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FIXED PROSTHODONTICS l OPERATIVE DENTISTRY

SECTION EDITORS

GORDON J, CHRISTENSEN SAMUEL E. GUYER


WILLIAM LEFKOWITZ WILLIAM F. P. MALONE ROBERT C. SPROULL

A classification and evaluation of composite


resin systems
Felix Lutz, D.M.D., M.D., Ph.D.,* and Ralph W. Phillips, M.S., D.Sc.**
Indiana University, School of Dentistry, Indianapolis, Ind.

C omposite resins are subject to wear under oral


conditions and, in time, undergo other physical and
The organic phase
There is now evidence to substantiate that the degree
chemical alterations. Posterior stress-bearing restora- of polymerization is crucial to the clinical performance
tions ,produce fatigue and adhesion types of wear, later of any resin system. The conversion percent of double
enhanced by chemical disintegration. This produces an bonds and the network formation, and thus the degree
unacceptable loss of substance that, to date, has pre- of polymerization, are affected by two major factors:
vented their use as a substitute for dental amalgam. In (1) the mode of curing used and (2) the type of resin
anterior restorations the esthetic appearance of a com- used in the organic matrix.2
posite resin may also change because of abrasion and An increasing degree of polymerization is achieved
chemical disintegration, altering color and surface generally in the order of chemical cure - light
texture.p2 cure - heat cure. For this reason the curing mode may
Recently a direct correlation has been demonstrated present one means of classifying composite resins.3,4
between changes induced by wear as related to both the The most commonly used components in the organic
components of the composite resin and the type of resin matrix are BIS-GMA, modified BIS-GMAs,
curing system.2 Thus, these appear to offer a scientific urethane diacrylates, TEG-DMA, and a number of
basis for the classification of composite resins from diluents.5-9 With chemically cured materials, the differ-
which conclusions may be drawn on the respective ences in the degree of polymerization resulting from
clinical performance of a given system based on its varying compositions of the organic matrix are in turn
classification category. This article presents such clas- reflected in the in vivo wear data derived from the
sifications based on the current state of the art. In occlusal contact areas ofmesial-occlusal-distal restora-
addition, the advantages and disadvantages of the tions as well as in in vitro wear rates from fresh and
currently available composite resins for anterior resto- aged composite resin specimens.* However, these dif-
rations will be delineated. Hopefully, guidelines will be ferences in wear performance were not seen either in
provided for dentists in the selection and use of contact-free occlusal areas or with anterior restora-
commercial products. tions. Thus, a classification of anterior composite resin
systems based on the compositions of their organic
COMPONENTS matrices does not appear to be an accurate mode.
Resin-based restorative materials are defined as
three-dimensional combinations of at least two chemi- The interfacial phase
cally different materials with a distinct interface.3 Bipolar molecules, mainly organosilanes, are usually
Generally, a composite resin encompasses three phases: used as coupling agents to connect the inorganic fillers
(1) the organic phase (the matrix); (2) the interfacial and the organic matrix. With prepolymerized partially
phase (the coupling agents); and (3) the dispersed organic filler particles, the bond is polymeric in
phase (the fillers). Each phase has the potential to nature.0-2 Both these types of agents, and all current
provide a basis for a classification. The respective versions of interface adhesion, are equally sensitive to
suitability of each for this purpose will be analyzed. chemical disintegration. Hence, using coupling agents
as a basis for classification does not seem to be an
appropriate mechanism.* 3I3

The dispersed phase


*Visiting Associate Professor of Dental Materials from the Univer-
sity of Zurich. Under oral conditions the interfacial bonds deterio-
**Associate Dean for Research. rate in time to reveal the dispersed phase. In current

480 OCTOBER 1983 VOLUME 50 NUMBER 4


COMPOSITE RESIN SYSTEMS

composite resin constructions, these exposed fillers MACRC!+lLLERS - MICROFILLERS - COMPLEXES: AVERAGE SIZE f AS I I SIZE DlSTRlRTlON , SD b

demonstrate distinct differences in properties. There-


fore, they may provide a basis for establishing a 1 nl * IO-6 In

,I 1-h
workable classification. Hence, the various types of A5: 2 8 I
MICROFILLERS .-I j 5ax
fillers will be discussed in some detail. so 0.1 - IW I

Based on the manufacturing technique, the average


AS: 0.04 I i
size (Fig. l), and the chemical composition of the filler MICROFILLERS 7;; ;
so 0.03 - 0.8 *
particles, three categories can be characterized: (1) ,I :

traditional macrofillers, (2) microfillers (pyrogenic sili-


ca), and (3) microfiller-based complexes.
Traditional macrofillers. Traditional macrofillers
are mechanically prepared from larger pieces of the COMPLEXES: k ,,
15 - 103x
I
material by grinding and/or crushing. The particles SD: 1 - ,sOiXXI

are purely inorganic; usually splinter shaped; and are Fig. 1. Dispersed phase illustrating average size and
quartz, glass, borosilicate, or a ceramic. Heavy metal size distribution of inorganic fillers and microfiller-
glasses that provide adequate radiopacity are available. based complexes as well as lower and upper limit of
The ground chips fall into a size range of from 0.1 to wavelength of visible light. Arrows identify smallest
100 pm. The lower limit of the size distribution is particle size of each type.
established by the manufacturing method. At present
no mills provide particles smaller than 0.1 pm. On the
other hand, inorganic fillers larger than 100 pm would
present a diversity that would be highly visible if used
in a composite resin system.
In recent years there haI; been a definite trend to
smaller, softer, and more rounded macrofillers, with
mathematically calculated size distributions available.
I 1
With modern composite resin constructions containing 1 HOMCGENEWS
CCMpOSITf
MICROFILLED
RESIN I

this type of fille.r, the average particle size is generally


reduced from the original range of 5 to 30 pm to 1 to
5 pm.7*4
Microfillers. Microfillers are derived chemically by Fig. 2. Composite resin classification (right column)
w HETERWENWS
COMPOSITE
MICROFILLED
RESIN
I

hydrolysis and precipitation and consist of very finely based on types of fillers (left column) they contain.
dispersed radiolucent glass spheres.* Originally, the Figure depicts construction of respective classes.
commonly used primary particles generally had an
average size of 0.04 km (Fig. 1).7,o,1,5,6 Recently, a inorganic loading. with microfillers. There are three
tendency to use larger average particle sizes, approxi- different types: (1) splintered prepolymerized micro-
mately 0.05 to 0.1 pm, has become apparent. filled complexes, (2) spherical polymer-based micro-
Pyrogenic silica has a strong thickening effect if filled complexes, and (3) agglomerated microfiller
added directly to a liquid mixture. This effect on complexes.0-12~
viscosity of the paste has to date limited heavy inorgan- Splintered prepolymerized microjlled complexes.
ic loading of a resin matrix with microfillers. Such a These are made by incorporating pyrogenic silica into a
mix becomes extremely viscous and difficult to manip- resin matrix and then heat-curing the mixture. It is
ulate. Therefore, alternative ways of admixing micro- then milled into particles that cover a rather large
fillers to an organic matrix were needed to increase range, from 1 to 200 pm (Fig. 1). Such particles
the filler load without jeopardizing the handling sometimes are erroneously labeled organic fillers. It is
properties. true that the matrix of the particles is organic in
Microfiller-based complexes. Microfiller-based nature, but harbored within the resin is inorganic
complexes have been developed to attain maximum silica. Consequently, they are more correctly termed
splintered prepolymerized particles., x z I6
*If the particle size ranges between 0.001 and 0.1 /.un, the dispersion Spherical polymer-based microfilled complexes.
is colloidal. Hence, only microfillers smaller than 0.1 pm (Fig. 1) These are commonly named spherical prepolymerized
can be colloidally dispersed. particles and are manufactured by incorporating pyro-

THE JOURNAL OF PROSTHETIC DENTISTRY 481


LUTZ AND PHILLIPS

genie silica into partially cured polymer spheres that Table I. Composite resins and manufacturers
have an average diameter of 20 to 30 pm. Again, a
a B-21 Bayer AG, Leverkusen,
sophisticated size distribution permits an extremely West Germany
dense Racking.2 B-23
Agglomerated microfiller complexes. Agglomerated Superfil H. J. Bosworth Co.,
microfiller complexes consist of artificially agglomer- Skokie, Ill:
ated microfillers in the range of 1 to 25 pm. In contrast b Superfil Light (VLA)
C Ful-Fil (VLA) L. D. Caulk Co., Milford,
to the above-mentioned types of complexes, these Del.
particles are purely inorganic. Prisma-Fil
Based on the present state of polymer and filler Nuva-Fil
technology, of the three phases of the composite resin, Vytol
Finesse
the composition, chemical properties, size and size
Uvio-Visio-Dispers Espe GmbH,
distribution. of the dispersed phase or filler particles Seefeld/Oberbayern,
appear to provide the best information for determining West Germany
the potential in vivo performance of a restorative d Nimetic-Dispers
composite resin. Therefore, the following classification d Visio-Dispers (VLA)
e Miradapt Johnson & Johnson, East
is focused principally on the fillers they contain.
Windsor, N:J.
CLASSIFICATION AND CLINICAL Adaptic
Answer
PERFORMANCES Aurafil
The three types of fillers previously described repre- Smile Kerr Mfg. Co., Romulus,
sent the backbone of the classification. Fig. 2 depicts Mich.
Simulate
how traditional macrofillers, microfillers, and micro- Command
filled complexes are organized into four major systems. Command Ultrafine
The schematic diagrams of each type of composite Estic Microfill Kulzer & Co., GmbH,
resin, (which will be discussed next), are shown in Friederichsdorf, West
Germany
Figs. 3 to 8, The materials and manufacturers are
g Estilux Posterior, Rx
listed in Table I. (UVLA-VLA)
g Durafill (VLA)
Traditional composite resins Smile
g
A schematic presentation of the structure of a h Clear81 Kuraray I? Co.,
traditional composite resin can be seen in Fig. 3. Kurashiki, Okayama,
Japan
Representative products of this type, the average parti- Concise 3M Co., St. Paul, Minn.
cle size of the filler, and the advantages and disadvan- P-10
tages of that system are presented in Table II. P-30 (VLA)
The differences in hardness of the two bulky phases Silar
Silux (VLA)
and the high visibility of the rather large macrofillers,
Phaseafill Phasealloy Inc., El Cajon,
which in general are larger than the wavelength of the Calif.
visible light, make it difficult to finish the resin to a k Lite (VLA)
smooth surface. Therefore, trimmed restorations soon I Profile S. S. White, Philadelphia,
become rough and prone to stain and plaque accumu- Pa.
m Isopast Vivadent AG, Schaan,
lation as hydrolysis of the interfacial bond and the fast
Liechtenstein
&ear of the organic matrix facilitate protrusion and/or m Heliosit (VLA)
dislodgment (plucking out) of the macrofillers. For that m G-2
reason, the rather poor wear properties .observed in m M-18
both stress-bearing and contact-free situations are not m Iso-Ex
surprising.8, 18,9 VLA = Visible light activated; UVLA = ultraviolet light activated.
As mentioned previously, the modern, traditional
composite resins contain smaller, more rounded, softer a higher inorganic filler load; (2) shelf life; (3) iian-
macrofillers, coupled with an appropriate size distribu- dling characteristics of the freshly mixed resin; (4)
tion. Furthermore, these fillers are frequently radi- wear resistance, particularly with single-paste light-
opaque. In this manner, several properties can be curing formulations; (5) radiopacity; and (6) a. poten-
improved: (1) packing of the organic matrix to provide tial to be finished to a smoother surface. Nonetheless,

482 OCTOBER 1983 VOLUME 50 NUMBER 4


COMPOSITE RESIN SYSTEMS

Fig. 3. Traditional composite resins. Schematic draw- Fig. 5. Homogeneous microfilled composite resins.
ing shows components: organic matrix plus traditional Schematic drawing shows components: organic matrix
macrofillers. Representative products are listed in plus microfillers. Representative products are G-2,
Table II. M-18, and Iso-Ex.

Fig. 4. Hybrid composite resins. Schematic drawing Fig. 6. Heterogeneous microfilled composite resins
shows components: organic matrix plus traditional with splintered prepolymerized particles. Schematic
macrofillers plus microfillers. Representative products drawing shows components: organic matrix plus
are listed in Table III. microfillers plus splintered prepolymerized micro-
filled complexes. Representative products are listed in
Table IV.
the improved smoothness is still only short lived as the
macrofillers become dislodged. Is,20,
composite resin plus pyrogenic silica. Hybrids still do
Hybrid composite resins not make ideal anterior restorations because of their
It is now common practice to reinforce the organic surface properties. Even if acceptable smoothness can
matrix with microfillers to reduce the differences in be achieved by means of an optimal finishing tech-
properties between the inorganic macrofillers and the nique, it is short lived because of the wear pattern
unfilled organic matrix. In addition, the microfillers inherent in a resin system that contains traditional
provide better control of the viscosity and improve wear macrofillers. Nevertheless, the surface morphology of
resistance. That technology is used even with the a hybrid composite resin is superior to that of the
leading traditi0na.l composite resins of the 197Os, such traditional type. A further improvement can be antici-
as Adaptic and Concise. Hence, the purely traditional pated with the use of even smaller macrofillers, which
types of composite resins have become rare.2,22 would have an average size of approximately 1 pm.
A typical hybrid composite resin is depicted in Fig. The basic characteristics of the currently available
4; and again, representative products, classified accord- hybrids are seen in Table III.
ing to the size of the macrofillers they contain, are Apart from the common hybrid type of composite
presented in Table III. These materials contain inor- resin, there are some rather rare constructions of this
ganic macrofillers of an optimized traditional type of kind that combine the elements present in a hybrid

THE JOURNAL OF PROSTHETIC DENTISTRY 483


LUTZ AND PHILLIPS

Fig. 7. Heterogeneous microfilled composite resins Fig. 8. Heterogeneous microfilled composite resins
with spherical prepolymerized particles. Schematic with agglomerated microfiller complexes. Schematic
drawing shows components: organic matrix plus drawing shows components: organic matrix plus
macrofillers plus spherical polymer-based mi- microfillers plus agglomerated microfiller complexes.
crofilled complexes. Representative products are Representative products are Answer, Nimetic Dis-
B-21 and B-23. persd, and Visio-Dispersd.

Table II. Traditional composite resins Table III. Hybrid composite resins
Average particle size Average particle size
(rtm) (urn)
Adaptice (1970s) Adapt2 (1980s) > 10
ClearfiP > 10 Concise (1980s)
Concise (1970s)
Aurafil
Command (VLA) Estilux Posterior, Rx+
Estilux Posterior, Rx-8 (UVLA/VLA)
(UVLAWLA) Ful-Fil (VLA) < 10
Nuva-Fil (UVLA) Miradapt
Profile < 10 P-10 >3
Simulate P-30 (VLA)
Smile Vytol

Prisma-FilC (VLA) <5 Command Ultrafine <3

UVLA = Ultraviolet light activated; VLA = visible light activated. UVLA = Ultraviolet light activated; VLA = visible light activated.
Advantages Disadvantages Advantages Disadvantages
Favorable optical properties Lack of polishability Favorable optical properties Surface morphology inferior
Favorable physical properties Surface roughness Favorable physical properties to that of microfilled
Long clinical observation period Plaque accumulation and Improved wear resistance composites
Radiopacity achievable stain in time Surface morphology superior to Increased surface roughness
that of traditional composites with time
Radiopacity achievable Short clinical observation
with microfilled complexes. Representative of this type period
are Finesse and Uvio-Visio-Dispersd. Because these
two products do not demonstrate superior properties containing inorganic fillers, which are smaller than the
when compared to their microfilled equivalents, they wavelength of visible light, visually appears homoge-
will not be discussed further. neous. Consequently, this results in a high degree of
surface polishability. In addition, even if the microfill-
Homogeneous microfilled composite resins ers are mechanically or chemically dislodged because of
Homogeneous microfilled composite resins are com- in vivo wear, the polished surface retains its enamel-
binations of an organic matrix and directly admixed like luster because the induced surface irregularities
microfillers, as shown in Fig. 5. cannot be detected optically. Second, the homogeneity
They are considered optimal with regard to at least and the extremely small particle size provide only a
two properties. First, a composite resin exclusively minimal working surface for wear plucking-out pro-

484 OCTOBER 1983 VOLUME 50 NUMBER 4


COMPOSITE RESIN SYSTEMS

cesses.This has raised expectations for superior wear Table IV. Heterogeneous microfilled
properties. composite resins with splintered
However, the inorganic loading with such small prepoiymerized particles
particles, approximately 0.04 to 0.2 pm, is still limited
Estic MicrofiW Durafillg (VLA)
because of the viscosity effect resulting from the large Isopast Heliosit (VLA)
surface area they present.16 Hence, a homogeneous Phaseafill Lite (VLA)
microfilled composite resin has not as yet been mar- Silar Silux (VLA)
keted as an anterior restorative material. Therefore, SuperfiP Superfil Lightb (VLA)
other technologies were required to incorporate the VLA = Visible light activated.
microfillers in a higher concentration without effecting Advantages Disadvantages
viscosity, as noted earlier. Polishahility Technique sensitivity
Permanent surface smoothness Radiolucent
Heterogeneous microfilled composite resins Excellent esthetics Short clinical observation
Good wear resistance period
Heterogeneous microfilled composite resins are com- Alteration in certain physical
binations of an organic matrix, directly admixed properties
microfillers, and microfiller-based complexes. Different optical properties
Heterogeneous microfilled composite resins fall into
three different subclasses: (1) those with splintered pre- strength is strong enough to resist wear in non-
polymerized particles, (2) those with spherical prepoly- stress-bearing situations, as in anterior restorations and
merized particles, and (3) those with agglomerated in contact-free occlusal areas in posterior restora-
microfiller complexes. tions.2
Heterogeneous microfiled composite resins with However, this lack of a perfect polymeric interfacial
splintered prepolymerized particles. The admixture bond is the main reason for the technique sensitivity
of splintered, prepolymerized complexes to a microfill- seen with microfilled composite resins. Improper fin-
er-reinforced organic matrix, as previously described, ishing techniques can readily cause damage. Green and
is one of three methods that are technically feasible for white stones or tungsten carbide burs, especially when
augmenting the inorganic loading and volumetric filler used dry, can fracture the prepolymerized particles and
content without further increasing the viscosity and form fissures along the interfacial surface phase. Con-
jeopardizing the handling characteristics of the com- sequently, when such restorations are incorrectly fin-
posite resin. Such a system can be labeled as a ished, they do not demonstrate the same lusterlike
heterogeneous microfilled composite resin with splint- surface finish possible when finished with kinder
ered prepolymerized particles and is shown schemati- flexible disks @of-Lex disks, grit 150, 360, 600, 1200,
cally in Fig. 6. Representative products based on this 3M Co., St. Paul, Minn.) or specially developed
type of formulation are listed in Table IV. superfine finishing diamond burs (Composhape-Set
Such a resin will be comparable in characteristics to [made by Intensiv], W. Hubschmid Sohn, Switzerland;
a homogeneous microfilled composite resin that has U.S. distributor: Teledyne, Denver, Co10.).~~
excellent polishability, a permanent surface smooth- Apart from their sensitivity to the finishing tech-
ness, excellent esthetics, and good wear resistance, nique, heterogeneous microfilled resin systems also
provided that two crucial conditions are fulfilled: (1) demand additional modifications of other clinical pro-
the concentration of the dispersed silica microfillers cedures. As they have a somewhat greater polymeriza-
must be equal in the prepolymerized particles and in tion shrinkage, they should be used in combination
the polymerizable organic matrix in order to provide a with long-beveled cavity preparations, the enamel-etch
uniform distribution throughout the composite resin technique, and bonding agents. This will safeguard an
following polymerization and (2) the bond between the excellent marginal adaptation and provide superior
reinforced organic matrix and the partially organic esthetic results.24,25Furthermore, as their optical prop-
complexes should be as str0n.g as the cohesive forces erties differ from those of traditional or hybrid compos-
within the phases. ite resins and the surface texture does not interfere with
With regard to the dispersion of the inorganic phase, the esthetic appearance of a restoration, the dentist may
current products (Table IV) are in general more or less have to relearn selection of shades.
homogeneous. However, the polymeric interfacial bond At present, the heterogeneous microfilled composite
is not adequate under certain circumstances and may resin with splintered prepolymerized particles is the
occasionally contribute to failure.16,23 The bond most common type of microfilled composite resin. The

THE JOURNAL OF PROSTHETIC DENTISTRY 485


LUTZ AND PHILLIPS

Table V. Polishability (according to five-point Heterogeneous microfilled composite resins with


rating system) agglomerated microfiller complexes. Agglomerated
Homogeneous microfilled composite resin Ic * * *
microfiller complexes are similar to traditional macro-
Heterogeneous microfilled composite resin*** fillers in size and chemistry, but not in structure.
Traditional and hybrid composite resin (< 5 Mm)*** Further, they allow a substantial increase in the
Traditional and hybrid composite resin (< IO pm)** microfiller content when admixed to a microfiller-
Traditional and hybrid composite resin (> 10 pm)* reinforced organic matrix. Such a restorative resin is
schematically depicted in Fig. 8. It can be termed a
Table VI. Permanence of surface smoothness heterogeneous m&o$lled com>osite resin with agglom-
(according to five-point rating system) erated microfiller complexes. Such a composite resin
demonstrates excellent finishing and perfect surface
Homogeneous microfilled composite resin*****
qualities. 25 Unfortunately, however, not much is
Heterogeneous microfilled composite resin****
Traditional and hybrid composite resin (< 5 Fm)*** known about the in vivo performance of that filler type
Traditional and hybrid composite resin (< 10 pm)** and consequently of these resins. Those essential clini-
Traditional and hybrid composite resin (> 10 pm) cal studies are not available.

COMPARISON OF SYSTEMS
Table VII. Esthetics (assuming use of
New materials are often troublesome, even if they
adequate technique) (according to five-point
are deemed progressive, because they may be associated
rating system)
with a reevaluation of the established techniques of use.
Homogeneous microfilled composite resin* * * * l Furthermore, there is an unavoidable time lag in
Heterogeneous microfilled composite resin* + l * establishing the precise relationship of properties to
Hybrid composite resin***
clinical performance. Thus, the introduction of micro-
Traditional composite resin*
filled resin systems has led to considerable controversy,
both from the standpoint of the dentist and within the
Table VIII. Technique sensitivity (according scientific community. However, it is possible to evalu-
to five-point rating system) ate the four main composite resins classes that have
been shown in Fig. 2 and were then described. This has
Traditional composite resin*****
Hybrid composite resin * * * been done in Tables V through IX by use of an
Homogeneous microfilled composite resin** arbitrary five-point rating system. An assignment of
Heterogeneous microfilled composite resin** one asterisk indicates the lowest rating, while five
designates the best rating in that category. The respec-
tivecomparisons cover the features iha; have clinical
Table IX. Clinical observation time (according
relevance, namely, polishability, permanence of surface
to five-point rating system)
smoothness, esthetics, technique sensitivity, and in vivo
Traditional composite resin l * * * l observation time.
Hybrid composite resin * l As the filler particle size is reduced, the polishability,
Heterogeneous microfilled composite resin***
permanence of surface smoothness, and esthetics
Homogeneous microfilled composite resin*
improve. As would be anticipated, the hybrid, and
especially the microfilled, composite resins are marked-
general advantages and disadvantages of such a system ly superior to the traditional composite resins. For that
are summarized in Table IV. reason, the original macrofilled systems are now almost
Heterogeneous microfilled composite resins with obsolete. In the same vein, the profession has hailed the
spherical prepolymerized particles. Spheres with a microfilled resins for the superior esthetic results that
specific size distribution allow dense packing. There- are possible, if an operative technique is used that
fore, the so-called heterogeneous microfilled composite incorporates the cavity design and finishing procedures
resins with spherical prepolymerized particles, sche- previously stated. Certainly, they do have a greater
matically shown in Fig. 7, can be filled to a high technique sensitivity, which in turn can influence the
volume percent, which is reflected in a reduced poly- clinical performance.
merization shrinkage. Experimental versions of that However, it is fair to note that the older macrofilled
type of composite resin have shown promising results.2 composite resins do have the edge in terms of the
However, such a heterogeneous microfilled composite clinical observation period, simply because they have
resin has not been marketed to date. been in use for a longer period of time. Therefore, a

486 OCTOBER 1983 VOLUME 50 NUMBER 4


COMPOSITE RESIN SYSTEMS

time lag does exist for the newer hybrid composite Table X. Visible light cure versus chemical cure
resins and particularly the microfilled systems. Such
Advantages
clinical data are essential to determine the precise Single-paste formulation
performance of the microfilled composite resins over No mixing
the same time frame as the established macrofilled Less porosity
materials. This is of special importance in view of the Adequate working time
Suitable for incremental technique if desired
alterations in certain physical properties between the
Restoration color, opacity, translucency, and
two basic constructions. To date, the maximum clinical morphology can be optimized
observation time is only 7 years. However, the clinical Improved margin adaptation
reports on microfilled composite resins during the last 3 Faster cure
years have consistently been favorable.8,2s-27 More complete surface cure
Optimal physical properties
VISIBLE LIGHT CURE Wear resistance somewhat improved
Instant finishing possible
All the above-mentioned systems can be formulated
Disadvantages
to polymerize either chemically or by light. It is not the
Technique sensitivity
purpose of this article to discuss at length the differ- Polymerization starts under operating light; thus, not
ences between the two curing mechanisms; however, unlimited working time
light cure does provide a higher degree of polymeriza- Limited depth of cure
tion than chemical cure. For that reason photocured Additional equipment necessary

restorative resins do have some definite advantages, as


is shown in Table X.3,4 This is particularly true with resins to the operating light. Therefore, the resin
microfilled composite resins. The single-paste formula- should be shielded from light until a few seconds before
tions do not require mixing; consequently, there is it is to be inserted.
much less porosity in the restoration. Thus, with All factors considered, the potential to achieve virtu-
light-cured microfilled composite resins, perfectly ally undetectable anterior restorations by use of a
smooth enamel-like surfaces that are free of irregular- combination of a microfilled composite resin and the
ities can be achieved. Furthermore, such a system visible light cure is certainly attractive.
allows sufficient working time for a more precise
insertion of the material. Thus, these systems are CONCLUSION
particularly suitable for an incremental technique, Hybrid composite resins can be considered an opti-
which provides an improved margin adaptation. In mal combination of the well-tried traditional and the
addition, it facilitates an optimal match to the sur- new microfiller composite resin technology. The most
rounding natural tooth structure with regard to color, promising anterior types, especially with regard to
opacity, translucency, and morphology. Finally, the esthetics, consist of an extremely small (1 to 2 rm),
faster and more Icomplete cure is of great importance in rather soft, traditional macrofiller with a sophisticated
the feather-edged margins of freshly inserted restora- size distribution placed into a reinforced organic
tions. In contrast, the degree of polymerization of matrix. Such a resin system demonstrates all the
chemically cured resins is, among other factors, mass favorable properties seen with modern, traditional
dependent. Therefore, the thin and frail marginal areas composite resins but has a somewhat superior wear
of a restoration may be insufficiently cured. With resistance. Furthermore, the surface smoothness is
light-cured systems, an immediate finishing is possible definitely better, even though not ideal. Overall, use of
without jeopardizing the excellent initial margin adap- hybrid composite resins means remaining on the safe
tation. side. Good, but not perfect, restorations can be
As seen in Table X, there are some disadvantages to inserted.
be encountered with light-curing systems. Of course, it If esthetics is the primary concern and virtually
is necessary to purchase a light generator. Further- undetectable restorations are in demand, then micro-
more, some precautions must be noted with light-cured filled resin systems, particularly light-cured versions,
resins. The depth of cure may not be as great as is often are the materials of choice. At present, these are the
stated. Even with a curing time of 40 seconds, the depth heterogeneous microfilled composite resins with splint-
of cure may be in the order of 3 mm with the lighter or ered prepolymerized particles. However, in order to
universal shades and only 2 mm with the darker ones. achieve restorations of consistently outstanding quality,
In addition, the working time is actually not unlimited attention to technique sensitivity should be maintained,
since polymerization does sta.rt on exposure of the and certain modifications have to be made in the

THE JOURNAL OF PROSTHETIC DE:NTISTRY 487


LUTZ AND PHILLIPS

clinical procedures that are used with traditional 15. Gross, A.: Kunststoffe in der Zahnmedizin. Chemie unserer
Zeit 13:142, 1979.
composite resins. Cavity preparation and insertion and
16. Schaefer, H. W. R.: Fortschritte auf dem Gebiet der Kunst-
finishing techniques have to be adapted. It remains to staff-Fiillungen-Fiillungsmaterialien mit feinstteiligem Sili-
be seen whether the trade-off in certain in vitro ciumdioxid als anorganischem Fiillstoff. Quintessenz 321685,
properties will lead to a different clinical performance 1981.
as compared to the traditional and hybrid composite 17. Schmitt, W., Purrman, R., Jochum, P., and Hiibner, H-J.: Use
of silicic acid pellets as exipients for dental mass material. WO
resins.
81/01366-PCT/EP 80/00135 (patent).
REFERENCES 18. Lambrechts, P., and Vanherle, G.: Observation and compari-
son of polished composite surfaces with the aid of SEM and
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