Beruflich Dokumente
Kultur Dokumente
UNIVERSIDAD DE AMERICA
FACULTAD DE INGENIERIA QUIMICA
BOGOTA D.C.
2011
OBJETIVOS
OBJETIVO GENERAL
OBJETIVOS ESPECIFICOS
Diferenciar los tipos de calores que son utilizados para calcular el calor de una
reaccin.
DATO VALOR
Peso del beaker 1(gr) 87.45
Peso del beaker 2(gr) 46.96
NaOH (S) 1,01
Peso del (gr)
CALCULOS
1 gr de H 2 O
25 ml de H 2 O =25 gr de H 2 O
1 ml de H 2 O
1,02 gr de HCl
25 ml de HCl =25,5 gr de H 2 O
1 ml de HCl
3. Clculos para determinacin de entalpia del CASO I
NaOH S + H H O 2
H REACTIVOS= H
H H O =m c p T
2
J
2 (
H H O =( 25 gr ) 4,18
grK )
(24,215 )=961.4 J
H NaOH =m c p T
S
J
S (
H NaOH =( 1,01 gr ) 1,46
grK )
( 24,216 )=11.972 J
NaOH ( AC) + H H 2
H PRODUCTOS = H
1 mol H 2 O 1 mol de H 2
25 gr de H 2 O =0,6944 moles de H 2
18 gr de H 2 O 2mol de H 2 O
J
(
NaOH ac = ( 55.52 gr ) 4,184
grK )
( 24,221,9 )=530,935 J
H
J
2 (
H H =( 0,6944 moles ) 28,824
mol K )
( 24,221,9 ) =46,035 J
NaOH AC + H HCl 1M
H REACTIVOS= H
H NaOH =530,935 J
AC
H HCl =mc p T
1M
NaCl(AC) + H H 0 2
H PRODUCTOS = H
H H 0 =( 12,36 gr )
2 ( 4,18 J
grK )
( 24,221.9 ) =118.83 J
HCl 1 M + H 2 O HCl ac
a.
HCl1 M + H H O
2
H REACTIVOS= H
H H O =( 25 gr )
2 ( 4,18 J
grK )
( 24,217 )=752.4 J
H PRODUCTOS= H HCl ac
H HCl =( 50,5 gr )
ac ( 4,18 J
grK )
(24,217,5 )=1414.303 J
H HCl =1414.303 J
(AC )
H NaOH (S )=11.972 J
NaCl(AC) + H H 0 2
H PRODUCTOS = H
H NaCl =( 1,3873moles )
( AC) ( 50,50 J
molK )
(24,221.9 )=161.134 J
H H 0 =( 24,97 gr )
2 ( 4,18 J
grK )
( 24,221.9 )=240.06 J
RESULTADOS
HH O 961.4
2
H HCl 1M
566.306
H NaOH ac
530,935
H NaOH (S )
11.972
H REACCION (casoI )
-1095.042
HH O 752.4
2
H HCl 1M
725.577
H HCl ac
1414,303
H NaOH (S )
11.972
H REACCION (casoII )
- 1088.755
ANALISIS DE RESULTADOS
CUESTIONARIO
1. Qu es la ley de HESS?
H =mc p (T 2T 1)
HNaOH (diluido)
1 gr
25 mL H 2O x =25 grH 2O
ml
kJ
(
H NaOH (diluido)=( 0.026 kg ) 4,012
kg C )
( 24,221.9 ) C=0,2399 KJ
H B eaker=mCp (T 2T 1 )
cal
4,184 J
gC
1 KJ
1 cal
1000 g
1000 J KJ
C p =0,2 =0,837
1 kg kg C
KJ
H Beaker =0,08745 kg0,837 ( 24,216.18 ) C=0,587 KJ
kg C
Entonces:
H b = H a + H HCl (1 M)
H HCl=mCp ( l ) ( T 2T 1)
g 1 kg
m=1.02 25 ml=25.5 g =0.0255 kg de HCl
ml 1000 g
kJ
H HCl=0.0255 Kg 4.181 ( kg C )
( 24,217,9 ) C=0,6716 KJ
Entonces:
KJ
H Beaker =0,04696 kg0,837 ( 24,217.5 ) C=0,2801 KJ
kg C
H H 2 O=mCp ( T 2T 1 )
kg
m=V =2,5 105 m3 H 2 O 1000 3
=0,025 kg H 2 O
m
kJ
2 (
H H O =0,025 Kg 4.181
kg C )
x ( 24.217,5 ) C=0.7 kJ
kJ
H HCl=0.0255 Kg 4.181( kg C )
( 24,218 ) C=0,661 KJ
Entonces:
KJ
H Beaker =0,04696 kg0,837 ( 24,217.5 ) C=0,2801 KJ
kg C
1 kg
mSln =28 g =0,028 kgSln (1 M ) deHCl
1000 g
kJ
(
H HCl (diluido )=0,028 kg 4.181
kg C )
( 24.217.5 ) C=0.7843 KJ
H NaOH (s )=mCp (T 2T 1)
cal
4,184 J
gC
1 KJ
1cal
1000 g
1000 J KJ
C p =0,35 =1,464
1 kg kg C
kJ
(
H NaOH (s )=0.001 Kg 1,464 )
kg C
( 24.222.9 ) C=0,0019 KJ
Entonces:
H d =( 0,2801+0,7843+0,0019 ) KJ=1,0663 KJ
H RUTA I = H a+ H b
H RUTA II = H c + H d
BIBLIOGRAFIA