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The amount of product produced can be calculated by deducting the mass at different time
intervals by the original mass of the contents (CaCO2 + HCl). Then, the rate of reaction can
be calculated by using the following formula:
mount of Reactants Used Up
Rate of reaction = A
Time
After comparing the reaction rates of the different surface areas with Calcium Carbonate, it
would be evident how the amount of surface area can affect the reaction rate with solutions.
In previous scientific work, it has been seen that decreasing the particle size (or increasing
the surface area) of a solid reactant will increase the rate of reaction. Understanding the
relationship between the surface area and reaction rate is important; For example, in
industries, dusts such as wheat, sugar, flour, coal and pharmaceuticals can cause terrible
explosions. Fine particles like those have a very high surface area for their volumes. This
can be dangerous if there is plenty of oxygen around each particle, so if there is a spark
(enough activation energy), a massive number of combustion reactions can occur, which can
cause an explosion.
Hypothesis Bii
I predict that the larger the surface area of the calcium carbonate (i.e. the more finely
powdered) it is, the higher the rate of reaction will be. Conversely, the smaller the surface
area of the calcium carbonate (i.e. the larger the marble chip), the lower the rate of reaction
will be.
When a lump of Calcium Carbonate is chopped into smaller pieces or grounded into powder,
there are more surface particles. When there are more surface particles exposed, there will
be more particles for the other reactants to collide into, resulting in a higher chance of an
effective collisions taking place. However, if particles are trapped within the solid itself, they
cannot react with particles of the other reactant.
For example, consider a block of 8 cm x 8 cm x 2 cm. The exposed surface area is 4(8 x 2) +
2 (8 x 8) = 192 cm2. When the block is divided into 16 smaller pieces, the total surface area
will become 16 (6 x 2 x 2) = 384 cm2. This shows that there will be a larger surface area
when things are divided into smaller pieces, which also result in more surface particles for
reactant particles to collide to.
Therefore, increasing the surface area of a solid can increase the rate of reaction with the
other reactant.
Unit(s) of IV No unit
Dependent variable The dependent variable will be the change of mass of the
conical flask and its contents at regular time intervals (i.e. 20
seconds)
Unit(s) of DV Seconds
Unit(s) of DV No unit
Describe and explain The rate of reaction at any point of the experiment can be
the procedure to calculated by using the following equation:
calculate the derived
variable. Rate of Reaction
= Reactants used up
Time
(Reactants used up can be calculated by deducting the mass at
certain time interval by the initial mass of the reactants)
Chemicals:
- 5g of Calcium Carbonate in solid (large sized chips) form x 3 (CaCO3)
- 5g of Calcium Carbonate in solid (small sized chips) form x 3 (CaCO3)
- 5g of Calcium Carbonate in powdered form x 3 (CaCO3)
- 50 cm3 of Hydrochloric Acid (2 mol/dm-3) x 9
Method / ProcedureBiv
1. Collect all materials listed above. Put on your safety goggles and lab coat.
2. Put the conical flask on the electrical balance and press tear so it returns to 0g.
3. Measure 5g of large sized Calcium Carbonate chips in the conical flask using the
electric scale.
4. Measure 50 cm3 of Hydrochloric acid in one measuring cylinder.
5. Measure 50 cm3 of water in the other measuring cylinder.
6. Pour both the water and the Hydrochloric acid into the conical flask at the same time
and start the timer. Take down the initial mass.
7. Take down the mass of the reactants in 20 seconds time intervals.
8. Stop recording results after you have reached 400 seconds.
9. Repeat steps 1 to 7 for 2 more times.
10. Repeat steps 1 to 8 for medium sized Calcium Carbonate and powdered Calcium
Carbonate.
Results - Ci
Table 1: This table shows how large Calcium Carbonate chips affect the rate of reaction with
Hydrochloric acid.
Independent Variable 1: Large Calcium Carbonate Chips
Table 2: A table that shows how small Calcium Carbonate chips affect the reaction with
Hydrochloric acid.
Independent Variable 2: Small Calcium Carbonate Chips
Table 3: A table that shows how powdered Calcium Carbonate affect the reaction with
Hydrochloric acid.
Independent Variable 3: Powdered Calcium Carbonate
Qualitative Observations- Ci
When the calcium carbonate was put with the dilute hydrochloric acid, it creates a fizzing
sound, and bubbles evolved onto the surface of the liquids.The larger the surface area of the
calcium carbonate, the bigger the bubbles were, and vice versa. The reactants react to form
a white precipitate in a colourless solution.
Processed data- Ci
Table 1: A table that shows how the large calcium carbonate chips affects the average of the
rate of reaction with dilute hydrochloric acid at different time intervals.
Independent Variable 1: Large Calcium Carbonate Chips
0 105.17 105.17-105.17 0 0 0
0
0 105.49 105.49-105.49 0 0 0
0
Table 3: A table that shows how the powdered calcium carbonate affects the average of the
rate of reaction with dilute hydrochloric acid at different time intervals.
Independent Variable 3: Powdered Calcium Carbonate
0 105.21 105.21-105.21 0 0 0
0
From graph 1, comparing the reactants used up of large calcium carbonate chips and
powdered calcium carbonate, the graph line of powdered CaCO3 has a steeper gradient at
the beginning, which shows that its reaction is quicker. We can see for example that, at 120
seconds, the large calcium carbonate chips only used up 0.08g of its reactants, while the
small calcium carbonate chips used up 0.26g its reactants, and the powdered calcium
carbonate already used up 0.46g of its reactants. The reason why the large and small
CaCO3 chips dont reach a horizontal line at the end of the graph is because its reaction has
not ended by 400 seconds.
From this, the data was elaborated further. When comparing the rate of reaction of different
surface areas at a certain time, it can be seen that the largest surface area of CaCO3
(powdered) has the highest rate of reaction. For example, at 20 seconds, the large calcium
carbonate had a rate of reaction of 0.001, and the small chips and powdered calcium
carbonate had a rate of reaction of 0.003 and 0.006 respectively.
In order for a chemical reaction to occur, the reacting particles must collide. For an effective
collision to happen, there must be sufficient energy in the collision to break the chemical
ffective collision
bonds in the particles, or else the particles will bounce off each other. An e
is where collisions have enough energy to break up those chemical bonds.
Even though none of my other classmates have done a similar investigation, there have
been real scientific research done previously that is similar to mine. Even though the
experiment was not exactly the same, it can still prove my hypothesis and the validity of my
data. The experiment was to compare how the surface area of sodium thiosulphate affect
the speed of reaction with hydrochloric acid, and it proved my hypothesis as well as the
collision theory: When 20 g of sodium thiosulphate pellets took 60 seconds to react with 10 g
hydrochloric acid, while the same grams sodium thiosulphate powder only took 6.51 seconds
to react with hydrochloric acid. This proves that the increase of surface area speeds up the
reaction.
To conclude, I believe that my hypothesis was valid not only because of the experimental
data I have collected, but by looking through the results of other similar experiments to mine.
These scientific studies all support my hypothesis, which is why I am confident with the
validity of my hypothesis.
This is because when Calcium Carbonate and Hydrochloric Acid reacts, it produces carbon
dioxide, which is dense and quite a heavy gas. When the carbon dioxide is produced and
escaped from the reaction flask, it is easy to witness a the loss of mass in different time
intervals, compared with reactions that produce lighter gases, for example, hydrogen. In my
experiment. I could then deduct the mass at a certain time interval by the initial mass to find
out the amount of reactants used up, and therefore using that to calculate the rate of
reactions. Therefore, the method is valid to investigate the effect of surface area on the rate
of reaction.
However, the scales on different electric weights might differ, so an alternative method is by
finding the reactants produced using the gas collection methods. For example, using a gas
syringe to measure the amount of reactants produced. A gas syringe is connected from a
tube to a stopper on the conical flask. The hydrogen released in the experiment will pass
through the tube into the gas syringe, which has marks along its length. We can easily
measure the volume of hydrogen produced as the time increases by reading the markings
on the syringe, and therefore use the data to work out the rates of reaction.
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