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Wednesday 2/2/2015
14.00 17.00: Available for questions/discussion at TTPL
Thursday 3/12/2015
11.45 14.30: Lecture - Azeotropic distillation methods
15.00 17.00: Available for questions/discussion at TTPL
Friday 4/12/2015
13:30 15.00: Available for questions/discussion at TTPL
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Outline
Introduction
Statoil
Natural Gas
Gas Quality in the Value Chain
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4
Statoils natural gas business
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What is natural gas?
Components
Mainly methane, ethane, propane and
butanes
Small amounts of pentane (C5) and heavier
components (C6+)
Acid/sour gases such as CO2 and H2S
Inerts such as nitrogen (N2)
Trace components such as mercury (Hg)
and sulphur compounds (S)
Water (vapour)
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Natural gas compositions (typical values)
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Natural Gas Terminology
Rich Gas: Rich in heavy components.
Further processing required
Sales gas (dry gas): Ready for sale to
the market
Liquified Natural Gas (LNG): -162C @
1 bar
Natural Gas Liquids (NGL): Ethane and
heavier HC (C2+)
Naphtha: Rest of the NGL (C5+)
Condensate: Heavier liquids from
integrated gas/oil production (C6+)
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Natural gas transport
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Norwegian Gas
Transport Network
Complex system
8 000km of pipelines
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Upstream
Subsea and wells
Gas Value Chain
Upstream
Subsurface
Offshore processes
(reservoir, production
and wells, flow
assurance)
Gas Processing
(processing, extracting high added value products)
Downstream
Receiving terminals
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Gas Quality
Scientific field dealing with the compositions,
the physical properties and the
specifications of natural gas
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Gas quality specs along the value chain (1/2)
Specifications for rich gas transport
Offshore processes
Designation and unit Specification
Max operating pressure (barg) 210
Min operating pressure (barg) 112
Max operating temperature (C) 60
Min operating temperature (C) -10
Rich gas
Max cricondenbar pressure (barg) 105 transport
Max cricondentherm temperature (C) 40
Max water dew point (C at 69barg) -18
Max carbon dioxide (mole%) 2 Onshore processes
Max hydrogen sulphide and COS (ppmv) 2
Max O2 (ppmv) 2
Max daily average methanol content (ppmv) 2.5
Max peak methanol content (ppmv) 20
Max daily average glycol content (litres/MSm3) 8
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Gas quality specs along the value chain (2/2)
Specifications for sales (dry) gas transport Onshore processes
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Natural Gas Processing
Water dew point
Water occurs naturally in the reservoir
Free water phase is removed in 3-phase separators
Water (vapour) is physically dissolved in the natural gas
(in equilibrium)
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Water dew point specifications
Offshore processes Onshore processes
Transport Process
specification: specification:
-18C at 69 barg 0.1 to 1 ppmv
(20-30 ppm)
Process needed:
Process needed:
Adsorption on
Glycol absorption
solids
process
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Water removal offshore - Glycol absorption (physical)
Counter-current mixing with tri-ethylene glycol (TEG)
Water
Meets pipeline water dew point specifications (-18C at 69 barg) vapour
Glycol
Contactor
Rich TEG
Glycol/condensate
separator
Filter
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Water removal onshore - Adsorption on solids
Adsorption in to a solid material
Used in deep gas processing at low temperatures
Removal of smaller amounts of water
Extreme dryness, down to 0.1 ppm water
Porous structures with high internal surface area (200
800 m2/g)
Strong affinity for water, 5 25 % by weight
Common adsorbents
Molecular sieve (3A or 4A type) (Zeolite)
Activated alumina (Al2O3)
Silica gel (SiO2)
Regenerative processes
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Water removal by adsorption
Acid/sour gas removal (CO2 and H2S)
Most natural gas contains acid gas
CO2 (acid)
H2S and other sulfur compounds (sour)
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Acid gas removal (CO2 and H2S) by
absorption (physico-chemical) in amines
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H2S (traces) removal on metal oxide
Acid gas content <1%
Chemical reaction
MeO + H2S MeS + H2O
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Mercury in oil & gas
Occurs naturally in virtually all oil & gas reservoir
Mineral cinnabar (red), HgS, is the main source of
mercury in reservoirs
Concentrations vary from few to hundreds of ppb
Mercury compounds are highly toxic
Mercury is always removed in LNG plants and
sometimes in gas processing - to avoid severe
corrosion of aluminium equipment
Mercury is removed by adsorption on solids
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Mercury removal by adsorption on solids
Main removal methods:
Sulfur impregnated activated carbon
Hg + S HgS
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Hydrocarbon dew point - Phase envelope of
natural gas
Dense phase
C Critical point
Cricondenbar N Cricondenbar
M Cricondentherm
Liquid Cricondentherm
Vapor + liquid
The phase envelope is ONLY
Gas a function of COMPOSITION
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Effect of composition on phase envelopes
Effect of heavy ends (C7+)
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Practical importance of phase envelopes
Rich gas pipeline (ab)
Gas transport in pipelines a - Cricondenbar specification
- Transport at high pressures
b - No liquid formation above
cricondenbar (dense phase)
- Manipulate phase envelope
by removing NGL to reach a
cricondenbar spec.
a
Sales gas pipeline (ab):
- Cricondentherm spec
b
- Transport at intermediate/low
pressures
- No liquid formation above
cricondentherm (gas phase)
- Manipulate phase envelope by
removing NGL to reach a
cricondentherm spec.
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Manipulation of phase envelopes along the Value Chain-
HC dew point control
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HC dew point processes (NGL recovery)
S2
S1
PRODUCT-FLAS
VALVE
PRODUCT-FLAS S3
FEED
FEED
LIQUID
LIQUID
JT-valve (isenthalpic)
Expander process (isentropic) creates shaft work -
achieves lower temperatures (deeper NGL extraction)
Expander combined with a compressor (energy recovery)
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HC dew point processes (NGL recovery)
Pre-cooling and expansion
S2 S2
S1 S1
S3
PRODUCT-FLAS PRODUCT-FLAS
S4 EX1 EX1
S5 S4
E1 E1
S3 E2
S5
GAS S7
GAS
FEED-FL ASH
FEED-FL ASH
FEED
FEED
LIQUID LIQUID
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NGL fractionation
NGL fractionation in series of distillation columns
Make high added value products (C2, C3, C4, C5+)
Propane
4 3
C2+ from
1 2
NGL recovery
Feed
C2
Sea
water
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6
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Steam
8 C3 Sea
5 water
De-etanizer Sea
water
Steam
iC4
De-propanizer
Steam
Steam nC4
Butane
C5+ splitter
De-butanizer
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Examples from real plants
Snhvit
Norne
sgard Heidrun
Kristin
TS Haltenpipe
Ormen Lange Tjeldbergodden
Statfjord
Nyhamna
Troll
Frigg Kollsnes
Vesterled
Sleipner Krst
St Fergus
Ekofisk Europipe II
Europipe I
Langeled
Zeepipe I Norpipe
Franpipe
Easington
Emden
Zeebrugge
Dunkerque
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sgard B Process
CO2/H2S
removal HC dew point
Water dew point
RICH GAS
EXPORT
FEED (3-phase)
Inlet separation
Oil stabilization
STABILISED
OIL
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Snhvit
Krst plant
Norne
sgard Heidrun
Kristin
TS Haltenpipe
Ormen Lange Tjeldbergodden
Statfjord
Nyhamna
Troll
Frigg Kollsnes
Vesterled
Sleipner Krst
St Fergus
Ekofisk Europipe II
Europipe I
Langeled
Zeepipe I Norpipe
Franpipe
Easington
Emden
Zeebrugge
Dunkerque
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Krst plant: Feed pretreatment
H2S
removal
Mercury
removal
Turbo-expander
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Future Oil & Gas Production
ROV
intervention
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Thank you
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