s (B) CaCO3 s CaOs CO 2 g
(C) Cg O2 g CO2 g (D) N2 g O2g 2NO g
76. The work function of a metal is 4.2 eV. If the radiation of 2000 falls on the metal, then kinetic
energy of the fastest photoelectron is
(A) 1.66 1019 J (B) 3.22 1019 J (C) 1.66 1020 J (D) 3.22 1018 J
77. Among NO3 , AsO33 ,CO32 ,ClO3 ,SO23 , and BO 33 ions, the non-planar species are

(A) AsO33 ,SO32 and ClO3 (B) NO3 ,SO23 and ClO3

(C) CO23 , AsO33 and SO32 (D) NO3 ,CO32 and ClO3

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78. At what temperature, will the average speed of CH4 molecules have the same value, as O2
molecules have at 300 K?
(A) 300C (B) 300 K (C) 150C (D) 150 K
79. When BaCrO4 is used as oxidizing agent in acidic medium, the equivalent weight of barium
chromate is [At. wt. of Ba = 137.34; Cr = 52.0; O = 16]
(A) 137.34 (B) 84.45 (C) 114.45 (D) 68.67

80. For the reaction NH3 OCl N2H4 Cl occurring in basic medium, the coefficient of N2H4 in the
balanced equation is
(A) 1 (B) 2 (C) 3 (D) 4
81. 100 mL of 0.1 N Na2S2O3 solution decolourised iodine produced by the addition of x g of crystalline
copper sulphate (Mol. Wt. = 250) to excess of KI solution. The value of x is
(A) 1.25 g (B) 12.5 g (C) 2.5 g (D) 25.0 g
82. An oxide of a metal (M) contains 40% by mass of oxygen. The metal (M) has a relative mass of 24.
The empirical formula of the oxide is
(A) M2O (B) MO (C) MO2 (D) M2O3
83. 20 ml of decinormal HCl solution was added to 10 ml of a decinormal AgNO3 solution. AgCl was
precipitated out and the excess acid was titrated against a decinormal NaOH solution. The volume
of NaOH required for this back titration is
(A) 10 ml (B) 5 ml (C) 20 ml (D) 30 ml

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84. Which of the following isomeric hydrocarbons is most acidic?

(A) (B) (C) (D)

85. The major product formed during the reaction of 1-methyl cyclopentene with CF3CO3H is

(A) (B) (C) (D)

86. Among the given halides, which one will give same product in both SN1 and SN2 reactions.

(I) (II)

(III) (IV)

(A) (III) only (B) (I) & (II) (C) (III) & (IV) (D) (I), (III) & (IV)
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87. Which of the following react with HBr at faster rate?

(A) (B)

(C) (D)

88. A

B ; product (B) of the reaction is:

(A) (B) (C) (D)

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89. 5

D , product D is

(A) (B)

(C) (D)

90. Product (B) of this reaction is:

(A) (B)

(C) (D)

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