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that of hole
In a metal the electron mobility and the hole mobility is the same. Only reason for a
difference in the mobilities in a semiconductor is different spatial symmetry of the
envelop function for an electron and a hole.
The mobility of electrons and holes is different, because the electrons and holes have different
spatial symmetry. The electrons have s-orbital-like symmetry of the envelop wave function. The
holes have p-orbital-like symmetry of the envelop wave function.
There are two reasons why the difference in the spatial symmetry causes the different mobility.
They may sound different, but they explain the same fact.
The first reason, why the mobility is different, is that it takes a longer time for an electron to
circle around the p-orbital than around the s-orbital.
A delocalized electron simultaneously moves along the crystal lattice and rotates around millions
of atomic nuclei . It might sound strange that it is possible to rotate around several objects
simultaneously. Since an electron is a wave, it is possible. For example, when light is diffracted
by a diffraction grating , each photon is reflected from each of million steps of the grating)
simultaneously. Any wave can interact with many objects simultaneously. It is not forbidden.
There are many experimental proofs that delocalized electrons have a non-zero orbital moment.
For example, their g-factor is different from 2, they experience the center-symmetrical spin-orbit
interaction and the existence of the split-off valence band is other proof. The non-zero orbital
moment literally means that the delocalized electron is orbiting around atomic nuclei.
The second reason, why the mobilities (effective masses) are different for holes and electrons in
a semiconductor, is that the magnitudes of the s-like and p-like envelope functions are different
in the vicinity of the atomic nucleus. The electrons of different symmetry interact differently
with the nucleus. Therefore, the amplitude of the lattice periodic potential is different for
electrons and holes in a semiconductor. This causes the different effective masses.