Beruflich Dokumente
Kultur Dokumente
Vol. 22, No. 02, pp. 293 - 302, April - June, 2005
Abstract - This work aims at modeling and simulating the drying of whole milk emulsion in spray dryers.
Drops and particles make up the discrete phase and are distributed into temporal compartments following
their residence time in the dryer. Air is the continuous and well-mixed phase. Mass and energy balances are
developed for each phase, taking into account their interactions. Constitutive equations for describing the drop
swelling and drying mechanisms as well as the heat and mass transfer between particles and hot air are
proposed and analyzed. A set of algebraic-differential equations is obtained and solved by specific numerical
codes. Results from experiments carried out in a pilot spray dryer are used to validate the model developed
and the numerical algorithm. Comparing the simulated and experimental data, it is shown that the model
predicts well the individual drop-particle history inside the dryer as well as the overall outlet air-particle
temperature and humidity.
Keywords: Spray dryer operation; Particle distribution; Drying model; Numerical simulation.
fraction of moisture from powdered milk occurs products have characteristics crucial to its acceptance
slowly and is costly, and the final product is fine and commercialization. The quality of powdered
nonagglomerated particles (30-50 m) that do not milk is greatly affected by the operational conditions
readily disperse in water. A spray dryer attached to a of this process. Therefore, the knowledge of the
vibrating fluid bed system, as shown in Figure 1, spray-drying technology is essential for controlling
comprises the two-stage drying. In this method, these operational variables in order to obtain a high-
agglomerates are preserved at the exit of the spray quality product (King et al., 1984; Nath and
chamber and, thus, feed into the vibro-fluidized bed Satpathy, 1998).
system where they are gently dried and cooled. Based on the previous mathematical model
Nonagglomerated particles can be recycled into the presented by Clement et al. (1991), which focuses on
spray chamber, enhancing the quality of powdered Euler and Lagrange approaches for developing mass
milk by control of the particle size distribution. and energy balances, this work aims at modeling and
Three-stage drying, in which a stationary fluid bed of simulating the drying of whole milk emulsion in
powdered milk is added at the conical base of the spray dryers.
spray chamber to better control particle As shown by the results, a more detailed study of
agglomeration and drying, is an improvement of this the mass transfer model and the particle residence
method. After drying and cooling, the final time distribution has improved the original Clement
powdered milk product must be packaged in suitable et al. model. A new and more efficient method for
containers and stored, when necessary, under the numerical model solution was implemented.
conditions specific to its safe preservation. Simulations allowed evaluation of model
Of all these steps, drying is the one in which applicability, study of operational parameter
powdered milk properties are defined. As is well- sensitivity and prediction of the dryer outlet conditions
known in the literature, powdered milk and its by- at several levels of operational parameters.
MATHEMATICAL MODEL FOR DRYING hot gas and milk suspension are continuously
MILK EMULSION IN SPRAY DRYERS injected into the top of the dryer chamber at
uniform rates;
Initial Assumptions the gas phase, formed of air and vapor, behaves
as an ideal mixture and flows inside the dryer as a
The mathematical formulation is based on the perfect mixture;
following assumptions (Clement et al., 1991): the suspension is properly atomized forming
gas phase;
the overall drying rate is a weight sum of (
Wc W * Pwg ,Tp
)
individual rates of all particles that remain in the
dryer; Mean particle diameter dp
the drying kinetics is represented by two distinct
( )
1/3
periods: the first one, in which free water is 6 ms W0 Wp
evaporated from drops until a thin semipermeable dp = dp0
3
Wp > Wc (3a)
water
crust is formed on the particle surface, and the
second one, characterized by the thickening of
this crust as predicted by the shrinking core 6 ms ( W0 Wc )
1/3
model. d p = d3p0 Wp Wc (3b)
water
Model Development
Mass of dry solids inside the drop ms
The model comprises a set of constitutive
algebraic equations that describes mass and heat susp d p03
transfer between gas and single particles, the drying ms = (4)
kinetics of a single particle surrounded by gas and (1 + W0 ) 6
functions of the particle residence time distribution
inside the chamber; a group of differential equations Equilibrium moisture content W*
that expresses the mass and energy balances for a
single particle and a continuous gas phase and a set
( )
0.621
of algebraic equations that express the overall W* = (0.109 Tp ) 2.02 104 ln UR (5)
distributed balances of particles inside the chamber.
In this work, only the main model equations are
where particle temperature, Tp, is expressed in K.
presented; complete information about the entire Equations (1) and (2) respectively describe the
model is given by Birchal (2003). Constitutive
heat and the mass transfer between a particle and
algebraic equations concerned with a single particle
gas. For estimation of the convective heat and mass
can be summarized as transfer coefficients, h and k, Nusselt (Nu) and
Heat and mass transfer rates per unit of the Sherwood (Sh) numbers are supposed to be equal to
particle surface area q& and m &v 2, since the relative velocity between particle and gas
is nearly zero. The f factor in Equation (2) represents
(
q& = h Tg Tp ) (1) the resistance of the crust to water vapor diffusion
through it, and this value arises only in the second
drying period (Wp < Wc). Right at the beginning of
P Mw 2Diff
&v=
m the first drying period, even when the particle
Tg + Tp 2Diff temperature, Tp, becomes greater than the wet-bulb
R d p f + temperature, the drying rate is adjusted by an
2 kd p
(2) additional term to make the vapor pressure in the
PP bulk air, Pwg, equal to the saturated vapor pressure at
ln
wg wet-bulb temperature, Pw*(TBU). This additional
*
( )
P Pw Tp
drying rate per particle area, m & vap , is thus included
in the modified model, as shown in Equation (11).
with Equations (3a) and (3b) describe the particle/drop
diameter during drying. The initial drop diameter,
Brazilian Journal of Chemical Engineering Vol. 22, No. 02, pp. 293 - 302, April - June, 2005
296 V. S. Birchal and M. L. Passos
dp0, a function of atomizer design parameters and the models for the particle residence time distribution
suspension flow rate, is estimated by the specific can be easily incorporated into the model program.
correlation for the rotary disc atomizer (Masters, Based on this assumption, particles fed into the
1985). chamber at the initial time (t = 0) are distributed
According to the model assumptions, in the along different routes in the dryer and are removed at
second drying period this diameter becomes different times, as predicted by
constant. The mass of dry solids inside a particle, ms,
constant throughout the process, can be obtained E ( / r ) = exp( / r ) or
from Equation (4). Equation (5) describes the (6)
particle equilibrium moisture content, W*, as a t
function of particle temperature, Tp, and relative
humidity of the air, UR. This sorption curve, specific (
Fc ( t ) = exp rp
0
) d
rp
(
= 1 exp t rp )
for the whole powdered milk used in this work, was
obtained from experiments carried out under Since particles take different routes inside the
dynamic conditions (Birchal, 2003). This curve is drying chamber, it is necessary to distinguish, at any
also used to specify the critical particle moisture operating time t, that particle fraction of ages less
content, Wc, by making UR close to 1. Note that Wc than or equal to t, which is removed from the dryer
depends on Tp because of the crust formation on the and that particle fraction of ages greater than to t,
particle surface. which is kept inside the chamber. It is also necessary
To determine the mass and energy balances of the to differentiate, in these fractions, the correct particle
particle population in the dryer (discrete phase), it is age in order to determine the water evaporation rate
necessary to specify the effective contribution of and the rate of heat exchanged with the gas phase.
each particle or particle group to the overall drying This requires combining same-age particles into n
and heat exchange rates. This contribution is directly temporal compartments, which can simplify
related to the residence time of the particle in the identification during the operating time, the
dryer. Hence, a detailed and clear description of the remaining and removed fractions of particles
residence time distribution function is extremely according to age. This approach of temporal
important. compartmentalization is justified, since in the drying
The residence time distribution function of model, particles of the same age have the same
particles in the dryer is expressed as a function of the diameter, moisture content and temperature. Note
cumulative fraction of particles which leaves the that, in the model assumptions, drop coalescence and
dryer at time t, Fc(t), or even as a function of the age drop breakage are both neglected. Therefore,
distribution of these particles, E(/rp), in relation to particles of the same age, belonging to the same
the mean particle residence time, rp. In this work, temporal compartment, can be found in different
the particle residence time distribution is based on spatial positions in the drying, as represented in
the perfect mixture model; however, different Figure 2.
Using this approach, the disperse phase is thus fraction of particles fed in at t = 0 leaves the dryer. If
supposed to be comprised of particles that are there is no perturbation in this dryer system, the
distributed into n temporal compartments by age. permanent regime is established at t = n. The Np,1,j
Under inlet condition = i > 0 (i = 2 to n), the (= F/ms) compartment is composed of particles of
particle fraction that remains in the chamber at a age 1 = 0 at t = (j -1) for 1 = j = n; Np,2,j (= r1 Np,1,j-
time t > i is expressed by 1) by particles of age 2 = at t = (j -1) for 2 = j <
n; Np,3,j (= r2 Np,2,j-1) by those of age 3 = 2 at t = (j
-1) for 3 = j = n and so on consecutively until Np,n,j
1 Fc ( t i ) = exp d =
t i
rp rp
(= rn-1 Np,n-1,j-1) is reached at t = (n-1). For any i
(7) value, ri = exp (-/rp) is constant. From this matrix
( t i ) scheme in Figure 3, compartments composed of
= exp particles fed into the dryer at t = 0 are on the
rp principal diagonal (i,j = i) corresponding to Np,i,j=i.
Compartments with particles fed into the dryer at t =
Equation (7) allows calculation of the fraction of are located on the diagonal (i, j = i + 1),
particles of an age between i and (i + d), which corresponding to Np,i,j=i+1 and so on successively. In
remain in the dryer at operating time t. Figure 3 each compartment, there are two outlet currents of
illustrates the model compartments corresponding to particles: one formed by the particle fraction Np,s =
the particle age at any time t = i t (0 i n). Note (1-ri)Np,i,j that leaves the dryer at (j -1) = t = j
that at t = (n-1), the n compartments are all filled and the other by the particle fraction Np,r = riNp,i,j that
with particles of ages varying from 0 to n. remains in the dryer and feeds the next time
Moreover, at this operating time, the remaining compartment, Np, i+1,j+1.
Moreover, this scheme, different from the one Overall water evaporation rate
suggested by Clement et al. (1991), allows easy
identification of the particle fraction that leaves the t
F
exp & v d
dp m
2
dryer at t > . Based on this, water evaporation and ms rp
0 t
the heat transfer rates can be determined during the n
N ( t ) &v= &v
2
p,i,j
entire operating time, since the individual mass and d p2 m (8)
heat transfer rates estimated in each i of the Npi,j d p m
i =1
compartments in the j column of a given operating
time, can be summed up as follows: Overall heat rate
Brazilian Journal of Chemical Engineering Vol. 22, No. 02, pp. 293 - 302, April - June, 2005
298 V. S. Birchal and M. L. Passos
F
exp d p q& d
2
comprises (2n+2) differential equations.
ms rp
0 t (9) Overall rates of mass and heat transfer between
n phases, the mean particle moisture content, Wp , and
N ( t ) q& = q&
2
p,i, j
d p d 2p
i =1 temperature, Tp , can thus be calculated at a given
operating time, t, as
Np,i,j is the particle fraction in the i,j compartment
(1 = i = n) with j = constant corresponding to a given Overall heat rate supplied by gas
operating time and expressed as
n
N p,i,j = N p,i ( t ) = ri
(10)
& =Q
Q & (t) = Q
& =
j N p,i,j d p,i,j 2
q& (15)
i =1
F t i
N p,i 1,, j1 = exp Overall heat rate used for water evaporation
ms rp
t i
n
with i = ( i 1) .
&
Q &
evap = Qevap,j = + ( C pv )(
Cpw Tp,i,j Tref
)
i=1
(16)
Based on Equations (8) and (9), mass and energy
&v
2
Np,i,j dp,i,j m
balances for both solid and gas phases were
developed as follows:
Mass balance for a single particle (applied to n Overall mass transfer rate for the solid phase
compartments) & & &
M evap = M evap ( t ) = M evap, j =
(17)
dW p
= d p ( t )
2 n
ms
dt = N p,i,j d p,i, j 2
( m& v + m& v ap )
(11) i =1
( m& v + m& v ap ) Mean particle moisture content in the dryer
Energy balance for a single particle (applied to n n
compartments)
W p,i, j (1 ri ) N p,i,j
W p ( t ) = Wp , j = i =1
=
d
(
dp ( t ) q& = ms Cps + WpCpw Tp ( t ) Tref + )( )
2 n
dt
(12) (1 r ) N
i =1
i p,i, j
( )
+ + Cpv Tp ( t ) Tref dp ( t ) m
& v +m
& vap ( )
2
(18)
n
dY G Y0 Y + ( ) &v
d 2p m r N i p,i,j
= (13) i =1
dt Gr
Mean particle temperature in the dryer
Energy balance for the gas phase
Tp ( t ) = Tp,j =
d
dt
(
Gr C vg + YCvv + VCp ) ( T T ) =
g ref n
(19)
Figure 4: History of particle drying inside the spray dryer (n = 600; nr = 200).
Brazilian Journal of Chemical Engineering Vol. 22, No. 02, pp. 293 - 302, April - June, 2005
300 V. S. Birchal and M. L. Passos
RESULTS AND DISCUSSION combining low (-1), medium (0) and high (+1) levels of
three operational variables: F, vatom and Tg0, as shown in
To analyze and validate results from the model Table 1. More details of these experiments can found in
developed, experimental tests were conducted at the work of Birchal (2003).
IEN/CNEN in an APV-ANHIDRO model PSD 52 Results obtained with the model by using the
pilot spray dryer made of stainless steel with a 1 m of computer program developed are presented in Table
diameter and a 0.6 m of height (cylindrical part) and a 2 together with experimental data, deviation and
7.5 kg/h of evaporation capacity. Drying air at a rate of fitted error (model fit to experimental data). In
0.041 kg/s and a humidity of 0.010 to 0.020 and whole figures 5-a, 5-b and 5-c, the agreement between
milk emulsion with a 49% solids concentration at 51C experimental and simulated data can easily be
are fed in concurrently, reproducing the industrial observed. In these figures, vertical bars on the
conditions of dryer operation. The atomizer is of the experimental data points represent the experimental
rotary disc type. Nine inlet conditions were tested by error given in Table 2.
As shown in Figure 5-a, all values of Tg are experimental and simulated data, which is explained
predicted well by the model within the experimental by the considerable measurement errors obtained
uncertainty range. This variable is one of the most with instruments. The model predicts satisfactorily
important in the spray drying operation, since it is an nine out of eleven data. Larger and no predictive Wp
indirect measurement of solids properties, such as deviations obtained in experiments 3 and 7 may be
the outlet powder moisture content and temperature related to the severe inlet conditions imposed on the
in the industrial production of powdered milk. From milk drying (higher temperature and lower emulsion
this, it is also possible to calculate thermal dryer feed rate), which resulted in a burned product with a
efficiency and to analyze particle temperature history possible loss of some volatile components.
and possible alterations in properties of the In Figure 5-c, Y is also predicted well,
powdered milk. considering the experimental uncertainty involved in
Figure 5-b indicates a larger deviation between measurement of this variable.
Brazilian Journal of Chemical Engineering
Modeling and Simulation of Milk Emulsion Drying 301
(a) (b)
(c)
Figure 5: Comparison between experimental and simulated data for a) Tg, b) Wp and c) Y.
CONCLUSIONS NOMENCLATURE
Brazilian Journal of Chemical Engineering Vol. 22, No. 02, pp. 293 - 302, April - June, 2005
302 V. S. Birchal and M. L. Passos