Topics: Thermo dynamics, Thermo chemistry, Groups 15 to 17 & Electrochemistry

Single correct Questions

1. If enthalpy of hydrogenation of C6H6 (l) in to C6H12 (l) is -205 KJ and resonance energy of benzene is -152KJ/mole, then
the enthalpy of hydrogenation of cyclohexene is (Assume enthalpy change for the vaporization of benzene, cyclohexane
and cyclohexene are equal).
(a) -535.5KJ/mole (b) -238KJ/mole (c)-357KJ/mole (d)-119KJ/mole.

2. 2 moles of an ideal monoatomic gas undergoes a reversible process for which PV 2 = Constant. The gas is expanded from
initial volume of 1 L to final volume of 3 L starting from the initial temperature of 300 K. find the enthalpy change for this
process
(a) -600 R (b)-1000R (c)-3000R (d) none of these

3. Enthalpy of neutralization of H3PO3 is -106.68 KJ/mole using NaOH. Calculate the enthalpy change for the ionization (in
KJ/mole) of H3PO3 in to its ions
(a) 50.84 (b) 5 (c) 2.5 (d) none of these

4. Which of the following is correct?

(a) S3O9- contains no S-S linkage (b) S2O62- contains O-O linkage
(c) (HPO3)3 contains P-P linkage (d) S2O82- contains S-S linkage

5. For the hypothetical reaction A2 (g) + B2 (g)

2 AB (g)
r G and r S are 20KJ/mol and -20J/K/Mole respectively at 200 K. If r C p 20 JK-1 then r H o
o o

At 400 K is
(a) 20 KJ/mole (b) 7.98KJ/mole (c) 28KJ/mole (d) none of these

6. Cl2 + Ba(OH)2 X(aq) + BaCl2 + H2O

X + H2SO4 Y + BaSO4

Y
365K Z + H2O + O2
Y and Z respectively are
(a) HClO4, ClO2 (b) HClO3, ClO2 (c) HClO3, ClO6 (d) HClO4, Cl2O7

7. What is the normal boiling point of mercury if H of (Hg,l) = 0, S0(Hg,l)=77.4j/K/mol

H of (Hg,g) =60.8KJ/mol S0(Hg,g)=174.4J/Kmole
(a) 624.8K (b) 626.8K (c) 636.8K (d) none of these

8. If H of (C2H4) and H of (C2H6) are x1 and x2 k cal /mole respectively, then the heat of hydrogenation of C2H4 is
(a) X1+X2 (b) X1-X2 (c) X2-X1 (d) X1+2X2

9. Xenon tetraflouride is
(a) Tetrahedral and acts as a fluoride donor with SbF5
(b) Square planar and acts as a fluoride donor with PF5
(c) Square planar and acts as fluoride donor with NaF
(d) see-saw shape and acts as a fluoride donor with AsF5

10. Two moles of an ideal gas is expanded reversibly and isothermally at 37 0C until its volume is doubled and 3.41 KJ heat is
absorbed from surroundings. Stotal is (inj/K)
(a) 0.62 (b) 8.66 (c) 22.52 (d) 0.52

11. k1 and k2 are specific conductance of the solutions . a and b in the same conductivity cell. if equal volumes of solutions a
and b are mixed, what will be the resistance of the mixture using the same conductivity cell, whose cell constant is x ?
(Assume there is no change on the degree of dissociation on mixing).
2 K1 K 2 2x
(a) None (b) R (c) R 2x K1 K 2 (d) R
x K 1 K2

12. The molar conductances at infinite dilution of HCl, NaCl and NaZ (sodium crotonate) are 425 x 10 4, 125 x 104 and 80 x
104 s m2 mol1 respectively. the specific conductance of 0.001 m aqueous solution of crotonic acid (HZ) is 3.8 x 103 sm1.
 ka for crotonic acid?
(a) 1.11 x 105 mol dm3 (b) 1.1 x 103 mol dm3
(c) 7 x 104 mol dm3 (d) none

13. What is the emf of the galvanic cell (ksp of agcl = 1.0 x 1010)
Ag, AgCl(s) | 1M KCl (aq.) || 1M AgNO3 (aq) | Ag
(a) Zero (b) 0.592 v (c) 1.391 v (d) 0.592 v

14. Given:
a2+ + 2e a(s) Eo = 0.10 v b+ + e b(s) Eo = 2.71 v
x2(g) + 2e 2x Eo = 1.08 v
Which of the following statements is not true?
(a) x2(g) will oxidize both a and b
(b) a2+ will oxidize b
(c) The reaction 2x (1.0m) + a2+ (1.0m) x2 (1 atm) + a(s) will be spontaneous
(d) The oxidizing powder of a2+, b+ and x2(g) is in the order: b+ < a2+ < x2

15. Find the standard cell potential involving the cell reaction
in2+ + cu2+ in3+ + cu+, at 298 k
o o
2 3 2
Given: k Cu / Cu = x1 v; E In / In = x2 v; E In / In = x3v
(A) x1 + x3 x2 (B) (x1 + x3 2x2)/ 3 (C) x1 + x3 2x2 (D) x1 + x3 + 2x2

16. A gas y at 1atm is passed through a solution containing a mixture of 1 m x and 1 m z. If the reduction potentials vary in
the order x > y > z, then which of the following is correct?
(a) Both x and z get oxidized (b) z is oxidized but not x
(c) y is reduced but z is not oxidized (d) y is reduced and x is oxidized

17. In electrolytic reduction of a Nitroarene with 50% current efficiency, 20.50g of the compound is reduced by 2 x 96500 c of
electric charge. The molar mass of the compound is:
(a) 20.50g (b) 10.25g (c) 123.00g (d) 61.50g

18. A 1.0 m with respect to each of metal halides ax 3, bx2, cx3 and dx2 is electrolysed using platinum electrodes. If E o A /A
=
o o o
B2 / B C3 / C D2 / D
1.50 v, E = 0.34 v, E = 0.74 v, E = 2.37 v, the correct sequence in which the various metals are deposited
at the cathode is:
(a) a, b, c, d (b) d, c, b, a (c) a, b, c (d) c, b, a

o
19. The equilibrium constant for the disproportioation reaction: 3Cu +(aq)

Cu(s) + Cu2+ (aq) at 25oc (E Cu / Cu
= 0.52 v;
o
Cu2 / Cu
E = 0.16 v) is:
(a) 1.2 x 106 (b) 6 x 104 (c) 6 x 106 (d) 1.2 x 106

20. Electrolysis is carried out in three cells: (a) 1.0 m CuSO 4, pt electrodes; (b) 1.0 m CuSO 4, copper electrodes; (c) 1.0
m KCl, pt electrodes. If volume of electrolytic solution is maintained constant in each of the cells, which is correct set of
ph changes in (a), (b) and (c) cells respectively
(a) Increase in all the three (b) Decrease in all the three
(c) Increase, constant, increases (d) Decrease, constant, increase

Numericals

N1. How many of the following compounds liberate nitrogen on heating?

(NH4)2Cr2O7 NH4Cl NH4 NO3 NH4Br
NaN3 (NH4)2SO4 NH4NO2 (NH4)2CO3

N2. How many of the following are non cyclic phosphates: H5P3O10, H6P4O13, H5P5O15, H7P5O16, H4P2O7

N3. One mole of an ideal gas undergoes a change of state (2.0 atm, 3.0L) to (2.oatm, 5.0L) with a change in internal energy
 of 30 L atm. The change in enthalpy for the process in L-atm is X. the value of X/4 is

N4. In how many of the following compounds oxygen is liberated during its hydrolysis
XeF6, XeF4, XeF2, urea, XeOF4, XeO3

N5. The average molar heat capacity at constant volume of gaseous mixture containing 2 mole of each of two ideal gases A
(Cv=3/2 R) and B (Cv =5/2 R) is

N6. After the electrolysis of a sodium chloride solution with inert electrodes for a certain period of time 600 ml of a 1n
NaOH solution was left, during the same time 31.8 g of cu was deposited in a copper voltammeter in series with the
electrolytic cell. The percentage efficiency for the production of sodium hydroxide is (atomic wt of cu = 63.5).
Give the answer after multiplying with 101.

N7. Ag(s), Ag2CrO4(s) 0.1 M K2CrO4 || Ag+ (0.01M), Ag(s) is 0.206 v. Calculate the ksp of Ag2CrO4.express the answer in
nearest integer after multiplying with 1013

N8. Zn 2

Graph between Ecell Vs log Cu

2
was linear with intercept on Ecell axis 1.1 v.
Ecell for Zn | Zn2+(0.1 M) || Cu2+(0.01 M) +| Cu is

N9. E 0Cd 2 / Cd
Emf of the cell Cd | CdSO4 | H2SO4 (0.01 m) | H2 (1 atm) | Pt is + 0.362 volt at 25 c. The is 0.403 volt at
same temperature. The Solubility product of cdso4 in scientific notation is y 10-x. the value of x is

N10. A sample of water from a large swimming pool has a resistance of 9200 ohm at 25oc when placed in a certain
conductance cell. When filled with 0.02 M KCl solution the cell has a resistance of 85 ohm at 25 0C. 500 grams of
sodium chloride were dissolved in the pool which was thoroughly stirred. A sample of this solution gave a resistance of
7600 ohm. The volume of water in the pool is approximately 2x10 y liters. The value of y is---- (Given molar
conductivity of sodium chloride at that concentration is 126.5 ohm-1cm2mol-1 and molar conductivity of potassium
chloride at 0.02 m is 138.3 ohm-1cm2mol-1.)

1. D 2. B 3. B 4. A 5. A

6. B 7. B 8. C 9. B 10. D

11. D 12. A 13. D 14. C 15. C

16. B 17. C 18. C 19. D 20. D

N1. 4. N2. 4 N3. 9 N4. 0 N5. 2

N6. 6 N7. 1 N8. 1 N9. 5 N10. 5