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1. pH OF DEIONIZED WATER
120 6.19
140 6.09
160 5.71
180 5.53
Comment: The pH of deionized water tends to be lower than normal water because the
dissolved salts (ions) in the normal water can neutralize that is also dissolved in the water.
2. pH OF STRONG ACID
Data Calculation:
The current [OH-] = n/V = 9x10-4/0.19. Thus the final pH = 14 - (-log[9x10-4/0.19) = 11.7
Comment: The pH value depends on concentration of H+ .Strong acid often have a small pH
value because the it dissolves completely in water to produce the large amount of H+ . The pH of
strong acid will be increase when [OH-] is increased. The reality value of pH in the experiment is
different comparing with the theoretical one due to the laboratory conditions and the mistake
during experimental procedure.
3. pH OF WEAK ACID
0.1M acetic 2.67 4.67x10-5 CH3COOH plays role as the very weak acid,
acid results in dissolving partially and forming little
H+, which leads to the pH value is higher than
0.01M acetic 3.05 8.72x10-5 the strong acid. The less concentration of H+ in
acid the acetic acid solution, the more increasing in
0.001M 4.12 6.23x10-6 the pH value.
acetic acid
Data Calculation:
CH3COOH H+ + CH3COO-
Initial 0.1 0 0
(CM)
Change -x x x
Equilibrium 0.1-x x x
[H ][CH3COO ] x2
[CH3COOH] 0 .1 x
Thus the Ka = = = (10-2.67)2/0.1 - 10-2.67 = 4.67x10-5
Second, 0.01 M acid acetic and applying the same equation above
[H ][CH3COO ]
[CH3COOH]
Thus the Ka= = (10-3.05 )2/0.01- 10-3.05 = 8.72x10-5
Third, 0.001 M acid acetic and applying the same equation above
[H ][CH3COO ]
[CH3COOH]
Thus the Ka = =(10-4.12 )2/0.001- 10-4.12 = 6.23x10-6
[H ][CH3COO ]
[CH3COOH]
Ka= = (10-4.12 x 0.001)/0.001= 6.3 x 10-5
4. pH of SALTS:
0.1M NaCl 7 5.45 NaCl is a salt of strong acid (HCl) and a strong
base (NaOH), which makes NaCl have the
0.1M >7 7.11
neutral property and the pH value reach to 7
CH3COONa
CH3COONa is the salt of a weak acid
0.1M NH4Cl <7 6.02
(CH3COOH) and the strong base (NaOH),
which makes this substance have the base
property and the pH value is larger than 7.
Comment:
The pH of the salts depend on the compound of that substance, if the compound is the strong
non-metal such as Na and the weak acid component such as CH3COO-, the pH is over 7, on the
contrary, the pH is less than 7, and if 2 components are strong acid/base, the solution becomes
neutral.
5. pH of BUFFERS:
Data Calculation:
CH3COOH CH3COO- + H+
0.001 x x (mol)
n 0.001
V 0.01 0.04
[Acid] = [CH3COOH] = 0.02 M
n 0.004
V 0.01 0.04
[Base] = [CH3COONa] = 0.08 M
[H][CH3COO ] 0.08 x
[CH3COOH] 0.02
Ka= = = 1.8 x 10-5
Comment
Buffer A have the highest pH value because it contain more CH3COONa ( basic salt)
Buffer B have the smallest one, because it contain more CH3COOH ( acid)
pH value of buffer C is at the middle because of the same amount of CH3COONa and CH3COOH
in this solution
When we add acid HCl into the buffer, the pH value decrease because concentration of H+
increases
On the other hand, we add base NaOH, pH increases because concentration of H+ decreases.