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2. Which state function is given by the heat of reaction at constant volume? Which
state function is given by the heat of reaction at constant pressure? Under what
conditions are these heats of reaction equal?
3. What equation defines ΔH in general terms? How is this expressed when the
system involves a chemical reaction? In general, why are chemists and biologists
more interested in values of ΔH than ΔU?
4. Will the entropy change for each of the following be positive or negative?
a. Moisture condenses on the outside of a cold glass
b. Raindrops form in a cloud.
c. Air is pumped into a tyre
d. Frost forms on the windscreen of your car
e. Sugar dissolves in coffee.
5. At constant pressure, what role does the enthalpy change play in determining the
spontaneity of an event?
7. When glucose is oxidised by the body to generate energy, part of the energy is
used to make molecules of ATP (adenosine triphosphate). However, of the total
energy released in the oxidation of glucose, only 38% actually goes to making
ATP. What happens to the rest of the energy?
8. Toluene, C7H8, is used in the manufacture of explosives such as TNT
(trinitrotoluene). A 1.500 g sample of liquid toluene was placed in a bomb
calorimeter along with excess oxygen. When the combustion of the toluene was
initiated, the temperature of the calorimeter rose from 25.000 °C to 26.413 °C.
The products of the combustion were CO2(g) and H2O(l), and the heat capacity of
the calorimeter was 45.06 kJ K-1. The reaction was:
9. One thermochemical equation for the reaction of carbon monoxide with oxygen
is:
a) Write the thermochemical equation for the reaction using 2 mol of CO.
b) What is Δ for the formation of 1 mol of CO2 by this reaction?
10. We can generate hydrogen chloride by heating a mixture of sulfuric acid and
potassium chloride according to the equation
12. Use the following thermochemical equations to calculate the standard enthalpy of
formation (in kilojoules per mole) of Mg(NO3)2(S).
13. Nitrogen dioxide, NO2, an air pollutant, dissolves in rainwater to form a dilute
solution of nitric acid. The equation for the reaction is
14. Calculate the value of in kJ for the following reactions, using data in
tables 8-2 and 8-5. Assume that Δ and ΔS are independent of temperature