Question: Some thousands of voltage is generated when you walk on

carpet or even on dry concrete, floor. How this charge gets accumulated
continuously and never gets discharged?
Answer: See at end under "research" for charge generation methods.
In your case rubbing or "triboelectric effect" is almost certainly the main
mechanism.

Importantly - the generation methods do not contain reciprocal

discharge mechanisms.
For discharge to occur the conditions for discharge need to be met separately. If
they are not met - eg warm dry conditions with good insulation to other
differentially charged objects then discharge will not occur. Charge will
accumulate on the capacitor that the body forms relative to ground. For a given
amount of charge, the lower the capacitance the higher the voltage.

So for a fixed charge, halving capacitance means double voltage, and voltage is
a squared factor in energy.

Question: Why it discharges through your fingers, when it is really built

up on your shoes or clothes. If you touch you clothes with the door knob
nothing happens but if you touch your finger, boom, you get shock? How
does the whole process work?
Answer: Discharge will occur when there is a low enough resistance path to
some other body for the charge to drain through it - ie for a current to be
created. There will ALWAYS be a discharge path BUT it may be of such large
resistance that the discharge time is long. If the time to discharge is more than
say ten seconds to half discharge then you may notice the effect and if the half-
charge discharge time is more than one minute you are almost sure to discover
it.

Charge is stored in capacitance. That's a whole area in its own right - but your
body has a capacitance if typically 100 pF to ground - see Wikipedia body
capacitance article. The objects attached to your body that generate most of the
charge have low capacitance compared to that of your body. Charge is stored in
proportion to capacitance so your body acts as a reservoir for the charge
"generated" by your clothing.
You will feel pain from "shock" when discharge energy rate and magnitude fulfill
some complex relationship. If the discharge current is too low you will not feel
pain or shock sensation.

Touching clothes etc to a grounded object provides a very high resistance path
to ground so charge transfer is slow. Charge does flow from your via clothes to
ground but the all imporant enegy transfer rate is low.

If you touch a grounded object wit part of your body then charge stored on your
body has a low resistance path to ground and you will be much more likely to
fel "pain" than if the discharge path was low resistance. If you touch hair or dry
clothing to ground, the discharge path resistance may be 10's to 100's of
megohms and you will feel no pain 0 even though these objects generated the
charge that your body stored.

1000 V on a 100 pF capacitor contains about 0.1 millijoule of energy !!! - and
you may feel the discharge. A 10 kV voltage on 100 pF stores about 10 mJ or
energy and you WILL feel the discharge if you touch ground.

If a group of 6 or so people all hold hands and shuffle across a static inducing
carpet and one person extends a finger and touches an unattached person then
all 7 people get a substantial shock but especially the two at the main contact
point. Ask me how I know :-).

Warning: When fully charged it is a bad idea [tm] for the finger pointer to touch
a filing cabinet with their outstretched finger !!!. Ask me how I know :-). In the
latter case the filing cabinet will be a large capacitance in its own right and at
ground potential due to leakage via its path through its base and carpet etc.