Quiz CHEMISTRY

Chemical Bonding

Straight Objective Type

1. Mark out the structure which has all formal charge zero BH NH
Cl B-H
(A) N C C N (B) O
(C) HN (D) N N O
C
Cl BH NH

2. Mark out the correct comparison of stability of the following structures.

O

CH3 CH2 C O CH2 CH O

III
I II

(A) III < II < I (B) III < I < II (C) I < II < III (D) I < III < II

3. The compound (SiH3)3N is expected to be

(A) Pyramidal and more basic than (CH 3)3N (B) Planar and less basic than (CH3)3N
(C) Pyramidal and less basic than (CH3)3N (D) Planar and more basic than (CH3)3N

4. I4O9 is a/ an
(A) ionic compound (B) Covalent compound (C) Coordinate bond (D) double salt

5. Which of the following is not correct regarding the structure of POCl3

(A) Lewis structure violates octet rule
(B) It has irregular tetrahedral geometry
(C) P = O bond and P Cl bond repulsion is greater than P Cl and P Cl bond repulsion
(D) Cl P O, bond angle is lesser than Cl P Cl bond.
Multiple Correct Answers Type
6. Which of the following is/are planar?
(A) F2C C CF2 (B) F2B C C BF2 (C) (s1H3)3N (D) H2N NH2

7. Which of the following is/are

(A) HI < HBr < HCl < HF ionic character (B)HF < HCl < HBr < HI reducing strength
(C) HF < HCl < HBr < HI bond length (D) HF < HCl < HBr < HI Stability
8. Mark out the incorrect decreasing order of Physical properties given in bracket.
(A) H2O, H2S, H2Sc, H2Te (Dipole moment) (B) HF, HI, HBr, HI (Boiling Point)
(C) CH4, SiH4, GeH4, SnH4 (Enthalpy of vaporisation) (D) NH3, PH3, AsH3, SbH3 (Melting point)

9. Mark out the Molecules/ions having linear structures

(A) SnCl2 (B) NCO- (C) H2O (D)CS2

10. Mark out the incorrect match of shape

(A) XeOF2 Trigonal Planer (B) ICl4- Square Planer
(c) SbF6 Square pyramidal (D) NH2 Pyramidal
 Quiz CHEMISTRY

Paragraphs

Hybridisation is measure to express the molecular shapes. reasonable. Hybridisation, although theoretical, but is
highly correlated with molecular shapes or inter- orbital angles. If there is any departure in geometry (on the basis
of VSEPR theory), the apparent departure in hybridisation can be observed.
And the following characteristic relationship is the easiest way to interpret that departure. Any sp 1 hybrid is
charatrized by the following relationship
1 i fp
fs or fP and i
i 1 i 1 fs
(for sp3.i = 3 , sp2, i = 2) for an orbital. fs + fp = 1 while all the s,p hybrid of a given atom must satisfy the condition)
fs = 1.00
1
And inter- orbital angle between two equivalent (same fs and fp) hybrid orbital is given by cos
i

11. H2O molecules consist of two bond pairs (O-H) and two lone pairs of electrons. Molecule shape is bent (V-shaped)
having O

H H bond Angle 104.50. What Oxygen hybrid are used to make O H bonds
(A) sp3 (B) sp4 (C) sp2-d (D) sp5

12. VSEPR theory suggests a small departure from 1090.28 for NH3 Molecule. The HNH bond Angle has been found
to be 1070.1 What kind of N hybrid contains. The non bonding pair
(A) sp3 (B) sp3.4 (C) sp2.13 (D) sp2

13. What S- character is used by the C atom in the orbitals directed to the Hydrogen in CH2F2 molecule? (HCH)
bond Angle in CH2F2 is 1110.9)
(A) 27.1 % (B) 23.7 % (C) 18 % (D) 17.1 %
 Quiz CHEMISTRY
14. Match The Following

COLUMN I COLUMN II
(A) P-nitro phenol (P) Debye force

(B) HBr (Q) Keesom force

(C) HBr in CCl4 (R) London force

(D) I2 (D) Hydrogen bonding

15. Match The Following

COLUMN I COLUMN II
(A) CO2 (P) Subtractive
F H
(B) C=C (Q) Additive
H OCH3
(C) I F (R) R 0

(D) BF3 (D) R 0

Fill in the blanks:

O O
II III
16. Correct relation of bond length of C O in O C CH2 C O His .
I IV
17. B2 molecule has character

18. The bond angle between lone pair containing hybrid orbital is than bond angle between
bond pair containing hybrid orbital in H2O molecule.