ANDHERI / BORIVALI / DADAR / THANE / POWAI / CHEMBUR / NERUL / KHARGHAR

IIT JEE: 2016 CRASH COURSE (A1) DATE: 20/11/15

TOPIC: GASEOUS STATE & CHEMICAL ENERGETICS

SECTION-I
This section contains 10 multiple choice questions. Each question has 4 choices (A),
(B), (C) and (D) for its answer, out which ONLY ONE is correct.

1. 2 mole of an ideal monoatomic gas undergoes a reversible process for which PV2 =C. The gas is
expanded from initial volume of 1 L to final volume of 3 L starting from initial temperature of 300
K. Find H for the process :
(A) 600 R (B) 1000 R (C) 3000 R (D) None of these

2. One mole of an ideal monoatomic gas at 27C is subjected to a reversible isoentropic compression
until final temperature reached to 327C. If the initial pressure was 1.0 atm then find the value of ln
P2: (Given: ln 2 = 0.7).
(A) 1.75 (B) 0.176 (C) 1.0395 (D) 2.0

3. Two mole of an ideal gas is expanded irreversibly and isothermally at 37C until its volume is
doubled and 3.41 kJ heat is absorbed from surrounding. Stotal (system + surrounding) is:
(A) 0.52 J/K (B) 0.52 J/K (C) 22.52 J/K (D) 0

4. For a perfectly crystalline solid Cp,m = aT3 + bT, where a and b constant. If Cp,m is 0.40 J/K mol at
10 K and 0.92 J/K mol at 20 K, then molar entropy at 20 K is :
(A) 0.92 J/K mol (B) 8.66 J/K mol (C) 0.813 J/K mol (D) None of these

5. A heat engine operating between 227C and 27C absorbs 2 KCal of heat from the 227C reservoir
reversible per cycle. The amount of work done in one cycle is
(A) 0.4 Kcal (B) 0.8 Kcal (C) 4 Kcal (D) 8 Kcal.

6. Assuming that O2 molecule is spherical in shape with radius 2 , the percentage of the volume of
O2 molecules to the total volume of gas at S.T.P. is:
(A) 0.09 % (B) 0.9 % (C) 0.009 % (D) 0.045 %

7. A gas cylinder containing cooking gas can withstand a pressure of 14.9 atmosphere. The pressure
gauge of cylinder indicates 12 atmosphere at 27 C. Due to sudden fire in the building temperature
starts rising. The temperature at which cylinder will explode is:
(A) 472.5 K (B) 99.5 C (C) 199 C (D) 572.5 K

8. A compound exists in the gaseous phase both as monomer (A) and dimer (A2). The atomic mass of
A is 48 and molecular mass of A2 is 96. In an experiment 96 g of the compound was confined in a
vessel of volume 33.6 litre and heated to 273 C. The pressure developed if the compound exists as
dimer to the extent of 50 % by weight under these conditions will be
(A) 1 atm (B) 2 atm (C) 1.5 atm (D) 4 atm

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9. According to kinetic theory of gases, for a diatomic molecule
(A) The pressure exerted by the gas is proportional to the mean velocity of the molecule.
(B) The pressure exerted by the gas is proportional to the rms velocity of the molecule.
(C) The rms velocity of the molecule is inversely proportional to the temperature
(D) The mean translational K.E. of the molecule is proportional to the absolute temp.

10. Which of the following is correct statement of the second law of thermodynamics?
(A) It is impossible for a cyclic process to transfer heat from a system at a lower temperature to one
at a higher temperature without converting some work to heat.
(B) It is impossible to convert heat completely into equivalent amount of work without producing
changes elsewhere.
(C) Every perfect machine working reversible between the same temperatures of source and sink
have the same efficiency whatever be the nature of the substance used
(D) All of these

SECTION-II (Multiple Choice Questions)

This section contains 20 multiple choice questions. Each question has 4 choices (A),
(B), (C) and (D) for its answer, out which ONE OR MORE is/are correct.

11. Pick out true statement among the following:

(A) Reversible adiabatic process is isentropic process.
(B) Ssystem for irreversible adiabatic compression is greater than zero.
(C) Ssystem for free expansion is zero.
(D) Ssurr for irreversible isothermal compression is greater than zero.

12. Select the irreversible process(s)?

(A) Mixing of two gases by diffusion (B) Evaporation of water at 373 K and 0.1 atm pressure
(C) Free expansion of gases (D) None of these

13. Fro which of the following substances, heat of formation in the standard state will not be zero?
(A) e ( g ) (B) H + ( aq ) (C) Br 2 (l) (D) H 2 O(l)

14. Which one of the following statements are true about the effect of an increase in temperature on the
distribution of molecular speeds in a gas?
(A) The area under the distribution curve remains the same as under the lower temperature
(B) The distribution becomes broader
(C) The fraction of the molecules with the most probable speed increases
(D) The most probable speed increases

15. Select correct statement(s):

(A) We can condense vapour simply by applying pressure
(B) To liquefy a gas one must lower the temperature below TC and also apply pressure
(C) At Tc, there is no distinction between liquid and vapour state, hence density of the liquid is
nearly equal to density of the vapour
(D) None

16. The curve of pressure volume (PV) against pressure (P) of the gas
at a particular temperature is as shown, according to the graph
which of the followings are correct (in the low pressure region):
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 (A) H2 and He show +ve deviation from ideal gas equation.
(B) In low pressure region CO, CH4 and O2 show negative deviation from ideal gas equation.
(C) H2 and He show negative deviation while CO2, CH4 and O2 show positive deviation.
(D) H2 and He are less compressible than that of an ideal gas while CO2, CH4 and O2 more
compressible than that of ideal gas in low pressure region.

17. Which of the following are correct statements?

(A) Vander Waals constant a is a measure of attractive force
(B) van der Waals constant b is also called co-volume or excluded volume
(C) b is expressed in L mol1
(D) a is expressed in atm L2 mol2

18. Which statements about the behavior of a real gas are true?
(A) Real gas exerts more pressure compared to an ideal gas.
(B) Real gas can be compressed more compared to an ideal gas.
(C) Real gas with high value of Vander Waals constant, a is easily liquefiable.
(D) H2 and He are less compressible compared to an ideal gas at ordinary temperature.

19. The figure shows the effect of pressure on the compressibility factor, Z of a
gas:
The right conclusions are
(A) The curve AE can be explained by PV = RT
(B) The curve AF and CD can be explained by PV = RT + Pb
(C) The curve AB can be explained by PV = RT (a/V)
(D) All the three curves AF, AE and AD shows the real behavior
20. Which of the following are true about resonance energy?
(A) Resonance energy = Experimental heat of formation Calculated heat of formation
(B) Resonance energy = Calculated heat of formation Experimental heat of formation
(C) Greater the resonance energy, more the compound will be stable
(D) Lesser the resonance energy, more the compound will be stable

21. Which of the following are correct for ideal gas?

U H T P
(a) =0 (b) =0 (c) =0 (d) =0
V T P T P H T V

22. Compounds with higher positive enthalpy of formation

(a) are less stable (b) are in energy rich state which leads to unstability
(c) are stable (d) are in low energy state which leads to stability

23. Identify the incorrect statement regarding a spontaneous process:

(A) Exothermic processes are always spontaneous.
(B) Lowering of energy in the reaction process is the only criterion for spontaneity.
(C) For a spontaneous process in an isolated system, the change in entropy is positive.
(D) Endothermic processes are never spontaneous.

24. Select the incorrect set of statements

(A) Work done by the surrounding in case of infinite stage expansion is more than single stage
expansion
(B) Irreversible work is always greater than reversible work.
(C) On an ideal gas in case of single stage expansion and compression system as well as surrounding
are restored back to their original states

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 (D) If gas is in thermodynamic equilibrium is taken from state A to state B, by four successive single
stage expansions. Then we can plot 4 points on the P-V indicator diagram.

25. Consider the reactions

(i) S (rhombic) + 3/2 O2(g) SO3(g), H1
SO3(g), H2
(ii) S (monoclinic) + 3/2O2(g)
(iii) S (rhombic) + O3(g) SO3(g), H3
SO3(g), H4
(iv) S (monoclinic) + O3(g)
(A) H1< H2< H4 (magnitude only)
(B) H1< H3< H4 (magnitude only)
(C) H1< H2 = H3 < H4 (magnitude only)
(D) H1 + H4 = H2 + H3

26. Which of the given substances have non-zero standard enthalpy of formation?
(A) O3(g) (B) S2(g) (C) C2(g) (D) O(g)

27. Correct statement(s) about reversible expansion/compression of an ideal gas is/are

(A) More work is done by the system when it undergoes isothermal expansion than during adiabatic
expansion.
(B) More work is to be done on the system when it undergoes isothermal compression than during
adiabatic compression.
(C) There is no change in enthalpy during isothermal as well as adiabatic processes.
(D) Temperature of the system falls during adiabatic expansion but it increases during adiabatic
compression.

28. Which of the following thermodynamic parameters is/are zero for isothermal compression of an ideal
gas?
(A) H (B) T (C) U (D) q

29. Correct statements among the following are

(A) First law of thermodynamics rules out the existence of an engine which does work without
absorbing equal amount of heat from the surrounding.
(B) For a cyclic process U = 0
(C) Bond dissociation is always endothermic.
(D) Enthalpy of formation is always negative.

30. Which of the following statements are correct?

(A) The system of constant entropy and constant volume will attain the equilibrium in a state of
minimum energy
(B) The entropy of the universe is on the increase
(C) The process would be spontaneous when (S)E,V< 0, (E)S,V> 0
(D) The process would be spontaneous when (S)E,V> 0, (E)S,V< 0

SECTION III (Integer Answer Type)

This section contains 20 questions. The answer to each of the questions is a single
digit integer, ranging from 0 to 9. The correct digit below the question number in
the ORS is be bubbled.

31. In gas phase, acetic acid is at equilibrium with a dimer held together by a pair of hydrogen bonds
with an equilibrium constant of 3.56 at 100 C. If the pressure of acetic acid in a glass bulb is 0.75
bar, what is the partial pressure of the dimer in bar?

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32. An equilibrium reaction has H = -134 J mol-1. What is the slope of a plot of log K eq vs T-1 ?

33. How many of the following gases have higher critical temperature than H 2 ?
CO 2 , CH 4 , CO

34. 11.2 litres of water vapour at STP, when condensed to water, occupies V mL. of volume, then the
value of V is ?

35. A 0.5 dm3 flask contains gas A and 1 dm3 flask contains gas B at the same temperature. If density of
A = 3 g/dm3 and that of B = 1.5 g/dm3 and the molar mass of A = 1/2 of B, the ratio of pressure
exerted by gases is :

36. The mass of molecule A is twice that of molecule B. The root mean square velocity of molecule A is
twice that of molecule B. If two containers of equal volume have same number of molecules, the
ratio of pressure PA/PB will be

37. The kinetic energy of N molecules of O2 is x joule at 123 C. Another sample of O2 at 27 C has a
kinetic energy of 2x. The later sample contains y molecules of O2 then what is the value of y/N?

38. The ratio between the r.m.s. velocity of H2 at 50 K and that of O2 at 800 K is

39. A rigid and insulated tank of 3m3 volume is divided into two compartments. First compartment of
volume of 2m3 contains an ideal gas at 0.8314 MPa and 400 K and while the second compartment of
volume 1m3 contains the same gas at 8.314 MPa and 500 K. If the partition between the two
compartments is ruptured, the final temperature of the gas is T K then T/160 is

40. A gas expands adiabatically such that T V1/2. The value of (Cp,m/Cv,m) of the gas will be y
then what is 2y?

41. Calculate the change in pressure (in atm) when 2 mole of NO and 16 g O2 in a 6.25 litre originally at
27C react to produce the maximum quantity of NO2 possible according to the equation.
2NO(g) + O2(g)
2NO2(g)

42. A bulb of constant volume is attached to a manometer tube open at other end
as shown in figure.
h
The manometer is filled with a liquid of density (1/3)rd that of mercury.
Initially h was 228 cm. Through a small hole in the bulb gas leaked causing
pressure decrease as
dP
= kP. If value of h is 114 cm after 7 minutes. If value of k= 0.8x hour1
dt
then x is______
[Use: ln (4/3) = 0.28 & density of Hg = 13.6 g/ml]

43. A reversible heat engine A (based on Carnot cycle) absorbs heat from a reservoir at 1000K and
rejects heat to a reservoir at T2. A second reversible engine B absorbs, the same amount of heat as

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 rejected by the engine A, from the reservoir at T2 and rejects energy to a reservoir at 360K. If the
efficiencies of engines A and B are the same then what is the value of T2/100 is

44. What is the free energy change (G) when 1.0 mole of water at 100C and 1 atm pressure is
converted into steam at 100C and 1 atm pressure?
45. An ideal gas is taken around the cycle ABCA as shown in P-V diagram. The net work done by the
gas during the cycle is equal to W then W/P 1 V 1 is

46. A certain amount of gas is enclosed in a sphere of volume 5L at pressure 7atm and temperature
327C. It is then connected to another sphere of volume 2.5 L by a narrow tube and stopcock. The
second sphere is initially evacuated and the stopcock is closed. After opening the stopcock, the
temperature of gas in the second sphere becomes 127C, while the first sphere is maintained at
327C. Find the final gas pressure within the two spheres.

47. From the following data of H, of the following reactions,

C(s) + O2 (g) CO (g) H = 110 kJ
C(s) + H2O (g) CO (g) + H2(g) H = 132 kJ
If mole composition of the mixture of oxygen and steam is y/10 on being passed over coke at 1273
K, keeping temperature constant then what is y?

48. Reactions involving gold have been of particular interest to alchemists. Consider the following
reactions,
Au(OH)3 + 4 HCl HAuCl4 + 3 H2O, H = 28 kcal
Au(OH)3 + 4 HBr HAuBr4 + 3 H2O, H = 36.8 kcal
In an experiment there was an absorption of 0.44 kcal when one mole of HAuBr4 was mixed with 4
moles of HCl. Then % of HAuBr4 converted into HAuCl4is

49. If 2 kcal heat is given to a system and 6 kcal work is done on the system then the internal energy of
system will increase by how many kcal?

50. Certain amount of a gas confined in a piston-filled cylinder is heated from 27oC and the gas
expanded against a constant pressure doing 4.157 kJ of work on surroundings. The number of moles
of gas present in the cylinder is (are) ____________.

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CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 7
 ANDHERI / BORIVALI / DADAR / THANE / POWAI / CHEMBUR / NERUL / KHARGHAR
CRASH COURSE (A1)
TOPIC: GASEOUS STATE & CHEMICAL ENERGETICS

1. (B) 2. (A) 3. (B) 4. (C) 5. (B)

6. (A) 7. (B) 8. (B) 9. (D) 10. (D)

11. (ABD) 12. (ABC) 13. (ABD) 14. (ABD) 15. (ABC)

16. (ABD) 17. (ABCD) 18. (CD) 19. (ABC) 20. (AC)

21. (ABC) 22. (AB) 23. (ABD) 24. (ACD) 25. (ABD)

26. (ABCD) 27. (AD) 28. (ABC) 29. (ABC) 30. (ABD)

31. (2) 32. (7) 33. (3) 34. (9) 35. (4)

36. (8) 37. (1) 38. (1) 39. (3) 40. (3)

41. (2) 42. (3) 43. (6) 44. (0) 45. (5)

46. (4) 47. (6) 48. (5) 49. (8) 50. (5)

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