8/8/2014 Method for obtaining liquid humic fertilizer. RU patent 2263092.

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Method for obtaining liquid humic fertilizer.

RU patent 2263092.

Price Iron Ore Mining

sinoftm.com/

FIELD: agriculture, production of fertilizers.

SUBSTANCE: the present innovation deals with manufacturing ecologically pure

complex fertilizers out of humate-containing raw material. It includes the following
stages: preparing an aqueous suspension of humate-containing raw material, the
peat, also, suspension should be supplemented with a substance as the source of
plant's nutritive elements, then comes treatment of the mixture obtained with
alkaline agent while mixing, storing the suspension and separation of liquid phase.
As humate-containing raw material one should additionally apply biohumus and/or
sapropel, and/or defecated mud, or their mixture at any ratio, and as a substance -
the source of plant's nutritive elements - ash of residues after agricultural production
at the quantity to provide the content of potassium in ready-to-use fertilizer being
not less than 15 g/l, as for phosphorus - not less than 15 g/l. The method enables to
increase the content of humic acids and nutritive elements, simplify the process to
obtain the fertilizer and provide its microbiological safety.

EFFECT: higher efficiency of the obtained fertilizer.

1 cl, 9 ex

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IPC classes for russian patent Method for obtaining liquid humic fertilizer. RU patent
2263092. (RU 2263092):

C05F11/02 - from peat, brown coal, or similar vegetable deposits

Another patents in same IPC classes:
Peat processing method / 2259385
Method of wasteless processing of peat is accomplished by two-step heating
of peat to release gaseous and solid constituents. In the first step, peat is
dried to moisture content not higher than 15% using portionwise supply of
peat with 350-1050 g/s portions and heating to 1205C, while treating and
withdrawing flue gases. In the second step, solid residue is heated for 1-6 sec to 520-530
without access of oxygen. Resulting pyrolysis gas is condensed into liquid fuel.
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8/8/2014 Method for obtaining liquid humic fertilizer. RU patent 2263092.

Humus substance-base biopreparation / 2258687

Invention relates to soil ecology, namely, to producing agents based on natural
components used for elimination of technogenic pollutions of soils. The biopreparation
based on humus substances is prepared by mixing and milling turf, avian dung and alkali
with addition of water in disintegrating device. Turf, avian dung, alkali and water are taken
in the ratio, mas. p. p. = (15-20):(11-16):(0.3-0.6):(0.3-0.6), respectively. Mixing and
milling all components in disintegrating device can be carried out with addition of wood
saw-dust taken in the amount 3 mas. p. p. per 1 mas. p. of mixture of other components.
The biopreparation elicits the strongest reductive function with respect to heavy metal
oxides and can be used for improvement of soil ecology after technogenic emergency and
for prophylaxis aims for neutralization of oxides and enhancing the humus content in soils.
Invention can be used in carrying out measures for reducing pollution degree and toxicity
in forest, agricultural and other soils with recovery of biota.

Natural catalyst for agrocenosis ecological equilibrium / 2257365

Invention relates to the natural catalyst of ecological equilibrium of agrocenosis that
comprises the natural activating agent of soil formation prepared by mixing turf, solid
alkali and cellulolytic enzyme. Catalyst comprises additionally biologically active mixture of
triterpenic acids obtained from coniferous species trees and cellulose-containing substrate
in the ratio = 1:0.5:0.5, respectively. Product provides enhancing the productivity of
agricultural crops up to 25% by enhancing their resistance against diseases and different
unfavorable physical-climatic factors and to reduce ripening time by 15-20 days. Also, the
preparation intensifies formation of ecologically pure humus. Invention can be used in
manufacturing fertilizers, agents for plants protection and preparations reducing negative
results of technogenic effect on the nature.

Method for preparing complex microfertilizer and microfertilizer / 2255925

Method for preparing the complex microfertilizer involves stirring humin-containing
components with alkali an aqueous solution. Sodium (potassium) hydroxide an aqueous
solution is used as alkali. Method involves addition trace elements for plants nutrition to
the solution, among them copper sulfate and accessory substances - elements for mineral
nutrition, among them zinc sulfate or magnesium sulfate. Method involves additional using
manganese sulfate, polyvinyl alcohol as a sticking agent and Trilon B as a chelating agent.
Lignin is used as a humin-containing component that is added to alkali solution by
portions at constant stirring, brought about to boiling, converted to the state of stable
suspension and kept for 50-60 min. Then water is added, brought about to boiling and kept
for 20 min followed by mixing the suspension with solution of zinc sulfate, manganese
sulfate, ammonium molybdate, copper sulfate, cobalt sulfate, Trilon B in water heated to
50C. Stirring is carried out for 20 min followed by addition to microfertilizer organic
sticking agent as solution of polyvinyl alcohol in water heated preliminary to 70C being
polyvinyl alcohol is kept to the complete dissolving. Prepared microfertilizer comprises
polyvinyl alcohol as a sticking agent in 5% solution in the following ratio of components,
wt.-%: zinc sulfate, 0.44; copper sulfate, 0.05; cobalt sulfate, 0.02; manganese sulfate,
0.05; ammonium molybdate, 0.04; Trilon B, 1.0; sticking agent, 5.0; humic acids, 93.0.
Invention provides enhancing quality of microfertilizer, to reduce cost, to exclude evolving
harmful substances to the environment and to increase the yield of the ready product.
Invention can be used in manufacturing ecologically pure complex lignin-base
microfertilizers.

Method of manufacturing biological stimulator of growth and development

of plants from humus-containing substances / 2253641
Invention is intended for use in manufacture of plant growth stimulator and
liquid complex organomineral fertilizers from humus-containing substrates
comprising living soil microorganisms, in particular from vermicompost
(biohumus), zoocompost, other composts, brown coal, peat, and sapropel.
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8/8/2014 Method for obtaining liquid humic fertilizer. RU patent 2263092.

Method comprises preliminarily watering of humus-containing substances and subsequent

alkali extraction, separation of alkaline extract, and neutralization thereof. According to
invention, after preliminary watering of humus-containing substances and stirring, material
is subjected to microbiological fermentation for 3-24 h at 20-35C and continuous aeration
increasing biomass of soil microorganisms. Thereafter, suspension is settled to give
enriched aqueous extract. Extract is separated from humus-containing substance and
added to neutralized alkali extract of humus-containing precipitate. Alkali extraction is
effected with 0.02-0.23 N alkali solution at 60-100C and separated alkali extract is then
neutralized to pH 8.0-9.5. Resulting enriched aqueous extract is stirred and settled to
produce desired liquid product.

Method of "ideal"-peat substrate preparation / 2251542

The invention is dealt with peat industry, in particular, with production of nutrient
mediums on the basis of peat for growing of seedlings of forest cultures and garden
species and bushes with the closed root systems and a non-polluting vegetable production
in a glass-covered ground. The method of preparation of the peat substrate provides for
clearing of the peat raw material from large remains of wood and other impurities,
introduction of a bio-activator, commixing, fermentation, gauging, packing. In the capacity
of peat raw material a weakly decomposed high sphagnum peat or a mossy waste are used
and in the capacity of the bio-activator they use a nutrient yeast or a compost ferment in
amount of 0.9-1.1 kg per 1 m3 of peat with a density of 0.02-0.1 g / cm3. Fermentation is
conducted at the temperature of 10-36C and moistures of 50-60 %, and gauging after
fermentation - up to the particle size of no more than 24 mm. The method ensures
production of a product of a loose fibrous structure with the optimal hygroscopic
properties, optimal concentration of the nutrient substances and a low toxicity.

Method of producing humate-containing compounds from brown coal /

2249622
Weathered vitrinite brown coals from Baga-Nursk coal field having ash level
36-48% and moisture 20% are ground to granule size 0.5-0.9 mm. Resulting
powder us sulfurized for 6-8 h with 98% sulfuric acid at 60-80 and coal-to-
acid weight ratio from 1:3 to 2:3. Sulfurized coal is neutralized and treated
with 10-15% sodium hydroxide aqueous solution at weight ratio of alkali solution to initial
coal (10-15):1 to form water-soluble sodium sulfohumate, after which water-soluble
residual coal is separated by centrifugation. Centrifugate is mixed with 10-15% aqueous
hydrochloric acid at volume ratio (10-15):6 to form precipitate, which is allowed to settle
into compact form during 40-60 min. After decantation of liquid phase, solid residue is
partially dried at 40-60 until pasty mass is obtained.

Method for producing of humic fertilizer / 2248339

Method involves exposing peat suspension to electric current; preparing peat suspension
by mixing peat with solution of salts of weak acids of potassium, and/or sodium, and/or
ammonium in various ratios and combinations; placing into vessel equipped with N-pairs of
opposite-polarity electrodes; exposing liquid phase of suspension to electric current of
density sufficient to provide for alkaline reaction of cathodes and acidic reaction of anodes,
with current being supplied in the form of sequence of rectangular pulses of duration
sufficient for alteration of partial pressure of gases generated in suspension volume and
interval between pulses being sufficient for relaxing of said pressure; while acting upon
suspension with electric current, mixing suspension and continuously controlling pH value
of its liquid phase; stopping said action, when acidity reaches predetermined value;
separating suspension into liquid and solid products. Weak acid salts used are salts of
carbonic acid and phosphoric acid. Method allows mineral and organic peat components to
be more completely converted into mobile chemical compounds.

Brown coal fertilizer and a method for manufacture thereof / 2246470

Fertilizer contains brown coal with particle size 0.001 to 5 mm and additive, in particular
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8/8/2014 Method for obtaining liquid humic fertilizer. RU patent 2263092.

biological humus, at weight ratio 1:(0.001-0.05). Prior to be mixed with additive, brown
coal is ground to required particle size. Mixing is carried out until homogenous free flowing
product is obtained. Fertilizer can be used to raise fertility as product accessible for any
user from individual summer residents to large agricultural economies.

Method of isolating humus acids from sapropel / 2246469

Invention relates to isolation of humus acids (humin acids and fulvene acids) from natural-
origin humate-containing substances, in particular from sapropel, to use them in
manufacture of organomineral fertilizers, biologically active additives used in manufacture
of therapeutic preparations and pharmaceutical products. Method comprises treating wet
sapropel with potassium pyrophosphate solution and simultaneously affecting sapropel
with ultrasound with frequency 22-23 kHz and emission power 50-160 W/dm3 for at least
90 min. Weight ratio of wet sapropel to potassium pyrophosphate does not exceed 100:1.

Organomineral fertilizer manufacture method / 2243956

Method comprises mixing peat, household sewage sediments, manure, and marble filings
(0.5 to 10%) followed by composting in storage piles.

Method of isolating humus acids from sapropel / 2246469

Invention relates to isolation of humus acids (humin acids and fulvene acids) from natural-
origin humate-containing substances, in particular from sapropel, to use them in
manufacture of organomineral fertilizers, biologically active additives used in manufacture
of therapeutic preparations and pharmaceutical products. Method comprises treating wet
sapropel with potassium pyrophosphate solution and simultaneously affecting sapropel
with ultrasound with frequency 22-23 kHz and emission power 50-160 W/dm3 for at least
90 min. Weight ratio of wet sapropel to potassium pyrophosphate does not exceed 100:1.

Brown coal fertilizer and a method for manufacture thereof / 2246470

Fertilizer contains brown coal with particle size 0.001 to 5 mm and additive, in particular
biological humus, at weight ratio 1:(0.001-0.05). Prior to be mixed with additive, brown
coal is ground to required particle size. Mixing is carried out until homogenous free flowing
product is obtained. Fertilizer can be used to raise fertility as product accessible for any
user from individual summer residents to large agricultural economies.

Method for producing of humic fertilizer / 2248339

Method involves exposing peat suspension to electric current; preparing peat suspension
by mixing peat with solution of salts of weak acids of potassium, and/or sodium, and/or
ammonium in various ratios and combinations; placing into vessel equipped with N-pairs of
opposite-polarity electrodes; exposing liquid phase of suspension to electric current of
density sufficient to provide for alkaline reaction of cathodes and acidic reaction of anodes,
with current being supplied in the form of sequence of rectangular pulses of duration
sufficient for alteration of partial pressure of gases generated in suspension volume and
interval between pulses being sufficient for relaxing of said pressure; while acting upon
suspension with electric current, mixing suspension and continuously controlling pH value
of its liquid phase; stopping said action, when acidity reaches predetermined value;
separating suspension into liquid and solid products. Weak acid salts used are salts of
carbonic acid and phosphoric acid. Method allows mineral and organic peat components to
be more completely converted into mobile chemical compounds.

Method of producing humate-containing compounds from brown coal /

2249622
Weathered vitrinite brown coals from Baga-Nursk coal field having ash level
36-48% and moisture 20% are ground to granule size 0.5-0.9 mm. Resulting
powder us sulfurized for 6-8 h with 98% sulfuric acid at 60-80 and coal-to-
acid weight ratio from 1:3 to 2:3. Sulfurized coal is neutralized and treated
with 10-15% sodium hydroxide aqueous solution at weight ratio of alkali solution to initial

http://russianpatents.com/patent/226/2263092.html 4/6
8/8/2014 Method for obtaining liquid humic fertilizer. RU patent 2263092.

coal (10-15):1 to form water-soluble sodium sulfohumate, after which water-soluble

residual coal is separated by centrifugation. Centrifugate is mixed with 10-15% aqueous
hydrochloric acid at volume ratio (10-15):6 to form precipitate, which is allowed to settle
into compact form during 40-60 min. After decantation of liquid phase, solid residue is
partially dried at 40-60 until pasty mass is obtained.

Method of "ideal"-peat substrate preparation / 2251542

The invention is dealt with peat industry, in particular, with production of nutrient
mediums on the basis of peat for growing of seedlings of forest cultures and garden
species and bushes with the closed root systems and a non-polluting vegetable production
in a glass-covered ground. The method of preparation of the peat substrate provides for
clearing of the peat raw material from large remains of wood and other impurities,
introduction of a bio-activator, commixing, fermentation, gauging, packing. In the capacity
of peat raw material a weakly decomposed high sphagnum peat or a mossy waste are used
and in the capacity of the bio-activator they use a nutrient yeast or a compost ferment in
amount of 0.9-1.1 kg per 1 m3 of peat with a density of 0.02-0.1 g / cm3. Fermentation is
conducted at the temperature of 10-36C and moistures of 50-60 %, and gauging after
fermentation - up to the particle size of no more than 24 mm. The method ensures
production of a product of a loose fibrous structure with the optimal hygroscopic
properties, optimal concentration of the nutrient substances and a low toxicity.

Method of manufacturing biological stimulator of growth and development

of plants from humus-containing substances / 2253641
Invention is intended for use in manufacture of plant growth stimulator and
liquid complex organomineral fertilizers from humus-containing substrates
comprising living soil microorganisms, in particular from vermicompost
(biohumus), zoocompost, other composts, brown coal, peat, and sapropel.
Method comprises preliminarily watering of humus-containing substances and
subsequent alkali extraction, separation of alkaline extract, and neutralization thereof.
According to invention, after preliminary watering of humus-containing substances and
stirring, material is subjected to microbiological fermentation for 3-24 h at 20-35C and
continuous aeration increasing biomass of soil microorganisms. Thereafter, suspension is
settled to give enriched aqueous extract. Extract is separated from humus-containing
substance and added to neutralized alkali extract of humus-containing precipitate. Alkali
extraction is effected with 0.02-0.23 N alkali solution at 60-100C and separated alkali
extract is then neutralized to pH 8.0-9.5. Resulting enriched aqueous extract is stirred and
settled to produce desired liquid product.

Method for preparing complex microfertilizer and microfertilizer / 2255925

Method for preparing the complex microfertilizer involves stirring humin-containing
components with alkali an aqueous solution. Sodium (potassium) hydroxide an aqueous
solution is used as alkali. Method involves addition trace elements for plants nutrition to
the solution, among them copper sulfate and accessory substances - elements for mineral
nutrition, among them zinc sulfate or magnesium sulfate. Method involves additional using
manganese sulfate, polyvinyl alcohol as a sticking agent and Trilon B as a chelating agent.
Lignin is used as a humin-containing component that is added to alkali solution by
portions at constant stirring, brought about to boiling, converted to the state of stable
suspension and kept for 50-60 min. Then water is added, brought about to boiling and kept
for 20 min followed by mixing the suspension with solution of zinc sulfate, manganese
sulfate, ammonium molybdate, copper sulfate, cobalt sulfate, Trilon B in water heated to
50C. Stirring is carried out for 20 min followed by addition to microfertilizer organic
sticking agent as solution of polyvinyl alcohol in water heated preliminary to 70C being
polyvinyl alcohol is kept to the complete dissolving. Prepared microfertilizer comprises
polyvinyl alcohol as a sticking agent in 5% solution in the following ratio of components,
wt.-%: zinc sulfate, 0.44; copper sulfate, 0.05; cobalt sulfate, 0.02; manganese sulfate,
0.05; ammonium molybdate, 0.04; Trilon B, 1.0; sticking agent, 5.0; humic acids, 93.0.
http://russianpatents.com/patent/226/2263092.html 5/6
8/8/2014 Method for obtaining liquid humic fertilizer. RU patent 2263092.

Invention provides enhancing quality of microfertilizer, to reduce cost, to exclude evolving

harmful substances to the environment and to increase the yield of the ready product.
Invention can be used in manufacturing ecologically pure complex lignin-base
microfertilizers.

Natural catalyst for agrocenosis ecological equilibrium / 2257365

Invention relates to the natural catalyst of ecological equilibrium of agrocenosis that
comprises the natural activating agent of soil formation prepared by mixing turf, solid
alkali and cellulolytic enzyme. Catalyst comprises additionally biologically active mixture of
triterpenic acids obtained from coniferous species trees and cellulose-containing substrate
in the ratio = 1:0.5:0.5, respectively. Product provides enhancing the productivity of
agricultural crops up to 25% by enhancing their resistance against diseases and different
unfavorable physical-climatic factors and to reduce ripening time by 15-20 days. Also, the
preparation intensifies formation of ecologically pure humus. Invention can be used in
manufacturing fertilizers, agents for plants protection and preparations reducing negative
results of technogenic effect on the nature.

Humus substance-base biopreparation / 2258687

Invention relates to soil ecology, namely, to producing agents based on natural
components used for elimination of technogenic pollutions of soils. The biopreparation
based on humus substances is prepared by mixing and milling turf, avian dung and alkali
with addition of water in disintegrating device. Turf, avian dung, alkali and water are taken
in the ratio, mas. p. p. = (15-20):(11-16):(0.3-0.6):(0.3-0.6), respectively. Mixing and
milling all components in disintegrating device can be carried out with addition of wood
saw-dust taken in the amount 3 mas. p. p. per 1 mas. p. of mixture of other components.
The biopreparation elicits the strongest reductive function with respect to heavy metal
oxides and can be used for improvement of soil ecology after technogenic emergency and
for prophylaxis aims for neutralization of oxides and enhancing the humus content in soils.
Invention can be used in carrying out measures for reducing pollution degree and toxicity
in forest, agricultural and other soils with recovery of biota.

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