Set

SCHOLASTICA
(Mirpur Branch)

Mock 1
Academic Session: 2016-2017
Name: ______________________________ Full Marks: 40 Score:

________

Class: XI Section: Roll: _________

Subject: Chemistry Paper 3 Duration: 2 hours

READ THESE INSTRUCTIONS FIRST

Give details of the practical session and laboratory where appropriate, in the boxes
provided. Write in dark blue or black pen.

You may use a soft pencil for any diagrams, graphs or rough
working. Do not use staples, paper clips, highlighters, glue or
correction fluid.

Answer all questions.

You may lose marks if you do not show your working or if you do not
use appropriate units.

Use of a Data Booklet is unnecessary.

Qualitative Analysis Notes are printed on last two pages.

At the end of the examination, fasten all your work securely together.

The number of marks is given in brackets [ ] at the end of each

question or part question.

1 In this experiment you are to determine the relative formula mass of an iron( II) salt by titration
with potassium manganate(VII).
Weigh the 250 cm3 beaker and record the mass in the space below.
FA 1 is the Add
iron(all the FA 1 provided to the beaker. Weigh the beaker with FA 1 and record the
II) salt.
mol dm3 potassium manganate(VII), KMnO4.
mass.
FA 2 is 0.0200
FA 3 is dilute sulfuric the
Calculate acid, H2SO
mass of4.FA 1 used and record this in the space below.
Use a measuring cylinder to add approximately 100 cm3 of FA 3 to the beaker. Stir
(a) Methoduntil all the solid has dissolved.
Transfer the solution into the 250 cm3 volumetric (graduated) flask labelled FA 4.
Pipette 25.0 cm3 of FA 4 into a conical flask.
Washaout
Preparing the beaker
solution of FAthoroughly
1to add 20 using3 distilled water and add the washings to the
Use a measuring cylinder cm of FA 3 to the flask.
volumetric flask. Make the solution up to the mark using distilled water.
Fill the burette with FA 2.
Titrate
Shake FAthe flaskFA
4 with thoroughly
2 until the to solution
mix the solution
changesbefore using it forpink
to a permanent yourcolour.
titrations.
Perform
This solution
Titration
a rough oftitration
the iron(andII) salt is FA
record 4. burette readings in the space below.
your
 The rough titre is ............................ cm .
3

Carry out as many accurate titrations as you think necessary to obtain consistent
results.
Make sure any recorded results show the precision of your practical work.
Record in a suitable form below all of your burette readings and the volume of FA 2
added in each accurate titration.
 25.0 cm3 of FA 4 required ........................ cm 3 of FA 2 [1]

(c) Calculations

Show your working and appropriate signicant gures in the nal answer to each step of
your calculations.
(b) From your accurate titration results, obtain a suitable value to be used in your calculations.
Show clearly how you have obtained this value.
(i) Calculate the number of moles of potassium manganate( VII) present in the volume
of FA 2 calculated in (b).

moles of KMnO4 = ..................... mol

(ii) The half-equation for the reduction of a manganate(VII) ion is:

MnO4 + 8H+ + 5e Mn2+ + 4H2O

Give the half-equation for the oxidation of an iron( II) ion to an iron(III) ion.

....................................................................................................................................

Therefore, 1 mole of manganate(VII) ions reacts with 5 moles of iron(II) ions.

(iii) Calculate the number of moles of iron(II) ions present in 25.0 cm3 of solution FA 4.

moles of Fe in 25.0 cm3 of FA 4 = ....................... mol

2+

iron(II)ofions
(iv) Calculate the number of moles of moles Fe present of FA
in 250
in 250 cm 3
cm43 of
= solution
2+
FA 4. mol
.......................
 [5]

(d) (i) A 25 cm pipette is accurate to 0.06 cm .

3 3

Calculate the maximum percentage error when the pipette was used to measure
solution FA 4.

percentage error in measuring FA 4 = ...................... %

(ii) State the maximum error in the mass of the 250 cm beaker that you recorded in (a).
3

(v) In 1 mole of the iron(II) salt, FA 1, there is 1 mole of iron(II) ions. maximum error = .................. g
Use the mass of FA 1 you weighed out to calculate the relative formula mass of the iron( II) salt.
(iii) Calculate the maximum percentage error in the mass of FA 1 used in (a).

maximum percentage error = ....................... %

[2]

[Total: 15]
2 In this experiment you will determine the enthalpy change, H, for the catalytic
decomposition of

hydrogen peroxide into water and oxygen.

H2O2(aq) H2O(l) + 12O2(g)

FB 3 is aqueous hydrogen peroxide, H2O2.

FB 5 is manganese(IV) oxide, MnO2, the catalyst for the decomposition.

(a) Method

Read through the method before starting any practical work and prepare a table for
your
results in the space below.
For the first experiment, support the plastic cup inside the 250 cm 3 beaker.
Use a measuring cylinder to transfer 40 cm 3 of distilled water into the plastic cup.
Use a measuring cylinder to add 10 cm3 of FB 3 into the plastic cup.
Measure and record the initial temperature of the mixture.
Add a heaped spatula measure of FB 5 to the mixture in the plastic cup.
 Stir constantly until the maximum temperature is reached and record this
temperature.
Calculate and record the temperature rise.
Wash and wipe out your plastic cup and rinse the thermometer, ready for the second
experiment.

For the second experiment, support the plastic cup inside the 250 cm 3 beaker.
Use a measuring cylinder to transfer 30 cm 3 of distilled water into the plastic cup.
Use a measuring cylinder to add 20 cm3 of FB 3 into the plastic cup.
Measure and record the initial temperature of the mixture.
Add a heaped spatula measure of FB 5 to the mixture in the plastic cup.
Stir constantly until the maximum temperature is reached and record this
temperature.
Calculate and record the temperature rise.
Wash and wipe out your plastic cup and rinse the thermometer, ready for the third
experiment.
Carry out the third experiment in a similar way.
Transfer 20 cm3 of distilled water into the plastic cup.
Add 30 cm3 of FB 3 into the plastic cup.
Measure and record the initial temperature of the mixture.
Add a heaped spatula measure of FB 5 to the mixture in the plastic cup.
Record the maximum temperature, then calculate and record the temperature rise.

For the fourth experiment, use 10 cm 3 of distilled water and 40 cm3 of FB 3.

[5]

(b) Using the grid below, plot a graph of the temperature rise (y-axis) against the volume of FB 3
(x-axis).
Draw the line of best t.

II

III

IV

Use your graph to calculate the average temperature rise for each 1.0 cm of FB(c) 3 Calculation
3 used.
..............................................................................................................................................
Show your working clearly on the graph. [1] (i)
[4]
 [Total: 14]

3
Qualitative Analysis
colour changes seen
the formation of any precipitate
gases are released they should be identied by a test, described in the appropriate place
Where
At each
the stage of any
solubility test you
of such are to record
precipitates in an details
excessofofthe thefollowing.
.............................................................................................................................................
reagent added
 (iii)
To a 1 cm depth of FB 3 in a test-tube, add an equal volume of sulfuric acid, FB 2.
Then add a 1 cm depth of FB 7, followed by a few drops of starch solution.
Record all your observations.
Draw what conclusions you can about the ions in FB 7. If no conclusion is possible, write
not known.

observations .......................................................................................................................

.............................................................................................................................................

.............................................................................................................................................

FB 7: cation .................................................. anion ..........................................................

(b) FB 7, FB 8 and
CarryFBout
9 are
the aqueous
following solutions, each containing one cation and one anion. Note [5]
tests in test-tubes.
that FB 7(i)
wasUse
also1used in (a)(iii).
cm depths of solutions.
 Complete the table by recording your observations.

(ii) Suggest the identify of the cation in FB 9.

Explain your answer.

cation ............................................................................................................................
......

explanation ...................................................................................................................
......

(iii) Give the ionic equation for the reaction between FB 7 and FB 9.
 ......................................................................................................................................
.......

(iv) From your observations, identify FB 8.

......................................................................................................................................
....... [6]

[Total: 11]
 Qualitative Analysis Notes

Key: [ppt. = precipitate]

1 Reactions of aqueous cations

reaction with
ion
NaOH(aq) NH3(aq)

aluminium, white ppt. white ppt.

Al (aq)
3+ soluble in excess insoluble in excess

ammonium, no ppt.

NH4 (aq) ammonia produced on heating
+

barium,
no ppt. (if reagents are pure) no ppt.
Ba2+(aq)

calcium,
white ppt. with high [Ca2+(aq)] no ppt.
Ca2+(aq)

chromium(III), grey-green ppt. soluble in excess grey-green ppt.

Cr3+(aq) giving dark green solution insoluble in excess

copper(II), pale blue ppt. blue ppt. soluble in excess

Cu2+(aq) insoluble in excess giving dark blue solution

green ppt. turning brown on contact green ppt. turning brown on contact
iron(II),
with air with air
Fe2+(aq)
insoluble in excess insoluble in excess

iron(III), red-brown ppt. red-brown ppt.

Fe3+(aq) insoluble in excess insoluble in excess

magnesium, white ppt. white ppt.

Mg2+(aq) insoluble in excess insoluble in excess

off-white ppt. rapidly turning brown off-white ppt. rapidly turning brown
manganese(II),
on contact with air on contact with air
Mn2+(aq)
insoluble in excess insoluble in excess

zinc, white ppt. white ppt.

Zn2+(aq) soluble in excess soluble in excess
2 Reactions of anions

ion reaction

carbonate, CO2 liberated by dilute acids

CO3
2

chloride, gives white ppt. with Ag+(aq) (soluble in NH3(aq))

Cl (aq)

bromide, gives cream ppt. with Ag+(aq) (partially soluble in NH3(aq))

Br (aq)

iodide, gives yellow ppt. with Ag+(aq) (insoluble in NH (aq))

I (aq) 3

nitrate,
NO3 (aq) 3

NH liberated on heating with OH (aq) and Al foil

nitrite, NH liberated on heating with OH (aq) and Al foil;
3
NO2(aq)
NO liberated by dilute acids
(colourless NO (pale) brown NO2 in air)
sulfate, gives white ppt. with Ba2+(aq) (insoluble in excess dilute strong acids)
SO (aq) 4
2

sulfite, SO2 liberated with dilute acids;

SO (aq) 3
2
gives white ppt. with Ba2+(aq) (soluble in excess dilute strong acids)

3 Tests for gases

gas test and test result

ammonia, NH3 turns damp red litmus paper blue
carbon dioxide, CO2 gives a white ppt. with limewater
(ppt. dissolves with excess CO2)
chlorine, Cl 2
bleaches damp litmus paper
hydrogen, H2 pops with a lighted splint
oxygen, O2 relights a glowing splint
turns acidified aqueous potassium manganate(VII) from purple to
sulfur dioxide, SO2
colourless