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65 Aufrufe10 SeitenPaper on modeling of iron ore pelletizing furnace for induration

Apr 22, 2017

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Paper on modeling of iron ore pelletizing furnace for induration

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65 Aufrufe

Paper on modeling of iron ore pelletizing furnace for induration

© All Rights Reserved

Als PDF, TXT **herunterladen** oder online auf Scribd lesen

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89 (2008) 3039

j o u r n a l h o m e p a g e : w w w. e l s ev i e r. c o m / l o c a t e / i j m i n p r o

Mansoor Barati

Department of Materials Science & Engineering, University of Toronto, WB140-184 College Street, Toronto, ON, Canada M5S 3E4

a r t i c l e i n f o a b s t r a c t

Article history: A mathematical model of pellet induration process in the straight-grate system is presented. The important

Received 21 October 2007 physical and chemical phenomena known to affect the heat and mass transfer in the process have been taken

Received in revised form 16 July 2008 into account in the formulation of the model. These include heat transfer between gas and pellet, gas ow,

Accepted 3 September 2008

evaporation and condensation of moisture, oxidation of magnetite, combustion of coke breeze, calcination of

Available online 19 September 2008

lime and dolomite, and shrinkage of pellet and pellet bed slump. The model is validated by comparing its

Keywords:

predictions against actual measurements in an industrial scale plant as well as a pilot pot grate. The effect of

Mathematical modeling several process parameters on the induration regime are evaluated using the model. It is demonstrated

Pellet induration through a case study that the model can be employed as a valuable tool for such purposes as process

Straight grate optimization and design of the induration machine.

Pellet shrinkage 2008 Elsevier B.V. All rights reserved.

Iron ore pelletizing

grate typically consists of four distinct phases: drying, preheating,

Production of pellet as a desirable feedstock for ironmaking ring, and cooling. The rst stage of drying is updraft to prevent

furnaces has exceeded 300 Mt per year in 2005, accounting for condensation of water and consequential pellet deformation in the

about 24% of the iron ore processed globally (UNCTAD, 2006). The bottom layers of the pellet bed. Drying is continued in a subsequent

production of iron ore pellets involves two major steps, forming the downdraft stage by relatively hot gases coming from the ring zone of

green pellets in rotary disks or drums, followed by heat hardening the furnace. The rate of heat transfer and moisture removal has to be

them subsequently at elevated temperatures around 1200 to 1400 C controlled in a certain range, as otherwise spalling may occur. In the

to increase the pellet strength. preheating phase, pellets are heated to about 1000 C by downdraft

The heat hardening or induration of pellets employs one of the gas owing through the bed. Hot gas is typically recycled from the

three conventional furnace types: vertical shaft furnace, grate-kiln cooling zone and augmented with auxiliary heat from hood burners, if

system, and travelling straight grate. The latter process that was required. During this phase, pellets are completely dried and reactions

primarily developed by Lurgi and is currently owned by OutoKumpu such as decomposition of carbonates (e.g. lime, dolomite), magnetite

Technology, accounts for two thirds of the world's installed pelletizing oxidation and coke combustion take place. The reactions continue in

processes capacity. This study is focused on simulation of pellet the ring stage, where the gas temperature is raised to ~ 1350 C. The

induration process in the straight-grate system. strength of the pellets increases at this stage because of recrystalliza-

tion, sintering and formation of partially liquid phases. The pellet

1.1. Description of induration process in straight-grate machine porosity on the other hand is decreased. Temperature and owrate of

gas together with the duration of the ring phase have to be

Fig. 1 depicts schematic of a typical straight-grate induration controlled with care to produce pellets of high strength and adequate

system. The grate bars xed on a moving strand are rst covered with porosity. Some of the off-gas from the ring zone is recuperated to the

a layer of burnt pellet, known as hearth-layer. The green pellets drying zone after mixing with air. The remainder of the gas is vented

containing 7 to 9 wt.% free moisture and 10 to 14 mm in size are then off through the stack.

fed onto this layer and travel together with the sub-layer through The induration zone of the furnace is generally divided into several

several thermal zones of the furnace. The role of the heart layer pellets sections and the gas owrate through each section is controlled by a

is to act as a neutral heat absorbing media and protect the grate bars separate fan. This is intended to provide the operator with the exibility

of controlling the heating prole for better pellet quality and grate bar

protection. After ring, burnt pellets undergo cooling where ambient air

Tel.: +1 416 978 5637; fax: +1 416 978 4155. is drawn upward through the bed. The hearth layer prevents a severe

E-mail address: mansoor.barati@utoronto.ca. thermal shock to the pellets by preheating the air. The off-gas leaving the

0301-7516/$ see front matter 2008 Elsevier B.V. All rights reserved.

doi:10.1016/j.minpro.2008.09.008

M. Barati / Int. J. Miner. Process. 89 (2008) 3039 31

early stage of cooling has a temperature around 1000 C. The gas is induration in pot grate (Kucukada et al., 1994; Seshadri and da Silva

directed to the ring and preheating zones where is it further heated by Pereira, 1985). Wynnyckyj and Batterham (1985) have presented a

the burners. The gases from the later stages of cooling have lower comprehensive review of the physical and chemical phenomena

temperature, hence they are used for drying of pellets. pertaining to sintering and pellet ring and the approaches towards

It is clear from the description of the process that considerable modeling of such phenomena.

attention has been paid to enhancing the energy efciency of the Despite the considerable studies on modeling of these processes and

overall process. Numerous advancements have been made that enable pellet induration in particular, only a few have developed a model for

the operators to alter the process conditions (e.g. gas ow and straight-grate induration process consisting of complete drying, ring

temperature, grate speed, etc.) and achieve both high pellet quality and and cooling cycles. In addition, each model has been developed by taking

low energy consumption. However, optimization of thermal treatment into account a few of the many reactions and physical changes involved.

of pellet is inherently an iterative process and determination of the One phenomenon that is generally overlooked, yet plays a signicant

optimum operating conditions in a working plant is extremely difcult, role in the process performance, is variations of pellet porosity and

time consuming and costly. Besides, the measurement of critical corresponding bed shrinkage as the pellet bed passes through different

process data such as temperature within the pellet bed is virtually thermal zones of the furnace. The present article describes development

impossible. As a result, induration processes have traditionally relied and validation of a complete mathematical model for pellet induration

on laboratory pot grate test results for determination of optimum by the straight-grate method. The major improvements over the

design and operating parameters. However, results of a single pot grate previous studies in this area are rst, including all important reactions

experiment are decient in making distinction between the effects of in the model and second, taking into account pellet shrinkage and the

different variables on the heating prole and pellet quality. On the resulting pellet bed slump as they undergo the thermal treatment. The

other hand, a complete study of the effect of even one variable on the model is based entirely on the existing knowledge pertaining to physical

process requires numerous experiments, with other variables kept and chemical changes in the pellet induration process.

unchanged. Also, pilot tests do not directly provide information on

local interactions, reactions rates and heat and material balance. As a 2. Mathematical model

complementary, and sometimes alternative, method of process

analysis, mathematical modeling has been put forward (Young, 1963) The mathematical model is developed to predict the detailed

soon after the pelletizing technologies came on stream. process information including temperature, owrate and composition

of gases, rate and extent of progress for the reactions, porosity and

1.2. Previous models of pellet induration in straight-grate machine chemical composition of pellet, and bed slump at any position and in

different times. In the formulation of the model, the following

The original works on calculation of temperature prole in moving phenomena have been taken into account.

pellet beds date back to over four decades ago. Early studies on a purely

theoretical approach to modeling of the process by Hasenack et al. i. Heat transfer between pellet and gas with temperature and com-

(1975) and Voskamp and Brasz (1975) presented signicant insights into position dependent thermophysical properties for both phases

the details which have to be considered. Hasenack et al. took into ii. Evaporation and condensation of moisture

account convective heat transfer as well as conduction resistance within iii. Oxidation of magnetite

each pellet. In their calculations, they omitted to consider calcination of iv. Calcinations of limestone (CaCO3) and dolomite ((Ca,Mg)CO3)

carbonates as well as oxidation of carbon since they used non-uxed v. Combustion of carbon (e.g. coke breeze)

pellet with no addition of carbonaceous materials. They collected very vi. Reduction in pellet porosity and the corresponding bed shrinkage

valuable information from an operating plant and showed that their Certain assumptions with acceptably small impact on the accuracy

model provided satisfactory agreement with the measurements. of calculations were made. These include:

Voskamp and Braz assumed that the temperature gradient inside each

pellet is negligible. They further approximated thermal properties of gas, i. The induration process is at steady state conditions

pellet and grate bar with constant values in each furnace zone. ii. Gas distribution through the pellet bed is uniform, i.e. no

Following these pioneers, a substantial number of models have channeling of the gas occurs

been put forward for iron ore sintering (Cumming and Thurlby, 1990; iii. The thermal conductivity of individual pellets is innitely high so

Young, 1977), and pellet induration in shaft furnaces (Norgate et al., that temperature gradient within each pellet can be neglected

1985)), grate-kiln system (Cross and Young, 1976; Davis and Englund, iv. The pellet bed is represented as a porous packed bed of uniformly

2003; Pape et al., 1976; Thurlby, 1988a,b,c; Young et al., 1979), and sized spheres

travelling grate machine (Drugge, 1975, 1981; Breitholtz and Hillberg, v. Vertical gas velocity is much greater than the horizontal grate

1980; Thurlby et al., 1979). Several authors have also simulated pellet speed

32 M. Barati / Int. J. Miner. Process. 89 (2008) 3039

vi. Heat conduction within the pellet bed is insignicant relative to the pellet surface to the gas bulk. The rate expression for this stage is

the convective gassolid heat transfer rate presented as:

vii. Heat losses are limited only to the initial heat storage in the

grate bars Rw kw A weg wg 6

viii. Heat released/absorbed by the chemical reactions is solely

where the mass transfer coefcient, kw, can be derived from a

exchanged with the solids, except the heat of moisture

correlation similar to that of the heat transfer coefcient (Keey, 1972;

condensation that is split equally between gas and solid.

Perry and Chilton, 1973) as:

" #

The equations forming the mathematical model are presented DH2 O Rep 1=2 1=3

kw 2:0 0:6 Sc : 7

below. The denition of all symbols is provided in nomenclature at dp b

the end of the paper. Some thermokinetic properties and constants

that have been used in the model development are given in the The saturation water vapor pressure of the gas, weg, is calculated

Appendix. from the equilibrium conditions at the pellet surface temperature. The

diffusivity of water vapor through the gas phase can be obtained from

2.1. Heat transfer the correlation provided by Fuller et al. (1966).

1:2 109 Tg1:75

The dominant heat transfer mechanisms are conduction and DH2 O : 8

radiation between gas and pellet. Using an effective heat transfer PV

coefcient (h) that contains the contribution of radiation, the governing The value of critical moisture content was assumed to be 120 kg/m3

equations are given by: (Hasenack et al., 1975; Voskamp and Brasz, 1975).

In the second step of drying, when the pellet humidity drops below

ATg X

GCg hA Tg Tp 1 i Ri Hi 1 the critical concentration, an evaporation front penetrates toward the

Az

pellet centre and pore diffusion within the dry shell begins to play the

for the gas phase, and role as the rate limiting step. A mixed control model consisting of two

resistances, diffusion through the dry shell and mass transfer in the

ATp X

b Cp hA Tg Tp i Ri Hi 2 gas phase, may be used to express the drying rate as:

Az

A weg wg

for the pellets. The gas and pellet heat transfer area is calculated from: Rw 9

rp rp rw

1

2rw De

61 b kw H2 O

A : 3

/dp

where DeH2O is the effective diffusion coefcient of water vapor through the

In Eqs. (1) and (2), i is the fraction of heat from ith reaction, that is pellet pores and is calculated from the following correlation (Perry and

retained by the solids. As indicated in the assumptions, i is set to 0.5 Chilton, 1973):

for water vapor condensation and unity for all other reactions. It was p

DeH2 O DH2 O 10

noticed that because of a high heat transfer coefcient, the heat of

reactions is immediately distributed between the two phases,

with tortuosity () related to the pellet porosity (p) via (Perry and Chilton,

regardless of the initial share of each phase from the heat.

1973):

It is evident from Eqs. (1) and (2) that the heat transfer coefcient

has a signicant contribution to the rate of heat transfer. A wide range 0:41

p : 11

of correlations have been put forward by several authors for

calculation of the heat transfer coefcient in packed beds. Seshadri Towards the end of drying, the evaporation rate is controlled by

and Pereira (1986) evaluated the validity of different heat transfer heat transfer from the gas to the pellet and is represented by:

expressions in predicting the temperature distribution for pellet beds

hA Tg Tw rw

and concluded that Eq. (4) known as the RanzMarshall correlation Rw : 12

Hv rp

(Ranz, 1952) correlation provides the best agreement between the

experimental and the calculated results. The point of transition between the two latter mechanisms of

drying is when the rate of drying in the heat transferred controlled

Rep 1=2 regime becomes smaller than that of the mixed control regime. Tw in

Nu 2:0 0:6 Pr1=3 : 4

b Eq. (12) is wet bulb temperature and can be calculated through

iterative methods (Parsons, 2005) or expressions obtained by

The coefcient for heat transfer to the grate bar is calculated by the

regression through the experimental data (Seshadri and da Silva

equation presented by Voskamp and Bransz (1975)

Pereira, 1985), as presented in the Appendix.

Nu 5Re1=2 : 5 Condensation of water vapor occurs in the layers of pellet with

temperature lower than the saturation temperature of the gas. Eq. (6)

It is important to note that the heat transfer coefcient calculated presents the rate of condensation as a negative value and the heat of

from these equations has essentially the effect of radiation embedded condensation is portioned equally between the gas and the pellets.

in, as it has been validated at high temperatures where radiation has

an appreciable contribution to the heat exchange. 2.3. Chemical reactions

2.2. Evaporation and condensation of moisture The rates of all chemical reactions including decomposition of

carbonates, combustion of coke and oxidation of magnetite are expressed

The drying of pellet can be best represented by a three stage model using a topochemical or unreacted shrinking core model (Levenspiel,

(Cumming and Thurlby, 1990; Seshadri and da Silva Pereira, 1985). In 1972). In this model, as schematically illustrated in Fig. 2, reaction

this model, before the pellet water content reaches a critical commences at the pellet surface and progresses toward the centre,

concentration, the rate of drying is controlled by mass transfer from leaving behind a shell of reaction products (voidage in case of carbon).

M. Barati / Int. J. Miner. Process. 89 (2008) 3039 33

the pressure drop across the bed, which is controlled by the fan draft.

The equation proposed by Ergun (1952) relates the pressure gradient

and gas ux as:

2

AP 150 g 1 b 1:751 b 2

2 3 G G : 17

Az dp dp 3b g

b g

tion/condensation or other reactions, the quantity and compositions

of both phases change with time and position. The changes in the gas

owrate and concentration of individual gas species are related to the

rate of reactions via Eqs. (18) and (19).

AG X

Ri 18

Az

Awi R

i Bi : 19

Az vg

Fig. 2. Schematic of the topochemical reaction progress model.

the mass of the reacting gas species to that of the solid through the

corresponding reaction i. (1 for water, 32/928 for magnetite oxidation

and so on). vg is the supercial gas velocity and is calculated from:

For magnetite oxidation, the reaction consists of three steps:

transfer of oxygen from the gas bulk to the pellet surface, pore G

diffusion through the hematite layer, and interfacial surface reaction vg : 20

g

with the magnetite particles, i.e.

Concentration of pellet constituents also changes according to:

1

2Fe3 O4 O2 Y 3Fe2 O3 : 13

2 Awj 1

Ri : 21

A kinetic model based on mixed control mechanism and applicable At 1 b

to the entire oxidation duration has been proposed by Papanastassiou

and Bitsianes (1973a) in the following form: 2.5. Pellet and bed shrinkage

drm COg 2 COe 2 Gas owrate and temperature prole of the pellet bed is strongly

14 inuenced by the compactness and the height of the pellet bed. The

dt m 2

rm 2

4 2k

rm

Drem r1m r1p k1mV previous models of pellet induration in straight-grate have been

O2 O2

where kO2 is the rate of oxygen gas phase mass transfer and is constant during the process. However, it is well known that the pellet

presented by an equation similar to Eq. (7), with DO2 replacing DH2O. porosity decreases signicantly after ring due to formation of semi-

Diffusivity of oxygen can be calculated from the correlation developed liquid slag phase and more importantly, due to solid state sintering

by Fuller et al. (1966) (Wynnayckyj and Fahidy, 1974). It is important to consider in the

model formulation the changes in the pellet physical properties and

9:2 1010 Tg1:75 their impact on the heat and mass transport phenomena.

DO2 : 15

PV Wynnayckyj and Fahidy (1972) have indicated that the shrinkage

km in Eq. (14) is the rst order rate constant for magnetite oxidation of pellet is a thermally activated process and can be related to the

which can be calculated from the correlations gathered from literature ring time and temperature as

and provided in the Appendix. V0 Vt

An expression similar to Eq. (14) is valid for the rate of carbon ks t n : 22

1 Vp Vt

combustion, with the difference being that the equilibrium oxygen

concentration is approximately zero in this case. This equation can be rearranged and differentiated to provide the

Calcination of carbonates is controlled only by temperature and rate of change in the pellet volume as:

can take place within the entire pellet when it reaches an appropriate

temperature. The rate of calcinations of dolomite or limestone is thus dVp nks t n1 V0 Vt ks t n

Vt : 23

expressed as: dt 1 ks t n 1 ks t n

Rl=d kVl=d ml=d 16 For a commercial iron ore concentrate, regression analysis of their

experimental data yields the following expressions for ks and n.

where ml/d is the concentration of the species of interest. Dolomite is

considered to decompose as two separate carbonates CaCO3 and MgCO3. 77000

ks 3:3 1021 exp 24

It must be emphasized that in the reactions' sub-model, it is T

assumed that all of the considered reactions can take place

simultaneously with distinct boundaries. n 13:18501:58622 102 T 4:88318 106 T 2 : 25

34 M. Barati / Int. J. Miner. Process. 89 (2008) 3039

shrinkage which in turn affects the characteristics of the bed such

as its height and void fraction. Hoffman and Finkers (1995) have

presented a model that relates the bed void fraction to density, size

distribution and sphericity of the randomly packed particles. This

model, shown in Eq. x(26) has been validated for a very wide range

temperature history of the pellet. At any new time (and tempera-

ture), rst an equivalent time at temperature, te, is calculated

from Eq. (22). This time is then substituted into Eq. (23) to calculate

the rate of volume change and the new volume for the pellet.

Using this value and the initial volume, the porosity can then be Fig. 4. Comparison between measured and predicted temperature proles in a pilot

determined. induration test.

M. Barati / Int. J. Miner. Process. 89 (2008) 3039 35

Table 1 equations are solved to yield temperatures and the reactions rates. The

Comparison between measured and calculated gas owrates of a straight-grate exit gas owrate and pressure drop across the element are then calculated

machine

using Eqs. (18) and (17) respectively. Thermodynamic and thermophy-

Process fan Measured Estimated Calculated Total % Difference sical properties of the gas and pellet are recalculated at the newly

owratea leakagea owrateb calculated obtained temperatures and substituted back in the same equations. This

(Nm3/s) (Nm3/s) (Nm3/s) owrate

process is repeated until the temperatures for two consecutive iterations

(Nm3/s)

agree to an acceptable accuracy. Calculations are then continued for the

Hood exhaust fan 116.5 40.9 81.3 122.2 +4.9

Windbox exhaust fan 176.0 23.9 138.3 162.2 7.8 next elements in the column until the owrates and pressure drops for all

Updraft drying fan 126.9 17.8 98.3 116.1 8.5 elements are obtained. The total pressure drop across the bed is then

Cooling-air fan 269.0 30.6 259.6 290.2 +8.1 calculated by summing all pressures losses. This value is compared with

a

Measurements reported by Hasenack et al. (1975). the measured P across the bed and if the error is adequately low, the

b

Flowrate through the bed, without taking into account the leakages. calculations are continued for the next time step. Otherwise, the initially

estimated owrate is adjusted proportional to the difference between the

of particle sizes and is used here to discuss the effect of pellet size calculated and measured pressure drops and the calculations are repeated

on the bed voidage. using this updated owrate as the starting value.

b 1 1 0:68exp 0:0371Vp dVp 0:32 exp1:72 0:848 : 26 4. Model validation

It can be demonstrated by using Eq. (26) that in the range of pellet size A complete validation of the model requires collecting data from an

(1014 mm) and density (~3000 kg/m3), and with the reduction in the operating plant under steady state conditions. Measuring temperature

pellet diameter being typically less than 10%, the changes in the bed void inside a moving bed and away from the side bars (to avoid effect of heat

fraction are not considerable in the induration process. This is in losses) is rather impractical. Therefore, temperature predictions were

agreement with other ndings, showing that the bed void fraction is not validated against measurements in a pilot pot-grate induration facility.

signicantly increased after ring. For example Wynnyckyj and Batterham The experiments were carried out in the pilot unit of pellet plant at

(1985) have discussed from an unpublished work of Thurbly that the bed Mobarakeh Steel Company (MSC). The pilot facility consists of a rotating

voidage of 0.37 for green bed increased to 0.39 after induration. It is disk for producing green pellets and a cylindrical pot furnace with an

therefore reasonable to assume that the effect of pellet shrinkage on the inside diameter of 26 cm and a height of 50 cm. Typically, for each

bed void fraction is negligible and it primarily gives rise to the bed slump. experiment,10 cm of red pellets are loaded onto the bottom plate of the

The bed height is thus related to the pellet porosity through: pot and the pot is lled with green pellets to a desired height, usually

35 cm. Five thermocouples, identied as T1 to T5 are positioned on top of

1p

H Hsl H0 : 27 the pellet bed, 5 cm, 25 cm, 35 cm below the surface, and 5 cm below the

b

bottom plate (in the gas duct), respectively. Pressure drop across the bed

and temperature readings are logged continuously during the indura-

3. Numerical solution procedure tion test. The details of measurements and also a mathematical model

for the pot-grate are discussed in a separate publication (Barati, 2008).

A computer program coded in Visual Fortran (Intel) and called The results are shown in Fig. 4. As seen, the model generated data

INDMOD was developed for numerical solution of the described coincide very well with the measurements. There are slight deviations

equations. Initially, the operating parameters of the system are set. between the thermocouple readings and the calculated values

These include pellet properties (size, sphericity, porosity, composition, particularly at high temperatures. This can be mainly due to the fact

and moisture content), induration machine parameters (length and that at high temperature, the radiation losses from the bed surface and

speed of the grate, lengths of various zones), and operating conditions the pot grate wall become signicant, while this has not been taken

(pressure drop and on-gas temperature in various cycles, bed porosity). into account in the model calculations. Moreover, the error in the

For solving the differential equations, a nite different scheme is used. thermocouple readings caused mainly by inaccurate positioning can

The bed of pellets is divided into several segments, forming a column of be in the order of deviations between the two values.

elements. The vertical spacing of the elements is set to an initial value of The model of straight-grate was further validated against gas ow

0.1 cm for the beginning of the process but is decreased corresponding to measurements reported by Hasenack et al. (1975). They measured the

reduction in the bed height as the temperature increases and the pellet gas owrates of an operating plant in the gas ducts by pitot tubes. The

undergoes shrinkage. The total process time is divided to 1 s time input parameters to the model such as gas temperature and pressure

intervals to ensure the stability of the solution and accuracy of the results. drops were extracted from their paper and the gas owrate was

The differential equations are discretized with respect to the distance calculated. Since the model provides the gas owrate through the bed

(height) and time and are solved subsequently. The calculations are made and not for the measurement points (in the ducts), the ingress owrate,

on nearly one million nodes for the base case of pellet bed height and estimated by Hasenack et al., were added to the model predictions to

grate speed. It was realized that for larger elements, the convergence may arrive at the total predicted ow. The results of the calculations are

not be reached under some conditions such as very small pellets, high compared with the measurements in Table 1. As can be seen, the model

rates of reactions, etc. The program was run on a 2.4 GHz personal calculations are within 10% of the measured values. Bearing in mind that

computer with the calculation time being normally 1 to 3 min. the calculations of gas leakage and also ow measurements by pitot tube

Integration of the discretized equations over the elements requires

determination of the gas owrate in each element. Generally, the pressure

drop measurements are more reliable and readily available than the gas Table 2

owrates. Therefore, it was decided to set the pressure drop as an input Values of process parameters used as the base case of simulation

parameter and calculate the gas owrate using Eq. x(17). However, this Parameter Value Parameter Value

approach requires iteration as the gas owrate is dependent on the Greed pellet bed depth 35 cm Magnetite content 41 wt.%

reactions rates and thus on temperature distribution. The approach Sub-layer depth 10 cm Pellet initial moisture 8.8 wt.%

toward simultaneous calculation of owrate and temperatures is shown Pellet diameter 1.3 cm Grate width 4.6 m

in Fig. 3. An estimate of the gas owrate is rst calculated via Eq. (17). This Pellet sphericity 0.95 Induration time 40 min

Pellet initial porosity 32% Pellet bed bulk density 2200 kg/m3

owrate is assigned to the rst element of the column and the differential

36 M. Barati / Int. J. Miner. Process. 89 (2008) 3039

shown in Fig. 5. It is seen that the drying of pellets in the middle of the

bed requires longer time than those in the top and bottom layers.

However, some condensation takes place in the top layer during the

updraft drying stage. The entire pellet bed is dried within the rst

10 min of the process. The drying times calculated using the model

agree well with the measurements of Seshadri and da Silva Pereira

(1985), showing that depending on the position in the bed and on-gas

temperature, drying will require about 5 to 10 min to complete.

Shape and size of the pellet have signicant impacts on the heating

and drying regimes. Fig. 6 illustrates the effects of pellet size and

sphericity varied between some arbitrarily selected values on the

maximum pellet temperature. It is palpable that more spherical and

larger pellets facilitate gas passage and enhance the heat transfer, thus

giving rise to the pellet temperature increase.

The pellet porosity is one of the most critical properties affecting both

strength of the burnt pellet and its reduction behavior in the down-

Fig. 5. Drying prole of pellet in different depths of the bed.

stream ironmaking process. The variations in the pellet porosity were

incorporated into the model as discussed previously. Fig. 7 depicts the

are subject to a few percent errors each, the predicted owrates are pellet shrinkage during the thermal treatment that was shown in Fig. 4.

considered well consistent with the actual values. It is seen that the pellet porosity of 0.32 for green pellets decreases to

0.22 for the burnt pellets. In this gure, the calculations have been

5. Simulation results and discussion compared with two measurements. In one experiment, the ow of hot

gases was stopped during the ring and the pellets were cooled by

All the input parameters to the model including arrangement of various owing nitrogen. The porosity was then measured for several pellets

zones, feed characteristics and operating conditions may be changed in- from this batch. In other experiment, the induration was completed. As

dividually or together to study the effect of these variables on the process shown, the model predictions are well consistent with the actual

performance. Each time the model is run, the following information are measurements, proving that the pellet shrinkage model is capable of

calculated and recorded for every element within the pellet bed: reproducing the actual values. The reduction in the pellet porosity, as

discussed earlier, gives rise to reduction in the pellet size and bed height.

Temperatures of gas and solid

These in turn affect the gas owrate in two opposing ways; bed slump

Chemical composition of pellet and gas

results in higher gas owrate (under constant pressure drop) and

Rate of reactions and moisture condensation/evaporation

smaller pellets create more resistance against the gas ow. The balance

Flowrate and pressure of gas

of the two effects determines the overall impact of the pellet shrinkage

Porosity of pellet and height of the pellet bed

on the gas owrate. Fig. 7 compares gas owrate for two cases: with and

In this article, results obtained from varying only a few of the input without considering the pellet shrinkage. As can be seen, the overall

parameters are discussed. The process characteristics used as the base error introduced by neglecting the pellet shrinkage is relatively small (3

case simulation are shown in Table 2. to 4%).

Fig. 6. Effect of (a) pellet size and (b) pellet sphericity on the maximum pellet temperature.

M. Barati / Int. J. Miner. Process. 89 (2008) 3039 37

Fig. 7. Variations of pellet porosity with induration time and the effect of porosity on the

Fig. 9. Effect of carbon addition on the temperature prole of pellet layer just above the

gas owrate.

heart layer.

5.2. Effect of pellet chemical composition evident from Fig. 9 that the addition of carbon increases the maximum

temperature together with the period the pellets remain at this

The favorable effects of magnetite presence in the iron ore feed on temperature. The strength of pellet from this layer thus should be

more uniform temperature distribution and pellet quality as well as enhanced substantially by addition of a proper amount of carbon.

reduction in induration energy consumption have been well recog- One of the great advantages of using simulation tools in process

nized and documented. The effect of magnetite content of the pellet analysis is giving insight into the details of different phenomena from

on the thermal behavior of the pellet is studied here using the model. several perspectives. Combustion of carbon, for instance, may be

Fig. 8 compares the maximum bed temperature for the base case visualized by presenting the variations in the oxidation rate, carbon

(40 wt.% magnetite) and magnetite pellets (95 wt.%). It is seen that the content, and temperatures or gas composition. As an example shown in

temperatures of the bed upper layers are not considerably inuenced Fig. 10, one can clearly determine the onset and duration of the reactions

by the heat release associated with the magnetite oxidation. On the from the changes in the gas oxygen content. The rst drop in this gure

other hand, a substantial temperature rise is realized in the bottom represents a decrease in the oxygen concentration because of the increase

layers of the bed, because the heat is gradually built up in the gases in water vapor content of the gas. The second valley points to decrease in

owing downward and exchanged more vigorously with the deep oxygen content by the oxidation reactions. It is apparent that the

layers of pellet. The magnetite oxidation, hence gives rise to a more magnetite oxidation (0% carbon case) consumes much less oxygen that

uniform temperature distribution, which in turn reduces the varia- then carbon combustion reaction (1% and 2% carbon cases). From this

tions in the quality of the produced pellets. gure, it can be concluded that the oxidation reactions begin after the

A similar improvement in the heating regime is achieved by addition pellet is dried and they take about 5 min to complete throughout the bed.

of carbon bearing materials to the pellet feed (Appleby and Shaw, 1985;

Audet et al., 2003). Fig. 9 depicts the effect of carbon addition on the 5.3. Effect of multiple variables

temperature variations in the pellet layer on top of the heart layer.

Typically, the pellets in this depth do not receive sufcient heat and the The model may be employed to investigate the effect of several

nal pellet strength is lower than those in the upper layers. It is well parameters on the induration performance and determine the optimum

operation or deign conditions. For example increasing the bed height

Fig. 8. Effect of pellet feed magnetite content on the bed temperature prole. Fig. 10. Oxygen content of the gas versus time in a layer just above the heart layer.

38 M. Barati / Int. J. Miner. Process. 89 (2008) 3039

h Heat transfer coefcient (J.m 2.s 1.K 1)

kg Thermal conductivity of gas (J.m 1.s 1.K 1)

km First order rate of magnetite oxidation (m.s 1)

kl/d First order rate of lime/dolomite decomposition (s 1)

kc First order rate of carbon combustion (m.s 1)

kO2 Mass transfer coefcient in the gas of oxygen (m.s 1)

ks Rate constant of pellet shrinkage (s 1)

kw Mass transfer coefcient in the gas of water vapor (m.s 1)

ml/d Concentration of lime/dolomite (kg/m3)

n Constant in pellet shrinkage equation ()

Nu Nusselt number Nu = hdp/kg

P Gas pressure (Pa)

P Gas absolute pressure (atm)

Pr Prandtl number (Pr = gCg/kg)

Rep Pellet Reynold's number (Rep = Vggdp/g)

Ri Rate of reaction i (kg.m 3.s 1)

Rw Rate of water evaporation/condensation (kg/.m 3.s 1)

Rl/d Rate of decomposition of lime/dolomite (kg/.m 3.s 1)

Fig. 11. Effect of carbon addition on temperature of pellet layer 45 cm below the surface Sc Schmidt number (Sc = g/gDi)

of a 55 cm pellet bed.

t Time (s)

Tg Gas temperature (K)

and pellet throughput is generally limited by two factors: disintegration Tp Pellet temperature (K)

of weak pellets in the bottom layers due to static load of the bed, and Tw Wet bulb temperature (K)

inadequate heat supply to the same layers during ring. While the V0 Volume of raw pellet (m3)

disintegration problem may be mitigated by appropriate choice of Vp Volume of pellet at any time (m3)

binder type and content, additional heat can be provided to the bottom vg Gas velocity (m.s 1)

layers by addition of coke breeze as an auxiliary heat source. This Vt Volume of pellet containing no porosity (m3)

scenario has been examined using the model and the results are rh Relative humidity of the gas

presented in Fig. 11. The bed height was increased to 55 cm and the rm Radius of unreacted magnetite core (m)

temperature prole was calculated for two cases, without carbon and 1% rp Radius of pellet (m)

carbon addition. Fig. 11 compares the temperature of the pellet bed in rw Radius of wet core of the pellet (m)

35 cm depth for the two situations. As seen, in the case of carbon-free wg Moisture content of the gas (kg.m 3)

feed, the maximum temperature is below 1100 C, which is insufcient weg Equilibrium concentration of water vapor between gas/solid

for heat hardening of the pellets. Addition of 1% carbon however (kg.m 3)

increases the temperature to 1220 C for a fairly steady period of about wi/j Concentration of gas (i) or solid (j) constituents (kg.m 3)

8 min. Therefore, the negative effect of increasing the bed height can be z Depth of pellet bed (m)

compensated for by carbon addition.

Greek Symbols

6. Conclusions i Fraction of heat from reaction i, retained by solids

b Void fraction of pellet bed

A model of pellet induration process in moving straight grate has p Pellet porosity

been developed. All major reactions and physical changes taking place p Porosity of raw pellet

throughout the process have been incorporated into the model. g Gas viscosity (kg.m 1.s 1)

Comparisons with logged data from an operating plant and direct p Specic gravity of pellet ()

measurements in a pilot pot grate have indicated that the model b Bulk density of pellet bed (wet/dry) (kg.m 3)

predictions are well consistent with the actual values. By simulating g Density of gas (kg.m 3)

several scenarios, it was demonstrated that the model provides insight Pellet sphericity

into the details of the process and can be deployed as a valuable tool for Hi Enthalpy of reaction i (J.kg 1)

design of the furnace and optimization of the process. Hv Enthalpy of moisture evaporation/condensation (J.kg 1)

graphically determined standard deviation of log-normal

Nomenclature particle size distribution

A Gaspellet apparent contact area (m 1) Tortuosity

Bi Stoichiometric coefcient relating gas consumed/released

per unit wt. of solids reacted (32/12, 32/928 for magnetite Acknowledgments

oxidation, and so on)

Cg Specic heat of gas (J.kg 1.K 1) The author wishes to thank R&D department and pelletizing plant of

Cp Specic heat of pellet (J.kg 1.K 1) Mobarakeh Steel Company, Mr. R. Saoleimanpour in particular, for

Di Diffusivity of component i (m2.s 1) nancial support of the project and conducting the pilot tests. The

Die

Effective diffusivity of component i (m2.s 1) contributions by Dr. A. Saidi and Dr. M. Alizadeh are greatly appreciated.

dp dimensionless pellet diameter in m divided by a scale of

1 m () Appendix A. Supplementary equations and constant used in the

dp Pellet diameter (m) model

G Supercial gas owrate (kg.m 2.s 1)

H Pellet bed height (m) Many correlations for calculations of physical and transport

H0 Initial height of the raw pellet bed (m) properties and thermokinetics of the reactions were used in the

M. Barati / Int. J. Miner. Process. 89 (2008) 3039 39

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DCO2

PV (Fuller, 1966) Parsons, R. (Ed.), 2005. ASHRAE Handbook Fundamentals, ASHRAE, Section 6.9.

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> 2 2 2 5 2 Kogakusha, Tokyo.

> 173:44:166rh 2:57 10 rh Tg 0:3648 1:4585 10 rh 8:688 10 rh Tp b 373 K

>

< Ranz, W.E., 1952. Friction and transfer coefcients for single panicles and packed beds.

2

Tw 197:7 125:753rh 11:64749rh2 Tg 0:39640:697929rh 6:31750 10 rh2 Chem. Eng. Prog. 48, 247253.

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> 2

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