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224
Properties of Black Oils-Definitions 225
131.5 ,
Solution
Yo
=Po
P W
"API 141'5 -
= - 131.5
Y O
B, =
+
volume of oil dissolved gas leaving reservoir at reservoir conditions . (8-3)
volume of oil entering stock tank at standard conditions
The units are barrels of oil at reservoir conditions per barrel of stock-
tank oil, res bbl/STB . The volume of stock-tank oil is always reported at
60"F, regardless of the temperature of the stock tank. Thus, stock-tank
liquid volume, like surface gas volume, is reported at standard condi-
tions.
Solution
bo = - 1
(8-4)
BO
The formation volume factor may be multiplied by the volume of
stock-tank oil to find the volume of reservoir oil required to produce that
volume of stock-tank oil. The shrinkage factor can be multiplied by the
reservoir volume to find the corresponding stock-tank volume. Both
terms are in use, but petroleum engineers have adopted universally the
formation volume factor.
Formation volume factor also is called reservoir volume factor.
Since the method of processing the produced fluids has an effect on the
volume of stock-tank oil, the value of the formation volume factor will
depend on the method of surface processing. However, the effect is small
for black oils.
multicomponent mixtures, and the quantities of gas and oil are estab-
lished by gas-liquid equilibrium.
The quantity of gas-forming molecules (light molecules) in the liquid
phase at reservoir temperature is limited only by the pressure and the
quantity of light molecules present. A black oil is said to be saturated
when a slight decrease in pressure will allow release of some gas. The
bubble-point pressure is a special case of saturation at which the first
release of gas occurs.
On the other hand, when the black oil is above its bubble-point
pressure, it is said to be undersaturated. An undersaturated oil could
dissolve more gas (light molecules) if the gas were present.
The quantity of gas dissolved in an oil at reservoir conditions is called
solution gas-oil ratio. Solution gas-oil ratio is the amount of gas that
evolves from the oil as the oil is transported from the reservoir to surface
conditions. This ratio is defined in terms of the quantities of gas and oil
which appear at the surface during production.
Fig. 8-2. Typical shape of solution gas-oil ratio of a black oil as a function
of pressure at constant reservoir temperature.
Properties of Black Oils-Definitions 229
Solution
R, =
1.21 scf = 702
scf
STB (8-5)
~
Fig. 8-3. Volume change as pressure is reduced below the bubble point
at constant reservoir temperature.
Fig. 8-4. Typical shape of total formation volume factor of a black oil as a
function of pressure at constant reservoir temperature compared to shape
of black oil formation volume factor at same conditions.
Properties of Black Oils- Definitions 23 1
Solution
co = - ( dln V
7 ) T
or c, = - (T )
dln VM
T
232 PETROLEUM FLUIDS
results in
or
(8- 11)
Properties of Black Oils- Definitions 233
Solution
v2 (8- 11)
C, (p2 - pJ = - In -
v1
c, =
- ln(60.37 cd59.55 CC) = 13.68 x 10-6
(4014.7 -5014.7) psia
(8- 14)
c, = (8-15)
234 PETROLEUM FLUIDS
Thus,
(8- 16)
(8-17)
results in
(8- 18)
or
(8-19)
(8-20)
( %)T
(8-21)
Properties of Black Oils- Definitions 235
(8-22)
- (%)T
Thus, at reservoir pressures below the bubble point, the total change in
volume is the sum of the change in liquid volume and the change in free
gas volume.
(8-23)
(8-27)
The petroleum engineer rarely uses this liquid property since petroleum
reservoirs normally are operated at constant temperature.
There is also a physical property called thermal expansion. This is not
defined as above but is simply the ratio of the volume of oil at high
temperature to the volume of the same oil at low temperature, with both
volumes measured at the same pressure.
Solution
Interfacial Tension
There is an imbalance of molecular forces at the interface between two
phases. This is caused by physical attraction between molecules. This
imbalance of forces is known as interfacial tension.
A molecule in a liquid is uniformly attracted to the surrounding
molecules. This is represented schematically by the sizes of the arrows
on the molecules of Figure 8-9.
A molecule at the surface is attracted more strongly from below
because the molecules of the gas are separated much more widely, and
the attraction is inversely proportional to the distance between molecules.
This imbalance of forces creates a membrane-like surface. It causes a
liquid to tend toward a minimum surface area. For instance, a drop of
water falling through air tends to be spherical since a sphere has the
minimum surface-to-volume ratio.
Volatile Oils
All of the properties discussed in this chapter are defined in exactly the
same way for volatile oils as for black oils.
Formation volume factors and solution gas-oil ratios normally are not
measured for volatile oils. These quantities are used primarily in material
balance calculations which do not apply to volatile oils. If these
quantities were measured for volatile oils, they would have the shapes
indicated in Figures 8- 10 and 8- 1 1 . The large decreases in both curves
Exercises
8-1. A stock-tank oil has a specific gravity of 0.875. What is its density
in lb/cu ft?
8-2. What is the gravity in "API of the oil of Exercise 8-l?
8-3. A stock-tank liquid has a density of 46.4 Ib/cu ft. What is its
specific gravity?
8-6. What is the gravity in "API of an oil with a density of 56.4 lb/cu ft?
8-7. A liquid sample from a black oil reservoir had a volume of 227.0
cc in a laboratory cell at reservoir temperature and bubble-point
pressure. The liquid was expelled through laboratory equipment
which is the equivalent of the field separator-stock tank system.
The oil volume collected in the stock tank was 167.4 cc. The
separator produced 0.537 scf of gas, and the stock tank produced
0.059 scf of gas. Calculate the formation volume factor of the oil
and the solution gas-oil ratio.
8-9. A black oil reservoir has just been discovered. Reservoir pressure
appears to be above the bubble-point pressure of the oil. Measured
at reservoir conditions, 86.3 barrels per day enter the wellbore.
The oil is processed through a separator into a stock tank. The
stock tank accumulates 57.9 barrels of 44.2"API oil each day. The
separator produces 43,150 scf/d of 0.724 gravity gas, and the stock
tank vents 7240 scf/d of 1.333 gravity gas. What is the formation
volume factor of the oil? What is the solution gas-oil ratio? Which
of the previous answers applies only at the bubble point?
Properties of Black Oils-Definitions 243
Plot oil formation volume factor and solution gas-oil ratio against
pressure. Compare the shapes of your plots with Figures 8-1 and
8-2. Compare the shapes of the B, graph and the R, graph. Save
your graphs; you will need them in Exercise 8-17.
8- 11. Determine the value of total formation volume factor of the black
oil of Exercise 8-10 at 2400 psig.
8-12. Determine the value of total formation volume factor of the black
oil of Exercise 8-10 at 3500 psig.
8-14. Early in its life a well produced 0.766 gravity gas at 933 scf/STB
and 43.7"API stock-tank oil. A sample of reservoir oil was placed
in a laboratory cell at reservoir temperature of 186F. Pressure
was varied and oil volume measured as follows.
Reference
1. Martin, J.C.: Simplified Equations of Flow in Gas Drive Reservoirs
and the Theoretical Foundation of Multiphase Pressure Buildup
Analyses, Trans. AIME (1959) 216, 309-311.