ANALYTICAL CHEMISTRY (CHEM 300)

University of Santo Tomas 2nd Semester AY 2015-2016

Faculty of Engineering Quiz # 5 & 6 Application Take Home
Department of Chemical Engineering (Module 4: Acid-Base Titration
Module 5: Precipitation Titration)

Name: Section: Date:

Item numbers Raw Score Percentage

Application 1-4 __ / __

Instructions:
1. Solve the following problems and place your answers in an MS Excel file.
2. Put each titration curve and problem in separate sheets and name each after the question number.
3. Obtain equilibrium constants from the Appendix section of your textbook (Skoog et al.).
4. Your final answers should be BOLD and highlighted in yellow (BOLD). DO NOT USE RED as a font color.
5. Save your file in the following format:
(Section)_(Surname, Initials)_Chem300Quiz6.xls e.g. 2ChE-A_Tamolang, RAZ._Chem300Quiz6.xlsx
and upload it in the designated folder for your section found in the Content Tab.
6. Deadline is May 15, 2017 (Monday) 7:59:59 PM.

I. For each of the following precipitation titrations, calculate the cation and anion concentrations and construct a titration curve by plotting
the p-function of the cation versus the titrant volume in mL. Follow this template in constructing the titration curves:

A. Titration of 50.00 mL of 0.0800 M KSCN with 0.0400 M Cu+.

The solubility product of CuSCN is 4.8 x 10-15.
At each of the following volumes of titrant, calculate pCu+ and construct a graph of pCu+ versus mL of
Cu+ added: 0.10, 10.0, 25.0, 50.0, 75.0, 95.0, 99.0, 100.0, 100.1, 100.0, 110.0 and 120.0

B. Titration of 25.00 mL of 0.0400 M Hg2(NO3)2 with 0.0500 M KIO3.

The solubility product of Hg2(IO3)2 is 6.9 x 10-7
2 (3 )2() 22+ + 23
Choose the volume of titrant to be 0-80 mL, with 10 mL increments.

C. Titration of 40.00 mL of 0.02500 M BaCl2 with 0.0500 M Na2SO4.

Choose the volume of titrant to be 0-80 mL, with 10 mL increments.

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