6 CARIBBEAN EXAMINATIONS COUNCIL ADVANCED PROFICIENCY EXAMINATION (CHEMISTRY. id Paper 0) 90 msiret aE TS) READ THE FOLLOWING INSTRUCTIONS CAREFULLY. “This tat consists of 45 items. You will have 90 binutes to answer thera, fl enswer shect and 2 Dats Booklet. In addition to this test booklet, you should have Each itcm in this tos has four suggested answei ‘you are about to answer and decide which choi ‘On your answer sheet, find the mamber which of having the same letter as the answer you have fs best. Look atthe sample item below. ‘Sample item Which of the following is the HIGHEST energy rinsition in an organic compound? GP atoce ‘Sample Answer (B) nton © cos ©2000 io oe ‘The best answer to this item is “orto a", so answet space (C) has been shaded. | HF you went to change your answer, be sure to erasé it completely before you fill in you! choice. ‘When you we told to begin, turn the page and work as quickly and as carefilly ws vou ep. IF you cannot answer an item, orat and go on to thelcext one. You ean come back to the or item ater. Your score will be the total number of garrect answers, i You may do any rough work ia this booklet, Figures are not necessarily drawn to seale The use of silent, non-progeammuble: ealeulators ix allowed, TOLD TO DO.SO, DO _NOT TURN THIS PAGE UNTIL YOU Al eral (A), (B),(C)-(D). Rend eal item izesponds to your item and shade the pace new itedBalt boas ItwasNOT part ofDalton’s atomicthedty 2, Aradioactive element, M, of mass number that atoms ‘A, and atomio number Z| indexgoes decay, followed by « decay. The final (A) ae indivisible clement, N, will be (@) ae characterised by their sp umber whe (©) of an element have ident properties t @ “tN (©) ofan clement dite from those df other elements | © BAN | @ EN t Item 3 refers to the following diagrams. | | i i i “a @|| © ) ‘The electronié configuration ofthe ele L. ‘with atomic number 20 (Z,= 20) is given by (A) tet 288 pt 368 3p at I © wewsya |) © Is? 2s" Qp* 3s? Spt 4s! 4p! (D) Is? 2s? 2p? 3s? 3p) da! 3d? i Which of the following solids has « giant molecular lattice’? | | (A) Carbon dioxide (B) Copper oxide (C}— Magnestum oxide (0} Silicon dioxideWhich of the following describes potsssium bromide? (A) A actwork of covalently bonded ‘atoms (B) A substance which boils at 59°C and decomposes at high tempera- tures (A solié with a very high molar enthalpy of vaporization end, in 4 liquid state, does not conduct clectricity (D) — Anon-conducting solid which melts to form liquid that conducts alectricity ‘The equation for the reaction of magnesium with hydrochloric acid is, Mg(s)+ 24"(eq)—+ Me™ (aq) + H(8) “The molar volumeofa gasatet.p.=24¢dm? ‘The votume of gas produced when [.2.g0f Mag reacts at om termporature and pressure is (AY Lad (8) 24d (C) © 12.0dm" (D) 24.0 dee Which of the following is TRUE about 3 din’ of hydrogen and 5 den’ of oxygen at O°Gand 101 kPa? {A} They react to produces $ den! of water (B) They possess the same amount of kintic energy. (©) ‘They contain the sume eumber of molecul (2) ‘They eeact completely with eael ‘ter Ia the following redox reactions involving chromium compounds, whats thy oxidation ‘umber of chromium in EACH cpmpound? Naor ltt 0, > Necro, — CHO? andwater —-HS0, G0, | NaGo, Tle,0* @l 3 +6 +6 es a 6 © | +6 +6 @) +3 +6 =6 ‘When 86 g of the ionic salt, CeS(), 21,0, is heated co that all ofits water of crystallisation is drivenoff and 68.0g 0fCaSO, tema, the value of xis fat @ 2 © 3 © 4 HEV ENRCPEVCLILE NEWT OneM 2 13, a4. ‘Which ofthe following does NOT repsedent a balanced redox equation? () Zale) + 21a + Zac oop HK) B) — MaO>, (ag) + Ske (aq) + 8H 4 » Min (aq) SFe* (aa)+ 412,001) ©) $0) + B1,() + 28,00) + 44 aq)-+ $0 (0q) + 2Br(0q) (0) S9{6) + FINO, (eq) —+ $006) + NO, (2) + H,0(9 ‘Which of the following gases wilt bata MOST ideally? (A) Ammonia (8) Helium © Methane that proceeds in two stages? | — | nergy “ave : ‘Tine Sf “These CG) Energy GOON FO TENE Pate“ae “The second ionisation energy of calcium is 1150 XY mot. Which of the following equations represents this statement? kd mo * (A): Calg) Ca (+20 AH =+ 1150 B) CH@+ce*@+e — aH=+1450 © er@rcHr~@re — sn~1is0 ©) Ca ce@ere —-at=+1hs0 [em 15 refers tothe following standard enthalpy btcombsistion for carbon, hydrogen a Atif ks mor carbon 394 | Hydrogen -286 Octane 5476 : 15, The standard enthalpy of imation, AHS| of ogane is eslulated se “ @ © fen Hgin ta aeam 5416) mot! 8 (394) ~9( 286); $476 kJ mol (BD) AH (octane) ~ 8 (-394) -9(~- 286) +5476 kd mol! | | | | | | loctene,16, 1 ‘Tem 16 refers to the following graphs for the reaction between reactants P, Qand P+Q+R— Products Rate ate mr a Rae awe ae Te ‘The cate equation is A) Rate (8) Rat (HQ (POP (Rate te P}LQIRL (D) Rate =& (PHQP IRE Tine () __[(K{ (mol da) or) a0 30 at 109 ota 15.0 0.07 20.0 aso ow XY yields the following rate dh, {he oa tnd XL. Wl trons (A. 0.0308 (By 0.069 5 Oy 14,008" (D) odo GOONTO THE NEXTERGEem I8ireters to the diagrams below which shoy the Maxwell-Boltzmann distribution. t y a bo% ~ 1 + ” gl 4 i og ° q 4 1 & ‘ s oe 5 | a Poe ee > Rinctic enarey \ inet energy | Tt @) D) i i m 4 lig é he 5 hi j H Z z ‘nelc energy ' Riaetie omargy 18. Which of the disgrams above represents the effect bf an inerense én temperature (roe Tod: (ry ww sorcery? 19. Which orthe following sttement(s)about” —20.| | Which of the following slatemets dacs scatalyat i (are) true? | NOT refertoa aysten it dynamic Equity ri? 1. {increases the equilibrium coustant : i for the forward reaction only, (A) The reaction ig reversible. Ui Wiaereases the cquitiiam constant | (8) Theamnunty atu he sped athe for both the forward and backward | system goninin constant, reaetions (€) The eaneantentiocr af all datas UL Al hus no effeet on the positian of | nd products wre equal, | squirm | co) Theme ot the Yantai equal to tho ao of the behav fonly | rete ' (BU only | ©) Cand tt only (O} tage ly GOON TO THE NEXT RAGE24, 2, <8. Equilibrium is established inthe eactiod X (aq) +¥ (aq) ==> Z (aa). tt the sis concen- trations are [X]~ 02 mol dar, [¥}~= 03 mol dar? and [2] 0.6 mol dav, which of the value of the equilibrium constant K,? w 0.1 mol doa? i @) Oa mol" dim? © = 10.0 mol dar* ©) 100 mot daw \ Baking soda decomposes when heated acgording to the equation 2NGHCO, (6) = NaC, () + 10 (8) 1 following is + 00,09). If 100 g of baking soda is hested to 363 K, the total pressure of the gases is 55.23 KPL. Whatis the value of K, at 363 K? ! @ nos | B) 165.7 © 1626 ©) 3050 {pure ethanol, (C,H,08), the following NHJ + C.H,OH === NH, +C,H,0H,! Which of the following combinations descr Brénsted-Lowey theory? NH! Hon (AY Acid Base (B) Base Acid (©) Conjugete acid Base ) Acid Conjugate by ium cn exist with ‘ammonium ions, Hes the function of NH," and C,H,OM adzording to the fie GOON TO THE NEXT PAGE24, Whatis a suiteble indicator for the titration of 0.10 mol dur* acetic acid with 0.10 mol darlaqueo-us ammonia? . (A), Bromotaymol blue (pH reuge 6.0- 7.6) GB)" Metbyl orange (pErange 32-42) (©) Phonolpithslein (pH range &.2- 10.0) (D) There is no suitable indicator. 25, Whichofthe following graphs shows the change in pH wea 0.1 mol dar°HICl (a) is graduafly added 0:20 om of 0.1 mol dar? NaOH (ag)? | pe, w (od | “7 " or | J____, 5 s, ' ° a a i . Ei a Yotume of ack (om) | Volume of acid (om! | pa | pH, Mt i 14 7 On _—— rs ° 20 4 6 FA a ‘Volume of seid (em?) i Volume of weld (en26. 2. 28, 28, 30. “Which expression represents the solubility proiuct of irom(I) hydroxide? wa ® © tems 27-28 refer tothe following sets of opt strong scid against a strong base? weak acid against a strong base? Using standard electrode potenti, “ ®) © @) [em 30 refers fo the cell diagratn befow. znto| zat] x fou “ ®) © (b) aa sya ss || ate ee 4 | Soe Bromothymol blud 70 |) yellow > blue Phenolphthalein ° 5 |! colourless —> pink raise saagenianghiel sd I Which ofthe following will cause an increase 4 cell potential? -19- (Fe4 (OH-P . fe yORT [F(OH),] [Fe] BOH-P i \ Fey Bor] | Indicator pHof iy Colour Change ‘Zas) + Cu"(aq) + Za" (eq) + Cale) Zn(s) + PO(aq) —> Za%* (ag) + POLS) Pes) + Zn*(aq) —+ Pe?* (aq) +Zn(8) Cus) +Zn(aq) —+ Cu" (aq) + Zn(6) Increasing concentration of" tons only t following reactions would be MOBT feasible? Decreasing concentration of Zn**(aq) ions und increasing concentration of Cx*| (aq) fons Decreasing concentration of Cu¥ jons oly ‘Adding NaOH to Cu solution and increhsing the conoentration of Zn idns GOON TO THE NEX kageaL 32, 33. 34, oe Which ofthe following compounds conducts electricity? @) No ®) Sio, ©) 80, ©) 40, Which of the following Group Il elements . reacts yery slowly with cold water end buras with e bright white flame? A Barium @®)— Beryfliun © Magnesium ©) Stontium Which of the following reactions with the Group IV elements and concentrated bydro- chlorlo acid would NOT coct? 1 Ge + 2HC1 "> Geer, +H) I. Sa + 2HCl ——~ snci,t Hg) M1, Pb +28Cl ——> pec, +142) A Tony @®) “Monly © Wonly ©) Wand Monty Which’ pair of properties inoreases on descetiding the Group Il elements? Atomic radti ionisation energy Ii. Blectronegatvity 1%. Tonic radit (A) Land 1 only (8) Land TV only (© and tif only ©) tand {V only 35. Group I elements ofthe periodicltable Lave A) e) © © “high molting points but lbw den sity high clevtrical conductivity but low deasity Digh molting points bad igh Clectrieal conductivity Tow racking points §né poor clecrical conductivity Which of the following cbiprides of Group IV clements is the BEST) electricat conductor? Poct, ©) “sic, © acl, ©) ca, Tn which of the following eptiods are the halide ions placed in order of INCREASING reducing power? (A) Brcls i> ®t Brci- © ay Bryt ©) ChytsBr- When AgNO,(aq) is added to Austide ions followed by NH, (aq) the result is (A) @) © ©) ‘no precipitate white silver fluoride yellow silver fluoride reamcoloured ammonia Rutile39. 40, 4b fay ey © (0 Li. Items 39 - 40 refer tothe following options. 42, Ligand @ ©) Cetalyst © — Complex ©) — Coordination number Match each item below with one of thb ‘options above, each of which may be used once, more than once or nat ata. “The species conteining ions or moleoulet Linked tga ocatal atom by coordinate bond 43, “The species donating electron pai tt crate eam i Which dag seen the etctoid configuration of Cu"? ‘Note: [Ar] = 13%, 25%, 2p, 35%, 3p! i sa 4 tn [DEE ti) a] 1 i Mr} iti by tet 1 { 3a ds a, il tit! | 4 Tas. 3d i wor [ETL Le Cj An unknown sult soluijon containing « single anion is tested wit ead (0) nitrate sotution followed by dilule HNO, A hie precipitate is observed which dissolves in acid with effervesceace. ‘These observa. tions indicete the presencd of (A) COR and cr ®) S0Pand soe (©) 80> end Co~ @) $0 ,-and Cr Which of the following metals give s green flame whan heated? (A) Magnesia ©) Calcium ©) Sodiun ©) Copper tems 4 (A) Acenteat ion ina ©) Aligand (©) Anoctahedral cory owing options. ples plex (BD) Awtrahedtal complex Match each tem below fwith one of the options above, Each opt fatto" CHNE, 1 may be eel ‘anee, once ar mpl at al IP YOU FINISH BEFORE TIME IS CALLED, CHECK YOUR WORK. ON Tus Test, O21 12010/CAPE 2011 t