Beruflich Dokumente
Kultur Dokumente
1. 4
a)
b)
c)
d)
Ans: 2
i. The lesser the charge separation, the more stable the resonating structure. (I) and (III) have less charge separa
tion. But in (III),+ve charge is on electronegative N atom. Therefore, (I) is more stable than (III).
ii. (II) is more stable than (IV) because in (II) positive charge is on electropositive C atom and negative charge
Exp:
is on EN (electronegative) N atom, whereas in (IV) it is reversed.
Therefore, .
So, the stability order is :
An organic molecules has 5 bonds (heat of hydrogenation for bond is 28.8 kJ mol-1) and expe
2. 4
rimental value for heat of hydrogenation is 99 kJ mol-1. The resonance energy in kJ mol-1 is
a) 45
b) 90
c) 70
d) 140
Ans: 1
Exp:
Given compound is
a) 2 - Bromo - 3 - nitrobutanal
b) 1- Bromo -1 - formy 1 -2 - nitropropane
c) 3 - Nitro - 2 - bromobutanal
d) All are correct
Ans: 1
a)
b)
c)
d)
Ans: 4
6. 4
8. 4
a)
b)
c)
d)
Ans: 1
As more stable is carboxylate ion, more is acidic strength.
Exp:
9. 4
10. In which of the following molecules, all atoms are not coplanar? 4
a)
b)
c)
d)
Ans: 3
Exp:
Due to this sp3 hybridized C atom all the atoms in this molecule are not coplanar.
Exp:
Which of the following is true for compound (X)?
12. 4
Exp:
13. In which of the following compounds lone pair on nitrogen does not participate in resonance 4
a)
b)
c)
Exp:
Here lone pair in N-is not in congested with the p orbital of benzene ring
b)
c)
Exp:
This molecule does not have more than two congested & coplanar P orbital.
Ans: 3
a)
b)
c)
Exp:
d)
Ans: 2
-NO2, -CN, and -CHO has M effect
Exp:
-NH2 exhibits +M effect.
18. The most unlikely representation of resonance structure of p-nitro phenoxide ion is 4
a)
b)
c)
d)
Ans: 3
Exp:
19. Which of the following alkenes will show maximum number of hyper conjugation forms? 4
a)
b)
c)
d)
Ans: 1
More is the number, of , more is hyper conjugative structure.
Exp:
a)
b)
c)
d)
Ans: 2
Exp:
Due to I and R effect of NO2 C.B gets stabilization, Therefore option B, is the correct answer
21. 4
a) CH3
b) OCH3
c) NO2
d) Both 1' and 2'
Ans: 3
(X) is a carbocation any group which has electron donating nature stabilizes (X) and any group which has elect
Exp: ron withdrawing nature destabilized (X).
As NO2 has (-)I and R effect, It destabilizes (X).
22. 4
Exp:
23. 4
Exp:
l.p. on N- is in conjugation with the ring electron , therefore l.p. is al
so less available here but availability here is more than the previous case.
24. 4
a) II III I IV
b) I II IV III
c) IV III II I
d) III II I IV
Ans: 1
Exp: Is most acidic due to Ortho effect steric inhibition of resonance of the COOH is near.
Exp:
IUPAC name of
28. 4
29. 4
a) I and II
b) II and III
c) I and IV
d) I and III
Ans: 1
30. 4
Which of the following orders is correct for no bond resonance energy of there radicals.
a) II > III > I
b) I > III > II
c) III > II > I
d) II > I > III
Ans: 2
Stability of free radical increases with increasing no. of hyper conjugative structures.
(I) has 7 hyper conjugative structures.
Exp:
(II) has 3 hyper conjugative structures.
(III) has 4 hyper conjugative structures.