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Note:
1. Isotopes: Same atomic number, different mass number.
Note:
2
z
1. Energy of nth orbit : En = 13.6 ev
n
n2
2. Radius of nth orbit : rn 0.529 A
z
Group number
atomic number
Element symbol
Element name
Period
atomic weight (average)
Electronegativity
Ionization Enthalpy
Electron gain Enthalpy
Electronegativity atomic radius ses
Atomic Radius
ter
harac
c
llic
eta
ses
n- m
No
ses
Note: Ist transition series starts from the atomic number 21 [Sc]
Chemical Bonds:
Bonds
Thermal Fairly high Very high melting Modernately high Low melting
melting point, point, good melting po int, po int
thermal insulators thermal insulators good heat conductors
Examples Magnesia, calcite, Diamond, carborundum Sodium, iron copper Argon, paraffins
NaCl, CaCl 2 ice
Crystal Structure:
Solid
Note:
stacking faults
external faults
Grain boundaries
Tilt boundary
Twin boundary
Note:
1. A grain boundary is the imperfections that separate crystal or grains of different orientation in
polycrystalline aggregate during crystallization
3. When the mismatch in orientation between adjacent boundaries is small (<10), then it is
called as tilt boundaries.
4. If the atoms on one side of the boundary is mirror image of atoms on the other side of the
boundary then it is called as Twin boundary.
5. 3-dimensional (volume) defects:
associated with
Cracks
Pores
Foreign inclusions
6. Phase diagram:
1. If phase diagram is plotted between T and percentage composition keeping P = const. then,
F = C P + 1.
2. F 0 P c 1.
3. at triple point F 0
Note:
1. Monotetic Reaction:
L 2 solid
L1
2. Eutectic Reaction:
solid1 solid2
L
3. Eutectoid reaction:
solid2 solid3
solid1
4. Perictectic reaction:
L solid1 solid2
5. Peritectoid reaction:
solid1 solid2 New solid
Monotectic
Eutectic
Eutectoid
Peritectic
2. Fe Fe3 C has 5 individual phases.
(a) ferrite:
BCC structure
(b) ferrite:
BCC
FCC
Complex orthorhombic crystal structure having 12 iron atoms and 4 carbon atoms per
unit
Pearlite containing 0.8% C is known as eutectoid steel which makes steel more ductile.
A0 : This temperature line lies in the bottom section of iron carbide diagram that is the 210C
temperature line. Here cementite changes from ferromagnetic to paramagnetic in nature.
A1: It is the lower critical temperature. Here at 727C temperature austentine to pearlite Eutectoid
transformation takes place.
A2 : This indicates curie temp. that is 768C below which a ferrite is ferromagnetic in nature.
A3 : This indicates upper critical temp. below which ferrites start to form from austenite.
Acm: This indicates upper critical temperature below which cementite starts to form from austentine.
Heat Treatment
2. To improve machinability
(I) Annealing:
Purpose:
1000
900
A3 Acm
0.8
Purpose:
Purpose:
(1)
g
o lin Martensite
t co mp
Fas w te
@lo Martensite
Moderate
Bainite
Austenite Cooling [C in ferrite] Heat
Slo Treatment
w co @ high
ol in Pearlite
g
[87% ferrite temp Spheroidite
13% cementite]
(4) Spheroidizing:
This type of heat treatment produces comentite in the form of globulus particles (Spheroids)
from pearlite.
Purpose:
1. Good machnability
2. High ductility
3. Maximum softness
Note:
Purpose:
4. Decreased hardness.
5. Improve strength
6. Reduce brittleness
7. Increase wear resistence
900
A
A3
B
723
C
0.8 % wt of c
A = Normalising
B = Annealing (or) Hardening
D = Tempering
Case hardening
(a) Carburising:
(a) Pack carburising:
(d) Nitriding:
(500 600)C
(1) Work piece
NH atmosphere
hardest case on steel.
3
Work piece is heated in the mixture of ammonia and hydrocarbon to a temp. 850C for
210 hrs.
(II) Induction Hardening:
The heating effect is due to eddy currents flowing in the surface of work piece up to
austentic range.
Quenched immediately to form martensite.
D = 10 mm 0.0045 mm
P
VHN = 1.854
d2
Pm(spin)
M
(ii) = = r 1
H
Magnetic material:
m 1
r 0
(b) Paramagnetic material:
(i) at H = 0; M = 0
at H 0; M 0
(ii) m = +ve
r 1
C
(iii) It follows curie law: m =
T
(iv) Above curie temperature its M = 0.
(c) Ferromagnetic material:
(ii) Pm = Pm(spin)
(iii) at H = 0; Bresidual = 0M
(i) m = 0
(ii) 0 = 1
C
(iii) Follows neels law, m =
T N
Ex: Ferrites
Suitable for high frequency application.
Electric and magnetic characteristics of ferrites:
(v) Mechanically hard and brittle. (v) Low eddy current losses.
Types of ferrites:
Ex: Mn Zn ferrites
Ni Zn ferrites
Application: Core of inductors and transformers.
Ex: Mg Mn ferrites
Cu Mn ferrites
Longitudinal magnetastriction
Transverse magnetostriction
Volume magnetostriction
(2) Fe Ni alloy
45% Ni Permalloy
79% Ni Superalloy
Loss
79% Ni Mu metal
Charactristics:
(1) Carbon steel 98% Fe, 10% Mn, 0.37C ; Compass needle
23% Co
11% Ni
22% Co
8% Al
4% Cu
21% Ni
20% Co
9% Al
Magnetic Anisotropy:
If material is having direction dependent magnetic properties then material is said to be magnetically
anisotropy and this property of material is called anisotropy.
There are 3 methods to include magnetic anisotropy in a materials:
(I) Cold working: In this method, material is cooled down using cold rollers. This method induces
magnetic anisotropic in direction of rolling.
(II) Magnetic annealing: It is the process of heating and slow cooling in the presence of magnetic
field.
(III) Magnetic quenching: It is the process of heating and test cooling in the presence of magnetic
field. In this method, material is cooled down to curie temp. in order to induce anisotropy.
Conducting materials:
(1) J = E ; ohms law
ne2
= ; conductivity
m
ne e ; e mobility of [cm / vs]
1
(2) ; as T ; . [Metals shows PTC]
T
Constant
rr
T
QD
Debye temperature
H0
Super Normal
-conductor
T
TC
T 2
HC H0 1
TC
Silsbees rule:
The maximum current allowed is IC to retain super conductivity.
Type - I Type - II
(a) Ideal super conductor. and exhibits Non-ideal/ hard super conductor
diamagnetic nature at super
conductivity
(b) Critical field and transition temp. are Critical field and transition temp. are
low high
M M
Vortex region
Super
conducting Normal
Normal state
state
H H
HC HC1 HC2
Super conducting
state
r r
Vortex
Super
Super conducting Normal
conducting Normal state
state
H H
HC
Semiconductors:
Eq.:
(1) For semiconductor.
T = 0K T = 30K
Si 1.21 eV 1.1 eV
Semiconductor exhibits
NTC.
Ge 0.78 eV 0.72 eV
Note:
(i) Width of energy band depends on Temp.
(ii) Si is more sensitive to temp. variation as compared to Ge.
(2) For metals:
Both CB and VB overlaps.
(3) For insulater
EG 5eV @ T = 0K
Insulator
Intrinsic n < ni 2
P > ni @ equilibrium: np = n i
simiconductor
(B, Al, Ga, In, Tl)
Trivalent atom
ni Ge ni si
C.B. C.B.
EC EC
ED
EA
EV EV
V.B. V.B.
@ T = 0K @ T = 0K
(Insulator) (Insulator)
N-type semiconductor P-type semiconductor.
EC EC
ED
EA
EV EV
@ T = 300K @ T = 300K
(conductor) (conductor)
Note:
(1) Temperature coefficient of resistance of doped semiconductor may be +ve/ve depending
upon level of doping.
(2) When alloying is done for group IIIV elements, the crystalline structure is formed of the
type ZnS (Zinc blende).
Hall effect:
Used to find:
n-type / P-type
Carrier concentration
Conductivity
Mobility
2
2 2
+
VH
d
VH
+
1
w N-type/metal
1
1 Voltage mv v Ptype
B
Note: (1) VH = RH
W
ve ; P type
(2) RH =
ve ; N type, int rinsic semiconductor
The fermi level represents the energy state at which 50% probability of finding an electron
exist:
Note: (1) EF n2/3 ; n = number of free es/volume.
(2)
EC
EF = N-type
ED
EF = intrinsic
EA
EF = P-type
EV
A B A A B B A B A A
(2) Random copolymer :
A B A B A B A B A
(3) Alternate copolymer :
(4) Graft copolymer : A A A A A A A A
B B B
B
B B
Classification of polymer:
Characteristics of polymers:
(1) Low density
(2) Good corrosion resistance
(3) Good mould ability
(4) Economical
(5) Low mechanical properties
(6) Can be produced transparent or in different colours.
(7) Low coefficient of friction
(8) Poor tensile strength.
Classification of plastics:
(1) They have long chains of polymers They have long chains of polymers
which are not cross linked. which are cross linked.
(2) They become soft on heating. Once set or mould it does not
Hence they can be moulded on become soft on further heating
heating and under pressure. i.e., the cannot be remoulded
on heating
(3) They are used for making: They are used for hot temperature
(i) Buckets application such as:
(ii) Pipes (i) Utensil handle
(iii) Carry bags (ii) Body of socket and plug
(iv) Toilet goods (iii) Furniture
(v) toys (iv) Telephone body
(v) Automobile parts.