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biogenic
gas
150F
65C
oil
window
300F
150C
wet gas
dry gas
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Total organic carbon (TOC)
3
TOC> 0.5 weight % minimum value for source
rock
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Source rocks
5
How do we know if temperatures have been
high enough in the source rock to form
petroleum?
We use paleothermometers
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Chemical paleothermometers
Pyrolysis
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Chemical paleothermometers
Pyrolysis
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Chemical paleothermometers
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Transformation ratio
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Transformation ratio
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Transformation ratio
Is also used to describe cracking to gas
Then:
oil cracking to gas is defined by transformation
ratios between 0.01 and 0.99
uncracked oils have transformation ratios less
than 0.01
crude oils that have completed cracking to gas
have transformation ratios greater than 0.99
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Paleothermometers
1) Chemical paleothermometers
2) Biological paleothermometers
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Biological paleothermometers
Vitrinite reflectance R0
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Biological paleothermometers
The shininess can be measured optically
150F
65C
oil
window
300F
150C
wet gas
Igneous intrusion
Fault or unconformity
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Wells
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Log type
Company name
API number
Location
Log elevation
information
Borehole
information
Casing information
24
KB=Kelly Bushing
DF=Drilling Floor
GL=Ground Level
Log elevation
information
API number
API#
37-121-37345-00-00
state
county
well number
sidetrack
event
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Expulsion and migration
Primary migration: migration from the
source rock to permeable carrier bed
Secondary migration: movement through
carrier bed into reservoir
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Oil seepages
These are puddles of asphalt that seeped to the surface from young
(Miocene) source rocks through faults. In the Pleistocene and
Holocene many animals perished in them and became fossilized.
Visit the George C. Page Museum in Los Angeles 31
Primary migration
When potential source and reservoir rocks
are buried, they contain water in their pore
space.
The oil or gas, therefore, has to replace this
water in the migration process when it
reaches the reservoir rock
formation water
32
Primary migration
Formation water:
the water that was present in the sediments
during or shortly after deposition
33
Primary migration
What happens with formation water during
burial?
Most formation waters are saline (with mainly
sodium and chlorine)
The salinity increases with depth
During compaction formation water is expelled
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water salinity vs. depth
35
Porosity-depth relationships for mudrocks 36
Sedimentary rocks compact during burial
37
Most water lost,
but this is above
the oil window
At larger depth
(T): smectite clay
lattice collapses
to illite, and
during this
process pore
space is further
reduced 38
During this phase hydrocarbons could be
expelled
39
Primary migration
40
During burial, the source rock compacts, its pore
fluids become overpressured with respect to
surrounding rocks that have higher
permeabilities
migration is possible
41
When porosity
decreases, pore size
decreases
The diameter of many
hydrocarbon molecules
may be too large to
migrate through the
shale pores, particularly
since structured water
on the clay surfaces
(water-wet) further
restricts the pathways
So, how does primary migration work? 42
With decreasing total porosity, micropore volumes
relatively increase whereas the sum of mesopores and
macropore volumes decrease 43
1. Oil is generated at temperatures of ~60 to
120 C, which are typically found at depths of
2 to 4 km
2. Source rocks at these depths are so
compacted that their permeability is too low
for efficient primary migration
44
1. Migration by diffusion. Because of
differing concentrations of the fluids in the
source rock and the surrounding rock there
is a tendency to diffuse. A widely accepted
theory
45
2. Migration by molecular solution in water.
While aromatics are most soluble in
aqueous solutions, they are rare in oil
accumulations, therefore discrediting the
general importance of this mechanism,
although it may be locally important
46
3. Migration along microfractures in the
source rock. During compaction the fluid
pressures in the source rock may become
so large that spontaneous hydrofracing
occurs. A useful, maybe underestimated
hypothesis
47
4. Oil-phase migration. Oil migration in the
source rock provides a continuous oil-wet
migration path along which the hydrocarbons
diffuse along pressure and concentration
gradient. This is a reasonable but unproven
hypothesis, good for high TOCs
48
Primary migration- thoughts
Very young oil is found, suggesting that early
expulsion is possible, perhaps in the form of
immature hydrocarbons
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Secondary migration
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Differential entrapment
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