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AS Level Chemistry
Paper 1 - Physical and Inorganic
Edexcel
A
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CONTENTS
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OUR MISSION4
HOW TO USE OUR GUIDES.4
Topic 1: Atomic Structure and the Periodic
Topic 2: Bonding and Structure
Topic 3: Redox I
Topic 4: Inorganic Chemistry and the Periodic Table
Topic 5: Formulae, Equations and Amounts of Substance
BREAKDOWN OF EXAMINATION.36
THE KEY TO DOING WELL.36
OUR MISSION
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EXAM
Mock Paper
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Assessed
Written exam: 1 hour 30 minutes
80 marks
50% of AS
Questions
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Topic 1: Atomic Structure and the
Periodic
Atoms
Notes 2. Put into equation for finding the relative atomic mass and
rearrange for the unknown value
Predicting mass spectra for diatomic molecules (E.g. Cl)
1. Express each % as a decimal (e.g. 75%0.75 and
25%0.25)
2. Make a table showing all the different Cl molecules. For
each, multiply the abundances of each isotope to get the
relative abundance of each molecule.
3. Look for any values in the table that are the same and add
up their abundances
4. Divide all the relative abundances by the smallest relative
abundance to get the smallest whole number ratio. And by
working out the relative molecular mass of each molecule,
you can predict the mass spectra
5. Plot the mass spectra with the relative abundances you
worked out on the y-axis and the relative molecular masses
(m/z) on the x-axis
Identifying compounds using mass spectrometry
1. Molecules in a sample are bombarded with electrons to
remove an electron and form a molecular ion, M
2. The molecular mass is shown by the molecular ion peak -
the peak with the highest m/z value, not including any M+1
peaks caused by presence of carbon-13
Electron Shells
- Made up of subshells and orbitals
- Electrons move around the nucleus in quantum shells (aka
energy levels)
- Shells further from the nucleus have a greater energy level
than those closer to the nucleus
- Shells contain different types of subshell, each of which
have different numbers of orbitals which can each hold 2
electrons
Subshells
This table shows the subshells and how many electrons can
be contained in each
Notes
Orbitals
- Orbitals within the same subshell have the same energy
- s-orbitals are spherical
- p-orbitals are dumbbell-shaped. There are 3 p-orbitals and
they are at right angles to each other
Electronic configuration
- Electrons fill up the lowest energy subshells first
- Electrons fill orbitals singly before they start pairing up
- Exceptions: Chromium and Copper - donate a 4s electron to
the 3d subshell because they are more stable with a full or
half-full d-subshell
Periodic table electron configuration blocks
- s-block elements have an outer shell electronic
configuration of s or s
- p-block elements have an outer shell electronic
configuration of sp to sp
Notes electrons
- The repulsion between two electrons in an orbital means
that electrons are easier to remove from a shared orbital
Atomic Number
Is the number of protons in the nucleus of an atom of that
element (Z)
Avogadro Constant
Is the number of atoms of Carbon-12 in exactly 12g of
carbon-12
Avogadro's law
States that equal volumes of gases under the same conditions
of temperature and pressure contain the same number of
molecules
Electronic Configuration
An atom shows the number of electrons in each sublevel in
each energy level of the atom
Hurd's Rule
States that electrons will occupy the orbitals singly before
pairing takes place
Mass Number
The sum of the number of protons and the number of
neutrons in the nucleus of that atom
Orbital
Is a region within an atom that can hold up to two electrons
with opposite spins
Pauli Exclusive Principle
States that two electrons cannot occupy the same orbitals
unless they have opposite spins. Electron spin is usually
shown by the use of upward and downward arrows
Periodicity
Is a rugularly repeating pattern of atomic, physical and
chemical properties with increasing atomic number
Quantum Shell
Defines the energy level of an electron
Relative Atomic Mass
It is the weighted mean mass of an atom of an element
compared to 1/12 of the mass of an atom of carbon-12
4BP, 1LP
119 and 89 degree angles
3BP, 2LP
Trigonal planar shape
What does a single covalent bond look like in dot and cross
form?
A covalent bond is a shared pair of electrons
What does a double covalent bond look like in dot and cross
form?
A double covalent bond is two shared pairs
What does a triple covalent bond look like in dot and cross
form?
A triple covalent bond is three shared pairs
Notes What does a dative covalent bond look like as a dot and cross
diagram?
Why does the least dense hydrogen halide have the highest
boiling point?
Because it has hydrogen bonding
What types of bonding can giant lattices be formed?
Ionic
Covalent
Metallic
What is an example of a giant ionic lattice?
Most ionic solids
What is an example of a giant covalently bonded lattice?
Diamond, graphite etc...
What is an example of a giant metallic lattice?
All metal solids
What is the order of bonding strongest to weakest?
Covalent, ionic, metallic
Why does the general boiling point increase for hydrogen
halides?
Because down a group the atomic radius increases increasing
the surface area leading to stronger London forces
Topic 3: Redox I
What is an oxidation number?
The charge that an atom in a compound would have if the
compound consisted only of separate ions
What oxidation number does an element on its own have?
Notes 0
What oxidation number do hydrogen ions almost always
have?
+1
What is the exception of the oxidation number of hydrogen
ions and when does it occur?
In NaH (sodium hydride) the H ions are -1
What oxidation number do oxygen ions almost always have?
-2
What is the exception of the oxidation number of oxygen
ions and when does it occur?
In H2O2 the O ions are -1
What oxidation number do chlorine ions almost always
have?
-1
What is the exception of the oxidation number of chlorine
ions and when does it occur?
Cl changes oxidation number with oxygen, e.g. Cl2O7: +6,
ClO: +2
What is the sum of the oxidation states in a compound?
Zero
What is the sum of the oxidation numbers equal to on a
complex ion?
The complex ion's charge
Is reduction loss or gain of electrons?
Gain of electrons
Is reduction loss or addition of hydrogen?
Addition of hydrogen
Is reduction loss or gain of oxygen?
Loss of oxygen
Is oxidation loss or gain of electrons?
Loss of electrons
Is oxidation loss or addition of hydrogen?
Loss of hydrogen
Is oxidation loss or gain of oxygen?
BREAKDOWN OF EXAMINATION
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