DEAN #37261 (McGHP) RIGHT INTERACTIVE

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PROPERTIES OF ATOMS, RADICALS, AND BONDS 4.41 base of rh

cap height
TABLE 4.11 Bond Dissociation Energies base of text
The bond dissociation energy (enthalpy change) for a bond A 9 B which is broken through the reaction

AB : A B
is dened as the standard-state enthalpy change for the reaction at a specied temperature, here at 298 K.
That is,

Hf298 Hf298(A) Hf298(B) Hf298(AB)

All values refer to the gaseous state and are given at 298 K. Values of 0 K are obtained by subtracting 32RT
from the value at 298 K.
To convert the tabulated values to kcal/mol, divide by 4.184.

Hf298 , Hf298 ,
Bond kJ/mol Bond kJ/mol

Aluminum Antimony (continued)

Al 9 Al 186(9) Sb 9 O 372(84)
Al 9 As 180 Sb 9 P 357
Al 9 Au 326(6) Sb 9 S 379
Al 9 Br 439(8) Sb 9 Te 277.4(38)
Al 9 C 255
Al 9 Cl 494(13) Arsenic
AlCl 9 Cl 402(8)
AlCl 2 9 Cl 372(8) As 9 As 382(11)
AlO 9 Cl 515(84) As 9 Cl 448
Al 9 Cu 216(10) As 9 Ga 209.6(12)
Al 9 D 291 As 9 H 272(12)
Al 9 F 664(6) As 9 N 582(126)
AlF 9 F 546(42) As 9 O 481(8)
AlF2 9 F 544(46) As 9 P 534(13)
AlO 9 F 761(42) As 9 S (478)
Al 9 H 285(6) As 9 Se 96
Al 9 I 368(4) As 9 Tl 198(15)
Al 9 Li 176(15)
Al 9 N 297(96) Astatine
Al 9 O 512(4)
AlCl 9 O 540(41) At 9 At (115.9)
AlF 9 O 582
Al 9 P 213(13) Barium
Al 9 Pd 259(12)
Al 9 S 374(8) Ba 9 Br 370(8)
Al 9 Se 334(10) Ba 9 Cl 444(13)
Al 9 Si 251(3) Ba 9 F 487(7)
Al 9 Te 268(10) Ba 9 I 431(4)
Al 9 U 326(29) Ba 9 O 563(42)
Ba 9 OH 477(42)
Antimony Ba 9 S 400(19)

Sb 9 Sb 299(6) Beryllium
Sb 9 Br 314(59)
Sb 9 Cl 360(50) Be 9 Be 59
Sb 9 F 439(96) Be 9 Br 381(84)
Sb 9 N 301(50) Be 9 Cl 388(9)
short
standard
long
DEAN #37261 (McGHP) LEFT INTERACTIVE

top of rh
4.42 SECTION 4 base of rh

cap height
TABLE 4.11 Bond Dissociation Energies (Continued) base of text

Hf298 , Hf298 ,
Bond kJ/mol Bond kJ/mol

Beryllium (continued) Bromine

BeCl 9 Cl 540(63) Br 9 Br 193.870(4)

Be 9 F 577(42) Br 9 C 280(21)
Be 9 H 226(21) Br 9 CH 3 284(8)
Be 9 O 448(21) Br 9 CH 2 Br 255(13)
Be 9 S 372(59) Br 9 CHBr2 259(17)
Br 9 CBr3 209(13)
Bismuth Br 9 CCl 3 218(13)
Br 9 CF3 285(13)
Bi 9 Bi 197(4) Br 9 CF2CF3 287.4(63)
Bi 9 Br 267(4) Br 9 CF2CF2CF3 278.2(63)
Bi 9 Cl 305(8) Br 9 CHF2 289
Bi 9 D 284 Br 9 Cl 218.84(4)
Bi 9 F 259(29) Br 9 CN 381
Bi 9 Ga 159(17) Br 9 CO 9 C6 H 5 268
Bi 9 H 279 Br 9 F 233.8(2)
Bi 9 O 343(6) Br 9 N 276(21)
Bi 9 P 280(13) Br 9 NF2 222
Bi 9 Pb 142(15) Br 9 NO 120.1(63)
Bi 9 S 316(5) Br 9 O 235.1(4)
Bi 9 Sb 251(4)
Bi 9 Se 280(6) Cadmium
Bi 9 Te 232(11)
Bi 9 Tl 121(13) Cd 9 Cd 11.3(8)
Cd 9 Br 159(96)
Boron Cd 9 Cl 206.7(34)
Cd 9 F 305(21)
B9B 297(21) Cd 9 H 69.0(4)
H 3 B 9 BH 3 146 Cd 9 I 138(21)
OB 9 BO 506(84) Cd 9 In 138
B 9 Br 435(21) Cd 9 O 142(42)
B9C 448(29) Cd 9 S 196
B 9 Cl 536(29) Cd 9 Se 310
BO 9 Cl 460(42)
B9D 341(6) Calcium
B9F 766(13)
BF 9 F 523(63) Ca 9 Ca 14.98(46)
BF2 9 F 557(84) Ca 9 Br 321(23)
B9H 330(4) Ca 9 Cl 398(13)
B9I 384(21) Ca 9 F 527(21)
B9N 389(21) Ca 9 H 167.8
B9O 806(5) Ca 9 I 285(63)
BCl 9 O 715(41) Ca 9 O 464(84)
B9P 347(17) Ca 9 S 314(19)
B9S 581(9)
B 9 Se 462(15) Carbon
B 9 Si 289(29)
B 9 Te 354(20) C9C 607(21)
H 3C 9 CH 3 368

short
standard
long
DEAN #37261 (McGHP) RIGHT INTERACTIVE

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PROPERTIES OF ATOMS, RADICALS, AND BONDS 4.43 base of rh

cap height
TABLE 4.11 Bond Dissociation Energies (Continued) base of text

Hf298 , Hf298 ,
Bond kJ/mol Bond kJ/mol

Carbon (continued) Carbon (continued)

(CH 3 )2C 9 CH 3 335 CF3 9 (N " NCF3 ) 231.0

(CH 3 )2C 9 C(CH 3 )2 282.4 H 2C " NH 644(21)
CH 3 9 C6 H 5 389 HC # N 937
CH 3 9 CH 2C6H 5 301 CH 3 9 NO 174.9(38)
(CH 3 )3C 9 C(C6 H 5 )3 63 C2 H 5 9 NO 175.7(54)
CH 3 9 allyl 301 C3 H 7 9 NO 167.8(75)
CH 3 9 vinyl 121 (CH3 )2CH 9 NO 171.5(54)
CH 3 9 C # CH 490 n-C4 H 9 9 NO 215.5(42)
CH 2 " CH 9 CH " CH 2 418 C6 H 5 9 NO 215.5(42)
HC # C 9 C # CH 628 Cl 3C 9 NO 134
H 2C " CH 2 682 F3C 9 NO 130
HC # CH 962 C6 F5 9 NO 211.3(42)
CH 3 9 CN 506(21) NC 9 NO 121(13)
CH 3 9 CH 2CN 305(8) CH 3 9 NO2 247(13)
CH 3 9 CH(CH 3 )CN 331(8) C2 H 5 9 NO2 259
CH 3 9 C(C6 H 5 )CN(CH 3 ) 251 C9O 1076.5(4)
CH 3CH 2 9 CH 2CN 321.8(71) CH 3 9 OCH 3 335
NC 9 CN 603(21) CH 3 9 OC6 H 5 381
C6 H 5 9 C6 H 5 418 CH 3 9 OCH 2C6 H 5 280
CH 3 9 CF3 423.4(46) C2 H 5 9 OC6 H 5 213
CH 2 F 9 CH 2 F 368(8) C6 H 5CH 2 9 OCOCH 3 285
CF3 9 CF3 406(13) C6 H 5CH 2 9 OCOC6 H 5 289
CF2 " CF2 318(13) CH 3CO 9 OCH 3 406
CF3 9 CN 501 CH 3 9 OSOCH 3 280
CH 3 9 CHO 314 CH 2 " CHCH 2 9 OSOCH 3 209
CH 3 9 CO 342.7 C6 H 5CH 2 9 OSOCH 3 222
CH 3CO 9 CF3 308.8 C"O 749
CH 3CO 9 COCH 3 280(8) H 2C " O 732
C6 H 5CO 9 COC6H 5 277.8 OC " O 532.2(4)
Aryl 9 CH 2COCH 2 9 aryl 273.6 SC " O 628
C6 H 5CH 2 9 COOH 284.9 C#O 1075
(C6 H 5CH 2)2CH 9 COOH 248.5 C9P 513(8)
C 9 Cl 397(29) C9S 699(8)
C9F 536(21) CH 3 9 SH 305(13)
C9H 337.2(8) CH 3 9 SC6 H 5 285(8)
C9I 209(21) CH 3 9 SCH 2C6 H 5 247(8)
C9N 770(4) OC 9 S 310.4
CF3 9 NF2 272(13) C 9 Se 582(96)
CH 3 9 NH 2 331(13)
C6 H 5CH 2 9 NH 2 301(4) Cerium
CH 3 9 NHC6H 5 285
CH 3 9 N(CH 3 )C6 H 5 272 Ce 9 Ce 243(21)
C6H 5CH 2 9 NHCH 3 289(4) Ce 9 F 582(42)
C6H 5CH 2 9 N(CH 3 )2 255(4) Ce 9 N 519(21)
CH 3 9 (N " NCH 3 ) 219.7 Ce 9 O 795(13)
C2 H 5 9 (N " NC2 H 5) 209.2 Ce 9 S 573(13)
(CH 3 )3C 9 N " NC(CH 3 )3 182.0 Ce 9 Se 495(15)
Aryl 9 CH 2N " NCH 2 9 aryl 157 Ce 9 Te 389(42)
short
standard
long
DEAN #37261 (McGHP) LEFT INTERACTIVE

top of rh
4.44 SECTION 4 base of rh

cap height
TABLE 4.11 Bond Dissociation Energies (Continued) base of text

Hf298 , Hf298 ,
Bond kJ/mol Bond kJ/mol

Cesium Chromium (continued)

Cs 9 Cs 41.75(93) Cr 9 Cu 155(21)
Cs 9 Br 397.5(42) Cr 9 F 437(20)
Cs 9 Cl 439(21) Cr 9 Ge 170(29)
Cs 9 F 514(8) Cr 9 H 280(50)
Cs 9 H 178.1(38) Cr 9 I 287(24)
Cs 9 I 339(4) Cr 9 N 378(19)
Cs 9 O 297(25) Cr 9 O 427(29)
Cs 9 OH 385(13) OCr 9 O 531(63)
O2Cr 9 O 477(84)
Chlorine Cr 9 S 339(21)

Cl 9 Cl 242.580(16) Cobalt
Cl 9 C 338(42)
Cl 9 CH 3 339(21) Co 9 Co 167(25)
Cl 9 CH3 213 Co 9 Br 331(42)
Cl 9 C(CH 3 )3 328.4 Co 9 Cl 398(8)
Cl 9 CH 2Cl 310(13) Co 9 Cu 162(17)
Cl 9 CCl 3 293(21) Co 9 F 435(63)
Cl 9 CF3 360(33) Co 9 Ge 239(25)
Cl 9 CCl 2 F 305(8) Co 9 I 235(81)
Cl 9 CClF2 318(8) Co 9 O 368(21)
Cl 9 CF2CF2 346.0(71) Co 9 S 343(21)
Cl 9 CH " CH 2 351
Cl 9 CN 439 Copper
Cl 9 COCl 328
Cl 9 COCH 3 349.4 Cu 9 Cu 202(4)
Cl 9 COC6 H 5 310(13) Cu 9 Br 331(25)
Cl 9 Cl 393 Cu 9 Cl 383(21)
Cl 9 ClO 143.3(42) Cu 9 F 431(13)
O3Cl 9 ClO4 243 Cu 9 Ga 216(15)
Cl 9 F 250.54(8) Cu 9 Ge 209(21)
O3Cl 9 F 255 Cu 9 H 280(8)
Cl 9 N 389(50) Cu 9 I 197(21)
Cl 9 NCl 280 Cu 9 Ni 206(17)
Cl 9 NCl 2 381 Cu 9 O 343(63)
Cl 9 NF2 ca. 134 Cu 9 S 285(17)
Cl 9 NH 2 251(25) Cu 9 Se 293(38)
Cl 9 NO 159(6) Cu 9 Sn 177(17)
Cl 9 NO2 142(4) Cu 9 Te 176(38)
Cl 9 O 272(4)
OCl 9 O 243(13) Curium
O2Cl 9 O 201(4)
Cl 9 P 289(42) Cm 9 O 736
Cl 9 SiCl 3 464
Dysprosium
Chromium
Dy 9 F 527(21)
Cr 9 Cr 155(21) Dy 9 O 611(42)
Cr 9 Br 328(24) Dy 9 Se 322(42)
Cr 9 Cl 366(24) Dy 9 Te 234(42) short
standard
long
DEAN #37261 (McGHP) RIGHT INTERACTIVE

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PROPERTIES OF ATOMS, RADICALS, AND BONDS 4.45 base of rh

cap height
TABLE 4.11 Bond Dissociation Energies (Continued) base of text

Hf298 , Hf298 ,
Bond kJ/mol Bond kJ/mol

Erbium Gallium (continued)

Er 9 F 565(17) Ga 9 O 285(63)
Er 9 O 611(13) Ga 9 P 230(13)
Er 9 S 418(42) Ga 9 Sb 209(13)
Er 9 Se 326(42) Ga 9 Te 251(25)
Er 9 Te 239(42)
Germanium
Europium
Ge 9 Ge 274(21)
Eu 9 Eu 33.5(165) Ge 9 Br 255(29)
Eu 9 Cl ca. 326 Ge 9 Cl 431.8(4)
Eu 9 F 528(18) Ge 9 F 485(21)
Eu 9 O 557(13) Ge 9 H 321.3(8)
Eu 9 S 364(15) Ge 9 O 662(13)
Eu 9 Se 301(15) Ge 9 S 551.0(25)
Eu 9 Te 243(15) Ge 9 Se 490(21)
Ge 9 Si 301(21)
Fluorine Ge 9 Te 402(8)
F9F 156.9(96)
Gold
F 9 F 251
F 9 CH 3 452(21) Au 9 Au 221.3(21)
F 9 C(CH 3 )3 439 Au 9 B 368(11)
F 9 C6 H 5 485 Au 9 Be 285(8)
F 9 CCl 3 444(21) Au 9 Bi 293(84)
F 9 CCl 2 F 460(25) Au 9 Cl 343(10)
F 9 CClF2 490(25) Au 9 Co 215(13)
F 9 CF3 523(17) Au 9 Cr 215(6)
F 9 COCH 3 498 Au 9 Cu 232(9)
F 9 FO 272(13) Au 9 Fe 187(17)
F 9 FO2 81.0 Au 9 Ga 294(15)
F9N 301(42) Au 9 Ge 277(15)
F 9 NF 318(25) Au 9 H 314(10)
F 9 NF2 243(8) Au 9 La 80(5)
F 9 NO 235.6(42) Au 9 Li 68.0(16)
F 9 NO2 197(25) Au 9 Mg 243(42)
Au 9 Mn 185(13)
Gadolinium
Au 9 Ni 274(21)
Gd 9 F 590(27) Au 9 Pb 130(42)
Gd 9 O 716(17) Au 9 Pd 143(21)
Gd 9 S 525(15) Au 9 Rh 231(29)
Gd 9 Se 431(15) Au 9 S 418(25)
Au 9 Si 312(12)
Gallium Au 9 Sn 244(17)
Au 9 Te 247(67)
Ga 9 Ga 138(21) Au 9 U 318(29)
Ga 9 Br 444(17)
(CH 3 )3Ga 9 CH 3 253 Hafnium
Ga 9 Cl 481(13)
Ga 9 F 577(15) Hf 9 C 548(63)
Ga 9 H 274 Hf 9 N 534(29)
short
Ga 9 I 339(10) Hf 9 O 791(8)
standard
long
DEAN #37261 (McGHP) LEFT INTERACTIVE

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4.46 SECTION 4 base of rh

cap height
TABLE 4.11 Bond Dissociation Energies (Continued) base of text

Hf298 , Hf298 ,
Bond kJ/mol Bond kJ/mol

Hydrogen Hydrogen (continued)

H9H 436.002(4) H 9 CHCl2 414.2

H 9 2 H or H 9 D 439.446(4) H 9 CCl 3 377(8)
2 H 9 2 H or D 9 D 443.546(4) H 9 CBr3 377(8)
H 9 Br 365.7(21) H 9 CCl2CHCl2 393(8)
H9C 337.2(8) H 9 CH 2 F 423(8)
H 9 CH 452(33) H 9 CHF2 423(8)
H 9 CH 2 473(4) H 9 CF3 444(13)
H 9 CH 3 431(8) H 9 CF2Cl 435(4)
2
H 9 C2 H 3 or D 9 CD3 442.75(25) H 9 CH 2CF3 446(45)
H 9 C # CH 523(4) H 9 CF2CH 3 416(4)
H 9 CH " CH 2 427 H 9 CF2CF3 431(63)
H 9 CH 2CH 3 410(4) H 9 CH 2I 431(8)
H 9 CH 2C # CH 392.9(50) H 9 CHI 2 431(8)
H 9 CH 2CH " CH 2 356 H 9 CN 540(25)
H 9 cyclopropyl 423(13) H 9 CH 2CN ca. 389
H 9 CH 2CH 2CH 3 410(8) H 9 CH(CH 3 )CN 377(8)
H 9 CH(CH 3 )2 395.4 H 9 C(CH 3 )2CN 364(8)
H 9 cyclobutyl 397(13) H 9 CH 2 NH 2 397(8)
H 9 CH 2CH(CH 3 )2 360 H 9 CH 2Si(CH 3 )3 414(4)
H 9 CH(CH 3 )CH 2CH 3 397(4) H 9 CH 2COCH 3 393(75)
H 9 C(CH 3 )3 381 H 9 Cl 431.8(4)
H 9 CO 126(8)
H9 339(4) H 9 CHO 364(4)
H 9 COOH 377
CH " CH2 H 9 COCH 3 364(4)
335(4) H 9 COCH 2CH 3 364(4)
H 9 CH
CH " CH2
H9 385
O
H9 343(4) H 9 COC6 H 5 364(4)
H 9 COCF3 381(8)
H 9 CH2 CH3 H9F 568.6(13)
C 414(4) H9I 298.7(8)
CH3 CH3 H9N 314(17)
H 9 NH 377(8)
H 9 C(CH 3 )2CH " CH 2 331 H 9 NH 2 435(8)
H 9 cyclopentyl 395(42) H 9 NHCH 3 431(8)
H 9 CH 2C(CH 3 )3 418(4) H 9 N(CH 3 )2 397(8)
H 9 C6 H 5 431 H 9 NHC6 H 5 335(13)
H 9 CH 2C6 H 5 356(4) H 9 N(CH 3 )C6 H 5 310(13)
H 9 C(C6 H 5 )3 314 HNF2 318(13)
H 9 N3 356
H9 310 H 9 NO 205
H9O 428.0(21)
H 9 cyclohexyl 399.6(42) H 9 OH 498.7(8)
H 9 cycloheptyl 387.0(42) H 9 OCH 3 436.8(42)
H 9 norbornyl 406(13) H 9 OCH 2CH 3 436.0
H 9 CH 2Br 410(25) H 9 OC(CH 3 )3 439(4)
H 9 CHBr2 435 H 9 OC6 H 5 368(25) short
H 9 CH 2Cl 423 H 9 ONO 327.6(25)
standard
long
DEAN #37261 (McGHP) RIGHT INTERACTIVE

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PROPERTIES OF ATOMS, RADICALS, AND BONDS 4.47 base of rh

cap height
TABLE 4.11 Bond Dissociation Energies (Continued) base of text

Hf298 , Hf298 ,
Bond kJ/mol Bond kJ/mol

Hydrogen (continued) Iridium

H 9 ONO2 423.4(25) Ir 9 O 352(21)

H 9 OOH 374(8) Ir 9 Si 463(21)
H 9 OOCCH 3 469(17)
H 9 OOCCH 2CH 3 460(17) Iron
H 9 OOCC3 H 7 431(17)
H9P 343(29) Fe 9 Fe 100(21)
H9S 344(12) Fe 9 Br 247(96)
H 9 SH 381(4) Fe 9 Cl ca. 352
H 9 SCH 3 ca. 368 Fe 9 O 409(13)
H 9 Se 305(2) Fe 9 S 339(21)
H 9 Si 298.49(46) Fe 9 Si 297(25)
H 9 SiH 3 393(13)
H 9 Si(CH 3 )3 377(13) Krypton
H 9 Te 268(2)
Kr 9 Kr 5.4(8)
Indium Kr 9 F 54

In 9 In 100(8) Lanthanum
In 9 Br 418(21)
In 9 Cl 439(8) La 9 La 247(21)
In 9 F 506(15) La 9 C 506(63)
In 9 O 360(21) La 9 F 598(42)
In 9 P 197.9(85) La 9 N 519(42)
In 9 S 289(17) La 9 O 799(13)
In 9 Sb 152(11) La 9 S 577(25)
In 9 Se 247(17)
In 9 Te 218(17) Lead

Iodine Pb 9 Pb 339(25)
Pb 9 Br 247(38)
I9I 152.549(8) Pb(CH 3 )3 9 CH 3 207(42)
I 9 Br 179.1(4) Pb 9 Cl 301(29)
I 9 CH 3 232(13) Pb 9 F 356(8)
I 9 C2 H 5 223.8 Pb 9 H 176(21)
I 9 CH(CH 3 )2 222 Pb 9 I 197(38)
I 9 C(CH 3 )3 207.1 Pb 9 O 378(4)
I 9 CH 2CF3 234(4) Pb 9 S 346.0(17)
I 9 CF2CH 3 216(4) Pb 9 Se 303(4)
I 9 C3 F7 209(4) Pb 9 Te 251(13)
I 9 CH " CHCH 3 172
I 9 C6 H 5 268(4) Lithium
I 9 C6 F5 276
I 9 Cl 213.3(4) Li 9 Li 106(4)
I 9 COCH 3 219.7 Li 9 Br 423(21)
I 9 CN 305(4) Li 9 Cl 469(13)
I9F 280(4) Li 9 F 577(21)
I9N 159(17) Li 9 H 247
I 9 NO 71(4) Li 9 I 352(13)
I 9 NO2 75(4) Li 9 Na 88
I9O 184(21) Li 9 O 341(6) short
Li 9 OH 427(21) standard
long
DEAN #37261 (McGHP) LEFT INTERACTIVE

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4.48 SECTION 4 base of rh

cap height
TABLE 4.11 Bond Dissociation Energies (Continued) base of text

Hf298 , Hf298 ,
Bond kJ/mol Bond kJ/mol

Lutetium Molybdenum

Lu 9 Lu 142(34) Mo 9 I 372
Lu 9 F 569(42) Mo 9 O 607(34)
Lu 9 O 695(13) MoO 9 O 678(84)
Lu 9 S 507(15) MoO2 9 O 565(84)
Lu 9 Te 326(17)
Neodymium
Magnesium
Nd 9 F 545(13)
Mg 9 Mg 8.522(4) Nd 9 O 703(34)
Mg 9 Br 297(63) Nd 9 S 474(15)
Mg 9 Cl 318(13) Nd 9 Se 385(17)
Mg 9 F 462(21) Nd 9 Te 305(17)
MgF 9 F 569(42)
Mg 9 H 197(50) Neon
Mg 9 I ca. 285
Mg 9 O 394(35) Ne 9 Ne 3.93
Mg 9 OH 238(21)
Mg 9 S 310(75) Neptunium

Manganese Np 9 O 720(29)

Mn 9 Mn 42(29) Nickel
Mn 9 Br 314(10)
Mn 9 Cl 361(10) Ni 9 Ni 261.9(25)
Mn 9 F 423(15) Ni 9 Br 360(13)
Mn 9 I 283(10) Ni 9 Cl 372(21)
Mn 9 Cu 159(17) Ni 9 F 435
Mn 9 O 402(34) Ni 9 H 289(13)
Mn 9 S 301(17) Ni 9 I 293(21)
Mn 9 Se 201(13) Ni 9 O 391.6(38)
Ni 9 S 360(21)
Mercury Ni 9 Si 318(17)

Hg 9 Hg 17.2(21) Niobium
Hg 9 Br 72.8(42)
CH 3 9 HgCH 3 240.6 Nb 9 O 753(13)
C2 H 5 9 HgC2 H 5 182.8(42)
C3 H 7 9 HgC3 H 7 197.1 Nitrogen
Isopropyl 9 Hgisopropyl 170.3
C6 H 5 9 HgC6 H 5 285 N9N 945.33(59)
Hg 9 Cl 100(8) N 9 Br 276(21)
Hg 9 F 130(38) ON 9 Br 28.7(15)
Hg 9 H 39.8 N 9 Cl 389(50)
Hg 9 I 38 ON 9 Cl 159(6)
Hg 9 K 8.24(21) O2 N 9 Cl 142(4)
Hg 9 Na 6.7 N9F 301(42)
Hg 9 S 213 FN 9 F 318(21)
Hg 9 Se (167) F2 F 9 N 243(8)
Hg 9 Te (142) ON 9 F 236(4)
O2 N 9 F 188(21) short
standard
long
DEAN #37261 (McGHP) RIGHT INTERACTIVE

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PROPERTIES OF ATOMS, RADICALS, AND BONDS 4.49 base of rh

cap height
TABLE 4.11 Bond Dissociation Energies (Continued) base of text

Hf298 , Hf298 ,
Bond kJ/mol Bond kJ/mol

Nitrogen (continued) Oxygen (continued)

N9I 159(17) C2 H 5O 9 OC2 H 5 159

F2 N 9 NF2 88(4) C3 H 7O 9 OC3 H 7 155
H 2 N 9 NH 2 297(8)
H 2 N 9 NHCH 3 271 Palladium
H 2N 9 N(CH 3 )2 264
H 2N 9 NHC6 H 5 213 Pd 9 O 234(29)
HN 9 N2 38
ON 9 N 480.7(42) Phosphorus
ON 9 NO2 39.8(8)
O2 N 9 NO2 57.3(21) P9P 490(11)
HN " NH 456(42) P 9 Br 266.5
N#N 946 P9C 513(8)
N9O 630.57(13) P 9 Cl 289(42)
HN " O 481 P9F 439(96)
NN 9 O 167 P9H 343(29)
ON 9 O 305 P9N 617(21)
N9P 617(21) P9O 596.6
N9S 464(21) Br3 P " O 498(21)
Cl 3 P " O 510(21)
Osmium F3 P " O 544(21)
P9S 346.0(17)
O3Os 9 O 301(21) P"S 347
P 9 Se 363(10)
Oxygen P 9 Te 298(10)

O9O 498.34(20) Platinum

O 9 Br 235.1(4)
HO 9 CH 3 377(13) Pt 9 B 478(17)
HO 9 CH " CH 2 364 Pt 9 H 352(38)
HO 9 CH 2CH " CH 2 456 Pt 9 O 347(34)
HO 9 C6 H 5 431 Pt 9 P 417(17)
HO 9 CH 2C6 H 5 322 Pt 9 Si 501(18)
HO 9 CHO 402(13)
HO 9 COCH 3 452(21) Potassium
HO 9 COC2 H 5 180
O 9 Cl 272(4) K9K 57.3(42)
HO 9 Cl 251(13) K 9 Br 383(8)
O9F 222(17) K 9 Cl 427(8)
O 9 FO 467 K9F 497.5(25)
FO 9 OF 261(84) K9H 183(15)
O9I 184(21) K9I 331(13)
HO 9 I 234(13) K 9 Na 63.6(29)
O9N 630.57(13) K9O 239(34)
HO 9 NCH 3 209 K 9 OH 343(8)
HO 9 OC(CH 3 )3 192(8)
HO 9 OH 213.8(21) Praseodymium
O 9 OH 268(4)
CF3O 9 OCF3 192 Pr 9 F 582(46)
CH 3O 9 OCH 3 157.3(8) Pr 9 O 753(17)
Pr 9 S 492.5(46) short
standard
long
DEAN #37261 (McGHP) LEFT INTERACTIVE

top of rh
4.50 SECTION 4 base of rh

cap height
TABLE 4.11 Bond Dissociation Energies (Continued) base of text

Hf298 , Hf298 ,
Bond kJ/mol Bond kJ/mol

Praseodymium (continued) Scandium

Pr 9 Se 446(23) Sc 9 Sc 163(21)
Pr 9 Te 326(42) Sc 9 Br 444(63)
Sc 9 C 393(63)
Promethium Sc 9 Cl 318
Sc 9 F 589(13)
Pm 9 F 540(42) Sc 9 N 469(84)
Pm 9 O 674(63) Sc 9 O 674(13)
Pm 9 S 423(63) Sc 9 S 478(13)
Pm 9 Se 339(63) Sc 9 Se 385(17)
Pm 9 Te 255(63) Sc 9 Te 289(17)

Radium Selenium

Ra 9 Cl 343(75) Se 9 Se 332.6(4)
Se 9 Br 297(84)
Rhodium Se 9 C 582(96)
Se 9 Cl 322
Rh 9 Rh 285(21) Se 9 F 339(42)
Rh 9 B 476(21) Se 9 H 305(2)
Rh 9 C 583.7(63) Se 9 N 381(63)
Rh 9 O 377(63) Se 9 O 423(13)
Rh 9 Si 395(18) Se 9 P 364(10)
Rh 9 Ti 391(15) Se 9 S 381(21)
Se 9 Si 531(25)
Rubidium Se 9 Te 268(8)

Rb 9 Rb 45.6(21) Silicon
Rb 9 Br 389(13)
Rb 9 Cl 448(21) Si 9 Si 327(10)
Rb 9 F 494(21) Si 9 Br 343(50)
Rb 9 H 167(21) Si 9 C 435(21)
Rb 9 I 335(13) Si 9 Cl 456(42)
Rb 9 O 255(84) Si 9 F 540(13)
Rb 9 OH 351(8) Si 9 H 298.49(46)
Si 9 I 339(84)
Ruthenium Si 9 N 439(38)
Si 9 O 798(8)
Ru 9 O 481(63) Si 9 S 619(13)
O3 Ru 9 O 439 Si 9 Se 531(25)
Ru 9 Si 397(21) H 3Si 9 SiH 3 339(17)
Ru 9 Th 592(42) (CH 3 )3Si 9 Si(CH 3 )3 339
(Aryl)3Si 9 Si(aryl)3 368(31)
Samarium Si 9 Te 506(38)
Sm 9 Cl 423(13) Silver
Sm 9 F 531(18)
Sm 9 O 619(13) Ag 9 Ag 163(8)
Sm 9 S 389 Ag 9 Au 203(9)
Sm 9 Se 331(15) Ag 9 Bi 193(42)
Sm 9 Te 272(15) short
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DEAN #37261 (McGHP) RIGHT INTERACTIVE

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PROPERTIES OF ATOMS, RADICALS, AND BONDS 4.51 base of rh

cap height
TABLE 4.11 Bond Dissociation Energies (Continued) base of text

Hf298 , Hf298 ,
Bond kJ/mol Bond kJ/mol

Silver (continued) Tantalum

Ag 9 Br 293(29) Ta 9 N 611(84)
Ag 9 Cl 341.4 Ta 9 O 805(13)
Ag 9 Cu 176(8)
Ag 9 F 354(16) Tellurium
Ag 9 Ga 180(15)
Ag 9 Ge 175(21) Te 9 B 354(20)
Ag 9 H 226(8) Te 9 H 268(2)
Ag 9 I 234(29) Te 9 I 193(42)
Ag 9 In 176(17) Te 9 O 391(8)
Ag 9 O 213(84) Te 9 P 298(10)
Ag 9 Sn 136(21) Te 9 S 339(21)
Ag 9 Te 293(96) Te 9 Se 268(8)

Sodium Terbium

Na 9 Na 77.0 Tb 9 F 561(42)
Na 9 Br 370(13) Tb 9 O 707(13)
Na 9 Cl 410(8) Tb 9 S 515(42)
Na 9 F 481(8) Tb 9 Te 339(42)
Na 9 H 201(21)
Na 9 I 301(8) Thallium
Na 9 K 63.6(29)
Na 9 O 257(17) Tl 9 Tl 63
Na 9 OH 381(13) Tl 9 Br 333.9(17)
Na 9 Rb 59(4) Tl 9 Cl 372.8(21)
Tl 9 F 445(19)
Strontium Tl 9 H 188(8)
Tl 9 I 272(8)
Sr 9 Br 332(19)
Sr 9 Cl 406(13) Thorium
Sr 9 F 542(7)
Sr 9 H 163(8) Th 9 Th 289
Sr 9 I 263(42) Th 9 C 484(25)
Sr 9 O 454(15) Th 9 N 577.4(21)
Sr 9 OH 381(42) Th 9 O 854(13)
Sr 9 S 314(21) Th 9 P 377

Sulfur Thullium

S9S 429(6) Tm 9 F 569(42)

S 9 Cl 255 Tm 9 O 557(13)
S9F 343(5) Tm 9 S 368(42)
O2S 9 F 71 Tm 9 Se 276(42)
S9N 464(21) Tm 9 Te 276(42)
S9O 521.70(13)
OS 9 O 551.4(84) Tin
O2S 9 O 348.1(42)
HS 9 SH 272(21) Sn 9 Sn 195(17)
Sn 9 Br 339(4)
short
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DEAN #37261 (McGHP) LEFT INTERACTIVE

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4.52 SECTION 4 base of rh

cap height
TABLE 4.11 Bond Dissociation Energies (Continued) base of text

Hf298 , Hf298 ,
Bond kJ/mol Bond kJ/mol

Tin (continued) Vanadium (continued)

BrSn 9 Br 326 V 9 Cl 477(63)

Br3Sn 9 Br 272 V9F 590(63)
(C2 H 5 )3Sn 9 C2 H 5 ca. 238 V9N 477(8)
Sn 9 Cl 406(13) V9O 644(21)
Sn 9 F 467(13) V9S 490(16)
Sn 9 H 267(17) V 9 Se 347(21)
Sn 9 I 234(42)
Sn 9 O 548(21) Xenon
Sn 9 S 464(3)
Sn 9 Se 401.3(59) Xe 9 Xe 6.53(30)
Sn 9 Te 319.2(8) Xe 9 F 13.0(4)
Xe 9 O 36.4
Titanium
Ytterbium
Ti 9 Ti 141(21)
Ti 9 Br 439 Yb 9 Cl 322
Ti 9 C 435(25) Yb 9 F 521(10)
Ti 9 Cl 494 Yb 9 H 159(38)
Ti 9 F 569(34) Yb 9 O 397.9(63)
Ti 9 H ca. 159 Yb 9 S 167
Ti 9 I 310(42)
Ti 9 N 464 Yttrium
Ti 9 O 662(16)
Ti 9 S 426(8) Y9Y 159(21)
Ti 9 Se 381(42) Y 9 Br 485(84)
Ti 9 Te 289(17) Y9C 418(63)
Y 9 Cl 527(42)
Tungsten Y9F 605(21)
Y9N 481(63)
W 9 Cl 423(42) Y9O 715.1(30)
W9F 548(63) Y9S 528(11)
W9O 653(25) Y 9 Se 435(13)
OW 9 O 632(84) Y 9 Te 339(13)
O2W 9 O 598(42)
W9P 305(4) Zinc

Uranium Zn 9 Zn 29
Zn 9 Br 142(29)
U9O 761(17) C2 H 5C 9 C2 H 5 ca. 201
OU 9 O 678(59) Zn 9 Cl 229(20)
O2 U 9 O 644(88) Zn 9 F 368(63)
U9S 523(10) Zn 9 H 85.8(21)
Zn 9 I 138(29)
Vanadium Zn 9 O 284.1
Zn 9 S 205(13)
V9V 242(21) Zn 9 Se 136(13)
V 9 Br 439(42) Zn 9 Te 205
V9C 469(63)

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long
DEAN #37261 (McGHP) RIGHT INTERACTIVE

top of rh
PROPERTIES OF ATOMS, RADICALS, AND BONDS 4.53 base of rh

cap height
TABLE 4.11 Bond Dissociation Energies (Continued) base of text

Hf298 , Hf298 ,
Bond kJ/mol Bond kJ/mol

Zirconium Zirconium (continued)

Zr 9 C 561(25) Zr 9 O 760(8)
Zr 9 F 623(63) Zr 9 S 575(17)
Zr 9 N 565(25)

Source: T. L. Cottrell, The Strengths of Chemical Bonds, 2d ed., Butterworth, London, 1958; B. deB. Darwent, National
Standard Reference Data Series, National Bureau of Standards, no. 31, Washington, 1970; S. W. Benson, J. Chem. Educ.
42:502 (1965); and J. A. Kerr, Chem. Rev. 66:465 (1966).

short
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