Beruflich Dokumente
Kultur Dokumente
(Mirpur Branch)
Mock 1
Academic Session: 2016-2017
Name: ______________________________ Full Marks: 40 Score: ________
There are forty questions on this paper. Answer all questions. For each question there are four possible
answers A, B, C and D.
Choose the one you consider correct and record your choice in soft pencil on the separate Answer Sheet.
- Each correct answer will score one mark. A mark will not be deducted for a
wrong answer. Any rough working should be done in this booklet.
Section A
For each question there are four possible answers, A, B, C, and D. Choose the one you consider to
be correct.
1 Which solid-line curve most accurately represents the distribution of molecular energies in a gas
at 500 K if the dotted-line curve represents the corresponding distribution for the same gas at
300 K?
A H2 + Cl 2 2HCl
B C2H4 + H2 C2H6
C N2 + 3H2 2NH3
D 2Na + H2 2NaH
1
The standard enthalpy change of formation of carbon dioxide is 393 kJ mol .
1
The standard enthalpy change of formation of water is 286 kJ mol .
1
The standard enthalpy change of formation of ethanol is 277 kJ mol .
5
M contains helium at 20 C at a pressure of 1 10 Pa. N has been evacuated, and has three
times the volume of M. In an experiment, the valve is opened and the temperature of the whole
apparatus is raised to 100 C.
electrical
electrical electrical conductivity
melting point conductivity conductivity
/ C of aqueous
of solid of liquid solution
6 Aluminium carbide, Al 4C3, reacts readily with aqueous sodium hydroxide. The two products of the
reaction are NaAl O2 and a hydrocarbon. Water molecules are also involved as reactants.
There is significant heat loss in this experiment. Therefore, the experimental value for the
enthalpy change of combustion, Hc, of the fuel will be different from the theoretical value.
Using the information above, what is the experimental value for the enthalpy change of
combustion, Hc, of the fuel?
1
A 1410 kJ mol
1
B 769 kJ mol
1
C 30.7 kJ mol
1
D 16.7 kJ mol
8 The reaction pathway diagram below illustrates the energies of the reactants, the products and
the transition state of a reaction.
A E1 E2 B E2 E1 C E2 E3 D E3 E2
9 Methylpropan-1-ol and butan-1-ol are structural isomers. Methylpropan-1-ol has a lower boiling
point.
Which statement explains why the boiling point of methylpropan-1-ol is lower than that of
butan-1-ol?
anode cathode
A carbon carbon
B carbon steel
C steel carbon
D steel steel
11 For which equation is the enthalpy change correctly described as an enthalpy change of
formation?
D It is an oxidising agent.
Which of these elements has the second smallest atomic radius in its group and the third
lowest first ionisation energy in its period?
A boron
B calcium
C magnesium
D sodium
15 Use of the Data Booklet is relevant to this question.
3 3
A sample of potassium oxide, K2O, is dissolved in 250 cm of distilled water. 25.0 cm of this
3 3
solution is titrated against sulfuric acid of concentration 2.00 mol dm . 15.0 cm of this sulfuric
acid is needed for complete neutralisation.
3
Which mass of potassium oxide was originally dissolved in 250 cm of distilled water?
16 Chlorine gas reacts with cold aqueous sodium hydroxide. It can also react with hot aqueous
sodium hydroxide.
What are the oxidation numbers of chlorine in the products of these reactions?
A 1, +1 1, +5
B 1, +1 +1, +6
1, +2 1, +5
C
1, +2 +1, +6
B Cl (aq) can reduce Br2(aq).
C Cl 2(aq) can oxidise Br (aq).
D Cl 2(aq) can reduce Br (aq).
Which graph correctly shows relative electronegativity plotted against relative atomic radius for the
elements Na, Mg, Al and Si?
20 Many organic reactions need to be heated before reaction occurs, but some do not require
heating.
Which pair of reactants, under suitable conditions, will produce this ester?
23 The hydrolysis of 1-chloropropane to produce propan-1-ol is much slower than the corresponding
hydrolysis of 1-iodopropane.
B The bond strength of the C I bond is less than that of the C Cl bond.
C The carbon atom in the C Cl bond is more + than that in the C I bond.
24 What is involved in the mechanism of the reaction between aqueous sodium hydroxide and
1-bromobutane?
2.76 g of ethanol were mixed with an excess of aqueous acidified potassium dichromate(VI). The
reaction mixture was then boiled under reflux for one hour. The organic product was then
collected by distillation.
HO2CCH=CHCO2H HO2CCH(OH)CH2CO2H
A acidified KMnO4
27 A reaction between chlorine and propane in ultraviolet light produces two isomeric
monochloropropanes, C3H7Cl, as products.
expected ratio of
type of bond fission
in initiation step 1-chloropropane to
2-chloropropane produced
A heterolytic 1:1
B heterolytic 3:1
C homolytic
1:1
D homolytic 3:1
If this compound is reacted with a cold, dilute, acidified solution of potassium manganate(VII),
how many chiral centres will be produced?
A 0 B 1 C 2 D 3
29 Geraniol is a constituent of some perfumes.
A Geraniol causes hot acidified potassium dichromate(VI) to change colour from orange to
green.
C There are three methyl groups and three methylene (CH2) groups in geraniol.
Section B
For each of the questions in this section, one or more of the three numbered statements 1 to 3 may
be correct.
Decide whether each of the statements is or is not correct (you may find it helpful to put a tick against
the statements that you consider to be correct).
A B C D
Which terms can be illustrated by an equation that shows the formation of a positive ion?
2 heterolytic fission
34 A farmer spreads lime on land which has already been treated with an ammonium nitrate
fertiliser.
35 Which of the halide ions, chloride, bromide or iodide, acts as a reducing agent when its sodium
salt reacts with concentrated sulfuric acid?
1 at least one of Cl , Br and I
2 at least two of Cl , Br and I
3 all three of Cl , Br and I
2 Y is a diatomic molecule.
3 Z is a polar molecule.
37 Disaccharides, C12H22O11, are important in the human diet. For example, sucrose is found in
pastries and lactose occurs in milk products.
Which reagents will react with glyceraldehyde to produce an organic product without a chiral
carbon atom?
1 CH3CH2CO2CH3
2 CH3CH2CH2CN
3 CH3CH2CH2Cl
40 X is an organic compound. X gives a precipitate with aqueous silver nitrate. Some or all of this
precipitate remains undissolved when an excess of dilute aqueous ammonia is added.
1 2-chlorobutane
2 2-bromobutane
3 iodomethane
1
4