LAWS OF MOTION 21 21

Contents
TOPIC PAGE NO.

1. Basic Concepts of Chemistry ............................................................................................................... 01

2. Atomic Structure ................................................................................................................................ 15

3. Gaseous State ........................................................................................................................................ 29

4. Chemical Energetics .............................................................................................................................. 47

5. Redox & Volumetric Analysis ............................................................................................................. 75

6. Chemical Equilibrium ........................................................................................................................... 85

7. Acid Base & Ionic Equilibrium .......................................................................................................... 95

8. Chemical Kinetics .................................................................................................................................. 123

9. Nuclear Chemistry ................................................................................................................................. 143

10. Electro Chemistry.................................................................................................................................... 147

11. Solid State ............................................................................................................................................... 169

12. Solutions ................................................................................................................................................ 185

13. Surface Chemistry ................................................................................................................................ 202

 3 GASEOUS STATE

1. An open ended Hg manometer is used to measure the pressure exerted by a trapped gas as shown in the
figure. Atmospheric pressure is 749 m.m. of Hg. What is the pressure of the trapped gas-

292 m.m.

(A) 292 m.m. Hg (B) 457 m.m. Hg (C) 749 m.m. Hg (D) 1041 m.m. Hg

2. A P-V curve at constant temperature is shown below. T1 and T2 in kelvin are-

T2
V (lit.)
T1
P (atm.)

(A) 500, 250 (B) 250, 500 (C) 300, 150 (D) 300, 300

3. The cylinder contains 100 gm of an ideal gas (mol. wt. = 40 gm/mol) at 27C and 2 atm. pressure. In
transportation the cylinder fell and a dent was created. The valve present cannot keep the pressure greater
than 2 atm. Hence 10 gm of a gas got leaked out. The volume of the container before and after dent is-
(A) 30.8 L ; 27.7 L (B) 27.7 L ; 30.8 L (C) 30.8 L ; 30.8 L (D) 27.7 L ; 27.7 L

4. A gas is present in a cylinder fitted with movable piston. Above and below of the piston there is equal
number of moles of gas. The volume above is two times the volume below at a temperature of 300K. At what
temperature will the volume above be four times the volume below-
(A) 600 K (B) 400 K (C) 200 K (D) 120 K
 13 SURFACE CHEMISTRY

1. The arsenius sulphide sol has negative charge the maximum coagulating power for precipitating it is of -
(A) 0.1(N) Zn(NO3)2 (B) 0.1(N) Na3PO4
(C) 0.1(N) ZnSO4 (D) 0.1(N) AlCl3

Passage Based Questions :

Passage-(Q.2 to 4)
White gelatinous precipitate of Al(OH)3 is slightly soluble in excess of NH3 solution. The solubility of
Al(OH)3 is decreased in the presence of NH4+ salts. A small portion of the precipitate passes into the solution
as colloidal aluminium hydroxide sol. The sol is coagulated on boiling the solution or upon the addition of
soluble salt for example NH4Cl yielding a precipitate of aluminium hydroxide, known as aluminium
hydroxide gel.

2. The precipitation of Al(OH)3 cannot occur by the NH3 solution if Al3+ is present with little amount of tartaric
acid. Because
(A) Tartaric acid reduces the basic strength of the NH3 solution
(B) Al3+ form stable complex with tartaric acid
(C) Al3+ liberate CO2 on reaction with tartaric acid
(D) All of the above

3. Al3+ solution + CH3COO solution excess + boil white ppt (X) ; (X) is
(A) Al(OH)3 (B) Al(CH3COO)3
(C) Al(OH)2CH3COO (D) Al2O3

4. Al2O3 + fewdrops of Co(NO3)2 solution + fusion (X), (X) is

(A) A deep red mass of Co(AlO2)2 (B) A black ppt of Co3O4
(C) A deep green mass of Co(AlO2)2 (D) A deep blue mass of Co(AlO2)2
Answers With
Hint & Solutions
 3 GASEOUS STATE
Sol.1 (D) Press. of the gas = 749 + 292 = 1041 mm Hg.

Sol.2 (B) T2 > T1

nRT 100 0.082 300

Sol.3 (A) Before dent vol. of gas = = = 30.75 L
P 40 2
nRT 90 0.082 300
After dent vol. of gas = = = 27.675 L
P 40 2

Sol.4 (D)
A
n mol
2V/3
300 K

Total vol. = V
300 K
B V/3
n mol

Let press given by piston = P0

PA + P0 = PB
or P0 = PB PA
nR 300 nR 300
or P0 =
V/3 2V / 3
Let the final temperature = T

n mol
T 4V/5
Total vol. = V

Bn mol T V/5

PB= P0 + PA
or P0 = PB PA
n RT n RT
or P0 =
V/5 4V / 5

n RT 5 3 n R 300 1
= 3
V 4 V 2
15 3
or T = 300
4 2
4 3
or T= 300 = 120 K
15 2
13 SURFACE CHEMISTRY
Sol.1 (D) More the valency of cation greater will be its coagulating power as per hardy schulze rule.

Passage Based Questions :

Passage-(Q.2 to 4)

Sol.2 (B) Al3+ form stable complex with tartaric acid

Sol.3 (C) Al3+ + 3CH3COO + 2H2O Al(OH)2CH3COO + 2CH3COOH

Sol.4 (D) 2Al2O3 + 2Co2+ + 4NO3 2Co(AlO2) 2 + 4NO2 + O2

If excess Co(NO3)2 solution is used then black ppt of Co3O4 is produced.