Note. (0) Orne! + cH, 20H CH Br +h. zcw-cn,-0, overt no fokeres ® Oct coche o Solventes , “pelares Mek: Algulacicnc vs plqulacith © dec fe bo (ae Cents Clg “CH=CH ach cr=cy, 25 OF Produc to Cinetico Producto Termed inam'co fore eae ie p (oH 4 ct gg Hs oa ° (oon + tein y fase cy Chee! 3 ° Clty theo.) on & Sila °. Neo, Feno Preparacion : @Fesicn Alaina ce feilealpenates O-e® Sa 66 @ bideclisis de Halaros Arilicos aa md OWa* ea + _AaoH @) act 2.) 350°C -Palta no2 ea on Ac. Riento Gs @ Sinfess del Hid WOz, eroxido de Gemeno * Ci cH-cet, He + CHy-cH =the, > ‘ # y= cu-CHs re Oe woche @ i Revisar el caprtule de Haleros Alqui lites ies 2 @ peclicos para lx onlerfecin de ke reacth: Eee (oy) denis para ebicrar cf procucko eha'ree 7 ne : Terwedincinice # En este paso 20 apliza atti diluide, Recacer : Hideélisis de Sales de Diazowo + Reaeciones hotter lencrién de fcvdez + he mater ou CQ 4 Mann HCL ee “HsSdy Cl Ko, [KO = H.CO3 o-s-e 700°C * Tambits 30 puede utilizar HAO, pena preparae Opa aecl —(o}onet la sal de diazont. O utes cored AMLIB! orice Ete Co + TilocccFs), (ey ch cooH OCG) OF 12H (BY cme” Heth le, 5) oo Ti (over ja Ah Los acdes regenerom al p enol ease ae Fo cl ¢ si eo + PL(ACOn Trijcheroactbie ©CO)-OH #2824, (Bont thn0- Jere — psa See uae le clore berceno _ : o-¢-CFs (ope-cts #2h Sve A se ¢! e A 0 clly-CH, + ho, Gy rl eo B{O)-mO2 + ciscH,or% Oy ce esc a S — © No,Neta. ® 29, (Oot ct BS cn,-on cl Qi ag Ser ~ ren § 20. (o> ¢- cH, “BS fo) é. ~ cH a (o> cel HS (6) coon DyPeaccines che substi fies ° 4 fra + Bo tile om D> Logg a. & ae F LL Dhwo. CL Cree @ Trans posicidn de Fries + o- C-cly , of - onl Cl co ot cre® + Pero cuando para esta capade, solo es ener, O=c- chy [ Ani'lle Aromat E® Reaceién de Halogenacih » en (oF +380, es a (oon + br. “GE @ Gr”(BB heac ih de M'fraciy ; ‘oe 2 oH (oon + Hees o . (er 2orc On >a uilaci&s de Feroles cls (odon +c-d-c1 the chy 4 7 seusa Ady , yer que es erkicado pore! -On & Dy Reacaisn de_Aerlacidy - ow ° P Beh OH 4 CMs CH oy. ee u-c~cH, note + P of o-¢-cr, et ciged C+ Se AlCl e ¥ ae che ores 3 one AlCl cee “tore Reaccion de Sulj ncicidh @ on ze (one 4 Cl Ha5Om eo] wee? Has04/ to0%e oor S Ao Reaccién de Carbonatacion + Onnet ee £ a5°g oy ca (ole Year Bor oe en pare GD Reaceisn de Reimer- Tema « of CHO ye (one ow (oO) + Ae lawn, FOr’Subsh' tucson Electrogriica : ® =OR activante moderado —~v ovientnciy orto y pera Grect, Brae) cers © oy ee ce 8. DyReacciones de los £ ED En _nedio aide xrdos + as CHy-Ch-CH, + CHy cis, CH t are HNO; WS0% once CHiy- CH= CH.“ O# raw 5 ce CHp-ch- Ct, + Cig ct O78", Hy CH CHa luego H+ © -Chh- Cty ED Con Reaetives de Origrord o* hos : cee curate # cect BE chy Hatt, E teres Preparacisn BPs hidnstaciom de Aleoholes - H2s0n Wee Perea ee aB0%¢ CHs- Chon CH -Cly-O- Cth Cy 180% wo ta Hy & ph-CH,-o-cm-Ph Teor : Se produce a tore © aq 1Borc ® Sintes’s de Wrillbamson Estadiada ew fevoles. Ph- Chon ) Aleoximercuracisn- Demercuvacb’n, » i) OH a) ty (00C ch), Ph- ¢- cHzcHty + cly-cit-city Ds OPC) fs by aa Bth, cH —— Ph-d ~ cH chy Sy b-cH-ciy cu x Adicisn Mor Kovw' Kou * No hay reordena miewto(Dpobteniin de Epoxides por peroxrdeciis do) (Q Deqraccise de bs E teres : @ Alquenos # Perexiatides D+ cco — © ebtercitn de Epoxides a perrtiv de Helohiclnines: Ph-cooolk , cH coool, yoosoH br, Ph fe Om Prochech, B= ph Chace, A> phciac, @obtencién industrial del Orde ne» a he + thOstbe , of Sy, 25 CWy-B-CHy + BF, —> CH- 6-H, “Br, Reactives: HB-la , HIM, Hsu ily te O-Chy + BB coy-co-om + chly ite | vot CHy- CHa Be (eporemeety + HE, Don + cmyete® # Con HSOufd ler reaceiiy es de elimmnacvs » CHhyrci-o-chcy MER CHaCHly + hy Cth OH [He Cis CH CHy=Cal- Hs a H-c,-0-(0) HES cHsctes (oo Cty-ctn0- Oy HE ca net, + Oye © Formocién de Peroxites + City “GH, O-Gt, +O, ——? Cl CH- OCH, 0-0-4Gonprestes_ Poli nidroxilades ©) @ Glicecing cH Ce cH, = cH -ch, AE Oh, a Ba CMe CH= ts Che - cht, Cit, -Ct- CHa Be, as On O4 OF @ nitro glicerina - CH,- OH Ch, 0-7% 1 tsoy Cy-On 4 BHA; =F Cy o- WO, + 3D 1 City-oH CHO“ VO @ Resoreivol * on 22H on Hts (Von pide on On age ow@ cateco! : a{oy on Ae08 (oyon tele (eden 3 03Aa one OH a (open Bes (5.01 Sets OH Gusyacel (ore are ree ETO to © Guinona [Dppidroguinone : ose + Fesae-(o-on wood on t Ae,CrOulte, 92/7)»