Beruflich Dokumente
Kultur Dokumente
LABORATORY1/
1/
A project report presented in partial fulfillment of the requirement of the course
in AE 173 Refrigeration and Air Conditioning for the Degree of Bachelor of Science in
Agricultural Engineering of the Visayas State University, Visca, Baybay City, Leyte under
the guidance of Engr. Ramon Orias.
INTRODUCTION
Background
Petroleum (from Latin: petra: "rock" + oleum: "oil".) is a naturally occurring,
yellow-to-black liquid found in geological formations beneath the Earth's surface, which
is commonly refined into various types of fuels. Components of petroleum are separated
using a technique called fractional distillation. [1]
It consists of hydrocarbons of various molecular weights and other organic compounds.
The name petroleum covers both naturally occurring unprocessed crude
oil and petroleum products that are made up of refined crude oil. A fossil fuel, petroleum
is formed when large quantities of dead organisms, usually zooplankton and algae, are
buried underneath sedimentary rock and subjected to both intense heat and pressure.
Petroleum has mostly been recovered by oil drilling (natural petroleum springs are rare).
Drilling is carried out after studies of structural geology (at the reservoir scale),
sedimentary basin analysis, and reservoir characterization (mainly in terms of
the porosity and permeability of geologic reservoir structures) have been completed. [2] It
is refined and separated, most easily by distillation, into a large number of consumer
products, from gasoline (petrol) and kerosene to asphalt and chemical reagents used to
make plastics and pharmaceuticals. Petroleum is used in manufacturing a wide variety
of materials, and it is estimated that the world consumes about 95 million barrels each
day.
Concern over the depletion of the earth's finite reserves of oil, and the effect this would
have on a society dependent on it, is a concept known as peak oil. The use of fossil
fuels, such as petroleum will have a negative impact on Earth's biosphere,
damaging ecosystems through events such as oil spills and releasing a range of
pollutants into the air including ground-level ozone and sulfur dioxide from sulfur
impurities in fossil fuels. The burning of fossil fuels plays the major role in the current
episode of global warming.
Physical Characteristics and its Composition
In its strictest sense, petroleum includes only crude oil, but in common usage it includes
all liquid, gaseous and solid hydrocarbons. However, in an underground oil reservoir the
proportions of gas, liquid, and solid depend on subsurface conditions and on the phase
diagram of the petroleum mixture. [3]
An oil well produces predominantly crude oil, with some natural gas dissolved in it.
Because the pressure is lower at the surface than underground, some of the gas will
come out of solution and be recovered (or burned) as associated gas or solution gas.
A gas well produces predominantly natural gas. However, because the underground
temperature and pressure are higher than at the surface, the gas may contain heavier
hydrocarbons such as pentane, hexane, and heptane in the gaseous state. [4] At surface
conditions these will condense out of the gas to form natural gas condensate, often
shortened to condensate. Condensate resembles gasoline in appearance and is similar
in composition to some volatile light crude oils.
The proportion of light hydrocarbons in the petroleum mixture varies greatly among
different oil fields, ranging from as much as 97 percent by weight in the lighter oils to as
little as 50 percent in the heavier oils and bitumen. [5]
The hydrocarbons in crude oil are mostly alkanes, cycloalkanes and various aromatic
hydrocarbons, while the other organic compounds contain nitrogen, oxygen and sulfur,
and trace amounts of metals such as iron, nickel, copper and vanadium. Many oil
reservoirs contain live bacteria. [6] The exact molecular composition of crude oil varies
widely from formation to formation but the proportion of chemical elements varies over
fairly narrow limits as follows:
Composition by weight
Element Percent range
Carbon 83 to 85%
Hydrogen 10 to 14%
Nitrogen 0.1 to 2%
Oxygen 0.05 to 1.5%
Sulfur 0.05 to 6.0%
Metals < 0.1%
Of all energy sources, liquid hydrocarbon, a form of fossil fuel, occupies the biggest
portion of the Philippine energy mix, largely because of its tremendous varied and
efficient utility. It is singularly the most important component of a nation's economic
structure, so that the exploration and development of one's indigenous source of crude
oil is always a primary undertaking in any country.
Sectors of Petroleum
Crude oil is one of the most valuable commodities in the world, but only after it has
been refined into petroleum products. Crude oil refining is a key transformation step in
the Midstream Sector of the oil and gas value chain (Figure below) because it adds
commercial value to the oil by transforming it into many different marketable products.
Two Kinds of Heat in the Design of Air Conditioning
The two kinds of heat plays important role in the design of air conditioning unit, those are
sensible and latent heat.
Latent Heat (LS): Heat that changes the state of matter from solid to liquid or liquid to
gas is called latent heat. The latent heat of fusion is that which is needed to melt a solid
object into a liquid. A property of the material, it is expressed per unit mass (per pound
or per kilogram). The latent heat of vaporization is the heat required to change a liquid to
a gas. When a gas liquefies (condenses) or when a liquid solidifies, it releases its latent
heat.
Enthalpy: It is the sum of the sensible and latent heat of a substance. For example, the
air in our ambient environment is actually a mixture of air and water vapor. If the total
heat content or enthalpy of air is known, and the enthalpy of the desired comfort
condition is also known, the difference between them is the enthalpy or heat that must
be added (by heating and humidification) or removed (by cooling and dehumidification).
A packaged system always has a refrigeration system that uses a DX-coil to cool
air directly.
A central system has a refrigeration system that uses chilled water as a cooling
medium to cool air indirectly. In addition, in order to designate an air conditioning
system more clearly and correctly, the main characteristics of its air system may
be added to the description of its basic category (that is, individual, packaged, or
central). More clearly specified terminology for an air conditioning system with a
designated air system and primary cooling and heating plant is a combination of
items from two or three of the following columns.
Process Flow
B. The Pocess
C. Operations in Petroleum Processing
e. Solve;
1 = 1 + 1 1 = (1.0062*10) + (0.0023*2519.8) = 15. 86 kJ/kg
2 =1 =0.0023 kg/kg
2 = 1=0.369 kPa
0.369
2=2 = 1.8168 = 0.203 or 20. 3%
2
d. Solve
i. Solve
b. Ceiling conduction
1. Outside airfilm 0.029
2. Sheating fiber 10 0.232
board
3. Gypsum board 10 0.08
4. Inside airfilm 0.12
(29C-
(11*15)=165
Sub-total 20 0.461 20C)=9 4.7
C
c. Door conduction
1. Outside airfilm 0.029
2. Aluminum with 5 0.32
insulation
3. 2-airspace 15 0.34
4. Gypsum board 10 0.08
5. Inside airfilm 0.12
A1=16 9C 0.162
Sub-total 20 0.889
A2=3 9C 0.03
Over-all total 8.692
Therefore;
3 = + + = 1.125kJ/s + 0.8952 kJ/s + 1.83kJ/s =3.8502kJ/s
iv. Solar load: Minimal effect due to complete shading of the walls.
v. Sensible heat load, 6 hrs cooling period
140kg petroleum supply
Petroleum has a specific gravity of 0.88 which means 1 liter
weighs 0.88 kilograms.
So 1 barrel weighs:
158.9872972 * 0.88 = 139.908821536 kilograms
= 140 kilograms (7)
= 980 kilograms/day
= 29C, = 20C
= 0.963
Thus,
(980)( 0.963)(29C20C)
5 = ( - )= 63600
= 0.393225kJ/s
Therefore;
0.0012 gm 2 2850 kJ 1 hr
6 = x x 980 kg x = 0.00353 kJ/s
264 2 3600 .
= 1 + 2 + 3 + 5 + 6
= 8.692 kJ/s + 1.04304 kJ/s + 3.8502kJ/s + 0.393225kJ/s + 0.00353 kJ/s
= 13.981995 kJ/s
For 50% safety factor
2 = 13.981995 kJ/s (50%) + 13.981995 kJ/s
2 = 20.9729925 kJ/s
k. Needed mass of air
Energy balance about the Powder Storage
2 (2 2 ) = 2
2 . /
2 = ( )
=(34.84556 kJ/kg 21.92027 kJ/kg) = 1.622 kg/s
2 2
l. Volume of air; 2
2 = 2 (2 1 )
kJ kJ
2 = 1.622 kg/s(21.92027 kg 15.86 kg
)
2 = 9.83 kJ/s
4. Moisture removal in this area
2 = 2 (2 2 )
2 = 1.622 kg/s (0.0058 kg/kg 0.0023kg/kg)
2 = 0.005677 / of moisture
2 = 5.677 / of moisture
3 =1 =0.0023 kg/kg
3 = 1=0.369 kPa
0.369
3=3 = 2.062 = 0.17895 or 18%
3
d. Solve
i. Solve
j. Cooling load
b. Ceiling conduction
1. Outside airfilm 0.029
2. Sheating fiber 10 0.232
board
3. Gypsum board 10 0.08
4. Inside airfilm 0.12
(29C-
Sub-total 20 0.461 (5*5)=25 23C)=6 0.542
C
c. Door conduction
1. Outside airfilm 0.029
2. Aluminum with 5 0.32
insulation
3. 2-airspace 15 0.34
4. Gypsum board 10 0.08
5. Inside airfilm 0.12
(29C-
Sub-total 20 0.889 23C)=6 0.052
C
Over-all total 1.62
Therefore;
3 = + + = 2.5 kJ/s + 1.1936 kJ/s + 4.066kJ/s = 7.7596 kJ/s
iv. Solar heat load: Minimal effect due to complete insulation/shading.
So 1 barrel weighs:
158.9872972 * 0.88 = 139.908821536 kilograms
= 140 kilograms (7)
= 980 kilograms/day
= 29C, = 23C
= 0.963
Thus,
(980)( 0.963)(29C23C)
5 = ( - )= 63600
= 1.266 kJ/s
Therefore;
0.0012 gm 2 2850 kJ 1 hr
6 =
x 264 x 980 kg x 3600 . = 0.00353 kJ/s
2
= 1 + 2 + 3 + 5 + 6
= 1.62 kJ/s + 0.1944 kJ/s + 7.7596 kJ/s + 1.266 kJ/s + 0.00353 kJ/s
= 10.84353 kJ/s
3 (3 3 ) = 3
3 . /
3 = ( = (40.8223.94) = 0.9636 kg/s
3 3 )
l. Volume of air; 3
3 = 3 (3 3 )
3 =0.9579 kg/s (0.00695 0.0023)
3 = 0.004454 / of moisture
3 = 4.454 / of moisture
4 =1 =0.0023 kg/kg
4 = 1=0.369 kPa
0.369
4=4 = 2.339 = 0.1577 or 15.8%
4
d. Solve
i. Solve
b. Ceiling conduction
1.Outside airfilm 0.029
2.Sheating fiber 10 0.232
board
3.Gypsum board 10 0.08
4.Inside airfilm 0.12
(29C-
Sub-total 20 0.461 (2*5)=10 25C)=4 0.174
C
c. Door conduction
1.Outside airfilm 0.029
2.Aluminum with 5 0.32
insulation
2-airspace 15 0.34
3.Gypsum board 10 0.08
4.Inside airfilm 0.12
(29C-
Sub-total 20 0.889 25C)=4 0.035
C
Over-all total 0.68
=(5hp)(0.746)(0.08)(3)=0.8952 kJ/s
3. Workers , 5 including the operator and stay 8hrs/day
305/58
= = 0.5083kJ/s
241000
Therefore;
3 = + + = 0.125 kJ/s + 0.8952kJ/s + 0.5083kJ/s = 1.5285 kJ/s
= 1 + 2 + 3 + 5 + 6
= 0.68+ 0.102 + 1.5285
= 2.3105 kJ/s
For 50% safety factor
4 = 2.3105kJ/s(50%) + 2.3105
4 = 3.46575 kJ/s
k. Needed mass of air, 4
Energy balance about the office
4 (4 4 ) = 4
4 ./
4 = ( =(43.1853825.964) = 0.2012 kg/s
4 4 )
l. Volume of air; 4
4 = 4 (4 1 )
4 =0.2012 (25.96 15.86)
4 =2.03212 kJ/s
4 = 4 (4 4 )
4 =0.2012(0.00788 0.0023)
4 = 0.001123 / of moisture
4 = 1.123 / of moisture
5 =1 =0.0023 kg/kg
5 = 1=0.369 kPa
0.369
5=5 = 1.4022 = 0.263 or 26.3%
5
d. Solve
5 = 5 + 5 5 = (1.0062*12) + (0.0023*2523.4) = 17.88 kJ/kg
e. Design room condition
j. Cooling load
b. Ceiling conduction
1.Outside airfilm 0.029
2.Sheating fiber 10 0.232
board
3.Gypsum board 10 0.08
4.Inside airfilm 0.12
5.mineral fiber 50 1.94
(13*23)=299 (33C-
Sub-total 70 2.401 2.24
15C)=18C
c. Door conduction
1.Outside airfilm 0.029
2.Aluminum with 5 0.32
insulation
2-airspace 15 0.34
3.Gypsum board 10 0.08
4.Inside airfilm 0.12
5.mineral fiber 90 1.94
(29C-
Sub-total 110 2.829 0.079
15C)=14C
Over-all total 4.419
=(1)(2hp)(0.746)(0.08)=0.11936 kJ/s
3. Workers , 2 including the operator and stay 4hrs/day
305/24
= 241000
= 0.102 kJ/s
Therefore;
3 = + + = 0.075 kJ/s + 0.11936kJ/s +0.102kJ/s = 0.296 kJ/s
So 1 barrel weighs:
158.9872972 * 0.88 = 139.908821536 kilograms
= 140 kilograms (7)
= 980 kilograms/day
= 29C, = 23C
= 0.963
Thus,
(980)( 0.963)(29C23C)
5 = ( - )= 63600
= 1.266 kJ/s
= 1 + 2 + 3 + 5 + 6
= 4.419 kJ/s + 0.35352 kJ/s + 0.296 kJ/s + 1.266 kJ/s + 0.00353 kJ/s
= 6.33805 kJ/s
5 (5 5 ) = 5
5 . /
5 = ( =(37.8517.88) = 0.4761 kg/s
5 5 )
l. Volume of air; 5
5 = 5 5 = (0.4761 kg/s)( 93.7843 /kg) = 44.65063 /s or
2679.0333 /min.
5 = 5 (5 1 )
5 = 0.4761(17.88 15.86)
5 = 0.9617 kJ/s
5 = 5 (5 5 )
5 =0.4761 (0.009 0.0023)
5 = 0.00319/ of moisture
5 = 3.190 / of moisture
Zone 5. Processing Equipment Building
d. Solve:
hs6 = Cp Ts6 + W s6 hgs6 = (1.0062*20) + (0.002592*2538.2) = 26.7030 kJ/kg
e. Design room conditions: T6 = 24C; RH6 = 45%, u, air velocity = 0.25 m/s
f. Read: Pd6 = 2.982 kPa, hg6 = 2545.5 kJ/kg, vg6 = 45.93 m3/kg
h. Solve:
(0.622)6 (0.622)(1.3419 )
6 = 6
= 101.31.3419
= 0.00835 kg/kg
i. Solve:
Material
A. Wall Conduction
1. Outside airfilm 0.029
2. Face brick, 50 mm 0.038
3. Concrete, 120 mm 0.066
4. Gypsum board, 10 0.080
mm 0.120
5. Inside airfilm 0.333 160 6 2.883
A. Ceiling Conduction
1. Outside airfilm 0.029
2. Sheating fiber board, 0.232
10 mm 0.80
3. Gypsum board, 10 0.120
mm 0.461 100 9 1.952
4. Inside airfilm
Sub-total 4.835
ii. Infiltration Load: Heat gain due to the entry of outdoor air through door
opening/closing is assumed 10% of the transmission load.
Q2 (10%) = 0.10(4.835) = 0.4835 kJ/s
=(12)(3hp)(0.746)(0.08)=2.14848 kJ/s
3. Workers,5 including the operator and stay 8hrs/day
305/58
= 241000
= 0.5083kJ/s
Therefore;
3 = + + = 0.6 kJ/s +2.14848 kJ/s +0.5083kJ/s = 3.257kJ/s
iv. Solar heat load: Minimal effect due to complete insulation/shading.
v. Sensible heat load, 12 hrs cooling period in this area and 12 hrs maintaining
So 1 barrel weighs:
158.9872972 * 0.88 = 139.908821536 kilograms
= 140 kilograms (7)
= 980 kilograms/day
= 29C, = 20C
= 0.963
Thus,
(980)( 0.963)(29C20C)
6 = ( - )= 63600
= 0.0393 kJ/s
Therefore;
0.0012 gm 2 2850 kJ 1 hr
6 =
x 264 x 980 kg x 3600 . = 0.00353 kJ/s
2
= 1 + 2 + 3 + 5 + 6
= 4.835 kJ/s + 0.4835 kJ/s + 3.257kJ/s + 0.0393 kJ/s + 0.00353 kJ/s
= 8.618 kJ/s
For 50% safety factor
5 = 8.618 kJ/s (50%)+8.618 kJ/s
5 = 12.9272kJ/s
6 (6 6 ) = 5
6 ./
6 = ( )
=(45.40426.7030 ) = 0.6913 kg/s
6 6
l. Volume of air; 6
6 = 6 (6 1 )
6 =0.6913 (26.7030 15.86)
6 =7.496 kJ/s
6 = 6 (6 6 )
6 =0.6913(0.00835 0.002592)
6 = 0.00398 /
6 = 3.98 / of moisture
Plant Layout of a Petroleum Refinery Laboratory
Site Development Plan