Beruflich Dokumente
Kultur Dokumente
2014 (TI)
'?'81211 fcJ$1/rt
rrR q?{
'fl'1l71 : 3:00 cit ~: 200 Jfq;
I. 311rR ~ t
q;T 'lfT'CZl1r TiT I ~ rRte7T ~ "sf r.;q; y:ff rtrm;f'm (20 '1f7T I A'#+ 50
'm7T 'BI + 75 'm7T 'C' "sf ) ffSC7 fiicm;q rrFf (M CQ) ~ 7JT{ ~ I ;mr:rq;T 11T'T 'AI "sf ?t
~ 15 JfR- '1f7T 'B # 35 JrFf}' nwr 11T'T 'C' "sf ?t 25 rrFff <t ~ eM ~ 1 ~
1
f.!!tdfffl # ~ rrFff <5 ~ (?v 7JT{ 'ffr ctcm 11T'T 'A' # 15, ~ 'B' # 35 rmr 11T'T
'C' # 25 ~ I:JC'f'f# ctt \ifiq <!ft. iii7Vifr I
2. 3/t.f[~f.~. UfiR rp_y 3TWJ # ~ 1fllT ~ I 3TfFfT m-r
rrTiiV 3ft? R CfiT "fT1f f&.g.t #
rn:<;f w lifiq ~ frff ~ # rpo 1fJ 3fR ?rift ~ nwr Cfflft. # <R-flit 'flff ~ 1 ~
~ ~ 'ffr JfTl1 $Pilvflc>ic'< # i3Wt ~ ctt ~ ~ q;r ~ "fiR ~ ~ 1 ~!
~ # 3/t. f{11.JIR. ~ rr=l q;T ~ lifiq c>f I ~ ~ # vr5 q;rq Ci>Ff qi fc:/f[
~f:Ft~~ I
3. 3/t. f{11.:37R. ~ Cj3fCff qi rpo 1 "sf ~ 7JT{ re!Ff rR JTTFfT ~m-r ..,..,.
fr2lT ~ rffllfff
~ <PT iff11TC11 ~ '<'fT2T tt JTTFfT ~ ~ JTCml cR I
4. JfTl1 ~ 3lt.f{11.JIR. ~ rr:;;;; -sr ?R;r m frrtm em. ~ c;;R: JtT? R <1iT\5 ~
~ ~ vm- <'Iff <liT& ~ rR # J1Cml qm;rr tR 1 w ~[iff 1fPj{ rrtterTPff ctt
~u'lcnfl "! frff ~ ~ gffflCfiT "If~ w Mff q;r f!ft
fii4EIRt # wwr cR. ~ <r
m w ~ ~ w wdt fffrqt ?t ~ rttr q;v Wf!717. ~ Jtrrrr. :mrlCiiT
~ tcrrf/71 37W<iff ~ ~ Cfft ~ ~ mfirc;r t:, llt ~ t
I
5. 11T'T A I fr2!T '177T 'B' # rTfllq; rwr <5 2 ar<fi 'C' "If ~ rrFr 4 3Tilf <PT
1
t
1 !lfllq; rmn
~ <PT '3h.OJIMCfJ ~ 25 % Cfft <:"? # fitK:rr iJTTV1TT I
6. ~ rrFr <5 rfTi1 "ilR fiicm;q f?v 7JT{ ff I ~ # <tern \[iff fitq;c;q tt "mfr 3f2/CfT
~ rn t 1 3l7fl7fiT rTfllq; !1FT q;r ?rift JT2T<ff ~ rn ~ t 1
7. "'7lfM m ~ llT ~ ~ CfiT >I7Wr C~mt ~ ~ ~ ~ ~ q;7 ffl J~R 3RJ
1Wit ~ qi {t;rv ~ 06?TllT lifT ~ "! I
8. ~ rm \3'ffi? llT ?Vi A c5 ~ ctJtf JfR <tJE1 ~ ~ f&Jro ~ 1
9. tfl<'1f1iHc'< q;r ~ Cl>F! Clfr ~ ~ t 1
I0. rRmr_ f/11Tfo . rw ~ ~ ffd%G rewr # 3/t. f{11.JTR". \3'ffi? rffl7fi q;f ~ -q-;VI
~~e'< rm ~ Jff.v-r.JrR. iJfflV rrw; i'l'frT:t $ rmnn ;mer _p:rqft q;YJ'1<4fl ~
c>i' lifT W<fflt ~I
I I. ftrcft 7fT'UT11/~ q; rrFr "If ~ m /rn<) lifFt w 31?lvft ~ ff1fTfiJrq; fft7rT I
ctcm rrtterr qfr f!ft J!<f(i)' nq; tio.t <nc-1 ~ q;t tt rrtterr ~ '<'fT2T (7 lifFt ctt
JTTf{fr eft vmnft I
VTC7 ~ ...................... .
S/55 CSI/14-1AH-1A
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S /55 CSI /14- 1AH -18
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~~~
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LIST OF THE ATOMI C WEIGH TS OF THE ELEME NTS
Element Symbol Atomic Atomic Element Symbol Atomtc Atomic
Number Weight Number Weight
Acttruum Ac 89 (227) Mercury Hg 80
Alumtntum AI
200.59
13 26.96 Molybdenum Mo
Amcnctum 42 95.94
Am 95 (243) Neodymium Nd 60 144.2.4
Anttmony Sb 51 121.75 Neon Ne 10
Argon Ar 20.183
18 39.948 Neptunium
Arsentc Np 93 (237)
As 33 74.92 Ntckel Ni 28 58.71
Astatine At 85 (21 0) Niobium Nb 41 92.91
Banum Ba 56 137.34 Nitrogen N 7 14.007
Berkelium Bk 97 (249) Nobelium No
Beryllium Be
102 (253)
4 9.012 Osmium
Btsmuth Os 76 190.2
Bt 83 208.98 Oxygen 0 8 15.9994
Boron B 5 10.81 Palladium Pd
Bromtne Br 46 106.4
35 79.909 Phospho rus p
Cadmtum Cd 15 30.974
48 112.40 Platinum Pt 78 195.09
Calctum Ca 20 40.08 Plutoruum
Californium Cf
Pu 94 (242)
98 (251) Polonium Po 84 (21 0)
Carbon c 6 12.011
Cerium Potassium K 19 39.102
Ce 58 140.12
Cestum Praseodymium Pr 59 140.91
Cs 55 132.91
Chlorine Promethium RTl 61 (147)
Cl 17 35.453
Chromtum Protactinium Pa 91 (231)
Cr 24 52.00
Cobalt Radium Ra 88 (226)
Co 27 58.93
Copper Radon Rn 86 (222)
Cu 29 63.54
Rhenium Re 75
Cunum em 96 (247) 186.23
Dysprosium Rhodium Rh 45 102.91
Dy 66 162.50
Etnstetruum Rubidtum Rb 37 85.47
Es 99 (254)
Erbium Ruthenium Ru 44 101.1
Er 68 167.26
Europium Eu Samarium Sm 62 150.35
63 151.96
Fermtum Fm Scandium Sc 21 44.96
100 (253)
Fluorine F 9 Selenium Se 34 78.96
19.00
Franctum Fr 87 Silicon Si 14 28.09
(223)
Gadolinium Gd 64 Silver Ag 47 107.870
157.25
Gallium Ga 31 Sod1um Na 11 22.9898
69.72
Germanium Ge 32 stronttum Sr 38 87.62
72.59
Gold Au 79 196.97 Sulfur s 16 32.064
Hafntum Hr 72 178.49 Tantalum Ta 73 180.95
Helium He 2 4.003 Technetium Tc 43 (99)
Holm tum Ho 67 164.93 Tellurium Te 52 127.60
Hydrogen H 1 Terbium Tb 65
1.0080 158.92
Indium In 49 114.82 Thallium 11 81 204.37
Iodine I 53 Thorium Th 90
126.90 232.04
lndtum lr 77 Thulium Tm
192.2 69 168.93
Iron Fe 26 Ttn Sn
55.85 50 116.69
Krypton Kr 36 Titanium 1i
83.80 22 47.90
Lanth anum La 57 138.91 Tungste n w 74 183.85
Lawrenc tum Lr 103 (257) Uranium u 92 238.03
Lead Pb 82 207.19 Vanadium v 23 50,94
Lith tum Li 3 Xenon
6.939 Xe 54 131.30
Lutetium Lu 71 Ytterbium
174.97 Yb 70 173.04
Magnesium Mg 12 Yttrium y
24.312 39 88.91
Mangan ese Mn 25 54.94 Zinc Zn 30 65.37
Mendelevium Md 101 (256) Zirconium Zr 40 91.22
eased on mass or C 12 at 12.000.. . The ratto or these
weights or those on the order chemica l scale (in which
natural isotopic compos ition was assigne d a mass or 16.0000 oxygen or
... ) Is 1.00005 0. (Values In parenthe ses represen t the most
stable known isotopes .)
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I. 5%~ 8. ~ 3l<ri'Sfi'IJOI'
..) ~~ q:m t?
2. < I% c>rra:r 2, 3, 4, 7, 6, II, 8, 15, 10 ...
3. <!% ~ I. 12 2. 13
3. 17 4. 19
4. ~~m~~
8. What is the next number of the following
S. A person sells two objects at Rs.l 035/- each. sequence?
On the first object he suffers a loss of I 0% 2, 3, 4, 7, 6, II, 8, 15, I0 .. .
while on the second he gains 15%. What is
I. 12 2. 13
his net loss/gain percentage?
3. 17 4. 19
1. 5% gain
2.
3.
< 1% gain
< 1% loss 9. ~ <.YR:r qlq~Sh<H ~ ~ * ~ 20%
4. no loss, no gain :mftu'r M ~ lfcli ~ ~ 3kK ~ q']"(f 6
I :mftu'rM~'~~'F~~~
6. vefi~'Q'Cfi~~~t~ ~ ~ 'R ~ 20% ~ q']"(f 6 I
1600 ~ ~ ft:tQ' ~ m:rr Fvrcnr 3l"TaT ~ ~ GITC; 'll1tr 16 fcrtmft iH1-?tJtl{ ~. m
em ~ ~
~ JOOO/- ~
t,
Fvrcnr
~ &lffi5f ~ ~
~ ~ 400 ~
"
1
'#
qJo~Sh<H
I.
-
32
* C!it'f
..)
~ ~
2.
:mftu'r tir?
64
~ ~ .
3. 25 4. 100
t,TM1 &lffi5f ~ ~
l. 250 2. 183
9. 20% of students of a particular course get
3. 148 4. 190
jobs within one year of passing. 20% of the
remaining students get jobs 'by the end of
6. A bank offers a scheme wherein deposits
made for 1600 days are doubled in value, the second year of passing. If 16 students are still
interest being compounded daily. The interest jobless, how many students had passed the
accrued on a deposit of Rs.l 000/- over the course?
1. 32 2. 64
first 400 days would be Rs.
3. 25 4. 100
1. 250 2. 183
3. 148 4. 190
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10. ~ d c;m ~ d/2 <l> "QCfi Jmi ~ VCfi 12. "QCii ~ ~ ll<fi ~ 'R ~ R ('fCfl
iiiT{ ~ ~ eli Pit QCf "QCfi art ~ ~ mfr f; I W ~ rnt cnT ~ rT
~ <l> f7rt qt- ~ U111<IT aT<1T ~ ~ c:rm~~melim-or~~m-
" ~
ii!T{H~~q;r~~ rT "QCii ~ ~ ~ ~. VCfi ~ offi1 eli
*
~
I. I: I
3. J :3
2. I :2
4. I :4
m~ 3fldT(1T t 1 'ilR ~ ~ q1l" s*
~~ ~~2 ~~f;~~~ R/2
10. A rectangle of length d and breadth d/2 is ~~HJW~~~
revolved once completely around its length
and once around its breadth. The ratio of
volumes swept in the two cases is
I.
3.
I: I
1:3
2.
4.
I :2
I :4
@
1. .fi ~ 2. 2~
11. ~ Jliilctfi1 'I *
~ :;rcrrc; CfiT ~ 3. z{f~ 4. 4~
gtsjf H ~<r 3'CNr ~~PIT 1fliT f; I <$
12 . A long ribbon is wound around a spool up to
~~rnnr~*~~~ a radius R. Holding the tip of the ribbon, a
~ 6. m ~ ~ *:m ~ eli Jm..<r 'R boy runs away from the spool with a constant
speed maintaining the unwound portion of
~ ~IC'f cr<lCT1(1J4 tiT?
" t he ribbon horizo ntal. In 4 minutes, the radius
~ In what
400
350
of the wound portion becomes
(250 further time, it will become R/2?
300
75J (200
250
75)
200 [150
150
SOJ
1 (100 +
100 SOJ
50
400
350
(250 c
300
75J [200 i
250
(150 75J
200
150
so, (100
100 so, B
50
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13. A ladder rests against a wall as shown. The ~ ~ t I ~ ~ qw:r ~ q;l'f V<li
top and the bottom ends of the ladder are "
marked A a)td B. The base B slips. The
3reR' ~ 'QCti' Jtq:; cnr ~ ~ t 1 3fa'RT
central point C of the ladder falls along A~ zrrcn, ~ ~~ 9 ~~~~~
~~~aT~~
1. 936 2. 1148
3. 1872 4. 2574
~ ~ tf ll)JJQ)(>l ao + a1 + a2 +.... +
~ ~ arr<tiTt ~ c:rtrr ~ ~ ~ 3f1'Cm'
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18. Weights (in kg) of 13 persons arc given 21. The reaction betW!!t:n SbF5 and iwo equivalent s
below: of HF leads to the formation of
70. 72. 74, 76, 78, 80, 82. 84. 86, 88. 90, 92, I H2Sbro + 2F2
94 2 H SbF~T 3F2
3. Sbf, + H2 + 2F2
Two new persons having weights 100 kg and 4. [SbFor [H2F] '
79 kg join the group. The average weight of
the group increases by
22. o-~~~~~t. Qt;~
I. 0 kg 2. 1 kg
3 1.6 kg 4. 1.8 kg 1. 'dx2- /CJmd~2.,2 ~
2 du crm du .3fTfftu;r
19 ~ nVC!i' tm ~ t. nT 3. d,y CitfT dx~ ~
n(n+ I )(n+2)(n+3 )(n+4 )(11'1'5)(n+6)
4. dyz ~TT dyz ~
~t:
I. 3~~7~o:$i' 22. The 8-bond is formed via the overlap of
2. 3 3fit7 ~ I d/ /and d/. / orbitals
2 dxz and dtt orbitals
3. 7~~3~~
3. dxy and dxyOrbitals
4. ;f m3 ~. ;f 1 ~ 4 dyz and d\'Z orbitals
19. rfn is a positive integer, then
n(n+ I )(n+2)(n+3 )(n+4)(n+S )(n+6)
23. F",Na\02 c;tlTMg 2 '~
~ ~ ~
~ ~ (itlT cr4Cii(iJOI ~' ij' ~ ~T:
*
is divisible b}
I. 0 2. c:JmNa-
"
I. 3 but not 7
2. 3 and 7 2 F- c;m Mg2
3. 7 but not 3
3. o2- ~ Mg2
4. neither 3 nor 7
4. Mg2 'c:Jm o 2-
20. 3ITll111 50 1ft.. 120 ;fr \rei 130 ;fr ci; 'tJCF
23. 1\mong F . Na , 0 1 and Mg' ions, those
ft)(h'lu"4 ~ q:;r e~ cenT~ R)~
having the highest and the lowest ionic radii
1. 3000 2. 3250
respectivel y are
3. 5550 4. 7800
I. 0 2 and Na
.,.
20. The area (in tn 2 ) of a triangular park of
2 F and Mg-
2
dimension s 50 m. 120 m and 130 m is 3. 0 and M!(
4. Mg2 'and0"
I. 3000 2. 3250
3. 5550 4. 7800
24. (a)~. (h) Ch)Q.-\511$1R 8 12 CitiT (c) CfC'fi:J.)fQl(>l
cfi ~ ~ ~ ~ n-$<'lct?I01 'fl~J;Jij
31TcTT ~ I PART I B I
q:;r q ~JOIIUI f3rn' ~ Cf;T 3r.i'ffi'Ur ~
.;)
t.
~t
(a) (c)> (b) 2. (a )> (b)> (c )
3. (c )-. ( a )> (b) 4. (b) ::<-(a) > (c)
~~~~~f:rmur~t
(if; tit 24. The extent of n-elcctron conjugatio n m
1. H2SbFl + 2F~ macrocycl ic rings of (a) heme. (b) coenzyme
2 H SbF 2 + 3F2 8 1 ~ and (c) chlorophy ll follows the order
3. Sbf1 + H~ + 2F1 I (a) > (c ) ' (b) 2 (a)> (b) (CJ
4. (sbr6J [H2rr 3 (c )>{a )>(b) 4 (b) ""(a)> lc)
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!. tran.1-(PtCI2(N0 2 )(Nfhl]
32. /ram-[Cr(enh Fll. c=IWr [TiCI~I,. ~ ft:rQ- fa~
2 ,-,~-(PtCI 2 ('\0l )(NH.> I
mw 'HIH~i?llli 6. ~T: 3. rram-[PtCJ,(N H;),]
D3d <1m 4. C/S-(PtC12(M>2hll
1. D,c1~D1d 2. D4d
I. clo.w-~
2 nido-~ 3<>. ~ 61'fHT 'HIll ~<ri ~ ~ 6rfH' rRT?Jroi
3. arachno- ~ it> ~ ~ ~ ~ 'HA.-ClfllCi
*t ~ 6 Sfi1f~L
33. Co4(C0), 2 adopts the L 2, 3 c;m 3, 3
I. closo - structure
2 3. 3 ('f~lT 2. 3
2 mdo - structure
3. arachno- structure 3. 3, 3 Cim2. 2
4. hvpho- structure 4. 2, 4 c;m 3. 2
tii~~I.J1o11Cf>o{ Ul
*~ 'fiA.,-qll oxyhcmocyanin and oxyhemerythrin.
~f; I (Rh AUSM * Ri(>llllq-, respective!), are
q;'r~~) I. ::!, 3 and 3, 3
I. T-~ CfiT [Rh(PPh)hCI ] 2 3, 3 and 2, 3
2 ~ ~ [Rh(PPh 3 hCif
3. 3~ 3 and 2. 2
4. 2. 4 and 3. 2
3. T- .mq:;fct
c.
<liT [Rh(H)(PPh,) CJf
4. ~ ~ [Rh(H)(PPh 1h] 37. ~ cfi ~. 'QCii q4iaor ~ ~ ~
R ~ ~ q:;T qt::all'ill:! I
34 Reductive elimination step in hydrogenation
of aiJ...enes by Wilkinson catalyst results in A. Cfilhtulillo-t"l ~ ~ ~
(neglecting solvent in coordination sphere of MeHg' R '{lql.,-(1~<1 <fit~ t
Rh) B. ft Rl01 ~ Uf$'JITc;r 11'Cf ~ ~ cfi
..:>
I. T-shaped [Rh(PPh3 ) 1CI]
2 Trigonal-planar [Rh(PPhJh Cif ~ Gitrc=rr
..:>
~ t:tft f;
3. T-shaped [Rh(H)(PPh ,)ctr c. :Mlc;_ll'rfJrq:; ~ ~ mq;fr ~
4. Trigonal-planar [Rh(H)(PPh3 h] UT ~ ~ ~ ~<riiAIC:I ~ ~ I
~~f;
35. ~Chrlffiffi'l<1 ~ ~
NH3 I. A c=IWr B 2. A~C
[PtCI~f ~ NO_ --+ A __, B
.) . B~C 4. A, B CimC
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@N~
environment pollutant. Me
N'
A. Carbanionic biomethylation converts
it to MeHg oANI
weN
BF 4-)t_
[}E)
N+
I
B. Thiol group of cysteine has strong affinity Me H2N'" NH2 BF4- Me
for mercury
II Ill
C. Mercury containing industrial catalyst
release caused Minamata disaster I. I<II<III 2. I<Ill < ll
The correct answer is 3. 11 <1<111 4. II<III<I
I. A and B 2. A and C
3. 8 and C 4. A, 8 and C 40. The increasing order of pKa values of the
circled hydrogens in the following
38. compounds is
0
@N~
Me
I
N
I. R (;tiTS 2. S CfmR
oA N
[}E)
N+
3. R C1trr R 4. scrm s I BF . I
Me 4 Me
0
H N
[1
0
8
II
0 Ill
E>=o
IV
N
II Ill
N
IV
39. The compound that is antiaromatic is 41. The decreasing order of basicity of the
H following compounds is
0
B
J? 0 II Ill
IJ::'-=0
IV
[>>
H
N
N
&H-N~) 0 N
I. I 2. II II Ill IV
3. III 4. IV
I. l > Il>III>IV
2 lV>I>II>III
{;j k1 ~ ft!l C1 ~
40. if;
crm * ut6 sv 3.
4.
HI > IT> I> IV
(\l$~)31crt'i ~ pKa ~ q;r ~ q;r sn11 TV> III> II > I
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OH: Rlt!1ari'l4;
.:>
i-Pr: fa<i1ctn"i'l
.:>
Cim Me:
:rD
,
0
. 0 l
.
4.
31aft<r
4. OH: fa<i1c:tcfl4
.:>
; i-Pr: :trmrrm Me:
44. The reaction of 1-bromo-2-fluorobenzene
with furan in the presence of one equivalent
42. In the most stable conformation of neomenthol, ofMggives
stereochemical orientation of the three substi-
l. 2.
tuents on the cyclohexane ring are
1. OH: equatorial: i-Pr: equatorial and
Me: equatorial
2 OH: axial; i-Pr: equatorial and Me:
equatorial
3. OH: equatorial; i-Pr: equatorial and 3. 4.
Me: axial
4. OH: equatorial: i-Pr: axial and Me:
equatorial
43 . f.!l<hl1ffiffi<1 ~ t- ~ ~ t- 45.
fcf;t<;r ~ em ~ ~ ~
Et .,H )J0 Et "'>''H HO"'>',,H
1 BrCH20MefP(OEt)~DME ...
. .X~..,,........_..:_J . . . . -
LiAIH4
~ ..- ,/"-'fs ., 2. NaHIOMF
Me Me
Major product I. 2.
r-0
I.
3.
3R, 6S
3R, 6R
'~
I
3.
starting ketone in the following reaction is
H HO"'>''H
Et....._.,
~~s"
Me Me 45. The product for the following sequence of
MaJor product reactions is
I.
3.
3R, 6S
3R. 6R
2.
4.
3S,6S
3S. 6R 6 0 1 BrCH 20MefP(OEt)31DME
2. NaHIDMF
3. H3o+
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I. 2.
3. CHO 4.
6 COOH 2. COOH
~ ~
46.
' ~ ~
47 . The major product of the following reaction
is
I. 2.
2. COOH
3. 4.
~
~
46. The major product formed in the following
reaction is 48.
~r j
Br' Q ~
I
I. 2. : : ,. . s
3. Br 4.
Br~
I ~
0}-sr : : ,. .
Br
s
3. 4.
48. The major product of the following reaction is
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cQ-ar I -,
~
Br
s 1. ,;0
-~
2. 0~0
l_j
r o
49. filk1~flliC1 1TcmT-{1'814filCfl ~ q;r* 4.
~ t~ 3. 0 ~0,
'3('tiT?;
1\-o I
~
Me~''Me_v_a_p-'-'~-~-r-p-ha_s_e.,
0
Me~''Me vap~~r
fragmentation sequence is
phase
Dethy phthalate Fl. F2. + co
0 (M, 222) (177)
__(p -,.,
I. 2. o-'>=o
.... -..../
=>-. The ratio of the relative intensities of the
carbon signals in the first order uc NMR
.J-O spectrum of CDJCI is
/
l. 1:4:6:4:1
3. ...- 0 4. ~o.. ' 2
..,
I :3:3: I
)=:O I .). 1:6:15:20:15:6:1
~.J 0 4. I :3:6:7:6:3:1
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2 tla<'l'f~q, ~
55. Bond lengths of hornonuclear diatomic
3. ihWH'l f.A<t> ~ molecules can be determined with the help of
4. ~;)fACfl ~ both
l. rotational and vibrational spectroscopy.
53. The biosynthet ic prl!cursor of abietic acid is 2. rotational and rotational Raman spectrosco py.
I. shikimic acid 3. rotational Raman and electronic spectrosco py.
2 mevalonic acid 4. vibrational and electronic spectrosco py.
3. chorismic acid
4 cinnamic ac1d 56. 'fft ~ o=qCf<'i'll1 e;~4{Jii01Cf i 3fC1T c);- ~
" .. .:> .:J
~ ~ ~ CfiT ~ 3m c);-
54. ~ ftcr crftm ~ c);- ~ JT"FN QCCh' ~ 'HiliG'IIcr(i{ ~ ~F ~ t. err ~-~
COOH ~~mrrt
H2N~ : 2. ~ Pntrr Q ~~
3. ~ Qntrr R~~
O 'Ph
4. ~ P, Qntrr R ~~
H,N~~;COOMe
57. ~ m CfiT 'Q'Cfl' CfiUT
55. 'H J'IG'I'~~Cf~ l1 e;' ~ q{ill o~Icti JiUT3tT ~ .3mfO=tT 57. For a particle of mass m confined in a box of
~
length L, assume 6x = L. Assume further that
~<R~~~~~~ 1
6p(min) = (p 2 ) h. Use the uncertainty
6. cf ~ 6 principle to obtain an estimate of the energy of
I. ~ ntrr cf;q;; 'fq<t<;l?!ct'J I the particle. The value will be
" h 2 /(8mf2 )
2. ~ nm ~ {"1101 t=q~l?!ct'li I. h 2 /(8mL2 ) 2
2
3. h /(32mL ) 2
4. h 2 /(2mL2 )
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58. 59. For the cell reaction,
Sn(s) + Sn4+ (aq) .= 2 Sn + (aq),
2
Sp~
58. H H
I I I I
H2+-s - S-==~ s- s -
~ 61@,1\?1411 <fiT ~ (p) ~ t m61$$,91411
~ G*t ~ em Jhr <H'II41141cfl t ..)
2
I. p ~' 2. p iiil
h ~I
1 3
3. p h iiil 4. p
59. ~ ~ Sn(s) + Sn4 ... (aq) ~ 2 Sn 2 +(aq) If the pressure of H2 (p) is small, the fraction of
the surface covered by hydrogen is proportion al
~ ~ ~ $<'lif?)s ~3!T ~ zsc
'R 3ftrci $<'1Cf?)s ftmcr ~ ~ ~ ~
~~~~~
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18
61. For n process in a closed system, temperature 64. X-~ ~ckAG1 ~ ~ q;)f 'ti<=tt"1k<ACfi
is cqunl to
~~~~.~~
I. ('Ill)s
i)p
2. -(:~)T I. ~<mf
2. ~oW'
3. (:~)r 4. (iJ/1)
/JS p
3. ~oW'
4. 31Rhfei>fFt1 oW'
62. F.'ik1rnffil<1 if ~ .1~ ~ f(x,y) <iiT 64. X-ray diffraction does not give any structural
~ 3fC1CiiN ~ information for
I. xdy 2. dx-=-dy 1. metallic solids
y 2. ionic solids
3. ydx- xdy 4. l
-dx X
--dy 3. molecular solids
y y2
4. amorphous solids
62. The exact differential df of a state function 65. ~A+ 8 + C-+ D~ Rh<4i~IV <iiT
j(x,y), among the following, is
~ Cfit ~. ~ ~
I. xdy 2. dx- :.dy A+ B ~ AB
y
1 X AB + C-+ D
3. ydx- :xdy 4. -dx
y
--dy
y2
~ ~ tiG 3{TCf1'lfcfi ~ ~ ~ ~ ~
63. ~ mf.rT ~ Lz
~ ~ <iiT ~ ~ exp[iA0]1 ~ ~
= -ih : 0 cii ~ ~~ ~ ~
lrtt ~("cfl q~aAct01 *
AH ~ ~ Gfclt1~'4 ~ ~ <Hfsh<QUi ~
~ ~ '(!"q; ~ QlWT 314~arn(1 ~ ~. E0 ~ ciT ~ ~ ~ <Hfsh<Qvl ~ Cii'r
~~q;'r~~~Aciimtf ~~.~~
;:m:r ~ l. Eo 2. E0 -AH
3. E0 + AH 4. E0 + 2AH
I.
0--1 3 5 A+ B ~ AB
4. , 2, 2, -2 , ...
AB + C-+ D
63. The angular momentum operator Lz = -ih : has in which first step remains essentially in
0 equilibrium. If llH is the enthalpy change for
eigenfunctions of the fonn exp[iA0]. The the first reaction and Eo is the activation ener~:,ry
condition that a full rotation leaves such an for the second reaction, the activation energy of
eigenfuction unchanged is satisfied for all the the overall reaction will be given by
values of A I. E0 2. E0 - AH
1 2 4
I. O, 3. 3. 1, 3 .... 3. E0 + AH 4. E0 + 2AH
2. 0, 1, 2, 3, ... $~Cf~I01 .311v.r ~ ~
66. '(!"q; .toft ~ oi7r
1 3
3. 0 -2' 1+-
- 2'
... ~ (A nrn ;f) ~ tovr 24 ~ A~ 30 ~ I
1 3 5 3{1'<Q;i ~ ~ ~ q;r ;:m:r f.;mci;
4. 0---
2, 2. 2 , ...
~. ~ ~ = 1.6 ev)
1019
f.'i<fiC:(1A (1 J
5155 CSI/14-1AH-2B
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19
l. 32 eV 2. 42 eV
69. 'Q'Cfi~~~~~~
3. 52 eV 4. 62 eV
4{1'fHUt!1lc1'l ~ ~I
66. Wavelength (..:t in run) of the Lyman senes I. 3ffi'-3fRic:r ~ 3m'
for an one-electron ron is in the range
24 s; A. s; 30 . The ionization energy of the
2. mr- JtR:rc:r ~ 3m'
3. ~ 3m' 3tT'ffi:r ~ ~
ion will be closest to (1 J = 1019
1.6
ev) 3fTfU'qq; ::rl"{
(iUT
number average molar mass and (Mw) for the 3. 5.6 4. 9.6
weight average molar mass. The variance of
Mn will then be 70. 10 ml of0.02 M NaOH is added to 10 ml of
I. 39 2. 3 0.02 M acetic acid (pKa = 4.75). The pH of
3. I 4 87 the solution will be closest to
1. 7.0 2. 8.4
68. VCfi Q.-1511$A-~ ~ ~ ~ ~ OllT 3. 5.6 4. 9.6
v
(S;o ~ m.:<:T ~ <nT ~ 40 S ~ 'llfa'
~*r~Z.Sf.I.M JmT ~ I PART ' C '
~m~~
I. 40 Lmol- 1 s- 1 11. mkfrn ~(i ~ ~ ~ ~ Cf)T"(C11' ~ fa1m:r ~
2. 10-4 Lmol- 1s- 1 ~tnml
3. 107 Lmol- 1s- 1
104 Lmol- 1 s- 1
A. mt-<n=r ~ .114a~li1iCfl * q~a~li1
4. B.~~ ~ C\Cij\Cf>{UI ~ fa~IS11i1
c.~ croff ~~r
68. For an enzyme-substrate reaction, a plot D.~ *t qtT ~
1
between .!. and -[ yields a slope of 40 s. If the
v s10 1. A. B OllT C 2. B,C'CI'mD
enzyme concentration is 2.5 JiM, then the 3. A, C CltrrD 4. A, B (1tlT D
catalytic efficiency of the enzyme is
I. 40 Lmol- 1 s- 1
71. Which ofthe following will result in deviation
2. 10-4 Lmol-1 s- 1 from Beer's law:
A. Change in refractive index of medium.
3. 10 7 Lmol- 1 s- 1 B. Dissociation of analyte on dilution.
4. 104 Lmol- 1 s-:
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20
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21
3. 1-(f);Il-(b);lll-( c);rv-(a)
~ ~ffi:rr t1 [(rl-CGH6)Cr(C0)3] ~ 1
J-I NMR
4. 1-(e); II -(d); III -(c); IV -(a)
~ (ppm) Jl C6 H6 ~ cfrr ~
77. Na[{tl-CsH 5)Fe(CO)z] ~ Br2 ~ ~ A 'ii'RillfilCfl ~ 3tk :mCfiT qiRUJ' (~ ~) ~/6
~ ~ I LiAIH4 ~ A cfrr ~ B ?;cfr ~I 1. 4.5 ; m;m ~ q;r m-r ~-mr
" B~~NMR~#l~~~ 2 9.0; ~ IJ:l-TTCf
~~~~CJ;T3~5:1 ~I 3. 7.2
4. 2.5; ~ ~ <1m 'Cf(iflf ~ Wr
~A~B~~T:
Cf;T~
I. (11 5CsHs)Fe(CO)zBr ~
(r/- CsHs)Fe(COhH 79. 1
H NMR spectrum of free benzene shows a
2 (rl-CsHs)Fe(C0)2Brl ntrr peak at - 7.2 ppm. The expected chemical
(r,C- CsHs)Fe(CO)zHBr shift (in ppm) of C 6H 6 ligand in 1H NMR
3. (tT-CsHs)Fe(COhBr~ spectrum of [( 176-C6H6)Cr(CO)~) and the
(r/- CsHs)Fe(COh(H)2 reason for it, if any. is/ are
1. 4.5 ; disruption of ring current
4. (tf-CsHs)Fe(CO)zBr~
2 9.0; inductive effect
(,f- CsHs)Fe(CO)zHBr 3. 7.2
4. 2.5; combination of inductive effect
77. Na[(rf-CsHs)Fe(C0) 2] reacts with Br2 to and disruption of ring current
give A. Reaction of A with LiAI~ results in
B. The proton NMR spectrum of B consists
80. [Mn(H20)6f ~ CJ;T td'f ~ ~ 'R
of two singlets of relative intensity 5: I. ~
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22
82. st$ti1Prl<'!sl$<tt4)'<1f~~01 <frr \MI' ~ 1:2 1ffi:rr 83. According to Wade's rule, anion C2B9H12- adopts
act ~ ~
1. closo - structure
3r._f1<i ;j' ~ 3(=q1G A
2 nido - structure
l00C ~ 3lfl)q; nTQ' l:R 1TR ~ l:R '(fcf; 3. arachno - structure
~ 3l'1laT ~ 3(=q1G B ~ ~ I A (ftlT 4. hypho- structure
B~~r:
84. [Cp*2ThHl (ftlT co<frr lmTi1' 1ffi:rr ~ 'R
~ q;y ~ 3"fti1G ~
1.
Cp*2Th--0
2 "'cn2--Thcpl
2.
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23
~ ~ I
#T
2
B. SN 1ca Psfi:a1faR.r CfiT ~ [CoCI(NH3) 5] +
~ 'ft!ISt'\Cfi{OI ~ft
2.
Cp*zTh--0~--ThCpl
l. A<imB 2. A <'fmC
.., A <'fm D
.). ~B 4.
4. 3fTli01 ~ Sflh'lc.'IJ.lcfi'J ~I
87. ~ (X) ~ .31J"I)fil41 ~ ~ 1Tcfi
85. Hinder ed /3- diketon ates like dpmH (dpmH = Gfi<)~l$~1$5 CfiT m (Y)
11
~ Y ~ 8 a-m
dipival oylmet hane) arc used for the separat ion NMR ~if? A it 1Tcfi f:tcfi rim thrci; ~ ~I
of lanthanides becaus e comple xes formed with
dpmH can be separat ed by ~X 6'
I. Gel pennea tion chroma tograph )
2 Gas chroma tograph y
3. Gel filtration chroma tograph y ia to
87. A borane (X) is reacted with ammon
4. Ion exchan ge chroma tograph y dride (Y). The
11
8 NMR
give a salt of borohy
spectru m of Y consist s of a triplet and a
cr;r ~ ~~ ~ ~
86. [CoCI(NH 3) 5 )
2
+
~ - quintet . The borane X is
~ *t ~ ~. ~ [Co(CN )6f CfiT I. B 2H6 2. B,H9
3. B4Hs 4. BsH9
~ ~ ctr I M" cf; ft:Rr G\ ~ ~ ~
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24
88. XefG nm NaN 03 cfi'r W1Tii1 ~ 1l'T'IT.3it cfrr 91 . [CrCl6] 3- ~ ~ ~ (J..ls) (1t1T ~ +
onfr~~..:)~~tl J~ (J..lS+L) i_!fkl li ~ ~ 'RfGl t
I. Xe0F4, NaF Ci'tiT N02F I. 3.87 BM 'C1'tiT 5.20 BM
2 Xe0 2F2, NaF, NOF Ci'tiT F2 2 2.84 BM Citrr 5.20 BM
3. XcOF., NaN02 Cim F2 3. 3.87 BM Citrr 6.34 BM
4. XeF., NaN02 Ci'tiT F20 4. 2.84 BM Citrr 6.34 BM
88. The main produc ts of the reaction of 91. The spin-on ly (~s) and spin plus orbital
equimo lar quantit ies ofXeF6 with NaN0 are (J.Ls+L) magne tic momen ts of [CrCI6 ) 3- are
3
I. XeOF4, NaF and N0 2F I. 3.87 BM and 5.20 BM
2 Xe02F2, NaF, NOF and F2 2 2.84 BM and 5.20 BM
3. XeOF4, NaN02 and F2 3. 3.87 BM and 6.34 BM
4. XeF4, NaN0 2 and F20 4. 2.84 BM and 6.34 BM
89. The spin-on ly magne tic momen t and the 92. Compl exes HM(C O)s and [(775-csHs) M'(CO )Jh
spectro scopic ground state term symbol of obey-th e 18...electron rule. Identify M and M' and
manga nese centre in [MnF6]3- ion respect ively, their 1H NMR chemicaLshifts relative to TMS.
are 1. M=M n,-7 .5 ; M'=C r, 4.10
l. 4.9 BM and 5D 2 M = Cr, 4.10; M ' =Mn, -7.5
2 4.9 BM and 4 F 3. M=V, -7.5; M'=Cr,4. 10
3. 3.9 BM and 3D 4. M = Mn, 10.22; M' =Fe, 2.80
4. 4.9 BM and 3F
93 . I2-Sfil'3Vf-4 ~M1ft:I~C1 SfW1 it m me;
90. <:itf7rcf> [Co(Co(NHJMOHh)JJBr6 *t ftt3.rn:rrR'r .3mfa'IT ~ ~ CR'ffi ~
.:>
~* Lt>>Na+>K+>es~ <liRUT
I. ~Co-OO'miifJWCo-N ~~
1. ~ CflT ~ 3ffCfiR' ~
2 ~ Co-O ntrr ~ Co-N ~~ 2. ~ q~a~01 q;r tl011<+tCfl ~ ~
3. ~ Co-O O'm~Co-N ~~ 3. snT3Gi ~ CflT ~ <'lifl (>llq01 ~
4. ~Co-O O'm ~ Co-N 3mrrtr ~
4. snT3Gi ~ *" ~ ~
90. The three dimens ional structu re of compo und 93. 12-Cro wn-4 binds with the alkali metal ions
[Co(Co(NH3)4(0H)z)3)Br6 has in the followi ng order:
1. twelve Co-O and twelve Co-N bonds Li+ >> Na+> K+> Cs+. It is due to the
2 ten Co-O and ten Co-N bonds 1. right size of cation
3. fourteen Co-O and ten Co-N bonds 2. change in entropy being positive
4. twelve Co-O and ten Co-N bonds .3. conform ational flexibil ity of crown ether
4. hydrop hobicit y of crown ether
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25
4.
s
1.
. ~
:' .2(1 \
E
E
3. 2.
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26
s~
. . . ~/~<: '.,.\. . - .
====i :'
96.
E ', : ;: 'e::::;:: t
HOOC ' ( "COOH 1. Me2C(0Me)2, TsOH (cat)
.\ t~.:i.::( 2. BH3, THF
OH
' -: ~\!!u\11:::':.>---- 3.H3o
.
0~ 0~
/
. .--ft_:i'.,.
1. 2.
OH bH
4.
3.
OD
Hd.
4. 0~
HO
I. 0~ 2. O D
OH ':-OH
A~ D. a-nt<:r ~ tm_prr
C. crnT-~ D. ifi11 3n'fUacfi 31R' ~ qCGI$m
2. B ('!"tiT C
9H 0 0
4. A ('!"tiT D
Ph~w-~
l.
MeL P
Me.,..\
95. Gel permeation chromatography can be used to 2.
Ph
separate which of the following
OH 0 O
A. Lanthanides B. Alkaline earths Ph~N-'<
C . Fatty acids D. Low molecular weight Me L P
3. Me.,.. \ 4.
peptides Ph
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27
0
97. . product formed
The maJor in the following
transfonnation is
0 0 I. MeO
J::b>
~N_/( 1 au.,BOTi, i-Pr2NEt >
Me~~ 0~
2. PhCHO
3.
OH 0 0 OH 0 0 0
)_J~tr J(0 )..__Jl_ l{
l -~ 0
Ph ~ . Ph'
f.~r. /---( Me~ 99. . prod uc t of the foliowing reaction is
The maJOi
(.
Me Ph 2. Me Ph
3. 4.
98. 0
I. f!.eO
en>
Q""NMe2 ONMe2
3. ot::Q 0
3. 4.
NMe2 NMe2
100. fi!Mfc:lfi!r.r ~~ <nT ~~~I
s
12 (1 equ1v)
0
I#~,;___ A
hcxnne, rt.
excess MezNH ... o
2. NaOH
!. 2.
(_)"r~Mez
J. 4. 'iJMa 2
2.
Me
99.
H~
ax
Me \_NH
4.
F!
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28
100. The major product of the following reaction is
Fl
MeN Me
LOA
H 1. H 3o, hv PdC!,. 0 2 , I . NaOEI
~Dr A CUCI, OMFH,O B 2. H,O
2. NaOH
H l. A; 0 B: 0
M(\ Me ~ 6l f
cff elf e 2
AH(J B 0
I.
H
2
H
'H
cYY
(t '
3 A: 0
Me
6r
e
4.
~" ~
3. H - H
H
4. A; OH B. 0
Meo-""'y ')'''~-b~~Ph
0
102. The products A and Din the following reaction
Meo'' V sequence are
OPh
I
o ::::P\OPh
N--
! 0 ~
A PdC!,, 0,
Cuel, OMF-H,O
B 1 NeOEI
2. H,O (O=o
Meo: : t J
I. MeO'''
''68
Mco" 'y ') ...., l. A: 0
.oV'" NI
~
0
Meo"" 'y ')"';NH MeO
3. MeO',..l,__)..,,o ' ,,0
4. f'- OPh
PhO 2.
H~
A; B. 0
101. The major product for the following reaction is
~
B:
MeO''..
4. A: OH B: 0
Meo ::tJ
HN~
f o' ~ ~CHO
2. Meo
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29
I. A: B:
P Pl'h1 *'d EtO,CN =NCO,Et
B 0 0
4. A.
~OH
B: A. Ta.........._N,CH0 . - . Tt..-....NC
H
B. 0 o
0 0
~H,
Q-coct
l. B: H2 N~""cooH ~I.:..:M;:.:e~
3S::::iC::::I:..::M::::e:::O.:..:H_, A 8
OH 2. Et3 N, heat Pyridine
BockHN
OH
;/
A
0
SiMe3
2. A: a BocHN
~pH A.
3. A: 8:
3 A
0 ~ HN"'y]
B
4. A: e
~OH OY''NH,
0
0
105. The products A and B in the following reaction
sequence are
104. ~JtT (Reactions) 3tR' ~
(Reagents)~~~ t ~H,
1 Me,SICl. MeOH
r\~coct
H 2 N~COOH A ~ -... B
OH 2. Et,N heat Pyndino
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30
I A
0
'"ft(J (1 "?.
.- ' ( ' " ( NH
107.
0 .J'oH
. . .a.
t>o
2 A
0 e 0
"""(:7 p
Oil
oCo
l A
""'""('~ D
""'y
O
0
NH1
O "NH-c-o (I
0
""'y
4
" 0 0
O
0
'~NhJ
0 CHNl ? uo .... ~, 2.
NC~
0
\I IS
Eto~e
I. NC EtOOC . N- R NC CN
2.
N-R >=<
NC CN
.....
0 0 heat
~
II
J. EtOOC
N
wR
e
4. EtOOC
NYB Me wR
Me2N~CN
I.
106. The major product of the following reaction is
MeD
0 CNH 2. Mc 2N~NMe2
CN
Mo,N-~~N
N
I
R
3. H20. OH. 3.
4.H NC
~0
0
eto~ N
EtOO
4.
I. NC
2. N- R
N-R
108.
0 0
~ _____ ..
II
N~
1 T&.F. MtCN. 50"c Heal
A B
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31
O" El 0
h 109. f:iMI?I~Ci ~ sm1 ;;- 3c-4~ ~
PhS
~~j ~
_.t
r-h
C(p'El ~~
lJ-r:'= 1 EtCOCI. Et 2N
c)-rOMOM ______
A CO,Me a: co,Me OH 2. LOA, THF, -78 C, TMSCI
.,..
E);-~?.,..N
3. 1\
4. 1-130+
/ SPh 0
2 A B
0:" co~
'
5. CH2N2
OCOEt
r sl'll ~OMOM
cc~
; Et
1' 2. ( ).._., OH
TMS 0 0
~
r SPII
3 HOOC~d -4. Mooo cJ-o'
Me
~
Me
~
1. EtCOCI, Et3N
OH 2. LOA, THF -78 C TMSCI
108. The products A and Bin the following reaction
sequence are c)-rOMOM 3.6
~=N ''SPII
I TBAF MeCH , SO"C
OCOEt
Nh 9i1Ao
A 0 ~OM
~ OM
1.
'
CO,Mo ' 2 EtOA_0~et
0 0
TMS O
2 lYOH
0
0
N Et
/YOMOM J~OMOtA
1 A
PhS '-N
~ c:~.
.11.
B.
;b.
cr~
~.
Et
3 HOOC
Me
4. MeOOC
~
Mt>
0
"et.r..
110. f:iMI?I~Ci ~ ~ '# A C1'm D ~
PIISCB:~a 6.
2 A:
.~
N
CO,Mt B
~
~
I
ti:tilCiil<l
OH
~l:
Cl v lh
~
12 PPh, . Br
r SPII PhS) mdazole CN
lw-'
3 A
~
MoOOC' 0 El
Be
&0 'II
N
CQzMo
I
Boc
A
Zn. Pd(dppi)CI2 (cat)
Cul(cat)
NC
[l
~
PhS)
~
CN
MoOOC
N ,
..
Et
cxO
- ; N Co,Et Boc-NJ - 1 Boc- NJ-- -6--B r
A EtO,C e C:~. 2
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32
CI- Q -NJ-OH
HN~- OH 1. DIBALH (1.1 equlv), hexane -78 C
3. ~ CN
Mev+{_
Me~Me 2. CICH2 COOH, dlethyl azodlcarboxylate
PPh3
H Me 3. LIAIH4
Br--p-NJ -OH
HN~ OH
4. ~ NC
H CH H .QH
110. In the following reaction sequence, the structures Mev+->- Me Me~ Me
of A and Bare, respectively, Me~ Me' '--1:-f
CI'Ql
1. . H Me 2. R Me
H
lob
Br
c5 I
Boc
A CN
Boc-NQ-1 Bec-NJ-d-Br
;:n;IT (values) <ill' ~ ~ ~
2.
Entry Reaction Entry p
CI-Q-NJ-OH
value
HNo-OH p
3. CN A ArNH 2 + PhCCCI in +2.01
benzene
Br--p-NJ-OH B ArC - + Etl in EtOH Q -0.99
4.
HNo-OH
NC
c ArCC 2Et + aq NaOH R -2.69
in EtCH
s +0.78
Me~ Me Me~Me
value
A ArNH2 + PhCCCI p +2.01
Me~ Me/ '--1:-f in benzene
1. H Me 2. R Me . B ArO-+ Eti in Q -0.99
EtCH
M
ti
-
PH
.
H CH c ArCC2Et+ aq
NaCH in EtOH
R -2.69
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33
~or,
0
I. Free radical and 4-iodomethyloxepan-2-one
2 Free radical and 5-iodooxacan-2-one
3. Carbene and 3-oxabicyclo[5.l.O]octane-2-one
II 4. Carbene and (E)-5-iodopent-3-en-1-yl acetate
Me
2 PMBO~
Me
'
OMe
~
3.~
X 4. ~
0 0
Me Me
m."li'CRff' (11IT ~~
OPMB OH
1 Ho~
Me
2- PMao.-. . . . . .-\~
Me
OMe OMe
1.
2
1f<f(1'
~
2-ffivf
1f<f(1'
~
~ ~ 4-~311Cffi'I~01-
"
~ ~ 5-.3inrn)'311Cfflili>01-2-3ffrr
"
3
9
a ' o
l__.. 1 --./""-...-:? 4 .~
2.
? ''jl ~,..
~1e Me
S/55 CSI/14-1AH-3
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34
116. 3fOj ~ C1oH1202 qi'f' Cfii4f':ict; ~
Prikl~lll<'1 :Flct?(A'l ~ ~~ *' M H
V---(0 -
X
BO,Ph
~0 ~
Soy>h
o:1'-C00Et
lR: 3400 (br), 1600 em.
1H NMR:
o
1.85 (3H, d, J 6 Hz), 3.8 (3H, s), 0 0 0
5.0 (1H, s, ~0 far!All'), 6.0 (1H, dq, J = 18, 6 1. X= PhS02H, BF 30Et2 andY = CH =CHC00Et, BF 0Et
2 3 2
Hz), 6.28 ( IH, d, J 18Hz), 6.75 ( IH, d, J = 8
Hz), 6.8 (1H, s), 6.90 (1H, d, J = 8Hz) ppm; 2 X = 1. PhSH, PTSA; 2. m-CPBA and Y =CH2=CHCOOEt. BF3 0El2
13
C NMR: o 146.5, 144.0, 131.0, 130.5, 123.0,
119.0, 114.0, 108.0, 55.0, 18.0 ppm.
~~~t' 4. X:: 1. PhSH, PTSA; 2. m-CPBA andY = LOA, CH2=CHCOOEI
3.
QCM' 2. X =1. PhSH, PTSA; 2. mCPBA andY o: CH2~CHCOOEt BF3 OEt2
OMe 4.
Me~O
123.0, 119.0, 114.0, 108.0, 55.0, l8.0ppm .
The structure of the compoun d is 1. 2.
~ Me
1.
Hoy
OMe
2.
HO~Me
OMe
3. Me
ft 0 0 4. Br ~ ONa
3. OMe 4.
Br~., Br
2. PhSeNa
3. m-CPBA, heat
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35
2.~0
1. LOA, THF 1. M-..gBr. Et20
B
2. ICH2CH2CH2Cl 2.H,o
Me 0
4.Br~ONa 1. A: eX:
I~
0
c1~
0
I
Ta
3. A: ~OEt B: ~
1. 0?3 I
Ts
2.
-4. A:
3.
dYH d9H Ts
I
4. I
Ts
following reaction sequence are
1. LOA, THF
A B
~era
0
~CHO
~N~ I
T1
1. CH3NHCH~OH, Et3N, DMF
2.1tellt
1. A: eX:
I~
0
1. C8 I
Ts
2.
2.
3.
A:
A:
Cl~
l__)l_OEt
l_)lOEt
B:
B:
c1~
~OEt
Me
0
4.
d9H
N
I
Ts
-4. A: B: C6.. OEI
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36
1. r112 2. r -1/2
3. r-s/2 4. r-7/2
k.t 1.
k2 2.
A* p
3.
~ 4Jif tft ~ ~ ~ ft:nr ~ ~ 4.
CfiT a\ Frill<'1iCfl koo t1 ~ ~ CfiT a\
123. The low and high temperature limits of
PrillC1iCfl k;' m- ~ t "aiif A CfiT GT6T [A] 1;z
vibrational partition function are (0 = hv/k )
~t" l. e-8/T and ie-8/T
2. e-8/2T and ie-8/ZT
3. e-8/ZT and ie-8/T
4. e-8/2T and ~e-8/ZT
l. 0 2. I
For this Teaction, the first order rate constant at 3. L/2 4. 2/L
high pressure is k 00 Thefrrst orderTate constant
becomes k;'
when pressure of A is [A] 1; 2 . ~: J;: f(x)o(x- a)dx = f(a)]
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37
~ 3UT <f;tr.:r ~
.. .:;,
*~ t .:J
S/55 CSI/14-1AH-4A
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38
S/55 CSII14-1AH-4B
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39
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40
~~*tmrcr~~
tmiT (~ ~: ~ j *t 3mlii>G(11 BJ)
I. 1 2. g~
I. 16 2. 12
3. 8 4. 6
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p p
143. 311"i1&41
p
~ ~ ~ ~4ctiif1 m- fi1r;; ~
~~. 0.01 M ~ 0.04 M ~ ~ ~ ~~ M4AIII1 ~~41Gf~~
~c;t4"i, "A" 1 1ro ~ ~I ~log :o.o = 0.3 ctt qRac%111 q;r ~ 'QCfi Gf (=fliT ~
0.01
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