Chemical Data Guide Book

U.S.
Department of
Homeland Security
United States
Coast Guard
Chemical Data Guide

for Bulk Shipment by Water
1990
CIM 16616.6A
U!illepartment Commandant ( G-MTH-1) MAILINC ADDRI!S$:
United States toast Guard
cl Transportotk>n Washington, DC 20593
llnhciSiales Phone: ( 202) 267-1577
Coast Guard
COMDINST M16616.6A
0 8 NOV 1990
COMMANDANT INSTRUCTION Ml6616.6A
Subj: Chemical Data Guide for Bulk Shipment By Water
1. PURPOSE. This manual has been prepared to assist Coast

Guard personnel and others involved in bulk chemical
shipment by water.
2. DIRECTIVES AFFECTED. The Chemical Data Guide for Bulk

Shipment by Water, dated January 28, 1982, is cancelled.
3. CHANGE. Recommendations, comments, additional data and

suggestions for improving this guide are requested by the
Commandant (G-MTH-1).
~~
Rear Admiral, U.S. Coast Guard
Chief, Office of Harine Safety,
Security and Environmental Protection
DISn..lllmON SDL No. 12 9
A 1 1
a b c d
1
f h
1
I j
1
k I
1
m n 0 p q
' s t u
1
v w , Iv
'
8 8 20 5 1 2 2 5 1 5 1 1 4
c 1 1 1 10 1 5 10 1 1 1
D 1 3 1 1 1 1 1 1 1 1 1 1 1
E 1 1 1
F
G
H
NON.STA.NOA.FlO 01STFl1BUT1QJ\I
B:c MLCs (6 extra); CG-21
For sale by the Superintendent of Documentll, U.S. Govemment Printing Office

Wuhington, D.C. 20<102
CHEMICAL DATA GUIDE
FOR
BULK SWPMENT BY WATER
Table of Contents
Commandant Instruction MI6616.6A ................................................. .

Table of Contents ...... ..... .... ..... ..... .......... ........ ..... ......... ..... ..... ......... ...... iii
Preface to the Seventh Edition ............................ .................. .......... .... v
Introduction .. ............................ .............. ..... ...................... .................... vii
Explanation of Data ............. .................. .... ................. ..... ......... .... ........ viii
Chemical Hazards Response Information System (CHRIS) ............. xviii
National Response Center (NRC)........................................................ xxi
Ouide Sheet............................................................................................ I
Data Sheets .......... ......... ..... .... ......... .... .... ..... ........ .... ..... ..... ......... .... ..... .. 2
Synonym Index...................................................................................... 313
Appendixes:
A. Compatibility Information, 46 CFR !50-Subpart A......... 360

B. Medical Kit Information-Cyanide-like cargoes;
Carcinogens listed in the Ouide ................ .... .... ................ 408
C. List of Oils-Appendix I, MARPOL 73/78;
Composition of Common Petroleum Products................ 410
D. Conversion Factors................................................................ 412
E. Temperature Conversion ....................................................... 417
The information in this book was collected from various sources
believed to be reliable. However, the Coast Ouard makes no claim that
these data are either correct or sufficient and assumes rio liability for
any consequences arising from their use.
The courses of action described in this guide are meant as sugges-
tions only. This guide carries no force of law or regulation except for
46CFR 150.
iii
PREFACE TO THE SEVENTH EDITION
The first edition of this Guide was issued on I June 1965. It con-
tained data on 127 cargoes. This edition contains data on over 300 car-
goes. A number of new cargo data sheets have been added, and several
obsolete cargo data sheets have been dropped.
Most of the data for the new cargoes were obtained from complet-
ed CG-4355 forms. This form, Characteristics of Liquid Chemicals Pro-
posed for Bulk Water Movement, or the International Maritime Organi-
zation's equivalent form, BCH/Circ.26, Characteristics of Liquid
Chemicals Proposed for Marine Transport in Bulk, or other equivalent
data source is required prior to the classification of a bulk cargo.
On 6 April 1987, Annex II of the 1978 Protocol to the Internation-
al Convention for the Prevention of Pollution from Ships, 1973
(MARPOL 73/78) came into force. This Convention controls oper-
ational discharges from chemical tankers and provides additional pro-
tection from accidental spills. With the advent of the MARPOL Con-
vention, carriage requirements for chemical cargoes are now deter-
mined by evaluation of both their safety and pollution characteristics.
This edition of the Guide includes the International Maritime Organiza-
tion (IMO) Pollution Category, and for domestic carriage, the U.S. En-
vironmental Protection Agency (EPA) Category.
All data have been updated where new data were available includ-
ing the Threshold Limit Values (TLVs) adopted in the 1989-1990 edi-
tion by the American Conference of Governmental Industrial Hygien-
ists (ACGJH). Included with this edition for the first time are the Per-
missible Exposure Limits (PELs) adopted by the U.S. Occupational
Safety and Health Administration (OSHA) in Table Z-1-A, 29 CFR
1910.1000.
v
INTRODUCTION
The U.S. Coast Guard is vitally concerned with safety at sea. In

the interest of safety, the Coast Guard reviews all chemicals proposed
for bulk shipment by water. All cargoes classified as dangerous are reg-
ulated.
The number and variety of unconventional liquid cargoes being
transported in bulk by water continues to steadily increase. Although
the transportation hazards of common petroleum products are generally
well understood, newer commodities often have unusual fire and explo-
sive properties such as wide flammable range, low ignition temperature
and foam incompatibility in addition to other hazards such as toxicity
and'dangerous reactivity. It became increasingly evident that a conven-
ient reference guide listing properties and emergency procedures for
bulk liquid cargoes was needed by Coast Guard personnel concerned
with the various aspects of safe transportation (marine inspection, port
safety and security, marine environmental response and rescue coordi-
nation) and by civilian personnel with similar safety interests. The result
of these concerns was this Chemical Data Guide.
This manual was prepared by the Marine Technical and Hazardous
Materials Division staff at Headquarters in connection with the regula-
tions governing bulk chemical transportation. The data in this guide
were compiled from a number of sources. Too often contradictory data
were found, and for many commodities desired data were simply non-
existant. However, as additional data become available, appropriate cor-
rections and additions will be made to update and continuously im-
prove this guide.
Although this Chemical Data Guide is intended to be helpful in the
initial stages of emergencies and casualties, users should seek more de-
tailed, specific and competent emergency medical services as soon as
possible.
This Chemical Data Guide was developed in the interest of safe
water movement of bulk chemicals. Hopefully, by providing key chem-
ical information in an easy to use form, this guide can help prevent or
at least minimize the harmful effects of chemical accidents on the
waterways.
vii
EXPLANATION OF DATA
Format
Data sheets are arranged alphabetically by the most commonly
used chemical name. Following the data pages is a synonym index
which shows other names for the products.
A standard form is used for each product to permit rapid reference
and to group data in a logical manner. General information on identifi
cation and physical properties is given at the top of the page. Data per
taining to the three basic types of hazard (tire, health and reactivity)
are given in separate blocks below. Suggested action in the event of a
spill or leak is given in the bottom block. Regulatory classifications are
included in the top section, while special information is given at the
bottom of the page under "Remarks."
This book will be used by personnel with varying degrees of
chemical training and experience. For this reason, non-technical terms
are used whenever possible.
The guide sheet preceding the data sheets is intended to help inter-
pret and identify the information on the data sheets.
Explanation of Terms
Synonyms:
Alternate and common names are listed. In general, proprietary
and trade names are not used.
Formula:
The constituent elements and a simplified structural formula are
shown.
Appearance-Odor:
A brief descriptive statement of these properties is given.
Specific Gravity:
This is the ratio of the weight of a volume of the cargo to the
weight of an equal volume of water. In the case of liquids of lim
ited solubility, the specific gravity will predict whether the prod-
uct will sink or float on water; for example, if the specific gravi-
ty is greater than I, the product will sink, and if the specific
gravity is less than I, the product will float.
viii
Chemical Family:
This is a general chemical category which facilitates the use of
the compatibility chart for predicting the type of reactions
which can be expected.
Pollution Category ... USEPA IMO _ __
In the blanks are indicated the category assigned by the U.S. En-
vironmental Protection Agency (USEPA), for domestic user in-
formation, and the Noxious Liquid Substance (NLS) Pollution
Category (Pol. Cat.) assigned by the International Maritime Or-
ganization (IMO) for international shipment on oceangoing ves-
sels.
USEPA
X, A, B, C, D-Category associated with reportable quantities
of I, 10, 100, 1,000, and 5,000 pounds, respectively. See 40 CPR
Table 302.4-List of Hazardous Substances and Reportable
Quantities.
IMO
A, B, C, D-NLS Category of Annex II of MARPOL 73/78.
III-Appendix III of Annex II (non-NLS cargoes) of MARPOL
73/78.
!-Considered an oil under Annex I of MARPOL 73/78. See
page 410 of the Data Guide for the complete list.
#-No determination of NLS status. For shipping on oceango-
ing vessels, see 46 CPR 153.900(c).
@-The NLS category has been assigned by the U.S. Coast
Guard, in absence of one assigned by the IMO. The category is
based upon a GESAMP Hazard Profile or by analogy to a close-
ly related product having an NLS assigned.
"gas"-The IMO generally does not assign Pol. Cats to gases as
these cargoes present little to no hazard to the aquatic environ-
ment.
Applicable Bulk Regulation 46 CPR Subchapter _ _ _ __
In the blank is indicated the CPR reference for the carriage of
the commodity.
United Nations Number;
The number assigned to a particular cargo by the United
Nations.
CHRIS Code:
The three letter designation assigned to every entry in the
Chemical Hazard Response Information System.
ix
Boiling Point:
The temperature at which the liquid boils, given in c and F at
a pressure of 76lJ mm Hg, one atmosphere or 14.7 psia. Thus, the
boiling point is the temperature at which the vapor pressure is
76lJ mm Hg, one atmosphere or 14.7 psia
Freezing Point:
The temperature in c and in F at which the liquid solidifies.
Vapor Pressure:
The equilibrium pressure of the saturated vapor above the liquid,
measured in millimeters of mercury (76lJ mm Hg = 14.7 psia) at
20"C (68.F) unless another temperature is specified. Conversion
is done as follows:
psi = mm Hg x 14.7
76lJ
Reid Vapor Pressure:
Equilibrium pressure exerted by vapor over the liquid at 100F,
expressed as pounds per square inch absolute (pisa), defined in 46
CFR 30.10-59.
Vapor Density:
This is actually a specific gravity rather than a true density be-
cause it equals the ratio of the weight of a vapor or gas (with no
air present) compared to the weight of an equal volume of air at
the same temperature and pressure. Values less than I indicate
that the vapor or gas tends to rise and values greater than I indi-
cate that it tends to settle. However, temperature effects must be
considered. For example, although methane at 68F has a vapor
density of 0.55, it becomes denser at lower temperatures. At
-259F, the boiling point, the vapor is heavier than air. Vapors
from an open container of boiling methane fall rather than rise.
Solubility in Water:
The following terms are used to describe the solubility of the
product by weight in cold water:
Negligible less than 0.1%
Slight 0.1%-1%
Moderate 1%-10%
The % by weight will be given when the solubility is of particu-

lar importance; for example, a highly toxic material which is
only slightly soluble.
X
Fire & Explosion Hazard Data
Grade:
The classification assigned by the Coast Guard to flammable or
combustible liquids is defined as follows:
Grade A Flammable liquid with a Reid vapor pressure of 14
pounds per square inch absolute (psia) or more.
Grade B Flammable liquid with a Reid vapor pressure of more
than 8 '12 psia but less than 14 psia.
Grade C Flammable liquid with a Reid vapor pressure of 8 '12
psia or less and a flash point of 8op or below.
Grade D Combustible liquid with a flash point above 80F, but
below I5oF.
Grade E Combustible liquid with a flash point of !Sop or
above.
Electrical Group:
The electrical group is based on the explosive characteristics of
air mixtures of gases or vapors. The 1986 edition of Manual for
Classification of Gases, Vapors, and Dusts for Electrical Equip-
ment in Hazardous (Classified) Locations, NFPA 497M, or the
1982 edition of Classification of Gases, Liquids, and Volatile
Solids Relative to Explosion-Proof Electrical Equipment,
NMAB 353-5. These publications provide details and list the
chemicals by Group. (Both publications were current as of press
time of the Data Guide.)
Flash Point:
The lowest temperature at which the vapors of a liquid may be
ignited momentarily. Values given in the data sheets are open
cup except where designated "(cc)," which indicates the closed
cup value. In general the open cup value is about 10 to 15p
higher than the closed cup value.
Flammable Limits:
The range of gas or vapor concentrations (percent by volume in
air) which will burn or explode if an ignition source is present.
Limiting concentrations are commonly called the "lower explo-
sive limit" (LEL) and the "upper explosive limit" (UEL). Below
the LEL the mixture is too lean to burn, and above the UEL it
is too rich to burn.
xi
Autoignition Temperature:
The minimum temperature required to ignite gas or vapor with-
out a spark or flame being present. Values given are only ap-
proximate and may change substantially with changes in geome-
try, gas, or vapor concentrations, presence of catalysts, or other
factors.
Extinguishing Media:
A list of firefighting materials suitable for use on the burning ma-
terial. For certain specific chemicals special formulations are
available for extinguishing fires in addition to the standard
agents. No mention of these can be made here because of the
large number of such media available under various trade names.
The flreflghting agents listed here are as follows:
Water fog-a finely divided mist produced by either a high or
low velocity fog nozzle. It is used for knocking down
flames and cooling hot surfaces.
Water foam-either mechanical or chemical, produced by a
special foam nozzle or by a fixed system. It is used to
form a blanket over the surface of burning liquids. It
is effective only with liquids which are not apprecia-
bly soluble in water.
Alcohol foam-this material blankets fires in the same manner
as conventional foam, but is intended for use with liq-
uids which are soluble in water, such as alcohol and
acetone. It must be applied more carefully than regu-
lar foam because the mechanical strength of the bub-
bles is less.
CO,-Carbon dioxide gas stored in cylinders. It may be ap-
plied through a fixed or semi-fixed system, or from a
portable extinguisher. It is useful for inerting a com-
partment or for putting out small local fires.
Dry chemical-Sodium or potassium bicarbonate or monosodi-
um phosphate powder, usually available from a semi-
fixed or portable extinguisher.
In case of a large-scale chemical fire aboard a vessel, it is proba

ble that water wiii be the medium used because of its availabil-
ity. Other agents may by more effective, but their supply is nec-
essarily limited. During such a tire, water should also be used to
cool tanks of chemicals which are not burning in order to pre-
vent explosion or tank rupture. The only case in which water
would not be used is that of a burning chemical which reacts
xii
violently with water. Precautions should always be observed be-
cause of the hazardous properties of many cargoes in a fire. Ex-
amples include the formation of toxic combustion products, the
reactivity with extinguishing media and the need for protective
clothing and breathing apparatus.
General Fire Fighting Procedures:
For flammable liquids and volatile solids having flash points be-
tween approximately 100' and 212'F, water fog may be used.
For liquids with flash points below IOO'F, water may not extin-
guish, but possibly will control the fire.
Flammable liquids having specific gravities greater than that of

water (sp.gr. = 1), and not water soluble, may be extinguished
by gentle application of water to blanket the surface.
For flammable liquids with flash points above 212'F, and also
for some very viscous materials, the use of water may cause
frothing of the burning liquid. Water spray, if carefully applied,
however, may be effective.
Generally, foam is a good extinguishing agent for fires in flam-

mable liquids, except for those that are more than slightly solu-
ble in water. These require the use of "alcohol" foam.
Health Hazard Data
Health Hazard Data Ratings are given in the same consecutive
order as those given in columns II, III and IV of Table II of the Na-
tional Academy of Sciences (NAS) Publication 1465 (1973 Revision).
The first rating deals with the hazard presented by "irritating
vapors" to the skin or to the mucous membranes of the eyes, nose,
throat, and lungs. These ratings have the following meanings:
0 Chemicals that are nonvolatile, or the vapors from which are
nonirritating to the eyes and throat.
Chemicals that cause a slight smarting of the eyes or respiratory

system if present in high concentrations. This effect is tempo-
rary.
2 Chemical vapors that cause moderate irritation, such that
personnel will find high concentrations unpleasant. The effect is
temporary.
xiii
3 Moderately irritating volatile chemicals, such that personnel will
not usually tolerate moderate or high vapor concentrations.
4 Severe eye or throat irritants, vapors are capable of causing eye
or lung injury, and cannot be tolerated even at low concentra-
tions.
The second rating deals with the hazard of "irritation from liquids
or solids" with regard to a chemical's tendency to burn or irritate
human skin from contact. Ratings have the following meanings:
0 No appreciable hazard. These chemicals are practically harmless
to the skin. Included are certain very volatile compounds that
evaporate quickly from the skin.
Minimum hazard. Usually includes chemicals which, if spilled on
clothing and allowed to remain, will cause smarting and redden-
ing of the skin.
2 Chemicals that cause smarting of the skin and first-degree burns
on long exposure.
3 Fairly severe skin irritants, usually causing pain and second-
degree burns after a few minutes' contact.
4 Severe skin irritants, causing second and third-degree burns on
short contact and very injurious to the eyes.
The third rating deals with the hazard presented due to "chemical
poisons" entering the body through inhalation, oral ingestion, or skin
penetration causing bodily harm. Ratings have the following meanings:
0 No likelihood of producing injury.
Minimum hazard. Includes most chemicals having threshold
limits above 500 ppm.
2 Some hazard, typically having threshold limits of 100 to 500
ppm.
3 Moderately hazardous chemicals.
4 Severely hazardous chemicals usually having threshold limits

below 10 ppm.
NAS Publication 1465 (1973 Revision) may be consulted for more
detailed information on the guidelines employed in rating each class of
hazard. This publication may be obtained as AD 775756:
xiv
National Technical Information Service (NTIS)
Telephone: 703-487-4600
U.S. Department of Commerce
5285 Port Royal Road
Springfield, VA 22161
Odor Threshold:
The smallest concentration, expressed in parts per million (ppm)
by volume in air that can be detected by smell by most people.
This is not an absolute value. It will vary among individuals and
will vary from day to day for any one person. The odor of a
potentially dangerous vapor may be hidden by another odor. In
addition, certain vapors are likely to produce olfactory fatigue,
which is deadening of the sense of smell. For these reasons, the
sense of smell alone is not a reliable indicator of the presence or
absence of a dangerous vapor.
Permissible Exposure Limits (PEL); Threshold Limit Val. (TLV):
The Permissible Exposure Limit and the Threshold Limit Value
refer to an airborne concentration of a product expressed in parts
per million (ppm) by volume in air. These are the Time-Weight-
ed Average (TWA) concentrations believed to be safe for the
average person during an 8-hour workday and 40-hour work-
week for prolonged periods. The susceptibility of individuals will
vary.
The values listed are those assigned by the Occupational Safety

and Health Administration (OSHA) in Title 29 of the Code of
Federal Regulations Part 1910.1000, et. al. (29 CFR 1910.1000),
and those accepted by the American Conference of Governmen-
tal Industrial Hygienists (ACGIH) as published in Threshold
Limit Values and Biological Exposure Indices for 1989-1990. In all
cases, these values should NOT be used to compare the relative
toxicities of different materials.
The equilibrium concentration of a gas which can be produced

by a liquid can be calculated as follows:
cone. (ppm) = vapor pressure in mm Hg X 1300.
"Skin" -the notation used to indicate that the product can be ab-
sorbed through the skin, including mucous membranes and eyes.
Prevent or reduce exposure to the extent necessary in the cir-
XV
cumstances through the use of gloves, coveralls, goggles, or
other appropriate personal protective equipment, engineering
controls or work practices.
Short Exposure Tolerance:
Vapor concentration, expressed as parts per million (ppm) by
volume in air, which should not be exceeded for the exposure
times specified. Other exposure information obtained from
sources believed to be reliable is included. In many cases little or
no data on human exposure are available.
Exposure Procedures:
First aid procedures recommended by manufacturers and safety
organizations. These are emergency procedures only. The victim
should be examined by a physician as soon as possible.
Poisons:
Some products are classified for regulatory purposes as poison-
ous liquids. Definitions are given in 49 CFR Part 173, Subpart
D.
Reactivity Data
Stability:
The susceptibility of the products to dangerous reactions when
exposed to conditions such as high temperature and shock.
Compatibility:
Structural materials compatible with the cargo are listed; also,
structural materials, contaminants and other cargoes which react
dangerously with the commodity are given. This list is by no
means complete or all inclusive. In some cases a very small
quantity of material can act as a catalyst and produce violent re-
actions such as polymerization, dissociation and condensation.
These catalysts, when known, are also listed.
The accidental mixing of one chemical group with another
can in some cases be expected to result in a vigorous and hazard
ous chemical reaction. The generation of toxic gases, the heating,
overflow, and rupture of cargo tanks, and fire explosion are pos-
sible consequences of such reactions.
The purpose of the Compatibility Chart, which is fully ex-
plained the 46 CFR 150 is to show chemical combinations be-
lieved to be dangerously reactive in the case of accidental
mixing.
xvi
Spill or Leak
The information given is intended to be used only as a guide.
Many factors must be considered before deciding on a course of action
in a particular case.
Remarks
Some special regulations which apply are listed. Other information
of particular importance is also listed.
xvii
CHRIS
CHEMICAL HAZARDS RESPONSE INFORMATION SYSTEM
The Chemical Hazards Response Information System (CHRIS) is

an official publication of the U.S. Coast Guard. It consists of the fol-
lowing manuals:
MANUAL I COMDTINST Ml6465.11A A CONDENSED GUIDE
TO CHEMICAL HAZARDS
Intended for use by response personnel who may be the first to
arrive at the site of an accidental discharge or fire to assess the
I dangers and consider the appropriate large-scale response neces-
sary to safeguard life and property (contains 1100 chemicals).
MANUAL 2 COMDTINST Ml6465.12A HAZARDOUS CHEMICAL
DATA
This manual is the cornerstone of CHRIS. It lists the specific
chemical, physical and biological data for about 1100 chemicals
needed for the preparation and use of other components of the
system. It is intended for use primarily by the On-Scene Coordi-
nator (OSC) and by regional and National Response Centers for
devising, evaluating and carrying out response plans.
NOTE: Coast Guard offices can obtain CHRIS manuals at no cost
through the directives system. All others must purchase the manuals
from the Government Printing Office. Please confirm availability and
price with GPO before placing your order. (Use order numbers to iden-
tify Manuals to GPO).
ORDER FROM: Superintendent Of Documents
Government Printing Office
Washington, DC. 20402
(202) 783-3238
ADDITIONAL INFORMATION: Commandant (G-MER-2)
U.S. Coast Guard
2100 2nd Street, S.W.
Washington, DC. 20593-0001
(202) 267-0440
xviii
MANUAL I COMDTINST M16465.11A A CONDENSED GUIDE
TO CHEMICAL HAZARDS
CONTENTS order number: 050-012-00224-0
BINDER order number: 050-012-00151-1
MANUAL 2 COMDTINST M16465.12A HAZARDOUS CHEMICAL
DATA
CONTENTS order number: 050-012-00215-1
xix
NATIONAL RESPONSE CENTER
LOCATION
U.S. Coast Guard Headquarters, Washington, D.C. 20593.
HOURS OF OPERATION
24 hours a day: 7 days a week.
PERSONNEL
Staffed by Coast Guard Officers trained in the methods and pro-
cedures of Pollution Response.
FUNCTION
To received notification of actural or potential oil hazardous
chemical incidents and relay these reports to proper authorities
for response actions.
CAPABILITIES
A toll free number (800-424-8802) for receiving reports of pollu-
tion incidents within the Continentia! U.S. from any phone in the
Continentia! U.S. (In Washington, D.C. area call (202) 426-
2675.)
Continuously manned Communications Center.

Access to environmental and safety information on chemicals.
Contact points with other Government Agencies for access to

response to pollution emergencies.
xxi
Chemical Dele Sheets
MOST COMMONLY USED CHEMICAL NAME
Syrtoayms-Other chemical names by which known United Natiollll Number ...
CHRIS Code.
Formula-Simplified structural formula

Boiling Point , ... at 14.7 psi _ _ _ c
c -
c
- -'F
---
....
Specific Graity-Wat6f= 1.0
Chemical Family-
Free~lng Point ..
Vapor Pressure 20"C (68"F) (mmHg) ..

c ===F
Reid Vapor Preuure (p~~ia).
Vapor Preuure 4li"C tl15"F) (p~Jia) ..
Pollution Catqory-USEPA - - - JMO - - - Vapor Density CAir = 1.0).,.
Applicable Bulk Reg. 46 CFR Subchapter . Solubility In Water ..
FIRE & EXPLOSION HAZARD DATA

Grade-The classificatiOn assigned to liquids which bum, as shown in 46 CFA 30.10-15 and 46 CFA 30.10-22.
Eleetrical Group-Assigned by Electrical Hazards Panel; NA means "not applicable" if the nash point is above
150"F
GeneraJ-Unusual fire or explosion hazards and/or special conditions governing the hazard will be mentioned
here.
Flash Point CFJ .. Open cup unless otherwise noted.

Flammable Limits .. LELand UEL.
Autoipltlon Temp. ("F) ... The temperature at which the vapor will catch fire.
Extinpisbin1 Agents Suitable agents are listed.
Special Fire Procedures .... If water is unsuitable or dangerous to use, or if special protective equipment is
needed, mention will be made here
HEALTH HAZARD DATA

Health Hazard Ratlnp Odor Threshold (ppm) PEL!TW A (ppml TLV!TWA (ppnll
Gi!nerai-General and specific statements about the hazards to health from exposure to the chemrcal.
Symptoms-The most common sensations felt by the appearance of a person exposed to the product.
Short Exposure Tolerance-The vapor concentration and exposure times known or reported to cause effects in
human beings will be given if available.
Exposure Procedur-First aid measures to be taken immediately. THIS DOES NOT REPLACE MEDICAL
ATIENTION BY A PHYSICIAN! Any time a person has experienced respiratory distress or has come into
contact with a corrosive or blistering agent, proper medical attention must be given.
REACfiVITY DATA
StahilitY-The stability of the product and its likelihood of undergoing dangerous reactions under special
conditions
Compatibility-Material: In general, the substances with which the product could react dangerously. This
includes materials of construction, impurities and other cargoes.
Cargo: The group number assigned by the compatibility chart is indicated here.
SPILL OR LEAK PROCEDURE

Description of the immediate steps to be taken should the material be released into the air, onto the vessel's
structure or into the water '
If 1plll oceuu, WI the Nati011al RtsponM Center, 100-424-8802.
Remarks: Any specral factors and/or quahfyrng rnformatlon wrll be mentroned here.
760 mm = 14.7 psi KEY NOTES
V. Low= Very low > = Greater than
V. High = Very high < = Less than
NP = Not pertinent - = Approximate(ly)
ACETALDEHYDE
Synonyms- Acetic aldehyde, Aldehyde; Ethanal; Ethyl United Nations Number.
aldehyde
CHRIS Code
Formula-CH,CHO
Appearance-Odor-Colorless hqu1d; pungent suffocat1ng

Boiling Point ..
c ___ .,
______21'C _____l2"F
odor; lru1ty odor when diluted.

S~ific Gravity-0 78
Fn>ezing Point ..
c .,
-121"C ----=..!ll"F
Vapor Pressure 200C (68'F) (mmHgJ. _I&_

Chemical Famil) -Aldehyde Reid Vapor Pressure (psia) ... --ZlL
Vapor_ Preuure 46'C (115"FJ (psia) __]JL_
Pollution Catet~ur~-l'SJ-:PA _ _ C_ IMO _ _
C_ Vapor Dem;ity (Air "" 1.()). __LOL
Applicable Bulk Ret~. 46 \t'R Subchapter __o_ Solubility in Water .. Complete

Grade-A. Flammable l1qud
Ell'(:trical Gmup-C
General-Produces .mtat,ng vapor when heated If pressure 1s used to unload tank, nitrogen or other inert gas
must be used A1r pressure may cause e~plos1ve pero~1des to form Flashback along vapor trail may occur.
Vapor may e~plorle il 1gn.ted m an enclosed area
F1ash Point ("Fl 36 (CC)
F1ammable l.imits 40to57~o
Autoignition Temp. t"FI 365
Extinguishing Agents COo, dry chem1cal, alcohol loam. water fog
Special !''ire Procedures Avo1d e~posure to vapors Wear self-contained breathing apparalus. u..
water log on large fires Use hose streams at max1mum range to cool exposed tanks Fight fire from a sale
distance or from a protected location
HEALTH HAZARD DATA

Health Ha1Jll'd Ratings Odor Thruhold (ppm) PEL/TWA (ppm) TLV/TWA (ppml
3. 1, 2 2.3 100 100
General-Suspected carcinogen Vapor irritating, liquid causes skin and eye burns.
Symptoms-Burn1ng of eyes. nose and throat, headache, rapid heartbeat: possible drowsiness with prolonged
exposure.
Short Exposure Tolerance-1100 ppm lor 2 hours IS severly 1rr1tat1ng to mucous membranes: 11,000 ppm for 1-2
hours has been reported as fatal
t:xposure Procedures-Vapor-remove v1ct1m to fresh a1r; if breathmg stops, apply artificial respiration. Skin or
eye contact-remove contammated cloih1ng and gently flush affected areas with water for 15 minutes. Get
medical advice or attention
REACTIVITY DATA
Stability-Highly reactive Can form explosive peroxides under air pressure. Slowly polymerizes to paraldehyde.
Can react vigorously With oxidizing matenals Explodes when m1xed with iodine
Compatibility-Material: Negligible corros1on to m1ld steel May d1ssolve rubber.
Cargo: Group 1g of compallbill\y chart.

If possible, wear rubber gloves, self-contained breathing apparatus and protective clothing. Cover spill with
sodium bisulfite (NaHSO,) Add small amount of water and mht Scoop up. Wash site with soap solution. Secure
ignition sources
If a spill occun, call the National Response Center, 800-424-8802.
Remarks:
2
ACETIC ACID (Glacial)
s,-,.__ Acetic acid glacial; Ethanoie acid: Glacial UnJted Natlou N11111ber. ,10%-80%
acetic aclcl; Methane carboxylic acid; Vinegar acid Glacial, >BO%
CHRIS Code ...
Fonnula-CH,COOH
BoiUD& Polllt .. _____jJJ'C ____lli'F
~Ofi88S liquid; pungent vinegar-like c _ _ _ 'F
Freeztna PoJ.at .. ____uc ____,\l'F
"""'
Spedftc Grmty-1.05 c _ _ _ 'F
Vapor Preuure lO'C (68'F) (mmHI) .. ___l1.L

Cbemleal F...tiJ-Organic acid Reid Vapor Prellure (pda) .... ___Q&Q_
Vapor Preaure 46'C (ll5'F) (p!lla) ... _Q,iL
PoUatlon c.tqory-USEPA ___.1L_ IMO _{L_
AppUable hlk R. . 46 CFR Subebpter ...... ____Q__
Vapor Deul.ty (Air = 1,0)...
SolubWty Ia Water .. -=-
Complete
f1RE 4 EXPLOSION HAZARD DATA

Grade-D: Combustible liQUid
Eleetrkal G1'011p-0
Guenll-lgoited by heat and by some oxidizing agents. Vapor may explode If ignited In an enclosed area.
Flull PtNDt ('FJ .. 110

Flam-ble Umlls .. 5.4 to 16% at 212'F
Autolpltloa Temp, ('F) .. 1050
Ex~Aplltl .. CO., dry chemical, alcohol foam, water fog
SpeeW fl1n ProeediU'el ... Use personal protective equipment when contact with liquid is likely. Skin or
clothing contact can cause serious burns. Wear self-contained breathing apparatus. Cool exposed tanks
with water.
HEALTH HAZARD DATA

Hellllb Hazarcl Ratinp Odor 'Illrftbold (ppm) PEVIWA (ppm) TLV/TWA (ppm)
2, 3, 2 1.0 10 10
Geaerai-Vapor extremely irritating. Uquld causes severe burns.
Symptoms-Burning of skin in cootact with liquid. Irritation of eyes and respiratory system.
Short EJ:ponre Toleraaee--40 ppm lor 5 minutes.
Eipotlll'e ProcedllJ'ei-Vapor-remove victim to fresh air; II breathing stops, apply artificial respiration. Skin or
eye contact-remove contaminated clothing and gently nush affected areas with water for 15 minutes. Get
medical attention. Wash contaminated clothing, including shoes, before reuse.
REAcrJVITY DATA
Stdllity-Can react vigorously with Oxidizing materials. Reacts violently with potassium hydroxide (caustic
potash) and sodium hydroxide (caU8tlc soda).
Complltlbillty-M.terlal: Highly corrosive to metals when dilute. 316 and 318 stainless steels and aluminum are
satisfactory construction materials.
c.rso: Group 4 of compatibility chart. See also Appendix !-Exceptions to the Chart.

Secure Ignition source&. If poSSible, wear rubber gloves, face shield, and protective clothing. Body shield and
self-contained breathing apparatus should be available. Cover spill with soda ash or sodium bicarbonate. Mix,
and add water II neceaaary for mixing. Scoop up sluny. Wash site with soda ash solution. Flush spills with large
quantities ol water. Usually a spill into a navigable waterway woold quickly dilute to a harmless coocentration for
humans. If a ~p~li oeeun, ea11 the NatioDal Rfiiiiii!IR Cealer, 800-4l4-880l.
ReJIW'b: Below 62"F the ac1d may lreeze and expand enough to burst its containar.
3
ACETIC ANHYDRIDE
S,W.)'IU: Acetic acid anhydride; Acetic oxide: Acetyl UaUed N.OO. N . .ber...
oxide: Ethanoic anhydride
CHRIS Code ..
F-ula-(CH,CO)tO
BcHIInl Pohlt .. ~c --..ZIY'F
A.~lorlessllqOO; pungent, highly c 'F
irritating odor Freeztq Pohll... _z:rc
___ c --:j'jiiF
___F
Spldftc: Gl"llYit)'-1.08
Vapor Pre.llre lO'C (61'F') (mmHI) .. ~
Reid Vapot" Prea1are (pita) ......................... _.o..a...._
VaptQ" Pre.11n .t6'C (115'F') (pii'-J... ____g.!_
PoDudoll C.teawJ-USEPA ----'L_ IMO ----'L_ Vapor D...aty (Air = 1.0).......................... _ U -
Applkable Bulk Rea. .t6 CFR S11beiaapm- ....... __Q__ SolllbWty Ia Water.. . 12% Apgraclllbl!
FIRE It EXPLOSION HAZARD DATA

Grade-D: Combustible liquid
Electrical Gro11p-D
Galeral-Aeacts violently with water generating dangerous heat and pressure In confined spaces. Ignited by
heat. Vapor may explode if Ignited in an enclosed space.
Flub Point ('F) .. 121 (CC)

n-....Weu.u.. 2.7 to 10%
Alltolpltloa Temp. ('F) .. 734
btlnpiAina: A.pa.tl ... CO:!, alCohol foam, water fog' or dry chemical.
Spec:laJ F:lre Proeed- .. Cool outside of tanks with water spray. Apply water cautiously. DO NOT
contaminate anhydride system with water. Usa self-contained respiratory protection and protective clothing.
HEALm HAZARD DATA

Hlth Huud Rr.tlap <Hor nre.ltold (ppm) PELITW A (ppm) TLVirWA (ppm)
3, 3, 3 0.14 5 5
Ge~~erai-Vapor extremely irritating. Liquid causes severe burns.
Symptomt-Coughing: burning sensation in nose and throat. Severe eye and skin bl.lrns. Warning properties are
good because compound Is highly irritating.
Sbort bp~M~w-e Toleruee-Less than 40 ppm for 5 minutes.
ExpoMre ~Vapor-remove victim to fresh alr; If breathing stops, apply artifiCial respi"ation. Skin or
eye contact---f&lnOVe contaminated clothing and gently flush affected areas with water for 15 minutes. Get
mecNcal attention.
REACJIVITY DATA
SUINiity-Reacts with water to form acetic acid and produces conaiderabla heat. Reacts violently with
potassium hydroxide (caustic potash) and sodium hydroxide {caustic soda).
c-,atibWt)'-M.terial: Highly corrosive to iron and steel when moist. Softens many plastie8. Usually stored In
aluminum or stainl888 steel tanks.
Carte: Group 11 of compatibility chart.

Wear full-prntective clothing. Body Shield and self-contained breathing apparatus should be available. Secure
Ignition scuces. If ponlble cover spill with soda ash or sodium biCarbonate. Mix and add water If necessary to
effect good mixing. Scoop up slurry and wash aile with soda ash solution. Usually a spill Into a navigable
waterway would quickly dilute to a point where It would present little danger to humans.
If .,W occtlt't, eaU t1te NatloDsl ReQoue Cuter, 100-424 11101
RIIIWb:
. AvOid getting water 1nto acetic anhydride tanks.
4
ACETONE
s,.,ay __ Dimethyl ketone; Ketone propane; United Natioa N ...ber...
betaketo-Propane: Propaoone; 2-Propanooe;
Pyroacetic ether
CHRIS Code ..
Formula-CH.COCH,
BoUI:aaPoJat.. ~c ~F
AppearaDCe-Odor-Colortess liquid; sweetish odor c ___ 'F
Freezl.a& Poblt.. -ftS'C ---=l.ai'F
Speclfte Gnrdty--0.79
___ c ___F
VllpOI' Preaure lCI'C (61'F) <mH&).. .....1lW.....
Chemical Family-Ketone Reid Vapor Preaure (plia)... ....L2a......
Vapor Preaure 46'C (115'F) (plla).. .....1QL
Pollution Category-USEPA _..c.__ IMO _JJl__ Vapor Deal:lty (Air = 1.0) ......................... ---Z.Q_
Applle~~ble Bulk Rea. t6 CFR Subchll(ttu ....... _..c.__ SolabUity Ia Wllter .. Cprrtp!tte
FIRE .t EXPLOSION HAZARD DATA

Grade-C; Flammable liquid
Elecbical Group-O
General-Highly flammable. Flashback along vapor trail may occur. Keep away from heat, sparks, and open
flame. Vapor may explode if ignited in an enclosed area.
Flub Point ('FJ .. 15

Flam-We Umlts ... 2.5 to 12.8%
Autolgnltloa Temp. ('F) .. 1040
Extlnpl.tllna Aaeuts .... GO,;, dry chemical, alcohol foam, water fog
Spedal Fire Procedure. .. Water may be Ineffective on fire. Cool exposed tanks with water. If water is
used, large quantities must be applied in order to prevent re-.ignition. A solution of 4% acetone and 96%
water has a flash point of 129"F.
HEALTH HAZARD DATA

HeaJtb Huard Ratf.Dp Odor 'lbredtold (Jipml PEL/'IW A (ppllll TLV !TWA (pplll)
1, 0, 0 200 to 400 750 750
Geaeral-lnitant to eyes, nose and throat. Anaesthetic effects after high concentration exposures. Prolonged or
repeated skin contact may cause defatting of the skin and may produce dermatilas from frequent dally
contact.
Sympt-Drowsiness and throat irritation.
Sbort Expo11ure Tolenuace-10,000 ppm has been reported as endurable for 3~ minutes without symptoms.
Expt:Miure Proeedut"eS-Vapor-remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or
eye contact-remove contaminated clothing and gently flush affected areas with water for 15 minutes. Get
medical advice or attention.
REACI'IVITY DATA
Shlblllty-Stable.
CompatlbUity-Materlal: Will dissolve many plastics and rubber.
Cif&o: Group 18 of compatibility chart. See also Appendix 1-Exceptiona to the Chart.

if possible: Wear rubber gloves, lace shield and protective clothing. Have ali-purpose canister mask available.
Secure ignition sources. Flush spilled acetone away with water. Do not flush into confined space such aa a
sewer because of the danger of explosion.
If a 1pill ocam, call tlae National R~ Center,I00-4:z 111102.

Rem.arkJ:
s
ACETONE CYANOHYDRIN
Sy-ymt- alpha-Hydroxyisobutronitrile; Uulted Nations Number ..
alpha-Hydroxyisobutyronltrile;
2-Hydroxy-2-methylpropanenitrile;
2-Methylacetonitrite; Propanenitrile,
2-hydroxy-2-melhyl CHRIS Code ..
Formula-(CH.).C(OH)CN
Appear ... ~or-Cotorless to straw colored liquid;

___.,
Boiling Point .. ~ffiPQ.$.~.~-- --=.!ZQ"C --"l!'F
c
almond color
Specific Grnlty--0.93
Freezing Point
___ c ___.,
-19'C ---=.2:'F
Vapor Pressure 20'C (68'FJ (mmHg). ____Q.L_

Cbendcal Family-Cyanohydrin Reid Vapor Pressure (p~~la) .. ___2.L_
Vapor Presaure 46'C (115'FJ (psla) __Q.L_
Pollutfoa Catqory-USEPA __A__ IMO ___A__ Vapor DeDatty (Air = l.OJ .. ___ll_
Appllc:at!le Bulk Re11- 46 CFR Subchapter ...... ____Q__ Solubility in Water .. Complete
FIRE & EXPWSION HAZARD DATA

Gnllle-E: Combustible liqu1d
EJeetrica.l Group-O
Gefteni-Gives oft llammable and po1sonous cyanide gas when heated. Vapor may explode if ignited in an
enclosed area Dilution with water causes decomposition with the formatiOn of hydrogen cyanide.
Flub Point (" FJ . 165 (cc)

flammable Umlts 2.25 to 11%
Autoipltloa Temp. ("Fl 1270
ExtinpJshin11 Agenb CO,, alcohol loam, water fog
Speclrol Fire Procedures DO NOT USE SODA-ACID EXTINGUISHER! Cool exposed tanks with water.
Apply water cautiously. DO NOT contaminate cargo with water. Respiratory protection required for
firefighting personnel. Wear full protective, airtight clothing.
HEALTH HAZARD DATA

Health Hazud Ratings Odor Tbresbold (ppm) PEL/fW A (ppm) TL V!TWA (ppm)
1, 2, 4 Unavailable Unavailable Unavailable
General-Vapor very poisonous by inhalation. Liquid poisonous by absorption through the skin. Grade 8 poison.
Symptom-Headache, dizziness, nausea; blueness of lips and fingernails.
Short E11pot11re Tolerllllce-Unavailable
E11poture Procedu..-Vapor-remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or
eye contact-remove contaminated clothing and gently flush affected areas with water lor 15 minutes. Keep
victim at rest. Gel prompt medical attention lor liquid or vapor exposure. Wash contaminated clothing,
including shoes. before reuse.
See Medical Kit Information, Appendix 8
REACTIVITY DATA
Stability-When heated, decomposes to form cyanide gas. Must be kept slightly acidified. Dilution with water
causes decompos1t1on with formation of hydrogen cyanide.
Compatibility-Material: Alum1num and stainless steel are satisfactory, rubber will swell.
Carao: Group 0 of compatibility chart. See also Appendix 1-Exception to the Chart

If possible, wear long rubber gloves, sell-cootained breathing apparatus, and protective clothii'IQ. Eliminate all
sources of ignition. Evacuate personnel not equipped with respiratory protection. Do not flush spill where
humans or animals may contact.
If a spill occurs, eall the Natlomal Re.pome Center, 800-414-8802.
Remarks: Decomposes at the bo1I11'1Q pomt.

Avoid getting water into cargo tank.
6
ACETONITRILE
s,-,.-Cyanomethane; Ethanenllrlle; Ethyl nitrile; U..... N.a-~................................ ....lW_
Methyl-
CIDUS Code ................................................ ~
'-la-CH,CN
. . . . P*t .......................... --11~ _.lli"F
~liquid; aromatic odor c "F
Spedftc Gratft:J-0,78
. _ ............................ -we
_ _ "C _ _
-10
v.,... ,_.we (WFJ c-111) .......... ......D.AL.
~ "-07-Nible .... v.,... p , _ . (llilla)........................... ....A&IL..
v...,.. ...._.we (US"FJ ~-- _JMtil._
Polldcla ~USEPA ___.ll_ IMO ___JlL__
~ Bldk .... 46 CPR~-- ___..2._ .
=-~:.: ~~::::::::::::: ~ ..
FIRE A EXPLOSION HAZARD DATA
_.,_._,
Gnde-C: Flammable liquid
GeaaW-Aeacta with -.m and acida to produce toxic and flammabte vapm. Ignited by hell,
flame. Fluhback along vapor nil may occ:u. Vapor m.y exp6ode If lgnltt In an encloeed ..._
"*"" or OJ*I
-u.Jto
111a11a Pomt
A~T..,.("P)
rFJ ... ..........
--
....... .
.........................
CO,,
Water""'
Spedal Fin Proceanl ............... -
may be
4.2
4.<4 to 18.0%
................ 975
alcoholCool
lneffecllve. loamexpoHd tanks with water IPfiiY C.. nut be
taken not to expote fire flghtera to the fume. of thia material. Any who mull enter a contaminated
atmosphere must be provided with respiratory protection.
............. ._
1, 1,3
throat Uquld ll'l'ltatlng to skin and eyes.
.._..,..
~1'1888, headache,
"""-- HEALTH HAZARD DATA
.... ...
PELITWA-
a...J-Highly toxic. Can be absorbed through skin and reeplratory b11ct. Vapor Irritating to
...,....
UV/IWA~
-ves. 110M end
nauaea, and blueneee of lipl and flngernalll. Inhalation will cauH dlfflcUt
Sllort EQoRre T~ exposure to 500 ppm has produced some noM and ttro.t nttatlon.
EJ:,_re ~Remove victim to fresh air. Apply artificial reaplratlon If he etops brw.thlng. Get medlclll
anentlon. If liquid contacta lkln, wash off with plenty of water.
See Medical Kit InfOrmation, Appendbc B
REACilVITY DATA
St.ldlitJ-Stable.
c M'tr-MMerial: Mild steel and atalnlesl lteel are compatible.
CareD: Group 37 of oompaUblllly chart
SPILL OR LEAl: PROCEDURE
--
If postlble, wear long rubber gkwea. self-contU1ecl breathk1g ~ and protective clolt*g. AVOid
contact wtlh liquid. Secure Ignition ICII.!I'()M, Small eplls may be wuhed Md)' with ...... Mly add ..... ol
ab'ong calcium hypocNortte solution to apiM anc1 scoop up skny. w.-,
111e wtlh _,. .olulkln ~ IOII'Ie
U ..a1 0C11W1t call ... N.a-1_~ C.., a.Gt .az

a-u: NOTE: Odor thrHhold is not coneldered ~te WMllng of potentill ~ v.por
concentrations. High vapor concentrations catMe rapid death.
7
ACRYLAMIDE SOLUTION, 50%
U.._. Nlldcl. N.-................................. ...JQZL.
C11R1S CaM........ . ......................
&ow., PcUt .......................... ----lQZ:g ----ZlA:;

Fnea., N.a ...................... ___j"C ==--F
. . . . . Gtftkr-1.05 ___ c ---
.,._,.....,__ v.,....r-nzoc<WF')~
.... v.,.. rr-n .......... __._
(IIIAa)........................... ___i__
v.,.... r - c <ns., (fla8) ............ _,i__
.......... ~-USEPA. ___JL_ IMO __Q__
- -.... "en-.. . . . ----'L. =...,.~=-=--~~~:::::::::::::. . . . . ."*;#-
-- --
Gr...
---.
HofriiMimatJM
Note: Aa'ytlmlde ia not fJarnrnM)Ie or cornbudMe. It ia lhlppecl cheolved In ..., (50%
by weight). Acf)'tMIIde wll polymerize In lha wat.r tolutlon If hMI<.
~Tox6c OXidH ot nitrogen may be formed in fire.
............ ("F) .......................

~l.l-.ltl .................. ....... ...-...
Bl:
I II T-..rJI) ............
I
'!'JA~~U ............ .......
.,.... Jlln ........_ ................ War full prntecttve clothing, Mlf-oontahed brNthlng ~
---
~V~par
.. I
0,1, 9
1nttat1ng to ~
HEALTH HAZARD DATA
CNor nn.llold C,.)
"""""-
PEL/TWA-
0.3 mg/m 1/Skln
noM and thro.at Uqulcl will bum aKin and eye~.
Jt'ICIW...,..,.., ataxia, Incoordination, tremorl, halluclnaliont. An.ckl central

n.VITWAw.>
o.3 mgtm 1/Sidn
r'IIM)UI tyltem.
lllort ~T..............UMYail.tJII
I:QaMw Pi I
Ramowa 10 fr-.h U. Ad"*"ler artificial respiration or oxygen u neceaary. FMh ~
wtlh .-nty 01 watw. Remow contaminated clothing and shoes and fluah with vmer. It awallowed and
conecloul, give war or mNk, Induce vomiting.
REACTIVITY DATA
---(-).May,.,.,_. -on molting.
- 7 CU;-IriCCKI1Idble with Olddlzlng ~.reducing agents, acldt, buM, and vinyl
.,_.....,., ... _""""""

pol)lzdoi

Cowt with Inert Milorbent or tlulh with wat.. Do not allow spill to dry. w.. ful protecllve dothlng,
..ek:o~Uiiled blwtNng ....... rubb gloves.
If~~ ocan, all tM- NdGMI . . . , _ c.a.r -.a 1110.2

. _ _ VIIPOf Prell&n: 1111 rnmHg at 25"C.
t"-
8
ACRYLIC ACID
s,.-,..._Acfoleic acid: Ethylene carboxylic acid: United N.UOU Nuablr ...
2-Propenlc acid: 2-Propenolc acid; Propanoic acid;
Vinyl formic acid
CHRIS Code ..
Fonnla-C.HaCOOH
Bollia& Pobal.. .
Appearuce-Odor-Colorless liquid; acrid odor
Fnleziq; Polal ...
Spedlk Gn'f'lty-1.05
Vapor Pre.IIJ'e lO'C (61'F) (mmii&J ..
CbeDdeal Family~ acid Reid V.,or Prelnre (pela)...
Vapor Preaare 46'C (115'F) (pda) ..... .
Polllltkm c.te,ory-USEPA - - - IMO __c__ Vapor o-.tty (Air = 1.0).
A,Ualble Bllllr. Ret. 46 CPR S.bc:bapter ....... __..0__ SolWUty t. Water ..

GNik-0: Combustible liquid
"""""'Groop-D
Geaeral-Preaents no epacial fire or e)(plosion hazard because of Its relatively high flash point and low vapor
pre88Ut&. Poisonous gases may be produced in a fire.
, . . Pobll ('F) .. 130

JllannnaWe Undtl .. Unavailable
Autoipi.d011 T-p. ('F) .. 835
EUiquiAiq A~t~~D .... Water, dry chemical, alcohol foam, CO.
Spedal Fin Prveecharel . Use ot CO. where it could blanket the vapor apace of a container ia not
recommended. A fire involving a spill outside of tanks oould be extinguished wlth dry chemical. Wear full
protective clothing, eye protectioo and seH-contalned breathing apparatus.
HEALTH HAZARD DATA

H..Jth Huanl Ratillp Odor nr.lto., (ppm) PEL/TWA (ppm) 1LVII'WA <pp.l)
3, 3, 2 Unavailable 10/Skin 10'
Geuerai-Acrylic acid, when in cootact with skin or eyes, may rfi84Jit in a bum upon short contact Vapors may
present an inhalation hazard from single exposures; irritating to eyes, nose and throat.
Symptomt-Vapors are capable of causing definite skin or eye irritation, nasal irritation and lachrymation.
Sbort Ex~ To~.5 pPm
Exponre ~II contact with skin or eye occurs, Immediately flush with plenty of water lor at least 15
minutes. Get medical attention promptly. Immediately remove contaminated clothing and shoes.
REACI'IVITY DATA
StabWty-Potymerizes readily. Should be inhibited to insure aafety and stability during storage or handling.
c:o..,.tlbiUty-M.terial: Severely corrodes iron and steel. Glass, low carbon content stemless stael and high
purity aluminum are recommended for containment in order stated.
Clqo: Group 4 of compatibility chart. See also Appendix !-Exceptions to the Chart.

If possible, wear rubber gloves, lace shield, protective clothing. Body shield and 181f-contalnecl breathing
apparatus should be available. II possible, cover contaminated surtacea and spill with large quantltin of soda
ash or sodium bicarbonate. Mix and add water if needed for good mixing. Scoop up alurry. Wash site with soda
ash solution.
II a .,W ocean, cd die Natioal a..,_ ee.ter, II00-4l4--llltl.
ae-u Proposed change In TLV . " notation.
to 2 ppm, with "Skin
9
ACRYLONITRILE
S,AW)w---An; Cyanoethylene; Propene~oltrile; UIIIW N.u- N................................. .....Ja....
2-Propeo ~&nitrile; VInyl cyanide
CHRIS Code .. . ............................... .
--
P-a.-cHaCHCN
~liquid;
s,.cutc Grmtr-0.81
a..lell FadlJ-Nitrile
Polbldoll Catepy-USEPA. ____L_ IMO _.1L_

resembles that of
AfplkUie lhlk Rea. 46 CFR . . . , . _ ....... ~

a.w.a Pomt
V~q~e~r
............... _____E.'C ____lll'F
Preezb11: Polal... .. ................
v.,_ Pr..-e l:O'C IA'F.I <-Ita) ..........

c
-B5'C ----:;-ijF
___ c ---
v.,.... rr-re (Jilll)...........................
v.,.. Dea11t7
Reid
~ <N'C (115'Fl (fila) ............. ___,AJL_
(Air =
So1H01tJ 1D W_. .............
t.D)............... .....
_J.,I..._
Mpdtrlll
___IL_
__JJ__
'F

........,.....,_0
Gnde-C: Flammable 1kJ*1
c-.1-When heated thia material may evolve toKic cylll1ide gas, or explOde, or both. Flashback along ~
trail may occur. Fire may cauae violent rupture of tank.
...
--
FlaM PoiBI ('F) ...... ......... 32
.,......u.ha .... ................... 3.0to17.0%
AnlipftloD Te.p. ('F) .. .
................... CO.. dry chemical, alCohol foam
S,edal Fire Procedllrel .. .......... 00 NOT ull8 dry chemical for a large, confined fire. Water or foam may cauee
frothing. Are pertie8 must wear respiratory protection and full protective clothing Including nbber boots.
Keep tank cool with water spray.
...................
3, 1, 3
HEALTH HAZARD DATA
Odor 'nrelllold (Pflll)
21.6'
PEL/I'WA <R-)
29 CFR 1910.1045
n.v!TWA c,.)
2/Skln
c-.l--5uapected carcinogen. Harmful by Inhalation and akin absorption. Pene1rates leather, liquid In lhoel
cauaes delayed burns. Contaminated leather shoes and gloves should be del1royed,
-
Sy.pt--eye Irritation, headache, naue.ea. bluenen of lips and fiogertips. Con1act with akin may also cau1e
SJiort
EK.-re
~ TolenDco-400 ppm tOJ 30 minutes.
Jtroeed .. Remove victim to fresh air. " he Ia not bfeath'ng, apply artificial mplratlon. Remove
contaminated clOthing and wash chemiCal from akin with a 98ntle flow of water. Get medical attention. "
patient Is unconscious, administer vapor of amyl nitrite.
See MediCal Kit Information, Apperdx 8
REACTIVITY DATA
StlddUIJ-Very reactive; may polymerize explosively In the preeence of strong bases. Must be inhibited to
prevent polymerization. POlymeriZation coold be Initiated by viSible light.
eo.,.tlbiUIJ-Matertat: Copper and copper allOys are attacked and should not be used. Attacks aluminum In
1>9> """"""'-
c.rto; Group 15 of compatibility chart. See also Appendx 1-Exception8 to the Chart

It poselble, wear long rubber glcwea, aelt-contained breathing apparatus. protective clothing. Avoid contact
with liquid. Secure Ignition sources. May add excess of strong calcium hypochlorite solution. Scoop up tk.rry.
Wash site of spill with soap solution containing some hypochlorite.
If slplll ocan, adl tile N~ a..,_ c.c.r, IOIJ...4.1t 1102

a...r~rt; " NOTE: Detectable odor Is greater than the TLV. Exposure to potentially dlngeroui vapor
concentrations can occur before the vapor Is detected.
10
ADIPONITRILE
s,._,._ 1,4-Dicyanobutane; Tetramethylene cyanide UnUed Nlltlou Number...
CHRIS Co4e ..
F0111111la-NC(CH,)4CN
BolliDaPolnt.. ~c ~F
A~lorless liquid; practically odorless
___ c ___F
Freeziq PWDt.... . ____J'C ~F
s,edlk Grarity-{1.95
___ c ___F
Vapor Pre.ure lO'C (61'FJ (mmH&) .. ___J,.gw_
C1lemkal Funny-Nitrile Reill Vapor Pre~~~~re (plia)... .....La...
Vpor Preaare 441i'C (tU'F) (]IN.).... ____l.mt_
Polllltion c.teaorJ-USEPA - - - IMO _.JL_ VIJIOI' Deall.ty (Air = 1.0).... . ......... ......a.n_
Appllaltle &.lk a._ 46 CFR SubcUpter ....... ___Q__ Solubility iD Wlller.. Slight

Grade-E: Combustible liquid
Eleetrlad Group-O
Geaenll-On being heated to Its flash point this material can decompose to form highly poisonous cyanide gas.
Vapor may explode If ignited in an enclosed area.
Flub. Poblt ('F) .. 199

..,__ble LJItl ..
Autoipitloa Temp. ('F) ..
LEL= 1.0% at 200'C
Unavailable
Extlnpilhina Aaentl .... CO., dry chemical, alcohol foam or water fog.
Spedal F1re Procedure~ .. Keep tank cool with a water spray. Combustion may produce cyanide gas, so
fire parties should wear self-contained breathing apparatus and protective clothing.
HEALTH HAZARD DATA

Hellldl Huard lbtlltp Odor 'I'IIresltold (ppm) PELJTW A (ppm) TLV /TWA (ppm)
Gaeral-Harmful by skin contact. Gas from fire Is poisonous if inhaled. Liquid or solid is irritating to skin and
oyeo.
S)'DlptoJQ-Headache, nausea: blueness of lips and fingertips.
Short Ell:ponre Toteraaee-Unavallable
Ell:pohl'e Pfoeed"res Remove victim to fresh air. Remove contaminated clothing. If breathing stops, give
artificial respiration. Wash spill from skin with geotle flow of water. Get medical attentiOn.
See Medical Kit Information, Appendix B
REACTIVITY DATA
StabWQ>-Stable up to tempef'8tures near the flash point.
c-.,.tlbftlty-Mtlterial: Compatible with steel, wood, most rubbers.
Carao: Group 37 of compatibility chart.

If possible, wear long rubber gloves and protective clothing. Add an excess of strong calcium hypochlorite
lution to the spill. Scoop up sluny. Wash site of spill with soap solution containing some hypochlorite.
It 1 spill 0tt11r1, Clll tile N.tiODII RelpoMe Center, 800-4:Z4 880:Z

Remark&:
11
ALKYLBENZENESULFONIC ACID
Synon,..._ decylbenzeneaultonlc acid; Un-, Do-, Tfi.., UnJtM NM:IIIIQI Nlllllber...
Tetra-, Penta- or Hexa-: Oodecytbenzenaaultonic
odd
CHRIS Code ..
Bouma Pot.t.... c ___ 'F

Appearance-Odor-While to yellow liquid; odorless
Freezln& Pot.t.. ---.C ---,F
c 'F
Spedtk Gra'rit)'-1.0 to 1.4 ==c_F

VlfOJ' PrlaiU'e lO'C (QI"F) <-HI).. __!__
Cltemkal Funily-Acids Reid Vapo!' Preaure (plla)... ____L_
V11110r PreiHre 46'C (ll!I'F) (...).. _L_
Polllltlon Cateaory-USEPA ~ IMO ____Q__ Vapor De-'tJ (Air "" 1.0) .......................... ___L_
AIIPUet~ble Blllk Rea. 46 CFR Sukbapter ....... ....12....0..:. Solbillty Ill Wllter .. Sglublp

Electrlea.l Group-NA
General-Slightly flammable when exposed to heat or flame. Irritating suUuric acid mist may form In fire.
Flammable hydrogen gas may be produced on contact with metals.
Fluh Point ("Fl 395

Fl.unmble Limltt. Unavailable
Autolpition Temp. ('F). Unavailable
Extinplshlng ApDUI .. Alcohol foam, dry chemical, CO.
Special Fire Procedura ... Water may be ineffective on lire.
HEALTH HAZARD DATA

Heal.tb Hazard Rat:llap Odor Tbresbold (ppm) PELii'WA (ppm) nV!lWA (ppll)
Unavailable Unavailable Unavailable UnavaHabla
General-Uquid is irritating to skin and eyes, corrosive.
Symptomt--lrritatlon of eyes and skin. Ingestion causes irritation of mouth and stomach, nausea.
Short Exposure Toleraace-Unavailable
Expo~ure Proeedura-Eyes-flush with water for at least 15 minutes. Skin-flush with soap and water.
lngestioo--glve large amount of water.
REACTIVITY DATA
StabiUty-Stable.
CompatiiHHty-Materlal: Attacks metals and gives off flammable hydrogen oas.
Carao: Unassigned in compatibility chert. See also Appendix 1-Exceptlons to the Chart.

Avoid contact with liquid. Flush with water, rinse with dUute sodium bicarbonate or soda ash solution. w..,
goggles or face shield and rubber gloves. Secure ignition sources.
If "'" ocean, call cbe Natioul ......... ee.ter I IJOO-tl4-8102.

Remarkl: 4% or tess regulated by Subchapter D; over 4% 18 regulated by Subchapter 0.
t Unavailable.
:1: Unassigned.
12
ALLYL ALCOHOL
s,._,_propenol; 1-Propenol-3; 1-Propen-3-ol;
2-Propenol: 2-Propen-1-ol: Propenyl alcohol: Vinyl
carbinol
CHRIS Code ..
F01111ula-CH. = CHCH.OH
Bomn1 Potllt .. ~c ____iQ'F
A~r-Colorless liquid: pungent odor c 'F
Freezing Point.. -129'C
-?OO'F
Specllk Gra"rity-0.85
___ c ___ F
Vapor Pre.ure lO'C (68'F) (m111HK) .. ___l.,Z2._
C'ltemicaJ FamUy-Substituted allyl Reid Vapor Preaure (plia)... ___l.Q___
Vapor Preaure 4fi'C (115"F) (IJII..).. ____1,.__
PoUIItlon Catecory-USEPA ~ IMO ____e__ Vapor Density (Air = 1.0).... . .............____2.2_
AppUetble Bltlk Rea. 46 CFR Sabcbapter ....... __Q__ SolubiUty iD Water... ComPlete
FIRE ol; EXPWSION HAZARD DATA

Gnlde-C: Flammable liquid
Elec:trlc:al Groap-C
Geamd-Poisonous gases may be produced in a lire. Readily ignited by heat, sparks, or open flame. Flashback
along vapor trail may occur. Vapor may explode il ignited in an enclosed area.
Fladl Point C'Fl .. 90 (oc); 70 (cc)

Flammable Limits .. 2.5to 18%
Aucotpitloa Temp. ('F) .. 713
EJ.tlquilbial Aaentll ... CO., dry chemical, alcohol foam, water fog
SPial Fire Procedwa .. Use respiratory, body and eye protective equipment and clothing. Water may
be ineffective. Cool exposed tanks with water.
HEALTH HAZARD DATA

Heald! Huard Ratlnp Odor lbresltold (ppm) PEL/TWA (ppml TI..V!TWA (ppm)
3, 2, 3 2 to 5 2/Skin 2/Skin
GeDeral-Vapor poisonous if inhaled or if skin is exposed. Liquid is poisonous if swallowed or if skin is exposed.
Vapor extremely irritating. Lung and eye injury may be delayed. Liquid causes severe burns. Grade B
poison.
Sympto1111-Vapor exposure-irritation to respiratory tract. Liquid splashed on the skin causes "deep bone
ache" if not removed promptly. Disabling irritation and corneal injury to eyes may be delayed.
Short Expoare Tolenmce-1000 ppm has been reported as fatal (exposure time not reported); 5 ppm can be
tolerated for 30 minutes.
Expon~"eProcedura-Vapor-Remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or
eye contact-immediately flOOd affected areas gently with water for at least 15 minutes: remove
contaminated clothing and shoes at once. Keep patient at rest and under observation lor 24-48 hrs; effects
may be delayed. Wash contaminated clothing before reuse, destroy ahoes. Get medical help.
REACTIVITY DATA
StabiUty-Chemically stable.
Comp~~tlbllity-MIIterial: Swells rubber. Not corrosive to steel.
ear,o: Group 15 of compatibility chart. See also Appendix !-Exceptions to the Chart.

If possible, wear rubber gloves, face shield and protective clOthing. Secure ignition sources. Use respiratory
protection. Keep unprotected personnel upwind of contaminated area. Flush spill with water. May absorb very
small spills with absorbent material (sand, etc.).
If a .,til ocnn, WI lite Natloal. Reepoue ee.ter, 1100-424-8102,

Re...-ks:
13
ALLYL CHLORIDE
s,._,._ChloraHytene; 1-Chloro-2-propene; UnUed Natto. N11ber...
3..chloropropena; 3-ChiQro.-1-propene;
3-ChiOfoprC~pylene; alpha-Chloropropytene
CHRIS Code ..
F~Hs "" CHCH.CI

Bonlq PoiDt .. ___j'C __.1_1.3"F
A~-Ciear to strawberry colored liquid; c "F
sweetish odor Free.daa: Point .. ----=134c --:?QjiF
Sfedl'k Gnlty-0.94 c ---
Vapor Pre.u~ 20'C 168'F') lllliiiHI) .. ~
Reid Va,or Pre11are (JIIa) .... ...1M....
Vapor Prea~n 46'C (115'F) (JIIIa) ... ....JM...
PoU11tloa Calqory-liSEPA ____.&.__ IMO ____a__ Vapor Dealt)' (Air = 1.01 .... .....2JIL
A.,Uable Blllk Rq. 46 CFR S11bdu!Jiter .. . .. ___Q_ SolabUity ill Water ... 0.3%

Gr.dfo-8. Flammable ltquld
Eledrical Group-O
Gemenai--Corrostve hydrogen chloride gas looned upon combustion. Becomes more reactive and corrosive
when wet. Ignited by heat. sparks or open !lame. Flashback along vapor trail may occur. Vapor may explode
if ignited 1n an enclosed area
A.~~ Polat ("F) 20 (cc)
Aaa..ble U111lb .. 33 to 11.9%
AllloJpltloa T-p. ('F) 737
Eat:lllpilb.Jnl ltpnb . CO.. dry chemical, alcohol foam.
Spedal Fire Procellurft .. Water may be ineffective oo lire. Cool exposed tanks with water spray.
Firefighting personnel should be protected against hydrochloric acid fumes by wearing self-contained
breathing apparatus and lull protective clothng.
HEALTH HAZARD DATA

HeaJtb Huvd lbtiiiP Odor TlueOold (ppm) PEL/lW A (,.,_) TLVIIWA (pp.)
3, 2, 3 above 1 1 1
General--5uspected C81"cinogen. Poisonous if inhaled, if swallowed, or if skin is eJ<pO&ed. Vapor extremely
irritating. Uquid causes bums. Grade B poison.
Sym.pro..-Vapors 81"8 irritating to eyes and respiratory tract. The liquid irritates the skin.
Short Expogre Toleruee-lnhalation of 100 ppm lor 60 minutes has baen reported as fatal.
EJ:,.....re Prot:edura-Vapor-remove victim to fresh air. II breathing is difficult, administer oxygen; if breathing
stops, apply artificial respiration. Skin or eye contact-remove contaminated clothing and gently flush
affected areas with water lor 15 minutes. Get medical help.
REACTIVITY DATA
St.bolllty-Chemically stable.
Conlpatiltllity-M.terial: Highly corrosive to steel and aluminum. Nickel and monel are suitable materials of
construction.
Carp: Group 15 of campatibllily chart.

Wear rubber gloves, seH-contained breathing apparatus and protective clothing. Avoid contact with liquid.
Secure ignition sources. Do not flush spill into conrl08d spaces where flammable vapors can accumulate.
If a IP'D occun, eall tbe N.Uoual RIIIPUue Cnter, II00-4l4 8102.

ae....-u:
14
AMINOETHYLETHANOLAMINE
s,._,..._ 2-((2-Amlnoethyl)amino)ethanol; United N1tton. Nanaber .............................. ___L_
N(Amlnoethyl)ethanolamine;
N-(2-Amlnoethyl}ethanolamine;
Hydroxyethylethyenediamlne:
N-8-Hydroxyethylethylenecllamlne; CHRIS Code ................................................ ~
N-Hydroxyethyl-1 ,2-ethylenedlemlna
Fonlllla-NH.CH,CHtNHCHtCHIOH
BoWq Poiat ......................... _mc ~-F
A~laar, colorJess liquid with mild c 'F
ammonical odor F'reliillll& PoJIIt. ...................... -ZB'C -lOB'F
Spedlk Gn'f'ltJ-1.03
___ c ___ .,
v.,_ Preleare lO'C (61'F> <HI) ......... __j,gyt_
Reid v.... Preleare (ftia)... ---l.mL..
Vapor Prellure 46'C (115'F> (plia) ............ --1.mL_
l'olhatlo. c.teaorY-USEPA - - - IMO ___.1L_ v.,... De.itr (Air = 1.0) .......................... ___a.a_
Applic:alde Blllk Rea. 46 CFR S.ldlpler ........ ____Q__ SolatdlUy Ill Wlller.. Cqmp!aJt
F1RE 4 EXPLOSION HAZARD DATA

Gnde-E: Combustible Nquld
......... """p--C
Geaenl-No smoking or open lights.
,..... Poi.Dt ('F) ............................ 275

F1alull!ble Llal.tl ............. 15.0 to 27.0%
AutoipltloJI T,. <'F> ............... 695
--' .............
El:tlnpillaiq Apatl ..... ... ..........
...............
Carbon dioxide, dry chemical or alcohol foam
Coot exposed tanks with water. Water or loam may cause frothing.
...................
1, 3, 1
General-Causes 98V8f8
--.- HEALTH HAZARD DATA
Unavailable
eye initatlon.
PEL/TWA (ppm)
Unavailable
s,...,._Uquid causes skin irritation with poSSibiWty o1 burns or prolOnged contact. Vapor causes mild
TI.VII'WA q,p.)
Unavailable
resplratcMy IrritatiOn.
Shrt EllJ101'1111 TolenuH:e-Unavailable
Ellpoare Procedllra-ln case ol eye contact, Immediately flush eyes with plenty of low-pressure water for 15
minutes. If discomfort persists or reappears, see a physician.
REACI'IVITY DATA
StUWty-Stable.
Comp~t~WU~y-Matertal: Incompatible with copper, copper alloys, aluminum and zinc.
c.rao: Group e ol compatlbiMty chart.
SPll.L OR LEAK PROCEDURE

Avok:l contact with liquid. It possible, wear butyl rubber gloves, lace shield, and protective clothing. Cover spill
with sodium bisulfite. Spray with water and wash away with large excess o1 water.
If a .,W. GCe111'1, caJJ tbe Ndoul 1te1po.e Ceatel", IIJ0....424-8802.

Remarb: +UnaS81Qned
IS
AMMONIA ANHYDROUS
Synonyaa-Ammonia: Ammonia gas: H.N: Liquid United Natto111 Nlllllller...
ammonia
CHRIS Code ..
Fonnulii-NHs
BoJilna: Pomt ... ~c ---=..2G'F
AppUf'811CeOdcu-Colorless liquid or gas: pungent, c 'F
highly irritating odor Freez.lag PoJat.. -78'C -108'F
Specific Graflty-0.77 at oc ___ c ___ .F
Vapor Preuure lO'C (68'F) (HI) .. . ....MIL
Cbemie.l Family-Ammonia ReJd Vapor ~re (...I)... . ...2ll...L_
Vapor P~re WC (115'F) (piU).. ~
Pollutioa C.lqory-USEPA ____Jl_ IMO ____gu_ Vapor De.Wty (AJr = 1.0).. ...................... ..Jl.aL
Applleable Bulk Reg, 46 CFR Subduipter .. ... __Q____ SoluWiity Ill Water.... Apprecjlb!a

Grade-liquefied Compressed Gas (LCG)
Electrical Group-O
GeMrai-F1re hazard when in h1gh concentrations and at high temperature. Oil 01' other combustible vapors
increase the fire hazard
Flub Point ("F). lndeltrlite, below 32'F (sometimes difficult to ignite). Not flammable under
conditions likely to be encountered
Flammable Limits 16 to 25'o
Autolpltlon Temp. ("1-'l 1204
Extlnruiahlng Agents. Stop the flow of gas (lighter than air); cool tanks with water spray.
Speclal Fire Procedurn Use respiratory and body protection when approaching
ammonia-contaminated atmosphere liberal use of water fog, where possible, will reduce vapor
concentration.
HEALTH HAZARD DATA

HeaJth Haunt Ratinp Odor (ppm)
Thre~~hold PEL/1WA (ppm) TLV/fWA (ppm)
4, 2, 2 approK. 50 Unavailable 25
General-Vapor extremely nritating. Liquid causes bums; will cause frostbite.
Symptoms-Coughing; burning sensation, eye irritation or pain. Frozen areas turn white.
Short Exposure Tolerllll(e-A 2500 ppm (0.25%) concentration of ammonia in air may be fatal within 30 minutes.
Exposure Pr~~dures-Remove victim to fresh air. Gall a physician at once. If not breathing, apply artificial
respiration, oxygen. If breathing is difficult, administer oxygen. Flush affected areas of body with plenty of
water for 15 minutes. DO NOT FLUSH FROZEN AREAS. If the liquid has spilled onto the skin, points of
contact may be frostbitten; handle gently and protect from mechanical damage. DO NOT RUB. Remove
contaminated clothing and shoes. Get prompt medical attention. Low-velocity fog Is effective for
decontaminating the atmosphere.
REACTIVITY DATA
Stability-Normally stable. Reacts with acidic matEifials.
Compatlbllity-MiteriaJ: Corrosive to galvanized surfaces, copper and copper alloys. Iron and steel are suitable
for the construction of containers, fittings and piping. Forms explosive compounds with mercury.
CarKO: Groop 6 of compatibility chart.

Evacuate area in case of large leaks or tank rupture. Shut off leak if without risk. Wear sell-contained
breathing apparatus. If necessary to enter spill area, wear full protective clothing Including boots. Water spray is
extremely effective in abscrbing ammonia gas and shoold be used around leaks of gas only. DO NOT PUT
WATER ON LIQUID AMMONIA.
If a ..m oceun, eaU tbe National Rnpoaae Ceater, 800-4l4-880l,
Remarb:
16
AMMONIA SOLUTIONS
Synonym&- Ammonia, aqueous; Ammonia water; United Nations Number.. 10-35% __..2Z2_
Ammonium hydroxide; Aqua ammonia; Household 35-50% .....2QZL_
ammonia; Spirit of Hartshorn 50%ormore ~
CHRIS Code.
Formula-NH.OH
Boiling Point ... ~c~F
AppearaJK:e-Odor-Colortess liquid; pungent odor c 'F
Freeziq Point .. Yariesc yarjes"F
Spe~:ific GriYity-0.88 at 20'C (liquid) c ___ .,
Vapor Pressure 20"C (68"F) (mmHg) .. --'lliDn_
Cbemlcal Fantily-Amine Reid Vapor Pressure (psiaL --'lliDn_
Vapor Pressure <Ui'C (IIS"F') {psi.a) .. ...YI!in.._
Pollution Catqory-USEPA _____Q___ IMO _____Q__ Vapor Density (Air = 1.0). ---LZL
AppJicable Bulk Reg. 46 CFR Subchapter ....... ____Q___ Solubility In Water .. Complete

G....-
Electriel.l Group-O
Genel'll1-VapOI's are capable of forming an explosive mixture in air.
Flub Point ('F) .. Varies

Flammable Umltll .. 16to 25%
Autolpidon Temp. ('F) .... 1204
Ex:tlnguillllna Aaents .. Water fog
Spedal Fire Procedures .... Due to the toxic and irritating nature of ammonia vapOfs, lull respiratory
protection must be provided lor firelighters. Coot exposed tanks with wate1. Water log will reduce vapor
concentration.
HEALTH HAZARD DATA

Health Huard Ratings Odor Threshold (ppm) PEL/TWA (ppm) TLV/TWA (ppm)
2, 2, 2 approx. 50 Unavailable Unavailable
General-Vapor extremely irritating. Liquid causes burns.
Symptoms-Liquid: varies from mild dermatitis to severe burns and skin destruction. Vapor: burning of the eyes,
skin irritation, swelling of eyelids and lips, coughing.
Short Exposure Toleranee-400 ppm causes throat irritation & 700 ppm causes eye irritation, both with no
serious results for exposure tess than one hour; 1720 ppm causes convulsive coughing for exposure less
than half an hour.
Exposure Procedures-Inhalation: remove victim to fresh air; if breathing stops apply artificial respiration;
administer 100% o Skin contact remove contaminated clothing; wash with cool H20 followed by lemon
juice, vinegar, or 25% acetic acid; follow with more water.
REACfiVITY DATA
StabiUty-See: Ammonia, anhydrous
Compatibility-Material: Corrosive to galvanized surfaces, copper, copper .alloys and aluminum alloys.
Cargo: Group 6 of compatibility chart.

See: Ammonia, anhydrous
If 1 spill oecurs, call the Natloul Re.poue Center, 800-U4-880l.
Remarks:
17
AMMONIUM SULFIDE SOLUTION, 45%
Synoayms- Ammooium monosulfide solution; UnUed Nat"-t Number....
Diammomum sulfide solution
CHRIS Code ..
Fonnula-(NH.).S
Bolltq Pomt .. ~c .1.Q2::2.1.2'F
c ___.F
Appearaace-Odor-Greenish to reddish yellow solution;
strong ammonia, hydrogen sulfide (ronan eggs) Freezins Point... -18'C ____Q'F
odo
___ c ___.F
Speelfte Gnrfity--0.993 at 60'F Vapor Pra.un :zoc (68'FJ <H&).. ___i__
Chemielll. Family-Caustics Rtl4 Vpor Preuun <.,.W... ____2Z.1._
Vapor Preaun 46'C (115'}1) (plla)... ---2.L
Pollution Cateaory-USEPA _.1L_ IMO _.a_ Vapor Deult)' (Air = 1,0)... ................... _ i _
A.pplinble Bulk Reg. 46 CFR Subehapter ____Q__ SolubiUty bl Water.. Comp!ft!a

Grade-A: Flammable liQUid
ElectriCII Group-O
General-Toxic sulfur oxides produced 1n ltre. Ltquid solution gives off ammonia and/or hydrogen sulfide gas
depending on the pH; vapor evolution rate 1ncreases when heated. Flashback along vapor trial may occur.
Vapor may explode in an enclosed area.
Flash Point ("FJ. 71.6 (cc)
F1ammble Umib .. 4.3 to 46% as hydrogen sulfide
AutOIIIJIItion Temp. ("F) Unavailable
&;tlnpls.hing Agenb .. Water spray, foam, dry chemical, carbon dioxide
Special Fire Procedures . Wear eye protection, protective clothing and self-contail'led breathing
apparatus.
HEALTH HAZARD DATA

Health Huard Rtlngs Odor Tluelbold {ppm) PEL/fWA (ppm) TI.VII'WA (pp)
Unava'rlable Unava'rlable Unavailable 1 0, as hydrogen SYifide
Generai-Mrldly alkaline and evolves toxic hydrogen sulfide and/or ammonia depending on pH.
Symptoms-Eyes: irritation. conjunctivitis. Skin: irritation, corrosion, dermatitis, chemical burns. Ingestion: nausea,
rrritation and corrosion of mucous membranes and stomach. Inhalation: irritation, pulmonary edema,
pneumonia, bronchitis, tracheitis, respiratory problems
Short EJ:poaure Tolerance-
EJ:po~~ureProcedura-Call physician. lnhilation: Aemove to fresh air; give oxygen or artificial respiration as
needed. Ingestion: If concious, give large amounts of water or milk, but do not induce vomiting. Eyes: Hold
eyelids open, flush with water for 15 minutes. Skin: Flush with large amounts of water for 15 minutes.
REACfiVITY DATA
Stability-When heated, toxic hydrogen sulfide and/or ammonia evolve. Reacts with acids to form hydrogen
sulfide. Reacts with bases to form ammonia.
Compatfblllty-Mterial: Compatible with mild and stainless steel, neoprene, polypropylene. Incompatible with
aluminum, brass, bronze, copper, tin, zinc
Cargo: Group 5 of the compatibility chart

Stop release if possible. Wear neoprene apron, gloves, boots, and goggles or full shield. plus self-contained
breathing apparatus. Secure ignition sources. Dike large spills, prevent spill from entering sewers and drains,
recover liquid, treat ground with diluted hydrogen peroxide. Absorb small spills with earth, sand, or other inert
absorbant and properly dispose.
H l)lill occurs, call tile Natkmal Rt.poue Cater, II00-424-8110l.
ReiiW'ks: At 100"F, bubbles of hydrogen sulfrde gas lonn.
t Unavailable "'"
18
Iso-AMYL ACETATE
~Amyl acetate; 118CAmyl acetate: Arnylacetlc: Ulllted NatiOM Nllllltler... ................ --1l2L
eater; Banana oil; Isoamyl acetate; Isoamyl
ethanoate; lsopentyl acetate; 3-Methyl-1-butanol
acetate: 2-Methybutyl ethanoate; Pear oil
CIIRIS C . __l!l_
BoWq Pot.t...... __.lli'C ______agQ'F

~-liquid: pleaunt fruity, c 'F
banana-like odor Freatq Poblt.. ..................... zoc ----:-ijF
-
StMdfte GrariQ-o.aa ___ c ---
vapor Pr-.e zoc (A'Fl (malta) ......... _J,Q_
o..tc:al FaMily-Ester Reid v..- Pr-.e (piJa)... ____Q.L_
VllfOI' ~ we UU'Fl {Jd8) ........... ......2.K.._
Pelhd1oll. C.UrtorJ-USEPA ____1L_ IMO ___c__ Vapor o..H,. (Air = 1.0)..... . ................ ___J.5..,_
A..,uable Built Rq. iN CFR S~ ...... .......D......Q SohabiUty bl Water....... Slj!td

GrMe-0: CombustMlle liquid
Elo<trl<aiG...,...O
GeDeraJ-No smoking or open flames. Flashback along vapor trail may occur. Vapor may explode if ignited In
an enclosed apace. Precautions should be taken to prevent the accumulation of statiC electricity.
PlMII Polal ('Fl ... 100

FJaa..we u.ta ... 1.1 to 7.5%
A~T-p.("F). .. 714
Es:tbl&al*lq A . .ts ... CO., dry chemical, alcohol fOam, water fog
Special Fire Proc:edarel .. . Water may be ineffective.
HEALTH HAZARD DATA

HeUtb Huanl Ratillp Odor nre.ltohl Cpp.l PEL/TWA <pp.ll nvnwA (.,..,
1, 0, 1 7 to 10 100 100
Geaent-Uttle hazard trom inhalation below 500 ppm. It may dry and defat skin.
S,.~eadache. dizziness, nausea; irritation of mucous membranes Of eyes and respiratory tract,
"""""""
Sllort Expolure TolenMe--500 to 1000 ppm lor 30 to 60 minutes will produce definite irritation of eyes, throat,
and trachea.
Ell)IOtllre Proeedurw-Vapor-remove victim to fresh air; if breathing stops, apply artlflc:lal respiration. Skin or
eye cootact-remove contaminated clothing and gently flush affected areas with water for 15 mlnutea. Get
REACI'IVITY DATA
StQmty-Chemically stable.
c-padiiWty-Material.: This compound will soften, then dissolve, a great many plastic materlall, and rubber.
Attacks asbestos.
cu,o: Group 34 of compatibility chart.

Wear rubber gloves, face shield, proteCtive clothing. Have aN-purpose canister mult available. Avoid contact
with liquid. Secure ignition sources. Flush minor spills away with water.
Ir 1llplll occut, eall die Nllioul Re1Doae Cuter, 100-4~
19
nAMYL ALCOHOL
Synony--Aicohol C-5; 1-Amyl alcohol; primary-n- Ualted Ntltloa Number...
Amyl alcohol: n-Butylcarblnol: 1-
Pentanol: Pentyl alcohol
CHRIS Code ..
Formala--CH,(CHt) 4 0H
BoUiq Poillt .. __mc __m"F
Appuruc:e-Odor-Colorless liquid; mild odor
Freezlq Polat ..
c
-Zg"C ---
---=.1.1Q"F
5pKHk Gravlty-0.82 c ---
Vapor Preaure lO"C <68'F) <-HJ) ..
Reid Vapor Pre.fare (.,.) ...
--'"'"'-
.....ll....
Vapor Preltllre 4Ci'C (115'F) (JIM) .. ....J!.L_
Pollullaa Clltqory-USEPA - - - IMO _.c._ VQOl' Deulty (Air = 1.0) .... _.1.2!...
Applkable &lk Rea, 46 CFR Sabcbapter ....... _.c._ SolubWty Ia Water .. Slight
F1RE & EXPWSION HAZARD DATA

Grade-D: ComOOstible liquid
Electrtc:lll Grou.-o
Getteral-Moderate fire hazard when exposed to heat or !lame. Flashback along vapor trail may OCCU'. Vapor
may B)(plode If ignited in an enclosed area. wh9n heated, it emits acrid fumes; can react with oxidizing
materials.
Flub Poblt ('F) ... 118
Flammable Umit. .. 1.210 10.0%
Autolpltlon Temp. ('F) ... 572
Eztiqullhina: Apnts .. Carbon dioxide, dry chemical or alcohol foam.
Special Fire Procedure~~ ... Wat&f may be ineffective on life. Cool exposed tanks with water spray. Wear
self-contained breathing apparatus.
HEALTH HAZARD DATA

Health Huanl Ratinp Odor Thrahold (ppm) PEL/I'W A (ppm) TL V/lWA (ppm)
1, 0, 2 0.12 Unavailable Unavailable
GeneraJ-Vapor may be irritant to the eyes and the upper respiratory tract.
Symptoms-Vapor inhalation causes psychic stimulation, insomnia, palpitation of heart, headache, and vertigo.
Short Expot:IU'e Toleranee-150 ppm for 30 minutes.
Expoa:ure Procedur-Vapor-remove victim to fresh air; If breathing stops or is very weak, apply artificial
respiration. Skin or eye contact-Jemove contaminated clothing and gently flush affected areas with water
for 15 minutes. Get medical advice or attention.
REACTIVITY DATA
StabiUty-Very stable.
CompatlbUity-MaterW: Can be stored in copper, aluminum, or plain steel tanks.
Carse: Group 20 of compatibility chart.

Wear rubber gloves, face shield, protective clothing. Have all-purpose canister mask available. Avoid contact
with liquid. Secure ignition sources.
If 1 I)IIU OCtllrt, call the Nadoaal ........ Cu.ter, IJ00...4l4-880:Z,

Remarb:
20
ANILINE
S)'11011yms- Aminobenzene: Aminoptlen; Aniline oil;
Benenamine; Benzenamine; Blue oil; Phenylamine
CHRIS Code ..
Boillq Point .. ~c
___ c ___.,
~F
Appearanee.Qdw-Oily colOrless-to-brown liquid: odor
not unpleasant
Spedfle Gra'fity-1.02
Fnez:ID& Point.. ------=.'C ~F
c ___.,
Vapor Pre.iiii'C! lO'C (68'Fl (mmH&) .. ___M_
Chemk:al Flmily-Amine Reid Vapor Pnuun (pl'ia)... _Q,QL
V11p0r Prelll&re 46'C U15'Fl (pllli) .. .....ll.2L
Poltutioli Cateaorf-USEPA -----'l__ lMO _.Q.._ Vapor De...tty !AU = 1.0) ... ___.UL
A,Utab&e Bulk Rq. 46 CFR S1lbchapler ....... ____Q__ SolubUity In W1ter .. 30%

Gr!Mie-E: Combustible liquid
Electrical Group-O
GeHnl-Poisonous gas is produced when heated. Vapor may explode if ignited in an enclosed area.
Flab Poillt ('F) .. 158 (cc)

Fluuuble u.J.tl ... LEL=1.3%; UEL=11%
Autoipidt~J~r- C'FJ ..
bdllpillllq Aaenta .....
1143
CO., dry chemical, alcohol foam, water spray
Special Ftre Proeediii'IS " Protect personnel against exposure to either the vapor or Vquid; wear full
protective clothing and self-contained breathing apparatus.
HEALTH HAZARD DATA

Hl:lll.tll Hazanl Radnp Odor Threebold (ppm) PEL!fWA lppml nvrrwA Cppml
1, 1, 3 0.5 2/Skin 2/Skin
Ge.eral-Suspected carcinogen. Poisonous by inhalation or skin absorption. It will cause cyanosis, a serious
blood condition. Class 8 poison.
SymptoiDI-Headactle, weakness, irritability, dizziness, bluish discoloration of lips and fingernails, drowsiness,
and unconsciousness.
Short E:.:poHre Toleranee-50-100 ppm probably can be tolerated for 60 minutes.
E:.:ponre Proeed.-Aemove VIctim to fresh air. Apply artificial respiration if needed. Remove any clothing wet
with aniline. Flush e!Cp()sed skin area thoroughly with water. Get medical attention as soon as possible.
Administer oxygen if available. Keep patient at rest. Wash clothing thoroughly with strong soap solution
before reuse, or destroy.
REACfiVITY DATA
St.billty-Stable. Reacts dangerously with oxidizing agents and inorganic acids.
Compatit1Wty-Ma~: Corrosive to copp&f and COP!)&r alloys. Not corrosive to iron or steel.
Caract: Group 9 of compatibility chart.

Avoid contact with liquid. Wear butyl rubber gloves, plastic protective apron and sell-contained breathing
apparatus. Secure ignition sources. May mix with sand and soda ash mixture (90-1 O), scoop up into cardboard
boxes and pack with excess crumpled paper. Then bum In open pit.
If 1 lfllll ocaan, esll die Natto.sl Relpoul Cemter, 800-4l4-8801.

Remukl:
21
ASPHALT (typical)
S)'!lllnyms- Asphalt ti1tumen; Asphalt cement; United Nations Number ...
Asphaltum; Bitumen; Judean pitch; Mineral pitch:
Petroleum asphalt: Petroleum pitch: Tars liquid
CHRIS Code
Formula-Mixture of solid or semi-solid hydrocarbons

Dollins Point.. __llj'C __...i,4'F
Appellrallce-Odor-Thick brown to black semisolid; tarry c 'F
O<b Freedn11 Point.. Yartes'C YJn8s'F
Spedl'lc Grnlty-0.9 to 1.1
___ c ___.,
Vapor Pressure lO'C (68'Fl (mmHg). .Jl&lili_
Chemical Family-Miscellaneous hydrocarbon mixture
Rold Vopo' """"re '"''' .. ..YI!iU..
Vapor Pressure .ui'C (11.5'FJ (psja).. ~
Pollution Category-USEPA - - - IMO _ _ I_ Vapor Density Wr = 1,1})... ................. ~
Applicable Bulk Reg. 46 CFR Subchapter _____Q____ Solubility in Water.. N9Qijgjble

Grade-Varies with the composition of the product.
Eleetrieal Group--O
General-There are many grades of asphalt, each with different properties. For example, the flash point may
vary from SO"F to over 400"F
flash Point !"Fl. 50 to 400 depending on grade of asphalt

Flamm11ble Limits.
Autoignition Temp. ,., Vanes
905
Extinguishin11 Agents. CO,, dry chem1cal, foam. water fog
Special Fire Procedures Water spray or foam may be ineffective because of frothing; apply cautiously.
DO NOT d1rect a solid stream o~ water 1nto hot asphalt
HEALTH HAZARD DATA

Health Hazard Rating.; Odor Threshold (ppm) PEL/TWA (ppm) TL V!TWA (ppm)
1, 2, 1 Unavailable Unavailable 5 mofm'
General-When heated to a l1qu1d stale 11 Will cause severe burns. It IS not corrosive. There is a possibility of
Skin po1soning or dermatitis by contact
Symptoms-Fumes of hot asphalt can cause nausea and dizziness.
Short J."1posure Tolerance-Unavailable
Exposure Procedures-If sp1lled onto sk1n. flood w1lh water. Do not bind up, and do not try to scrub off adhering
matenals Gel medical attent1on.
REAGnVITY DATA
Stabilit}-Most grades are stable.
Compatibilit}'-!\laterial:

Avoid contact with hot liqu1d. Wear heavy work gloves, safety goggles or face shield, PfOiective clothing for
hot liquid. If asphalt heated above 212"F is spilled into water, persons nearby risk being scalded by the steam or
hot water formed. Most grades of asphalt will present little or no problem if spilled.
If a spill oeeun, call the National Response Center, 800-424-8802.
Remarb:
n
BENZENE
Sy~t~~ay- Bem:ot; Benzole; Coal naphtha; Coal tar United Nations Number .....
naphtha; Cyctohexatriene; Phene; Phenyl hydride
CHRIS Code ..
Boi111111 Polat .. __Q'C _jl'F

___ c ___.,
Appearance-Odor-Clear colorless liquid with a typical,
pleasant aromatic odor
SpeeUk Gra'rity-0.88
Freeziq Point ..
_ _ c ___.,
_____'C ____!i'F
Vapor PreauR lO'C (68'FJ (allaH&).. _lL_

Cbemkal Flllllily-Aromatic hydrocarbon Reid Vapor Preaure (paja)..... ...1.22_
Vapor Preuure 46'C (ll!I"F) (pai.l) .. ___ll._
Pollution Catqory-USEPA ___A_ IMO ~ Vapor Dentl.ty (Air = 1,0) ... ~
Appliadtle Blllk Re&, 46 CFR SabeUpter .. .. .. __Q__ Solubility In Water .. NM!jgjbls

Grade-C: Flammable liquid.
Electrleal Group-O
General-Extremely flammable. Ignited by heat, sparks, open flame. Flashback along vapor trail may occur.
Vapor may explode if ignited in an enclosed area. Precautions must be taken to prevent static electricity
buildup.
Fladl Point ('F) .. 12 (Benzene is solid at 12'F)
Fluunable Umlts ... 1.4 to B.O%
Autolpltion Temp. ("F) .. 1076
Exttnpillllna Agent. .. COa, dry cllemical, foam, water fog
Special Ftre Procedures ... Water may be Ineffective on a fire. Fire parties must wear respiratory
protectiOn and rubber boots. In other respects, fight like a gasoline fire. Explosion hazard is great if ignition
has not already occurred and hence civil defense autt>orities should also be alerted. Cool exposed tanks
with water.
HEALTH HAZARD DATA

Healdro Hazard Rlltblp Odor Threshold (pplll) PEL;TW A (ppm) TLV/TWA (pplll)
1, 1, 3 4.68 29 CFA 1910.1028 10
General-Benzene is a known carcinogen. Benzene vapors are severely toxic by inhalation. Benzene has a
pleasant odor and narcotic effect and thus has poor warning properties.
Sympto11111-Dizziness, headache, and drowsiness.
Sllort Es.poslln! Tolenlllee-Vapor concentrations: 3000 ppm is endurable for :m-60 minutes (single exposure):
7500 ppm is dangerous in 30-60 minutes (single exposure): 20,000 ppm has been fatal in 5-10 minutes.
Exposure Procedurn-Vapor-remove victim to fresh air; if breathing is difficult, administer oxygen If breathing
stops, apply artificial respiration. Skin or eye contact-remove contaminated clothing and gently flush
affected areas with water for 15 minutes. Get medical help.
REACTIVITY DATA
StllbUity-Stable under normal conditions.
Co.npdblllty-Material: Rubber on prolonged exposure to benzene first swells, then softens.
Carao: Group 32 of compatibility ctlart.

Wear rubber gloves, face shield, plastic coated clothing. Wear self-contained breathing apparatus. Approach
from upwmd side. Avoid contact with liquid. Secure tgnition sources. Small spills may be flushed away with
water.
If I aplll OCC"Pn, Clll the N1tional Rapo111e Ceater, II00-4l4-8802.

Re~~~&rb:
23
BENZENE, TOLUENE, XYLENE MIXTURES
s,._,._ Benzene concentrate; BTX mixtures; Coal
tar light oil; Coke oven light oil; Oripolene; Light oil;
Secondary light oil
CHRIS Code ....
P-.a.-Benzenes, toluenes, xylenes and other

aromatic hydrocarbons Bolllq Poln.t.... _ _ j ' C _ _ _ 'F
A~ Yellow to amber liQuid; characteristic
___ c ___ 'F
"gasoline" odor FreeDna: Potat... ~c ---.:;.U'F
Spedfle Gn.tty-approx. 0.84
___c ___'F
Vapor PreltW'e lO'C (61'F) <-HcJ.. ......lL.._
CHmbl Family-Aromatic hydrocarbon Reid Vapor rr-re I,.Aa)...... . ___;.__
Vapor~ 46'C Clt!I'F) (..... ).. --.l.L
hllutiH C.tqory-USEPA - - - IMO ---<Ill<_ Vapor Density (Air = 1,0).......................... ___.2.1..._
Applkable &.Ilk Rq, 46 CFR Subdlapter ........ ___Q__ Sol~llty ln Water.. NtpDglblt

er.de-C: Flammable liquid.
Elec1riad ~Unassigned (Benzene, D; Toluene, 0; Xylene, D)
General-Extremely flammable. Ignited by heal, sparks, opeo flame. Flashback along vapor trail may occur.
Vapor may explode If Ignited in an enclosed area. Precautions miJSI be taken to prevent static electricity
buildup.
Flub Pelnt ('F) .. 80
na.-bk U.ttl .. 2.2 to 11.0%
AutolpldCNI Temp, ('F) .. approximately 1076
ExU.Ifi&IIIWat Aaen ..... Confined-CO.. dry chemical. Open-water, foam.
Spedal Fire Procedura .. Fife parties must wear respiratory protection and rubber boots. In other
respects, fight like gasoline fire. Explosion hazard is great.
HEALTH HAZARD DATA

Healtb Hazan! RaUnp Odor Tbral&ohl (ppm) PEL/TWA (ppm) TLV/fWA (ppm)
1, 1, 3 0.01 see benzene
Ge!leral-Benzene is a known carcinogen. Mild irritant in contact with skin; avOid repeated or prolonged
exposure. Minor inji.H)I from ingestion or inhalation--repeated contact may be more hazardous.
Sy~Watering eyes, mild skin irritation, dizziness, headache and drowsiness.
Skort Ex~MJAre Toleruce-Some evidence of carcinogenic behavior to animals has been observed for
prolonged skin contact.
Exponre ~Flush skin and eye contact at once with plenty of water. If inhaled, remove to fresh air.
No specific antidote is known. Call a doctor.
"Benzene: 29 CFR 1910.1028.
REACI'IVITY DATA
Stalllllty-Stable.
C.O.patlbiUty-M.terlal: Steel and other metals completely resistant but not copper alloy. All elastomers are
attacked and any coatlnge except baked phenolic are etripped. Most plastics are eeveraly attacked.
Carao: Group 32 ol compatibility chart.

Wear rubber glovee. face ehield, plaetlc coated clothing. Wear sell-contained breathing apparatus. Approach
from upwind side. Avoid contact with liquid. Secure ignition sources. Small spills may be fluahecl away with
wato<.
If~ .,W oecus, call the Natioal RelpoDie Center, 100-424-Mn.

Relnarb: t Unavailable
:t Unueigned
24
BENZYL ALCOHOL
s r - r - Benzene carbinol; alpha-Hydroxytoluene; U11lled Nadou Nber...
Phenyl carbinol; Phenyl methyl alcohol
CHRIS Code ..
BoJIIq Polllt.. --.2QS'C __!Ql'F

Appearnee-Odor-Colortess liquid; mild pleasant
___ c ___F
aromatic odor FreezJq Polnt.. ~c ______5'F
Speclfte Graflty-1.05 at 1S'C
___ c ___ F
Vapor Pr..u.re lO'C (68'F') 1-tf&).. ~
C1lemkal Family-Aromatic alcohols Rehl v apof' Preaure ep.D) ....................... ... ____!__
Vapol' Pr.....-e 46'C (115'F> CpU)... ___i_
Pollutfoll Calepy-USEPA - - - IMO ~ Vapor Drealty (Air = 1.01 .......................... ~
App)kabte Bulk Res. 46 CFR S..beU.pter ....... _____Q__ SolubWty ill Water.. 4 4%

Gnde-E: Combustible liquid
ElectrkaJ Groap-0
GeDerai-Can give off toxic combustion products in a fire.
Flub Potat ('F) .. 220 {oc); 2.3 (cc)

..,__ble Ullll.tl .. Unavailable
Alltoipld011 T-p. ('F) ..
Esttnp~~Wq Aentl ... "'
Alcohol foam, dry chemical, carbon dimclde
Spedal Fire Proc:edura .. Water and foam may cause frothing. Wear seH-contained breathing apparatus,
protective clothing. Use water to keep tanks cool.
HEALTH HAZARD DATA

Heal.tb Huard Ratlnp Odor 1'bmiMIId (ppa) PEL/fWA (ppM) TLV/IWA (ppM)
Unavailable 5.5 Unavailable Unavailable
General-AVOid direct contact with r1quid and prolonged exposure to vapor-absorbed through sl<in.
SymptoJu-lnitation to eyes, skin. Vapor irritates upper respiratory tract and produces headache, dizziness,
nausea. Ingestion causes abdominal pain, vomiting, diarrhea.
Sbort bpo~:are Tolen.Dee-Must have adequate ventilation or use respiratory protection.
bponre PI'Gceda~Eye contact: Flush with water for at least 15 minutes; call physician. Skin contact: Wash
with soap and water for 15 minUtes. Inhalation: Remove the fresh air, give oxygen if necessary; call
physician. Ingestion: II conscious, give water, Induce vomiting, contact physician.
REACTIVITY DATA
Stl.butty-Generally stable. Slowly oxidizes in air and oxygen. Reacts with mineral acids generating heat; reacts
with strong oxidizers.
Co!apadbutty-Carried in stainless steel or phenolic resin lined mild steel tanks. Noncorrosive to steel and most
metals but corrodes aluminum at high temperature. Will attack some non-flourinated plastics, will not attack
polypropylene.

Wear goggles, lace shield. Cover small spills with absorbent (sand, sawdust); dispose. Dike large spills for
pumping to storage tank; dispose or reclaim.
Remub: t Unavailable
It 1 JpW oeean, call. tile NatloallteipoMe Cellter, 800-4lt IIOl.
....
25
BENZYL CHLORIDE
Syno11y-- Benzene, chloromethyl-; (Chloromethyl)
beru:eoe; alpha-Chlorotoluene;
omega.Chlorotoluene
CHRIS Code ...
BoU1111 Point... . _____lli'C ___.W.'F

Appeapee-Odor-Colorless to slightly yellowish liquid; c 'F
pungent, aromabc, irritating odor FreeDna Point.. ---=3Qc --::]QF
Speclfk Gra"rity-1.1 at 25' /25'C
c ___'F
V11por Pre.ure ZO'C (68'Fl (mmll&).. ___.i_
a.e.1aa1 F-ily-Halogenated hydrocarbon ReJd Vapor Prellure (pliaL. ___2&Z_
Vapor PreuiU'e 46'C (IU'F) (JII.I>-- ____Q.2i,_
Pollution Cateaory-USEPA _a__ IMO _a__ Vapor DeQity (Air = 1.0)... .................. ~
Applkallle Bulk Rea;. 46 CFR S.bcba,ter ..... ____Q__ SolubWty 111 Wter.. Nea!kib!@

Gnwle-E: Combustible liquid
Electrical Group-O
Geaeni-Moderate fire hazard. Keep away from open flame or ignition sources. Irritating gases are produced
when heated. Decomposes with water to produce hydrogen chloride fumes.
Flull Point ("F) .. 165 (eel

Flam-ble U111ltll .. LEL~1.1%, UEL-Unavailable
AutoipltJOD Tep. ('F) 1065
Enipitllln& AIIQU. CO,, dry chem1cal, water fog
Special Fin Proeedura ... Use complete personal protective clothing. Wear self-contained breathing
apparatus for indoor fires. Water mist may be used, but in farge quantity to hold down hydrogen chloride
fumes and flush away acid
HEALTH HAZARD DATA

Hattb Huard lbtlnga Odor Threshold (ppm) PEL;TWA (ppm) TLV!TWA (ppm)
4, 2, 4 0.01 1 1
General-Suspected carc1nogen Vapor e~tremely irntating. Liquid causes bums.
SymptOJDt-Vapors are 1rntat1ng to eyes and resp1ratory tract, causes tears and coughing, possible loss of sight.
Liquid causes skin 1rntation resulting 1n burns on prolonged contact.
Sbort E:rJI'I)Surt Toltr&llct-10 ppm lor 30 minutes
Ex~urt PrOidurn-Vapor-remove v1ct1m to fresh air immediately, if breathing stops apply artifiCial
respiration. Skin or eye contact-remove contaminated clothing and flush with large amounts of water for 15
mmutes. Get medical advice or anent1on.
REACI'IVITY DATA
Shlbillty-Unstabihzatlon results m rap1d condensation reaction in presence of particular metals. liberates
hydrogen chlonde from decomposition reaction with water.
CompiitibUity-Miterial: Avo1d copper, aluminum, iron, zinc, magnesium and tin; violent polymerization will
result. Nickel is recommended
Cargo: Group 36 of compatibility chart

Wear full protective clothing, rubber boots, face shield, eye protection, self-contained breathing apparatus.
Immediately flush with large quantities of cold water. Freely ventilate to remove odors. Sodium carbonate or lime
can be used it water is unavailable. Remove all contaminated clothing and thoroughly clean.
If spnt ocrun. ell! tbe N1tiOJJIIl Reapo~~te Cater, 800-424 88G:Z.

Re-.rb:
26
BUNKER C
S~Fuel oil no. 6; Heavy Industrial fuel Oil; UJdled N.tioal N...ber ............................ ___.1__
Residual fuel oil no. 8
CHRIS Code ............................................... ~
--
'-ala-Indefinite mixture
11oi1iJ11 Poiat .. ~c ~F
_ _ _ 'C 'F
==F
A,_...ce--dor-Very 1110008, dark colored liquid;
FreedQ roat ...................... ___rc - -.
Spedflc Gra"rlty--0.92 to 1.07 ___ c
VlfOI' ~ 20'C (61'1') (..JIK) .. ....2JM2.._
a.e.lcal F..UJ-Misc. hydrocarbon mixture ReW Vapor Pn11an (plla) .................... ~
VlfOI' Pre1Are 46'C 1115'F) C,.a.> ............ _QJft_
PolhalkNI CUeaorJ-USEPA - - - IMO __L_ Vapor DeDiib' (Air = 1,0) ......................... ___..1..___
Appllc:aWe a.tk Rea. 46 CPR S.tdlapter ........ ___.IL_ SohlbWty Ia Water .... NfK!!Iqlble

Deetrk:lll Grw,_o
Geaenl-Muat be heated to sustain combustion.
__
Plala Poillt ('F)
n....ble IJJdtl ...
......................
.............
Alltoipltlml Tp. ('F') .............. 765
EJ:tiJipillliq Apiatl ....
150 to 430 (cc)
1 to 5%
Foam, CO.. dry chemicals

............... Water may be ineffective on fires.
....................
Unavailable
HEALTH HAZARD DATA
Odor 'I1IniiMIId <pp.)
Unavailable
PEL/TWA (pplll)
Unavailable
TLV/I'W A (ppm)
UnavaWable
Geneni-AvOid breathing vapor.
S,.,._tieadache, r:aausea, dizziness, vertigo, unconsciousness.
Short ~ Tolerance-Unavailable
E][JIOIIIft Procedarel-lnhalation: Remove victim to fresh air, prevent ch1lllng, and apply artificial respiration if
breathing has stopped. Get immediate attention if victim Is overcome by vapors.
REACTIVITY DATA
SUbWI)'-Very stable.
eo.,.tRIOitJ-Materlah Compatible with moat materials Of construction.
caqo; Group 33 of compatlbHity chart.

Wear rubber glOves, face shield, protective clothing. Have all-purpose canister mask available. can soak up
spill with paper, sawdust. rags, etc.
U a .,W ocnrs, call tile Natloula.,._ c.tv,I00-424 IIIIOl.

; Unassigned
27
BUTADIENE
s , _ , _ Blettlylene; Bivinyl; 1,3-Butadiene: alpha, United Nat&o. Nmber...
gamma-Butadiene; Oivinyl; Erythrene; Pyrrolylene;
Vinyl ethylene
CHRIS Code ..
Formu~H,, or CH. = CHCH = CH.

BolllqPolnt.. ~c ~F
~lorless gas or liquid; mild, c 'F
aromatic odor Freedq Point.. -109'C -164'F
Speclnc Grnity-0.62 at 20'C (a liquid) ___ c ---
Vapor Prealare :ZO'C (61'F) (mmHIJ) ... ..J1iL.
Cbemical Famny-Unsaturated hydrocarbon Reid Vapor Prature q.la)... ____Al_
Vapor Pr_.-e 46'C (li5'F) (pita).. ~
Pollatlon Cateaory-USEPA - - - IMO ___...___ Vapor l>enllty (Air = I.OL __l.H_
Applic:llble Blllk Rea. 46 CFR Subdaapter ........ __Q__ Solubility In Water.. Neg!lqlble

Grade-Liquefied Flammable Gas (LFG)
Electrical Group-8
General-Unless flow of gas can be stopped, extinguiShing a butadiene fire may permit accumulation of an
explosive concentration of vapor, and subsequent explosion or re-flash. Fire may cause violent rupture of
tank.
Flall Potat ('F) ... -105
Flammable Limits .. 2.0 to 11.5%
Autolpltion TemJ. ('F) .. 842
Ell:till8llll1Uill Asentl .. Stop flow of gas: CO,, dry chemical, water fog
Special Fire Procedure~ .. Keep buming tank and adjacent tanks cool with a water spray. Wear full
protective clothing and self-contained breathing apparatus.
HEALTH HAZARD DATA

Healtb Hazard RlitlDp Odor lbresbold (ppm) PEIJIWA (ppm) TLV!IWA (PJIIII)
1,1,1 above 1000 unavailable 1000
General-Suspected carcinogen. Liquid or cold gas may cause Skin or eye injury similar to frostbite.
Symptoms-Inhalation: dizziness, headache. Skin contact: frostbitten areas Will appear white. Irritating to eyes
and respiratory tract.
Sbort Exposure Tolennee-8,000 ppm was found endurable for 8 hours with only slight irritation of the eyes and
upper respiratory tract.
Exposure Proeedure.-Vapor-remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or
eye contact-remove contaminated clothing and gently flush affected areas with water for 15 minutes.
Protect frostbitten areas from abtasioos and mechanical damage. DO NOT RUB. Get medical advice or
attention.
REACTIVITY DATA
stabWty-Must be inhibited to prevent polymerization. Forms unstable pero>Cides In presence of o>eygen and/or
iron rust.
Comp.tibJIIty-Materlal: Unsafe in contact with acetylide-forming materials such as monel, copper or copper
alloys.
Car10: Group 30 of compaf1blllty chart.

Wear rubber gloves, face shield, protective clothing, and self-contained breathing apparatus. Secure ignition
sources. The spilled liquid will boil away leaving no residue.
If a lfiU oec11111, call tbe Natioul. RCIIpOIIR Cater, 800-4l4-880l.
28
nBUTANE
S)'DOIIym- Butane; Diethyl; Methylethylmethane United Nad- Number ...
Botu.1 Pomt .. ~c _______al, 'F

Ap~Odor-CoiOI'Iess; odorless gas c 'F
Freezin& PoiDL -J38'C -21Z'F
Specllk Gra'f'lty-0.58 at oc (a liquid) ___ c ___ F
Vapor '"'-re lfi'C (68'F) (mmHS) .. --H.iKL
ChenUul Family-Saturated hydrocarbon Reid Vapor Pr-..re (pl:la)... ~
Vapor Preaure 46'C (115'F) (pita)... ~
Pollution C.teaory-USEPA _ _ _ IMO ___gu._ Vapor Deaalty (Air = 1.0).. ___z.QL_
AppUc1ble BuJk Rea. 46 CFR Subchapter ...... ___Q._Q_ SolubiHty ia Water.. ln3Qiybla

Grade--Uquefied Flammable Gas (LFG)
Electrlcal Gro.p--0
Geaeral-Unless the flow of gas can be stopped, extinguishing a butane fire wilt permit acCl.lmulation of an
explosive concentration of vapor, and subsequent explosion or re-flash.
flub Point ('F) .. -76

Flumuble Umlb .. 1.9 to 8.5%
A11tolpitlon Temp. ('F) .. 761
Extinaull.blaa Apnu .. Stop flow of gas; CO., dry chemical, water fog.
Special Fire Procedures .. Keep burning tank and adjacent tanks cool with a water spray. Stop flow of
gas.
HEALTH HAZARD DATA

Health HPIU'd Rattnp Odor Threlhold {ppm) PEL;TW A (ppm) n. v rrw A (ppmJ
0, 0, 0 5000 800 800
General-Produces drowsiness. Simple asphyxiant. Liquid or cold gas may cause frostbite.
Symptoms-Dizziness and drowsiness.
Short Eli:ponre Toleranc:e-10,000 ppm (1 %) for 10 minutes will cause drowsiness.
Expo11ure Pn:x:edura-Remove victim to fresh air. II breathing has stopped, give artificial respiration. II the liquid
has spilled onto the skin, points Of contact may be frostbitten: handle gently and protect from mechaniCal
damage. DO NOT RUB. Get medical attention.
REAcriVITY DATA
Stability-Stable product.
CoiiiPIII:IIIIUty-Materlal: Non-corroSive to most materials of construction.

Wear rubber gloves, face shield, protective clothing. Have all-purpose canister mask available. Secure ignition
sources. The spilled liquid will boil away rapidly, leaving no residua.
If a 1piU 0CCUJ11, call the Nadoul RtlpODBe Cater, 800-tl4-8101.
29
Iso-BUTYL ACETATE
s,..-,.- Acetic acid, iso-butyl ester; Butyl acetate; UnUed Nadoa N ...ber...
Isobutyl acetate; 2-Methylpropyl acetate;
2-Methyl-1-propyl acetate; bela-Methylpropyl
ethanoate
CHRIS Code .. _JBL
"{iso-, n-)" ____8A2L_
Formula-CH.COOCH.CH(CH,).
BoUina Poillt .. _____lljj'C ~F
Appearmce-Odor-Colorless liquid; pleasant, fruity odor ___ c ___ 'F
Freeana Point .. -=l.QQ'C ---=.H'F
Speclfk Gralty-0.87 ___ c ---
Vapor Pra.ure lO'C (61'FJ <-lfal ..
Reid Vapor Preaure (paa)...
Vapor Pra.ure 44i'C (115'Fl (pebi) ..
Pollutioll Catqory-USEPA _____12__ IMO ____jL_ Vapol' Dellllty (Ail' = 1.0) ...
Applicable Bulk Rq. 46 CFR S.bcbapteT ....... .....Q..Q_ SolubWty bl Water ..

Electrk:al Group-O
Gettenl-Flashback along vapor trail may ocpur. May explode if ignited in an enclosed area.
FlMII Point ('F) ..

Fii.Julable UmiQ ..
Autolpltion Temp. ('F) ..
.
2 to 15% (approx.)
793
Exd~t~~~blbial Apn.tl .. CO,, dry chemical, alcohol foam, water fog
Special. Fire Procedlll'el ... Use of dry chemical where it can get into a tank of butyl acetate is not
recommended. Fife involving spills outside of tanks can be eKtinguished with dry chemical. Water may be
ineffective. Cool adjacent tanks with water spray.
HEALTH HAZARD DATA

Haltb H~Uanl Rartnp Odor 1'hrelbold (ppaa) PELffW A (ppm.) TI..VffWA (ppm)
1,1,2 10 150 150
Getleral-Vapor irritating to eyes, nose and throat. Liquid irritating to skin and eyes.
S)'lllptollll-lnhalalion of vapors will cause headache, irritation of respiratory passages and eyes, dizzineaa, and
nausea.
Short Expopre Tolen.nce--200-300 ppm produces some nose and eye irritation upon brief exposure.
Expos&~re
Procedures-Vapor-remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or
eye contact-remove contaminated clothing and gently Hush affected areas with water for 15 minutas. Ge1
REACTIVITY DATA
StabJIIty-Generally stable, however, will slowly decompose on standing to form acetic acid and isobutyl
alcohol.
ContJN1tlbWty-MstcrW: Softens and dissolved rubber and many plastics.
Cvao: Group 34 of compatibility chart.

Wear rubber gloves, face shield, protective clothing. Have all-purpose canister masks available. Avoid contact
with liquid. Secure ignition sources. For a gas leak from a faulty tank, keep concentration of gas below the
explosive mixture range by ventilation.
If lpill otc:W"t, c:aU lhe Nstioul Rapoue Ceater, 800-4l4-8801.

Reaaarb! Vapor Pressure: 10 mmHg at 12.8 C.
30
nBUTYL ACETATE
S)'11011)'111t- Acetic acid; butyl ester: Butyl acetate:
normal-Butyl acatate; Butyl ethanoate
CHRISCo* .. .....lll<JL
"(iso-, n-r ____aM_
Bolllna; Pollll .. ~c ~F
c _ _ _ F
..\~-Colorless liquid; pleasant, fruity odor
FreeDq Point .. -11'C --=.l.QZ'F
Spedtk Gnl-.ttr-o.ee
_ _ c _ _ _ F
Vapor ~re lO'C (61'F) (-"a) .. ___u_
Olemkal Famtly-Ester Refd V!lpOI' PreiMre (,.U) ... ~
Vapor PreiMre 46'C Ut5'F') (pm) .. _Jl.L_
PoUutlH c.tepy-USEPA ____Q__ IMO _.Q__ v.,.- ne.Jty <Air = 1.01 ... ___4.lL_
Applleahle Ballr. Rea, 46 CFR SubeUpter ....... ____Q,_Q_ Solubllity I W.ter .. SliaM

Elerirkal GI'QIIP-0
Geoeni-Volatila, wtth a low flash point. Flashback along vapor trait may occur. Vapor may aKPiode it ignited In
an enclosed apace.
F'IMII ..... ('F) .. 90

Flammable UDdb .. 1.4 to 7.6%
Autolpltioll Tea~p. ('F) .. 790
E:a:tlD....Iq Apllt.. CO., dry chemical, alcohol foam, water fog
Spedal Fire Proeedurn .. Use ol dry chemical where it can get into a tank of n-butyl acetate is not
recommended. Fires Involving spills outside of tanks can be extinguished with dry chemicals. Water may be
ineffective. Cool exposed tanks with water spray.
HEALTH HAZARD DATA

Healtlro Haanl Ratiap Odor Thresbokl (ppm) PEL/TWA (ppm) 1LV/1WA 1.,....1
1, 1, 2 10 150 150
General-Low level of toxicity. Vapor irritating to eyes, nose and throat. Liquid irritating to skin and eyes.
Symptong-Headache, irritation of respiratory passage and eyes, dizziness, and nausea.
Sltort Exposure Toleranee--200-300 ppm produces some nose and eye irritation upon brief exposure.
Ezpo~~~reProted11ra-Vapor-remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or
eye contact-remove contaminated clothing and gently flush affected areas with water for 15 minutes. Ge1
medical advice Of attention.
REACI1VITY DATA
Stabtuty-Stable, however, will hydrolyze (react with water) on standing to form acetic acid and n-butyl alcohol.
Co.pUlbfllty-Materlal: Softens and dissolves rubber and many plastics.
c.,..: Group 34 of compatibility chart.

Wear rubber gloves, lace shield, protective clothing. Have all-purpose canister mask available. Avoid contact
If 1 .,01 oc:c:wn, ad! the National Rapo.e Center, 800-4:14-8801.
Remarb:
31
sec-BUTYL ACETATE
s,..oa,._ Acetic acid, 1-methylpropyl ester: Acetic Vatted Nattoa N . .bes'..... .
acid, sec-butyl ester, 2-Butanol acetate;
1-Mathylpropylacetate
CHRIS Code .. .... __IILL
_mc ~-F
A~lorless liquid; mild, pleasant odOf c 'F

F'rMzbla PoJat .. -zac -too'F
Spedfle Gn..tr~-89 c ---
Vapor l'reaure lO'C (ISI'P) <-a,> ---2ll.L
Clemlcal FI.IIUiy-Ester Reid Vapor PreiMre (...)... ..... ....l.lL
Vapor~ 46'C (llS'F.I (....) .. _u_
Pollutm. C.tqory-USEPA ----'L._ IMO _.1L_ Vapor J>eal'l:y (Air = 1,0).. ..... ---.4.2....
Ap,lk:Ule lhllr. Re8- 46 CFR SubcUpter ....... ----'L._ SolaWUtr ln Water . SJ!sjtt

~D: Combustible liquid
Eaeetrlcal Gro.p-0
Guerai.-Volatile with low flash point. Flashback along vapor trail may occur. Vapor may explOde if ignited in an
enclosed area.
F1MII Polat ('F) ...

l'lammUie Ualltll ....
to
1.1 9.8%
Aatollaltlon Temp. ('F) .. 750 to BOO
Extblpidllq Apaq ... CO.., dry chemical, alcohol foam, water log
SpeclaJ Fire Prvc:edurel .. Use of dry chemical where It can get Into a tank of butyl acetate Is not
recommended. Fires involving spills outside of tanks can be extinguished With dry chemical. Water may be
ineffective. Cool exposed tanks with water spray.
HEALTH HAZARD DATA

Health Hazard lbtiDp Odor lb.-esltold (p..-J PEL/I'WA q.p.) TLV/I'WA (ppm)
1, 1, 2 be~ 200 200 200
General-Vapor irritating to eyes, nose and throat. Liquid Irritating to akin and eyes.
Sym...-Headache, irritation of respiraiOI)' passages and eyes, dizziness, and nausea.
Sltort Exponn= Tolerance-300 ppm
EJ:...,.un= PnlcedlllJ'ei-Vapor-remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or
eye contact---femove contaminated clothing and gently flush affected areas with water for 15 minutes. Get
REACfiVITY DATA
StlibJIIty-Stable, however, will hydrolyze (react with water) on standing to form acetic acid and secbutyl
alcohol.
Co.patiiHUty-Material: Softens and dissolvea rubber and many plasticl.
euao: Group 34 of compatibility chart.

Wear rubber gloves, lace shield, protective clothing. Have all-purpose canister mask available. Avoid cootact
with Hquid. Secure ignition sources.
If a spW ocnra, call tlte Natloul Rl:lfiOIIM Cealer, 100-424-IIOl.
32
lsoBUTYL ACRYLATE
Sy-)'lnl-Acrylic acid, iso-butyl ester; Isobutyl Uniled Nati- Namher ...
acrylate; lsobutyt-2-propenoate; 2-Melhyl-1-propyl
acrylate
CHRIS Code ... ___at,[_

"(iso-, n-)" ---ll6B...._
Fonaala-CH. =CHCOOCH,CH(CH,).
BoDina PWnt.. ______u:zc ______211'F
Appeu'Piee-Odor-Colorless Uquid; sharp, fragrant odor c 'F
F'Nedll& PoUlt.. ~Bl'C -ZA'F
Speclfk Gra,.lty-0.88
___ c ___ F
Vapor ~ lO'C (61'F) (mmHI).. ___lQL_
ReWI Vapor Pnaure (plia)..... ____2.!._
Vapor Pre.ure 46'C <US"F') (ptla).. ___2.L_
PoUuU011 CateaorY-USEPA - - - IMO __.ll_ Vapor Dellll.ty (Air = 1.0)... .... ~
Applklable Balk Rq. t6 CFR Subdnapler ....... ___Q__ Solubility ill Water.. $light
FIRE 4 EXPWSION HAZARD DATA

Electrleal Gr~~~~p-D
Ge.enl-The main hazard is its very easy polymerization. Ignited by heat and open flame. Fire may cause
violent rupture of tank.
Flub PoiDt ('F). .... :" 86

Fla.-ble Umlbl .. 1.9 to 8.00%
A.tolpltiOD Temp. ('F)- 644
E:dillpillliq; Apnb .. Ceh, water log, dry chemical, loam
Special Fire Proceduns .. Provide fire fighters with breathing apparatus. Keep tank cool with water
spray.
HEALTH HAZARD DATA

Health Hazan~ Radnp Odor 'Illrabold (ppm.) PEL/TWA (pp!ll) TLV/TWA {ppm)
1,1, 1 Unavailable to Unavailable
General-Vapor irritating. Avoid skin contact with liquid.
Symptollti-Siight rednass from skin contact with liquid.
Sllort Ex)IOIIure Toleraaee-Unavailable.
Exlti*Q'e Procedares-Skin or eye contact-flush immediately with large quantities of water for at least 15
minutes. If any initation or injury develops after washing, prompt medical attention should be obtained.
Vapor inhalation-remove victim to uncontaminated area and obtain prompt medical anention If any Illness
is observed.
REACfiVITY DATA
Stability-Polymerizes readily on heating. Must be inhibited.
Complltlbillty-Material.: Compatible with most materials of construction.

Wear rubber gloves, face shield, full protective clothing. Have all-purpose canister mask available. Secure
ignition sources. Small spills may be flushed away with water.
If a qNU oecun, Clll.l the Natl.onaJ RelpOIIM Cealer, 800-4l4-18Cll.
33
nBUTYL ACRYLATE
Synonyma- Acrylic ac1d, nbutyl ester; Ualted Natiollll NumbH ...
n-Butyl-2-properlOale; 2-Propenoic acid, butyl ester
CHRIS Code .. ___lillL_

"(iso-, n)" --B.aB_
AppeariUKe-Odor-Colorless liquid; sharp, biting,

Boillna Point ..
c ___.,
__ill"C ___,Jj)Q"F
ester-like odor.
Specific Gruity-0.90
Freell!ing Point .. -64'C
c ___.,
~F
Vapor Preuure lO'C (68'FJ (111mH&) .. ____u_

Cbemiul Family-Acrylate
Pollution Catel(lry-lJSEPA - - - IMO ____L_

Reid Vapor Preure (&Mia) ..
Vapor P.--re 46'C UHI'F') IP'lal ..
Vapor De.Wty (Air = 1.0)....
-=--
___Q.L_
.....ll_
Applluble Bulk Rea. 46 CFR Subchapter ___Q__ Sohoblllcy In Water Negljpiblt

Grade-D: Combustible liqu1d
Electrical Group-O
General-The ma1n hazard 1s 1ts very easy polymerization Ignited by heat and open flame. Fire may cause
violent rupture ol tank.
Flub Point ('FJ .. 120

Flammable Limits 1.5 to 9.9%
Autolgnition Temp. CFl 567
Ext1nguisbin11 Agents Carbon dioxide, dry chemical, alcohol foam, water spray.
Special Fire P~edura Provide tire fighters with breathing apparatus. Keep tank cool with water
spray
HEALTH HAZARD DATA

Healtb HUIU"d Ratings Odor Threshold (ppm) PEL!IWA (ppm) nv!IWA (ppm)
1, 1,1 Unavailable 10 10
General-Vapor and liqUid are irritating.
Symptoms-Eye Irritation; watenng of eyes and salivation when Inhaled.
Short Exposure Tolel'1lllce-Unavailable.
Exposure P~edura-Skin contact should be washed thoroughly with soap and water. In case of eye contact,
flush wtth water tor 15 minutes. Get medical attention or advice.
REACTIVITY DATA
Stability-Polymerizes read1ly on heating. Must be inhibited.
Compatibility-Material: Compatible with steel, stainless steel or aluminum.
Car11o: Group 14 o! compatibility chart.

Wear rubber gloves, face shield, lull protective clothing. Have all-purpose canister mask available. Avoid
contact with liquid. Secure ignition sources.
If 1 1pill occun, WI tbe National Rnpoue Center, 800-4l4-880l.
Retnrks:
34
Iso-BUTYL ALCOHOL
SynoayiiUI-Aicohol C-4; Fermentation butyl alcohol; United NatioiUI Number ...
1-Hydroxymethylpropane; IBA; tsobutanol; Isobutyl
alcohol; lsopropylcarbinol: 2-Methyl-1-propanol
CHRIS Code ..
Formula-(CHs)CHCH,OH
Boiling Point ____llll'C ~F
Appearance-Odur--CoiOI'Iess liquid; sweet odor
___ c ___ .,
Freezing Point.. ~c
Speclfte Grarity-0.81 at 15'C
c ----=..12:'F
___.,
Vapor Pressure lO'C (68"FJ (mmH!V . ____jL_
Cbende.l Family-Alcohol Reid Vapor Preaure (psia).. ----1..._
Vapor Pres~sure 46'C (ti5"Fl (psia) _.Q..i__
PoUution CateK<Jry-USEPA _ _ _ IMO ___llL_ Vapor Denllty (Air = l.OJ. .. ... ..... ............ ____2..___
Appliable Bulk Reg. 46 CFR Subchapter ..... _____Q______ Solubility In Water.. Moderate

ElectrteaJ G!'oup-D
General-Ignited by heat or open flame. Flashback along vapor trail may occur. Vapor may explode if ignited in
an enclosed area.
Flub Point ("FJ 100

Flanunable Limits. 1.7 to 10.9% at 212"F
Autoip.ltion Temp. CFJ .. 825
Extini!Uiablnll A~nts .. co,, dry chemical, alcohol foam. water log
Special Fire Procedures Water may be 1neffective.
HEALTH HAZARD DATA

HeaJtb HIWird RatinRS Odor Threshold (ppm) PEL/TWA I ppm) TLV!TWA (ppm)
1, o. 1 Unavailable 50 50
General-Not hiQhly toxic. Eye contact should be prevented, and prolonged or repeated exposure to the vapors
should be avoided. Prolonged or repeated skin contact may cause defatting of the skin and may produce
dermatitis from daily contact
Symptoms-Headache and dizziness
Short Expo~~ure Toleran-150 ppm
Exposure Procedures-Vapor-remove v1ctim to fresh air; if breathing stops, apply artificial respiration. Skin or
eye contact-remove contam"1nated clothing and gently flush affected areas with water for 15 minutes. Get
REACfiVITY DATA
St.bllfty-Stable.
Compatibility-Material: Compatible with plain steel Water-free isobutanol reacts with aluminum at
temperatures above 120"F
Carao: Group 20 of compatibility chart. See also Appendix !-Exceptions to the Chart.

Wear rubber gloves, face shield. protective clothing. Have all-purpose canister mask available. Avoid contact
Ir a spill Ottlll"s, call the National Response Center, 800-4N-8802.
Remarks: t Unavailable
35
n-BUTYL ALCOHOL
Synonym~- Alcohol C-4; Butanol; 1-Butanol; n-Butanol;
Butyl alcohol; Butyric alcohol; 1-Hydroxybulane;
NBA; Propyl carbinol; n-Propyl carbinol
CHRIS Code ..
Formula-CH,(CH:r.),OH
Bolllna: Point... __uzc _____wF
Appearmw:e-Odor-Cotorless liquid; pungent alcohol c 'F
od~ Freez.lai Point..... -84'C -120'F
Specific Grnity-0.61 ___ c ___ "F
Vapor Pre..ure lO'C (611'F) (IIIDIHK) . __j.L_
Cbemiatl Family-Alcohol Reid Vapor Preuure (pita)... __,Q,a__
V&JIOI" Preuure 46'C (lt5'F) (IJilJ.).. ~
Pollution Cate1ory-USEPA _____Q__ IMO ___llL_ Vapor Denalty (Air = l.OL ............... ~
Applicable Bulk Re11. 46 CFR Subcllapter ...... _____Q__ Solubility ID Water.. Mgdtp

Grade-D: Combusltble liqu1d
Elntrical Group-O
General-lgmted by heat, sparks. or open flame. Flashback along vapor tratl may occur. Vapor may explode If
1Qn1ted 1n an enclosed area.
Hash Point rli. 103

f.1ammable Limits 1.4 to 11.2%
Au!Oignltlon Temp. <'Fl 690
Extinguishinll A11enb Dry chemical, CO,, foam, water fog
S~Jial Fire Procedures Water and alcohol foam may be ineffective on fire.
HEALTH HAZARD DATA

Health Ha2.11rd Ratinp Odor Threshold (ppm) PEL/TWA (ppm) TL V /I'W A (ppm)
1. 1, 2 25 50/Skin 50/Skin
General-Causes significant injury to the surface of the eye. Repeated skin contact may have a defatting action
on the sk1n and may produce dermatitiS from daily contact. Avoid prolonged and repeated breathing of
vapors
Symptoms-Headache, diZZiness and respiratory irritation.
Short Expusul"f! Tolerance-ISO ppm
Exposure Proceilures-Vapor-remove victim to fresh air, if breathing stops, apply artificial respiration. Skin or
eye contact-remove contaminated clothing and gently flush affected areas with water for 15 minutes. Gel
medical adv1ce or attention
REACTIVITY DATA
Stability-Stable.
Compatibility-Material: Recommend carbon steel tanks, valves, and piping. Water-free n-butanol reacts whh
aluminum at teJlllaratures above 120"F
Carao: Group 20 of compatibility chart. See also Appendix 1-Exceptions to the Chart.

If 1 1plll occurs, call the Natlolll1 Relponle CeDter, 800-424-880:Z.

RemarQ:
36
sec-BUTYL ALCOHOL
Synony-- Alcohol C-4; 2-Butanol; sec-Butanol; United Nat'- NuMber...
Butylene hydrate; Ethyl methyl carbinol;
2-Hydroxybutane: Methyl ethyl carbinol; SBA
CHRIS Code.
Formula-CH,CH.CHOHCH,
BoUi111 Polat .. __asc ----Zll"F
Appeannee..Odor-Colorless liquid; strong, pleasant
""'"
SpeeUk: Gra"rity-0.81
Freezln& PolaL.
c
-10&"C
_ _ c ___..
-185'F
"F
Vapor Pret.ure ZO'C (68'F) CmmHI) ..

Cbe111ka1 Family-Alcohol Reid Vapor Preullft (ptla).... --..2..2.._
Vapor Preuure 46'C (115'F') (plla).. ---1..3__
PoUutlon CateaorY-USEPA - - - IMO ___ill_ Vapor De.lty (Air = 1.0)... .............. --...2&._
Appllable Blllk Rea. 46 CFR Subch-,ter ...... ____Q__ SolubUity I Willer.... ModtrJte

Grade-C: Flammable liquid
Eleetrlcal Group-O
Geaerai-Dangerous when exposed to heat or flame. Flashback along vapor trail may occur. Vapor may
explode if ignited in an enclosed area.
Flub Point ('F). 74

Fluunable Umits .. 1.7 to 9.8% at 212'F
Autolgnldoa Telll)l. ('F). 763
ExdoiiJlihlnl Allflltli .. C02, dry chemical, alcohol foam, water fog
Speclal F1re Procedures .. Water may be ineffective on fire.
HEALTH HAZARD DATA

Health Huard RatiRglil Odor Threshold (ppm) PELJTW A (ppm) TLV!TWA (ppm)
1, 0, 1 Unavailable 100 100
General-Avoid inhalation of high vapor concentrations. Prolonged or repeated skin contact may cause defatting
of the skin and may produce dermatitis from daily contact.
Symptoms-Headache and dizziness.
Short Exposure Tolerance-150 ppm for 30 minutes
Exposure Procedure.-Vapor-remove victim to fresh air. Give artificial respiration if breathing stops. Skin or eye
contact-remove contaminated clothing and gently flush affected areas with water for 15 min. Get medical
help.
REACfiVITY DATA
Stability-Stable.
Compatibility-Material: Usual materials of construction are suitable.
Cargo: Group 20 of compatibility chart. See also Appendix !-Exceptions to the Chart.

with liquid. Secure ignition sources
If a pill occun, c:all tbe National Reapon11e Cuter, 800--4l4-880l.

Remarks: V&PQI" Pressure: 31 mmHg at 32"C.
37
tart-BUTYL ALCOHOL
Synonyms- Alcohol C-4; tart-Butanol; United NatioRII Number ..
2-Methyl-2-propanol: TBA: Trimethyl carbinol
CHRIS Code ..
Formula-(CH,).COH
Boiling Point.. ~c _____lll'f
AppearanfeOdor-Colorless liquid wr crystalline solid: c "F
pungent. camphor-like odor Freezing Point ______zf!'C _____TI!"F
Specific Gravity-0.78 at 26T (a liquid) ___ c 'F
Vapor Pressure 20"C (68'F) (mmHg) .. ____aQ&.._
Chemical Family-Alcohol Reid Vapor Pre$Sure (p!Jia).. ____1.___
Vapor Pressure 46"C (115"FJ (psia). ---Z.L
Pollution Category-USEPA - - - IMO __1_11_ Vapor Dens.ity (Air = l.(l).. ____2&__
Appliuble Bulk Rtll. 46 CFR Subchapter. _Q_______ Solubility In Water. Complete

Grade-C. Flammable hquid
Electrical Group-O
~neral-Dangerous when exposed to heat or flame Flashback along vapor trail may occur. Vapor may
explode 1f ignited 1n an enclosed area
1-lssh Point (1-1 52 (cc) (terlButyl alcohol IS solid at 52" F)

Flammable Limits 2 4 to 8 oo. o
Autoignition Tem11. 1'FI 892
Extinguishing A~~:enh CO,, dl)l chem1cal, alcohol foam, water tog
Special fire Pw.e.1ures Water m.'ly be ineffective on fne.
HEALTH HAZARD DATA

Health Hazard Rlltini!S Odur Threshold l!'pml PEL/TWA (ppm) TLV!TWA (ppm)
Generai-Avo1d breaH"ng rugll vapor concentratrons. Prolongeu or repeated skin contact may cause defatting of
the skrn anJ may proJucP dermatitis from dail~ contact
Symptums-Hea(jache and d1zzme%
Short E~pO!mre Tol~ranc~--UnavailabiiO'
Exposure Procedure~- Vapor-remove vrct1m to fresh a1r. Give artifiCial resp1rat1on if breathing stops. Skin or eye
contact-remove contam1nated clothmg and gently flush allected areas with water for 15 minutes. Get
medical advice or attention
REACTIVITY DATA
Stability-Stable.
Compatibility-Material: Usudl matenals ot cunstruct1on are suitable.

Wear rubber yloves. lace shreld. protective clothrng. Have all-purpose canister mask available Avoid contact
with liQuid Secure 1gn11ion ::;'~l.w::<cs
If a spill occurs, call the National Respon11e Center, 800-424-8802.
Rem11rks:
38
lao-BUTYLAMINE
~ 1-Amino-2-MethylprOpana; lsobulylamine; Ualted N.tkuul Number ....
mono-IIObutylamlne; 2-Methylpropylamlne
CHRIS Code ..
F_._(CH,).CHCHaNHa
-
Bomq Poi!ll.. __M'C -..l..Ql'F
A,...u:e Odor Colorless liquid with ammonia-like c 'F
FreedaJ Poiat... - 86'C - l?3'F
___ c ___.,
Spedtk Gra'ffty-0.73
Vapor ~re lO'C lA' F) <-HIP.. ......2lL
Olealad Pamlly-Aikyl amine Reid Vapor Pre..re (peW)..... ---..U.._
Vapor Pr-.e 46'C (115'F:I (ptla)... _.a.L
Polhado-. ~-USEPA _..c._ IMO _..Q._ VIPOI' Deallty IAH = 1,0)... ____z.g__
~ lhllk Jtea. 46 CPR S..bclaafter ....... ____Q_ SolllbftitJ In Wllter .. Complete
--
~: Flammable liquid
.
FIRE lc EXPWSION HAZARD DATA
Gueni.-Toxlc oxides of nitrogen may ba formed In tire. Aammable, high fire riSk. Aashback along vapor trail
may occur. Vapor may explode It Ignited In an enclosed area.
Plaia PoiDI ('F) ..

Fta..IWe u.&tl ..
AlltoJpltlon T_,_ ('F) ...
10
1.710 9.8%
712
Es.dllpW!bta:Apatl ... Dry chemical, alcohol foam or carbon dioxide.
Spedal Ptre ~ .. Water may be ineffective, but should be used to keep containers cool.
HEALTH HAZARD DATA

H-.1111. Huard Ratlap Odor 'I1Inllwlld (ppm) PEL/TWA <pp.) TLVII'WA (ppm)
2, 3, 0 Unavailable SISkin' SISkin'
Ge.eral-Moderately to~eic, eye, skin and respiratory irritant.
Sym---L.os8 of consciousness may occur. If taken internally, convulsions may also occur.
Short Ell:po~Ue Tom.-1 015 ppm is highly irritating.
~emove clothing and Shoes. FluSh affected areas with plenty of water. If in eyes flush
Ew.JIOIIII'fl
eyes thOroughly with water. If taken internally, and victim is conscious, have him drink water. If victim is
unconscious, do nothing except keep him wann. cau a doctor.
REACfiVITY DATA
StUWI)'-8table. Keep separated from heat and oxidants.
C...pdbiiii)'-M.terlal: Store in carbon steel, aluminum, atalnless steel for purity. Copper and Its alloys should
NOT be used.
Carse: Group 7 of compatibHity chart

Wear butyl rubber glovaa, protective clothing and self-contained breathing apparatus. Avoid contact with
liquid. Secure Ignition sources. Cover spina wHh sodium biaulfata and spray with large amounts of water.
U a ...W ocean, call die N.uo.I Relpoae Ceater, 800-4l4-1102..

Rti!W'kl: PEL and TLV based upon n-ButylaiTIIne.
39
n-BUTYLAMINE
s,._,..._ 1-Aminobutane; 1-Butanamine; Butylamine; Ullfted NadoM N.-ber...
Mono-n-butylamine; Norvalamine
CHRIS Code ..................... ;;Bii'iiOM;; ~
Bolllil& PcN.t ... __l'C ____ll2'F

A~lorklss liquid with a pungent, c 'F
ammonia-like odof Freezbl& Pobd.. - 5Q'C -M'F
Speeilk Gnl'rlty~.74
___ c ___F
vapor Pr-.e we <61'Fl t-HaJ .. . ___llZ__
ate.kaJ FIUilily-Aikyl amine Retd v.,., ~ (JIU)....... --.J..a._
V.,or ~ 46'C (llli'F) (plla) ___.2L_
Poll.tion Catepry-USEP A ____c__ IMO ____c__ VIIJIOI' ne.tty Wr = 1.0) ........................ ____2.A_
A.,Uct~ble Buill: Rea. 46 CFR Sllbc:IN!pter ....... _Q__ SolllbWIJ m w.- .. Cgmpftll

Eleetrlc:al Grou.-D
Geaeral-Toxic oxides of nitrogen may be formed in fire. Flammable, dangerous fire risk. Ftaahback along vapor
trail may occur. Vapor may explode if ignited in an enclosed area.
Flub Poillt ('F) .. 10

f1am1Uble Umlb .. 1.7 to 9.8%
Autolpldon Temp. ('F) ... 594
E:dinaui&btna: Aaenb .. Confined-dry powder, C~. Open-water, polar solvent foam.
Special Ftre Procedur .. Keep tanks cool ith water spray. Provide tnt fighters with protective clothing
and self-contained breathing apparatus against toxic fumes.
HEALTH HAZARD DATA

Health Huard lbltbap Odor 'lltrahold {JIPIII) PEL/TWA (Jig) TLV/IW A (psD)
4, 4, 4 1 to 2 5/Skin 5/Skin
GtmeraJ-Poisonous if inhaled or if skin is exposed to the vapor. Irritation of eyes and respiratory tract. severe
damage afteJ contact of short to modeJate periods.
Symptoms-Severe damage to skin or eyes by liquid, irritation of upper respiratory tract and eyes, mild
headaches and flushing of skin of lace, cumulative effects have not been observed.
out of 3
Short Expo~u:re ToleJ'IIDee-Ten to 15 ppm is highly irritating during short expostn; 3100 ppm kUied 3
rats in 50 min.; whereas rats survived a single 4hour exposure ol 2000 ppm. Hazards unknOwn for humans.
Espo~ure Proeedur-Fiush skin or eyes immediately with large amounts ol water for approximately 15 minuteL
Remove all contaminated clothing and flush underlying areas with water. In case of eye contact or
inhalation of high concentrations of vapor, victim should be immediately placed under physician's care.
REACllVITY DATA
Stability-Stable, but readily combines with acids, aldehydes, chlorohydrios, and organic sulf\K compounds.
Com)lfltlblllty-Material: Store in carbon steel containers or aluminum or stainless steel for pxlty. Copper and
its alloys should not be used.
Carlo: Group 7 of compatibility chart.

Wear butyl rubber gloves, protective clothing, self-contained breathing apparatus. Avoid contact with liquid.
Sect.lre Ignition sources. Cover spill with sodium bisuHate. Spray with large amounts of water. Bum In open pit
after dissolving in waste alcohols or in an incinerator with afterburners and scrubber.
If 1 IPW ocean, c:al1 tk Natloul Rllpoae Cater, ~
40
HC-EIUTYLAMINE
.......... ___.____
CHRIS CoOo __EL

"allleomen" ___IIIL
F-.la-CHaCH(NH1)C.H.
BoUiq Potat . ____jji'C __J.~:"F
A,..,..ee Odoa Colarkla liquid; ammonia-like odor. c 'F
FrMUq Poillt... . -104'C -155'F
Spedlk Gra1'ftJ.....O. 73 ___ c ---
CIMU:III r..u,---Aikyl amlnes
v.,.. P.--.e we <A'F> c-HI> ......... ____ug_
Reid V.,or p.._. c,.t.l)......................... ......4J._
v.,.. rr-.e we ms., (JIIa) ........... __I.Q_
PolhRioll c.tepr-USEPA ~ IMO ____Q_ v.,. n..ltJ (Air = 1.0)..... ........... ......uL..
A,.uc.we Bldlr; . . . . 46 CFR ~ ....... ___Q_ Solllllftltr 1a waer ... .. ..... _ Cqmp!ttt
--0
Gtwle-C: Flammable liquid
GIMrat-TOXIc oxtdn of nitrogen
~
qy be formed In fft. Flammable, dangerous fire rllk. Fluhbac:k along vepor

trail may occur. Vapor may eJCpkJde If ignited In an enciOMd ......
Polat ('F) ............

~Ualtl ...
...........-T-..<'F>
"
.................... Unavllllable
............... 712
EJ:tiap...... Allatl- .............
Confined-dry powder, co..
Open..polar solvent foam, water.
s,ect.l Plre ~ ...... KMP tank8 ooo1 with water spray. Provide lire fighters with protectiye clothinu
_
and Mlf<OI1talned breathing apparatus.
............. HEALTII HAZARD DATA

u..,.._
Odor nn.ltold C,.) PI!LITWA-
5/Skin'
U.VII'WA <pp.)
SISkin*
3, 2, 3
e-nd-Moderately toxic.
Sp; Coughll~g, Irritation of eyes and mucoua membranes, redness or Irritation of akin.
Aort EspoRre ~navallable
Ex,...ePt
eye
Fluah lkln and eyes Immediately with large amounta of water lor 15 minutes. In caa of
contact, Inhalation of high concentrations, or II"'Q8$ti0n, vtct1m should be placed under ~ C8Jfl,
REACilVITY DATA
SbbWtJ-Stable.
~-Mater:lal: Carbon steel.
c.qo; Group 7 ot compatibility chart
SPILL OR LEAl: PROCEDURE

Wear butyl rubber boots, gloY8. protectiYe clothing, eetf-contalned brNthlng apparatua. Avoid contact with
liquid. Secure Ignition ~. Cov.- with IOdlum blaulfate and wash with plenty of water-or cluolve In waste
alcot'lc* and tun. Burn In open pit or In an Incinerator with after burners and acrubbat.
U ..W __..,all die N-*'-1 . . . . . . c:.ter, -..u4 IMil.

.._.._ PEL and TlV baed ...,on n-Butylamlne.
*".........
41
tert-BUTYLAMINE
SynonyiiUI- 2-AminoisobtJtane; United NatioiUI N11mber ...
2-Amino-2-methylpropane; Dimethyl ethylamine;
1, 1-Dimethylethylamine; 2-Methyl-2-propanamine;
T rimethylaminomethane
CHRIS Code .. ...l!lJA_
"all isomers" ....JilY..._
Formu..-(CH,),CNH,
Bolllna Point.. ~c --I..U'F
Appellrl.nce-Odor-Water white liquid; ammoniacal odor c 'F
FreezinR Point.. -67"C -M'F
SpecifiC' Gnntty-0 70 ___ c ---
Vapor Praaure lO'C (68'F) {mmHI) .. ~
Chemkal Family-Alkyl amine Reid Vapor Pnalll"e (...a)... ----l.L..
Vapor Preuure 46'C (115'F) (,_ta).. --12._
Pollution C'-llteaory-USEPA _____Q__ IMO ____Q__ Vapor Density (Air = 1.0) ........................ ~
Applicab~. Bulk Rrg. 46 CFR Subchapter ____Q___ Solubility in Water.. Complete

Grade-S: Flammable liquid
Electrltal G roup--0
General-Toxic oxides of nitrogen may form in lire. Vapors form explosive mixtures with air. Flashback along
vapor trail may occur Vapor may explode if ignited in an enclosed area.
Fhsb Point ("I'') about 50

Flammble Limilll 1.7to 9.0%
AutolgnitiOD Temp. CFl 612
Extinguishing A1ents Dry chemical. alcohol foam or CO.
Specllll Fire Procedures Keep tanks cool with water spray. Provide fire fighters with protective clothing
and self-contained breathmg apparatus.
HEALTH HAZARD DATA

Hulth HIWird Ratings Odor Threshold (ppm) PEL!I'W A (ppm) UV!I'WA (PPJII)
2, 2, 3 Unavailable 5/Skin 5/Skin
Generlll-Causes Irreversible damage to eye tissue. Moderately toxic by oral intake. lrritaling to eyes, skin,
lungs. Not absorbed through skin.
Symptoms-Red or Irritated eyes or skin, coughing, irritation of mucous membrane, nausea.
Short E~:posure Tolerance-Animal test for l~quid eye irritation produced destruction of corneal tissue with 2-3
min. Vapor inhalation for 5 minutes was fatal to test animals.
EJ:posure Procedures-Flush skin and eyes immediately with large amounts of water for 15 minutes. Remove all
contaminated clothing and flush underlying areas with water. In case of eye contact or inhalation of high
concentrations of vapor, victim should be immediately placed under physician's care.
REACTIVITY DATA
Stability-Stable.
Compatibility-Material: Doesn't react with steel, wood, cloth; softens rubber and paint.

Wear butyl rubber protective clothing, seHcontained bl'eathing apparatus. Avoid contact with liquid.
ignition sources. Cover with sodium bisuHate and wash with plenty of water. Do not flush spill into confined
spaces where flammable vapors can accumulate. Burn in an open pit or an incineratOf with afterburners and
"""""
scrubber.
If apill occun, c:all tlle Nadonal lleqoDR Cellter, IJ00..4l4-880l.
Renw-b: PEL and TLV based upon n-Butylam~ne.
:t Unassigned
42
BUTYL BENZYL PHTHALATE
s,_,..._ BBP; Benzyl n-butyl phthalate; Phthalic
acid, benzyl butyl ether; Santlcizer 160
OIRIS Code ..
BoWq Polat ... ______azoc ~F

Appeanutee-Odor-Col0fle88, oily liquid; slight, ___ c ___ 'F
characteristic odor. freezl.na: Poblt ... ---=.3'C __d.l'F
s,edftc: Granty-1.12 ___ c ___ 'F
Vapor Preaure :ZO'C (61'F) (mmHC) ..
ll.dd V1por Pre.lure (pfia) ...
Vapor Preuure 46'C (115'F) (pela) ...
Polllldoll Caletorr-USEPA ____IL_ IMO ___A__ VlfOJ' Deuity (Air = 1.0) ...
Appllabte Bulk Rea, 46 CFR Sakbapter ....... ____ll._Q_ SelubWty In Water ..

ESectrical Grotlp-D
General-Fire hazard slight when exposed to heat or flame. carbon monoxide, carbon dioxide, and water
produced by combustion.
Flalll Polat ('FJ ..... 390

F'bamdlle UmU .. LEL=0.26% (calculated) UEL-Unavailable
Aatolpltioa Temp. ('F) .. Unavailable
Extiii~Plfttu.l A.-g ... Confined-GOa. dry chemical. Open-water, loam.
Special Fire Proeedva .. Water or loam may cause extensive frothing.
HEALTH HAZARD DATA

HeaJcb Hazard Rlrt:lll(ll Odor 'l'brahold (ppm) PEL/IW A (ppm) TLV1TWA (ppm)
General-No apparent hazards-low toxicity.
Sy111pC01U-lOW toxicity.
Short Ex)IOIIU'e Toleraace-Will not cause irritation to skin.
EJ:~K~Nre Proeedra-Skin contact-ash affected areas with water. Vapor inhalation-remove victim to fresh
air. Call a doctor.
REACTIVITY DATA
Stabillty-Stable at moderate temperatures; no spontaneous decomposition. Can react with oxidizing materials.
Comp~.dbUlty-M.terial: Destructive to rubber and paint. No effects on steel, wood, or cloth. Recommend
containers of steel.
Carao: Group 34 of compatibiHty chart.

Wear rubber gloves, face shield. Confine and absorb on suitable material such as sawdust, clay, or fiHercel.
May be incinerated.
If lplll oce.n. eall dte Nlltkmal Jtapo.e Center, 100-424-1101.

0
Re!Ulb: Vapor-Pressure: 0.16 mmHg at 150 C.
* Unassigned
43
BUTYLENE
SJDOIIYIIIII-Butene: 1-Butene: alpha-Butyleoe; Ualted Natto. N ...tter ...
Ethylettlylene
CHRIS Code ..
BoiiiDI Poblt.. _ d " C ____21"F

Appearuce.Odor-Cotorless gas; sweetish odor
c ___F
Freezbla PoiDt.. -lMI"C ----=..3.Q2"F
Specific: GnoYlty-0.60 at 20"C (a liquid)
___ c ___.F
Vapor ..,_re lO"C (61"F) <mmHI).. ___l,Q3Q_
Cll-a! Family-Olefin Reid Vapor Preaure (pda)... _&L
Vapor Pralltre 46"C (115"F) (plia).. __lL
Polludoa C.tqof'y-USEPA - - - IMO ~ Vapor DeJuilt)' (Air = t.OJ.. .................... ---l..i!.....
Appllcatllt Bulk Rea;. 46 CFR Subdlapttl' ....... ......Q..Q_ SoluiHUty hi Wlller .. lnpn\Wit
FIRE .t EXPWSION HAZARD DATA

Gnde-Lquelied Flammable Gas {LFG)
ElectriC'al Group-O
Genen.J-Unless the flow of gas can be stopped, extinguishing a butene lire will permit accumulation of an
ell:;p\osive concentration of vapor, and subsequent explosion or re-llash.
FlatJI Point ("Fl. 110 (cc)

Flammable Umlts 1.6 to 9.3%
A11tolpltion Temp. ('F) 723
E:dinplablna A1enh Stop flow of gas; C(h, dry chemical, water fog.
Special Fire Procetlura ... Keep burning tank and adjacent tanks cool with a water spray.
HEALTH HAZARD DATA

Health Huard Ratings Odor 1bnsbold (ppa~l PELJTWA (ppm) TLV!IWA (,m)
Unavailable Unavailable Unavailable Unavailable
General-May produce anesthetic effects on exposure to high vapor concentrations. Contact with liquid may
produce a frostbite.
Symptom-Breath"lng high concentrations of gas tor some time may cause dizziness. Contact with liquid may
cause skin and eye injury similar to frostbite.
Short Exf1011ure ToteraDU-Unavailable
Ex)IOHre Proeeclret-Remove to fresh air. If breathing has stopped, give artificial respil'ation. If the liquid has
spilled onto the skin, points of contact may be frostbitten; handle gently and protect from mechanical
REAcriVITY DATA
StllbJIIty-Stable. can react with oxidizing materials.
ColapatlhWty-Materll: Noncorrosive to most materials of construction.

Wear rubber gloves, face shield, protective clothing. Have atlpurpoSe canister mask available. Secure ignition
sources. The spilled liquid will boil away rapidly, leaving no residua.
Ir 1 1p.U ocean, call dte Nltloul Re1p0111e enter, 800-424-IIOZ.

Remarb:
44
BUTYLENE MIXTURES
s,~ No common synonyms. United Natioa Nuber..... .
CHRIS Code ..
c
--.c
___.,.,
---.,
==c
A~--Gu with gasoNne-like odor.
s,.:tnc C..rltr-unavailable
Freellla& Polat ...
==F
V.,or Pr-.re ZO'C (lSI' F) (111111Hcl ..
c
Reid Vapor Pre11ure (pm) ........ ..

Vapor ~ 46'C CI15'F) (pila)
Polhatloa CatetorJ-USEPA - - - IMO - - - - - v.,.., De..tty (Air = 1,0)... ..... ............ ----1.i_
AppllaWe hlk Rea. 46 CFR S1lllcMpter ....... .....Jl.....Q_ Sol.WUty In W.ter . . lnltllubl&

Gnde-A: Uquefled Flammable Gas (LFG)
EJeetrica1 Gro.p-(Jnasai5Jled
Geaerai-Unl8S1 the flow of gas can be stopped, extinguishing a lire will permit the accumulation of an
expiOeive concentration of vapor, and subsequent explosion or re-nasn.
..,..... Pobd ('F) .. - 24 approximately

~bleUadtl .... 1.0 to 10.0% (approx.)
AlltOipldoll T1111p. ('F) .. 615 to 725 (appmx.)
Ext~apl~Wq AJMtl ...... Stop flow of gas: ~. dry chemical, water spray
Sptdal Fire l'roc:edllrel Use water to cool contain8f'S in order to reduce possibility of rupturing tank.
Try to seal the gas leak. Use water spn~y to knock down water vapors. Flash back along vapor trail may
occur.
HEALTH HAZARD DATA

Heatdi Huanl Ratinp Odor 'I1IrelboJd (ppm) PELI1W A (Jipm) nvJTWA <ppm>
Gneral-Essentially non-toxic at low concentrations. At higher concentrations, it can act as an anesthetic.
Sypt-causes dizziness and difficult breathing. LiqUid will cause frostbite.
Sbort E::&,.,...... Tolenmc:e-Unavailable
E:r:,...re Proc:edani-Remove victim to fresh air. 11 breathing has stopped, administer artificial respiration. If
breathing is dlfftcult, give oxygen. If the Hquid has spilled onto the skin, points of contact may be frostbitten:
handle gently and protect from mechanical damage. 00 NOT RUB. Get medical attention.
REACI'IVITY DATA
Stalillhy-Will react with acids and alkyl halides.
Compltilrilfty-MIIIerlal: Usual materials of construction are suitable.
CUto: Group 30 of compatibility chart.

Wear rubber glOves, face shield and protective clothing. Have all purpose canister mask available. Keep
concentration of leaking gas below explosive mixture range by ventilation. Secure ignition sources. Do not flush
spill into confined spaces where flammable vapors can accumulate.
If a .,m OCCIII'I, call die Nadoql a...o- Center, 800-4:Z4 IIIO:Z,
Remarb: . Some data are undeterminable because thiS category considers m1xture of butylenes.
:1:: Unassigned
45
1,3-BUTYLENE GLYCOL
Synoay....- Butane-! ,3-.diol; 1,3-Butanediol; U11lted Ntltl0111 N ... ber ...
beta-Butyleneglycol; 1 ,3-Dihydroxybutane;
Methyltrimethylene glycol
CHRIS Code ..
Fonmala-CH,OHCH,CH(OH)CHI
Bolli111 Point.. _____221'C ~F
Appeannce-Odor-Practically colorless; odOfless liquid. c 'F
Freedna: PoiDt.. _____zac ______.M'F
Spedtlc Gradty-I.Ql ___ c ---
Vapor Pre.IIIJ'e lO'C (68'F) (mmll&) .. --2.QL.
Chemical Family-Glycol Reid Vapor Pre.are (...)... ......L.iDL...
Vapor Pre.illl'e 46'C (115'F) (plbi).... ___j,gr(_
Pollutioa C.tqory-USEPA - - - IMO ___lL_ Vapor Dellllty (Air = 1,0) .......................... .....J.l.A._
Applicable Bulk Reg. 46 CFR Subdaaptu ...... __ll__ Sol11billty In Water.. Complete

Elec:tric&l Group-O
~~~toral-Shght fire hazard when exposed to heat or flame.
fluh Point ('F) 250

Fhmmble Undts Unavailable
Autolpltion Temp. ("F) 710
Extinpi1hing ApDb .. Wat91', carbOn dioxide or dry chemical, alcohol foam.
Spedal Fin Procedures .. Cool exposed tanks with water.
HEALTH HAZARD DATA

Health Haz.ard Ratinp Odor lbreaotd (ppm) PEL/TWA (PJIIIII) 1LV/TWA (ppm)
General-Not considered toxic under ordinary conditions of handling.
Symptom-unavailable
Sbort Expo~~ure Toleranee-Unavailable
Expo~~ureProceduru-Vapor-remove victim to fresh air. Skin or eye contact-gently Hush contaminated areas
with wat8f !Of 15 minutes.
REACIIVITY DATA
Stability-Stable. Can react with oxidizing materials.
Compatibillty-!\taterlal: Usual materials of construction are suitable.
Carao: Group 20 of compatibility chart. See also Appendix 1-Exceptlons to the Chart.

Avoid contact with liquid.
If a 1piU oceurs. c:al1 the N.UO.W ltelpoue Ceatw, 801)...4l4 IIOl.
Remarlu: t Unasstgned
46
1,2-BUTYLENE OXIDE
s,._,.__ 1 ,2-Butylene oxide, stabiHzed;
alpha-Butylene oxide: 1,2-EpoK)'butane
CHRIS Code ..
BoW.. PfNnt... ~c _jj'F

Appearuee-Odor-Colorless liquid; sharp, pungent odor c 'F
Freezlna Pot.t .. -SQ'C -58'F
Speclfte Gra"rity--0.83 c ---
Vapor Prt.ure :ZO'C (68'Fl (mH&) ... ....2ll1....
Oaemical F...Uiy-Aikyiene oxide Reid Vapor ~ (plia) ... -->.L_
Vapor 1".--.re 46'C (115'F) (pita) .... ....LL.
Polladoa c.tqory-USEPA - - - IMO _J;_ VllfiOI' ne.tty Wr = 1.0)... ~
ApplkUle &.dk Jlea, 46 CFR Sbcbapter ....... ~ SolabJIIty m Wuer .. MQdtrata
FlRE .t EXPWSION HAZARD DATA

Gnlde-C: Flammable liQUid
Eleetrical Group-8
GeMral-Very flammable and vapors are highly flammable, even explosive. Fire or contamination may cause
viOlent rupture of tanks. Flashback along vapor trail may occur.
FlMII Pobat !"Fl... less than - 20

PIMiaDle LJaafb .. 1.5 to 25.1%
A11talpUioa. T-p. ('F) .. 959
Ez~Apabl .. Confined-COt. Open-Water, foam.
s,edal Flrt Proceclu. .. Cool tanks with water spray. Use water spray to "knock down" vapor.
HEALTH HAZARD DATA

Heatdl Hazard btl... Odor nr.hold (ppm) PEL/I'W A (ppm) TLV fiW A (ppm)
Not Listed Unavailable Unavailable 400"
Geaeral-lrritatlon of eyes and respiratory tract. Overexposure will cause serious injury. Contact with eyes will
cause bum. Contact with uncovered skin produces frostbite. Ingestion will cause serious illness or death.
Sya~pt-Coughing, watering eyes, sickness of stomach, frostbitten skin.
Sltort ~IM"'I" Tolerance-Prolonged contact with skin causes frostbite burn.
~pollll'l! ~Vapor-remove victim to fresh air; if bfeathing has stopped, use oxygen Inhalation. If
ingested, make victim vomit, at least 2-3 times. and then give victim a tablespoon of Epsom salt in glass of
water. Flush eyes immediately for approximately 15 minutes. Remove contaminated clothing or other
wearing apparel immediately. Clothing can seldom be decontaminated. Wash skin with soap and water.
REACTIVITY DATA
StabiUtr- Thermodynamically unstable; decomposition is rapid. Polymerization will occur in presence of acids,
bases, and certain salts.
eo.,.dbllitr-Matertal: Mild steel or stainless steel is unaffected. Storage tanks and other equipment should
be absolutely dry and free from air, ammonia, acetylene, hydrogen sulfide, rust, and other contaminants.

Evacuate area, wear respiratory protective devices as well as impervious clothing (boots, gloves, etc.). Use
large amounts of water to dMute to at least 22 parts H.O to 1 part of oxide. Leaking containers should be
immersed into large amounts of water if possible. Secure Ignition sources.
H a .,W ocaan, call die Natloul. ~ Cellter, 800-4l4-180l.
Remarks: Use an 1nert gas to displace the atr 1n the storage of butylene oxide.
Value obtained from a CG-4355 form; however, this value was not confirmed.
47
n-BUTYL ETHER
SynOIIym-1-ButoKy butane; Butyl ether; Oibutyl ether;
Di-n-butyl ether: n-Dibutyl ether; Dibutyl ethers:
Olbutyl oxide; 1,1 '-Oxybis(butane]
CHRIS Cede ..
Formula-(C,H,).O
Boillna; Point .. __wc -A'F
Appearanu-Odor-Colorless liquid; mild, pleasant, c 'F
ether-r1ke odor Freezin& Poi11t. ---:Qsc ----::;4iiF
Specific: Grnlty-0.767 ___ c ---
Vapor Prealll'e :zoc <WFl <-HJ) .. .....!.L.
Cheiul Family-Ethers Reid Vapor Praaure (plill) ... .....:!.....
VIJIOI" Preaure 46'C (115'F) (ptla) .. ....ll.L
Pollution C.teaory-USEPA - - - IMO ~ Vapor De.Wty (Air = 1.0) .. __u_
Applkable Bulk Reg. 46 CFR Subc-hapter .... _....Q__ SolubiUty In Waler .. Neqllgjb!e

Grllde--0: Combustible ltquid
Electrical Grou.-G
Gene...:J-Fiammable, irritating vapors are produced. Flashback along vapor trail may occur. Vapor may explode
if ignited in an enclosed area. Ground all eqUipment and personnel!
f1aab Point ('FJ .. 92

Flammable Umlts . 1.5to76%
AutolpitiOD Temp. ("F) 382
ExtlnpllbiDI A~enh Dry chem1cal, alcohol loam, Celt
Special Fire Proced11re:1 Containers may explode in fire. Water may be ineffective. Cool exposed
containers with water. Secure ignition sources. Wear goggles or lace shield, rubber gloves.
HEALTH HAZARD DATA

Healtb HIWII"d Rtlnp Odor Tbrnbotd (ppm) PEL/TWA (ppnt) 1LVIJWA (ppm)
GtonerI-Vapor 1rr1tatmg to eyes. nose, and throat. L1quid irritating to skin and eyes.
S)mp1oms-lnhalat1on causes irritation ol nose and throat. Liquid Irritates eyes and irritates skin or prolonged
contact
Sbon E,;pollure Toler.ance-Data not available.
Expo~~ure Procedures-Remove to fresh a1r, admimster artificial respiration or oxygen as necessary. Remove
contaminated clothing. Flush areas with large amounts of water. If conscious, induce vomiting. Get medical
attention. SPEED IS OF PRIMARY IMPORTANCE.
REACTIVITY DATA
Stability-Stable. However, when anhydrous (dry), tends to form explosive peroxides in air.
Compalibillty-Mterial: Iron, aluminum, stainless steel, tin, polyethylene, porcelain, glass and enamel are
suitable for containers

Mechanically contain material and remove. Stay upwind. Wear face shield and rubber gloves, protective
clothing. Beware of flashback along vapor trail. Secure ignition sources. Ground all equipment and personnel!
If spill oc:cun, call the Narioul. Rapo.e Ceuter, 800 04 1802.

RftiW"b: t Unavailable
48
BUTYL METHACRYLATE
U.tted Nato. N ...........
CHRIS Code ...
~ar.
...,..._
s,ectftc: Gnmty-0.88
colorless liquid with a typical
BoW.. Polllt..
Freez1q Pohll....
~c __JU'F
c
-33'C
_ __
'F
-29'F
c ___ 'F
v.,.,.. Pr-.re :zoc <A'F> <-HI>.. ____3,.__
a..leal Fa.Oy-Acrylate (monomer) Rdd
VllpOf
v.,..
rr-r.
Preli.re (,.a.)...
46'C (115'FJ (....)..
--l.m!t.....
_____Q.z&._
PoUIItioll Catepry-USEPA - - - IMO _.c._ VIPOf' ne-tty (Air = J.OJ.... _J.L_
A,plbble lhllt Rea. 46 CFR SukUpter ....... ____.o__ SotaiNUty ID Wider..... 0 4%
--
~: Combustible liquid
Jllllll PoUlt ('F) ...

~eu.tt. ...
FIRE It EXPWSION HAZARD DATA
Geltenl-Heat will increase generation of toxic fumes.
105
2 to 8% (estimated)
Extlqai~Wq A.-. . .
A11toipitiM Temp. ('F) ..
Spec:lal Fire Procehra ..

562
Carbon diOxide, dry chemical or foam
Use water spray to cool tire exposed tanks.
HEALTH HAZARD DATA

H..adl Huard Ratiap Odor 'l'llreiHJd (ppm) PEL/IWA (ppm) TLV/IWA (ppa~)
1, 1, 2 less than 50 Unavailable Unavailable
Gaerai-Mikl skin irritant. can be absorbed through skin and lungs. Ingestion may cause serious permanent
damage or death.
S,pl Skin-mild initatlon and reddening of skin. Inhalation-irritation of mucous membranes and
respiratory tract.
Short Es:polllfe To!eruN:e-1100 ppm for one hour.
EzpoRre Procedara-Skln-wash affected areas with plenty of water. Eyes-wash with cool water tor 15
minutes. InhalatiOn-remove victim to fresh air. Administer artificial respiration if necessary, and then
oxygen. In all ca888 call a doctor.
REACl'IVITY DATA
St.blllty-Sutyl methacrylate II relatively stable If properly Inhibited. Exposure to oxidizers will initiate
polymerization.
eo.,.tfbWtJ-Materlal; Stainless steel is acceptable.
Carp: Group 14 Of compatibility chart.

Weas rubber gloves, face shield, protective clothing. Have all-purpose caniater mask ltYailable. Secure aN
ignition eources. Clean up liquid with paper towels and bum under hood.
Ir 1 iplll 11CC1H'1, all tile Nadonal R_,.,.. c.ter, IIOO-G4-II01.
49
lso-BUTYRALDEHYDE
Sy_y_ iso-Butyl aldehyde; lsobutanal; Ualted NaU.. Number ...
lsobutylaldehyde; lsobutyraldehyde; Isobutyric
aldehyde; 2-Methylpropanal
CHRIS Code-
Formula-(CH 3 ).CHCHO
Boilbl& Pol.t.. ---.!"C ----.UZ'F
c 'F
Appuruce-Odor-Colorless liquid; pungent odor
Freedq Point.. --=ooc ----=i:7'F
___ c ___.F
Vapor Preaure lO'C (68'FJ <-H&) .. __llg__
Chemical FIUIIily-Aidehyde Reid Vapor Pre.lare (....)... ~
VtiJIOI' ~ 46"C (115"F) (JIIIa).. ____.g__
Pollution C.teaory-USEPA - - - JMO _ L _ Vapor Delllky (Air = l.OJ.. ........2&1._
Applinble Bulk Rfi!ll. 46 CFR Subchapter ...... __Q__ Solablllty Ia Water.. 10 0%

GrMle-C: Flammable liquid
Electrle~l Group-C
General-Fires are difficult to control because of the ease with which the vapors reignite. These vapors are
readtly ignited by static sparks of relatively low energy. Flashback along vapor trail may occur. Vapor may
explode If ignited in an enclosed area.
Fluh Point ('F). -40
FWnmable Umlb .. 1.6 to 10.6%
Autoipition Temp. ('F) .. 433
Extln~PU~~IngAgentt ... C~.
dry chem1cal, water fog, alcohol loam.
Special Fire Procedures .. Keep tanks adjacent to lire cool with a water spray. Wear eye protection and
sell-contained breathing apparatus.
HEALTH HAZARD DATA

Health Hazard Rtlnp Odor Tkreahold (ppm} PELI1WA (ppm) TI.V/IWA (ppm)
2, 1, 2 0.047 Unavailable Unavailable
Genenli-lrritabon and burns of the skin and eyes follow contact of short duration.
Symptoms-Coughing, watering of eyes, and burning sensation in throat and nose. Drowsiness, incoordination.
headache
Short Exposure T olenmc:e-Animal experiments have shown that large doses produce depression of the central
neiVous system and anesthesia.
Exposure Procedures-Vapor-remove victim to fresh air; if breathing stops, apply artificial respiration. Oxygen,
when administered by trained personnel, is helpful. Skin or eye contact-remove contaminated clothing and
gently flush affected areas with water for 15 minutes. Get medical advice or attention.
REACI1VITY DATA
Stability-Undergoes ra~ OXidation to butyric acid in air.
ComptlbUity-Mterial: Mild steel is unsatisfactory because of corrosive action of butyric acid.

Wear rubber gloves, sell-contained breathing apparatus, protective clothing. Avoid contact with liquid. Secure
ignition sources. If possible, cover spill with sodium bisulfite. Add small amount of water and mix. Scoop up and
wash away with a large excess of water, after one ho11. Wash the site with soap solution.
If 1piU oc:cura, all tile NlldoaaJ ReiiiDIIIt Cntu, 800-424-8102.

Retnrkl:
so
nBUTYRALDEHYDE
s,...,.,__ Butaldehyde; Butanal; n-Butanal; Butyl UaUecl Nadea NaMber...
aldehyde; n-Butyl aldehyde; Butyraldehyde; Butyric
~- CHRIS Code .
BolUq PoJIIt .. _____l'C ~F

Appeiii'UCe-Odor-Colortess liquid; pungent odor. c 'F
FreezlDa; Poilli .. -99'C -146'F
s,eetfte Grarity--0.82 c ---
Vapor P-re lO'C (68'FI <-Ha> .. _n.L
Olemieal Family-Aldehyde ReW Vapor~( ....) ... ....3&_
Vapcw rr-e 46'C (115'F) (plia) ... .J.L_
Pollatioll c.tepy-USEPA - - - IMO _____a__ Vq~~~r Dulity (Air = 1.0) .. ....z&...
Applic:aMe lhlk Rq. 46 CFR Sulle'-pter ...... ____Q__ SoiINiity ln Water ... 85%
FIRE 4 EXPLOSION HAZARD DATA

Eteetrical GI'O'IIp-C
GeDerai-Fires are ditf~euH to control because of the ease with which the vapors reignite. These vapors are
readily ignited by static sparks of relatively low energy. Flashback along vapor trail may occur. Vapor may
Flub. Polat ('F) .. 20 (cc)
Flammllltle LbnlbJ .. 2.47 to 10.6%
Aatolpitioa Temp. ('F) .... 446
Estlapiabia1 Ase-b- CO., dry chemical, water log, alcohol foam
Special Fire Proc:edura .. Fire parties should wear body and respiratory protection to guard against both
inhalation and liquid contact. Keep tank cool with water spray. Fight fire from a safe distance, or from a
protected location.
HEALTH HAZARD DATA

Heald! Huard Ratinp Odor TltrePold (ppm) PEL;TW A (ppm) TLV (fWA (ppm)
2, 1, 2 0.0046 Unava"able Unavailable
GeDeral-lrritation and burns of the skin and eyes follow contact of short duration.
Sympto....-Goughing, watering of eyes, and burning sensation in throat and nose.
Short Expoeure Tolenmce-Animal experiments have shown that large doses produce depression of the central
nervous system and anesthesia.
E:xpoture Proeedures-Vapor---femove victim to fresh air; if breathing stops, apply artificial respiration. Oxygen,
when administered by trained personnel, Is helpful. Skin or eye contact-remove contaminated clothing and
gently flush affected area with water for 15 minutes. Get medical advice or attention.
REACI1VJTY DATA
Stability-Oxidizes to butyric acid readily.
Cota.ptfbility-Material: Mild steel is corroded by butyric acid formed in presence of air.
Carlo: Group 19 of co~pabbility chart.

Wear rubber gloves, sell-contained breathing apparatus, protective clothing. Secure ignition 80t6CSS. If
possible, cover spill with sodium bisulfite. Add small amount of water and mix. Scoop up. Wash the site with
soap solution. Rags used to wipe up small spills should be immersed in water or removed to a sale area without
delay othBfWise they may ignite spontaneously.
If a .,W occ:un, call the Nadoul Retpoue ee.ter, 100-4l4-81102.
Remarb:
51
n-BUTYRIC ACID
Syaony- ButaniC acid: Butanoic acid; Butyrk: acid:
Ethylacetic acid; PropanecarboJCylic acid;
Propylformic acid
CHRIS Code ..
BoUiq; Pomt.. ~c __...,azrF

A~Odor-Colorless liquid; p!.Jilgent, putnd odor c 'F
Freezlq PUt..... -5'C ===zjF
Speelfte Grnlty-0.96 ___ c _ _F
v.,.. rr-re :zoc <II'F> c-HI).. ~
Oae.k:al Funlly-Organ1c acid Reid v...,..
r r - (Jilla)... .......Lmr._
VlfOJ' ~ 46'C (115'F) (Jita).. ~
Polludoa C.trrorJ-liSJo:PA _ j l _ IMO _____D._ Va,or Deulty (Air = 1.0)... .................... ......J.2i.._
Applialble Blk Rra. 46 CFR Sbchapter ___Q__ Sol11~ty t. Water .. Cgmp!ttt
FIRE lc EXPLOSION HAZARD DATA

Electrical Group-O
Genend-Mod8fate fire hazard when e11posed to heat or flame. Yields flammable vapors which form explolive
mixtures.
F1a:b Poi_, ("F).

FWn.ab]e U..itl ..
A.tolpltloa T-p.
Speela]
('F) .
btiapiNlna: Alf:lltl ..
FJre PI'Geedur. ..
...
175
Z to 10%
Dry chemical, alcohol foam or carbon dioxide

Water may be ineffective. Wear eye protection and protective clothing.
HEALTH HAZARD DATA

Healtb Huard Ratinp Odor llllrahold <ppm) PEL/TWA(..,..) TLV 1TWA c,p.)
2. 3, 0 0.001 Unavailable Unavailable
~llfnll-Skin contact may be severely irritating or may cause moderate bums. Eyes are aerloualy Injured by
hqUid contact.
S)mplomt-Vapor: eye, throat, skin irritation. Liqlid contact: sevetely irritating with moderate burns.
Sbon Epon~ Toleruce-Eyes are sariol.lsly injured by a five percent SOlution ol the acid.
Expt;JM~ Proeed--contact with sll.in or eyes: immediately tluah with plenty ol cleat ruMing w.ter, walh eyea
tor 15 minutes and get medical care; remove contaminated clothing. Inhalation: move to fresh air; If
breathing is dlffic1Jit, give oxygen. Get medical attention.
REACTIVITY DATA
Stability-Can react with oxidizing material.
Compadblltty-Matertat: Storage tanks and piping can be o1 stainless steel or aluminum.
Carp: Group 4 ol compatibility chart.

Wear rubber gloves, lace shield, protective clothing. Body shield and self~ntalned breathing apparatus
should be available. EBminate all sources o1 ignition. If pouible, cover spill with large quantities ol soda ash or
sodium bicarbonate. Mix and add watet il needed for good mixing. Scoop up slurry. Wash tile with soda aeh
SOlution.
If I 1piU 011ra, eall tlte Nadoul R.,oue ee.ter, IOO-t24-aOl.
52
CAMPHOR OIL
s~ Gum camphor; Impure camphor: Ugh! Ualted NlltioJQI N11111ber ...
camphor Oil: Liquid camphor; White camphor oH
CHRIS Code ..
llo'lln1 PoJt.. ---=.2QQ'C ----=:..3i2'F

c ___ 'F
~ly liquid, colOrless, brown or blue:
penetrating camphor odor.
Spedftc Gra'ftly-(1.87 to 1.04
Freedq Point...
Vapor ~rt lO'C (68'F> (mmHaJ ..

_______Nf'C
___ c
'F
==F
____aiZ...._
a.e.tad P..By-Ketone Reid Vapor ~re (pMJ... _L_
v.,.. Pnleure 46'C (ll!I'F> (,.).. ____!__
Poll11doll c.teaorr-USEPA - - - IMO ___a_
A,uc.bte Balk R. . 46 CPR S.llcllapter ....... ___Q_
v.,.,..
Deul.t)' (Air = 1.0) ....................... ~
SoluWUty ID Water.. S!jghl

Eledrlcal Grollp-0
GeDei'III-Moderate fire hazard when exposed to heat. The solid often evaporates without first melting.
Plull. Polllt ('F) .. 117 (cc)

FlMaaiWe U.ttl .. Unavailable
Aatolpitioll TP ('FJ . 466'C
Extblpilhj.. Apatl ..... Foam, carbon diOxide or dry chemical
Spedal Fire Proee11un1 .. Cool exposed tanks with water.
HEALTH HAZARD DATA

Health Hazard lllltblp Odor 'Illrelllold (,...) PEL/1WA (ppm) TLV ITW A (ppm)
GeDeral-Vapors are nonirritating to the eyes and throat. If spilled on clothing and allowed to remain, smarting
and reddening of the skin may result.
Sympto~u-After swallowing, nausea and vomiting; headache, confusion; jerky movements.
Sbort ExpoAre Toleraaee--Reliable data unavailable.
Elr;poNre Proeedare.-ln case ol contact, flush skin or eyes with plenty of low-pressure water. Get medical
attention lor eye contact.
REACfiVITY DATA
St.WHty-Stable. Can react with oxidizing materials.
Com,.ubility-Materlal:
Carao; Group 18 ol compatibility chart.
SPIU. OR LEAK PROCEDURE

Wear rubber gloves, lace shield, protective clothing. Avoid contact with liquid. Secure ignition sources.
Shut.()fl leak. Flush area with watet.
If llill oeean, call tile Nadellal ..,.._ CenterI 800-4l4-I801.

Re...-b: t Unavailable
53
CAPROLACTAM SOLUTION, 80%
SyiHmflll'- Aminocaproic lactam; epailoo-Caprolac:tam; Ullltell N.U.. NUIIIer...
2-Ketohexamethylenimine; 2-0xohexamethylenimine
CHRIS CWe ....
Formllla-C.H,,NQ
Botllq: Polt .... .
Appearance-Odor-Clear light yellow, liquid; odorless
Fl-eeziD1 Pot.t .. .
Spedftc Grnlty-1.06
VIIJIOI' ~ :ZO'C (61'FJ (.mfla) ....
Chekal Family-Cyclic amide Rdd Vapor Pre.ure (pita)...
VIIJIOI' Pr-.re 46'C (115'F> (piW ..
Pollution Cateaory-USEPA - - - IMO ~ Vapor Delll'ty (Air = 1.0) .
Applleable Balk Rea. 46 CFR Subebapter ....... ___IL_ SoluWllty Ia W.ter ..

Grade-E: Combustible liqutd
Electric:al Group-NA
General-Toxic O)(ides of nitrogen may be formed in fire. Negligible hazard polymerization below 200'F.
Flull Point ('F) 230

fhmlllable Umils LEL= 1.84% UEL-Unavailable
Autolpition Temp. ("Fl Greatet than 264
E~:tinguilhina Alflltl .. Water, dfY chemical, foam, CO,
Special Fire PTocfllurn
HEALTH HAZARD DATA

Healtb Huard Ratinp Odor lbre~:bold (ppm) PEL/I'W A (ppm) TLV/IWA (.,m)
0. 0. 4 0.3 mg/m 5 5
GeneraJ-SIIght nazard, however, toxic vapors result from thermal decomposition above 400F. Possibility of
thermal burns from hot liquid if carried at elevated temperature.
Symptoms-Inhalation causes coughing or mild irritation.
Sbort Expo~~urt Toltranct-Not pertinent.
Expo.AJrt Procedurm-lnhlation-remove patient to fresh air. Eyes-wash with water for 15 minutes.
Skin-wash with soap and water.
REACTIVITY DATA
StabUlty-Stable.
Co111p~~tiblllty-Mterial: Non-corrosive to steel, wood, rubber, paint, cloth, or other common materials.
CarJo: Group 22 of compatibility chart.

Sect.Jre ignition sources. Spills may be ltushed with water.
If 1 apJII occura, eall tbe Narioul a.,.._ Ceale, II00-4l4-8101.
ReM~tb: .:t: Unasalgned
54
CARBON DISULFIDE
SJ11CM1r--Carbon bisulfide; carbon blsulphlcle; Uldled NadoM N ...ber...
carbon dlsulphlde; Dithlocarbonlc anhydride
CHRIS Code ..
-
~lorleas
Spedfk: Grol.ty-1.28
ClleJmeal F...Uy--Sulfide
liquid; strong disagreeable
Polladoll Catqory-USEPA __a__ IMO ____a_

A.,uc:nte Bulk Rea. 46 CFR S.bcbapter ....... _Q__
Bolli-.:Polllt ...
Fretzbaa PoJIIt ..
~c
___ c
Vapor Preaure lO'C (68'Fl CHJ) ..

ReW Va,or Preaure c..-)...
Vapcw Pre.ure 46'C (115'F> (pita) ...
Vapor Dellalty (Air = 1.01 ...
SolubiUty Ia Wlller ..
---.llli"F
_ _ _"F
----=..1.1.1"C ---=.!AZ'F
c _ _ _ F
.....2&L_
...1Q.L
.....l.2.L
_2M_
02?%

GrMe-B: Flammable liquid
Eleetrieal Gnmp-No electrical equipment allowed.
Gelleni-Highly flammable liquid with unusually low autoignition temperature; contact with steam line or hot,
bare electric light bulb can cause ignition. Burning releases irritating and toxic sulfur dioxide gas (SO!!).
!1l.dl Polt C'F> .. ~22 (cc)

FWa.ab1e Umib ... 1.3 to 44%
Av.tolpidoa Te.p. ('F). 212
EJ:dquilllbla A . .ls ... CO. or dry chemical
Spedal Fire Prvcedarel .. A self-contained breathing apparatus is recommended. When burning, carbon
disulfide produces sulfur dioxide, which Is toxic and highly irritating. Wear full protective clothing. Fight fire
from a safe ::liatance or from a protected location.
HEALTH HAZARD DATA

Hellldl Hazard Ratlap Odor Tbrfthohl (ppm) PEL/1WA (ppm) nvnwA (ppm)
2, 2, 3 0.21 4/Skin 10/Skin
General-Vapor harmful. Avoid skin contact with liquid.
SynqKo.-lighlheadedness, dizziness; prolonged contact with skin may ceuse burns.
Short Ez,aRre Tolennee-1,100 ppm tor 1/2 hour may cause severe symptoms and unconsciousness; 4,815
ppm for 1 hour has been reported as fatal.
EllpoN111 ~Remove to fresh air. Give artificial respiration if unconscious. Get medical attention as
soon as possible. It breathing Is difficult, administer oxygen.
REACfiVITY DATA
StlbWty--Cargo tanks shOuld be isolated from high temperature fluids. Under conditions encountered on
tankships and barges, carbon disulfide is not dangerously reactive. Must be shipped with pad of inert gas.
eom,.tfWHty-M.aertal: May be slightly corrosive to metals of construction due to imporltles. Softens rubber
and many plastics.

Wear rubber gloves, safety glasses, protective clothing and self-contained breathing apparatus. Have carbon
dioxide fire extinguisher available. Eliminate flammables and a" sources of Ignition. Note the low autoignitlon
temperature {212'F).
H 1 lpill Oftlln, c:all tile Na"-1. Jlel...-e Ceter, 800-4l4-I801.
55
CARBON TETRACHLORIDE
Sy-ymt- Benzinolorm; carbon tet; Methane, United N~OQ NuMber ...
tetrachloro-; Necatorina: Perohloromethane;
Tetrachloromethane
CHRIS Code ..
Fonnu!1-CCI
__2!!"C ____JB"F
c _ _ _F
AppearaacH>dor-Colorless liquid; sweetish odor
Freul.n& Polat .. -2j1"C ----=.i"F
Specific Gra.tty-1.59 c _ _ _ "F
\'1por Preaure 20"C (68"F) <mmHI) .. ....i!l.L
Cltem6cal Fa.Uy-Halogenated hydrocarbons Reid Vapor P.._re (Pilla)... _u_
V.- Pre.ure 46"C (115"F) (ptla) ... -->.L_
Pollutioa c.teaorJ-USEPA __A__ IMO __e__ Vapor DeMJty (Air = 1.0).... _.oa....
Appliallle B.tk Rea. 46 CFR Subc:Upter ____Q___ Solubility In Water. lnSQI!Ibla

Gnde-Nonflammable; hazardous l1qu1d
Ehctrical Group--NA
Geaenai.-Ooes not burn. Liquid or vapor in contact w1lh hot metal can form poisonous phosgene gas.
Flub Polt ("Fl. Non-flammable

Flammable Umlts .. Non-flammable
AutotpJtlon Temp, ("F). Non-flammable
E:~.tiapitbiq Aaentl Non-flammable
Special Ftre Proeedura Wear self-contained breathing appatatus. Cool tanks near fire with water
spray.
HEALTH HAZARD DATA

Healtb Har.ard Rat:lnp Odor Tllreabold (ppm) PEL/TWA (ppm) nv IIWA ,,,..,
2. 1, 4 so 2 SISkin
General-Suspected carcinogen. Breathing vapor in closed space can cause serious illness. The odor threshold
is not considered adequate warning of potentially dangerous vapor concentration. Prolonged or repeated
sk1n contact may cause defatting of the skin.
SymptomJ-Orowsiness followed by unconsciousness and by respiratory failure if exposure is prolonged.
Sb1 Exi'O'ure Tolrruc:e-Little or no iniury from single exposure to 300 ppm for one hour, 90 ppm lor 4 hours,
or 2000 ppm lor 6 minutes
Es.poeurr Procedura-Vapor-remove victim to fresh air. If breathing is diffiCult administer oxygen. If breathing
stops, apply artificial respiration. Sk1n or eye contact-remove contaminated clothing and gently flush
aflected areas with water for 15 minutes. Get medical advice or attention. DO NOT give victim any
preparation containing alcohol, because it could be fatal.
REACTIVITY DATA
Stability-Stable.
Compadblllty-Materlal: Becomes corrosive when in contact with water. Corrosive to most iron and copper
base alloys, aluminum and rubber.
Car;o: Group 36 ol compatibility chart.

Wear rubber gloves, aaH-contained breathing apparatus, and protective clothing. Avoid contact with liquid.
If 1 iplll occ.ra. c:al1 tbe Natfoaal Re.poue Ce11ter, I00-4U-810l.

Remarb: Odor threshold IS not conSidered adequate wam1ng of potentially dangerous vapor concentration&.
56
CARNAUBA WAX
____.___
CHRIS Code ....... ... ... ................ .... ............ .J!JS:A._
F....a.-ca~HaCOOC..Ha
Boillq Polat ..................... __j""C _ _ _ F
~ard. amorphous, light yalow to c 'F
greenish brown lumps: slight odor FreedJit: Pobtt ....................... __'C --:;aF
s,edllc Grmt:J--1.00 c ---
v....,.. Pr-.re :zoc CA'F> c-H&) ........ --l.mL..
v.,..v.,..
a-deal Fa.DJ-Ester Refd Pre..re (. .)......................... .....L&:fL...._
Pr.ue 46"C <US"F> (. .) ..... ___l.mt_
l'olhltlo. CatetDrf-USEPA - - - IMO ~ VIIPOI' De.lty (Air .,. 1.0) . ____L_
A.,uc.we Blllt Rea. 46 CPR S.Kbapter ........ _.c._ SolabWif I wmr. Naq!lpjbla
--
FIRE II EXPWSION HAZARD DATA
Gr.M-E: Combuatlbla
GoMni-Combus-.
P1MII Politi ('F) .. 540 (cc)

n....w. u.J:a ... Unavailable
~T-,_C'F) .......... Unavailable
Eztblpidllq Aaen ... Dry chemical, foam, or carbon dioxide
SpecW Plrt- Pnleedarel .. Wear bfeathing apparatus. Water or loam may cause frothing.
HEALTH HAZARD DATA

n.ltllllulnl lbtiJip Ollor nr.laolll (ppm) PEL/I'W A (ppm) TI.V/I'WA (JIIIIl)
0,1, 0 UnavaHable UnavaUable Unavailable
Ga.ai-Virtually non-toxic, but possibility of thermal burns from hot liquid.
S,.,...._Low toxicity
Sltort Ex,_are ToMnllce-Low toxicity.
Ez~~Q~Ue ~---Treat bums caused by hot liquid.
REACfiVITY DATA
St:UOity-Stable.
~lftJ'-MaaeriE Usual materials of construction are suitable.
Carto: Group 34 of compatibility chart.

Avoid contact with hot liquid. Wear goggles or face shield, protective clothing for hot liquid. Scrub, ehovel or
place Into package of paper or other flammable material and bum in incinerator.
If a liPiD oeean, call tH Natioal. . . , _ Ceater, 100-424 1102

~ Normally transported at elevated tami)Eifatures. See 46 CFR 36-Eiavated Temperature Cargoes.
t Unavailable
t Unassigned
57
CASTER OIL
Synonymt- Neolid; Oil ol Palma Christi; Ricinus oil;
Tangantangan oil; Turkey-red oil (suHated caster oil)
CHRIS Code ..
Formula-Not chemically distinguishable

BolllnaPr.oiat.. ~c ~F
Appeu-ance-Odor-Pale-yellowish or almost colorless c 'F
transparent, viscous liquid; faint mild odor FTeezina PoiaL -lO'C -14'F
Speclfk: c ...,lty-0.94 to 0.97
c ___ 'F
Vapor Praeure 20'C (68'F) (IIIIDHK) .. -2..2!_

Cbeallcal F...Uy-Esters Reid VllfOl' PreAIU'e o-Ja)... __Q,JL
Vapor PreuUR 46'C Cli5'F) (paD).. ~
Pollution C.teavry-USEPA _ _ _ IMO ___c__ Vapor Demllty (Alr = 1.0).. ........................ ____lQ__
Appllcab.le Bulk Rea. 46 CFR Subchapter ....... __Q__ SoluiNIIty ID Water.. !lnavajlab!a
FlRE & EXPLOSION HAZARD DATA

Gnde-E: Combustble liquid
Electric:lll. Group-NA
General-Slight lire hazard when exposed to heat
Fluh Point ('F) . 445 (cc)

Flam~Ublc: Umltll .. Unavailable
Autolpltlon Temp. ('F). 840
ExtlnpW.lna Age~~tl .. Dty chemical, foam, or carbon dioxide
Spedal Fire Procedure. .. Water or foam may cause frothing. Cool exposed tanks with water.
HEALTH HAZARD DATA

HeaJtb Huard Ratinp Odor Drnltold (ppiDI PEL/fWA {ppm) TLV!TWA (ppiD)
General-Non-toxic
Symptoms-Non-toxic
Sbort Esposure Tolenmce-Non-toxic
Esposure Procedura-Non-toxic. Wash thorou~,t"dy with soap and water.
REACTIVITY DATA
StabUity-Stable at room temperature.
Co.p~~tlbUity-Miterla.l: Usual materials of construction are suitable.
Cafao: Group 34 ol Compatibifrty Chart.

Wear rubber gloves, protective clothing and face shield.
If epUI oecun, call dte Nlltiolllll RetpOnR Ceater, 800-4l4--180:Z.

Remarb: t Unass1gned
58
CAUSTIC POTASH SOLUTION
Synoa)'llll- Lye; Potassium hydroxide; Potassium
hydroxide solution
CHRIS Code -.
Formula-KOH
Boillna: PoiDt ...... 45% soln. _ m c _ m'F
Appearuce-Odor-Colorless or light yellow syrupy 50% soln. ~c ----Z&a'F
liquid; odorless Freezia1 Point .. 45% soln. -~c -..2QL..=ZZ'F
Speclftc: Gn'lty--IJp to 1.54 (solid dissolved in water) 50% soln. ~c ~F
Vapol' Preaure lO'C (68"F) (mmH&) .. __L_
Cbelclll FamUy-Cauatic Reid Vapor Pretnre (plia)... ___1__
V.,or Preaure 46'C (Its-F) (plilt).. ___1__
PolludH CftetMy-USEPA __Q__ IMO ____Q__ v.,.....
ne.Jty (AJr = 1.0) ........................ --..2.2_
App]bbh- Blllk Rea. 46 CFR S.bcbapter ..... _Q__ SolubUity In Wattr .. Comp!ttt-

Gnlde-Non-llammable. Classified as a corrosive liquid.
.Ehc:trieal Gr011p-NA
Geuerai-Does not burn. It wiU react with many metals, giving off highy flammable hydrogen gas. If hydrogen is
trapped in confined spaces, it can form explosive mixtures with air. See data sheet for hydrogen.
Flull Point ('F) None

FlunmaWe Umits .. None
Aatolpdtiou Temp. ('F) .. None
E:rtfnauilbiq Apnu: .. None
Spedal Fire Proeedurell ... cannot catch fire. Cool exposed tanks with water. Fire parties respondir"IQ to a
fire in the vicinity of caustic solutions should wear protective clothing including full face protection and
rubber gloves, boots, and outer clothing.
HEALTH HAZARD DATA

Health Huanllbti:Jip Odor Thresbokl (ppm) PELJTW A (ppm) TLV1TWA (ppm)
0, 4, 1 No odor 2 mg/m ... 2 mg/m ...
General-causes severe bums of eyes, skin and mucous membranes.
Symptoms-If solutiOn splashes on skin no pain may be felt, but hair and skin in contact with the liquid will
begin to dissolve on contact.
Short Eltpo11ure Tolerance-No specific data.
E:r.popre Proeedura-00 NOT DELAY! Flush affected part gentry with plenty of water for at least 15 minutes.
Remove contaminated shoes or clothing. Get medical attention. Wash contaminated clothing, including
shoes before reuse.
REACI1VITY DATA
Staltllity-Considerable heat is generated when water is added to caustic potash; boiling and spattering of hot
caustic solution may result.
Colllpatlbillty-Mam-lal: Practically noncorrosive to iron and rubber at atmospheric temperatures. Attacks

clothing and a few metals, such as aluminum, tin, lead, and zinc and alloys containing these metals.
Carso: Group 5 of compatibility chart. See also Appendix !-Exceptions to the Chart.

Wear rubber gloves and boots, large face shield and rubber protective clothing. Avoid contact with liquid.
Secure ignition sources. Neutralize with weak acid and mop up or at dock flush with excess water.
If .,w ocean, call tbe Natlona1 Respollle ee.m- I 800-424-8802.

Remarb: Crystall1zaUon temp./Solid1fing temp.
In the form of a fine spray or mist.
t Unavailable
59
CAUSTIC SODA SOLUTION
SynonyiiiS-Lye; Soda tye; Sodium hyrdoxide; Sodium
hydroxide solution
CHRIS Code.
Bolllaa Point ...... 50% soln. -----14'C ------iif!'F

Appear...-Odor-Colorless Of gray. syrupy liquid; no 73% soln. __jj'C __HI'F
odor Freezt.a1 Point... 50% soln. ~c ____Jl.'F
Specific Gnvity-up to !.53 (solid dissolved In water) 73% soln. ___Z'C ____!4i'F
Vnpor P.._re lO'C (68'F) (mmHill ...... 1-t.ll....!n!.
O.emical Family-Caustic Reid Vapor Preuure (pejl).. _1.__
Vapor Preuure 44!i'C (lt!'F) ()llinl. _1.__
Pollution Cntegory-USEPA _..Q__ IMO _____Q__ V1por Dea.lty (Air = 1.0)... . ................. ____t:te...._
Applicable Bulk Reg. 46 CFR Subchpter ...... _Q__ Solubility In Water... ComQiaft

Grade-Non-flammable Classified as a corrosive liQuid
Electrlul Group-NA
GeneraJ-Non-flammable. It will react with many metals, g1ving off highly flammable hydrogen gas. If hydrogen is
trapped in confined spaces, it can form explosive mixtures with air. See data sheet for hydrOQen.
Flash Point ("Fl None

Flammable Limits .. None
Autoignition Temp. ("FJ None
Extinpishing A11ents .. None
Special Fire Procedures .... Cannot catch lire Cool exposed tanks with water. Fire parties responding to a
f1re in the vicinity of caustic solutions should wear protective clothing including full face protection and
rubber gloves, boots, and outer clothing.
HEALTH HAZARD DATA

Health Hat.ll"d Ratinp Odor Threshold (ppm) PEL!TWA (ppm) TLV!TWA (ppm)
0, 4, 1 No odor 2 mg/m"* 2 mg/m ..
General-Causes severe damage to the eyes. On contact with the skin, severe burns with deep ulcerations and
ultimale scarnng may result.
Symptoms-If the solution splashes onto skin no pa1n may be felt, but ha~r and skin in contact with caustic will
begin to dissolve on contact.
Short Exposure Tolerance-Unavailable.
Exposure Procedures-DO NO DELAY! Flush affected areas gently with plenty of water for at least 15 minutes.
Remove contaminated shoes or clothing. Get medical attention. Wash contaminated clothing, including
shoes before reuse.
REACI1VITY DATA
Stabllity-ConsideJable heat 1s generated when water is added to caustic soda; boiling and spattering of hOI
caustic solution may result.
Compadhility-Materilll: Noncorrosive to rubber at atmospl'teric temperatures. Slowly corrosive to iron, copper

and monel metal. Attacks clothing and a few metals, such as aluminum, tin, lead and zinc, and alloys
containing these metals.
Carao: Group 5 of compatibility charts. See also Appendix !-Exceptions to the Chart

Wear rubber gloves and boots, large face shield, and rtJbber protective clothing. Avoid contact with the liquid.
Secure ignition sources. Neutralize with weak acid and mop, or, at dock, flush with excess water.
If 1 spill occun, call tbe NatlonaJ Reaponae Cater, 800-414 8801.

Remarks: In the form of a fine m1st or spray
t Unavailable
60
NOTE: THIS CARGO tS PERMITTED TO BE SHIPPED IN BULK ON UNMANNED BARGES ONLY.
CHLORINE
Sy_,._ No common synonyms. Uaited Natloa NIUilbel" ...
CHRIS Code ..
Boilili&Poiat.. ~c ~F
A~-Greenish-yellow gas: irritating, c 'F
bleach-like choldng odor Freeztna PoiDt.. -101'C -15Q'F
Sped1k Grarity-1.47 at 32/39'F
___ c ___ F
Vapor Pri!IIW't lO'C (68'F') (mmHI) .. ~
Rtld Vapor PreNUn! I,.UJ... ___.lM._
Vapor Preuurt 46'C (115'F') (,.ta).. __l.WL_
Polllltlwl CateaorY-USEPA - - - IMO ___go_ Vapor Delllllty (Mr = 1.0).. __.2.!_
AppUeable Balk Rea, 46 CFR Subc:hapter ....... ___Q__ SolbJIIty In Water... 1 0% at Q'F

Grade-Liquefied Compressed Gas (LCG)
Eledrieal Groap--NA
General-Chlorine is nco-explosive and non-flammable. However, most combustibles will burn in chiOI'ina,
although gas is not flammable. Toxic products are generated when combustibles burn in chlorine.
Flab Polllt ('F) .. Non-flammable

Flalulahle Llmic. .. Non-flammable
Autoipltioll Temp. ('F) .. Non-flammable
ExtiRplalalaa Aanc. .. Non-flammable
Spedai Fire Procedara .. Chlorine tanks exposed to fire should be cooled with a water spray to
decrease the buildup of pressure. If leak seems likely, emergency personnel should carry self-contained
breathing apparatus so that facepiece may be donned without delay.
HEALTH HAZARD DATA

Hellltb Huard ibdp Odor Threahold (ppm) PEL!TW A (ppml TLV!TWA (ppm)
4, 2, 4 3.5 0.5 0.5
General-Gas is primarily a respiratory irritant; severe exposure can be fatal. Liquid or high concentrations of
gas in contact with skin or eyes will cause local irritation or burns.
Symptoma-Vapor: coughing, choking, burning sensation in eyes and throat, and shortness of breath. Liquid:
severe irritation or blistering. Frostbite can also result.
Short Explmll"i! Toleranee-Exposure to vapor concentration of 1000 ppm for 10 minutes has caused death.
Exponn! Proeedura-Aemove victim to fresh air. If breathing stops, apply artifiCial respiration. Oxygen,
administered by trained personnel, is often helpful. If eyes are effected, wash gently with water for 15
minutes. If liquid chlorine has spilled onto the skin, remove contaminated clothing and flood the exposed
area gently with walef for 15 minutes. Get medical attention promptly.
REACfiVITY DATA
StablUty-Will react with many inorganic and organic compounds, usually with an evolution of heat.
CoMpatlbWty-Material: Below 230 degrees F, copper, iron, lead, nickel, platinum, silver, steel and tantalum are
chemiCally resistant to dry chlorine gas or liquid. Certain copper and ferrous alloys;, Including Hastalloy "C",
monel and types 304 and 316 stainless steel also are resistant.
Cllrao: Chlorine is unassigned in the compatibility chart. For assistance, call
G-MTH-1 (202-2671577).

Wear rubber gloves, seH-contained breathing apparatus, and protective clothing. Evacuate all downwind
personnel not equipped with respiratory protection.
If a qMII oeeun, eall the Nadonal R11p0111e Ceat., II00-4Z4-8110l.
61
CHLOROACETIC ACID, 80%
Synouyms-Chloroacetic acid, liquid; MCA;
Monochtoroacetic acid
CHRIS Code ..
FonnuiJ,-CH.CI COOH
Boiling Point ..
Appeanna-Odor-Colorless liquid; acidic odor
Fnezi.na Poiat ..
Specific Grnlty-1.328
Vapor Preuure lO'C (61'F> CmHK) ..
CbemlraJ Family-Organic acid Reid Vapor Pre.lare (ptla) ...
Vapor ~re 46'C (115'F) (pala) ..
Polludon C.teaory-USEPA - - - IMO ~ Vapor De.lty (AJr = t,Ol ...
Applicable Bulk Rea. 46 CFR Sukhapter. ____Q__ SolubWty in Water ..

Grade-Non-flammable
EJectrical Group-O
General-Non-flammable, but when heated g1ves oH toxic gases. Decomposes to chlorine and phOSgene when
heated above its boiling point
Flash Point ("Fl Non-flammable

Fb.mmable Limits Non-flammable
Autoignltion Temp. ("F). Non-flammable
Exlingul8hlna Aaents. Non-flammable
SpeciaJ Fire Proeedure. .. Keep containers cool with water spray. Fire fighters must wear lull protective
clothing and self-contained breathing apparatus.
HEALTH HAZARD DATA

Health Huard Ratinp Odor Tbresbold (ppm) PEL;TWA(Jipm) TI..VIIWA (ppm)
~nerai-Very toxic water solution, can cause permanent injury or death. Always wear protective clothing when
handling.
Symptom$-lngestion: acute systemic intoxication, vomiting, internal burns and perlerations. Skin contact:
severe, painful burns and irritation; shock. Inhalation: heated vapor painful to lungs, pneumonia, breathing
problems.
Sbon E~:posure Tolerance-MISts harmful but vapor not harmful unless liquid heated.
ExpD!iure Proeedures-Aiways call physician. Eyes: flush with wat8f lor at least 15 minutes. Skin: remove
clothing, flush wrth large amounts of water. Ingestion: swallow several glasses of water, do not induce
vomiting. Inhalation: remove to fresh air.
REACTIVITY DATA
Stability-Reacts with strong bases. Stable at ambient temperature; decomposes, to toxic gases when heated.
Compatibility-Corrodes: mild steel, aluminum, copper, zinc, tin, brass, bronze. Compatible: stainless steel,
polyethylene (high density)
Carao: Group 4 of compatibility chart

Neutralize with sodium carbonate, dilute with water. In case of material being Involved, wear full-protective
clothing and self-contained breathing apparatus. Spray water on containers to keep them cool. Fight lire with
medium appropriate for fuel
,...
If a spill oceun, eall the Nadoaal RelpOIIM Ceater, 1100-4~1.
Remarb. t Unavailable
62
CHLOROBENZENE
S)'IIOil)'- Benzeoe chloride; Benzene, chiOfO-; United NlltiOIUI Namber ......
ChiOrobenzol; MCB; Monochlorobenzene; Phenyl
oNoride
CHRIS Code ..
FOIWIIIa-c.H.CI
BolliD& PoJIIt .... ____jB'C __n,Q'F
~-colorless liquid; almond-like odor c 'F
Freeziq Poblt... -45'C -48'F
S]'Kiftc Grmty-1.11 ___ c ---
Vapor Prea.re :ZO'C (61'F) <Hal .. ~
a....1c:a1 FudlJ-Haloganated hydrocarbon Refd VllfOl' Prell~~re (pda)... ____2...5_
Vapor Preaure 46'C (ll5'F') (pm) ............ _.ll.L_
Polhatioll c.teaorr-USEPA ____a__ IMO ____a__ Vapor Dellllty (Air = 1.0)... ___a.H...._
A,ue..lle a.lk Rt~~o 46 CFR S.bdaaptes' ....... ____jL_ SoiINiity l:n Water.. Neg!l!::ib!a
--0
Gnde--0: Combustille liQUid
Geaeni-Buming relaa8ea toxic and Irritating gases of phosgene and hydrogen chloride. ignited by heat or
opeo names. Flashback along vapor trail may occur. Vapor may explode in an enclosed area.
n.a Poa.t <'Fl .. 90 (cc)

Jllammatde IJmjg ... 1.3 to 7.1%
Alllofpltioll Temp. ('F) ... 1180
~.Apm ... co., dry chemiCal, water fog, foam
Special Fire Proeedarel Supply respiratory protection to fire fighting pet'SOnnel.
HEALTH HAZARD DATA

HealG Hazanl Ratfqp Odor nreaold <pp.) PEL/I'W A (ppm) nvrrwA (ppllll
0, 1, 2 Unavailable 75 75'
Gelteral-Vapor Irritating to skin, eyes and mucous membranes.
S,.pt--orowainess, twitching of extremities, and deep, rapid respiration.
Sbort Ell:,o.re Tolerance-Exposure for 0.5 hOurs to 6500 ppm or 1.0 hour to 2000 ppm would not be expected
Eipcure PI ....
to cause death.
Ramove victim to fresh air; if breathing stops, apply artificial respiration. Slo"o or eye
contact-remove contaminated clothing and gently flush affected area with water for 15 minutes. Get
medical advice or anentton.
REACfiVITY DATA
Stddlhy-Reacts vigorously with oxidizers. If heated to decompoeltlon, toxic chlorine compounds will be given
off.
eo.,.tl.blllty-M.terial: Relatively non-corroSive. Attacks rubber.
Carao: Group 36 of compatibHity chart.

Wear rubber gloves, self-contained breathing apparatus, and protective clothing. Avoid contact with liquid.
Secure Ignition sources.
If a AID ocean, call tile Natloaal a..,.._ Ceeler, II00-414-810Z,

Remarb: Proposed change In TLV to 10 ppm.
63
CHLORODIFLUOROMETHANE
SynonyiU--Oifluorochloromethane; United Nation~ Number ....
Dlfluoromonochloromethane; FIIJOfocartlon 22;
Freon 22; Monochlorodlfluoromethane: Propellant
22; Refrigerant 22
CHRIS Code ..
F01111ula-CHCIF,
BoillnaPolat .. -=.iJ.'C -=.,!2'F
Appearance-Odor-Colorless gas with a faint ethereal c 'F
odor like carbon tetrachloride Freezina PMnt .... -180'C ---::?58F
Speclfle Grnlty-1 .18
c ___ 'F
Vapor l're.UJ'e lO'C C68'FJ (mmlfl) .. _iH!L
Chemical Family-Halogenated hydrocarbon Reid Vapor ~re (p!llli) ... ....2l.2L
Vapor Pr-re 46'C (lt!I'FJ (p!lla) .... ~
Pollatlon Cate&Ory-USEPA - - - IMO ---aL... V.,or ne.tty (AJr "' un... ....2.iL
Applicable Bulk Rq. t6 CFR Subc:bapter ........ ___Q__ SolubUity In Water .. Slight

Grade-Liq~H~Iied Compressed Gas (LCG)
Electrk:ll Group-NA
Geaeni-Decomposition gasas are toxic and irritating. Weakly flammable gas.
Flub Polnt C'FL Non-flammable

Flammable Limit. .. Non-flammable
Autolpitlon Temp. ('F) .. 1170
E:diapltblna Apnb. Water, carbon dioxide, dry powder
Special Fire Procedura Shut off supply of gas. Tanks exposed to fire should be kept cool with a
continuous spray of water. Firefighters should wear self-contained breathing apParatus.
HEALTH HAZARD DATA

Healt.ll Hazard Rtinp Odor Thrahold (ppm) PEL/TWA (ppm.) nvrnu (,..al
o. 0, 1 Unavailable 1000 1000
General-Suspected carcinogen. Liquid may cause skin or eye Injury similar to frostbite. Breathing vapor may
cause unconsciousness withoot warning because of lack of o)()'gen.
Symptom-lnhalation-asphyxiation causing drowsiness with or without nausea. Skin contact-frostbite.
Sbort El.polllll"t ToleraDCe-Unavailable
Expoture Procedura-Vapor-remove victim to fresh air; if breathing stops, apply artificial respiration. Eye
contact-flood eye gently with clean sea or clean fresh water for at least 15 minutes. If the ~quid has
REACTIVITY DATA
-6tllblllty-Very stable. Decomposes slowly in presence of rust and moisture.
Com,.tibUity-Mterlal: Usual materials of construction are suitable.
Carao: Groop 36 of compatibility chart.

Have all-purpose canister mask available. Avoid contact with liquid. Secure ignition sources. Evacuate all
unprotected personnel. Flush spill with large quantities of water.
If 1 1pW oeewn, caU tbe National Rapcwe Center, 800-4U-880l.
ReiiW'b:
64
CHLOROFORM
Symmy- Formal trichloride; Methane, trichloro;
Metheny! trichloride; Trichloromethane
CHRIS Code ..
Bolllq Poiat.. ______l'C ______llZ'F

Appeanaee.Odor-CoiOrless liquid; sweat odor ___ c ---
Freeztna Poblt.. ~c -----=..azF
Spednc: Gra"rit)'-1.48 c ---
Vapor Pre~nre lO'C (68'F) {mmHI} .. ----1&_
Cllemfcal Ftly-Halogeoated hydmcarbon Reid VaiN" Pre..re (pd.IJ... ~
Vapor PraRre 46'C (lt5'F) (psia). ~
Po:lllldoa CateaorJ-USEPA ___A_ IMO ____a__ Vapor Deatity (Air = 1.6) ........................ ~
AppliCable Blllk Rea. 46 CFR Sllbdlapter ........ _Q_ SolubDity In Wale!'... Slight

Gnlde-E: Combustible liquid
EltctrkaJ Gro.p-0
Gosaerd-WIII bum only after prolonged exposure to flame or high temperatures. When heated or exposed to a
flame, chloroform decomposes to form phOSgene, which is highly piosonous.
flub Point ('F) .. None

FIHI-bae Ulllllll .. No~
Aatoipld011 T-p. ('F) ... 1155
El:tlnpidllllc AIMU .. NOM
s,eclll Fire Proced- .. Keep fife exposed tanks cool with water spray. Wear eye protection,
self-contained breathing apparatus and protective clothing.
HEALTH HAZARD DATA

HN.Itb Huard Ratiap Odor nre.llold (ppm) PEL/TWA (ppml TLV!TWA (ppm)
2, 1, 2 200 to 300 2 10
General-Suspect carcinogen. Breathing vapor in enclosed area can cause loss of consciousness. Odor
threshold is higher than the TLV. Exposure to potentially dangerous vapor concentrations can occur before
the product can be detected by smell.
S)'tll~lrritation of mucous membranes and skin; drowsiness.
Sllort Expo~ure Toleruee-lnhalation of 400 to 600 ppm for 30 minutes or tess can prove fatal.
Ex.-.re Procedara-Remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or eye
contact-remove contaminated clothing and gently flush affected areas with water for 15 minutes. Get
REAcriVITY DATA
StabUity-Oecompoaes in the ptesence of excess water or a high temperature to give phosgene and hydrogen
chloride, whidl are very toxic; can become explosive in the presence of strong alkaf1es and water.
Coll)llltlblllty-MIIIerial: Non.corrosive at normal atmospheric temperatures when free of moisture. In contact

with water and at high temperatures it becomes corrosive. Corrodes iron and certain other metals.
Cuto: Group 36 of compatibility chart.

Wear rubber gloves, self-contained breathing apparatus, and protective clothing. Avoid contact with liquid.
If a 1)101 oceun. call die NatlouJ Rapoue Cellter, IOII-4l4 8801.

Renwb:
65
CHLOROHYDRINS (crude)
Synon)'llll- crude Epichlorohydrin Un.lted NatloQ Number ...
CHRIS Code ..
M
Formula-CH.CHCH,CI
Appdl'&n"-Qdor-Light yellow turbid liquid; pungent,

Bollbag Point .. ~c
___ c ___.,
~F
garlic odor
Speclnc Gravity-1.20
Freedna; Point. ~c
___ c ___.,
~F
Vapor Pressure lO'C (68'F) (mmHS) .. .J..t_

ChellliW Famny-Epichlorohydrin Reid Vapor Preuure (,.Ia) ... __.ll.L_
Vapor Preuure 46'C Ul!i'F) (peifl) .. __Q.L_
Pollution Catqory-USEPA - - - IMO ____Q__ Vapor Den1lty (Air = 1.0) ... _:t_
Applicable BuiJr. Re1. 46 CFR Subchapter .. ____Q__ Solubility In Water .. 60%

Electrical Group-O
Genent-lgnited by heat and open flame. Burning releases hydrochiOfic acid fumes. Containen~ may explode in
fire because of polymerization.
Fluh Point ("F) .. 90 to 100

Flammable Limits 3.810 21%
Autolpidon Temp, ("FJ. 604
Extinplablng Agents .. Water, CO., alcohol foam and dry chemical
Spedal Fire Proeedures .. Wear self.contained breathing apparatus and full protective clothing. Cool
eltposed tanks with water. Avo1d use of dry chemical if fire occurs in container with confined vent.
HEALTH HAZARD DATA

Health HIWI!"d R1tings Odor Tbreabold (ppm) PEL;TWA (ppm) TLV /TWA (ppm)
3, 3, 4 <10 2/Skin" 2/Skin"
General-"Vapor extremely irritating. Lung injury may be delayed. Liquid causes severe bums. Absorbed by
leather and causes delayed burns. NOTE: Related cargo, epichlorohydrin, is a suspected carcinogen.
Symptom-Eye, nose, and throat irritation; headaches, nausea, vomiting.
Short Expo~~ure Tolei"IIDI:e-10 ppm for 30 minutes
Expo~~ure Procedures-Vapor-remove victim to fresh air; if breathing stops, apply artiftcial respiration. Skin or
medical attention as soon as possible.
REACTIVITY DATA
Stability-Unavailable
Comp~.tlbillty-Mterial: Dissolves most paints, causes rubber to swell. The wet product will pit carbon steel.
Car110: Group 17 of compatibility chart.

Wear rubber gloves, self-contained breathing apparatus, protective clothing. Evacuate personnel not equipped
with protective clothing and respiratory protection. Shut off all ignition sources. Flush area with water spray.
If 1 1plll U~~n, eaU the N1tiGnal Respoue Ceater, 800-414-8881.

Remarkl: PEL and TLV based upon Eptchlorohydnn.
t Unavailable
66
o-cHLORONITROBENZENE
Syll(lnyms-1-Chloro-2-nitrot>enzene: United Natfolll Number ...
2-Chloro-t-nitrobenzene; Chloronitrobeozenes:
o-Nitrochlorobenzene
CHRIS Code ..
Boillq PoiDt .. __..wc ~F

Appean~H::e-Odor-Yellow solid; aromatic odor ___ c "F
Freeziq Point .. ____azc
___ c _ _ _ F
gpF
Specific Gr..-ity-1.4
Vapor ~re lO'C (68'F) (nunfta) .. ~
Chemie-1 Famlly-Nitrocompounds !Wd Vapor Prat.re (. .)... __i_
Vapor~ 46'C (U!I'F) (peill) .. ~
Polludoo C.tqory-USEPA - - - IMO ____jL_ Vapor De-'ty (Atr = 1.0)..... ....u_
Applk:sble Balk Rea;. 46 CFR Subc:bapter ..... _.Q._ Sobdtillty In Water .. lnag!uble

Electria.l Group-Unavailable
General-Slight hazard when exposed to heat or flame. Tmcic vapors of nitric oxides (NO,J, hydrogen chloride
(HCI), and carbon dioxide (CO.) are given off by high temperatures or combustiOn.
F1-.b Point ("F) 261

FlaJnntable Limits. Unavailable
Autoipjtion Temp. ("F). greater than 300
Elltlagujablng Afenb ... Water spray, CO!. dry chemical, foam
Special Fire Procedures .. Water or foam may cause frothing. Weai self-contained breathing apparatus,
eye protection and protective clothing.
HEALTH HAZARD DATA

Health HllZIIrd Ratinp Odor Threlbold (ppm) PEL/TWA (ppm) TLV!TWA (ppm)
3, 2, 4 Unavailable Unavailable 1 mg/m'
Ge11.erai-Very toxic via inhalation, ingestion. Possibility of thermal burns from hot liquid. The molten liquid is
irritating to the skin. Class B poison.
Symptomt--Headache, weakness, anemia, shallow respiration, convulsions, coma, cyanosis.
Short Exposure Tole1"11Me-2 mgtm. The effects of this poison aie cumulative.
Exposure Proeed11~Remove from exposure. If indicated give artificial respiration. Flush eyes with large
amounts of water for at least 15 minutes. Wash sltin with soap and water. If swallowed, give emetic, gastric
lavage.
REACTIVITY DATA
SU.billty-Stable. Toxic vapors of NO., HCI, cea are given off by high temperatures of combustion. Reacts with
caustics.
Compatibillty-Mate1ial: Usual materials of construction are suitable.

Soak up with a mixture of sand and soda ash (9:1 ). Scoop up and place in cartons and bum. War butyl
Nbber gloves, self-contained breathing apparatus, protective clothing and safety shoes.
If .,m oecun, eall tbe N.t:IDDal Responae Ceater, II00-4l4-81102,
Remarlu: Shipped 1n the molten state at 40'C.

t Unavailable
67
CHLOROSULFONIC ACID
Synony--ChlorOsulfuric acid; Chlorsulfonic acid; United Natioa Nuber...
Chlorsulluric acid; Sulfuric chlorohydrin
CHRIS Code ..
-
Fonnula-HOSO,CI, Of SO,HCI
Boiling Polllt . ~c ____aQ'F
Appearaace-Odor-Colofless to light liquid; pt.lllgent c 'F
Freez.ina: Point.. -8Q'C ----::J'i2"F
Spedfte Gn't'lty-1.79 ___ c ---
Vapor ~re lO'C (68'F) (mmH&).. ___:d...!L
Cbemkal. Family-Inorganic acid Reid Vapor Prellmre (pda}... ......Q..Q1_
Vapor Prnlllre 46'C (115'}1) (pala).. ___QJll_
PoUdon CatesorY-USEPA _____Q___ IMO ____Q__ Vapor l>eJqity (Air = 1.0).. _..4.L
Appliable Bulk Rec. 46 CFR Subchapter ....... ____Q___ Solubility In Water ..

Grade-Non-flammable. Classified as corrosive liquid.
Electrical Group-B (based upon possible hydrogen gas (H.) generation should a teak or spill occur)
Ge!aeral-Non-flammable, but it may cause ignition by contact with combustible materials. Dangerously reactive.
Explosive coocentrations of hydrogen gas can accumulate inside metal tanks containing this acid. Spill in
confined space may produce explosive concentration of hydrogen. See data sheet for hydrogen.
FlMll Poillt ("F) .... Non-flammable.
Flammatlle LimJb .. Non-flammable.
Autolpitloa Temp. (F). Non-flammable
Exdnpi1hiD1 Apnb .. Non-flammable.
Speclal Fire Procedures .. DO NOT USE WATER Wear full l)fotective clothing, including self-contained
breathing apparatus. Cool adjacent tanks with water spray from a distance.
HEALTH HAZARD DATA

Health HIWIJ'd Rtinp Odor Threshold (ppm) PELJTWA (ppm) TLVJTWA (ppm)
4, 4, 4 3 Unavailable 1
Generai-Vapo; 1nhalation may cause loss of consciousness with serious damage to lung tissue. liquid causes
severe 1mtat10n and watenng of the eyes
Symplo1115-Contact of hqu1d with the skin can cause severe burns. Breathing the vapors will cause severe
trritalton and watenng of the eyes
Short Expowure Tolerance-30 ppm for t 0 minutes: I 0 ppm for 60 minutes.
Exposure Procedures-Vapor-remove v1ct1m to fresh air; if breathing stops, apply artificial respiration. Oxygen,
admtnlstered by tra1ned personnel, is often helpful. Skin or eye contact-remove contamflated dothing and
gently flush affected areas w1th water for 15 minutes. Get medical advice or attention.
REACTIVITY DATA
StMblllty-Violently reacts with water forming sulfuric and hydrochloric acids.
CompatlbUity-Mterial: Dangerously reactive. In addition to attacking many metals, the acid is a strong
oxidizing agent and will react with water and organic materials with evolution of heat and large quantities of
dense fumes.
CllrJO: Chlorosulfomc acid 1s unassigned in the compatibility chart. For compatibiHty assistance,
call G-MTH-1 (202-267-1577)

Wear fl.!bber gloves, self-contained breathng apparatus, protective clothing. Avoid contact with spilled liquid.
From a distance carefully flush the spill away with water. Great care must be taken as water and chlorosulfonic
acid react violently forming toxic HCI fumes and sulfuric acid. Consequently, clean-up personnel should work
with the wind at their backs. If water is not available or if inversion conditions prevail, apply dry sand, vermiculite
ashes or powdered clay to absorb the spill.
Ir aptll occura, ~:~~lithe NattonaJ ReMpoiiH Cetlter, IIOO-C24-881)Z,
ReMUb: Reacts 111olently torm1ng hydrochlonc and sulfuric aCJds.
68
COAL TAR
S)'JIOIIr-- Coal tar dlatillate; Crude coal tar; High United Natlo. N. .ber...
temperature coal tar; Tar: Tar, liquid
CHRIS Code ..
Fona.ta-Mixture
~
BoUina:Poillt .... ..Ai'C
___ c
A~Datk viscous liquid; aromatic odor ---
_____]'C _____]'F
_ _ c
Speclfk Granty-1.2
Vapor P-re lO'C (QI'F) (IIUIIHI) ..
---
.Jl.CLl!.
Reid Vapor Pre.are (!Ilia) ... __t__
Vapor~ 46"C (115"FJ (pila) .. __t__
PollutioD c.tqory-USEPA - - - IMO ___A_ Va,or Denlky (.Mr ... 1.0) .... ->..l.IL
ApplleOle hill Ret. 4Ci CFR SUdlapla .. _.o__ Solabllity lD Water .. . Ba!qw 02%

Eleetrical Gro...-D
GeDerai-MOderate lire hazard when heated.
FlMiro Poi11t ('F) .. 250 (varies according to compositiOn)

Fta..able Umit. .. Unavailable
A.tolpidOJI r-
EIUnpillllq AIPJib ..
<"F> .. Unavailable
Water spray, loam, CO., dry chemical
Speda] Fire Procedure~ .. wear full protective clothing and self-contained breathing apparatus. Remove
containers from fire if possible; if not possible, cool containers with water.
HEALTH HAZARD DATA

Health Hazard RatiDp Odor lbrab.old (ppm) PEL/IWA(pp~) TLV/TWA (ppm)
Unavailable UnavaWable Unavailable 0.2 mgtm
Geaeral-Prolonged exposure causes cancer in animals. Known carcinogen.
Sympt~lnhalation: headache, nausea, vomiting; irritation to respiratOI)' tract. Skin contact: highly irritating,
dermatitis; sensitizes skin to light. Eyes: vapor exposure irritating. Ingestion: vapor toxic, vomiting, mild
convulSions, hypothermia, dizziness
Sllort Ex)IOIIIft T.._Keep exposures below the TLV/TWA of 0.2 mg/m 3.
Expot~~re Proeedures-Eye contact: flush with water for at least 15 minutes. Skin contact: remove contaminated
clothing, wash affected areas with soap and water. lnhalafion: remove to fresh air. Oxygen or artificial
respiration as needed. Ingestion: induce vomiting, give oxygen if respiration shallow; swallow act!Yated
charcoal.
REAC'IlVITY DATA
StllltJIIty-Stable. Incompatible with strong oxidizing materials.
Colllpadbillty-Mater:llll: Swells and softens rubber.

Wear protective clothing and seH-cootained breathing apparatus. Remove all ignition sources. Ventilate spill
area if encloaed. Collect spilled liquid for proper disposition. Use absorbants for small spills: dike spill area for
large spills. After spill removal, wash down spill site. Material is a serious pollution hazard.
Re_,b: t Unavailable
U I l)liU OI:CIIrt, eall dte National Rapo1111 Cealer, I00-4:Z4 8(10l,
....
69
COAL TAR NAPHTHA
Synonymt-Crude solvent coal tar naphtha; Hight Uldled Nao. Number ...
solvent naphtha; Naphtha
CHRIS Code ..
Formula-MiKture
Boillq PoiDt .. __i3=2Q'C ~F
Appearaac:e-Odor-Colorless to pale yellow liquid with a ___ c 'F
benzene-like odor F'reedna: Point .. ~c __12'F
Spedfle Grarity-0.86 to 0.68 c _ _ _ 'F
Vapor Prea.re :zoc <68'F) <Hal .. ~
Chemical Family-Petroleum oils Reid Vapor Preaare (pala) .. ____Q,JL
Vapor Preaure 46'C (115'F) ()Ilia) .. ~
Pollution Cateaory-USEPA _ _ _ IMO _____a__ Vapor Dentity (AJr = 1.0) .... _.L_
Applieable Bulk Rq. 46 CFR Subdulpter ....... - ' L _ Solubility In Water ... Nagl!gjble

Electrk:al Group-O
General-Flammable. moderate fire risk
flub Point ('F) .. 100 to 107

Flamnu.ble Umits .. 0.8 to 6.0%
Alrtoignltlon Temp. ("F) above 530
Extlnguilhing Age11U .. Confined area-CO. dry chemical. Open area-foam.
SpU.I Fire Proeedures .. Fire parties must wear respiratory protection and rubber boots. In other
respects, fight like gasoline lire. Cool eKposed tanks with water spray.
HEALTH HAZARD DATA

Health HIIIU;rd Ratiap Odor Threthold (ppm) PEL;TWA (ppm) TLV/TWA (JIPIII)
Unavailable 5 100 100
General-Suspected carcinogen. Main hazard is vapor inhalation.
Symptoms-Dizziness, headache, drowsiness, vomiting, irritated skin, watery eyes.
Short EllpOSUre ToleriUiee-Unavailable
ExPf1$ure Procedures-Vapor-remove victim to fresh air; if breathing is difficult, administer oxygen. If breathing
stops, apply artificial respiration. Skin or eye contact-flush affected areas lor 15 minutes with water. Get
medical attention
REACTIVITY DATA
St.bltity-Stable.
CmapatlblUty-Material: Compatible with steel; certain rubbers and plastics are incompatible.

Wear rubber gloves, lace shield, plastic coated protective clothing. Wear seH-contained breathing apparatus.
ApproaCh from up-wind side. Avoid contact with liquid. Secure ignition SOUfces. Small spills may be flushed away
with water.
If a 1piU oeeur., ull the National Respoi!R Ce.ter, I00-4l4-8801.

Remark&: r Unavailable
70
COTTONSEED OIL
Sy_,....._ No common synonyms. Ualled Nation~ Nlllllber...
CHRIS Code ..
Formubi-Mhrture of C-14 to C-16 fatty acids.

BoUI&Polat.. ~c _ _.,
Appearuee-Odor-Pale yellow or yellowish-brown to c 'F
dark ruby red; odorless liquid when pure F'rtem1 Poblt... -O'C -32"F
Spedftc Gnlf;J--Q.92 c ___ .,
Vapot' Preaure lO"C (68'F) <-Hi).. ____2JL_
Cllndeal r-Uy-Ester Relll VaiiOJ' ~(pill.)..... ____u_
Vapw Pre.lll'e 46'C (U5"F) (,.fa)... ~
PoU.tloll Cateaory-USEPA - - - IMO _____.D__ Va,or Dellllty (Alr '"" 1.0).......................... _.L_
AfpUcMJe lid. Rea. 46 CFR S.bclaafter ........ _____.D__ SolbiHI)' t. Wider.. Noolkit"'

GrMe-E: Combustible liquid
Eleetrk:al. G.......-D
GeDenii-SNght fire hazard when exposed to heat or flame.
....... Pobll ("F) .. 486 (cc)

~llidtl .. Unavailable
Aalofpldoll T-p. ('F) .. 650
EithlpiUbl1 Apna ... Dry chemical, foam, or carbon dioxide.
S,.W Fire ProcedurM .. Water may be Ineffective on fire. Cool exposed tanks with water.
...................
0, 1, 0
HEALTH HAZARD DATA
Odor nl'fllllolll
Nooe
cp,.) PEL/1WA (Jipm)
No""
TLV/TWA
No...
(ppm)
Geaerai-Non-toxic
s,..~on-to)(ic
SHrt E:.:,...re Tolenace-Non-toxic
ExiM*Ift Proeedurs-Non-toxlc. If accidently splashed into eyes, wash eyes thoroughly with copious amounts
of water.
REACfiVITY DATA
StabiUty-Stable.
Cap~tlblllty-Materiah Usual materials of construction are suitabfe.

Wear rubber gloves and face shield. Clean up excess amounts and wash residua away with water.
If a .,w oce~~rs, call tile NatloQI Relpoue ee.aer, II00-4l4-11101.

Rem11rb: t Unav&Jiable
:t Unassigned
71
CREOSOTE COAL TAR
Synony-- Coal tar creosote; Creosote !rom coal tar;
Creosote oil; Dead oil; Heavy oil; Liquid pitch oil;
Tar oil; Wash oil
CHRIS Code ..
-=--
Formula-Unavailable
Bolllq; Point ......................... -~c-~F
Appeanace.Odor-Yellowish to dar11. green-brown; c
"F
characteristic tarry, aromatic odor Freed Point .. _____.!'C = = F
Speclftc C...tity-1.07 c ---
Vapor Pre.ue lO'C (61'F) c-HI).. ~
Cbnalnl F-lly-Hydrocarboo (aromatic) phenol Reid Vapor Preaure (plia}... ---L.I;B[_
v.,.,.. Prellure 46'C (JI5'F> {]lila) ............ ----l.Jm..._
PoUutioa C.teaor)'-USEPA _..x__ IMO ___A__ Vapor De.lty <Air ... 1.0)... ___f_
AppUable Bllllr. Rea. 46 CFR Subet.pter ....... ____Q.__ SoiWIIty Ia Wllter.. NMiipM)!e

Grltlr-E: Combustible liquid
Eteetrlcal GrGIIp--0
General-Moderate f1re hazard when exposed to heal or flame.
Fluh Point ('Fl. 180

Flul-ble Umlta .. Unavailable
Autoipltlon Temp. ('F) .. 637
Ell:tlnpilllln& APJ!tl .. Confined area-CO., dry powder. Open area-loam, water spray.
Spedal Fire Procedura .. Provide fire fighters with breathing apparatus. Water or loam may cause
frothing. Do not direct water directly into a fire.
HEALTH HAZARD DATA

Health Huard RatiDp Odor Thrabold (ppm) pEL/IW A {Pflll) TLV/IWA~)
2. 3, 2 Unavailable UnavaUable Unavailable
Genenll-Severe neurological disturbances when fumes are inhaled at high concentrations. MOderately toxic,
skin and eye Irritant.
Symptoms-Difficulty in thinking, sight impairment, difficulty walking in straight line, stammering or stuttering.
Short ExpOSure ToleraDCe-Unavailable.
Expotw-e Procedurn-lnhalation: Immediately remove victim from contaminated atmosphere. If breathing Is

interrupted, artificial respiration should be applied immediately. A physician should be called.
REACTIVITY DATA
Stab1Uty-5table.
Comp~tlbillty-MateriaJ: Not corrosive to iron or steel.
Carao: Group 21 of compatibility chart. See also Appendix 1-Exceptionl to the Chart.

Wear rubber gloves, lace shield, protective clothing. Have all-pupoae canister mask available. Secure all
ignition sources.
If I tpill occun, ealJ lite National ReapoaM Cealer, 100-434 IIOl.

Rl:....-b: t Unavailable
:j: Unassigned
72
CRESOLS
(a mixture of orlho, meta Mel e ICr!!O!)
s,--,..._Crnol (2, 3-, 4-); Craylic .cld; Cresylol; UaUed NMfou N-bef...
Hydloxymethyt benzene; Hydn)xytoluene;
Methytphenol (2-, 3-, or 4-); OxytoluenH; Tar acids;
Toluol (o-. m-, p..); Tricresol
CHRIS Code .. .. __.QBL
P----.cH,C.H.OH
BoWq Point.. .................. ..u::lJZ'C .2i5.::31]'F
~to-own liquid: smells like "C 'F
"LYIC)t" <llintectant, SWHI, tany Free:zmi Pobat .................... ~c 51 tp PS'F
___ c ___ 'F
s,.dfk Grnltr-1.03 to 1.05
v..- ~ lO'C IA'F> <-HI)... .. ......2.22.....
ReW Vapot' Pre-we (JIIIa). ........ ____iUl3__
v... P.......-e c ms'F) ()IIIII)... .. ....JlJI!IL..
PaUIJdoa C......,.-USEPA _.k_ IMO ___A__
A.,UC.W. lhlk Jtea, 4t: CPR...,._ ....... __Q_
v.,... DealtJ'
Sohd:IBhy ..
(Air = ............................. .....J..Z2._
WMer... 2S%
--0
er.le-E: Combustible
Gnera&-Moderllt. fire hlwlrd when exposed to heat or flame. When heated, toxic vapors are given off.
--
................ .............
f'IIIIIIIPfUt('F') ... 178 to 187 (varies with composition and purity)
LEL=1.1% UEL-unavailable
A~T-..rF) ... 1038 to 1195
........ ......... CO., dry chemical, to.m. water fog
s,edal Plre Proeredwa ..... Full body and lftpimory protection should be provided. Use water to keep
fira expoeed wu cool. Use water IPI'AY to dispefse vapors.
HEALTH HAZARD DATA

Heallla Huanll a.tblp Odor 'I'IIrelhW {Jfm) PEL/IWA(.....) TI.V/IWA {JIIIIa)
2, 3, 2 1005 5/Skln 5/SI<In
c....t-SI!8p8Cted carcinogens. C.U..s severe bums. Polaonous by akin absorption. Odor threshold is about
the aame as the TLV. Expoan to potentially dl!ngeroua vapor concentration can occur before ttla product
can be detected by 111'1811.
s,.,.,
...... Burning sensation ln throat. nose and eyes. Burning saoation at the site of contact: skin may turn
Sllort Ea:,..-e Teleraee-Extenstve skin contact may be latalln a very short time.
~:a:,..... Proeeduw-Vapor: Remove victim to fresh air; if breathing stops, apply artiftciaJ respiration. Skin or
eye c:on1act reti'IOIYe COitlaii*tatecJ Clothing 111\d gently ftueh affected area with water tot 15 minutes. Get
medical acMce or attentiOn.
REACJIVITY DATA
sa.biUty-Not dangerously reactive.
Co.pat~Wltty-Matertal: Not considered COITOSIYe to most of the usual materialS of construction.
CartD; Group 21 of compatibility chart

Weer rtbber gloves, lace sNeld, and protectiyfl clothing. AVOid oontact with the liquid. Do not IIUih into
navigable wat.- or wtwe It may be oontactec1 by human beings or animals.
H a .,W ocean, call tbe Nadoul a.,... C.ler, 100-424 IIOl,
73
CROTONALDEHYDE
Sy-y-2-Butenal; trans-2-Butenal; United Natlou N11111ber ...
Crotenaldehyde: Crotonaldehyde,
stabilized; Crotonic aldehyde; beta-
Methylacrolein; Propylene aldehyde
CHRIS Code ..
Fonna.la--CH,CH = CHCHO
Bolllq Po6nt... ___.,
__ruF
A,._.....c:e-Odor-Water white to yellow liquid;
suffocating tarry odor
Specltk Gra'rity-0.85
Frecdq Polllt .. ___.,
.........;;;.l,'F
Vapor Preaure lO"C (61"F') (mmHI) .... ____32_

~ical F-lly-Aidehyde Re6d Va,or '"'-e (plia)... _u_
PolluUoa. C.teaorf-USEPA _JL. IMO _a._
Applkal!le &.lk Res. 46 CFR Subdlaptw ....... ___Q__
Vapor Pnaure 46"C UU"F) (JIIta> ..
Vapor ne..lty (Air = 1.01 ...
Solublllt)' Ia Water ..
-=-
___2M_
Slight
--p--C
FIRE a: EXPWSION HAZARD DATA
Geaeni-At elevated temperatures, polymerization occurs. If the polymerization takes place in a closed
containEif, violent rupture is possible.
F1ub Point ('F) .. 55

FJ-1111.bk Um.lb. 2.1% to 15.5%
Autolpld011 Temp, ('F) .. 450
Edlnpilhilll Ap!IQ .. Alcohol foam, carbon dioxide or dry chemical.
Speeilll Fire Proceduns .. Cool hot container surfaces with water.
HEALTH HAZARD DATA

Health Huard Ratiap Odor Tbrnbold (PPJII) PEL/I'W A (ppm) nV!TWA (ppm)
3, 3, 3 0.13 2 2
Genen.I-Suspectad carcinogen. Vapor elrtremeiY irritaf1ng. Uquld causes severe burns. A lachrymator.
Syntptoma-Vapof causes f1'l8 irritation and burning skin irritation at high concentrations, and inhalation results
in coughing, watering of eyes and burning of nose and throat. Uquid causes- severe irritation to eyes and
skin
Sbort li:xpOSure Toleranee-Unavailable.
ExpOSure ProcedurM-In case of skin contact, wash thoroLV!Iy with soap and water for at least 15 minutes. In
case of aye contact flush with water then obtain medical ald.
REACI1VITY DATA
StabiUty-May polymerize when mixed with acids or bases.
CmnpatfbJIIty-MIerial: Compatible with aluminum and stainless steal.
Cu-so: Group 19 of compatibility chart. See also Appendix !-Exceptions to the Chart.

Wear rubber gloves, self-contained breathing apparatus, protective clothing. Avoid contact with Wquld. Secure
ignition sources. Cover with sodium bisulfite (NaHSO,). Add small amount of water and mix. Scoop up. Wash
site with soap solution.
It 1J11U otC!11n, eall t1te NUioaal Re.poue C..ler, 800-4:M-810l.

RentUb:
74
CRUDE OIL
s,._,._-Coal Oil; Mineral oil; Petroleum; Petroleum
crude oN; Rock oil; Seneca Oil
CHRIS Code ...
.............. ~c ~F
A..,...._..odorThick, heavy liquid, yellow to dark c 'F
reddish-brown or black color; distinct tarry odor. FneziD& Poblt... -45'C -SO'F
Spedlk GralitJ-Q.85 to 0.95 c ___ 'F
Vapor Pre.are 20'C (68'F) (mHIJ) .. . __l_jg_L
a.emk:U FamJiy-Hydrocarbon mixture Reid Vapor Pre.ure (plla)... ...=:::.2J2_
Vapor Preuure 46'C (115'F) (pdll).. ~
PoUIItiH Cateaorf-USEPA - - - IMO ~ Vapol' DeDalty (Air = 1.0)... ............ .i&m1..1
Applk:able Balk Jtec. 46 CFR Subeba,ter ........ ~ SohlbiUty In Water.. Nl!]llpible
---
Flub Point ('F) ..
F'laalaUie IJmlla ....
FIRE II EXPLOSION HAZARD DATA
GNde-C or D depending on flash point
General-When heated to decomposition, it emits toxic fumes. Moderate to severe.
-50 to +90
Unavailable
Alltolpidoa Teaap. ('F) .. Unavailable
Extiqailllhla Atem co., dry chemical, loam, water log.
Special Fire Proc:ettam ..... TankS exposed to fire should be kept cool with a water spray. Fire lighters
shOuld wear respiratory protection.
HEALTH HAZARD DATA

Heal.tll Haard RatiJip Odor Threlltold (pflll) PEL/l'WA (p~) TLV!1W A (pPJII)
0, 1,1 Unavailable Unavailable Unavailable
General-Liquid causes skin irritation.
S:r..-Skln contact; skin irritation and bums.
Short EJ:poAre To&eruee-Unavallable
EJ:poelll't ~Wipe spiNed liquid from skin, remove contaminated clottwlg, and wash affected areas
with soap and water. For eye contact, flush wtth water for 15 minutes while obtaining medical attention.
REACllVITY DATA
SUbUitJ-Chemlcally stable.
eo.,.dbiUt)'-M.terlal: Usual materials of construction are suitable.
car.: Group 33 of compatibility Chart.

Wear rubber gloves, face shield, protective clothing. Have all-purpose canister mask available. Secure
ignitioo sources.
........ U a .,W. 0CC11ft, call the Nlltioul Re1poMe Center, 800-424 IIIOl
75
CUM ENE
Syaiiii)'JIQI-Benzene, 1-methylethyl-; Cumol: Isopropyl Vnlted Nlltl0111 Number ...
benzene; (1-Methylethyl)benane; 2-Phenyl propane
CHRIS Code ..
BoJIIq; PoiDI .. _____lli1"C _____.a!lll"F

.,
Appearuce-Odor---Colorteas liquid; sharp, penetrating
aromatic odor
S,edfk Grnlty-0.86
Freeaq Point...
___
c
-98"C
c ___.,
-141"F
Vapor Preallre ZO'C (68"}1) (mmHI) .... ___I__

Cbentkal F...Uy-Aromatic hydrocarbon Reid Vapor Pnaare (pN.) .. __li.L_
Vapor P~re 46'C (ll!'JI) (,.U.) .. __.1!&_
Pollutioa c.teaorY-USEPA __Q__ IMO ____a__ Vapor Deasity Wr = 1,0) ... ~
ApplleQie Balk Rq. 46 CFR Subdlllpter . . ____D._Q_ Solubility Ia Water .. Nogljgjblt

Gr.de--0: Combustible liquid
Electrical Greup-D
Gelterlli-Vapor forms explosive mixtures with air.
Flub Poiat ('F) ... 102 (cc)

F1...~~~able Umltl .. 0.9 to 6.5%
Autolpltioa Temp, ('F) .. 795
Extinpldlln& Allfl!tl .. col. dry chemical, foam, water log
Specllll Fire Proeedure:~ .. Use water to keep fire-exposed containers cool.
HEALTH HAZARD DATA

Health Huard Ratinp Odor lbrabold <ppm) PEL;TW A {ppm) TLV/TWA q,p.)
1, 1,1 1.2 50/Skin 50/Skin
Generlli-Yapor and liquid imtation.
Symptoms-lmtat!on of nose and throat; drowsiness.
Sbort Expo~ure Tolerance-Occasional short exposure to concentration of 400 ppm probably would not be
harmful
Expoture Procedures-Vapor-remove victim to fresh air: if breathing stops, apply artificial respiration. Skin or
medical adv1ce or attention.
REACTIVITY DATA
Stability-Stable. It can react with oxidizing materials.
Comp!ltiblllty-Materlal: Attacks rubber.
C11r10: Group 32 of compatibility chart.

Wear rubber gloves, lace shield, protective clothing. Have all.purpose canister mask available. Avoid contact
with liquid. Secure Ignition sources. Small spills may be washed away with water.
If I tpW ocnn, WI tbe Natlou.l RelpoMe Center, 800-4~2.
Renwb:
76
CYCLOHEXANE
-
s , _ , _ Benzene, hexahydride; Benzene,
hnahydro-; [HeKBhydrobenzene; Haxametnylane;
,------,
F..........CH.(CH.),CH.
~mobile liquid; sweetish

UWied N.UO. N ............
CHRIS Code ....
BoW.. PoW .. ___11 c ----1ZZ'F

c 'F
odor when highly pure, pungent odor otherwl&e. Frwzlq Pobll ... _J."C +''F
s,edlk Gn:rlQ--0.78
___ c ___.F
VIIIIOI' Pr-.e :ZO'C (QJ'F) <mmlfl) ..
a.-tal F..Uy-Saturated hydrocarbon Reid Vllpell' ~ (plla)
VllfOI' Pr-.re 46'C (115'P:I (. .) ..
PolhdiGa ~-USEPA -...C.._ IMO ____&:...._ Vllf'll' De111itJ Wr = 1.6)..
AJipHcUie lhllk Ret. 46 CFR S.bdlllpter ........ -1W:L SoltlbWtJ Ill Water ..
--0
Gnde--C: Flammable liquid
~When
exposed to heat or flame it can react with oxidizing materials. Flashback along vapor trail may
occur. Vapor may explode If ignited in an ancloHd area.
Plldl Podt ('F) .. -4

"-aWe u..tu .. 1.3 to 8.4%
Aalvtpldoll T_,. ('Fl .. 500
._. .............. .. ............ Foam, carbon

~~
....... dioxide or dry Chemical
In unconfined fires, SOlid hOH streams tend to scatter the liquid and spread
the fire. Use water spray or high pressure fog to cool a burning surface and exclude air to control or
extinguish fire.
--- 1, 1, 2 300
HEALTH HAZARD DATA
Odor 'l1lnlltold (ppll) PEL/IWA (ppm)
300
TLV JTW A (fpm)
300
Geaeni-Undesirable eff8cta may occur from the inhalatiOn of excessive concentratiOns of cydohexane vapor,
prolonged or repeated skin contact with liquid, and from liquid contamination of eyes.
s,..,..__Dizzlnesa, nausea, vomiting, unconaclousnesa.
Sllort Ex)IOIIn Toleruee-No chronic effects have been observed to occur In workers exposed to vapor
concentrations in the range of 600-700 ppm.
Ex.-re Proeedarel-lf cyclohexane is splashed into the eyes it should be flushed out immediately with
copious amount of water. For over-expoaure by inhalation to high vapor concentrations, remove patient to
fresh air, administer oxygen therapy or artificial r88plration it necessary.
REAcriVITY DATA
std!Wty-Stable.
CollpaiWUty-Mmrial: Usual materials of construction are suitable.
ear.o: Group 31 of compatibility chart.

Wear rubber gloves, face shield, protective clothing. Haw all-purpose canister mask available. Secure
ignition sources.
If a ..W oc:can, call 11ae Natioaal a.,.._ Cater, IOQ..424 IJIOl.

a-b: . Pollution Category C oii-Hke, 33 CFR 151.49.
Vapor Pr8881.1'a: 97.6 mmHg at 25'C.
77
CYCLOHEXANOL
SyMJD)'IIII- Cydohexyl alcohol; Hexahydrophenol;
Hydroxycyclohexane
CHRIS Code ..
BoWq PeNaL.. ___jj 'C ------.a22:'F

AppeuaJM:r-Odor--Colortess to pale yellow oily liquid: c 'F
camphor-like odor Frentna Point.. ~c tJZ"F
Specific G ...-rlty-0.94 ___ c ---
Vapor Preaare lO'C (68'F) (-Hi).. _1JL_
Rrid Vapor ~ (pdl) __jU___
V.,or P~ 46'C (115'F) (. .)... ---2.L.
Pollution Categary-USEPA - - - IMO _____k_______ Va)IOI" De111Uy (Air = 1,0).... ............ ~
Applicable Blllk Rea, 4fi CFR Subchapter .. ___ll_Q_ Solubility Ia Water.. S!jght

Eledrieal Group-O
Geaerai-Moderate fire hazard. When exposed to heat or flame It can react with oxidizing materials.
Flab Point ('F) .. 154 {cc)

F'lanunallle Llmlb. Unavailable
Aotolpition Temp, ('F). 572
Es.tiDJUk!UIIIJ A,entl .. Alcohol loam, carbon dioxide, dry chemical.
Special Fire Procedlll'ft .. Cool exposed tanks with water. Wear self..contained breathing apparatus.
HEALTH HAZARD DATA

Health Huard Ratinp Odor Thre~~bold (ppm) PEI./l'W A (ppm) 1LVII'WA l.,ml
1, 2, 1 Unavailable 50/Skin 50/Skin
General-Vapor and nqu1d irritation. Systemic effects produced.
Symptoms-Vapor-nritat10n of mucous membranes, headache. Liquid-ulceration, thickening of skin.
Short Es.posure ToleriJiu-3 to 5 minutes exposure to I 00 ppm was objectiOnable, producing nose, aye, and
throat Irritation.
Exposure Pr~~~:edures-Vapor-remove vicllm to fresh ar, if breathing stops, apply artificial respiration. Skin Of
eye contact-remove contaminated clothing and gently flush affected areas with water for 15 minutes; 20 to
30 minutes tor eye contact Get medical attention.
REACTIVITY DATA
StabiUty-Stable.
Compatibility-Material: Usual matenals of construction are suitable.

Wear rubber gloves, face shield, protective clothing. Have all-purpose canister mask available.
with liquid. - oontact
If a apW OCtllnt adl tlte Natloaal Rapoae Center, 800-424-1102.
78
CYCLOHEXANONE
s,._,._ Cyclohexyl ketone; Ketohexametttylene;
Pimelic ketone
,------, CHRIS Code ..
Form.la-CHs(CHs),CO
BoWna Pobat .. _____.19'C ______aj_3_'F
A~Water-whlte to pale yellow liquid; c 'F
odor reminiscent of peppermint and acetone. Freezill& Poblt... -i11'C -24'F
Spedfk Gnml)'-0.95
___ c ___ 'F
Vapor PreMure lO'C (6B'F) ~H&) .. ____i__
Chemk:ll Fa.llJ-Ketone Rehl Vapor PreMure (pda)... ~
Vllf!OI' Pnaure 46'C (115'F') (plia)... __g.m_
PeiiJaticMI c.teeDrr-USEP A _____Q__ IMO _____Q__ VapoT DeD.lty (Air = 1.0).......................... ~
ApplkUle Blllk Ret. 46 CFR S.belulpter ...... ___Q__ SotablUty iD Waler.. Slight

Gn.W-0: Combustible liquid.
-G,.......O
Gmeral-Moderate fire hazard, when exposed to heat or flame.
,.... Pobll ('F'), ... 129
Alrtolpldoa r-,.
n-ble u.tta ..
Es:tiJiald*ialApall ...
<'F>
1.1 to8.1%
788
Alcohol loam, dry chemiCal, CO.
Special Ftre ProceUre. .. ............. wear full protective clothing, self-contained breathing apparatus.
HEALTH HAZARD DATA

Healtll Haunl RatiDp Odor 'l1lrelllold (ppm) PEL/I'WA- TLV!TWA (ppm)
3, 2, 1 0.12 25/Skin 25/Sidn
Gelteni.-Vapor inhalation Irritating to roocous membranes.
~Eye, nose, and throat irritation; narcosis, salivation; depresaion of body temperature, respiratory
rates, heart rates.
SJiort Exponre Toleruce-50 ppm for 3 to 5 minutes was uncomfortably Irritating, particularly to the throat
Definite eye, nose and throat irritation was reported at 75 ppm.
E:KJICIIIIftPtI

Vapor-rfiiTIOV8 victim to fresh air; If breathing stops, apply artificial respiration. Skin or
eye contact-remove contaminated clothing and gently flush affactad areas with water tor 15 mintues. Get
medcal advice or attention.
REACI'IVITY DATA
stQftltJ-Stable.
Cclmp.nftdUt,-Mater1al: Usual materials Of construction are suitable. WNI attack most paints.
Carao: Group 18 Of compatibility chart

It possible, wear rubber gloves, face shield, and protactlva clothing. Sectn ignition sources. Have all-purpose
canister mask avaMable. Keep unprotected personnel upwind of contaminated area. Flush spill with water.
If .,W OCCIIflt all tiM Natloul ...,._ Ceater, 8110-424-1101,
79
CYCLOHEXYLAMINE
~Aminocyclohexane; Cychlohexan~~mlne; Uuted Nauc.. N .................................... ....2iiAL
Hexah)'droanWine
CHRIS Code .. ....l<llA_
....., Pobll... ....... ____wc _mF

~18iiquid: strong c 'F
ammonia-like odor . _ ,_ ..... JI"C ~F
Spedllc C...rit)'-0.865 ___ c ---
v..-Pte.ua20"CCWF>~ .. -......l ..JU12....
a....iad FaaUy-Atlphatic amine Reid v.,.,.. p,_. c:,.ta)......................... _.1.,_
Vapor..,_..,. 46'C (115'11) (JIM) ...... ...JI.I11...
PolllldH Cllepry-uSEPA - - - JMO _..sL_ V11p0r n...hJ Wr = 1.0) .. ~
Afptlaltle Blllk Rea. 46 CFR S.llcbapter .... _..Q__ SolaWIIt:J ill W_. ........................ , Hth

Gnde-0: Combustible liquid
Electr:leal G~
ee.er.I-Dangerous when exposed to heat or fire; gives off toxic fumes. Fluhback along v.por trail may occur.
Vapor may explode if ignited in an enclosed ~~p~~ce.
F1ub Poi.t ('FL ... 90

-.......nleUIU .... Unavailable
Autotpfti011 Tep. ('F) .... 560
Eutqaialdq ....-, ... Foam, CO,, dry chemical
Spedal Plre Proeedum .... wear goggles and 881f..contained breathing apparatua. Cool expaNd tanks
with water.
HEALTH HAZARD DATA

Heald! HUIII'd Ratt.p Odor nre.Jiold (Pflll) PEL/TWA epp.) TI.VIIWA C,.)
GeaeraJ-Strongly caustic.
Symptoma-lnhalation of vapors, and skin and eyes contact with liquid wNI cause 88Yel'8 burnt.
Sbort Ell:ponre Tolenmce-Unavailable. Acute exposure cauM8 nauMa, anxiety, app~ehenelon, llurr8d tPMCf'l,
pupilary dilaf10n.
E:~.PGIUft Proced....-lnQ&ttion-do not induce vorriting. Eyes-nu.h with water tor at lAIIt 15 mlnuln, get
medical anention immediately. Skin-remove contaminated clothing and flueh akin with large amounts of
water.
REACI'IVITY DATA
SU...IIt:J-Stable.
ea.,.tfbftftJ-Materlal: Corroalve to copper and ita attoya.
Carta: Group 7 of compatibility chart

Avoid contact with liquid. Keep people away. w.., lUI protective clothing, eelf-contalned brftltllng apparalul
and rubber overclothlng. Try to contain. For large apllta claperM and ftwh. S.CW. \griUoro ~.
If a .,W ocan, caU tile Nadoal..._. ee.t.r,IIJO...G4 IIIOl
80
pCYMENE
s , _ , . _ Cymol; Dolcymene; 4-lsopropyt-1-methyl UnUed Nau- NaMber...
benzene; lsopropyltoluene; 4-lsopropyl toluene;
p.lsopropyttoluene: Methylisopropylbenzene:
.,..,....
1-Methyl-4-isopropylbenzene: Methyl propyl
CHRIS Code ..
BoUII Point .. ___!ll'C __ID'F

A~lees liquid; benzene-like odor c 'F
SpecHk Grarity-0.86
___ c _ _-90'F
-88'C
_ 'F
Vapor PrnHre lO"C (68'F) {tlunH&) .. ___LQ!L_
ca-b~ Fandly-Aromatic hydrocarbon Reid Vapor Prea.re <,.U) ... ___LQ!L_
Vapor Pr-..re 46'C (115'F) (pt.lll) .. __MlL_
PollutloD c.tqory-USEPA - - - IMO .......___ Vapor Dealty (Air = 1.0) ... ~
A,..icable &.Ilk R.._ 46 CFR SuiM:bapter ........ .....D....Q_ SohabiHtr iD Water .. Nagljqib!e

Gnde-D; Combustible liquid
Eledric::ll GI'OII~
General-Slight explosion hazard when in the form of Vapc!f.
Flub Pohlt ('F) .. 117
Alltot&DitlOJl r-,. <'F> ..

FJa.-ble Ual.tl ..
Extiqailld.. Apntl ....

0.710 5.6%
817
CO,, dry chemical, water fog, foam
Spec:lal Ftre Procediii'M .. Fight in the same manner as any Grade D petroleum product lire. Water may
be ineffective. The vapors of cymene are more toxic than those of petroleum products.
HEALTH HAZARD DATA

H..atb Huard IW:Iap Odor Threshold (ppm) PEUI'WA~l TLV!TWA (ppm)
General-High vapoJ concentrations are intoxicating.
s,-,._Dizziness, headache, and nausea. The victim may act as if drunk.
Sbort ExpoMre Toleranee-Unavailable
Expollll'e Proceii-Vapor-remove victlm to fresh air; if breathing stops, apply artificial respiration. Skin or
REACTIVITY DATA
Stabillty-Stable.
CompatiiNIIty-MIIterlal: Cymene will cause rubber to swell and soften.
Carao: Group 32 of compatibUty chart

Wear rubber gloves, faca shield, protective clothing. Have all-purpose canister mask available. Secure Ignition
"""""''
If a 11pJU oc:eun~, eall the N.ttoa.l Retp01111e Cellter, II00-4l4-880l.
Remarkl: Pollution category C 01l-l1ke, 33 CFR 151.49.
81
lso-DECALDEHYDE
s,._,....._ lsodecaldehyde, mixed Isomers; UaUed NatiHI N . .ber...
Trimethylheptanola
CHRIS Code ....
Fonnula-C,H,.CHO, mixture of isomers

BoUIII& Polllt.. ____JJZ"C _ w " F
A~r-Colorless liquid with a pleasant fruity c 'F
odol FNedq Polllt.. -M'C ---=TI2'F
Spec:lftc Gna,lly-0.83 ___ c ---
v..- rr..ur. .zoc C61'FJ c-HJ).. ~
Cbemkal F&adly-Aldehyde Reid v.,.,.. rr-te (flta). .....2JlL..
Vapor rr-re c Cll!I'F) C,u.J... _Q.QD_
Pollati1111 C.teaorY-USEPA - - - IMO ____@_Q_
A~lable Balk Re,:. 46 CFR Subdu;pter ...... ---'2.....Q...
v., De.lly Wr = 1.0)..
SoliiWIIty In Water
-A.B.....
ln112!ubft

Grade-E: Combtlstible liqu1d
Electrical Group-C
General-This matenal IS more of a health hazard than a fire hazard.
Flub Point ('f} 185

Flam~Uble Limlu Unavailable
Autoip.ition Temp. ('f) 375
E~:tiaguit;bina A~nU. Carbon dioxide, foam and dry chemical
Special Fire Procftura Cool container surfaces with water.
HEALTH HAZARD DATA

Health Huard Ratlnp Odor lbrabold (ppm) PEL/IWA C,.J nvIIWA <pp..~
1.1.1 Unavailable Unavailable Unavailable
General-Vapor Irritating to mucous membranes.
Symptoms-Coughing and sneezing, burning and tearing of eyes, salivation. Signs of Irritation of the mucous
membranes
Short ~1.p<:.11~ ToltllUIU-Unavailable
~1.poeure Proeedurm-Strong concentration on the skin will produce burns. Obtain medical treatment Weaker
solutions may cause discoloration, roug,ening and 1\ardening. Spills on skin should be washed Immediately
with soap and water.
REACilVITY DATA
StliiNUty-Stable.
CompattbUity-M1terlal: Compatible with aluminum, steel, stalnleu steel; not compatible with galvanized Iron.
SPill OR LEAK PROCEDURE

Wear rubber gloves, selt..c:ontained breathing apparatus, protective clothing. Avoid contact with liquid. Cover
spill with Sodium bisulfite (NaHSOa). Add small amount of water and miX. Scoop up. Wash sHe with soap
solution.
If I 'fNU occun, call tlle NllioDal a.,o- C.ler, 10(1...4l4 1801.
82
lao-DECYL ACRYLATE
~Acrylic acid, laodeeyl ester; lsodecyl
acrylate; lsodacyl propenoate
CHRIS Code ..
BoW.. h'at.. ______mc ______2;Q'F

~water while liquid; pungent odOf c 'F
Freedq; Pohlt.... ---=lOOc -HB'F
Spedne Grarity--0.89 ___ c ---
Vapor~ ZO'C IA'FJ <-HI).. ~
a-.kal FIUIIUy-Acrylate ReJd Vapor ~re (,.W... __j,gyt_
PoUatlon c.te,or,-USEPA - - - IMO _ A _

Vapor
VllfOI'
...._re
Dellllty
46'C (115'F)
(Air = 1.0)...
(pllaJ... ~
............... _LL_
Applkdlle Jhllk Rea. 46 CPR S..KIIapter ..... ~ SolabWty Ill Water........ Naq!lq!b!a

Electrical Gro11p-D
Gueral-May polymerize to gummy solid. Reaction i8 not violent.
,._. Pot.t ('F) .. 240

,.._..,le IJmjg .. Unavailable
Autoipldoll Tep. I'Fl .. Unavailable
Estblpillllq Aaen. Foam, dry chemical, CO,
Spea.J Fire~ ... Water might be ineffective. Cool exposed tanks with water.
HEALTH HAZARD DATA

Healtlr. Huanl Ratlnp Odor 'l'taraHJd (ppm) PEL/TWA (,_1 TLVIIWA lppml
1,1,1 Unavanable Unavailable Unavailable
Ge.enl-Uquid causes sweiNng and redness after about 10 minutes.
S)'lllptonii-Skin contact: SweiUng and redness.
Short EpotUJ"e Toleruce-8 hour exposure of rats to concentrated vapors approaching saturation in air was not
fatal. Inhalation causes mild irritation of nose and throat; vapor mildly irritates eyes.
~ ~V&pOf-remove victim to fresh air. Give artificial respiration H breathing stops. Sltin or eye
REAcriVITY DATA
St.lbWty-Stable if inhibited.
c-patJ.bWty-Material: Will swell and soften certain rubbers and soften and remove certain paints.
ear.o: Group 14 of compatibility chart.

If possible wear rubber gloves, face shield, and protective clothing. Have "-purpose canister mask available.
Secure ignition sources. Flush away with water. Do not !lush into confined space (such as a StiW8f) because of
the danger of explOsion.
H a ipiU oceun, call dae Nllttoul R..,...e ee.ter, lfi0.-424-IIIOl.

Re.arb: :t: UnaSSIQnecl
83
nDECYL ALCOHOL
s,._,.__Aleohol C-10; Capric alcohol: 1-0ecanol; U.tte.l N.u- N-ller- ............................. ___J___
N-""'
CHRIS Code .. ................................ ...JlaiL
"aN leomera" ~
-
A~loriess,
Speclfle G~nty-o.e3
C11e.1W F..U7-Aicohol
water white liquid;
PollutiH Catqory-USEPA - - - IMO ___L_

SOlK
-..........
Preeslq Po'ld ...
__mc __mF
c
=::::zc
___ c ---
VlpOI' Pr-..e 20"C (WFI (.-Hi) .......... ~
Reid Vapor Pr..-re (Jida) .......................... ~
v.,.. rre-re 46'C C115'F) (pita) ............ ll.....l.4fL_
Vapor De-.11)' (Ajr "" J.O) ........... __u__
'F
:::::::::ii'F
Applleable hlk Rea. 46 CPR s.~ ....... __...I2._Q_ SoJWiity Ia Water lnM!r He

G~E; Combustible liquid.
Eledrleal Group-O
General-Moderate hazard, when exposed to heat or flame; can react with oxidizing materials.
Flab Point ("F). 180

FJamnqbJe Umlb .. Unavailable
Autoipltioa Temp. ("F) .. 55()
ExtiapilldDI A,e11ts ..... Alcohol foam, carbon dioxide, dry chemical, water spray
Special F1re Pl-oeedurea .. Not pertinent
HEALTH HAZARD DATA

Health Huard Rltillp Odor nn.llold (Jipln) PEJ./TWA (,_, 1LV11WA (fpla)
0, 0. 0 Unavailable Unavailable unavailable
General-Practically non-toxic. Handle as a detergent Main hazard is liquid contact with eyes.
Symptonu-Skin and eye contact--eonsiderable pain and irritation to eyes; akin irritation.
Short Expo~un Tole....ee-Unavailable
Ex1100re Procedura-Eye contact-flood genUy Wflh clean water for at lent 15 mlnlllel. Skin contacl~
contaminated clothing and wash affected areas with plenty of water.
REACfiVITY DATA
Stability-Stable.
Com.,.UbUity-Malerial: Mild steel is suitable for tanks, pipes, valves.
Carp. Group 20 of compatibility chart. See also Appendix 1-Exceptions to the Chart.

Wear rubber gloves, lace shield, protacllva clothing.
If a lpiU occun, all tile N~ ~ c...a., IIIIJ-4lt 11102,
84
DIACETONE ALCOHOL
s,_,_ Diacetone; 4-H~-methyl-2-pentona; Uited NatiHI N. .ber...
4-Hyclroxy-4-methyl pentanone-2;
2Methyl-2-petllno4-4-one
CHRIS Code .
--
P-a.-cH,COCH.C{CH,)sOH
~to
Stectnc GrnltJ--0.94
.. _,
light yellow liquid; faint,
a..kal Fa.lb'-Ketone/Aicohol (.mibits properties
._. . ._ . CFR-.. . .
Nllldoll ~-USEPA - - - IMO ___lL_
___lL_
Boill.. Point..
Freab1a Pol.t...
v.,.,..
~ 2G"C <61"F) (IHIHJ) ...
~c ____HO.'F
___ c
.. ...... ~c
Reid V.,or Pre.ure (plla).....................

Vqm Pn.ure 46'C (115'F) (plla)...
Vapor Deulty (Air = 1.0)...
SohlbHltJ' 1a. wmr.. .
'F
-5B'F
___ c ___ 'F
. ............~
__1.2_
.....2.Ql__
___2.1_
Comptate
--
Gnlle-E: Combultibltl liquid
GMeni-Moderate hazard, when exposed to heat or flame.
Plaia Poial ('F) .. 126 {cc)
--
~IJaita ....... 1.8 to 6.9%
~T-p.('F) .. 1118
...... co,, dry chemical, water fog, alcohol foam
Stecilll Pin rr-m. .. Fire parties Should be provided with respiratory protection.
.................
1, 2, 0
DrelboW ,,..,
(Nor
25
HEALTH HAZARD DATA
PEL/TWA (ppm)
50
TLV/TWA(Pflll)
50
~Irritating to ayn and mucous membfanel. Narcotic in high concentratiOn. Experimentally has caused
anemia and damage to kldnaya and liver.
S,apln Burning of eyes and nasal pasaagea; dizziness, drowSiness.
Sllort ExpoRre Tot-150 ppm for 30 minutes.
E:qloAn: Pli
' Vapor--remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or
eye contact-remove contaminated clothing and gently flush affected areas wtth water for 15 minutes. Get
medlcl!l advice or attention.
REACfiVITY DATA
StUWty-Relati'lely stable. can react with oxidizing materials.
eo.,.tlblllt)'-MMertll: DiNoiYel or softena many platies.
CUp: Group 20 of compatibility chart. See also Appendix 1-Exceptloos to the Chart.

w.. nA:Iber gloves. face shlald, protective clothing. Have sll-purpoae canister mask avaUable.
11.- .,W .,..... CIIJ tbe Nadoul a..... c.ter, 100-424-1102.
85
DIBUTYLAMINE
sr-y-1-Butanamine, N-butyl-; Uafted Natioal NDIIber...
N-Butyl-1-butanamine; di-n-butylamine;
n-Dibutylamine; di-(n-butyl)amine
CHRIS Code ..
BoHina Pobl1.. ______mc __..il.A'F

Ap~lorless liquid; ammoniacal odor. c 'F
FreaUtt: Pofat.. --::5i'c
___ ---=ii'F
c ___ F
Vapor Pre..re lO'C (ti'F) <-Hal-- ~
Cbemkal Family-Alkyl amines Read Vapor ~ (JU). ___a.L
Vlpor rr..are 46'C CllS'Fl (,.u) __gj_
Pcilullon Calqory-USEPA - - - tMO ~ Vapor De.tty Wr = 1,0)... ................ ~
Appllalble Bulk Rq. 46 CFR Subdalpter ....... ___Q__ Solubility In Water...... A!XIJ!Giehla

EJectrical Group-C
Geom-al- Toxic oxides of nitrogen may form in fires. Flammable, moderate fire risk.
f11qb Point ('F) 125

Flammable Limit.. LEL=1.1% UEL-unavailable
Autoipitlon Temp. ("F) .. Unavailable
EJ:tlnguWiing Aaentf .. Confined space-CO.. dry chemical
Special Ftl't' Proced11rn .. Use water to cool fire exposed containers. Water may be Ineffective on fire,
Wear goggles and sell-contained breathing apparatus.
HEALTH HAZARD DATA

Heal.tk Huard RatiDp Odor 1'hrelllo1d (ppm) PEL/I'W A (..,.a) TLV1TWA ep,.)
4, 3, 3 Unavailable Unavailable UnavaNable
Genenll-ll'l'itation of eyes and respiratory tracts, severe to eyes and moderate to skin after contact of lhort
period of ekposure.
Symptoms-Wat9fing, redness, or burning of eyes, irritation of skin, irritation of mucous membranes.
Short Expoeure ToleTliiiCe--Unavailable
El<posure Procedura-ln case of contact with eyes and skin, immediately flush with plenty of water for at least
15 minutes. FOJ eyes get medical attention. Remove contaminated clothing and shoes at once. Call a
doctor.
REACilVITY DATA
Stllbllity-5table.
Compatibillty-Mterlal~ carbon steel, cast iron, aluminum, stainless steel, phenolic-lined eleei, nickel or tinned
Iron are suitable materials of construction. Do not usa copper or copper alloys.
Carp: Group 7 of compatibility chart.

Wear bulyl rubber gloves, face-shield, all-purpose canister respirator, protective clothing. Secure Ignition
sources. Cover with sodium bisulfate and clean up. Flush spill with large quantttiea of water.
If 1 lplU occan, call tbe Natloaal Re.poue c.ter, ~
Remarb:
86
Dlsec-BUTYLAMINE
Syrumy-- No common synonyms. Ulled Nations N11111ber ...
CHRIS Code ....
BotuaPmat.. ~c ~F
Appeanutee-Odor-Water white liquid: amine odor
___ c ___ F
Freedna: Pol:nt.. ~c ~F
Spedfk: Grulty-0.75 ___ c ___.F
Vapor Pratlare lO'C (68'F) {mmH&) .. ____1Z__
CleDdeal FIIIDIJy-AIXyl amines Reid Vapor Praillll'e (p~ilo)... ___j__
Vapor Preuure 46'C (ll!!i'Fl (ptja)... ~
Pollutloa c.tqory-USEPA - - - IMO __jJ__ Vapor Delllity (AU = 1,0)... ~
Applicable &.lk Rea, 46 CFR Subdlapta' ....... ____Q_ Solubility In Water.. Uoayajlable

Gnlde-C: Aammable liquid.
Eleetrkal Group-C
General-Dangerous tire risk.
Ftub PoUlt ("F) .. 75

Flam-ble Umltl .. Unavailable
Alltoipltlon Te~~~p. ('F) .. Unavailable
Extinpilldq Atem Confined space: CO., dry chemical.
Special Plre Procedure~ .... Cool exposed tanks with water.
HEALTH HAZARD DATA

Health Hazard bti.Dp Odor Tltrabold (ppm) PEL/IWA (ppml TLV JTW A {ppm)
General-Irritation of eyes and respiratory tracts, severe to eyes moderate to skil after contact of short period
of time.
Sympt01111-lrritation of eyes, skin, and mucous membranes.
Short Exposure TolenuM:e-Unavailable
E~ Proeeda~lush eyes and skin with water for 15 minutes. Remove contaminated clothing and flush
underlying area with water. Gall a doctor as soon as possible.
REACTIVITY DATA
Stabutty-Stable.
Compatfbllity-Materilll: Garbon steel, aluminum, stainless steel, nickel, tinned iron, and phenolic-lined steel
are suitable materials of construction. Do not use copper or copper alloys, zinc, or galvanized steel.

Wear butyl rubber gloves, face-shield or all-purpose canister respirator, protective clothing. Secure ignition
sources. Cover with sodium bisulfate and Clean up. Flush spill with large quantities of water.
If a lpUI oceun, call tbe National Re1p0111e CeDter, 800-424-8801.

Re..rb: II No Determmalton
t Unavailable
~ Unassigned
87
a-DICHLOROBENZENE
s,.,.,.__ Benzene': 1,2-dlchloro-; ..... ....1liL
1,2Dichlorobenzene; o-OichlorobenZol;
Dow\henn E; Orthodichlorobenzene
CHRIS Colle ... ..... ...lllKL
-
F1Jnl11la-C.H.Cl.
BoUlq Pobll.... ... ____lll'C ---..HZ'F
c
~ealiquid;
Spedtk Graftl:y-1.30
plelil8llt aromatic
FA~atJ~t Pot.t... --=tac
___ c
----=-
---
'F
'F
a...ac.J '-By-Halogenated compound

v.,_ Pr-.-e lO"C (WF') {..til)... .... .........1..._
Rdd VllfOI' Pr-.e (JII.)........... .... __..2JlL_
VlpOJ' ~ 46"C (115'F) (pda) ........... .....SlJ.._
Poll.UO. C.utorJ-USEPA _ . L . IMO ___J__
ANiiaWe BaUr: R. . 46 CFil Sabdlapter ........ ____Q_
v.,.. Dalill)' Wr - 1.0)......... .
SoiWIItJ ba w..... .........................
.....uz.....
Nwd!!f!lt

B*trical Gro.p--0
General-Dangerous. When heated to decompolitlon, emltl highly toxic chloride fumft.
PbA Pelllt ('F) .. 151

Jl1aaullk lJJaltl ..... 2to 9%
A11kltpltloa Ttlllp. ('F) .. 1198
EJ:tblpi*fal A ...m... Water spray. dry Chemieel, CO.. foam.
Special Fire Proeechlre. .. Wear full protective clothing and IMtlf-contalned breathing apparatul.
HEALTH HAZARD DATA

Healtll Huard Rat!... Odor nredtttid <pp.l) PEVIWA <pp.l tt.VITWA<Jt-l
2, 1,1
50
GelleraJ-Vapor inhlllation causes moderate local IrritatiOn ol nose and airway.
50/Sidn
Sypto--Drowsiness, unsteadiness, eye initatioo, difficulty in breathing.
Aort EJ:po~ure Tol~Painful to some at 60-100 ppm lot more than a lew minutes.
E:.:~ Prve:M.,_Vapor-remove victim to fresh U; If breathing stops, apply arttficial respiration. Skin or
eye contact-remove contaminated clothing and gently flush affected areas with water for 15 minU1et.. Get
mediCal advice or attention.
REACfiVlTY DATA
StUJUI)-Stable.
c-p.dWJUy-Matertal: Moat nbbert ara not compatible.
Carto; Group 36 Of compatibility chart.

If poseitH, WMl' butyl n.bber glovet, Mlf-contalned tltMthlng ~Ius, protective ClOthing. If poetii:IMI,
.tllorb or miX wlttt vermiculite, IOdlum blclrbonate or land. Thlt may be packaged In cardboard carton1 and
burned In an open pil WUh site thoroughly with ttrong soap tolutlon.
U .,W OCCIIfto cd ... Nlltioala..,.. c.t:.r, .......Ut -.J
88
DICHLORODIFLUOROMETHANE
sy-)'Jfti-Oifloorodichloromathane; F 12; Freon 12; United Natlou Number ...
Halon 122: Methane, dichlorodifluoro-; Propellant
12; Relrigerant12; Ucon 12
CHRIS Code ...
Formuii-CCI,F,
~c~F
Appearanee-OCior-Colorless. odorless gas or liquid. c 'F
Freezina Point .. -l58'C -252'F
Speeiftc Gravlty-1.35 at 15'C (a liquid) ___ c ---
Vapor Prea.re :W'C (68'f) (IIUIIH.a) ..
Chemical Family-Halogenated hydrocarbon Reid Vapor Prellllre (!IIIIa) ... ---.l1L_
Vapor Pre.ure 46'C (llS'F) (.-Ja) .. _w_
Pollution C.te&Ory-USEPA ____Q___ IMO ____g,n_ Vapor Density (AJr = 1.0) ..... ....!..1L..
AppiiCible Bulk Rea. 46 CFR Subdupter. ___Q__ Solubility In W1ter .. !nsglyb!e

Grade-Non-flammable
Elettriul Group-Unassigneo
Central-Does not burn. To)(ic fumes emrtted when heated to decomposition.
Fluh Point ('F) None

Flammable Umlts .. None
Autoipition Temp. ("Fl None
E~ttinpishing Agents None
Special Fire Procedure~~ When heated to decomposition temperature, it emits highly toxic fumes of
phosgene and fluorides. Fire fighters must wear selfcontained breathing apparatus and full protective
clothing. Cool tanks exposed to fire with continuous water spray.
HEALTH HAZARD DATA

Heal1b Hazard Ra11ngs Odor Tbrnbold (ppm) PEL/TWA (ppm) TLV!J'WA (ppm)
0, 0. 1 Unavailable 1000 1000
~nerai-LIGUid may cause skin or eye injury similar to frostbite. Vapor not toxic but breathing It may cause
unconsciousness without warning because of lack of oxygen.
Symp1oms-Drows1ness with or without nausea.
Short Expoaure Tolerance-Human e)(posure to 100,000 ppm for a few minutes produces unconsciousness.
E~:poaure Proc:edures-Remove victim to fresh air; if he stops breathing, apply artificial respiration.
If the liquid
has spilled onto the skin, points of contact may be frostbitten: handle gently and protect from mechanical
REACTIVITY DATA
S1abillty-Stable.
Compatiblllty-Ma1erW: Noncorrosive.

If 1 1plll occun, tall 1M National RelpoDR Cen1er,IJ00-4:u-810l.
Remarb: Vapor Pressure: 3800 mmHg at 16.5'.
89
1, 1DICHLOROETHANE
s,.....,_ Asymmetrical Oichloroathane; Chlorinated Ulllted Natlou Nuber...
hydrochloric ether, Ethane, 1 ,1-dic:htoro-:
Ethylidene Chloride: Ethylldene
dichloride; 1, t Ethylldene dichlOride
CHRIS Code .....
--
~-ColOrless oily
SJ*Ifk Grn:lty-1.18
CMatal F..U,-Halogenated compound
PoU.UO. Calepy-USEPA ~ IMO

liquid; chloroform-like
___a_
BoJIIIII Polllt .....
Freez1111 Point ...

~c~F
V11p0r Prelllll'e lO'C (68'F) (mmfla)..

Retd Vapor Pretnre (piia)...
Vapor ~re 46'C (ll!I'F) (p.k)...
c 'F
_gzc ---:-;:ijF
c ___.,
---.1U.,.._
~
-i.L
V1por De!Wty (AJr = 1.0).... . ................. __ML_
Applicdrle hlk Rea. 46 CFR Subcbpter ....... _.a_ Solubllity Ja Wter .. Nagf!pible
---
Flab PoiDt ("F) ....

Jllaa.aWeUmta ..
ee-.t-Whel'l heated, toxic and highly flammable vapors are given off.
17
6 to 16%
AlltolpltkHl Temp. ('F) .... 856
Extlapflillq Apatl ... Dry Chemical, foam, COt
S,edal Fire Proeedurel .... Water may be ineffective on lire. Keep exposed tanks cool with water sptay.
Provide fire fighters with protective clothing and self-contained breathing apparatus.
HEALTH HAZARD DATA

H..ath Huard RM:blp ()dOT nr.hold (ppa~) PEL/fWA (ppm) TLV!I'WA (ppl
1, 1, 2 Unavailable 1()0 200
Geun.I-Vapor irritating. liqukl slightly irritating.
S~Vapor causes eye irritation, dizziness, intoxication. liquid causes slight irritation.
Short bpo~~~n Toleruce-4000 ppm in 30 minutes.
~ Proeedune-Remove victim to fresh air, If breathing stops, apply artificial respiration. Skin or eye
contact-flush areas immediately with water tor 15 minutes.
liEACI'IVITY DATA
StUtlftJ-Generally stable, but decomposes when heated forming toxic and flammable vapors. Incompatible
with strong oxidizers and caustics.
eo.,.tfWHty-Material: Usual materials ol construction are suitable.

Wear protective clothing, lace shield, goggles, respiratory protection. Secure ignition sources. Water spray
may be used to flush spills away.
If a spllJ oecun. call tile NaUoul lletpoue Cuter, 800-4l4-880l.

Re.arb: This compound rs a teratogen: 1,2-Dichloroethane 1s a suspected cai"Cinogen.
90
2,2'-DICHLOROETHYL ETHER
Sy-)'llll- Chlorex: Chloroathyl ether: UaUedN.._N__.
bis(2-Chloroethyl) ether, bis-beta-Chloroethy1 ether;
OCEE; 2,2'-Dichlorodlethyl ether; Oichloroether;
Dichloroethyl ether; beta, beta'-Dichloroethyl ether,
sym-Dichtoroethyl ether; Dichloroethyl oxide: CHRIS Cede ..
Ethane, 1, 1'-oxybis[2-chloro-; 1,1 '-oxybls[2-chloro-;
1,1'.Qxybis[2-chloroethane)
FonauJa-CICHzCHzOCH.CH.CI BoUilll Poiat .. ~c _____JU'F
Appearance-Odor-Colorless liquid; chloroform-like odor c 'F
Freed& PoW .. -SQ"C
-S'F
Speelfte Gra'rity-1.22
___ c ___ F
Vapor Preuwe we C61'F> ~HI) .......... ___1.2___
Chelldcal Family-Ether Rdd Vapor Pr-.re (plla) ........................... __;t_
Vapor Pre.1are 46'C (115'F) (pil:l) ............. _Q.2!_
Pollutioll Cateaory-USEPA ___A__ IMO _____e___ Vapor ne.lty <Ab' = 1,0) ........... ___A.L_
App]kab~ Bulk Rea. 46 CFR Subclupter .. . ... ____Q__ Solbillty ill Water.. NMMp!blt

Grltde-0: Combustible liquid
Electrital Group-C
General-When heated to decomposition, it emits highly toxic fumes; it reacts with water Of slel.m to evolve
toxic or corrosive fumes.
Flub Poiat ("Fl.

Flammable Limits ..
Autoip.itioa Temp. ('F) .
Elltinplthin& Aaeuta ..
Special Fire Procedurea ..
..
131 (cc)
Unavailable
Foam, co.,dry chemical

Wear full PfOtective clothing and respiratory protection.
HEALTH HAZARD DATA

Health HllUJ"t Ratiags Odor nre.hold (ppm) PEUTWA~ TI.V/TWA C.,.)
3, 2, 3 Unavailable 5/Skln 5/Skln
General-Vapor is irritant to mucotsS membranes of eyes and nose. It affects kidneys and liver in varying
degrees, and is a mild narcotic.
Symptollll!I-Nausea, irritation of eyes and nose.
Sbort Ellpo~~ure Toleruce-500-1000 ppm causes severe irritation of tne ayes and nose after brief expoaure.
1 00 ppm produces slight nausea and irritation.
Expoaure Procedures-Remove victim to fresh air. Skin or eye contact-remove contaminated clothing and
gently flusn affected areas with water for 15 minutes. Get medical advice or attention.
REACI1VITY DATA
Stablllty-Stable until nested to decomposition. Will react with water or steam, and can react vigorously with
oxidizing materials.
CompatfbUity-Msterial: Unavailable.
Carao: Group 41 ot compatibility cnart.

Weat rubber gloves, large heavy face shield, self-contained breathing apparatus. Secure ignition sources.
Flusn with large quantities of water.
If 1 1piU OCC11111, ea1J tbe Nsdollll RelpoMe Ceater, I00-4l4--1102.

Relllll'lul: t Unav81lable
91
2,2'DICHLOROISOPROPYL ETHER
Syaoaymt- bis(2-Chloroi80J!f0PYI}8ther;
Dlchloroisopropyl ether. Ether,
bis(2-chloro1-methylethyl): Propane,
2,2'-oxybis[2-chloro
CHRIS Code .....
Formula-(CICH,C(CH,)H).O
BoWa1 PoJat ..... ---...lJZ'C ___auF
c 'F
FreeDaa: Point .. --:-ijc --=iF
S,edftc Graflty-1. 1 1 c ___ 'F
Vapor p,_re zoc <68'FJ <-HI)..... __jlJQ_
ClleJnk:a.l FamJiy-Ethers Reid Vapor Preaure (plla)... ____!...._
Vapor Preuure 46i'C (115'FJ (JIIfa) ........... ~
Polludcm Category-USEPA ____.L. IMO ___k__ Vapor Den.il)' (AJr = 1,0)... J.!!2_
Applbble BuJk Rea, 46 CFR Subdlapter ....... ___2__ Solubfllty Ia Water.. Slight

Electrieal Group-NA
Generai-Uberates hydrogen chloride vapors when combustion occurs.
FJu.b Polat ('F) .. 185

lllammatrle Umlb .. Unavailable
AutoipltJOD Temp. ('F) .. Unavailable
ErtlaiPibltln& APDII .... Water, loam, COa, cky chemical
Speelal Fire Proceclura: .. Water to blanket lire. Wear self-contained breathing apparatus.
HEALTH HAZARD DATA

Healtb Hazard RatiDp Odor Thrubold (ppm) PEL/IWA (ppm) 1LV!IWA (.,..)
Unavailable 0.32 mg/1 Unavailable Unavailable
General-Skin and eye irr"ilation by dll'ect contact.
Sympto~B~-Strong respiratory tract irritation and damage to liver and kidneys.
Short E.JIOIIID'e Tolerance-The lower lethal concentratioo for rats in 5 hours was 700 ppm.
E.posure Ptoc:c4wes-Remove immediately to fresh air. Administer artificial respiration or oxygen as necessary.
For ingestion, provide immediate hospitalization.
REACI'IVITY DATA
StabiUty-Stable. Reacts with oxidizing materials.
Co.INitibllity-M.terial: Incompatible with aluminum, copper, epoxy coatings.
Carao: Group 36 Of compatibility chart.

Wear seH-containing breathing apparattls, full protective clothing and rubbef gloves.
If a 1pill oec:un, eaU tbe National Relpoqe Ceater, 11011-414 8101,

Rt~~~~arlu:: t UnaVailable
92
DICHLOROMETHANE
s , _ , _ Methylene bichloride; Methylene chloride; Ullited Natto. N . .ber...
Methylene dichloride
CHRIS Code ..
Bolli~~~ PfNat.. ~c ~F
~orleu liquid with a c "F
chloroform-like Odor Freed.. Polat... -l!l"C -143'F
S)edtk Grftlty-1.34
___ c ___ F
VllfOI' Preaure lO"C (61'F> <-HI).. .....J;!L_
a-deal Family-Halogenated hydrocarbons ReWI VllfOJ' Preaun (JN)... ~
Vapor Preaure 46'C (115'F) (pefa)... .....l.U_
PolllrdOII C.tepy-USEPA - - - IMO _Q._ Vapor DeMit)' CAll' = 1.0).... _.a.g_
A..,lk:Uie Balk Ret- 46 CFR Sabdtl.pter ....... __Q__ Solulrillty a. Wr ..................... t il"'!r

Gnde-Non-flammable
Deetrieal Groap-0
Geaerai-No flash point by conventional methods, but loons flammable vapor-air mixtures at 212'F and higher.
EvOlves phosgene, a poiSOnous gas, and hydrogen chloride gas when heated.
FtaA PMnt ('Fl .. None

FlanuubJe u.ua .. 12 to 19%
Aatolpldoa T-p. ("F) .. 1033
El:diiiiiiiiiiJII Apllts .... Water, foam. dry chemical CO.
Special F1re Procedare~ .. Wear self-contained breathing apparatus. Cool exposed tanks with water.
HEALTH HAZARD DATA

Healtb Huard lbtilip Odor Threlltold (ppm) PEL/I'WA lllflll) TI.V/1WA 1..-J
2, 1, 2 214 Unavailable 50
Ge.eral-Su&pected carcinogen. Vapol' causes anesthetic effects at high concentrations. Liquid cau1e1 akin and
aye irritlltion. Prolonged Of repeated skin contact may cause defatting of the skin and may produce
dermatitiS from daily contact.
s,......-Ughtheadedness, mental confusion, nausea, vomiting and headache.
Sltort Espolllft Tolerance-Not well established, possibly in the range ol10,000 to 20,000 ppm by volume In U.
However, incoordination, dizziness and slight nausea begin after a haH-hour axpoSIXe to approximately 1000
ppm.
Ellpoture ~Iva artifiCial respiration if breathing has stopped. If the eyes are involved, flush and then
irrigate with large amounts of water lor at least 15 minutes. II Ingestion has occurred, obtain medical
attention.
REAC11VITY DATA
SC.INIIty-Stable: but contact with open flame causes decomposition.
eo.,.tJ.bfUty-Malerlal! Corrosive to aluminum and magnesium; corrosive to steel when wet.

- If a ...W--, ealllbe Nadoul R..,aaaa ee.ter,II00--4l4-lltll.
93
2 4DICHLOROPHENOL
Synoayms-Chlofophenols, liquid; Dlchlorophenol; United Nations Number ...
Phenol, 2,4-dichloro-
CHRIS Code ..
BoiiiDII Point .. ______2!!i'C ~F
Appeua.ee.Odor-White to tan solid needles: colorless c 'F

liquid; strong medicinal odor Freez.lns Point .. ......__._42'C ~F
Speclnc: Gra9ity-1.4 at140'F (liquid) ___ c _ _ _ 'F
1.4 at 59'F (solid) Vapor Preuure lO'C (68'F) (mmHJ) ... _.Q.1L
OltlnicaJ Family-Phenols Reid Vapor Pre.ure (!Millo) .. _i_
Vapor Preaure 46'C (ll!I'F') (pelro) .. _i_
Pollutfoa Crotqory-USEPA ___a_ IMO ___A__ Vapor Delllky (Air = 1,0) ... ___u_
ApplleUJe B111k Rq. 46 CFR Subebapter ...... ___Q__ Sol11blllty In Water .. 45 Q/1
FIRE II: EXPLOSION HAZARD DATA

Grtlde-E: Combustible liquid
Electrkal Gro.p-0
G9enl-Siight fire hazard when exposed to heat 01' flame. May decompose in a fire, releasing toxic products
including hydrogen chloride.
Flub Poblt ('F) . 237

Flanunable Umlts .. Unavailable
Auloipjtlon Temp. ('F) .. Unavailable
~tiiiJIIIUIDI Aaenh. Water log, alcohol foam, carbOn dioxide, dry chemical.
Special Fire ProcedW111 .. Water and foam may cause frothing.
HEALTH HAZARD DATA

Healtll Huard Ratlnp Odor l'hrabold (Jipm) PELJTWA (Jipm) TL V/TWA (ppm)
Unavailable 0.02 Unavailable Unavailable
General-Will irritate skin and bum eyes on short exposure. Possibility of thermal burns from hot liquid.
Symptoms-Irritation, burning, nausea, vomiting, diarrhea, hyperactivity, and/or convulsions.
Short Ex.,.,....-e Toleranee-lnhalation: Oust and vapor toxic; 15 ppm very irritating.
ExpoHre Proced11res-Get medical attention. Inhalation: Remove to fresh air, rest, mouth to mouth resuscitation
or OKYQ&n if needed. Ingestion: Do not Induce vomiting. Give large amounts of milk or water. Skin: Wash
with water for 15 to 30 minutes. Eyes: Flush with water for at least 30 minutes.
REACI'IVITY DATA
StllbUity-Stable below 200'C. Reacts with acids and caustic and alkali solutions.
CoeapatiiNilty-MHerlal: Rapidly corrOdes aluminum, slowly corrodes zinc, tin, brass, bronze, copper. u..
stainless 01' mild steel with nitrogen pad (to keep dry). Linings are generally unsuitable.
C&rao: Group 21 of the compatibility chart.

AvOid contact, wear goggles, body covering clothing including rubber or neoprene gloves, gaunUets, and
boots. Use self-contained breathing apparatus. For solid spills prevent entry into sewers or natural waterways;
shovel Into clean dry containers. For liquid spills, dike and let freeze, shovel into dry containers. Do not use
water. Material is a serious pollution hazard.
Rem11rlu: t Unavailable
If spill oceun, call t1te National Re~J~HM Center, 800-4l4-880:Z.
....
94
1,2DICHLOROPROPANE
s,...o.,....._ Dichloropropene; Propane,1,2dichloro-; United Nat1o1111 Naber...
Propylene chloride; Propylene dichloride
CHRIS Code ..
F. .ula-CHaCHCICH1CI
BoW., Poiot ... ___j"C ___.!QO"F
~--Colorless liquid: sweetish, c 'F
chloroform-like odor Freeztna Point.... -BO'C --=-l:i2F
Spedfle Gra't'lt,-1.16 ___ c ---
Vapor Pre.are lO'C (61'Fl lmH&> .. ~
c:::bR!al Faaiii)'-Halogenated hydrocarbons Reid Vapor Pre.ure (Jiia)... ___j,j_
Vapor Pre.ure 46'C (ll!I'F) (p!llll).. ___2.L_
PoUIItlon Catepry-USEPA ~ IMO _____a__ Vapor Deulty (Air = 1.0)... ........... ~
Appllalble Balk Rea. 46 CFR Subchapter ........ __Q__ SoluWIIty in Water.. Slight

Gl'llde--C: Flammable liquid
Electric:al Grou.-D
Gneral-Both the liquid and vapor, on contact with a hot surface 01' a naked flame, decompose to form
phosgene, an elctremely poisonous 988. Highly toxic hydrogen chloride gas is a combustion product.
Fluh Point ("Fl 65

Flammablf Limit.
Autolpition Temp, ,.., 3.4 to 14.5'%
1035
E~:tbapllblng A1ent1. CCh, dry chemical, foam, water fog
Special Fire Procedure. .. Keep exposed tanks cool with water spray. Provide body and respiratory
protection for fire parties.
HEALTH HAZARD DATA

Health HIWU"d Ratinp OdOI" Tbretltold (ppm) PEL/TWA (ppm) TL V;TWA (ppm)
1, 1, 3 unavailable 75 75
Geaend-Skin contact can cause dermatitis. Vapor inhalation causes fatty degeneration of the liver and kidneys.
Symptoms-Headache, w!'akness, nausea, dizziness. Skin contact may cause dermatitis.
Short Expo1ure Toleraace-Short-term peak exposures of workmen to 400 to 500 ppm were tolerated without
apparent ill effects.
Expo~ureProcedura-Vapor-remove victln to fresh air; If breathina stops, apply artificial respiration. Skin or
medical advice or attention. Symptoms may be delayed several days or longer.
REACTIVITY DATA
SW.Uicy-Generally stable. Can react vigorously with oxidizing materials.
Compattbutty-Miterlal: Corrodes akJmlrum.
Cuao: Group 36 of compatibility chart.

Wear rubber gloves and protective clothing. Avoid contact with liquid. Secure ignition sources.
If 1 ..W owan, call tbe Nstloul Rapoue Center, 800-424-880l.
95
1,3-DICHLOROPROPENE
5)-)m---alpha-Ctlloroallyl chloride; Ualted N.u- N . .ber............................... ~
gamma-Ct~Joroal chloride; DlchJoropropene;
1,3-0ichiOropl apJiene: alpha.
gamma-Dichloropropylana: 1-Propena, 1 ,3-dichloro-;
Te- CIIRIS Code ................................................ ~
A;; u
...........
s,edftt GnritJ-1.23-
F-.Ia-CICH. = CHCH.CI
OdD White or yellow liquid; sweet
Cbemlcal Fudb"-5ubatituted allyll

Boflblt: Pcdat .........................
Preeziat: Poiat ......................
VllfCR' ~ 20'C IA"Fl (-"1) ...... ---1QL_

ReW V~pe~r rr-e <.-I
~c --2..1j'F
-80'C
___
c
............... ___j.Q._
V.,ar rr-e 46'C (115'Fl (pU) ............ ~
-78'F
c ___ 'F
'F
Catlpoy-USEP A ____L_ IMO ____L_

PollldiGe; V.,or De.1CJ lAir 1.01... .... ......a.Bi.....
A,ua1 a.Jt ..._ 46 en~ ...... __Q__ SotabllltJ Ill W.ter.. 01%

Gnd.--0: Combustible liquid
-~
~-Combustion produces toxic vapors Of hydrogen chlOride, phosgene, and carbOn monoxide. Fire may
cauu violent rupture of tank .
--
.._.. Pot.t <'Fl ...
........ Ualltl ... "5.3 to 14.5%
AalolpltiH T..,, ('F) .. Uf'IIV8llable
.......... -...
....... .......... CO., dry chemical, foam, water fog
Fire parti88 must wear full respiratory protection and, where danger of Skin
contact exists, full body protection aa well.
HEALTH HAZARD DATA

He.Idl Haunl Radap Odor nreMold (llflll) PEL/IWA(ptllll) TLV/TWA(ptllll)
2, 2, 3 1to3 1/Skin 1/Skin
Goeral-Suspected carcinogen. Liquid Is severely Irritating to eyes. Vapor is a severe irritant.
.,...
S~listers and bums when In contact with Min. Breathing the vapors causes initatlon to nose and
SIMirt Expolure Toleruce-UMV8llable. Howevar, it Should be noted that the commercial product is a mixture of
laorners. The physical propertlu win vary somewhat depending upon the proportion ol each lsomar present.
The mixture should be handled in the aama manner as a Class 8 poison.
I:KJOIIII'I Pnleeduw-Vapor--remove victim to fresh air; II breathing stops, apply artilicial respiration. Skin or
eye contact-remove contaminated clothing and gently flush affected areas with watef tor 15 minutea. Get
REACI'IVITY DATA
StUWty-Stable.
Colllllldbftlt:J-Mu.lal: Will cause COIT08ion of stNI if wet or at elevated temperat!Xel; also attacks aluminum
ond..-.

Wear rubber gloves, self-contained breathing apparatus, protective clothing. Avoid contact with liquid. Secure
Ignition sourcn.
If a ..W ocan,. call tile Nlldoal a - CeateJ', IIII0-4l4 111101.
96
DICYLOPENTADIENE
~Cyclopantadlena; 1 ,3-Cyclopentadiene; United Na"-t Nmber ...
1,3-Cyclopentadlene dimer; Oicy: 3a, 4, 7, 7a-;
Dicyclo-1,4-pentadiene;
Tetrehydro-4, 7methanoindene
CHRIS Code ..
lkllliD& Polllt ... ____j_'C ____ru'F

4ppearuoe-Odor-Corless crystals or molten liquid; c 'F
camphor-like odor Freezia1 Potnt.. _____j,j'C ___ij'F
Spedftc Gnrity-0.98
___ c _ _ _ 'F
Vapor Prellure mc (68'F> CmH&) .. _l.L_

a..kal Family-Olefin Rekl Vapor Preaure (psia)... _2.JL
Vapor Preuure oM'C Cll5'F) (pail) .... _JW_
PGitutlo. Catepry-USEPA - - - IMO _____a__ Vapor Dea.lty <Air = 1.0) .. ~
Applkdlle Btlllr. Rea. 46 CFR Subchapter . .... ----'l...Q._ Solublllly Ia Water .. IOIO!yb!t
FIRE 1r EXPLOSION HAZARD DATA

G...._O: Combusbble
Eltettriad Group--C
Geaerai-Keep away from heat, sparks and lire.
F'Jub Point ('F) so to 100

Flanunable Limlb 0.6 to 6.3%
Aatolpldon Temp. ('Fl above 500
EdiiiJiilblna: A~ntll Foam, carbon dioxide, dfy chemical, water spray
Special F1re PTOdurea .. Water may be ineffective. Keep expoaed tanks cool with water Sp!'ay.
HEALTH HAZARD DATA

Healtb Huard Ratlnp Odor Threshold {pJIIII) PEL/IW A (ppm) nv!TWA (ppm)
1, 1, 2 leas than 0.003 5 5
Goeni.-Liquid causes skin and eye irritation. Avoid prolonged or repeated breathing of vapor. Possibility of
thermal burns from hot liquid.
SymptOJDJ-Inhalation-dizziness, drowsiness. Skin contact-dermatitis following prolonged contact.
Sllort E:~.po~ure Tolei"Pic:e-1 ppm caused slight eye and throat irritation after 7 minutes. Eye irritation resulted
after 10 minutes at 5.5 ppm.
E:I.POIIlre Proeedura-Vapor-remove victim to fresh air; if breathing stops., apply artifiCial respiration. Skin or
REACI'IVITY DATA
StabWty-Stable.
Compatiblllty-Miterlal: Usual materials of construction are suitable.
C11r10: Group 30 compatibility chart.

Wear rubber gloves, face shield, protective clothing. Have all-purpose canister mask availabe. Secure ignition
"'"""''
If alfJIIoecun, ealJ the National RMpOMe Ceutef, 800-4l4-8802.
97
DIESEL OIL
.,.,,._..;::~Oine4;;:;
__ ....
2-D; Petroleum oil
;;;;;~;F;.UOI;;.oi;;"'~-~1~-D~;~F:...;;~;,~.,.~-==~U~-==~N~~-::~N:,:.~...:.~. =====-=-...lZZL
CHRIS Code .. .... ....QllL
F-m-Not cherniclilly clatingulahable.
............... .. . . . . ~c-F
A~.
,.._ ellghtly viKoua liquid: smells
Freulq Pot..... ...........
c 'F
-2P'C --:gQF
___ c ___ 'F
SfeeUk Gn~.a to o.9
V.,or ~ 20'C (61'11) (-'II)
Cltnlkal ~I.e. hydrocartJon mixtures Reid Vapor Pr-.re (...)... .. ... :::: ~
v.,.... Pr-.n ~c <115'Fl <piU)... ... ..YDL
PelhdiGa ~-USEPA - - - IMO __l_ Vapor ne.Hy Wr = 1,0)... .. .. ~
_ .......... CFR . . . . . _ ........ __.IL_ Solbftltr In Water........ SJjgbt

GnN-0 or E depending on ftash point
-Gnoo--0
c-.t-Oiesel fwl, due to Its elevated flash point, wNI generally not constitute a lire hazard. Keep away !rom
hAt or flame.
-- ............................ 110 to 190

PlulaPcd.I('F)
-"""' .......................
A~ Talp, I'Fl
1.3 to6.0%
494
..... ............ CO.. dry Chemical, foam, water tog
s,.dal Fire Proc:edarel . ....... .. Water or foam may cause frothing. Do not direct water directly into fire.
.......... .._
u_,_
.....
Unavailable
--- HEALTH HAZARD DATA
PEL/IWA IIIPJil)
Unavailable
TLV!rWA <pp.l)
Unavailable
c-.I-Inhaldon Of high concentrations ot vapor can cause headache and stupor. Liquid Ia irritating to the
........... .._.
~Ingestion cauees Irritation Of stomach and intestines with nausea and vomiting. Inhalation:
Sllort Eapoure T--Unavallable
Ea.....,. PI .. Vapor-remove viCtim to frelh air; if breathing stops, apply artificial respiration. Skin or
eye contact-remove contaminated clOthing and gently flush affected areas with water for 15 minutes. Get
mec1ca1 acMce or attention.
REAcriVITY DATA
sa.blllty-8table.
C.C.,.tfllllUy-Malerial: Usual m.tarlals Of construction are suitable.
cutr. Groi.JP 33 Of compatblllty Chart.

Wear rubber gloves, protective clothing. Have reapiratory protection avaHabia. Secure Ignition sources. Soak
up with rags, paper, or dry vermiculite.
H .,W DCa11'1, call tile N.s-1 llelpoMe c.ter, IJ00-4lt IIOl.

R - a : Vapor Prauura: 2.8 mmHg m 50c.
98
DIETHANOLAMINE
S)'IIOII)'DQI- Dlethylolamine; 2,2' -Dihydroxydlethylamlne; Unhed Nati- N11ber....
Oi-(2-hydroxyethyf)amine; bis(Hydroxyethyl)amlne;
bi$(2-Hydroxyethyl)amine; 2,2'-lmioobisethanol;
2,2'-lminodlethanol
CHRIS Codll! ..
Bom111 Polat.. __ac ____ll!'F

Appearaau-Odor-Thick, colorless liquid; ammonia-like c 'F
ado< FreezU.a; Point... ____2J'C ____12'F
Speelfk Grnlty-1.09 ___ c ---
Vapor ~ :zoc <61'F) c-HI).. __sjU_
Cbemic:al Family-Amine Reid Vapor Pre..re (pila).... ___2.&L_
Vapor Preave 46'C (115'F) (pda).. L.LQL
PoU11tioa Catepry-USEPA - - - IMO ____jJj__ Vapor Dea1Uy (AJr = 1.0)... .................. ~
Applia1ble 811Ut Rea. 46 CFR Subdlaplfl . . ____Q__ SolaWUty ln Water.. Cqmp!tta

Electrical Group-O
General-Slight fire hazard when exposed to heat or flame. Irritating vapors are generated when heated.
Flub Point ('F)

Flammable Umih
Autolpitioa Temp. ('F). 1224
""
1.6% (calculated) to 9.8% (estimated)
EitiDpltbinl Apab .. CO,, dry chemical, watet fog, alcohol foam

Special Fire Protedura .. Water or loam may cause frothing. Provide fire fighters with self-contained
breathing apparatus and protective clothing.
HEALTH HAZARD DATA

Health Huard R1tlnp Odor lbrahold (ppm) PEL/IW A (pfm) 11.V /IWA (Pflll)
Gellenl-Liquid is irritating to skin and highly corrosive to eyes. Avoid inhalation of high vapor concentrations.
Symptoms-Itching or burning at points of contact
Sbort Es.po~ure Toleraace-Unavailable
~re Proeedura-Skin or aye contact-remove contaminated clothing and gently flush affected areas with
water for 15 minutes. Get medical advice or attention.
REACllVITY DATA
St..Milty-Relatively stable.
Com,.tiiNIIty-Mtlterial: Avoid copper and its alloys.
Clrgo: Group 8 of compatibility chart.

Wear butyl rubber gloves, lace-shield or all.ptXpeaa canister respirator, protective clOthing. May cover with
sodium bisulfate, spray wtth large 8)(C988 ol water and wash up.
H1 IJilU om~n, call tile N1tioul R.,.... Center, 800-424 IIO:Z,

Re......U: S1nce the pure material 11 solid at ambient temperatures, diethanolamlne may be earned in aqueous
solution or at elevated temperature to keep It liquid.
+ Unassigned
99
DIETHYLAMINE
s,....,._ DEN; N-Ethylathanamlne UnJied Nftlou N11111ber ...
CHRIS Code
aow.1 Pot.t .. ______sc _mF

A~ofless liquid; ammonia-like odor c 'F
Freez1Da Poblt... -50'C -M'F
Spedtk Grarity--0.71 ___ c ---
VllfOJ' PreM.re lO'C (61'F) ~HI).. -...2il..L_
ate.akal r..Uy-Amine Reid Vapor PreaMre (Pifa)... . _.Q.L_
VllfOI' Pr...-e 46'C (115'F) (pita) ---l...Q.......
Polllltioll c.teaorJ-USEP A ____a__ IMO ____c___ VllPOI' Den1ftJ (Air = 1,0)......................... --2..5...._
Applicable Bulk Jle8. 46 CFR S1lbcUpter ....... _.Q__ Sol11bftltJ Ill Water........ Ciqnpftll
FIRE 1r EXPLOSION HAZARD DATA

.......... """'>-"
Ge.eral-Extremely flammable. Dangerous when exposed to heat or flame. Vapors are heavier than air and
may travel considerable distance to an IgnitiOn 80Uf08 and flash~. Irritating vapors are generated when
heated.
Flub. Point ('F) .. -24
,._ble Uadb .. 1.8 to 10.1%
A.tolpldoa Te.p. ('F') . 594
-" ..............
Extlnplalq; Ae-ats ..
Clothing.
......
CO.., dry chemical or alcohol foam
Provide fire fighters with self-contained breathing apparatus and protective
HEALTH HAZARD DATA

Healtll Huard Rati... Odor nrenold (ppm) PEL/I'W A (,m) n.vrrwA (ppm>
3, 2, 2 0.14 10 10
Ge.raa-Uquld very Irritating on contact and is toxic by Uin absorption. Vapor causes severe Irritation of nose
and respiratory passages.
Sympto.ae-Uquid causes f'/8 Injury and skin irritatiOn.
Short Es:ponre Toleruce-100 ppm for 30 minutes.
Esponre Proceduret-ln case of contact with eyes or skin, immediately flush with plenty of water for at least 15
minutes: for eyes get medical attention. Remove contaminated clothing and shoes at once.
REACfiVITY DATA
Stability-Stable.
CompatfbllitJ-MRerlal: Steel and stainlesa steel are compatible. Copper and Its alloys should not be uMd.

Wear butyl rubber glovee, face-shield or all-purpose canister respirator, protective clothing. Secure Ignition
sources. Cover with sodium bisulfate and clean up. Flush spill with large quantities of water.
H a .,W ocean, Cllllbe Natioul. Retpoue Ce-.ter, 1100-424 8101.
100
DIETHYLBENZENE
s,-,__Oiethylbenzene (1,2, 1,3 or 1,4-); U.aa.dN...,_NIIer.................... . .. ....2114...
Oieth)ll)eroumt, m- or o- iM)IMI'S
rc-aaa-c.H.(C.H.h
~liquid;
$pedflc Gnmty-o.87
a.e.kal Fa.IIJ'-Aromlotlc hydrocarbon

benzene..Nke odor _
CHRIS Celie ..
.................
v.,.,.. rr-n lG"C (WFI
.... v..... ,..._,.
v.,... rr-re
....llliiL
____l.IZ"C ____BII"F
......... -::qc
c
___ c ---
(..tfa) ..........
(IIIia)...........................
<M'C (115'P:I (Jill) .............
'F
-o'F
____l___
.-.2Jli.._
S....,_ . . . .
r.u.tloa CafiiiOIJ-USEPA - - - IMO __.k_
A,ucuue Bllllr. Ilea. 46 CPR ---'2.....Q...
v.,.. n-tiJ' (Air - 1.0)...........................
SohaiiDltr .. w..... ...
.....Q.Ql_
~
Nrllrftle

~0: Cornbc.letible liquid
- - . ....,....o
GM.ai-Moderate hazard, when exposed to heat or flame.
,.... Poblt ('F) ... 133

FlamlaU1e Llmll:l ... Unavailable
A.totp~tloD. r-.. I'F.I ..
EatfapWI'-1 Apatl ...
B06
...... CO., dry chemical, folm, water tog
Sptda1 Fire Procehrel .. Fight in the same manner as any Grade D petroleum product fire. Firefighter
should wear respiratory protection.
"""' ......... ._
HEALTH HAZARD DATA
He.Jtb Huanl Ratblp
1,1,1 Unavailable u..,.._
PEL/TWA (N.) n.vJTWA c,..~
Unavdeble
Ge.ent-Vapor harmful.
SJ...-Headaehe, dizzlneu, nausea
Sltort EltpoRre To~navailllble
Ex..-re Procecbuw-Vapor-remove vlc:tlm to treah air; If breathing atops, apply artificial respiratiOn. Sldn or
eye contact-remove contaminated clothing and gently flush affecte<l areas with water for 15 mlrMeL Get
medical acMce or attention. The etfec:18 of inhalation lniY be delayed.
REAcnVITY DATA
Stddlfty-Relatively stable. can react wtth oxidizing materill8.
C4.111ldbftltr-M.ttriai: Rubber, on long immersion, will first twell, then toften.
CvtD: Group 32 of compatibility chart

Avoid contact with liquid. Secure ignition IOUI'Cft.
H a .,W oecan, adl ... N.uo.al a..-: c.ter, I00-4Zt 1102.

a-lui: Usually lhipped u a mixture of Isomers: the ortho and para forma will predominate.
101
DIETHYLENE GLYCOL
.,_,__.;:;:DE;;G;;~-;;:;,~Dihy;~~:o~,;de~t;h~yl~ettwor.;;:~,
2,2' -Oihydroxyethyl ether;bia(2-Hydroxyethyl)ether;
3-0xa-1 ,5,-pentanecllol; 2,2' -Oxyblaethanol;
'-"'=<=-~V~ol=lod~N~-::;:~N~-::bw:.~.=====-=-_t__
2,2'-0xydlethanol
CHRIS Code ....
FOIWIIIa-(CH,C~OH).O
Botli111Pof.t.... .. ~c ---.JZ2'F
~-Colorless, syrupy liquid; lllght odor ___ c ---
Freezine: Pol:at... .. ~c ---.21'F
Spedfk Gnmty-1.12 ___c ---
Vapor~ ZO'C CA'F) (.mila) ......... ~
o..lad ~-Glycol ethers RRd VlpOI' ttre..re (ptla)..... . ...Y.....l.ml..
v..- ttre.ure 46'C (115'Fl ,,.,___ .. ...Y...I.ml..
Polhltle!l c.teaorJ-USEPA - - - IMO ___lll_ VIIPQI' Dlllllty (Air "" 1.0).. . .......aJHL
AppHcUle Blllk Ret. 46 CFR Sbdiafter ........ _LL_ SCIIvbiUty Ill Water.. Cgrre\l1t

,_.,G,..,....C
Ge.rai-Siight hazard, when exposed to heat or flame; can react with OKidlzing materials.
-""""
FIMII Pofat C'F>... 255
........... 1.6 to 10.8%
Allto!pitloll T-p. ('F) ............... 444
EJ:IIapl8lq Atellt. .... CO.. dry chemical, alcohol toam, water spray
__
Special Fire Procedllrel ............. . Water or foam may cause frothing. Do not direct water directly Into fire.
._
HEALTH HAZARD DATA
Healtla Huanl Ratiap PEL/I'WA (ppm) TLVITWA (ppm)
Geaeni-Under ordinary conditions of handling, not considered toxic.
SymptoiDI-Sidn which has coma into contact wtth the riQUid may bum or itch.
Sltort E:r:pollll'e Tolenmce-Unavailable.
E:r:...-re ~Eye or akin contact-flush affected area gently with water for 15 minutes. For eye
contact, or If akin is blistered or peeled, get medical anention.
REACfiVITY DATA
Stability-Stable.
Comp.tfbllUJ-Millerlal.: Compatible with moat matenats of construction.
Carao: Group 40 of compatibiNty chart.

Wear rubber gloves. face-shield, protective cothlng. Avoid contact wtth liquid.
U a .W ocan, eall die Nalioaal. Reepo.R ee.ter, IMJG...4l4 1102.

Remarb: ; Unaastgned
102
DIETHYLENE GLYCOL BUTYL ETHER
Synony1111- Butoxydiethylene glycol; 2-(2-Buto"Y Ualted Natlorl1 Number ...
ethoxy) ethanol; 2-(2-Butoxy ethoxy) ethanol; Butyl
Carbitol; Butyl diglycol; Butyl dioKitol; Diglycol
monobutyl ether; Dowanol DB; Ektasolve DB
Solvent CHRIS Code.
BolliDI Polat . ___..2ai'C ~F

Appearance-Odor-Colorless !Quid; faint pleasant odor. c 'F
Freezlna Point. -6B'C -90'F
Specltle Grlfity-0.95 c ---
Vapor Preuure ZO'C (68'FJ (mmH&) .. .Y..WL
Cbemlea1 Family-Glycol ether Reid Vapor PreuiUe {p81a)... .Y..WL
Vapor Prelslll'e 46'C (115'FI (psla) .. .Y..WL
PoU11tion Catesory-USEPA - - - IMO __1_11_ Vapor Demllty (Air = t,Ct) ... ~
Applicable Bulk Reg. 46 CFR Subchapter _____Q__ SoluiNilty In Water ... Complate

E}eetrieaJ Group-(;
General-Moderate tne hazard when exposed to heat or flame.
Flub Point ("Fl .. 172

Flammable Limits Unavailable
Autoignition Temp. ("Fl 442
Extinguishing A~nts. Confined area-CO., dry chemicaL Open area-polar solvent foam
Special Fire Prunodures . Water spray may cause frothing.
HEALTH HAZARD DATA

Health Haunt Ratings Odor Threshold (ppm) PEL/TWA (ppm) TL V (fW A (ppm.)
1, 0. 1 Unavailable Unavailable Unavailable
General-Slight eye 1rntalion. Low toxicity.
Symptoms-Liquid-slightly painful and irritating to eyes; repeated skin contact causes slight irritation.
Vapor-eye irritation.
Short Exposure Tolerante-Unavailable
Ellposure PrO('edures-Liquid-flush with water. Vapor inhalation-remove victim to fresh air.
REACTIVITY DATA
Stability-Stable
Comptltlbllity-Materlal: Mild steel and stainless steel are suitable. Certain rubbers and plastics are unsuitable.

Avoid contact with liquid. Secure ignition sources. Absorb on paper towel and vermiculite.
If a .,m occ:un, call tbe N.tional Relpoue Center, 800-tl4-8102.

Remarks: ~ Unassigned
103
DIETHYLENE GLYCOL ETHYL ETHER
S)'lloa)'IIUI-Carbitol solvent: Dowanol DE; Ektasolve
DE Solvent: E1hoxy d1glycol;
2-(2-Ethoxyethoxy)ethanol
CHRIS Code ..
Fol'lllula-HOCHaCH,OCH.CH.OC,Ho
Bo1Ua1 Poiat ..
Appearaace-Odor-Cotorless liquid; mild pleasant odOJ
Freeda1 Point ....
Speciftc Gnrity-1.03
Vapor Pre11111re lO"C (68'F) (mmHI) .. ~
OlemlcaJ FunJiy-Gtycol ether Reid Vapor Preau.re (!Ilia)... ~
Vapor Preuu.re 46'C (ll!I'FI (p!llro).... ......QJll_
Polludou Cateaory-USEPA - - - IMO ___JJl.__ Vapor Deulty CAir = 1.0)... .......... ~
Appllcab&e Bulk Reg, .tel CFR Sabdtapter ....... _.c.._ SGiubiUty In Water.. Completo

Eleetrkal Group-C
GeDeral-Mod&fate hazard when exposed to heat.
F1u.b PoiDt ('F) .. 205

FIIUillllable Umits .. LEL=1.2% UEL=6.5% (est.)
Autoip.itfoa Temp. ('F) .. 400
ExtJ..,W.bJ111 Ageatl .. Dry chemical, alcohol foam or carbon dioxide.
Speclal. Fire Procedurn .. Coat exposed tanks with wateJ.
HEALTH HAZARD DATA

Health Huanl Ratinp Odor Thrahold (ppm) PELITW A (ppml UV /TWA (ppm)
GeDeral-Strong ingestive toxin. Mild local Irritant. Under ordinary conditions of handling not considered toxic.
Symptom~-None expected with oormal use.
Short Ex,.,.ure Tolerance-Unavailable.
Expo11ure Proeedurn-Vapor-remove victim to fresh air. Skin or eye contact-remove contaminated clothing
and gently flush affected area with water tor 15 minutes. Get medical advice for eye contact.
REACfiVITY DATA
Stablllty-$table. Can react with oxidizing materials.
Comp!ltJbiUty-M.terlaJ: Usual materials of construction are suitable.

Avoid contact with liquid. Secure ignition sources. Absortl on paper towel and vermiculite.
U a spiU oeeun, can the National Re.ponse Center, 800-4U-880l.

Remarks: :t UnasSigned
104
DIETHYLENE GYLCOL METHYL ETHER
Sy_y __ Oowanol OM; EktllsoiYe OM Solvent; U.Uted Nat'- N . .ber ...
2-(2-Methoxyethoxy)ethanot; Methyl Carbitot
CHRIS Code ....
-
Formula-CH.OCH.CH.OCH.CH.OH
BoUma Point.... ___li3'C ____lli'F
Appeuance-Odor-Corless liquid with a mild pleasant 'C 'F
Freedq; Point.. -84'C -12Q'F
Speelftc: Gnrity-1.03 ___ c ---
Vapor Preaure lO'C (A'F> (mmfla).. _.Q4_
a.-leal F'allllly-Giycol ether Reid Vapor .._re <.-.)... .....QJlL..
Vapor PreNure 4fi'C (115'F> q.la).. ......QJl2_
PoUIIlton Cateaory-VSEPA - - - IMO ~ Va,or Denll.t)' (Air .. 1.0).. ....... .....J.1i_
Appllalltle Bulk Rq. 46 CFR Sllbdlaptel' ....... ----'UL Solbillty In Wakr.. CQmglttt

Electrical Groap-C
General-Modefate fire hazard when exposed to heat or flame.
Flub Poillt ('fl .. 200

Flamnu.IM Umltl .. LEL=1.2% UEL-unavailable
Alltolpltlon Temp. ('FJ . Unavailable
Extinplsblna Aaenb. Water, carbon dioxide, dry chemical, or alcohol foam
Special Fire Pnx:eduret .. Cool exposed tanks With water.
HEALTH HAZARD DATA

Health Hazard Ratings Odor Tllrelbold (ppm) PEL/TWA (ppla) TLV/TWA~)
o. 0, 0 Unavailable Unavailable Unavailable
General-Not considered toxic under ordinary condltions of handling.
Symptom-Liquid may irritate eyes.
Sbort Expo~ure Toleruce-Unavailable.
E1poaure Procedurn-Vapor-remove victim to fresh air. Skin or eye contact-remove contaminated clothing
aod gently flush affected area with water lor 15 minutes. Get medical advice lor eye contact
REACTIVITY DATA
StabUity-Stable. Can raact with oxidizing materials.
Compltlblllty-Mterlal: Usual materials of constrl.ICtiOn are suitable.
Cu&o: Group 40 of compatibility chart.

If 1 IJilU occun, Clll tile N1tioal Rapoa. Cellter, I00-4Z4-1102.

Renwkl: t UnassiQned
105
DIETHYLENETRIAMINE
s,..,._ bls(2-Amlnoethyl)amine;
2,2'Diaminodlethylamine
CHRIS Code ..
Fonallla-NH.CH.CH.NHCH,.CH,NH,.
BotllnaPomt.. ___wc ~-F
--
Aptldr'UICe-Odor-Thick yellow NQUid; ammonia-like
s,edllc Gnrity-0.95
Caealk:a1 Family-Amine
Fneldii&PIMIIt...
Vapor Preaure lO'C (61'F) (mmHI) .....

Rlld VIIJIOI' Pre.are (pita)... ...
v.,.-~46'CC115'F)C,.W..
c
-39'C
"F
-3B'F
___ c ___ F
_l.a_
__Q.Qi_
~
Polbttloa Catepey-USEPA - - IMO ___lL_ V.,or ne..ty (Afr = 1,0)....... . ....... .......a.JI_
Allfl,lable Bulk Res. 46 CFR S....,._ ........ ____Q_ SoiWUtJ in Wat. CqmP'eta

Grade--E: Combustible liquid
-<ln>op--0
Ge.erai-At ambieot temperatures the fire hazard Is low. Irritating vapors are generated when heated.
, _ . Potat ('F) .. 215

m-ble u.J:a .. 1 to 10% (calculated)
AutMIItlidoll TeiiiJI. ('F) .. 750
~Aaelltl ... ................ CO.., dry chemical, alcohol toam. water fog.
Speelal Fin Procedares .. Water increases the amount of vapor produced. Fire parties should -r body
and self-contained breathing apparatus.
Healtla Hazar1l lbtlap ._........,._

HEALTH HAZARD DATA
PEL!IWA (ppm) TLV!1WA (ppllll)
2, 2, 2 10 1 1/Skin
Geaend-Uquid causes severe bums. Vapor is irritating.
Sym,ro.t-Throat irritation, nausea, wheezing breath. Liquid contact can cause serious eye and skln bums and
severe allergic reactions.
Sltort ExpoRN Toieruu-Unknown. No animal deaths followed on 8-hour exposure to saturated vapors at
room temperature.
Ez...-.re Procedllrei-Vapor-remove victim to fresh air; If breathing stops, apply artificial respiration. Oxygen,
administered by trained personnel, is helpful. Skin or eye contac:t-nti'TIOV8 contaminated clothing and genUy
flush affected areas with water tor 15 minutes. Get medical advice or attention.
REAcnVITY DATA
SbiWUty-Stable. Water dllvtioo will evolve toxic vapors.
CompatfbilltJ-Mtlterlal: Corrodes copper and Ita alloya.
Carao: Group 7 of compatibility chart. See alao Appendrx !-Exceptions to the Chart.

Wear rubber gloves, face-Shield or all-purpose canllter mask, and protective clothing. Avoid contact with the
liquid. May cover with SOdium bisulfate, spray with large excess of water and washup.
If a ipiU ocean. eaU tiM Natloul ae.o- C.t., 100-424 IIOl,
106
DIETHYLETHANOLAMINE
SJBOIIYJM- DEAE; Dlethylaminoethanol; 2-0iethyl
amino ethanol; 2-N-Oiethylamino ethanol; 2-0iethyl
amlnoethyl alcohol; beta-Diethylaminoethyl alcohol;
N,N-Diethylethanolamlne; Diethyl-(2-hydroxyethyl)
amine; 2-Hydroxytriethyl amine CHRIS Code ..
-
A~ss
Spedfk Grarity-0.88
Chemkal FIUilily-Amine
lquid; weak
Polllltloa Cateaor7-USEPA _ _ _ IMO ~

ammonia-~ke
....,,. '" ..
Fmzin& Poillt. ... polK point
Vapor " - r e lO'C (68'F')

Reid V.,or ~ (plda).....
Vapor Pralure 46'C (IU'F) (pm)...
Vapor ~>entity (Air = 1.0)...
_____mc ____mF
c
-ZS'C
___ c ___
<IIIDIHI> ..
'F
-1Q8'F
'F
~
___i_
~
---4JlL..
Applieable BoOr. Rea. 46 CFR Sbcbafter ........ ____Q__ Solbillty ln Water.. Cqmpfakt

Gl'lllle-0: Combustible liquid
Eltc'trical Groop-C
GeDel'lli-Moderate lire hazard when exposed to heat or llama. Toxic and irritating gases may be generated.
Flllfh Poiot <'FL .... 126

Flmamable Llnrlts. 7 to 12%
Alltolpldon Temp. ('F) .. Unavailable
Extinpl,biq Agenb ... Dry chemical, CO.. alcohol loam, water fog
Sptdal Fire Procedure~ .. Cool exposed tanks with water. Provide fire fighters with sell-contained
HEALTH HAZARD DATA

Health Huard Rltlap Odor Thretltold (ppm) PEL/lW A (ppm) TLV IJ'W A q,p.)
1, 1, 3 0.04 10/Skin 10/Skin
Geaeral-Vapor irritating to eyes, mucous membranes. liquid irritating to skin.
Sy...,._Vapors cause nausea, vomiting, respiratory irritation. Liquid causes eye and skin irritation.
Slwrt Expo.are Tolerance-500 ppm in 30 minutes: 200 ppm is toxic to central nervous system.
Expoture Procedarw-Remove victim to fresh air, if breathing stops administer artifiCial respiration. Immediately
flush with large amounts of water for 15 minutes, get medical attention.
REACTIVITY DATA
St.blllty-Can react with oxidizers and strong acids.
CompattbUity-Material: Incompatible with zinc, galvanized iron, copper, and copper alloys.

Wear protective clothing, goggles, gloves. Secure Ignition sources. Cover with sufficient quantities of sodfum
bisuHate and sprinkle water.
U a IJI(ll ocean, call tbe NadoMI JleepoeM Cenle!', I00-4:Z4 IIO:Z.

Remlll'U: t Unavailable
107
DIETHYL SULFATE
.....
s,_.,._ Ethyl aulfate: Sulfuric acid, dlethyl
CHRIS Code ..
BoiJJD& Polt .. _____:zQ'C ~F

~lorless oHy liquid; peppermint odor c 'F
Freed.. Point.. -24'C ~'F
s.eetne Grarity-1.18
___ c ___ .F
Vapor Preaure zoc C68'FJ <mnlllgl.. .. ....2.!lli_
Reid Vapor Pnaare (..ill)... ...Y....L.ml..
Vq,ar Prellare 46'C (115'F') (!Mila)... _.1..._
PoiD.tiH c.te,ory-USEPA - - - IMO _.IL_ Vapor Deultr (Air = t.OJ... _u_
AIIPHeUie Bllllr. Rea. 46 CFR Sbchafter ........ ___Q__ Sol11btllty Ia Water.. .. ln'21ub!t

""""""--D
Geaerai-Low hazard when exposed to fire or flame.
F1M11 Pofllt ('Fl .. 220

~bleU..U. ... 4.1 to 12.4% (estimate)
A.to!pidaa Temp. ('F) .. 817
~~Apm ..... Alcohol foam, CO., dry chemical
Spedal F1re Proeed- ........Water or foam may cause frothing. Do not direct water directly Into fire. Wear
self-contained breathing apparatus, gloves.
HEALTH HAZARD DATA

Health Huard Ratlnp Odor 1'llrwllold 0..) PEL;TWA (ppm) nv.rrwA <ppm)
ee.er.t-Highly toxic by Ingestion 8lld inhalation. Strong irritant. Decomposition liberates ethyl ether and suHur
oxides.
S)'lllpJODif-Highly irritating to skin and mucous membl'anes. Burns are caused on prolonged contact. Nausea
and vomiting.
Sltort ~ Toleruee-Anlmal studies showed the lowest lethal concentration to be 250 ppm tor 4 hours.
Serious Illness may result from prolonged contact.
Ex,oare ProeM Remove victim to fresh air. Administer artificial respiration or o>eygen as necessary.
Irrigate eyes with water. Wash akin wtth aoap and water. Get medical advice or attention.
REACTIVITY DATA
St.ltUftr-Decompoaea to form ethyl ether; water alowly decomposes substance to form sulfuric acid.
Incompatible with strong alkalies.
~-MIIterlal.: Aluminum, zinc, galvanized Iron, lead, nickel or copper and Its alloys should not be
used. Phenolic-lined or atalnleu 1teelare suitable.
c.rto: Group 34 of compatlbNity chul.

Wear protective clothing, self-contained breathing apparatus, gloves. Soak up small apilla with abaorbent or
IOda aah. Waah large apills with water.
It a ..,W oecva. call die Natloaal RelpoMe Ceaa., 800-414 180:Z,

Re.arb: Begins to decompose below Ita bo1llng point.
t Unavailable
108
DIISOBUTYLAMINE
Synoa)'IM- N-(2-Mathyl propy1)amlne; Ullllell N.u- N. .Mr ............................ ..
N,N-biS(2Mathy1propyl)llmlne; 1-Propaoamine,
2-methyl-
CHRIS Code .......................................... .....c&l.L

Fonnubt-C,H,.N
aow., Point.. ____JJi'C ____ili'F
Appearuee-Odor-Water white liquid: amine odor c "F
Freezt.1 P-"nt... -nc -tQZ'F
Spedflc: Gr...lty-0.745 ___ c ---
v.,.. ~re lO'C C61'F> C..HIJ).. ___JQ___
Retd Vapor rr-e (pila)... ............ ......Q.2i....
Pollution Catep~ry-USEPA - - - IMO _____c__

v.,....
'"-re 46'C 1115'F> ()Ilia) ............ ~
v.,....
ne-ll)' (Air .. 1.0)........................ .....J&..._
Applkdlle Blllk Rq. 46 CFR Su~ ....... _.Q._ Sol"aWHiy Ia W.ter .... Sllqb!

Gndr-0: Combustible liquid
E~lcal Group-C
General-Highly dangerous when exposed to heat or flame
Flab. Point ('F).. 84

Flam-ble Umltl .. Unavailable
AutolpltJon Temp, ('F) .. Unavailable
EsdnpiMin& Allflltl ... Alcohol foam, CO., dry chemical
Special Fire Proced!lrts .. Full respiratory protection as well as body protection.
HEALTH HAZARD DATA

Healtb Huard Ratinp Odor 'l1lrelhold (ppm) PEL/IWA (ppm) 11.V/I'WA (pfm)
3, 4, 3 Unavailable UnavaNable unavailable
Geueral-Uquicl causes burns and eye injury.
Symptome-lrritation of lungs and respiratory tract. Sklnllght irritation to burns.
Sbort Expo1ure Toleruce-E)(pOsures greater than 100 ppm will produce irritation of respiratory tract. Pulmonary
edema may resuh.
ExJIOillrt Proced ee--Remove to fresh air. Give artificial respiration Of oxygen ae necessary. Skin, eyes-fluah
immediately with water tor at least 15 minutes. Remove contaminated clothing at once.
REACJ'IVITY DATA
Stability-Stable.
Comp.tjbUity-Miterlal: Will dissolve paint and most plastic materials.
Carto: Group 7 Of compatibility chart.

Wear seHcontained breathing apparatus. lull protective clothing and rubber gloves. Avoid contact with liquid.
Secure ignitiOn sources.
If .,W occwn. eaJ1 tbe Nsdoul lteuoue c.ter, 100-424 8102.
109
DIISOBUTYL CARBINOL
Syncmr-- 2,6-Dimethyl-4-heptanol; aec-Nonyl alcohol Ullited Natloq Number ...
CHRIS Code ....
F-uJ-((CHa)JCHCH,)sCHOH
BoUiq; PoiDt.... ____!Z&'C ~F
~lor1ea&. oily liquid with. c 'F
characteristic odor Freezma Polllt... -65'C -85'F
Specltk Gra"rity-0.81
___ c ___ .,
Vapor ~- lfi'C (68'F) (laiDHa)..
v.,.., 1>eD1ftJ......_re <.-).......

____Q.a._
a..tea1 Fm.ily-Aicohol Reid Vapor _.QJl!t_
Preeare 46'C 1115'F) lptla)... __QJ__
Polllltlcm Caleaorr-USEPA - - - IMO .....JIR..k_ Vapor (Air = 1.0) .......................... ----i..iL_
APf]kallle Balk Rea. 46 CFR S.bdlafter ........ -..Q...Q.... SolubiUty 1D Water.. !nsolubl!
FIRE A EXPWSION HAZARD DATA

GnMie-E: Combustible liquid
Eleetrieal Group-O
General-Moderate hazard, when exposed to heat or flame.
Flub Potat ('F) .. 165

l'lammQle lJmjg .. 0.8 to 6.1% at 212'F
AutcnpJtio.. Temp. ('FL. 494
ExUquilbl111 Aaena ..... Carbon dioxide. dfy chemical. alcohol loam
SpedaJ F1re Proeedurel .. Not pertinent
HEALTH HAZARD DATA

Healtb Huard R1tblp Odor TllreUold (llflll) PEL/J'W A (ppm) TI.V!JWA(p)Uil)
Geaerat-Low toxicity.
SyptoiM-Vapor caUHs eye, nose, and throat Irritation. Uquid contact causes redness, flaking, cracking.
Short Ell:pogre Toleruce-Eye Irritation at leu than 5 ppm. Nose and throat irritation at 10 ppm.
Exposare Proced..._Vapor-remove victim to freSh air. Skin or eye contact-remove contaminated clothing
and lluah affected areas with water for 15 minutes. Get medical advice.
REAcriVITY DATA
StabWty-Stable. can react with OXIdizing materials.
CompatibiUt)'-Miiterlal: Usual materials of construction are suitable.

If 1P111 ocnra. C1I1 tbe N.a:loul ...,.._ C..ter, 100-424-IIOl,

Remarb. :t Unassigned
110
DIISOBUTYLENE
Synonyms- D1isobutene; Disobutylene, isomeric United Na1iODS Number ...
comp's; 2,4,4-Trimethyl pentene-1: 2,4,4-Trimethyl
pentene-2; Trimethyl pentane
CHRIS Code ..
_,
Formula--C.H 16
Aaranu.Odor-Water white liquid; typical organic

Boillna Point ..
Freezlna Point ..
___1Q2"C ___lli"F
-93'C
c "F
-138'F
Specifk Gra'l'ity-0.72
Vapor Preaure Zl)"C (68'F) (mmHJ) ...
c ---
Cbemical Family-Olefin Reid Vapor Preaure (,.ta) ... ~
Vapor Preuure 46'C {115"F) (psia) ..... _ll_
Pollution Category-USEPA - - - IMO ____a__ Vapor Dellllity (Air = un.... --'l.H.-
Appllable Bulk Reg. 46 CFR Subchapter ...... ~ Solubility In Water .... !nsntuable

Electrical Group-O
Ge~terai-Dangerous when exposed to heat or flame. Flashback along vapor trail may occur. Vapof may
explode if ignited in an enclosed area
Auh Point ("FJ .. 20

flammable Umits .. LEL=0.9% (est.) UEL-unavailable
Autoignition Temp. ("F).
Extiaguisbing Allfllts ..
Specllll Fin: Procedures .. ,
""
Foam, carbon dioxide, or dry chemical
Cool exposed tanks with water. Water may be ineffective on fire.
HEALTH HAZARD DATA

Health Hazard Ratings Odor Threshold (ppm) PEL/TWA (ppm) TLV/TWA (ppm)
General-Slight vapor hazard, and slight skin irritant.
Sympto11111-Headache, nausea, weakness, mental depression, inability for sustained attention.
Short Exposure Tolerllllce--lrritant and narcotic in high concentration. Has caused liver damage in test animals.
Expo:KUre Procedures-Vapor-remove victim to fresh air. Administer artificial respiration if necessary.

~"m-wash with copious amounts of water. Call a doctor.
REACTIVITY DATA
Stability-Will not spontaneously decompose.

Avoid contact with liquid. Secure ignition sources.
If a spill oc:cun, eall tbe Nlltional Response CeDter, 800-424-8802.
Remarks: Vapor Pressure: 67 mmHg at 35c.
111
DIISOBUTYL KETONE
SyltOIIyiDt- DIBK; sym-Dilsopropylacetone; sym-5- United Natm. Number .....
0iisopropylacetone; 2,6-Dimethyl-4-
heptanone; lsovalarone; Valerone
CHRIS Code ..
Formula-[(CH,).CHCHz]zCO
Boillna; Point .. _ _ll!"C ~,
Appearance-Odor-Colorless liquid; mild odor c 'F
Spedllc Grulty--0.81
Fne:zinc Point .. ~41"C
___ c _______.,
~42"F
Vapor Preuure lG"C (68"F') 1-Ha) .. ~

Cbemieal. Fllllll1y-Ketone Reid Vapor Pre.ure (pm)... ___2.ll_
Vapor~ 4Ci"C (115"F> (pita).. __2&L_
Poll1tl011 Catesory-USEPA ------- IMO _.lL_ Vapor Denl.lty lAir = 1.0) .......................... ____!.i_
Appllc:roble Built Rea, 46 CFR Sabdaapter ....... --'2......... Solubility ln Water.. Negl"lqj'ple

Elec:trleal Group-O
GeaeraJ-Moderate fire hazard when exposed to heat or flame.
Flath PoiDt ("F) .. 140

Flammable Limits .... 0.8 to 6.2%
AutolpJtlon Temp. ('FJ .. 745
EJ:tfnguilbial Apntl .. Carbon dioxide, dry chemiCal, alcohol fOam
Spedal Fire Proced~ .. Wear self-contained breathing apparatus. Cool fire-exposed tanks with water.
Water may be ineffective on fire.
HEALTH HAZARD DATA

Health Hazard lbltlnp Odor 'I'hreQoJd (ppm) PEL/TWA (ppm) TL V/TWA (ppm)
General-Fairly toxic if inhaled; minor skin irritation.
Symptoms-Redness or irritation of skin; irritation of eye, nose and throat.
Sbort Ell:ponre ToleriUlCe-Animal tests show minor skin irritation, traces of eye injury. Inhalation resulted in
33% death rate in 8 hours, on test.
Exposure Proc:edarea-lnhalation: Remove victim to fresh air, if breathing stops, apPly artificial respiration. Skin
or eye contact: Flush affected areas lor 15 minutes with water. Get medical advice or attention.
REACI'IVITY DATA
St.ltlllty-Stable. Can react with oxidizing materials.
ColllJIIItlltillty-Material: Mild steel can be used.

II possible, wear rubber gloves, lace shield, and protective clothing. Secure ignition sources. Have all-purpose
canister mask available. Keep unprotected personnel upwind of contaminated area. Flush with water.
II 1 spill ooeura, call tbe N1Uoul Relpoue Ceacer, 100-4l4-88Ql,

Remarb:
112
DIISOPROPANOLAMINE
SyltOII)'DII- 2,2' -Dihydroxydlpropylamina; DIPA; United Natioa Naber.............................. .
1,1 '-lminodi-2-propanol
CHRIS Code ..
Fona.uJa-(CH,CHOHCH.).NH
BoUiq Point.. .. __2!i'C ____410'F
A~While crystalline sotid or colorless c 'F
monen liquid; ammonia-like odor Freezhla Poblt.. __...U'C ----l.QI'F
Spedfte Graflty-0.98 at 42'C ___ c ---
Vapor Preuure lG'C (61'F) <-11&1 ......JML_
Olemiad F..mJy-Aikanolamines Reid Vapor r.-ure (pm)... _QJL_
VllfOJ' Preellll'e 46'C (115'F) (pita).. ~
PoUutloa Crotqory-USEPA - - - JMO ______Q__ Vapor Deulty (Air "" 1.0).... ~
Applleable &lk ReJ. 46 CFR Subcbapler ....... __Q__ SolubiHty Ill Water ........................ Cgmpltl!

GrMe--E: Combustible
Electrlc:al Gr011p-O
General-Slight fire hazard when exposed to heat. Material kept at 120'140'F for ease of handling. High
temperature evolve ammonia and other toxic vapors.
F1ub Point ('F).. 260

Flammable Limih. 1.1 to 5.4%
Autoipltlon Temp. ('F) .. 580
ExtlnpiUill& AteJ~h ... Carbon dioxide, dl'y chemical. alcohol loam.
Special F'JR PJ'Gcedure. .. Wear self-contained breathing apparatus and full protective clothing. Water
may be ineffective on fire; water or foam may cause frOthing.
HEALTH HAZARD DATA

Healtll Huard Ratlnp Odor Threellold (ppl PEL/I'WA~) TLV /TWA C:,.)
GeDend-Siight skin irritation from contact. Slight vapor irritation. Principal hazard Is to eyes. Wear eye
protection. Possibility of thermal burns from hot liquid.
Symptoms-liquid: skin irritation.
Short Expo~ure Toleruce-Breathing the mist generated from the chemical held at 338"F was not fatal to
animals in an 8 hour exposure.
Es:po~ureProcedures-If eyes are splashed with dllsopropanolamlne, wash with water immediately. Obtalo
medical aid.
REAcriVITY DATA
Stahllity-Chemically stable. Upon heating breaks down Into original starting materials.
Compatibility-Material: No action on common materials at ambient conditions. Copper or copper alloys should
not be used.
<:arao: Group 8 of compatibility chart.

Wear full face Shields or goggles with side shield, or equivalent Wear rubber gloves and protective clothing.
Avoid contact with liquid which can cause thermal burns.
H a spiU occun, call the NatiODal Relpoue CUter, 800-4~2.
Remarlu: t Unassigned
113
DIISOPROPYLAMINE
S)'IIODJ-- DIPA; N-(1-Methylethyl)-2-propanamine
CHRIS Code ..
Boillna Point . ~-c -----la'F

~--Colorlesa liquid; amine odOf c 'F
Specltk GravUy-0.72
FreeziD& Poi11t ...
___ c -=iiF
-----::Qijc ___F
Vapor Prellllre 20'C (68'F) (Bmlf&) ...
Cbelllkal Family-Amine Reid Vapor Preaure (plla) ..... .
VllpGI' Prealll'e 4Ci'C (115'F) (p!lla) .....
Pollutioa Qdeaory-USEPA - - - IMO __c_ V.I)Nir ne.ity (Air = 1.0) ......
ApplieUle Btllk Rea. 46 CFR Suber..pter ...... _.c.___ Sol111tlllty In Water ..

Electrical Group-(:
Ge.erat-Dangerous. Keep away from heat and open flame. Toxic oxides of nitrogen may form in fires.
Flashback alOng vapor trail may occur. Vapor may explode If ignited in an enclosed area.
PWb Poia.t C'FJ ... 30

F'luunah&e Umitl .. Unavailable
AutoipjtfH Temp, ('F) .. 600
EIU.......... Apntl ..... Alcohol foam, CO., dry chemical
Speda] Fire PfocedURII ,, Water may be ineffective. Wear eye protection and self-contained breathing
apparatus.
HEALTH HAZARD DATA

Health Hazan! Ratinp Odor nn.bold (ppm) PEL/l'W A (ppm) TLV!TWA (ppm)
3, 2. 4 Unavailable 5/Skin 5/Skin
Geneni.-Liquld irritating to skin and eyes on contact. Inhalation of fumes can cause pulmonary edema.
Symptoms-Eye, skin, and respiratory irritation.
Short Exponre Tolerance-Death results at 2200 ppm, or from repeated exposures of 260 ppm; nausea and
impairment of vision occur between 25 and 50 ppm.
EspotUre Procedlll'ei-Aemove victim to fresh air. Apply artificial respiration, if breathing stops. Skin or eye
contact-remove contaminated clothing and gently flush affected area with water for 15 minutes. Get
REACTIVITY DATA
Stability-Stable.
CompadbUity-Material: Avoid copper and copper alloys.
Cvao: Group 7 of compatibility chart.

If possible, wear butyl rubber gloves, face shield or all-purpose canister respiratory protection, protective
clothing. Secure ignition sources. Cover with sodium bisuHate and clean up. Flush spill with large quantities Of
water.
II aplll ocean. e.ll ta.e NRloul ~ Cellter, 800 ~2.
114
DIMETHYLAMINE
Synon)'lllll- Oimethytamine, anhydrous; DMA;
Methenamine, N-methyl-; N-Methylmethanamine
CHRIS Code
Boitioo Polol . ____..l"C ~F

Appearance..Qdor-Colorless gas; fish-l1ke or c 'F
ammonia-like odor Freezin1 Point.. --=ic -14l'F
___ c ___ .F
Spedfic: Gra'flty--0.68 atrc(a liquid)
Vapor Preuure lO'C (68'F) (miiiHR) .. _ll!2Q_
Cbem.ial Family-Amine Rehl Vapor Preuure (pita)... ~
Vapor Preaure 46'C (ll!!i'F) (pila).. ___M._
Pollu1ion Catepy-USEPA ____Q__ IMO ___QU_ Vapor DeDalty <Air = 1.0).. ............... ~
Applicable Bulk Reg. 46 CFR Subchapter. ____Q___ SolubiUty ill Water.. ApproGiabiA

Ele<trical Group-C
G..-nl'ral-Unless the flow of gas can be stopped, putting out a dimethylamine fire will permit an explosive vapor
concentraliOn to accumulate. Extremely flammable. Vapors are eye, skin and respiratory irritants.
Huh Point t"ll: .......... Flammable gas; solutions of 5% or more are considered flammable liquids
tlammable Umits 2.8 to 14.4%
Autoi!P'ilion Temp. ("F) . 756
t:dinguishlnl A~11ts .. Stop flow of gas; CO,, dry chemical, water fog
Spedal F1re Procedures Use of foam is not recommended Tanks exposed to fire should be cooled
w1th a water spray. Firefighting personnel should be provided with self-contained breathing apparatus and
body protection
HEALTH HAZARD DATA

Health HllZ.Ill"d Ratinp Odor Thrabold (ppm) PEL;TWA (ppm) TLV/TWA (ppA~)
3. 2. 3 0.047 10 10
~neral-Vapor extremely irritating. Liquid causes burns.
S)mptom1-Eye Irritation; irritation to nose and throat. coughing and sneezing; headache, nausea
Short E11:posure ToltlliJite-20 ppm for 5 minutes.
E11:poaure Proceduru-Vapor-remove victim to fresh air; if breathing stops, apply artificial respiration. Oxygen.
adm1mstered by trained personnel, is Often helpful. Skin or eye contact-immediately flood affected areas
gently with water. Remove contaminated clothing and continue to flush affected area for 15 minutes. Get
medical attention.
REACTIVITY DATA
Stability-Stable. DMA is highly reactive with other material.
Compatlblllty-Maten.J: Steel is a suitable construction material. Copper, aluminum, and their alloys,
magnesium, zinc and galvanized metal are attacked readily and should not be used.

Wear butyl rubber gloves, all-purpose canister respirator, protective clothing. Avoid contact with liquid. Secure
ignition sources. Flush spill with large quantities of water. For a gas leak from a faulty tank, keep concentration
of gas below the explosive mixture range by forced ventilation.
If a spill oceun, call tbe Nadoaal Rnponte Center, 800-4U-880l.
Reaw"ks:
115
DIMETHYLAMINE SOLUTION, 40%
Synony-- Methanamioe, N-methyl-; N-Methyl
methanamine, 40%
CHRIS Code ..
Fol'lllula-(CH,},NH
Boiling Point ... _____M'C ---.1.2!'F
Appevance-Odor-Ciear, colorless liquid; ammoniacal,
c ___ F
fishy odor
Specific Gnrity-0.892
FI'MZI.ng Point ..
___ c --=
-37"C ___.a~tF
'F
Vapor Preaure lO'C (68'F) (mmH&). ___11Q_
Cbeml&:al Family-Aliphatic amines Reid Vapor Preaure (psla) .... _u_
Vapor Preaure 46'C (115"F) (ptia) ... ____i.L_
Pollutioa C.teaory-USEPA _____..c._ IMO ___Q___ Vapor l>eMity (Air = 1.0).... ....1M_
Applleallle Balk Rea, 46 CFR Subcbapter ....... ____Q___ Solubility In Water . . AQP!JI!jj&b!e

Electrical Group-S
General-Vapor is elctremety flammable. Flashback along vapor trail may occur. Vapor may explode if ignited in
an enclosed area.
F1ub Point (F) ... -1 (cc)

Fblnunable Umitll .... 2.8 to 14.4% (anhydrous)
AutcHpitlon Temp. ('F) ... 752 (anhydrous)
ExtillJIIIIhinl ApinQ ... Water log, CO.. dry chemical, alcohol foam
Speelal Fire Proeedura . Use water fog to protect personnel ard cool containers. Wear protecf1ve
HEALTH HAZARD DATA

Health Haurd btinp Odor Thrnbold (ppnt) PEL/TWA (ppm) TLV!TWA (pplll)
3, 2. 3 0.6 10 10
General-Vapor very irritating, liquid causes burns.
S)'lllptoms-Vapor causes sneezing, coughing, plleumonitls, pulmonary edema. liquid burns skin, eyes, mouth,
throat.
Short Expo~~ure Tolerance-Vapor very irritating above 10 ppm.
Expo~~ure Proc:ed~Get med"~eal attention. Inhalation: Remove to fresh air, rest, give mouth to mouth
rescusltatiOrl or oxygen if needed. Ingestion: Do not induce vomiting. Skin contact: Flush skin and eyes for
at least 15 minutes.
REACTIVITY DATA
Stability-Generally stable; reacts with acids, strong oxidizers. Can explode In contact with mercury if ammonia
present, so keep mercury thermometers and similar instruments away.
Compatibillty-MterlaJ: Suitable: Stainless steel, mild steel, iron. Unsuitable: (Corrosive) Aluminum, copper,
zinc, brass, bronze.

Avoid contact, do not breath vapor. Wear protective clothing (face shield, hard hat, goggles, rubber gauntlet
gloves, apron, boots). Use self-contained breathing apparatus if needed. Do not flush into sewers; dike and
remove, then flush spill area with water. Secure all ignition sources.
,...
If I spUI oeeura, ad! the Nltioul Rapolllt' Center, 800-424-8801.
116
DIMETHYLAMINE SOLUTION, 50%
Sy_,__ Methanamlne, N-methyl-; N-Methyl
methenamine, 50%
CHRIS Code ..
...... ....... _-c __113"F

Appearuee-Odor-Ciean, colorless liquid; ammoniacal, c "F
fishy odor Freezlq Poblt.. -::qc -4B'F
Specific: Gruity-0.863 ___ c ---
V.,or Prealll'e lG'C {61'FJ ~HI).. . ~
CbeiBkal Fulily-Aiiphatie amlnes Reid Vapor rr-ure (pila)..... ___L_
Vapor Prellve 46'C (115'F') (plia)... ___L_
Polladon c.teaorr-USEPA ~ IMO __Q__ Vapor Deallty (Air = 1.0) ................. ~
Applicable Bulk Rea. 4fi CFR Sabcbapter ....... ~ Solubility ln. Wales-... Aoo!JtGinb!e

Grade-A: Flammable liquid'
E&ectrieaJ Group-8
GeMn~l-Vapor is extremely flammable. Flashback along vapor trail may occur. Vapor may explode if ignited in
an enclosed area.
Fl..b PoiDt ('F) .. -9

Flammable Umlb .. 2.8 to 14.4% (anhydrous)
Autolp.itlon Te111p. ('F) ... 752 (anhydrous)
Extinaullblna Aaeaa ..... Water fog, CO., dry chemical, alcohol foam
Special Fire Proeedura .. Use water fog to protect personnel and cool containers. Wear protective
HEALTH HAZARD DATA

Health Huanl Ratlnp Odor Thrahold (fpm) PEL/TWA (ppm) TLV/TWA {ppm)
3, 2. 3 0.6 10 10
General-Vapor very irritating, liquid causes burns.
Symptom-Vapors cause sneezing, coughing, pneumonitis, pulmonary edema. Liquid burns skin, eyes, mouth,
throat
Short Expo~~~re Tolerance-Vapor very irritating above 10 ppm.
Expoture Procedura-Get medical attention. Inhalation: Remove to fresh air. rest, give mouth to mouth
resuscitation if needed. Ingestion: Do not induce vomiting. Skin contact: Flush skin and eyes for at least 15
minutes.
REACI"IVITY DATA
Shlltility-Generally stable; reacts with acids, strong olddlzers. can explode in contact with mercury if ammonia
present, so keep mercury thermometers and similar instruments away.
Compatibillty-Mterlal: Suitable: stainless steel, mild steel, Iron. Unsuitable: (corrosive) Aluminum, copper, zinc,
brass, bronze.
Carlo: Group 7 ol compatibility chart.

Avoid contact, do not breath vapor. Wear protective clothing (face shield, hard hat, goggles, rubber gauntlet
gloves, apron, boots). Use eeH-contained breathing apparatus if needed. Do not flush into sewers; dike and
remove, then flush sp1ll area with water. Secure all Ignition sources.
If I Ifill OCCIIl'lt till tiM Nlllloul Relpoae Center, I00-4Z4-880l.

Remark~: Grade based on calculated vapor pressure for 55% solution. ,,.
t UnavaHable
117
DIMETHYLETHANOLAMINE
s,...,..._Oeanol: 2-(Dimethylamlno)ethanol;
betaDirnethylaminoethyl alcohol:
N,N-OimethyiN-(2-hydroxyethyl)amine
CHRIS Code .
Fonnllla-{CH.).NC.H,OH
BoWq Pobal .. __lli'C ___],]J,'F
~lor1ess liquid; amrnonill-iike odor c 'F
Pnezina: Point .. ___ c ---=z<i'F
-5i'C
Spedfk Graril)'-0.89
Vapor PreiMre ZO'C CA'P) (-tiiJ) ...
---
_4.L
Chendeal F..tiy-Atkanolamines Reid V11p0r Prelllll"e (pila) ... _1_
Vapor Preuure oM'C (115'F) (pN) ... _1_
Pollutto. Cateaorr-USEPA - - - IMO ___ll_ v...- Deultr (Air = 1.0)... ~
......
ApplleaWe hlk Rea. 46 CPR S.bdaapter ........ ____Q_ Sol'llbUity Ia Water .... Comp!tte
--p-C
Grade-D: Combus~la r~R~Jld
General-Moderate hazard, when exposed to heat or flame; can react vigorously with oxidizing materials.
. , . . Pobll ('F) .. 105

F'lamalble LbaUa .. Unavailable
AutoipddoD. Tem.. {'F) .. Unavailable
Ea:tblplaldq Apaa ... ................ CO. dry chemical, alcohol foam, water fog
Spedal Fire P'rocelblre~ .. Water may be Ineffective
HEALTH HAZARD DATA

Healdll Huard a.u.,. OCior 1'hredlold (ppm) PEL/J'W A (ppm) TLVIIWA (ppm)
Geaerai-Skin contact extremely dangerous.
S)'JIIptoiQ-Initation of nose and throat
Sltort b:pGIW'e Tolerlutre-Unavaliable
E:.:pollll'e Proeelliluret-Vapor-remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or
eye contact-remove oontaminated Clothing and gently flush affected areas with water for 15 minutes. Get
mediCal advice or attention.
REACI'IVITY DATA
St.bWty-This is a relatively reactive substance which can react with many other chemicals.
eom,.UbJIIty-Material: Copper and copper alloys, and zinc and galvanized iron are corroded readily and
should be avoided.
Carao: Group a of compatibility chart.

Wear rubber gloves, full-protective clothing. Avoid cootact with liquid. Secure ignition sources.
U a .,UI OCCIII"II, call. tile Natloaal RelpoDM Ceater, 1100-424 8801,

Remarb: t Unav8llable
118
DIMETHYLFORMAMIDE
Synonyms- N,N-Oimethylformamide; OMF; DMFA United Nations Numbllir.. ..
CHRIS Code ..
F011111ula-HCON(CH,).
Dolling Point .. ~c ____]lli"F
.,
c ___.,
Appearance-Odor-Colorless liquid: unpleasant and fishy c
-5B'C -Z3'F
'"'"
Specific Grnity-0.95
Freeztna Point ..
Vapor ~ure ZO'C (6B'F') (nunfl&) ..

Chemical Family-Amide Reid Vapor Preuure (plla) ... _.Q.JL
Vapor Preuure 46'C (115'F') (pma). ....ll.W.._
Pollution Category-USEPA - - - IMO ~ Vapor DeQity (Air = t.G) ... ~
Applicable Bulk Reg. 46 CFR Subdlapter ...... __Q__ SoluWiity in Water ... Compl&te

G111df-D: Combustible liquid
Electrical Group-O
Genuai-Moderate hazard, when exposed to heat or flame; can react with oxidizing materials. Vapors are
irntat1ng
Fluh Poinl ("FI 136

Flammable Limits. 2.2 to 15.2%
Aulolgnition Temp. ("F) 833
E~:tinguishing .4.~nts .. Alcohol foam, C~. or dry cl'lemical.
Special J<ire Procedures Provide lire-fighters with self-contained breathing apparatus and protective
clothing
HEALTH HAZARD DATA

Health Hazard Ratings Odor Thre:shold (ppm) PEL/fWA (ppm) TLV 11WA (ppm)
2, 2. 3 100 10/Skin 10/Skin
General-Moderate hazard. May be absorbed through skin. Experimental evidence of liver and kidney damage.
May defat skin. H1ghly imtating
Symptom-Nausea. vom1ting; skin irritation from liquid contact.
Sbort Expo~~ure Tolerance-Prolonged inhalation of 100 ppm has produced liver damage in experimental animals.
Expo~~ure Procedure:s-Wash contaminated skin with copioos amounts of water. Irrigate eyes with watiBf for at
least 15 minutes
REACTIVITY DATA
Stability-Stable
Compatlbility-\bterial: Compatible with all common metals except copper and copper alloys.
Carso: Group 10 of compatibility chart.

Wear rubber gloves, safety glasses, protective clothing. Avoid contact with liquid. Secure ignition sources.
Scoop up, add alcohol and burn in a safe place outside.
If a apW oceun. call tbe National Reaponae Cater, II00-4l4-8802.

Remarks: Vapor Pressure: 3.7 mmHg at 25"C.
119
DIOCTYL PHTHALATE
s,_.,__ Dl-(2-ethylhexy!Jphthalate: DOP: United Nations Number ...
bis{2-Ethylhaxyl)phthalate; Octoil; Phthalic acid,
bis(2-ethylhexyl}ester
CHRIS Code ..
__awrc ~F
~r-Colorless oily liquid; mild odor. c "F
Freeztna; Point .. -55"C -87'F
Spednc GI'Dity~.99
c ___F
Vapor Pra.ure lO'C (68'F) (mmH&) .. _J!JU_
Chellliad F...Uy-Ester Reid Vapor Prellwre ((11..) ... ___l.!M__.
Vapor Prea.re 46"C (ll!i'F) (pei-.J .. -Y...L<mc
Polhatfo. Cateaorr-USEPA - - - IMO ___JJL_ Vapor Density (Air = 1.0) .. ,..ll&_
AppUe.bh Bulk Rea. 46 CFR Subdlapter ....... _JL_ Solubility Ia Water .. lnSQiyble

Gnde-E; Combustible liquid
Electrical Groap-0
GeaeraJ-SIIght hazard, when exposed to heat or flame.
Flab Poiat ("F) .. 425

Flammable Uadb .. Unavailable
Autolpldu. Tep. ('F) .. 770
Extblpldlllll Aenta .. carbon dioxide, cky chemical, foam, water spray
SpedaJ Fire Proeectura .. Water or foam may cause frothing. Do not direct water directly into fire. u..
water to keep lire exposed containers cool.
HEALTH HAZARD DATA

Hellltb Hazanl Ratinp Odor Tlrorelhold (ppm) PELITW A (ppm) TLV /TWA (ppm)
Geaeral-Suspected carcinogen. Produces no ill effects at normal temperatures but may give off irritating
vapors at high temperatures.
S)'lllptoma-After repeated exposures to skin, liquid causes reddening and scaling of the skin.
Sbort Expopn: Toleruee-Unavailable
Expo~~~reProeedura-Skln contact-wash affected parts as soon as possible. Eye contact-flood aye gently
with clean water. Continue washing lor at least 15 minutes.
REACfiVITY DATA
Stalilllty-Stable.
Co.patlbiUty-Miterlal: usual materials of construction are suitable.
Carje: Group 34 of compatibility chart.

If 1 IJIW ocewa. eaU tbe National Rapoue Center, 800-4:M-880:Z.

ReiiW'b: :t: UnaSSigned
120
14-DIOXANE
s,..,., ___ Diethylene dioxide; 1 ,4-0iethylenedloxlda; Ullited N.u- N..................................... .....11A5....
Diethylene ether, Diethylene oxlda; Dloxan;
Dioxane; p.-Dioxane; Glycol ethylene ether
CHRIS Code .. ....................... .Jl!l.L
BoWq; Polat -c ____w"F

................ __jjU
o\... acm Odu Clear liquid; mMd, alcoholic odor c 'F
Freab1a Pomt ...................... =::iic 51'F
Spedlk Grftlty-1.04 at 20'/20'C ___c ---
V.,or rr-.t lO'C (68'P) <-HI) .......... ___:l]_
c::a..kal Faally--Cycllc ether Reid Vapor rr--e (Jila.) ........................... ~
VllpOI' ~ -M'C (115"F) (JIU)............. ___l.L_
Pelbltlaa Catepey-USEPA _____a_ IMO ____..C__ Vapor o-ltJ (Air = LO) ........................... __JJL__
. _ .......... CFR ................. _Q_ SoblbiHty Ill Wlltler ......................... Cgmpltle
--
Gnde-C: Fll.rnmable liquid
Jl1ah Pobll ('F') ....

"--We u.J.tl .....
Alltolpltlon r-.. <'F> ..
Geaenl-When anhydroua, forms explosive peroxides with air. DanQ8rOUS, when expo88d to heat or flame.
Flashback along vapor trail may occur. Vapor may explode if ignHed In an encloeed area. Toxic vapor~ .,.
generated when heated.
54 (cc); 74 (TOC)
2 to 22%
356
Estbtpillaiq .qe.u ..... CO,, dry chemical, alcohol foam
s,.w Fire Proeedlnl .. .......... Wear goggles, seU-contalned breathing apparatua and rubber overclott'llng.
Water may be ineffective on fire.
HEALTH HAZARD DATA

Health Huard bliql
1, 1, 3
""",.,....._
620 mg/m'"
PEVI'WA-
25/Sidn 25/Skln
n.vll'WA c,.)
Goenl-Suspectecl caroinogen. Vapor has poor warning properties and can be inhaled In amount8 which may
cause serious intoxication or death with injury of liver and kidneys. Liquid can be abaorbed through ekln In
sufficient quantities to produce injury.
S,.,co--tnitation to eyes, nose and throat (300 ppm)
Short h.-we T~OO ppm for 15 minutes cause mild irritation.
Ex~ I\ I For eye or skin oontact-flulh with water tor 15 minutes and remove any contaminated
clothing. Obtain medical care it exposed to high vapor concentration.
NOTE: Detectable odor Ia ""-ter than the TLV. Exposure to potentially dangerous vapor concentratiOns can
occur before the vapor Ill detected by smelt.
REACI'IVITY DATA
StllbWtJ-Stable, no polymerization: forms peroxide& with air, lhould be padded with nitrogen.
eo.,.dbWt,.-Mster:lal: Carbon steel recommended. Copper and copper alloyS may cause sight
dlscoiorizatlon.
Cuao: Group 41 ol oornpatibltity chart.

Wear rubber gloves, face shield, protective clothing. Have aii1)Urpose canister muk available. Secure ignition
sourcn. Small spills may be fluahed away with watef.
U a .,W oee.n, ca11111e Nal:loul ..,._. c.ter, I00-4l4 810l,
121
DIPHENYLDIPHENYL ETHER MIXTURE
s,_,__. Blphenykilphenyl ether mixture; United NM:Iou Number ......
Dlphenyl-dlphenyl oxide mixture: Oiphenyl
Cdde-diphenyl mixture; Dowtherm A: Phenyl
ether-biphenyl mixture
CHRIS Code ..
~sH1oO
~c ---..ill"F
A,......_.odor-traw colOr liquid; phenol-like odor c 'F
Freezlq: PoUlt ..... ~-c~F
s,.dftc C...ritJ-1.07
___ c ___.F
Vapor ~ lO'C (WFJ UmnHi) .. ..Y....l.mL
~ Fuatly-Ether Reid Vapor Preuure (JIIIa)... .....J.a.._
Vapor~ 441'C (115'F') (pda)... ~
Po1ldGa c.teeorJ-USEPA - - - IMO ___A._
A,.uawe Balk Rea. 441 CFR S.bcbapter ....... ~
v.,., ne.lty <AU = J.O)...
SoJaWiity Ia Water..
................ ~
Negligible
FIRE lo EXPLOSION HAZARD DATA

GrMe-E: Combustible liquid
,_...G...,....O
GeMni-Moderate hazard, when exposed to heat or flame. Irritating vapors generated when heated.
PlMk Poia.t rF.l .. . 255

~u.ttl .... 0.8 to 3.3% at 300'F
AalcHpltloa r-.. rFl .. 1150
Es~Apaa ... GOa. dry chemical, water fog and loam
Special Fin Prvcedaret .. . Wear self-contained breathing apparatus.
....... .._. ....... HEALTH HAZARD DATA

Odor l'hrelltold (ppm) PEL/I'WA (ppm)
Unavailable
nv/IWA (ppm)
Unavailable
-
1, 1, 1 1
GeMni-Skin Irritation Of more or 1888 mild degree may be expected only from prolonQ&d and repeated
S~lnhalatlon-eye or respiratory irritation. Skin contact-reddening, slight irritation.
Sllort l:x)IOIID'e Toluaace--Unavailable
~ ~vapor-remove victim to freSh air; If breathing stops, apply artificial respiration. Sll:in or
eye contact-remove contaminated clothing and gently flush with water.
REACTIVITY DATA
8abftlty-Very stable.
O....uwnt:J-MaterW: Usual materials of construction are suitable.
Carao: Group 33 of compatibiNty chart.

Wear rubber gloves. face shield, full protectiVe clothing. Secure Ignition sources. Small spills may be flushed
away with water.
If ~.,W _ocean, call tbe Natlmaal R........ CmteT, M-424-8802
122
DIPHENYLMETHANE DIISOCYANATE
5)'11011)'11111- 4,4-Diisocyanodiphenylmethane; United Nlltlon1 Number ...
4,4'-Diphenylmethane diisocyanate;
Diphenylmethane-4,4'-diisocyanate; MDI; Methylene
bis(4-phenyi rsocyanate); Methylene
bis-phenylisocyanate CHRIS Code ....
Formula-(OCNC.H,).CH,
BoiiiK Point .. Decomposes ~c -----Z3'F
Appurance-Odor-LIQhl yellow solid (at room c 'F
temp&Jature) or molten liquid; slightly musty odor Freezin& Point.. ~c __iS!'F
Speclfk Gravity-1.19 at 77'F (25"C)
___ c ___"F
Vapor Preaure lO'C (68'F) (llunHI).. ~
Cbemical F&~~~ily-lsocyanate Reid Vapor Preuure (plia)... ..Y.....I.mt...
Vapor PreaiU'e 46'C (115'F) (p~~la).. Jl....l2tL
Pollution CaltKor)-USEPA - - - IMO ~ Vapor Demllty (Air = 1,0)... . -A.L
Applicable Bulk Rtg. 46 Ct'R Sulxhapter .. . ____Q__ SolubiUty In Water ...

Grade-E Combustrble
..:Jedrinl (Oroup---NA
Genellli-Light yellow solid. Flammable at high temperatures. Toxic vapors of carbon monoxide, oxides Of
n1trQ9en. hydrogen cyanide are generated when heated. Fire may cause polymerization and decomposition
lead1ng to v1olent rupture of contatners or tanks.
f-lash P<>int (Ft 374
f1amm11hlf l.imils Unavailable
Autoignition fcmp. (F) 465
Extin~tuishinjt A~trnts Water spray, CO., dry chemical, water spray.
Special fo'ire Prt~el'dures Wear self-contained breathing apparatus ancf protective clothing. Cool
exposed tanks wtth water.
HEALTH HAZARD DATA

Health HUIIrd Ratings Odor Threshold (ppm) PEL!IWA (ppm) TLV!IWA (ppm)
3. 2, 4 Unavailable 0.01 0.005
General-Vapor is strong irritant to eyes and throat; can cause eye and lung injury. Cannot be tolerated even at
low concentrations.
Symptoms-Watering Of reddening of eyes, diarrhea, and loss of weight. Breathlessness, chest discomfort, and
reduced pulmonary function.
Short Exposure Tolei'1Uice-Animal tests have shown slight eye damage in 50% solution: oral lethal dose is In
excess of 21.6 g/kg of body weight; no primary skin irritation; no deaths by inhalation in 5-6 hours.
Exposure Procedur-Vapor-remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or
eye contact-remove contaminated clothing and immediately flush affected areas with water for 15 minutes.
Gall a doctor.
REACTIVITY DATA
Stability-Material must be blanketed with dry nitrogen; unstable in traces of moisture, slowly forming carbon
dioxide gas
Compatibility-Material: Do not have in direct contact with wood.
Car11o: Group 12 of compatibility chart.

Wear rubber gloves, face shield, protective clothing and self-contained breathing apparatus. Avoid contact
If a spill occurs. call die NatioDal. RttpoDH: Ceater, 800-4l4-880l.
Remarks: Negltgtble; reacts slowly.
123
Dln-PROPYLAMINE
SyiiOII)'--Oipropylamioe; OPA; 1-Propanamine, United NatloiUI Number ....
N-propyl-
CHRIS Code ..
Bollin& Poillt.. ------...12Z'C ~F

Apparuce-Oior-Color1ess liquid; pungent c 'F
ammoniacal odor Freezina Point.. ~83'C -Sl'F
Spedftc: Gra,ity-0.74 ___ c ___ "F
V1por Pre.ure :ZO'C (68'F) (mmH&) .. _2.Q._

a.e.at Famii)'-Amines Reid VllpOJ' Pre..ure (plla)... ~
VllpOJ' Preaure 46'C (115'F) (p~~la).. ~
PoUutloa. C.tqory-USEPA _____Q__ IMO __Q__ Vapor Deuity (Air = I.OJ.. ~
Appliable BWk Rea. 46 CFR Subc:lulpter ....... ____Q___ SoJublllty Ia Water.. 2 5% by wejght

_G.......,
General-Dangerous when exposed to heat ot llama. Flashback along vapor trail may occur. Vapor may
explode if ignited In an enclosed area.
Flub Polnt ('FJ .. 63

F'lulalabte Ultl .. Unavailable
Autolpltbm Tep. ('F) .. Unavailable
Estblpbldq; AaeaU .. Foam, COa, dry chemical
S,ecial F1re Pn:leed~~n~ .. Wear self-contained breathing apparatus and protective clothing.
HEALTH HAZARD DATA

Heal.tt. lbzvd lbt:IIIP Odor 'I'hre.bold (Jipm) PELJTW A (ppm) TLV!TWA (ppm)
Unavailable 0.01 to O.t Unavailable Unavailable
General-Toxic, noxious.
S)'llllpto--Skin bums, eye damage (permanent). Inhalation: pulmonary edema. Ingestion: alkaline burns, death.
Sltort E.JIOIIIU"e Tolerance-Inhalation: 1000 ppm produces severe irritation of respiratOf'Y tract and lungs, with
possible pulmonary edema.
Procedllret-Get medical attention. Inhalation: Remove to fresh air, administer oxygen if needed. Skin,
Ezpollll'e
eye contact: Flush with water for at least 15 minutes.
REACTIVITY DATA
StabWty-Stable. Reacts with acids.
Com,.dbWty-Material: Dissolves paint and most plastics; swells rubber. Suitable: Carbon steel, stainless steel.
Unsuitable: Copper, zinc, brass, bronze, aluminum, magnesium.
Carzo: Group 7 on compatibility chart

Avoid contact. Wear selfcontaioed breathing apparatus, lace shield, protective clothing. Wash clothing
thoroughly before reuse. For small spills, flush area with water spray. Secure ignition sources.
If a .,W oecllrl, c:aU t1te National Re1p011M Center, ~

....
124
DIPROPYLENE GLYCOL
SJilODY-- 2,2-Dihydroxydipropyl ether; Uaited NadOM N...,___
2,2' -Dihydroxyiaopropyl ether; 1,1 '..Qxydl-2-propanol
CHRIS Co4e ..
Fon11ala-(CHoCHOHCH.)..O
BeiUqPoblt.. . ....... __mc ~F
A,..earuce-Odor-Colorless, slightly viscous liquid: c 'F
odo,... Freez1q PobiC .... ,.. JUjijiCOOjlc = = F
Specific Grulty-1.03 ___ c ---
vapor~ :zoc CA'F> <-Ill> ~
Chemkal Faadly-Giycot ether Re6d Vapor rr-n, (pils) ~
PGitutioll eatqory-USEPA - - - IMO ____w__

v.,.. Prwwe 46'C (ll!I'P) (IIIia)...
Vapor De.lty (Ab' = 1,0)
.J.QL
...... ~
Applkable Bulk Rea, 46 CFR S.llcbapter ........ ____Q__ SotabUIIy 111 w.aer... ..................... Cgmpltlt
FIRE I< EXPWSION HAZARD DATA

-Groap-C
GeneraJ-SIIght hazard when exposed to heat or flame.
Flub Poiat ('F) .. 280

F1llllliUble UmJtl .. LEL=2.2% UEL-unavaitable
Autoipld011 Tep. ('F) .. Unavailable
Edlnpla!llna Apab ... Water, COa. dry ctlamlcal, alcohol foam
Speclal Fire Proudun11 . . Water or foam may cause frothing.
HEALTH HAZARD DATA

Health Huard Radap Odor 'lllraltold (Jifm) PEL/TWA~) nvnwA<..->
General-Not considered toxic under ordinary conditions of handling.
Sympto11111-Minor eye irritant.
Short E~:po~~ure Tolenuw:~navailable.
E~:ponreProcedures-Skin or eye contact-remove contaminated clothing and gently flush with water for 15
minutes. Get medical advice for eye contact.
REACI1VITY DATA
Stability-Stable.
Comp~~tlbUity-Mata'W: Usual materials of construction are suitable.

If a .,W OCCIII'It call tile Nadoul ........ C.W, IIOB-4l4 1102.

Remarlu: +UnaSSigned
125
DODECENE
s,._,_ alpha-Oodecylene; Propylene tetramer: United Natiou Number ....
Tetrapropylene
CHRIS Code ..
BoUiq Point .. ----.2.13'C ~F

Appearuee-Odor-CoOf'less liquid; pleasant odor ___ c ---
Freezing Point .. --=..azc ~F
Speeltlc Gra.tl)'-0.76 c ---
Vapor Prellu~ lO'C (68'F) CllllllHc> ..
Reid Vapor Pre.ure ((lll8J .. ....Jl.l!1.._
Vapor l"relwre 46'C (115'F) ((111.1) .. ..J!.l!L
PoUutlon Catqory-USEPA - - - IMO _fl._ V11p0r Deul:ty CAir = 1,0)... _lll_
AppUe~bte Bulk Rea. 46 CFR Subc:bapter ...... --'LQ... SolubWty Ia Waler .. NM!jgjb!a

Grade-D; Combustible liquid
Electrical Group-O
Geaerai-Moderate fire hazard when exposed to heat.
Flub PoiDt ('F) .. 144

F1anunabJe UmJb: .. LEL=O.S% UEL-Unavailable
Auloqnttlon Temp. {'F) .. 400
EidiiiUillllna; Apata ... Carbon dioxide, dry chemical, or foam
Spec.lal Fire Procedures .. Cool exposed tanks with water. Water may be ineffective on fire.
HEALTH HAZARD DATA

Healtll Haunl Radap Odor 'Illrelhold (Jipm) PEL;TWA (Jipm) nvJTW A cppm>
1,1, 1 Unavailable Unavailable Unavailable
General-Vapor slightly irritating in high concentrations.
Sy...pto--Siight smarting of the eyes 01' respiratory system if present in high concentrations.
Sbort Expo~~~n Tole11lDCe-Unavailable
Es:IIO'Ilfe ProeediU"eS-Vapor-remove victim to fresh air. Skin or eye contact-remove contaminated clothing
and gently flush affected areas with water.
REACilVITY DATA
Stalillity-Stable. Can react with oxidizing materials.
CompatlbiUty-Materllll: usual materials ol construction are suitable.
Carso: Group 30 Of compatibility chart.

Avoid contact with liquid. Secure Ignition sources.
If I ipiU OC:etlnt ellll tbe Natioul Reapoue Cuter, IIOO-U4 11801,

Remarb: Vapor Pressure: 1 mmHg at 47.2'C.
:t Unassigned
126
DODECYLBENZENE
SynonyiQ-Aikylbenzene: Detergent alkylate #2: United Natioas Number ..
nDodecylbenzene; Laury!benzene:
1-Phenyldodecane
CHRIS Code
Formula-C,,H~.4H,
Bollin& Point.. ~c ~~F
Appeara~~ee-Odor-Water-white liQuid: kerosene-like ___ c ___F
odo Freezing Point.. _ _ _4"C ~F
Spedflc Gravity-0.86 c ___ 'F
Vapor Praaure 20'C (68'F) (mmHt)... ____QJU_
Chemical Family-Aromatic hydrocarbons Reid Vapor Pre.ure (peia)..... --4.L
V.por Pres&&tn' 46'C (115'F) (p~~lal.. ____.!.L_
Pollution Cate11ory-USEPA - - - IMO ___l!L_ Vapor Detllalty (Air = 1.0). . ........... ~
Appliuble Bulk Reg. 46 CFR Subchapter.. _____Q__ Solubility 1ft Water.. Negljgjblo

Gradl'-E CombuStible liquid.
Eleoctrinl (;ruup-0
<rion~nU-CO and CO, fumes produced on combustion.
Flub Point (t-1 235

f.lmmble l.imits unavailable
.~utui~~:nitionTemp. t'll Unavailable
J,:uinguisbinK .4..ents Confined aFea-CO,, dry chemicaL Open area-foam, water spray.
SP'I'"Cial Fin PrDCfllurn Water or foam may cause frothing.
HEALTH HAZARD DATA

Health Huard Ratings 04or Threshold {ppm) PEL/TWA {ppm) TLV /TWA {ppm)
0. 0, 0 Unavailable Unavailable Unavailable
General-Very low tOXICity
Symptoms-Very low toxtcity.
Short Exposure Toleran~e-Very low toxicity.
Exposure Procedures-Sk"tn contact-wash well with soap and water. Eye contact-flush with potable water.
REACfiVITY DATA
Stability-Stable
Compatibilit)-:\lattrial: Usual materials of construction are suitable.
CU"go: Group 32 of compatibility chart.

Avoid contact wtth liQuid.
If a 1pill Dlln, eaU the National R.,uue Cealer, 11011-424-81102.
127
DODECYL PHENOL
Sy_,....._ No common aynonyms.
CHRIS Code ..
Boffin& PoJat .. ~-c~F

Appearaaee-Odor-Straw colored liquid; phenolic odor c 'F
Freul111 Point. __j'C ==F
Spedftc Gnlty--0.90 to 0.99 c ---
Vapor ~re ZO"C (68"F) (mm~ .. __!__
Cbll!ldeal Famlly-Phenola Reid V1por f"ns~W'e (p!lla) ... __!__
Vapor Pre.u.re 46'C (115'F) ill'lal .. __!__
Polludoll Catqory-USEPA - - - IMO ......A_ Vapor Deulty (Air = 1.0) .. _Mi._
Applkable &.llr. Rea. 46 CFR Subdulpter ....... ---'L_ Solubility In W1ter .. ln!IQiub!

Gr.de-E: Combustible liquid
Eleetric:al Gro~D
Geaeral-Siighl fire hazard when exposed to heat or flame: decomposes when heated yielding toxic products.
Flab PoiDt ('F).. 325

Flanunahle Umltl .. Unavailable
AtoftnJtion Temp. ('F) .... Unavailable
ElltiftllliMiq Apab .. CO., dry chemical, alcohol foam, water log
SpedaJ Fire Prooeduret .... Waat self-contained breathing apparatus. Water can cause frothing.
HEALTH HAZARD DATA

Healda HuanllbUDP Odor lbreebohl (ppm) PEL!TW A {ppm! TL V1TWA (ppm!
Unavailable Unavailable Unavalable Unavailable
Geaenli-Moderately toxic, highly irritating.
Sylllpt-lngestion: Burning pain in mouth and throat, abdominal pain, vomiting, diarrhea, weakness,
dizziness. Corrodes digestive tract Inhalation: Irritation, bronchitis, pnetJmonia. Skin: irritation, pain
SIMirt EI:)IOIW'e Toleruc:e-
El:ponrt l'rvcreftra-Get medical attention. Ingestion: Drink water or milk, swallow activated charcoal or castor
oN. Inhalation: Remove to fresh air. Skin contact: Wash twice with soap and water. Eye contact: Flush with
water lor at least 15 minutes.
REACTIVITY DATA
SlaiNUty-Generally stable but decomposes when heated forming toxic products. Reacts with oxidizing
materials.
Compat:lbJIItJ-Material:
Carjo: Group 21 of compatibility chart.

Avoid contact Wear protectivt! clothing and lace shield. If spill is heated or burning, wear seH-contained
breathing apparatus. Material is a serious pollution hazard.
,...
If a lptU oeeun, call the Nat:IOIW llelponte <:eater, 800-424 8802.
Remarlu: t UnavaJiable
128
EPICHLOROHYDRIN
Synony~~t~- 1-Chloro-2,3-epoxypropane;
3-Chloro-1 ,2-epoxypropane; ChloromethyloKirane;
2-Chloropropylene OXide: gamma-Chloropropylane
OKide; O>drane, (chloromethyl)-; Propane,
1-chloro-2,3-epo~ey CHRIS Code ..
ro-J
Formullt-CH,CHCH1 CI __ll"C ~F
BoUbl1 Pobll ..
Ap~IOfless liquid; chloroform-like, c "F
_ _ c -=7a'F
sweetish odor FTeeziq PoiDt .... -SB'C
_ _ _F
Speeltlc Graflty-1.18
Vapol' Prt.a!IIJ'e lO'C (68'F) (mmHI) .. _.Ill...
Cbemlcal F...Uiy-Eplchlorohydrin
Pollution Cateaory-USEPA _____a__ IMO _.Q__

Vapor Preleure 46'C (115'F) (pila) ..
Vapor Deuity (Air = 1.0) ..
-=-
Reid Vapw Prsnre (plia).........................
__..!.L
...... __j.JL_
Appllable Bu1k Rea. 46 CFR Subchapter ....... ____Q__ SolubiUty ID Water .. 8%

Electrlc:al Group-C
General-One of the products of combustion is hydrochloric acid gas, which Is both toxic and corrosive. Ignited
by heat and open flame. This product can decompose to form highly toxic phosgene gas.
FiuJI Point ('Fl .. 105

Fh.mmable L1111its .. 3.810 21%
Autolgnitlon Temp. ("F) ... 804
ExtinauJshinl Agentl .. co., dry chemical, alcohol foam, water log.
Specl1l Ftre Proeedurn .. Keep exposed tank cool with water spray. Provide respiratory and body
protection to firefighting personnel.
HEALTH HAZARD DATA

HeaJth HIIZIIrd Rstinp Odor Thnshold
(ppm) PEL/IW A (ppm) 1LV 11WA (ppla)
3, 3, 4 10 to 25 2/Skln 2/Sidn
General-suspected carcinogen. Vapor extremely irritating. Lung injury may be delayed. Liquid causes severe
burns; absorbed by leather and causes delayed bums. Class B polson.
Symptoms-The liquid blisters skin on contact. The vapor causes eye and respiratory irritation. It may also
cause vomiting, convulsions, rapid pulse, and respiratory paralysis.
Short Expo~~ure Tolel"lllee-Concentrations exceeding 40 ppm rapidly produce IITitation to nose and eyes.
E-.:poaure Procedures--Vapor-remove victim to fresh air; if breathing stops, apply artificial respinltion. Skin or
REACfiVITY DATA
Stlbillty-Stable under usual handling conditions. However, n will polymerize at elevated temperatures or in the
presence of certain catalysts; acids, alkalies and metallic halides are known to be effective catalysts for
polymerization and should be avoided.
Compadbillty-Msterlal: Usually carried in steel tanks; however, the wet prod!Jct will pit steel.
Cup: Group 17 of compatibility chart.

Wear rubber gloves, seH-contained breathing apparatus, protective Clothing. Evacuate personnel not equipped
with protective clothing and respiratory protection. Secure ignition sources.
If 1 tpW ocaan, Clll die N1tloal. RelpHM Center, 800-424 8802.
ReiiUU"kl:
129
ETHANE
S)'Jioa)'lllf- Blmethy1; Dimethyl; Ethyl hydride; United Natio"' Number .. refrigerated
Methylmethane compressed
CHRIS Code ..
- ~c
Bolllq Point.. -=.1.2'F
Appearuee.Odor-Cior1ess gas, colorless liquid:
_ _ c 'F
speanc: GraTit)'-0.45 (liquid)

_____:;jQ'C
___ c -=mF
_ _ _ 'F
Vapor Preaure lO'C (61'FJ <mHs> .. -'L..Jjjgh_

C...kaJ Family-Saturated hydrocarbon ReJd Vapor Prea11re (,.ta) .. -'L..Jjjgh_
Vapor Prea11re 4Ci'C Ut!I'F) (pljaJ .. -'L..Jjjgh_
PolbttiH C.teaory-USEPA - - - IMO ___gu_ Vapor DeDiily (AJr = 1.0) ... --l.llL
AppllcQ1e Btalk Rea. 445 CFR S.bcbapter ....... ---'2....Q_ Solabtllt)' In Water .. !ren!"b!'

Eleetrleal Group-O
Gaeni-Dangerous, when 8Xp08ec:l to heat or flame. Unless the flow of gas can be stopped, extinguishing a
lire will permit accumulation of an explosive concentration ol vapor, and subsequent explosion or re-flash.
Flail Poiat ('F) . -211

Plammahlt Umtts ... 3 to 12.5%
Atlloipjtlon Temp. ('F) .. 959
Extinpil.blq Asentl .... Stop flow of gas: CO., dry chemical
SpecJal F1re Prucedure. Shut off gas supply, then use dry chemical or CO,. Tanks exposed to fire
should be kept cool with a continuous spray of water.
HEALTH HAZARD DATA

Heald! Haanl Ratiap Odor 'Illrahold (ppm) PEL/TWA (ppm) TLV!TWA (pPIII)
Unavailable
Unavailable Unavailable
Gealnii-Simpla asphyxiant. Breathing vapor may cause unconsciousness without warning because of lack of
oxygen. Contact with liquid will cause frostbite.
S:r~lnhalation-haadache, dizziness, drowsiness. Skin contact-frostbite.
Sltort ~re T~sure of guinea piga to concentrations of from 4.7 to 5.5% for 2 hoors caused
only slight drowsiness and Irregular respiration.
Exposare Proced-Vapor-remove to fresh air; if breathing stops, apply artificial respiration. If the liquid has
spUied onto the skin, points of contact may be frostbitten; handle gently and protect from mechanical
REACTIVITY DATA
St.bWty-Stable.
Comp.ttbllit)'-Material: Noncorrosive

Wear rubber gloves, face shield, protective clothing. Have all-purpose canister respirator available. liquid will
evaporate rapidly. Secure all possible sources of ignition.
H 1 IJIIU oceun, tall the Nadoul lleepoue Center, 800-414 8801.

Remark~:
130
ETHANOLAMINE
S)'-)'1111-Aminoethanol; 2-Aminoethanol:
beta-Aminoethyl alcohol; Colamine: Ethylolamine;
2-Hydrmcethylamine: beta-Hydroxethylamine;
Moooethanolamine
CHRIS Code ..
Formula-HOCH,CH 2 NH,
Bolllna Point.. -----.ll2'C ~F
Appearanee-Odor-CoiOJiess liquid; ammonia-like odor c 'F
FreezJq PcNnt.. ___l.O'C ____;Q'F
Speclfk Gra:rity-1.02 ___ c ---
Vapor PreaKre lO'C (61'F) <-HI).. --'l.!_
a.e.leal Family-Amine Reid V1por PreiiUn (pda)... ... ~
Vapor Preu~~re 46'C (115'F) (pila).. __QJQ_
Polluti011 C.tqory-USEPA - - - IMO _____Q__ Vapor Deu.lty (Alr = 1.0).. ..................... .....2.J.L
Applk:llble Bulk Res. 46 CFR Subdlropter ....... ____Q__ Solubility Ia w.._.. Cgmp!ttt

Eledrical Group-O
Generlli-Moderate hazard, when exposed to heat or flame. Irritating vapoi'S generated when heated.
F1ub Point ('F). 200

Flammable Limits .. Unavailable
Autoipition Temp. ('F) .. greater than 500
Extinguishing Agents .. C~. dry chemical, alcohol loam, water log
Special Fire ProcedurH .. Respiratory and body protection should be wom by lire parties.
HEALTH HAZARD DATA

Health Hazard Ratinp Odor Tbretbold (ppm) PEL/TWA (ppm) TI.VIlWA q,p.)
General-Liquid contact causes severe eye irritation. Vapor inhalation causes respiratory irritation.
Symptoms-Respiratory irritation will range from itching to severe burning depending upon concentration.
Short Exposure Tolerance-50 ppm lor 30 minutes
Expoaure Proc:edure.-Vapor--remove victim to fresh air; if breathing stops, apply artificial respiration. Oxygen,
administered by trained personnel, is often helpful. Skin or eye contact-remove contaminated clothing and
gently flush affected areas with water for 15 minutes. Get medical advice or attention.
REACTIVITY DATA
StahiUty-11 will oxidize in the presence of air, so is often shipped under a pad of inert gas. Ethanolamine is a
reactive material combining chemically with many other substances.
Compatibility-Material: Corrosive to copper and its alloys; also attacks rubber.
Cargo: Group a of compatibility chart.

Wear butyl rubber gloves, face shield or allpurpose canister respirator, protective clothing. AvOid contact with
liquid. Cover spill with sodium bisulfate. Wash with excess of water.
If a lpJII oc:atn. call tile Nano.al an,_ Center, 800-4l4-11Ql,

Remarks!
131
ETHOXY TRIGL YCOL
S y _ , _ 2(2(2-EthyoxyethOKY)ethOJtY]Bihanol; United Nadon. Number...
-
Ethyoxytriethylene glycol: Trlethylene glycol ethyl
ether; Triglycol ethyl ether: Triglycol moooethyl
CHRIS Code ..
Bolllna Point . ____ruc _____ru'F

AppeiJ'IUICeOdot-Colorless and practically odorless
_ _ c 'F
Freezlna Point .. --=..ll!'C - 'F
___ c _ _ _ 'F
Vapor Preuure lO'C (68'FJ l111mHI) .. __Q,QL,_
CHmk:aJ Family-Glycol ether Reid Vapor Preaure (p~~la) ... ..l..l.Jmc
Vapor Pressure 46'C (t15'FJ (,_taJ .. ~
PoUultoa C.tqory-USEPA - - - IMO --'L_ Vapor Oen1ity (Air = 1,6)... ....uL
ApplieaWe Blllk Rea. 46 CFR Subdqpter ....... __Q__ Solubility 111 Water .. Cpmp!tte

Gnule-E: Combustible liquid
Elettrieal Group-C
General-Slight fire hazard, when exposed to heat or flame.
Flub Point ('FJ ... 275

FJ...nu~ble u ..tu .. Unavailable
AutoJpjtto. Temp. I'FJ .. Unavailable
Eztb1plahlaa Alftlb ... Carbon dioxide, dry chemical, alcohol foam
Special Fin: Proeedllfel .. Water and loam may be ineffective on fire. Cool exposed tanks with water.
HEALTH HAZARD DATA

Health Huard R.ldap Oclor lbrahold (pp~~~) PELJTWA (ppm) TLVITWA(PP!ft)
Geaerai-Under ordinary conditions of handling, not considered toxic.
Sym...-No appreciable hazard in ordinary handling or use.
Short Exponre Toleruee-Not pertinent.
Expo~ure Procedaret-Eye contact-flush gently with water.
REACTIVITY DATA
Stalrillty-Stable.
C:0.p8ti1HIIty-M..teriaJ: Usual materials of construction are suitable.

If a spJII &ecllrt. eaJI tlie National Rnpoue Center, IIJ0....4l4-8802,

Rnnarb: ~ UnasSIQned
132
ETHYL ACETATE
Synooynu- Acetic acid, ethyl ester: AcetiC ester; Acetic
ether; Ethyl ethanoate: Vinegar naphtha
CHRIS Code ..
BoUina Point .. ___ll:C _____lll'F

Appearai)Ce-Odor-Colorless liquid; pteasant, fruity odor c 'F
Freez.lq Potat .. -----:a3c -117"F
c ___F
Speciflc Gra~ity-0.90
Vapor Preuure lO'C (68'F) (mmHK) ..

Chemiul Family-Ester Reid Vapor Preuun (plia)....
Vapor Pre.ure 46'C (115'F) (pill!) ..
Pollution CateFry-USEPA _____Q_ IMO _____Q_ Vapol" Delll:lty (Ai:r = 1.0) ...
Applicable Bulk Rea. 46 CFR Subcbapter ....... _____Q_ Solu"lllty In Water ..

Electrical Group-O
General-Ethyl acetate is highly flammable and its vapors form explosive mixtures with air. Flashback along
vapor trail may occur. Vapor may explode if ignited in an enclosed area.
J<l115h Point ('F) . 24 (cc)

Flammable Limitl .. 2.21011.5%
Autoignitlon Temp. tF). 800
Elltlnguishing A11ents co.,
alcohol loam, water log, dry chemical
Special Fire Procedures .. Use of dry chemical Wh8fe it can get into a tank of ethyl acetate is not
recommended. Fire involving spills 01.1tside of tanks can be extinguished with dry chemical.
HEALTH HAZARD DATA

Health Hamrd Ratinas Odor Threshold (ppm) PELJTW A (ppm) TLV .trW A (pjNDl
1. 1, 2 100 400 400
General-Vapor causes some irritation. Absorption is chiefly by inhalation. Continued skin cootact will d'y and
crack skin with chance of dermatitis and infection.
Symptoms-Headache, irritation of respiratory passages and eyes.
Short Exposure Tolerance-! 000 ppm tor 5 minutes.
Exposure Pro~:edures-Vapor-remove victim to fresh air; if breathing stops, apply artificial respiration. Skin 01"
eye contact-remove contaminated clothing and gently flush affected areas with water for 15 minutes. Gel
REACfiVITY DATA
Stability-Stable. Will hydrolize (react with water) on standing to form acetic acid and ethyl alcohol. This
reaction is greatly accelerated by bases (alkalies). Can react vigorously with oxidizing materials.
Comp~~tibllity-Material: Softens and dissolves rubber and many plastics.
Cargo: Group 34 Of compatibility chart.

Wear rubber gloves, face shield, protective clothing. Have all-p~,~rpose canister mask available. Avoid contact
U 'Pill occura, call the National Raponte Ceater, 800-4~2.
Remarks: Vapor Pressure: 100 mmHg at 27"C.
133
ETHYL ACRYLATE
s,._,._._Acry1ic acid, ethyl ester, Ethyl propenoate; United NtJo1111 Number.. ..
Ethyl 2-propenoate; 2-Propenoic acid, ethyl ester
CHRIS Code ..
Bomaa Polat.. ..
c ___.,
____.illc _____ruF
Appeuam:e.Odor-lotless liquid; pungent odol'
Specific: Gra'fity-0.93
Freezing Poiat.. .
c ___.,
-39'C ----=..1.Qa'F
Vapor Prasure lO'C (68'F') (DIIa.H&) .. ___2U_

Cbemleal Funily-Acrylates Reid Vapor Pre.ure (p!UI) ... _LL.
Vapor Preuure 46'C (115'F) (plla) ... _ZJL_
PoUut1011 Catepry-USEPA _____D__ IMO ____A__ Vapor Deulty (AI:r = 1,0) .. ____a.;_
Appl~e Blllk Rea. 4Ci CFR Subchapter ...... ____Q._ SolubiUty ill Water .. 15%

Electrical Group-O
General-Ignited by heat, sparks 01' open flame. Flashback along vapor trail may occur. Vapor may explode if
Ignited in an enclosed area. Fire may cause violent rupture of tank. Toxic and irritating vapors generated
when heated.
Flail Potnt C'FJ .. SO(oc); 4S'F (TCC)
Flammable Umlb .. 1.8 to 9.5% (calculated)
Auto(Jnjtlon Temp. ('F) .. 700
E:r.tlnplllldq Aatats .. COa, dry chemical, water log, alcohol loam
Spedal Fire ProeediU'el .. Keep tank cool with a water spray to prevent polymerization. Wear chemical
protective clothing, eye protection and self-contained breathing apparatus.
HEALTH HAZARD DATA

Heald! Huard Radqp Oclor ThreAold. (ppm) PEL/TWA (ppm) TLV /TWA (ppm)
3, 2, 3 0.00047 5/Skin 5
Ge.eral-Suspected carcinogen. Vapor Irritating.
Symptom1-Eye and throat irritation, shortness of breath, and convulsions.
Sllort Expo~ure Tolerance-50 ppm for 15 minutes. 2000 ppm vapor killed rats in 4 hours with death attributable
to severe pulmonary irritation.
EJ:poiiU"e Proced.uret-Vapor-remove viCtim to fresh air; if breathing stops, apply artificial respiration. Skin or
eye cootact-remove contaminated clothing and gently flush affected areas with water for 15 minutes. Get
REACTIVITY DATA
StabiUty-Will polymerize spontaneously if not Inhibited.
CompatibiUty-M..terial: Usual materials of construction are suitable.

If a qNU oecun, call tbe National Reapoue Center, 800-424-8802.

Reatarb:
134
ETHYL ALCOHOL
Synoa)'llll- AlcohOl; Alcohol Anhydrous: Alcohol C-2; Ualtecl NUiou NumNr ...
Cologne spirit; Denatured alcohol; Ethanol; Ethyl
hydroxide; Fermentation alcohol; Grain alcohol;
Methyl carbinol
CHRIS Code ..
Fonnula-C.HoOH
Bollia& Poiot .. _____lli'C ~F
A~or-Color1ess liqwd; smells like wine or c 'F
shellac thinner FreednaPolnt.. -114'C -l73'F
Spedlk Gra"rity-0.79
___ c ___F
Vapor Pl'eaure lO'C (68'F) (mH&).. ~
Cltemkal FD11ly-Aicohol Reid Vapol" Pl'ftlllre (ptla)... ---2.L..
va,.... r ....re46'C (115'F) (plia).... ~
Pollutioa C.tep~ry-USEPA - - - IMO __JJl_ Vapor ~ty (Air = 1.01.. ---l..L.
Apf:lkalde &.lk Jle&. 46 CFR Sllbdlapler ........ _____Q__ Solabillty in WilleT.. Comp!tta

Grde--C: Flammable liquid
Elec:trkal Gt-o.p--0
Genen.J-Oangerous when exposed to heat or flame. Flashback along vapor trail may occur. Vapor may
&Kplode il ignited in an enclosed area.
FlMll Poinl ('Fl 65

Flammable Lhnlb 3.3 to 19%
Anlolpdtlon Temp. ("F). 793
E11tinpiUina A1enb .. CO:., dry chemical, alcohol foam, water tog
Special fire Proudures .. Water may not be effective unless large quantities are used.
HEALTH HAZARD DATA

Healtb Huard Ratiap Odor TbreaboJd (ppm) PEL/TWA (ppm) TLVITWA (ppm)
1, 0, 1 10 1000 1000
Geneni-One of the least hazardous industrial organic solvents.
Sympto....-Dizziness, double vision, alld other classic alcohol intoxication symptoms. These may be
accompanied by symptoms such as Yomiting, attributable to the denaturant.
Short E:r.I"J'IIre Tolerance-5000-10,000 ppm irritates eyes alld upper respiratory tract stupor alld drOWSiness
may result after an hour at this concentration. More than 1000 ppm may cause headache and eye Irritation.
E:r.JIOIIIIft l"roeedurft-Vapor-remove Yictim lor fresh aif; if breathing stops, apply artificial respiration. Eye
contact-gently flush with walef lor 15 minutes. Get medical advice or attention.
REACTIVITY DATA
Stability-Stable.
Com)Nitlblllty-Mterial: Usual materials of construction are suitable.

Secure ignition sources. Spills may be flushed away wittl water, but should not be flushed into a confined
space because of the exploeioo hazard.
If 1piU oceurs, eaU die Nltloul Rapoue Center, 1100-4l4-880l.

Re...-b:
135
ETHYLAMINE
Synoay--Aminoethane; Ethylamine, anhydrous; United Natioa Nuber..
Monoethylamine
CHRIS Code ..
BoUiqPol:nt.. _nc
___ c -....nF
F
A~lorless liquid or gas; strong
Freezinl PoiDt.. ------=.ll'C ---::<jj'4F
ammonia-like odor.
Speclfte Grarity-0.80
___ c ___F
Vapor Pre.ure zoc 16I'F> <-H&J.. ___ug__
Cbemiel.l FU1Uy-Amine Reid Vapor ~IIJ'e (pN}... ~
VllfOf PrMI~~re .WC (1U'F) (....).. -JQL
Pollution Cateaory-USEPA ___a_ IMO _ L _ Vapol' O..lty (Air = 1.0)... . .............. ~
Applk:able Bulk Rea. 46 CFR S11bchafter ...... ~ SolubUity Ia Wr.. Cpmp!ete
FIRE ol EXPWSION HAZARD DATA

Grade-A: Flammable liquid
Eledrical GI'GIIp-C
Geaerai-Toxic oxides of nitrogen may form in fire. Dangerous. Keep away from heat and open flame.
Flashback along vapor trail may OCC!Jr. Vapor may explode if ignited in an enclosed area.
Flalll Point ('F) ... less than 0

Flam-Me UllliQ .. 3.5 to 14.0%
Autolpid1111 Temp. ('F) .. 725
Ellt.IDptllbJq Apnb .. Alcohol foam, carbon dioxide, or dry chemical
Spedal Fin Procedul'e:l .. Keep burning tank and tanks adjacent to it cool with a water spray.
HEALTif HAZARD DATA

Hellitb Hazard Radap Odor 1bre.ttol4 (ppm) PEL/TWA (ppm) nv11WA ,,,..)
General-Direct contact can cause burns.
Symptoms-Liquid causes eye injury and skin irritation.
Short EII:JIO'IIIf Toknnce-Unavailable
Ex,...ure Procedura-ln case of contact with eyes or skin, immediately flush with plenty of water for at least 15
minutes: lor eyes get medical attention. Remove contaminated clothing and shoes at once.
REAcriVITY DATA
StabUity-Stable.
Comptiblllty-Materlal: Steel, stainless steel and nickel are compatible. Aluminum and copper should not be
used.
Carao: Group 7 of compatibility Chart. See also Appendix !-Exceptions to the Chart.

II possible, wear butyl rubber gloves, face shield or all-purpose canister respirator, and protective Clothing.
Secure ignition sources. Cover with sodium bisulfate. Clean up. Do not flush spill into confined spaces where
flammable vapors can acCtJmulate.
If a llplll oeeun, call tbe Natloul ~ Cater, 800-4l4-81102.

Remarlu:
136
ETHYLAMINE SOLUTION, 70%
Sy-,--Ethylamine, aqueous solutions; MEA, 70%; u ..lell NadoM Nw..-...
Monoethylamine solution, 70%
CHRIS Code ..
&om., Pmnt .. ___..aoc _____lllll'F

J\ppe:u'Uc:e-Odor-Colorleas liquid; sharp, ammoniacal c 'F
FreeaJaaPolnt... <-RD'C <-130'F
""""
SpectRe Gn'lty-0.8 ___ c ---
Vapor Prellure lO'C (61'}1) (mH&J.. ~
Reid V-.or ~re ,,., ....................... ~
V.,or Preaure 46'C (115'F) (....).. ......15L
Pollution Cateaory-USEPA - - - IMO ~ Vapor O....ty (Air = 1.0~... ............ .....1.9....-
Applicable &.lk Rea. 46 CFR Su~r ...... ____g__ Solubllit)' t. Wllter.. Cpmplt!t

Elec:triell GrH.p-0
Geaerai-Highty flammable vapor. Keep away from ignition sources. Flashback along vapor trait may occur.
Vapor may explode If ignited in an enclosed area.
Flqh Point ('F) ... below 0

F1am1Uble Limits .. 3.5 to 14.0%
Autolplt:loa Temp. ('F) 723
Ext:lnplsbtna Apatll ... Water log, dry chemical, CO., alcohol foam
Sped.. Fire Procedurn .. Wear protective clothing, &elf-contained breathing apparatus, and eye
protection.
HEALTH HAZARD DATA

Health Hazard Ratlnp Odor Thrabold (PII'IIl PEL/TWA (Jt&g) TLV/TWA q,.n)
3, 2, 3 0.83 10 10
General-This very volatile solution produces a toxic irritating vapor.
Symptoms-Inhalation: Irritation, coughing, chest pain, pulmonary edema. Ingestion: severe burns of mouth and
stomach. Skin and eyes: Severe irritation and burns.
Slwlrt Ex,agre Tole.-..e-High volatility means vapor concentration can easily exceed TLV even at room
temperature.
Expos11re Procedunt~-Get medical attention. Skin or eye contact: Flush skin and eyes with water fOr 15
minutes. Inhalation: Remove to fresh air and provide mouth to mouth resuscitation or oxygen as needed.
REACfiVITY DATA
StiiiNIIty-Stable. Reacts with acids and oxidizers. Reacts explosively with mercury.
eom,.ttblllty-Miterial: Suitable: Stainlees siMI, mild ateel, nickel, tinned Iron. Unsuitable: Copper, aluminum,
zinc, brass, bronze, ;alvanlzed Iron, polyethylene, rubber.
Carao: Gr0\4) 7 of compatibility chart

Avoid contact and stay upwind. EWminate ignition sources. Wear sell-contained breathing apparatus or
amine-type mask, plastic gloves, face shield, goggles. Wash clothing before reuse. Flush spill area with water.
Do not !lush spill into confined spaces where flammable vapors can acctJmulate.
"'u
Remarkl:
ua ote11rt. ea1.1 tbe Natloaal ~~e~- Ceater, II00-4l4-llfll.
....
137
ETHYLBENZENE
SYHIIY-- EB; EthylbenzOI; Phenylethane United Nlltioal Naber...
CHRIS Code ..
Bolli.. Point.. --la'C __m'F

~... liquicl; aromatic odor c F
Fnezill& Point... -P5'C -l3i'F
s,edftc Grmty--0.87 ___ c ---
Vapor Pr-.re lO'C {61'Fl <-Hal.. ---1aL
Clte.tal hally-Aromatic hydrocarbon Reid v.,.,..
Pna!are {]IU)...
Vapor Pr-.re 46'C {115'Fl (pU)...
......Q.!_
____Q,_
Polhltloa C.teaorr-USEPA ____c_ IMO ____k!_ V.,or Delllfty (Air = 1.0) ..............................a.e.....
Appl~e Bllllt Rea. 46 CF1l Sabdaapter ........ ......ll...Q.__ SolaWUty Ia Water.. Ntgtjqjble

Eledrieal Groap-0
Gueral-lrrltating ~ are generated when heated. Vapors may travel considerable distances from a source
in a flammablll concentration. Fiuhback along vapor traM may OCC\K. Vapor may explode H Ignited In an
encloMd area.
JllMII Poiat ('FJ ............................
50
n.a..we uma .. 1.0 to 6.7%
Aalolpftloa Te111J1. rP:I .. 810
Es.d.......IIIIA. .ta ... CO.,
dry chemical, foam, water fog
Spedal Pin Procedarw .. Fight In the aame manner as any Grade C petroleum fire. Firefighters should
wear self-contained breathing apparatus, protective clothing and eye protection.
HEALTH HAZARD DATA

Heald! Huanl RatiDp Odor 'l'llreallold {p)a) PEL/TWA (ppm) TI.VJ"JWA (ppm)
2, 2, 2 140 100 100
~Vapote cause eye irritation, dlzzlneaa, narCOSis (paralysis), bums of the skin, sensation of chest
constriction. IrritatiOn of respiratory tract, conjunctivitis, dennatitls. Exfoliation of large patches of skln and
chapped appearanoe result.
S)'lllfloet-lrrltatlon to eyes and throat, dizziness and a feeling of chest constrictiOn.
Short Exponre To&enaee-200 ppm fOr 30 minutes; 1000 ppm Irritates skin and mucous membranes. 2000 ppm
eJctremely irritating.
Expoaare Proctduret-Vapor-rernove viclim to fresh air; H breathing stops, apply artificial respiratiOn. Slc:'in or
medcal advice or attention.
REACilVITY DATA
Slablllty-81able.
O..patlbUUy-Miterlal: Rubber in prOlonged exposure to ethylbenzene first sweels, then aoftens.
Carao: Group 32 of compatlbirlty chart.

Wur rubber gloves, face lhleld, protective clothing. Have all-purpose canister mtllk aveilable. Avoid oontact
with liquid. Secure ignition aouroes.
It-a: . Pollution
If a .,W oeeua, adl die Ndcmal Reepoue Center, M-414 IBOl,
Category C 011-like, 33 CFR 151.49 .
IJ8
ETHYL BUTANOL
s,--,--2-Ethylbutanot; 2-Ethyl1butanol: 2Ethyl Uldled Natto. NHr..... .
butyl alcohol: sec-Hexyl alcohOl; aec-Pentylcarblnol:
Pseudotlexyl alcOhol
CHRIS Code ...
FoiWIa-C~CH,CH(C.H.)CHtOH
Boll... Pobit .. ----l!'C ----2i:J'F
A~sa flquicl; mild odor c 'F
Free:dDI Polal... . -114'C ----=vaF
Spedlk Grmty-(1.83 ___ c ---
Vapor P'-fe lO'C IA'F> C..H&)... _Q,i_
v.,.,..v.,..
~ F-.tly-Aicohols Relll ~(pita)... . _..Q.QL
rr-re 46'C (tlS'F) (paa).... --'L..lL.
Poll.U011 Caleaory-USEPA - - - IMO _JID._ V.,or o-tt, (Ab' .., 1.0) ......................... .....J.L_
A,Jiable 811111 Rea, 44!i CFR SabeUpter ....... _c.__ Solbftltr Ill Wider.. Slight

Gnde-0: Combustible Hquid
E~cal Group-O
Ge..era!-Moderate fire hazard when exposed to heat or flame.
Flub Point ('FJ. 137

FJa.mallle Llmib .. 1.9 to 8.8%
A11tcNpJtlon Te~~~p. ('F) .. 580 (calculated)
Ext:lapblhlns Aanta .... Water spray, dry chemical, foam or CO..
Special Fire Proeedllrel ... Cool exposed tanka with water. If a leak or spill has not ignited, use water
spray to disperse vapors.
HEALTH HAZARD DATA

H-.ltb Hazard lbtiap Odor Tllrahold (ppm) PEL/1WA (ppm) TLV/TWA (pi*)
1, 2, 0 Unavailable Unava~able Unavailable
General-Low !O)c:icity.
S)'lllptomt-Animals teats show minor skin irritation after 24 hours. Severe surface damage of eye when alcohol
in sufficient concentration. No deaths upon ingesfion.
Sbort Expo111re Toleruce-Unavallable
Ex)IOIIIft p, dar-Vapor---f'8fT10Ve victim to fresh air; If breathing stcJ9S, apply artificial rnpiration. Eye ond
skin contact-gently flush affected areas with water for 15 minutes. Get rnediclit attentiOn.
REACfiVITY DATA
StiiiNlity-Stable.
Coonpatfblllty-Material: Usual materials of constructiOn are suitable.

Secure ignition sources. Waar rubber gloves, face shield, protective Clothing. Have aJI..purpoee canister maSk
available.
u tplU oecart, adl tile NatloaaJ ....... Cealer I 1100-G4-1182.
139
ETHYL CHLORIDE
S)'!IOIIym.-Chloroethane; Ether, hydrochloric; United Nad0111 Nuber ...
Hydrochloric ethsr; MonochlorOelhane; Muriatic
ather
CHRIS Code ...
Bollin& Point . ____jl'C ~'F

Appeuuce-Odw-Colorless gas or liquid; ether-like ___ c ---
odo Freezin& Point.. ----=.!.ai'C ----=..2.1'F
Spedlk Grnl.ty--0.92 ___ c ___ 'F
Vapor Pre~~~ure 20'C (68'F) (m111HK} .... ~
Cbekal. Family-Halogenated hydrocarbon Reid Vapor Pre81lure (JBil)..... ~
Vapor Pra.un! 46'C (115'F') (psjaJ.. __.!Q___
PoUation C.teaory-USEPA - - - IMO __jJ__ Vapor Dmllty (Air = 1.0) ......................... ____l.tt_
Applieab&e Bulk Reg. 46 CFR Subehapter .. ____Q__ Solubility 111 W.ter.. Slight

Eleetrk:aJ GJ-OIIp-0
Genenl-A highly flammable, volatile liquid; produces highly poisonous phosgene gas when ignited. Unless flow
of gas can be stopped, putting out an ethyl chloride fire will permit accumulation of an explosive vapor
concentration.
Flub Point ('F) .. -45
Flammable UmiQ .. 3.6 to 14.8%
Autolpltlon Temp. ("F) .. 966
Extinp'-hlna Aaent. .. Stop flow of gas: COt, dry chemical, water log
Special Fire Proeedura .. Fire parties must wear respiratory protection. Keep tanks cool with water
spray.
HEALTH HAZARD DATA

Hellltb Hazard Ratinp Odor Thresbold (ppm) PEL/TWA (ppm) nv!TWA (ppm)
1,1,1 Unavailable 1000 1000
General-Vapor harmful. Liquid may cause skin 01" eye injury similar to frostbite.
Symptomt-lrritating to eyes. Drowsiness and dizziness. Frostbitten areas wtll be white.
Sbort Expo~~ue Toleranc:e-lnhalation of 19,000 ppm in air caused partial intoxication in one minute which
increased to distinct intoxication with slight analgesia in 12 minutes.
Expo~~ureProeeduea-Vapor-remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or
eye contact-remove contaminated clothing and immediately flush affected areas with wat9f for 15 minutes.
Handle frostbitten parts gently. Get medical advice 01" attention.
REACfiVITY DATA
Stab1Uty-Oang9fous reaction is possible with oxidizing agents. Slow hydrolysis (reaction with water) in
presence of saH or fresh water to form toxic and COI"rosive fumes of hydrogen chloride gas.
CompatfbUity-Materlal: Compatible with most materials of construction.

Wear rubber gloves, se"contained breathing apparatus, protective clothing. Secure ignition sources. If water
temperature is above 54'F, the ethyl chloride will soon boil off. Do not flush spill into confined spaces where
flammable vapors can accumulate. Personnel not wearing respiratOI"y protection should be kept upwind of the
spill.
If 1 pW oc:e-n, c:a11 tbe National Rnpou-e Center, 800--424-8801,
Remarb: # No Determ1nat1on
140
ETHYLENE
s,._, __ Bicarburettecl hyOrogen; Elayl; Ethane; Uaited N~ N-ber .. compressed
Olefiant gas refrigerated
CHRIS Code ..
Bolllna: Poblt .. ~c ~F
~ortess liquid or gas; very taint, c 'F
sweet odor. -t89'C -272'F
Specllk en,ttr-0.34 _ _ c _ _ _ 'F
Vapor Pre.are ZO'C (68'F) <milt) ..

Ctaeatlcal Famlly-Qielln Retd v.,r Prei.IIJ'e (pebi) ...
v.'"" Prea.t-e 46'C cnsFJ c,.w ..
Pol111tknl Catqory-USEPA - - - IMO ___.__ Vapor Deulty (Air = 1.0) ... ___.Q.aL
Appllable S.lk Ret;. 46 CFR Subdlapl:er ....... .....D....Q_ SolWHty Ill Water .. Nagllp!blt

Grlllle-Liquafield Flammable Gas (LFG)
EleetriCII Group-C
flow of gas can be stopped, putting out an ethylene fire will permit the accumulation of an
Ge~~t~~n.I-Unless
explosive vapor concentration. Vapors are anesthetic.
Flub Point ('Fl.. -213

Flam-Ilk Llmltt .. 2.7 to 34%
Autoipltloa Temp. {"F) ... 842
ExtU.au.llblq Apntl .. Stop !lOW of gas; CO., dry chemical, water tog
Spedal Fire Procedul'tll ... Tanks exposed in lire shOuld be kept cool with a water spray. Attempt to shut
off leak. Wear sell-contained breathing apparatus.
HEALTH HAZARD DATA

Healtb HIUal'd Ratillp Odor 'flllruhold (ppm) PEL/IWA <pp.) TLV trW A (ppm)
0, 0, t Unavailable Unavailable Unavailable
~Mriii-A 11imple asphyxiant. High concentrations cause anesthesia.
SymptoiiUI-Dizziness and drowsiness. Contact with liquid will cause frostbite.
Sbort E:.:po~~ure Toln-llllee-Unavailable
E:.:PQNre Pnxedurw-Vapor-remove victim to fresh air; d breathing stops, apply artificial respiratiOn. If the
liquid has spilled onto the skin, points of contact may be frostbitten; handle gently and protect from
mechanical damage. DO NOT RUB. Get medical attention.
REACTIVITY DATA
St.bllitJ-Ethylene is a reactive compound but must be catalyzed before most reactioos take place.
Cocn,.tilNUty-Materlal: Ethylene is not corrosive.

Wear rubber gloves, lace shield, protective clothing. Have alt.purposa canister available. For a gas leak from
a faulty .tank, keep concentration of gas below the explosive mixture range by forced ventHation. Avoid contact
with liquid. Secure ignition sources. The liquid will rapidly boil away, leaving no residua.
Ir a lpiU oec~~n, eall tbt Natloul Retpo.te Cealer, II00-4l4 880l.

Remarb: Ethylene IS a gas at temperatures above 48.7 F.
141
ETHYLENE CHLOROHYDRIN
s,_fJU- 2-Chlorethanol; 2-Chloroethanol;
2..Chloroethyl alcohol; Ethylene chlorhydrin: Glycol
chlorohydrin
CHRIS Code ....
Boilbll PtNnt .... _____j.2'C

A~lor1ess liquid; faint
_ _ c
alcohol-etherllke odor. Freedna; Potat ... ~c
Speelfte Grnlt)'-1.21
_ _c
Vapor PreiRire zoc C61'F> CHI) .. ~
Cbendeal Fandly-Aicohol ReJd Vapor Pnaure (pela)... -----~...-.....
Vapor Pre.ure 46'C (115'F) (IJ'4a)... __Q.!L_
Polludoll C.tqory-USEPA - - - IMO ____c__ Vapor Denaky (Air = t.O)... .. ........... -2.ZL
ApplkUle Btdk Rea, 46 CFR Subc......r ....... _.Q__ Soi1INHty 1D Water .. Complaft
FlRE .1: EXPLOSION HAZARD DATA

Eleetrteal Gro..,_o
Geoent-Moderate fire hazard when exposed to heat or flame. Dangerous; when heated to decomposition,
emits highly toldc fumes ol phosgene.
JII.A Pelnt ('F) ...... 140

FJaaunable Umla ... 4.910 15.9%
Autotpldoll. Temp. ('F) .. 797
EniiiJidtldDI Ap!ltl ... Water, CO., alcohol loam and dry chemical
Speelal Ftn Proeed.re~ .. Wear seN-contained breathing apparatus and full protective clothing. Cool
exposed tanks with water.
HEALTH HAZARD DATA

Health Haard RatiDp Odof 'Illnsbold (ppm) PEL/IW A (Pflll) UVII'WA (ppm)
3, 2, 0 High 1/Skin 11Skin
Geaeral-Litue margin of safety between early reversible symptoms and fatal into)(icatlon. Fatal amounts may be
absorbed by the skin.
S)'lllpron.-Vapor-causes nausea, vomiting, vertigo, incoordination, numbness.
Short Es:pi)IUJ'e Tol~bsorption by inhalation Of skin may cause death. lnhalafion-240 ppm lethal to rata
in four hOIKS. Human fatality at 350 ppm for two and one-half hours.
Es:po1ure Proeecblra-Vapor-remove victim trom vapor and administer o)()'Qen if available. Administer artificial
respiration if necessary. If swallowed, induce vomiting. Call a dOctor.
REACTIVITY DATA
StaWUty-Ds.ngerously decomposes at high temperatures.
Com-tiWIIty-Materilll.: Steel is satisfactory.

Wear neoprene gloves, plastic protective clothing and self-contained breathing apparatus.
ventHafion. Secure all ignition sources. WaSh skin immediately with water. """""" good
If a ipiU oeeurt, call tlte NatJoul Rlaf!IIDR ee.ter, 800-424-810l.

Remarb: Vapor Pressure. 6.8 mmHg at 25 C.
t Unavailable
142
ETHYLENE CYANOHYDRIN
Synony-- 2-Cyanoathaool; Glycol cyanohydrin;
Hydracrylonitrile; 1-Hydroxy-2-cyanoethane;
3-Hydroxyprope,_nenitrile; 3- Hydroxypropionrtrile;
beta-HyctroxypropiOnitrile
CHRIS Code
Boillna Poillt ....Q.e.<:.QIDR9.~ __2ZZ"C ~F

Appearuee-Odor-Straw-colored liquid; 1'101 unpleasant
Freed111 Point.. ~46'C
c ---
~F
ado<.
Speeifk: Gralty-1.04 c ---
Vapor PreNIIU lO'C (68"F) (lllmHI).. ~
Cbemtcal Family-Alcohol Reid Vapor Pre.ure (piUIJ... ~
Vpor ~re 46'C (115'F) (peia).. ~
Pollut&H c.teaory-USEPA - - - IMO ____Q__ Vapor Deaity (Air = 1.0)... ................ -2..JL
Appliubie Bulk Rea. 46 CFR Subcbapter ...... ____jL_ Solllbllity in Water.. ComPlete

GraOt-E: Combustible liquid
Elf'drinl Group-O
~neral-When heated, ethylene cyanohydrin gives off poisonous fumes of cyanides. Reacts with water to
produce cyanide gas, which is highly poisonous and flammable vapors.
Flub Point ('F) .. 265

Flammable Umlb . . 2.310 12.1%
Autoipltioa. Temp. ('F') .. 922
El[tinauldlin& Aseb-. CO., dry chemical, ak:ohol foam
SpKial Fire Procedures .. Firelighters should wear sell-contained breathing apparatus and full protective
clothing.
HEALTH HAZARD DATA

He.lth Huard Rlltip Odor Threshold (ppm) PEL;TW A (ppm) TLV /IW A (ppm)
Geaeral-Toxic by ingestion. Avoid high vapor concentrations.
Sy111ptom~-Headache, dizziness, blueness of lips and fingernails.
Sltort bponre Toleranee-Unavailabte
Expollll1l Proeedu..-lf ingested, induce vomiting at once; vapor-remove victim to fresh air; if breathing stops,
apply artificial respiration. Skin or eye contact-remove contaminated clothing and gently flush affected
areas with water for 15 minutes. Get medical advice or attention.
REACTIVITY DATA
Stability-Avoid basic: contamination to prevent polymerization. Stable on prolonged storage. Reacts with water.
Reacts vigorously with oxidizing materials, chlorsulfonic acid, oleum, sodium hydroxide, sutturic acid.
Co~npan"INIIty-Miterll: Corrosive to mild steel.
Cuao: Group 20 of compatibility cl\art.

Avoid all contact with liquid or vapor. Wear rubber gloves, lace shield, full protective clothing. Secure ignition
sources. Flood with copious amounts of water.
U 1 IPW oewrt, tiD tile Nltl011llilelpoae Ceater, 100-424-81101.
Rem1rks: t UnBSSigned
143
ETHYLENEDIAMINE
Sy-yllll-1 ,2-Diaminoethane; 1 ,2-Ethanediamlne; United NatloiQI Number ...
Ethylenediamine, anhydrous
CHRIS Code ..
Formula-N~CHtCH,NH,
__u:zc
~
Bollin& Point ..
Appeannee-Odor-Colorless liquid; mildly ammonia-like
odo
Speclftt Gra-rity-0.91
__uc
c
c ___..
---
---->Z"F
Vapor Prett~~n= lO'C 161J'F) (mmHI) .. __jjl.I_

Chemical Family-Amine Reid Vapor P..-re (piLl) .... __J!.L
Vapor PreMUre 46'C (ll!I'FI (pilbl) .. __l!.L_
Pollutl.,.. C.tegory-USEPA ~ IMO _____Q__ V1q10r DeDtlty {Air = 1.0) ... _1.1_
Appllcabk Bulk Rea. 46 CFR Subehapter ...... ___Q_ SolubiUty In Water .... Cgmp!tte

Grwlt-0: Combustible liquid
Electrh:lll Group--O
Getteral-lgnited by heat and open flame. Irritating vapors are generated when heated.
F1uh Point ('FJ .... 99

FIIUIUIIable Umlts., 5.8 to 11.1%
Autolpitl011 Temp. ('F) .. 725
Extblpllbin& A~enU .. COt. dry chemical, alcohol loam, water tog
Special Fire Proeedllret .. Because this material can cause severe eye and skin burns and respiratory
distress, lire parties must wear full body and respiratory protection.
HEALTH HAZARD DATA

Hultb Hazard RatiDp Oclor Threshold (ppm) PEL/TWA (ppm) 1LV!TWA (ppm)
~nerai-Causes severe burns. Vapor harmful.
Sy111ptont~-Coughing, redness ol eyes, wheezing breath. Liquid contact can cause immediate skin damage and
blistering.
Short Ex,...ure Toleranee--400 ppm has been reported to produce immediate and severe irritation to nose and
throat.
Ex,o.are Proc:edures-Vapor-remove victim to fresh air; if breathing stops, apply artificial respiration. Oxygen,
administered by trained personnel, can prove helpful. Skin or eye contact-remove contaminated clothing
and gently flush affected areas with water for 15 minutes. Get medical advice or attention.
REACTIVITY DATA
SUbUity-This is a reactive substance, combining chemically with many others.
Compatiblllty-Materlli: Copper and its alloys are corroded readily and should be avoided.
Carao: Group 7 compatibility chart. See also Appendix 1-Exceptions to the Chart.

Wear butyl rubber gloves, all-purpose canister respirator, protective clothing. Secure ignition sources. Keep
unprotected personnel away from spill. If possible cover with sodium bisulfate. Spray with water. An anernative is
to reduce vapor hazard by covering with alcohol foam.
If 1 tpUl oec11ra, caD the Natioul. Retpoue Center, 800-4l4 IIOl.

Re...-ks! On-scene supervisors should av01d vapor exposure to persons who have asthma or other resp.ratory
ailments.
144
ETHYLENE DIBROMIDE
Sy-)1111- Bromolume; 1,2-0ibromoethane;
sym-Dibtomoethane; EDB; Ethane, 1,2-dibromo-;
Ethylene bromide; Glycol dibromide
CHRIS Code ..
Bolllq Point . _____131'C ____2H'F

AJPUruce-Odor-Colorless liquid; sweet odor ___c ---
Fnezin& P!Nnt.. ~c ~F
Specific GniYity-2.17 at 60'F ___ c ---
Vapo~ P~re lO"C (68'FJ Cmfl&l.. ___i.2__
C!letn"-1 Fa.lly-Ha!ogenated hydrocarbon Reid Vapor Prn.ure (plja).. __ll.L_
Vapor P~ 46'C (115'FJ (pRa).. ___su__
Polluti011 c.tepry-USEPA __X__ IMO _____a__ Vapor Derwtly (Air = 1.0)... ____.L_
Applieable Balk Rea, 46 CFR Subchapter . .... ____Q___ Solubility In Water.. Slight

Grade-N A
Elettric::al Group-O
~nerat-Ethylene dibromide is difficulty flammable. Dangeroos, when heated to decomposition, it emits highly
tox1c fumes of bromides
Flash Point ('fl None

Flammable Limitll None
Autoignitlon Temp. ('F) .... 960
Extin&uishinil Aaents ... Water spray, dry chemcal, foam or CD!!
Special Fire Procedures .. Fire fighters should wear full-protective clothing and respiratory protection.
HEALTH HAZARD DATA

Health Haz.~~rd Ratings Odor Threshold (ppm) PEL/TWA {ppm) TI.VITWA (ppm)
1, t, 3 22 Unavailable Skin
General-Suspected carcinogen. Prolonged contact with skin should be avoided. Toxic by inhalation, skin
contact and ingestion
Symptoms-Blistering of skm; destruction of tissue
Short Exposure Toleruce-200 ppm for one hour: 5000 ppm for several minutes might be fatal.
EIP'O'Ure Proeedures-Contaminated shoes and clothing should be removed at once and the skin should be
thoroughly cleaned with soap and water. If eyes are accidently contaminated they should be flushed
thoroughly with flowing waiST for 15 minutes. A physician should be consulted.
REACI1VITY DATA
Stllbility-Stable, has no oxidizing or polymerizing characteristics. Will not react with air, waiST vapor, fresh or
salt water at temperatures below 115"F.
Compatlblllty-Materl&l: Reacts vigorously with aluminum and magneSium. No appreciable attack on steel,
wood, or cloth. Softens and detSTiorates rubber and paint.

Wear rubber gloves, sell-contained breathing apparatus. protective clothing. Wash away with water.
If a apjll otc:un, WI tlte Nadoul Reapoue Center, IJ00-.4l4 880l.

Remub:
145
ETHYLENE DICHLORIDE
ss,,._..;:_::~,-;;;;;;;::;;;;:,~~;::;:::;:~, ...
:..:""~u~-=~.~~-!';N;,_:;:..:.=:=:=:=::.:. .~.=.....lliL
----
Dutch liquid; Dutch E0G. Ethane, 1,2-dlchloro-;
Oil;
anus Code .. ...................... __EJlL
- e O.ar Col twa, oily
s,.euk Gntftr-1.26
,_,......,__
~; chloroform-like
...............
--
...... _____M"C --lJII"F
..... ----=a8c
___ c ---
v...,.. rr-. we <-lfl> .......... _ __
(di"JI)
c
-M'F
'F
__
.... v.,.. ...._. (fill,)........................... __J.],__
v.,.... ..._,. 46'C (115'F) ............. ......J.L
~
=-~=-=--~~:::::::::::::-~
Polhltlo. c.t.eorJ-USEPA __J__ IMO ___L_
~ a.lll. .... ~CPR~ ........ ---.JL.
.,__..,, FIRE ot; EXPWSION HAZARD DATA
-"'--"
c...J-The YIPC)rl are Irritating. In contact with a hot eurtace, ethylene dichloride decompoees Into
pho8gene, which 11 higtlly poiaonoul. Ignited by heat. ..,.,u or open name.
--
. . . Poiat ('F) .... ............. ........ 65
"---lllu.ltl ..... ......... ........ 8.2 to 16%
AlltotpittOII T-.. {'F) .............. m
.................. CO.. cty chemicl!l, foam, water tog
Spect.l Pin ~ ................ Keep expoeed tanks 0001 with water apray. Water may be ineffective on fire.
Supply Nlpiratory protection and full protective clothing for fire parties.
............. ._
2, 2, 3
04or nr.IMtW ~~
HEALTH HAZARD DATA
PEL/TWA <PP-11 1LV/'IWA (will
10
200"
'
o-aJ...--.&11pected carcinogen. 1/tlfXX twmful; causes sysfMiic poisoning through Inhalation. Liquid contact on
lldn may cauM dermatitis or a tun. Toxic by Inhalation, skWI contact and lngeetion.
., ,, Irritation, dizziness, nausea, rapid pulsa. blueness of Ups and fingernails .
Sllort Exf111U1 T~ ppm tOt" one hour.
Ea,....PI I -vapor-remove victim to frnh air; If breathing stops, apply artificial respiration. Skin or
eye contact~ contaminated clothing and gently fluSh affected areas with water tor 15 minutes. Get
medical adYice or attention.
NOTE: Detectable odor ill greater than the TLV. Expoetn to potentially dangaroue vapor conoentrationl can
occur batore tha VIPOf Ia detected by amell
REACilVITY DATA
._-..,..-.
~--MUertal: ~ at normal atmolpheric temperatura wMn dry. When contaminated with
water at elevated temperatures It OOI"''CCCCM Iron.
c.rta: Group 38 ot compatibility c1wt. See alae Appendbc 1-Exceptlona to tha Chart
--
._.,.
U
SPill OR LEAK PROCEDURE
w.. rubber gloYet, Mit-contained breathing apparatus, protective clothing. AVOid contact with liquid. Secure
111iD ooc.n. call 1M NaticMai ll...-e c.ter, ll-4lt IIOl

Vapor Pruaure: 100 mmHg at 29.4"C.
146
ETHYLENE GLYCOL
S)'JIIIIIYIIIII-1 ,2-Qihydroxyethane; 1 ,2-EthanedioJ;
Ethylene alcohol; Ethylene dihydrate; Glycol; Glycol
alcohol; Monoethytene glycol
CHRIS Code ..
BoWq Polat.. __ill'C ____3Z'F

Apfle&I'U&Z-O!Ior-Colorless, syrupy liquid; slight odor, c 'F
sweetish taste Freezina Pol.-:... --::3'2c WF
Speelftc: Gral'ity-1.13 ___ c ---
Vapor Pre.ure lO'C <A"Fl <-HI).. ~
Cbemical Family-Glycol ReAd VQOr Pre..re (pita)... ~
Vapor rr-re 46'C (115'Fl (,.U).. ..Jl.Q1_
Polbldoa Caleaory-USEPA - - - IMO __Q__ Vapor DelllftJ' (Air = 1.0)... _w_
Appllabte Balk Re8- 46 CFR Subdlapter ....... __Q__ Solbllllty In Water .. . Cpmplata

Eleetrieal Gmup-D
General-Slight hazard when exposed to heat or flame.
Flub Point ('F) ... 240

F'lanullaWe Limltl . LEL=3.2% UEL-unavallable
Autoipltlon T01p. ('F) .. 775 (antifreeze grade); 752 (pure)
Extilldblq Agents .... co,, dry chemical, alcohol foam, water fog
Special Fire Procedures .. Water may be ineffective on fire. Cool fire exposed tanka with water.
HEALTH HAZARD DATA

Heald! Hazud R1t1Dp Odor ~old <p.,.l PEL/TWA Cpp.) TLV/IWA (ppm)
Gmen~l-Aetatively non-toxic unless ingested. II ingested, serious Injury or death may resuH from as little as 60
ml (approx. 2 oz.).
Sylllpto1118-Headache, nausea, and dizziness.
Sbort Expoeure Tolerance-Inhalation is no hazard at normal room temperatures.
ExpoaUTe Proeedura-lngeslion: induce vomiting and call a physician. Never give fluids or induce vomiting If
victim is unconscious or having convulsions. Skin and eyes: !lush with water lor 10 minutes.
REACTIVITY DATA
Stability-Stable.
Cclmp!ltibUity-Matetilll: Most materials of construction are suitable.
Cu110: Group 20 of compatibility chart. See also Appendix !-Exceptions to the Chart.

Wear rubber gloves, face shield, protective clothing. Avoid contact with liquid.
If tplll call the Nadoul ae.o- ee.ter, 100-434 1102

Remarks:
. .. .
OCC:III'I,
..
Data are for the pure grade, not the ant~ofreeze grade . ..
:j: Unassigned
147
ETHYLENE GLYCOL BUTYL ETHER
s,_,__ 2-Butyl ethanol; Butyl Cellosolve; Butyl
oxltol; Dowanol EB; Ektasolve EB Solvent
Ethanol, 2-butoxy-
CHRIS Code ..
Fonnllla-HOCH,CHaOC.H,
Bolliq Po'ld .. ____lll'C ~F
~oily liquid: mild rancid odor c 'F
Fl'tiHiq Poblt ... -Bl'C -12S'F
Spedfte Graflty--0.90 c ---
Vapor Pre.ure lfi'C (68'F) <-Ha> ... ___Q,ZL_
Cllelllkal F. .tly-Giycol ether Rdd Vapor ttn-re (...)... _u_
PoURlcm Catesorr-USEPA - - - IMO ___.l1L_
ApplleUle Btdk Rea. 46 CFR S.IM:bapter ....... _..c__
Vapor Pre.ure -""C Cll!'FI <.-> ...
Vapor Deul.ty lAir = 1,0)...
Soi11WHty b1 Wider ..
~
-=---
Cgmp!ttt

Electrical Gro.p-C
Ge~ttrai-Moderate hazard, when exposed to heat or flame.
Fllllh Pol11t ('F) . 141 (CC)

.,__.,le Limits .. 1.1 to 10.6%
AutMpido. Temp, ('F) .. 472
ExthiiPiflbhll Aplltl ... Water, alcohol loam, carbon dioxide or dry chemical.
Spedal Fire Proced!lrM .. The same techniques used for fighting lire involving combustible petroleum
produCts are applicable. Cool fire exposed tanks with water.
HEALTH HAZARD DATA

Healtll Huard Ratlnp Odor ThreUold (llf!ll) PEL/TWA (ppm) lLVfiWA (ppm)
Ge.erai.-Eye and respiratory tract lnitation, narcosis, blOOd, kidney, and to a laaser degree, liver damage can
be produced in animals !rom a single or repeated exposures at concentrations less than saturation.
Sympt-Eye, nose, and throat irritation.
Sbort Expo~~ure Toleraaee----200 ppm lor approximately ooe hOtX.
Expotlll'e Pnleed~nt repeated skin contact by wearing protective clothing.
REACfiVITY DATA
Stalrillty-ln general, an inert solvent.
CompadiNIIty-MterlaJ: Compatible with usual materials of construction. Plastic materials and rubber are not
recommended.
Cario: Group 40 of compatibility chart.

Wear rubber gloves, face shield, protective clothing. Have all-purpose canister mask available. Avoid
personnel contact with liquid and vapor. Secure all sources of ignition.
If a .,til occiU'I, call die Natiou.l ilelpoMe enter, 1100-tu..-.2.

Remarkl:
148
ETHYLENE GLYCOL DIACETATE
S)'MWy--1,2-Ethanedol dir.cetate; Ethylene acetate; Ulllletl NatioM N.mber...
Ethylene di&cetate; Glycol diacetate
CHRIS Code ..
llo'llnaPoiDt... ~c ____u:i'F
A.,earuce-Otlor-Colorless liquid; faint fruity odor c 'F
Freed111 Pomt.. -41'C -42'F
Specinc: Gra-.lty-1.13
___ c ___ 'F
v.,.- PreAare lU'C (61'F) <nunflc) .... ~
..... v.,r l'reallre (pdll)... _L_
v"PDD' PrMare 46'C ms'FJ <Pilal.. ---l.a....
PollutiDil C.tqory-USEPA - - - IMO - - " - - v- DendtJ <Air = 1.01 .......................... _i.._
A.,tleablr &.lk Reg. 46 CFR Subcbapter ....... -D...Q._ Solultlllty In Water.. 10%
FIRE lc EXPLOSION HAZARD DATA

Grade-E Combustible ltquid
Electrlnl Group-O
General-Moderate lire hazard.
Allh Point ('f') . 205

Flmmablc: Limits .. 1.6 to 8.4%
Autolpitlon Temp. ('Fl. 900
E:~tirtJuishina: Apntl .. Confined area-eo., dry chemical. Open area-polar solvent loam, water log.
Spedl Fire Procedures . Unavailable
HEALTH HAZARD DATA

Health H1zard R1tlnp Odor lbrelbold (ppm.) PELITW A (PJIIBI TL V/l'W A (Jr-l
General-Low toxicity
Symptom~-Unavailable
Short Ezponre Toleru-Animal tests show: No primary skin Irritation, a trace ol eye injury. Inhalation caused
no deaths in 24 hour pel'iOd.
Ezponre ProeediU"a-Vapor-remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or
eye contact-remove contaminated clothing and gently flush affected areas with water. Call a doctor.
REACI'IVITY DATA
StlbUity-Stable.
Compatiblllty-Msterlsl: Usual materials of construction are suitable.
Csrao: Group 34 of compatibility chart.
~PILL OR LEAK PROCEDURE

Wear rubber gloves, lace shield, protective clothing. Have all-purpose canister mask available. AvOid contact
If a .,til oecun, call die Nstlonal R - ee.ter, 100-4l4-880l.

~ Unassigned
149
ETHYLENE GLYCOL ETHYL ETHER
~Celloaolve Solvent: Oowanol EE: EE ........ ~
....
Solvent; Ethanol, 2-ethoxy; 2-Ett'IOXyethanOI;
Ethytane glycol monoethyl ether; Glycol ~
CHRJS Colle... . ........ ~
F-llla-CiioCHsOCHtCH.OH
Bom.,Pofllt.... ......... ~c ___m'F
~liquid; etherlill;e odor. c 'F
Practioally odorless. Freal.. Pelat...... ......... -!'C -i4'F
s,ectfk GraftiJ--0.93
c ___ 'F
VllpOI' Pr...-e lO"C (611'11) <-HI) ........ __j,.Q__
v.,.,..v.,..
a..tcat F.mjly-Gtycol ethers Re6d Pre.ve (IIIIa).... ........ ~
Pr.-e 46'C (115'F') (piU:) ........... _QJL__
Polludolt ~-VSEPA ~ IMO _Q._ Vapor o.dtJ (Air ... 1.0) .................. ~
App1k:1b1e Bait; R.., 46 CFR SdleUpter.. .. _JL_ Solllbil:l.ty .. WUer ...... Cgmplelt
--
Ftam..ble u.JI:I ...

Alltolpldoa rem,. ('F) ..
GeDerai-Moderate hazard, when 8lq)OSed to heat or flame.
J01all Pohlt ("F) .... 120

1.7 to 15.6%
400
Ed......... .\pl...... .... CO.. dry chemical, alcohol foam, water tog.
SpedaJ Fire Proeedunl .. The same techniques used tor fighting fire Involving combustible petroleum
products are applicable. Cool fire exposed tanks with water.
HEALTH HAZARD DATA

Healtla Huan1 ltll:blp Odor nn.INikl (...-J PEVI'WA (pp.J 1LV/JWA <pp.l)
1, 1, 2 UnavaHabte UnavaNable 5/Skio
General-low hazard for acute inhalation; moderate for chronic inhalation.
Syptom.-Headache, nausea, eye Irritation.
Shrt E:qloAre Tolerance-Exposure to air saturated with cellosolve vapor (0.6%) for a few seconds reeolted in
Irritation of the eyes.
EJ:..-re Proeeduni-Vapor--remove victim to fresh air: if breathing stops, apply artificial respiration. Skin or
eye contact---i'8rrl0Vfl contaminated clothing and gently flush affected areas with water lor 15 minutes. Get
medrcal advice or attention.
REACI'IVITY DATA
StUlllty-This Is a relatively stable compound.
COI!Ipatfbility-M.terlal: Softens rubber and many plastics. AVOid aluminum and its alloys.
Cup: Group 40 of compatlbiNty chart.

Wear rubber gloves, face shield, protective clothing. Have all-purpose canister mask available. AVOid contact
with liquid. Secure Ignition sources.
If a .,W oceun, call die Nltleaal ........ ee.ter, II00-4l4 8IOl
150
ETHYLENE GLYCOL ETHYL ETHER ACETATE
s,_,.._. Cello&ONe Acetate; Ethanol, 2-ethoxy-,
acetate; 2-Ethoxyethylacetate; Glycol monoethyl
ether acetate
CHaiS Code ....... .
F..ula-CHaCOOC,H,OCaH,
...... Polot..... . ___li'C __lli'F
Appearact-OIIor--Coloriess liquid; pleasant fruity odor c 'F
F'7eedq P!NIIt... -62'C ~F
...
s,edlk: Grnlty-0.97
___ c ___ 'F
QeMIW F-'IJ-Ester
v.,.... ~ ZO"C (61"Fl <-Ht> ..
ReW Vapor r-e (Jita)...
--....1.2._
_Q.L_
v""" ..,_ ~c <nS'Fl <pMJ..... ........Q.2.._
PelllltiDII Catetory-USEPA - - - IMO _.l<_ v.,.. DeMhJ' (Air = 1.0) ..........................-.!.l2.....
Afplkallle B111k Rq. 46 CFR SHc:Mpter ....... __Q._.Q_ Sotabilltr hi wmr .. .. ....... 0 APW!Pibl

Gr.de-0: Combustible liquid
- """'p--C
Gellend-Moderate hazard, when exposed to heal or flame.
Pladl ~'mat ('F) .... 135

~lelJJIIits .. LEL=1.7% UEL-Unavallable
AlltOipltloa T-p. ('F) .. 715
Ex~Apatl ... COt, dry chemical. alcohol foam, water tog
s,edal Fire Procell.rel .... The same techniqu86 used tor lighting fire irwOMng combustible petroleum
HEALTH HAZARD DATA

u.lth Huard R1tblp Odor 1'llrelhoW. (p~) PEL/I"WA~l TI..V/1WA(..,_)
1,1, 1 0.056 Unavailable 5/Skio
Geaeral-Siight skin irritation. More of a chronic systemic hazard frOm inhalation.
Symptoms-Irritation from skin contact. Vapor: Irritation of nose and throat.
Sbort Exponre Tolerance-High vapor concentrations can cause nose and thrOat irrltatiort
Es~PI
' rei
Vapor-remove victim to freah ar. If breathing stops, apply artificial respiration. Skin or
eye contact-remove contaminated clothing and gently flush affected areas wtth water tor 15 minutes. Gat
medical advice or anention.
REAcriVITY DATA
Stnmty-This is a relatively stable compound.
C.O.,.tibmty-Materlal: Softens many plastics.
Carp: Group 34 of compatlbiHiy chart.

AVOid contact with lquid. Secure ignition sources.
If a .,W occ.,.., call 11ae Natioui . . . , _ C.ler, 180-4J4...180l.
151
ETHYLENE GLYCOL METHYL ETHER
S,--)"allt-Dowanol EM; Ethanol. 2-methoxy-; Glycol United N.UO. NM~ber ...
monomethyl ether; 2-Methoxyethanol:
Methyl Cellosolve: Methyl oxitol
CHRIS Code ..
Bonia& PoJnt .. _ l l i ' C __m'F

A~lortess liquid; mild, agreeable odor c 'F
FTteztnaPolllt..... -esc -tZt'F
c ___ 'F
SpecJtk GraritJ-0.97
Vapor Preefare lO'C C68'F) C111111H&).. _.u__
CltNikal F...Uy-Giycol ether Reid Vapor ~~re (,.U)... ~
Polhdoa c.te,ory-USEPA - - - IMO _JL..

Vapor ...._..re
46'C (115'F) (ptla)..... _.Q&_
Vapor Deadty (Alr = 1.0)... . .......... ...1.&1,_
A.,uabie 8aJt Rec, 46 CFR S.bdlapter .. .. __..ll_ SolubWty l Water.. .. Cornp!ttt

er.de-0: Combustible Qquid
Electrical Group-C
Geaeral-Moderate hazard, when expoaad to heat Ot"llame.
Fladl PWnt ('F) .. 115 (cc)

FIUI...we 11m.lb: ..... 2.5 to 19.8%
Aatolpjtton r-p. C'F) .... 551
~IAJed ... CO.. dry chemical, alcohol loam, water fog
Spedal Plre Proc:ediiRII .... The same techniques used fot f~ghtlng fires involving combustible petroleum
HEALTH HAZARD DATA

Healtb HIIUJ'd lbtl... Odor lbrelltokl (ppm) PEL/'IWA <JPIII) UV/TWA (ppm)
1. 1,2 0.9 Unavailable 5/Skin
Geneni-Harmful vapor; liquid absorption through the skin may be harmful.
Sy~Drowsiness, confusion, loss of mental ability, headache.
Shrt Eqonre Tolerance-Unavailable.
Exponre Proeelhi~Vapor-remove the victim to fresh air; if breathing stops, apply artificial respiration. Skin
or eye contact-remove contaminated clothing and gently flush affected areas with water for 15 minutes.
Get medical advice or attention.
REACI'IVITY DATA
SUWIIty-This is a relatively stable compound.
eo.,.tlbUiey-Material: Softens many plastics.

with liquid. Secure ignitiOn SOUI'Ces.
If a .,UI oceart, tall tbe Nadoul RNpoue Cuter, 800-G4-8802.
152
ETHYLENE OXIDE
Synony1111-Anprolene; Oimethylene oKide; EO;
Epoxyethane; 1,2-Epoxyethane; Oxirane
CHRIS Code ....
BolliD& Point .. __l.l'C ~F

A.ppearanee-Odor-Ciear. colorless liquid; ether-like odor c 'F
Freealq Point .. -lll'C -188'F
Speclftc GraYity-0.88 c ---
Vapor Pranre lO'C (61'F) <HaJ .... ~
ReHI Vlpol" ~re (ll'la) ... ....aL
Vapor Pr.IW"t 46'C (115'F) (peia) .. _5JL.
Polludon C.tett~ry-USEPA __A__ IMO __jj__ Vapor Denllty (Air = 1.0) ... ........ ....uL
Aptlil:able lkolk Rq. 46 CFR SubC'hapter . ___Q__ Solubility In Water .. Cgmplt!t

EJec:triul Group-S
General-Irritating vapors generated when heated. Flammable-dOes not need oxygen lor combustion. 11 local
"hot spots" develop in the tank, the ltquid in the tank may explode.
Fluh Point ('F) below o

Flammable Limits .. 2 to 100%
Autoipition Temp. ("F) .. 804
Extinpilbin1 Apnts. Stop flow of gas; CO., dry chemical, water log
Spect.l Fire Procedura .. It is important to keep the temperature of storage tank low; use large
amounts of wat&l'. Approach only after considering explosion danger. Keep firefightlng personnel behind
cover if practicable. II the water supply is inadequate or the tank shOws signs ot overheating, evacuate the
area.
HEALTH HAZARD DATA

Health Hau.rd Rallnp 04or Thretltold (ppm.) PEL/TWA(Pflll) TLV!TWA (pp)
3, 3, 2 50 29 CFR 1910.t047 1
Gnlerai-Suspected carcinogen. Moderate hazard, lor both acute and chrOnic 8Kposures. Volatility is high and
pulmonary absorption is rapid.
Sym.pto11111-Burning sensation in eyes, nose and throat; dizziness and headache.
Short Eposure Toleran-200 ppm for 30 m1nutes
E....,.llft Procedures-Vapor-remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or
eye contact-remove contaminated clothing and gently flush affected areas with water for 15 minutes. Gat
medical attention immediately.
REACTIVITY DATA
Stability-Ethylene oxide's tendency to polymerize increases rapidly when the temperature goes above 30"C. It
will decompose with explosive violencg when the temp&l'ature reaches 571"C.
Compatibility-Material: EO may polymerize violently when in contact with highly active catalytic surfaces such
as anhydrous iron, tin and aluminum chlorides, pure iron and aluminum oxides and alkali metal l"lydroxides.
Do not use copper, silver or their alloys.
Carjo: Unassigned in the compatibility chart. For compatibility assistance, call
G-MTH-t (202-267-1577).

Wear Nbber gloves, large heavy face shield (if in doubt use body shield also) and self-contained breathing
apparatus. Secure ignition sources. Avoid contact with liquid. Flush with large quantities of water. Do not flush
spin into confined spaces where flammable vapors can accumulate. Notify local fire department
If a 1pill occun. eaU the Natioul Respoae Caller, 800-4U-IIQ:Z,

Remarks:
153
ETHYL ETHER
s,._, __ Anesthesia ether, Anesthetic ether; Diethyl United Natl.ou Number ...
ether; Diethyl Q)(lde; Ethane, 1 ,1'-oxybis-; Ether;
Etnoxyethane; Ethyl oxide: 1,1 '..Qxybisethane;
Solvent ether; Sulfuric ether
CHRIS Code ...
Formu.la-(C.H1 ) 1 0
BoUina Polnt... ____M'C __M'F
Appeuaac:e-Odor-Colorless liq.Jid; sweet, pungent odor c'F
Freezinl Poblt.. ----=-li'Bc -lBO'F
c ___ .,
Speclfk Gn.,lty-0.70
Vapor Preaure :zoc <68'F) <nunHa> .. ~
Rekl Vapor ~re ((llllaJ...... -.l..Q__
Vapor ~re 46'C (IIS'F) <,.:1-J.. ____n..Q,_
Pollution Catqory-USEPA ___a__ IMO ____liL_ Vapor Denlity (Air = 1.0)..... ............. _uL_
AppUe~~ble Bulk Rea. 4fi CFR SubeUpta" ....... __Q__ SolubWty in Water.. ... 7 0%

Eleetrical Group--C
Ge.erai-A highly flammable, volatile liquid with a wide explosive range and low autoignition temperatl.lf'8.
Flashback along vapor trail may occur. Vapor may explode if ignited in an enclosed area.
Flub. Poblt ('F) .. -49

Flaamable Lbrutl .. 1.85 to 48.0%
Autoqnitlon TeMp. ('F) .. 356
Eitlqulslllq AIMCI .. CO,, dry chemical, alcohol foam, water tog
SpeciaJ Fire Procedva .. Cool tank with water spray. Keep surroundings cool to reduce the amount Of
vapors produced. The danger Of relgnilion Is high.
HEALTH HAZARD DATA

Hultll Huard Ratlap Odor 'I'bnlllokl (ppm) PEL/TWA (ppm) TLV/TWA (ppm)
1, 0, 2 1 400 400
Geaerat-Ethyl ather is a volatile liquid possessing irritative and narcotic properties. Absorption Of excessive
quantities by any route may lead progressively to a state of intoxication, loss of consciousness and death
due to respiratory failure.
Symptomi--EJI:hilaration may be experienced first followed by drowsiness and unconsciousness. Contact with
the skin may cause dermatHis.
Sltort ExpoAre Tole~Uee-1000 ppm IOJ 30 minutes.
ExiiOIIlR ~Vapor-remove victim to fresh air; if breathing stops, apply artifiCial respiration. Oxygen,
when administered by trained personnel, is helpful. Skin Of eye contact-remove contaminated clothing and
gently !lush affected areas with water IOJ 15 minutes. Get medical advice or attention.
REACfiVITY DATA
StabWty-ln the presence Of air, ether forms ethyl peroxide, which may explode if heated.
eo..,.tlbWty-MIerlal: Compatible with most of the usual materials of construction. Ether swells natural
rubber, so protective clothing should be made of plastic which resists ether.
CarlO\ Group 41 of compatib~lty chart.

Wear rubber gloves, large heavy face shield (if In doubt use body shield also). Have self-contained breathing
apparatus available. Avoid contact with liquid. Sactwe all ignition sources. Do not flush spill Into confined spaces
where flammable vapors can accumulate. If a spill occurs into navigable water, the ether will float downstream
and create a severe fire hazard until it has all vaporized.
If Ifill ote:va, c:all. tile N.Uoul RetpOUe Ceater, 100-424 8802.
Renwb:
154
2ETHYL HEXANOL
SJ~H~~~r-Aicohol C-8; 2-Ethyl-1-hexanol; UlllleiiN.s-N...............................
2Ethylt1exyl alcohol; Octanol; Octyl
alcohol
CHRIS Code ..
FONa...-cHo(CHo),CH(C,H.)CH 2 0H
--
___32"F
--
A~Ofless. slightly viscous liquid: "F
FNn~ae:Pot.t ... <-lOO"F
SJ*(fk Gnt,ity--0.83
V8fCM' Prelnre XI"C CA"F) <-H&) ...Jl.a.._
a.e.tcal Faally-Aicohol Rehl
Vapor
v.,.... rr-.
~
.....
(~
."C (115"P.I (plla)
..Roll_
..JIJUL
Pollutto. C.tqory-USEPA - - - IMO ....iii.J<...
Allf]ieable hllr. Jlea, 441 CFR S.bcllafter ....... ......I2....C..
v.,.,.. DIMHr Wr = 1.0).
SohWlltJ In w .......
S!lrtlt
....u.._
FlRE .t EXPWSION HAZARD DATA

Grade-E: Combustible "Quid
Eledr:lc:-.1 Groep--0
Flub Point ("F) .. 179

Run..bte Umib ....
Autolpldoa Temp, ("F) ..
,.,
Unavailable
E11dnpllbilll Apatl ... Alcohol foam, c~. dry chemical, water spray
Speelal Fire Procedur11 .. Cool &)(posed tanks with water.
HEALTH HAZARD DATA

Healtll Hazard lbtlap Odor Thrahold (.,.a) PEL/TWA CIIPJII) 1l.V/I'WA epp.)
1,1, 1 Unavailable Unavailable Unaval~la
General-Practically non-hazardous. Slight effect from absorption of liquid through Skin.
SyMptontJ-Mild skin irritatioo.
Sbort Ex~re Toleruee-Not pertinent
Expo~ure Proeedu...-Vapor-remove victim to fresh air: If breathing stops, apply artificial reapirl.tion. Stlln or
eye contact-remove contaminated clothing. Flush affected areas gantty with wter tor 15 mlnutel; 20-30
minutes for eye contact. Get medical attention.
REACI1VITY DATA
StabUity-WIII undergo self-reaction If contaminated. Does not require stabMizer.
Carp: Group 20 ol compatibility ctw1.

Avoid contact with llql.id.
If a .... II occun, call die Nadoaal . . _ _ C.ter, *-424 1101

Remarb; .f: Unassigned
!55
2-ETHYLHEXYL ACRYLATE
CHRIS Code .....
F-m-GHs "' C~CH.CH(C.~)C.H.

BoiU.& Polot..... .lliolli'C ~F
~liquid: pl....nt odor
___ c 'F
Freed Polat... ~c
___c --:Ji5F
___'F
Spedtk GraritJ--0.89
Vapol' ........re ZO'C (QI'F) (IIIIIIHK) .. _..2.L_
a..lal Fudly-Acryillte Reid Vapor Pr-.re (JII!a)... _wu_
Vapor Pre.are 46'C (115'F) (...)... -2.2J.L
Polllldoll CateeDrr-USEPA - - - IMO __1L__ Vapor DelllftJ (Air = 1.0)... ............. .....3L
A.,ucawe lllllk Rea. 46 CFR Subdlqter ....... ____Q_ Solabdit)' Ia Wider... Ntpljg!bfa

GrMe-E: Combultibte liquid
Dectrkal Groap-0
~-Moderate hazard, when exposed to heat or flame: wilt polymerize on heating.
FlaU PUt ("F) 188 (CC)

n.-uJe u.tt. .. LEL=O.B% UEL=6.4%
Atde!aaftloa T..,. ('F) .. 485
EJ:tlllpJalq: Apn ... Dry chemical, CO.., foam, water
Special Fire Proeedllnl .. Water or loam may cause frothing. Cool exposed tanks with water.
HEALTH HAZARD DATA

"-1111 HUII'd ..... Odor nr.bold ,,...., PEL!IWA (ppm) n v,rnvA (ppla>
Ge.eral-Uquld irritating to skin on contact.
S~kin tnitatlon.
Sllort EliJIOIIIre Tolenm-UnavaNable
Ex.-re ~Vapor-remove victim to fresh air; if btaathing stopa, apply artificial respiration. Skin or
eye contact--remove contaminated clothing and gently flush with water.
REACfiVITY DATA
StabWty-Unatable; polymerizes easily unlesa Inhibited.
C.O.,.obfllty-Malerial: Non-corroaive to carbon steel.

If poaeible, wear rubber gloves, face shield, and protective clothing. Have all-purpose canister mask available.
Secure ignition sources. Flush spill away with water.
Us .,W ocean, eaU lhe Natioal. a.,.,.. Celller, ~

Re.srb: Polymerizes.
i Unassigned
156
2-ETHYL HEXYL NITRATE
Synoay1111-Aikyl (C7-C9) nitrates; Mixed octyl nitrates:
Octyt nitrates
CHRIS Code.
Formula-CH,CH 2 C.H,,N03
Bolllna;Polnt.. ~c ~F
Appeannce-04or-Light yellow liQwd; ester. fruity odor Decomposu...blfmi'C ~'F
Freniq Point.. ___J.l"C --...9:'F
___ c ___ 'F
Vapor Preuure lO'C 168'f') (mmHa> .. ~
Chnlieal Family-Nitrates Reid Vap Preaure (,.U)... ___!___
Vapor Prtthre 46'C (ll!'F) (pila).... ---2..a.1_
PollatiOD C.teacwy-USEPA - - - IMO _____iL_ Va,or DeDalty {Air = 1.0)... ____L_
Applicable Bulk Rea. 46 CFR Subthlpler ..... ___Q__ SolubiUty In Wster .. . 0 02%

Grade-E: Combustible liquid.
Electrkll Group-NA
Generai-Combustible-g1ves off IOKic nitrogen oxides, carbon monoxide, and carbon dioxide gases when
heated or burned.
Flqh Poinl ('F). 175 (cc)

Flammsble Limits .. LEL,.- 0 25% UEL-Unavailable
Autolpltion Temp. ('F) 266
Exlinpishlna Allfllh .. Water tog, loam, dry chemical, COt
Special Fire Proudurn Avoid breathing vapor. Can explode if heated while confined-cool storage
container w1th water.
HEALTH HAZARD DATA

Health Hazard Ratings Odor Threshold (ppm) PEL/I'WA (JIINII) nv!lWA <ppm>
Unavailable 1 to 10 Unavailable Unavailable
General-When heated. decomposes to fOfm nitrogen oxides. low toxicity by illQeStioo and inhalation; slightly
tox1c by skin contact
Symptoms-Mild skm and eye Irritation on contdcl. Inhalation produces headaches, dizziness, nausea, and low
blood pressure
Short E1lpoa;ure Tolerance-Low health nsk from inhalation unless the liquid is heated to decomposition or mist
1s formed
E:~poa;urt Pr<~durn-lngestion: If conscious, drink water, induce vomiting. Inhalation: Remove to fresh air. Skin:
Flush w1th soap and water. Eyes: Flush with water lor at least 15 minutes.
REACTIVITY DATA
Stability-Stable at ambient temperature, decomposes when heated. Can explode if heated to high
temperatures wh1te conl1ned. Reacts with strollQ oxides, strong bases, strong reducing agents.
Compatlltllity-Materlal: Suitable: Mild steel, stainlj;~SS steel, aluminum, copper, zinc, tin, brass, bronze,
neoprene, nitrile rubber. Unsuitable: Butyl rubber, ethylene-propylene rubber.
CaJ'lllo: Group 34 of the compatibility chart. See also Appendix 1-Exceptions to the Chart.

Avoid contact, especially vapor. Secure all ignition sources. Wear goggles aod neoprene nitrile
gloves-use sell-contained breathing apparatus if needed. Dike spill, soak up with sand or earth; dispose by "'
controlled burning.
If 1 pill ocean, c:aU the National Respoue Center, IIOO-t24-IIJ02.

Remuks: Decomposition po1nt 1990
t Unavailable
157
ETHYLIDENE NORBORNENE
Sy-yas- 5Eihylidene bicyclo(2,2, 1)hept-2-ene: United NMJou N11ber ...
Ethylidene norbornylene; Ethylideoe norcamphene
CHRIS Code ..
Formula-C.H,.
Bollln1 Point... -----.H'C ____2H'F
Appearaace-Odor--Golor!ess liquid with a tl.lrpentine-like c 'F
Free.dq PobiL -80'C -112'F
"""'
Spec:lfte Grarity-0.90
___ c ___ 'F
Vapor PreiSIIn~ lO'C (68'F) <mH&J..... ~

Olemk:al Famlly-Oiefins Rdd Vapor PreuUR (pQ)... ___Q,Q_
Vapor Pr-..e 46'C (ll5'F) (ptla).. _UL
Pollution Catepry-USEPA - - - !MO _lL_ Vapor ~ty (AJr = 1,0)... ........ ____.!.1__
Applle~ble Bulk Rea. 46 CFR SubchapteT ....... ____Q__ Soluhlllty In Wlltel' ... S!jght

Electrical Group-C
Geaerai-Oangerous fire hazard.
F1ub Point ('F). 96

F1llllllllable Llmib .. 0.9 to 6.4%
Autolpltlon Temp. ('FJ .. 522
E:lliquifhlng Aaeata .. Carbon dioxide, dry chemical, loam
Speelal Fire Prueedurn .. Wear protective clothing. Water may be ineffective on lire. Cool exposed
containers with water.
HEALTH HAZARD DATA

Heald! Hazard Ratinp Odor Threlltold (ppm) PELJTW A (ppm) TLV!TWA (ppm)
3, 1, 4 0.007 to 0.14 5 5
General-Moderate skin irritant. Excessive contact with skin should be avOided.
Symptom-Inhalation-vapors cause headache. dizziness, nausea, vomiting and respiratory distress.

Ingestion-irritation of entire digestive system. Irritates eyes and skin.
Sbort E:.:po~ure Tolennee-Prolonged exposure to vapor proved toxic to rats.
E:.:poAre Procedures-Remove contaminated clothing and !lush affected areas with plenty ol water for at least
15 minutes. Remove victim to fresh air. Administer artificial respiration il necessary. If ingested. induce
vomiting. Get medical attention.
REACllVITY DATA
Stllblllty-Stable at termperatures below 200"C, but unstable above 350c. decom~ing rapidly in presence of
air.
CompJitibiUty-MaterW: Non-corrosive to steel, stainless steel and aluminum. Glass. "Teflon" and ceramics are
acceptable.
Car110: Group 30 of compatibility chart. See also Appendix 1-Exceptions to the Chart.

Wear butyl rubber gloves, lace shield and protective clothing. Secure ignition sources.
If a spjll oc:eun, adJ. t1te National R"'f((Jlle Center, 800 4l4 11102.
Remarb: :t Unass~gned
158
ETHYL METHACRYLATE
Synoar-- Ethyl 2-methacrylate; Ethyl
alpha-methacrylate; Ethyl 2-methyl-2-propenoate;
Methacrylic acid, ethyl ester; 2-Propenoic acid,
2-methyl-, ethyl ester
CHRIS Code ....
-
Ap~-Colortess liquid;
S]leclnc Gra'fity-0.92
Olemlcal FunUy-Acrylates
sharp unpleasant
Pollution Catesory-USEPA _____k_ IMO _____IL_

Bailill& Polm ....
Freezilla Polat ..
Vapor ~
Reid Vilf'DJ'
Va,or ~
____ill'C
-50'C
ZO'C (68'Fl I..Jfa) ..

Pre.ure (peia)...
46'C (ll!'F) (....) ...
Vapol' De.lty <Air "" 1.0)...
c
c
~F
'F
-M'F
_ _ _ 'F
____lL_
__JI.ZZ....
__JJL_
-.a.iL
Appllc:abk Bulk Rq, 46 CFR Subdl!lpter ....... _____Q__ SoluMJIIy I Water .. NtpNgibft

Grade--C: Flammable liquid
Electriaal Group-O
Gemerai-Ftre may cause violent rupture of tank due to potymerization. Forms explosive mixtures with air In the
presel'lCe of heat or flame. Flashback along vapor trail may occur. Vapor may explode if heated in an
enclosed area
Flub Point ('Fl 70
Aammablt Limits 1.8% to saturation
Autolpitlon Temp. ("Fl .. 740
Eztinplshins Agents. co.., dry chemical, chemical foam
Spedal Fire Proeedura .... Easily forms explosives mixtures with air. Remove all sources of flames,
sparks or other ignitiOn sources. Electrical devices should be grounded and bonded. Cool tanks with water
fog.
HEALTH HAZARD DATA

Healtb Huard Ratlap Odor 1brelllohl (ppmJ PELii'WA (ppm) nV!TWA (ppm)
Genenu-ModE!fately toxic, liquid causes skin irritation. Vapors mildly irritating.
Symptoms-Skin allergy develops, vapor causes corneal ulcE!fation, visual disturbance. irritation to respiratory
tract, lack of appetitie, nausea, convulsion, coma.
Short Expo~ure Toleranee-100 ppm over 8 hours. Animal tests show effects are not cumulative.
Expo~ure Proeedu~Remove victim to fresh air. Immediately !lush affected area with water, use mild soap and
water for skin exposure. Experiments have shown Ethyl Methacrylate to be a teratogen: this means that
physical defects can be produced in the developing embryo.
REACI'IVITY DATA
Stlibillty-Polymarizes: inhibitor required. Can react with oxidizing agents. O:round storage drums or tanks to
prevent accumulation of static etectricily.
Colll)llldblllty-Materlal: Glass, types 316 and 304 stainless steel, or aluminum are suitable: corrosive to mild
steel.

Protective clothing, goggles, neoprene gloves, self-contained breathing apparatus should be worn. Flush spWis
with water fog. Dike flaming pools and extinguish using chemical foams. Secure ignition sources.
If a ip1U oman, c:all tile Natloaal Relpoaae ee.ter, IOO-U4--110l.

Renwiu:
159
2-ETHYL-3-PROPYLACROLEIN
s,_,._ 2-Ethyl hexanal; 2-Ethyl-2-heiCanal;
2-Ethyl-3-propyl acyraldehyde
CHRIS Code ..
For:anda-C,HTCH = C(~Hr.)CHO
Bolliq Pol.t .. __ruc
c
~F
.,
A~YellOw
initatlng odor
Spedlle Gra.tl:y-0.85
liquid: sharp, powerful,
Freeziq Point ... ~-c
___ c =::::3a'F___.,
Vapor PJ'ftlure lO'C (68'F) (llllllfla) .... __...Q.Q_
a.e.k:al F-Uy-Aidehyde Reid Vapor .._re c..-)... . -'l.2L
Vapor P.--re 46'C (115'F) (plia) ............ __.0.12__
Polltloll c.teaorJ-USEPA - - - IMO _____B._ Vapllf Denilly (Air = 1.0)...... .. ....... ~
Applbble Bll1l R ... 46 CFR S..bdlapter ....... ___Q_ SolaWUty la Water.... NeqllqiR!a

Gntde-E: Combustible liquid
-G,......C
Geaerai-Moderata hazard, when exposed to heat or flame.
Jlladi PoUlt ('F) .. 155

~U..ttl .. Unavailable
A~T-...("F') ..392
Estlll&ai*Jaa A,em ..... CO., dry chemical, water fog, alcohol fOam
Special Fire Proee.l- .. The vapors ol thla chemical are highly irritating. For this reason, respiratory
protection Ia necessary. In other respects, firafiglting techniques will be the same as for a Grade E
petroleum product.
HEALTH HAZARD DATA

H.atb Hu.rd a.u... 04ol' nn.a.ow Cppml PEL/TWA (ppm) TLV!TWA (ppm)
General-Vapor is irritating to respiratory passages. Uquld irritating to skin.
Sym~Burning sensation in respiratory passages Of on skin in contact with the liquid.
Sltort ExiiOMre Toleruee-Unava~able
Expollll'e ProcedUJW-Vapor---femove victim to fresh air; if breathing stops, apply artificial respiration. Skin or
eye contact-remove contaminated clothing and gently flush affected areas with water for 1 5 minutes. Get
REACfiVITY DATA
StllbiUty-Stable.
Compatlblllty-M.aertal: Unavailable
Carao: Group 19 of compatibility chart. Sea also Appendix 1-Exceptlons to the Chart.

Wear rubber gloves, self-contained breathing apparatus, protective Clothing. Avoid contact with liquid. Small
spills may be washed away with water. For large spill, cover with sodium bi&ulme (NaHSO.). Add small amounts
of water and mile. Scoop up. Wash site with soap solution.
If a iplll OCCIII'I, eall tbe Natioul Re1poMe Cealer, I00-4:Z4 SIO:Z,
RIJIUIJ'b: :t Unassigned
160
FORMALDEHYDE SOLUTIONS (37 to SO%)
SyiiOil)'- Formalin; Formallth; Formic aldehyde Vatted NMAo. N........... solutiOns ....22!21...._
solutiOn; Formal; Fyde; Methanal solution: flammable lOin. --.1.1a....
Methylene oxide; Morbicld
CHRIS Code ..
Boillq PM~.. ____jz"C ____2QII"F

Appearuce-Odor-Color1ess liquid; pungent, irritating c "F
Freez:~. 1 Po'at... =:tc ==:"F
"""
Speelfte Gra'f'lty-1.11 to 1.13 ___c ---
Vapor Pr--= we <61"P:I <-II&) ..... ---1..a_
a.-6eal F-lly-Aidehyde Rdd v.,..~ ,..).... .......
Vapor Pre.ure .tfi"C lll5"P) {JIIfa) ........ ~
-'lJii..._
Pollutklll C.reaory-USEPA - - - IMO _ L _ Va,or Deallty Wr "" 1.0). ....... __JJQ_

Appllnblr B111k Rea, .tfi CFR S.bebaptel' ....... ___Q___ SoiHWty I W*t' .. Comp4tte.

Grwlr--0 orE Combusbbte liQUid (grade depends on concentration)
Eltc:tril:al Gro11p--B
Gtonrrai-When the solution Is heated, highly flammable vapors are giYen off.
F1ub Poinl ("Fl 122 to 185

F1ammablr Limits 7.0 to 73% (formaldehyde vapor in air)
Autolpition Temp. ("FJ .. 806
ExtinpisbinJ Aaenta ... CO:r, dry chemiCal, alcohol loam, water fog
S~WClal Fire Proce4uret .. The vapors are highly iJTilating, so tire parties should wear reepiratory
protection.
HEALTH HAZARD DATA

Health Haunt Ibtlngs
3, 2, 3
Odor Thrahold
below 1
(pplll) PEL/TWA <pp.)
3
TI..VITWA(.,_)
,.
Gellerai-Suspected carcinogen. Major effect is local irritation of eyes, nose, and throat. Strong formaldehyde
solutions cause a hardening effect and primary skin irritation upon direct contact.
SymptoiM-Coughing, copious wateling of eyes. severe respiratory irritation.
Short Ep011ure Toleraru:e-At a vapor concentration of 10 to 20 ppm breathing baOomes difficult Expoeure to
650 ppm for a few minutes may cause death.
EJtponre Proeedura-Vapor-remove victim to fresh air; If breathing stops, apply artificial respiration. Skin or
REACfiVITY DATA
Stllblllty-5olutions are often shipped at elevated temperatures to prevent polymer formation.
Comp.tiblllty-M.terlal: Corrosive to steel and to copper and its alloys.

Wear rubber gloves, sen-contained breathing apparatus, protective clothing. Avoid contact with liquid. Secure
ignition SOUfCe. If possible, cover large spills with sodium biSulma (NaHSO,). Add 1m1111 amount of wmer and
mix. Scoop up. wash site with soap solution.
It I IIPIU - .... eaU tbe Nltioul. ~ c.w. 188 421 1182.

ReJ~Wkl: The commercial material Is atupped as water SOlution of from about 37% to 50% concentration.
Methanol ia often used to Inhibit polymerization.
Proposed change in TLV to 0.3 ppm.
t Unavailable
161
FORMIC ACID
sr-,..._Fonnylic acid; Hydrogencarboxyllc acid;
Methanolc acid
CHRIS Code ..
-
Formula-HCOOH
Botllq: Poillt.. _____lQ.l'C --...2.J2'F
A~Otlesa liquid: sharp, penetrating c "F
Freezlna Polat... ~c
___ c ---!Z'F
___F
Speclftc Grl:ritJ-1.22
VapOT Pre.un~ 20'C (lSI' F) CmHK) .. . --'l.L
Reid Vapor Prelllll"e (pila)... ----1..L_
VIJIOI' rr-re 46'C (115'F) (JIIUJ.. _.2.L_
hlhadoa. ~SEPA ~ IMO ____ll_ Vti)IOI' DeaaUy (Air = 1.0) .......................... ---1...._
ApplkUle Blllk Rea. 46 CFR S.kbapter ....... ____Q_ Sol'llbilitJ In Wat.. .. Cqmp!ali

Gnde-E: Combustible liquid.
Etedrieal G"'..,_Q
Gelteni.-Formlc acid is a cOITOSive, combustible liquid. Toxic vapors are geneJated in fires.
Flail Poblt I'Fl .. 156 (cc)

~eU.It. .. tBto 57%
Aulolpltlon TOIJI. (' Fl .. 1114
ExU....illllna; Aant. ... CO., dry chemiCal, alcohol foam, water fog
Special Fire Procedllre~ .. Firefighting parties should wear rubber boots and gauntlets and self-contained
breathing apparatus.
HEALTH HAZARD DATA

HalO! Huan1 Ratlqt Odor 1bretbold (ppm) PELJTW A (ppm) TLVIIWA (ppm)
Geaeral-NatUffll, slow decomposition yields carbon monoxide (CO), a chemical asphyxiant, and water.
Enclosed spaces must be tested for oxygen content (19.5% min.) before entering. Vapot irritating. liquid
CIUMS bumS.
S~klng, respiratory lnitation, watering of the eytls; skin contact will cause sev81'e itching or burning.
Sllort E:.:,...llft Toleruee-Unavailable
Ezpoeure Procedufei-Vapor-remove vK:IIm to fresh air; If breathing stops, apply artificial respiration. Skin or
eye contact-remove contaminated clothing and immediately flush affected areas gently with water lor 15
minutes. Get medlcel attention. Use protective clothing to prevent personal contact.
REACTIVITY DATA
StllbUit:y-Reacts wHt base& (alkalis) to produce heat. H is also a reducing agent.
-
C:O....tlbWt:y-MIerlal: Type 316, stainless steel or lead-lined tanks are satisfactory.
ear,o: Group 4 of compatibility chart. See also Appendix 1-Exceplions to the Chart.

AvOid contact with liquid. Use 1'88f)iratory protection and protective clothing. Eliminate all sources of Ignition.
Cover contaminated surfaces and spill with large quantities of SOda ash or sodium bicarbonate. Mix and add
water if necessary for good mixing. Scoop up sluff)'. Wash site with soda ash solution.
- If a .,W otcur1, call tlte Nadcma.l RlfiiPDIIR Cater, 800-424 8102.
162
FREON
Sy.o~ Genetron; tsolron; Halon: Refrigerant gas:
Ucon
CHRIS Code .....
FOI'III.ala-'See "Remarks" below.
-
BoUIIII Poillt. c
---.c---.
'F
A~orless hqUd or gas, sweetish
Freeziq Polllt.. Vriu'C - - -
Speclftc Gnlty-above 1.0 c_'F
Vapor ...._N 20'C ta'FJ (-lfs).. .Jllr:iiL
Chemical FUUiy-Halogwlated compounds Reid Vapor ~ c,.ta)... ....ILiiL.
Vapor P.--.e 46'C <tt5'FJ (,a.).. ...:DI:il:l...
PoU.tloa Catepy-USEPA - - - IMO -'IIIIL Vapor 1>eRe1ty <Air - 1.0).. ............ ,.,,O....m..mmJ:
AppUcable Bulk Rea. 46 CFR Sndlapter ........ ---'l._ Sol1WHty Ia Waler .. Nmlkz!blt

G...de-NA
EJectrical Gro..-NA
General-Freon 11, 12, and 114 do not bum. Freon 22 and 113 when heated can form weakly combustible
mixtures.
Flub Point ("F) Non-flammable

Flammble Umlts Non-flammable
Autolipdtion Temp. ('FJ .. Non-flammable
Extinguishing Al}ents Non-flammable
Special Fire Procedura .... In contact with hot surfaces or a naked flame these compcKJncls form
phosgene, an extremely poisonous gas. Keep tanks, adjacent to fire, cool with water spray. Fire fighters
wear lull protective clothing including self-contained breathing apparatus.
HEALTH HAZARD DATA

Healtb Hau.rd Ratinp Odor Threshold (ppm) PEL/1WA (ppm) TLVIIWA (ppm)
Unavailable Unavailable Unavailable 1000
Geroe111l-Vapors are non-irritating to eyes. nose, throat, lungs, and skin, very low toxicity.
Sy111ptoms-Drowsiness with Of without nausea.
Sbort Exposure Toleraace-10,000 ppm for 5 minutes.
Exposure Proceduret-Remove victim to fresh air. II breathing stops, apply artificial respiration. Get medical
attention. If the liquid has spilled onto the Skin, points Of contact may ba frostbinen, handle gently and
protect from mechanical damage. DO NOT RUB. Get medical attention.
REACI1VITY DATA
Sbibllity-Chemically stable, but see Special Fire Procedures above.
Con!patlblllty-Materisl: Compatible with most materials ol construction.
Cup: Group 36 of Compatlbirrty chart.

Avoid contact with liqUid. The liquid may bOil away (see below) at ambient temperature. Extinguish open
flames in vicinity of the spill in order to avoid generation Of phosgene.
Remarkl:
- -
CCI,F
CCI 2 F1
CHCIF 2
CCioFCCIF2
CCIF,CCIF2
If I .,UI
Eoisl!J
11
12
22
113
114
0CC111'1, ea1J the Nsdoal Relpoale Cater, ~
113
122
121
233
242 163
Balllno l!JJJtJJ
+74.8"F
~21.6
~41.4
+117.6
+38.4
CJ::/.8.lS. QID
TCF
DCF
MCF
TIF
DTE
FURFURAL
s,._,.__ Ant oil, artificial; Artificial oil of ants: Furat; Ualled Natioltl N11111ber ...
-
2-Furaldehyde; 2-Furancarbonal:
2-Furancarboxaldehyde: Furfuraldehyde: Furfuran
carboxylic aldehyde; FurfU'Oie; FIXOie; Pyromucic
CHRIS Code ..
~uJa-C.~OCHO
BoUIDJ Polnt.. __wc __..W'F
A~~ss to reddish-brown r~quid", c ---
penetrating almond-like odor Freezi111 Point... .. ........... --=aic -----=..a!'F
Spedftc Gnrity-1.20 ___ c ---
Va,w Preaure lO"C (68'F) <mmH&).. ......1..QL
a.e.teaJ. F..Uy-Aldehyde Re141 Vapor rr-re (.,.W.. ......... ___.Q.l_
Vapor P~ <M'C (115'F) ~-- ......QJL
Polllldoa Caleton-USEPA _.Jl..._ IMO ____L_ VIIJIOI' Dt_.ty (Air = 1,6)... _:J.aJ_
A..,uc.we lid: Jtea. <M CFR Subdlllpter ....... __Q__ Solaltnlty ln Water.. .. 8 9%

Gnde-E: Combustible liqUid
-Groop-C
o-.1-Moderate hazard, when exposed to heat or !lame. Furfural can explode on contact with strong mineral
acids and alkalis (cauatics). Irritating vapors are generated when heated.
~ Point C'F.l .. 155

..,.._ble Umltl .. 2.1 to 19.3%
Alltotpltioll T~Pnp. ('F) .. . 743
Ex~Aantl--- CO.. dry chemical, alcohol foam, watef log
s,ecw Fire Proeedllnl ..... wear eye protection, self-contained breathing apparatus and protective
clothing.
HEALTH HAZARD DATA

Haiti! Huanl Ratlqs Odor TUeMoid (ppm) PEL/lWA (ppllll TLVII'WA (ppm)
2, 2, 3 0.4 2/Skin 2/Skin
Generai-LiQUd Is mtating to skin and eyes on contact. Vapot is respiratory irritant.
S,.pto.t-lrrltation of respir&tOJY passages.
Sllort EJ:~ Toleruce-15 ppm lor 15 minutes.
EJ:;pa.re Proeed._Vapor-remove victim to fresh air; If breathing stops, apply lr'llficial respiration. Sltln or
eye contact-remove contaminated clothing and gently flush affected areas with water for 15 minutes. Gat
madlcal advice or attention.
REACUVITY DATA
St.WIIty-Furflxal can explode on contact with strong mineral acids and alkalis. Reacts with numerous organic
materials.
Co.,.ullllit)'-Materlal: Dissolves or softens many plastics and rubber formulations.
Cuwo: Group 19 of compatibility chart.

Waar rubber gloves and protective clothing. Have seH-contained breathing apparatus available. Avoid contact
with Uquld. Small spills may be washed away with water. Cover large spills with sodium bisulfite (NaH~I- Add
small amount of water and mix. Scoop up. Wash site with soap solution.
If .,m oeaan, taU the Nadoul Ree,oa. eea, 800-4:Z4 ao:z.
164
FURFURYL ALCOHOL
s,.-,__ 2-Furancarbinol: 2-Furanmetnanot: Ualted N.U.. N. .ller...
Furturaleohot: Furylcarbinol; 2-Furylcarbiool;
alpha-Furylcarbinol: 2-Futylmethanot:
2-Hydroxymethylluran
CHRIS Code ..
A~-Colorless-arnber liquid turning to a.m.,Pomt.. __wc ~F

dartl. red-brown when exposed to light and air. c 'F
Slight brine-Nke odor. FHez.ll PtHnt.. -3t'C
-'F
Speelfk Gnl'tlty-1.29 ___ c ---
Vapor P..-e lO"C (61'FI <..ttc>-- ____!__
Ctelaical Fa.lly-AicohOI Reid Vapor Prellure (fiW... --'l.QZ._
VIJMW rr-te 46'C <115'F) (plill).. ......Q.1_
PoUutioll Catqory-USEPA - - - IMO ______Q__ Vapor DeMity (Air = 1.0)......................... ......a.n..._
A.,Ue.llte Balk Rea. 44i CFR Subdalpter ...... __Q.,Q_ Solabillty Ia Water.. Cgmp!tta

Eleetrieal Greup-C
General-Slight explosion hazard when exposed to heat or !lame. However it will react with explosive violence
in contact with mineral acids or their vapors, or with strong organiC acids or their vapors.
F1111b Point ("F). 167

Flammable Umlts .. 1.8 to 16.3%
Autolpjtion Temp. ('F) .. 916
Extillpihinl Aaenta. Confined area-CO., dry chemiCal. Open area-polar solvent f011m, water
spray.
Spedlll Fire Procedures Weat eye protection, clothing resistant to furfuryl alcohol, respiratory
protection.
HEALTH HAZARD DATA

Hultb HIUal'd Ratlnp Odor Thrwhold (ppm) PEVIW A (ppm) nVII'WA~
2, 1, 2 6 10/Skin 10/Skin
General-Skin absorption may cause toKic effects. Hatmful if swallowed. TOKic concentrations of vapors may be
present at temperatures above room temperature.
Symptom-Headaches, watering eyes, irritated skin.
Sltort EKposuN Tolel"llnCe-Vapor eKposures-Rats show 8 percent mortality after one siK hOIX &KpO&Ure to 47
ppm and 100 percent mortality at 243 and above. Absorption through skin ia very rapid.
EKposu.N Procedures-Eyes-wash with water for 10 minutes. Remove contaminated clothing and wash.
Sk1n-wash with soap and water. Ingestion-induce vomiting. InhalatiOn-move to fresh air. Get medical
adviCe or attenbon
REACfiVITY DATA
Stabillty-Stable. Reacllve with organic or mineral acids.
Comp~~tibillty-Materlal: Do not use near lacquers, varnish, or resins. Gan ship In ordinary steel.
Carlo: Group 20 of compatibility chart. See also Appendbc !-Exceptions to the Chart.

with liquid. Secure ignition sources. Spill area may be washed with water.
If a ..tn oecun, call the Natioall a - ee.ter, I00-4lt IIIOl.

Remar~ Ground storage drums or tanks to prevent accumulation of static electricity.
165
GASOLINE MOTOR
Synonyas- Benzin; Motor spirit; Petrol United Na._ NuMber...
CHRIS Code ..
Bolllna: PoiDI .. ~c~F

Appearaneeo()dor-Colorless to straw-white liquid; c 'F
sweet, pleasant odor-gasoline FreedB& Point .. _____j'C ===F
Spednc Grnlty-0.72 to 0.76 c ---
Vapor Prellure lO'C (61'F) (mHaL. __liL_
Cltemleal Fam.Uy-t.tisc. hydrocarbon mixture Reid Vapor Prealare ~- _LL_
Vapor Pre.ure 46'C (U!I'F') (.,.taL __t2.L
PoHut1011 c.tqory-USEPA _ _ _ IMO ~ VllfOl' o..ity Wr = 1.0)... ~
Applleabh Bulk Rea. 46 CFR Subdulpter ...... _.1L_ SoluiHiity In Water .. NagUqjb!a _

Eteet:rkal Group-O
General-Dangerous fife and explosion hazard in presence of heat or flame. Flashback along vapor trail may
occur. Vapor may explode II Ignited in an enclosed area.
f'llqb PoiDt ('F) .. -40

Flam-ble UmJU .. 1.4 to 7.6%
Alltoipldoa Temp. ('F) .. 495
EJ:tinpllblna; Apabl .. CO,, dry chemical, foam water fog
Spe~:lal Fire Procedura .. Tanks exposed to fire should be kept cool with a water spray. Water may be
ineffective on lire.
HEALTH HAZARD DATA

Health Huan1 lbltlllp Odor nreUold (ppm) PEL;TW A (ppm) 1LV/TWA (ppm)
1, 1, 2 0.25 300 300
GeDend-Uquid irritating to skin and eyes on contact. Vapor inhalation leads to intoKicatlon.
Sympto-lnhalatlon: Marked vertigo, inability to walk a straight line, hilarity, Incoordination, intense burning in
throat and lungs, possibly bronchopneumonia, nausea, vomiting.
Short Eipo~~ure Tolennce--0.5 to 1.6% vapor concentration was fatal to a man after 5 minutes exposure; 500 to
30,000 ppm was fatal to a youth.
Eipo~~ure Proeedura-lnhalation: Immediately remove victim from contaminated atmosphere. If breathing is

interrupted, artificial respiration should be applied immadiataty. A physician should be called.
REACTIVITY DATA
StabiUty-Chemically stable.
CompattWUty-Material: Almost any usual material of construction is suitable. Natural rubber Is softened and
will deteriorate rapidly.

Wear polyethylene gloves, face shield, protective clothing. Have all-ptJrpose canister mask available. Sec..e
ignition sources. Small spills may be flushed away with water.
If I)IW -n. atU tbe N~oul ilapoDM Center, I00-4l4-81101.
Re-b: t Unava1lable
166
GLUTARALDEHYDE SOLUTION, 50%
StniiNIJ'--Cidex; 1,3-Dfonnylpropane; Gluttlral; Uldml Nat~.- N . . -...
Glutaric dialdehyde; Gluu.o!; Pentanedial;
1,5-Pentanedial
CHRIS Code ..
Bolllq Point ... ___lU'C ____jzg:'F

A~ight yellow liquid; rotten apple odor c 'F
-14'C ______2'F
Spectftc Gn.i.Q<-1.124 c ---
Vapor Pre~~~~re lG'C C61'F') (-'Is) .. _u_
lte6d v...,.. Pl--. (. .)...
V-.or ~ 46'C lllS"F') (. . .) ...
_,;;i_
_.1...._
PoUIItlon c.teaorY-USEPA - - - IMO _.JL_ VllfOI' lleMIQ CAM- = 1,0)... _M_
Appliultle ..._ R., 46 en ~'-Jter ....... ____Q_ Sot.blllt)' Ill Wdlr .. So!ubll

Grade-Non-flammable
Electrlal Grwp-NA
General-Will decompose if heated (greater than approximately 400'C) to yield carbon monoxide, carbon
diO)Cide, hydrocarbons.
Fladl PoJnt ('F) .. Non-flammable

F111111-ble Umits .. Non-flammable
Autoipltton Temp. ('F) .. Non-flammable
Extlnlllibln& ARe~~ts .. Non-flammable
Sped.~ Fire Procedure. .. None
HEALTH HAZARD DATA

Health Hazard Rltiap Odor 1'hn:lhld (ppm) PEL/1WA (ppm) nvnwAc..,..,
1, 3, 3 0.04 0.2 0.2
Generlll-Moderate irritation to the skin.
Sympto~U-Extended exposlKes result in irritation of respiratory tract. Ingestion yields irritation of mouth and
stomach.
Sbort Exponre Tolennee-The lowest lethal concentratiOn for rats in 4 hours is 5000 ppm.
bpoHre Procedu~lmmedl&tely flush with plenty of water for 15 minutes. For ingestion, give large amounts
of weter and induce vomiting if conscious.
REAcriVITY DATA
StabiUty-Stable, but decomposes thermally about 4ooc forming carbon oxides and hydrocarbons.
Co~~tll'ltlblllty-Msterisl: Mildly corrosive to mild steel, aluminum, copper, zinc, tin, brass and bronze.
Cwao: Group 19 of compatibility chart.

Flush with water. Wear goggles or Ieee shield and rubber gloves. Prevent water contamination. Toxic to fish.
If a .,W occtll'lt csll dte Natto.sl llesDHie Celller, 1100-424-IIOl,

a-arks: t Unavailable
* Unassigned
167
GLYCERINE
Sy-ym-Giycerol; Glycyl alcohol; 1,2,3-Propanetriot; United NatiOIUI Number ...
Trihydroxypropane: 1 ,2,3-Trihydroxypropane
CHRIS Codfo .
Fon~~ula-CH,COCH,COH(CH,).
Bolllna Point .. _____wc
c ___.,
~F
c ___.,
Appeanuw:e-Odor-Colorless liquid; faint pleasant odOI'
Freednll Point .. ~-c _M"F
Specifk Gra,-lty-1.26
Vapor Preaure 20'C (68'F) (mmH&) ... ..l'...l.oL
Chemlcr.l FamUy-Ketone/ Alcohol (exhibits properties Reid Vapor Prn.ure (p&la)... ..l'...l.oL
of both) VallO' Preaure .U'C (tl!'F) (JI'ia> .. ..l'...l.oL
Pollutfoa C.tqory-USEPA - - - IMO ---.ll!._ Vapor De-.JI)' (AJr = t.G) ... -.llL
Applkallle Balk Rea, 46 CFR Subc... pter ........ --'l.._ Solubility In WateT .. Complete

Eleetrlca.l Group-O
General-Slight hazard, when exposed to heat, flame, or powerful mcidizers.
Flub Point ('F) ..

Flammable Umltl ..
Autolp.ltlon Temp. ('F).
Extinpisblq Apntl ..
Special Fire ProcediU'eS .
.
320
,
Unavailable
CO., dry chemical, alcohol foam, water log

Water may be ineffective on fire. Cool exposed tanks with water.
HEALTH HAZARD DATA

Health Huard Ratlnp Odor 'l'hrelllold (ppm) PEL/IWA (ppm) TLV /TWA (ppm)
0, 0, 0 Odorless 10 mg/m 1 as a mist 10 mglm' as a mist
GeDert-Skin contact with liquid causes slight skin irritation.
SymptoJIIli-Contact with the liquid can cause skin irritation.
Short 1Upo1ure Tolennce-No appreciable hazard.
Ex~~C*~re Proeedura-Wash glycerine from skin with water. Launder clothing contaminated by the liquid.
REACTIVITY DATA
Stllblllty-Reacts with strong ox"1dizing agents. Polymerizes about 300"F.
Com,.tibillty-MterW: No apparent effect on steel or aluminum.

Secure ignition sources. Spills may be washed away with water.
If 'Pill oenrs. cllll the National Rn)IOIIM Center, 800-414 8801.
Remrks: Even a small amount of water or other 1mpunty w1ll greatly lower the freezing po1nt.
t Unassigned
168
HEPTANE
Synonymt- Dipropylmethane; n-Heptane; Heptyt Ualted Natlo... Nlllllber...
hydride; Normal heptane
CHRIS Code ..
F01111u1a-CH1 (CH 2 ).CH,

Bollin& Pol~~ot .. ______iD'C ~'F
AppearaD~:e-Odor-Volatile, colorless liquid; sweet c 'F
gasoline-like odor Free.dn1 Point... ~!WC -132'F
Spec:llk: Gralty---0.68
___ c ___F
Vapor Pranre 20'C 16I'F) lmmHI) .. ___l.l.d_
Chemical Funlly-Saturated hydrocarbon Reid Vapor P..-re (plill)... ___l.L_
Vapor ..,._re 46i'C (115'F) (paa).. ___i.i_
PoUutJon Cateaory-USEPA - - - !MO _ L _ Vapor o-l.ty (Air = 1.01.. ___a.g_
Applicable &lk Jle&, 46i CPR Sllbdlapler ........ _J2.jL Solultlllty bl Water.. NmlisJlb!e

Electrlc-.1 Group-O
General-Highly flammable, dangerous lire risk. Flashback along vapor trail may occur. Vapor may explode it
tgntted in an enclosed area.
Flash Point ("FJ ... 25 (cc)

Flaznmab~ LimitJ. 1.210 6.7%
Auloipltion Temp. ('F). 433
E~:tiftlllishing Agents ... Confined area-CO.. dry chemical. Open area-foam.
Speci1l Fire Procedures .. Fire fighters should have respiratory devices. Keep fire exposed containers
cool with water.
HEALTH HAZARD DATA

Health Hu.anl R.tlnp Odor Thfelbold (pplll) PELITW A (ppm) TLV/TWA(IIPIII)
0, 0, 1 220 400 400
Generlll-Moderately toxic by inhalation.
Symptoms-Irritation of mucous membranes. dizziness, slight nausea, intoxication.
Short Exposure Toleranee-1000 ppm lor 6 minutes developed slight dizziness. 500 ppm lor 15 minutes results
in a condition resembling intoxication by ethyl alcohol.
Exposure Procedurn-lf inhaled in cone. amounts, remove victim to fresh air and use oxygen. If splashed in
eyes, wash with water for 15 minutes. Gall a doctor.
REACTIVITY DATA
Stllbllity-Non-reactive but dangerous lire risk. Keep away from heat, sparks, or open flame.
ComfllltlbUity-Materilll: Mild steel and stainless steel are suitable. Natural rubber will soften and deteriorate
rapidly.
Clrjo: Group 31 of compatibility chart.

Avoid contact with liquid. Have all-purpose canister masks available. Secure ignition sources.
H 1 Ifill occurs, all the Natloaal RMpoae Celller, 800-4l4-8110l.

Remark~:
169
HEXAMETHYLENEIMINE
s , _ , . _ Azacyclohelane: HeKahydroazepine;
Homopiperidlne
CHRIS CoH ..
BoUI.. PWat .. _JB'C ____iZ2'F

A~lortess to light yellow liquid; c ___.F
ammonia-Nke odor Freezta1 PoUlt... -38'C ~F
Spedftc Gnrity~.88
___ c ___.F
Vapor PraAre zoc <61'F) CmaH&) .. ____;,__
Cbentleal. F.....Uy-lmine ReW Vapor Pranre (pita)... ~
Vapor~ 46'C (ti5'F> (plia)... ____5._
PoUatlon Cate8W)'-USEPA - - - IMO ~ VIIJOf Denll.ty (Alr = 1.0) .......................... ___!__
Applbble Bulk Rea. 46 CFR Sabe'-Pter ....... ___Q_ SotabWty iD w.._.. Qomp!ate

Eleetrlcal. Groii)I'--C
General-ToxiC oxides of nitrOgen may form in fire. Dangerous fire hazard. Flashback along vapor trail may
occur. Vapor may explode if ignHed In an enclosed area.
Flallro Po'nt ('F) .. 62

Flam-ble Ultl .. 1.6 to 2.3%
Atolaaition Tep. ('F) ... Unavailable
Ell:tlnplalllq Alfllb .... Water, CO,, dry chemical
SpedaJ Fire Proeedlll'ell .. Wear eye protection and sell-contained bfeathing apparatus.
HEALTH HAZARD DATA

Healtb Hll&llrd llldp Odor Thrnhold (ppm) PEL;TWA (p!MI) nvnwA c,..J
GeDeral-Uquid is irritating to the skin and respiratory tract and the vapor causes eye injury. High vapor
concentration may cause serious eye injury.
Sypto~a~-Eye, skin and respiratory irritation.
Sltort Expo111re Tolermee-The approximate lethal vapor concentration for a four hour exposure is reported to
the 4800 ppm in rats.
Expo111re Proc:edlua-Vapor-remove victim to freSh air; if breathing stops, apply artifiCial respiration. Oxygen,
admln"1stered by trained personnel, is often helpful. Skin or eye contact-immediately flood affected areas
gently with water. Remove contaminated clothing and continue to flush affected areas for 15 minutes. Get
medical attentiOn.
REACTIVITY DATA
StaiiWty-Stable.
CompaUbBitJ-Materlal: Corrodes copper and Its alloys in air; corrodes aluminum especially when wet.
Removes paint: swells rubber. No effect on carbon steel, wood, cloth.
Carso: Group 7 of compatibility chart.

Self-contained breathing apparatus of all-purpoaa canister maP: should be worn when contact is anticipated.
Wear impeMous gloves and safety goggles. Keep away from heal, spart>:s and open flames: avoid breathing of
vapors. Flush spill with large quantities of water. Secure Ignition sources.
H a .,W ocean, call die Natioal. a.,.._ Cater, 100-424 IIOl.

Re-a: t Unavailable
170
lao-HEXANE
Sy11H~ 2-Methyl pentane
CHRIS Code ..
Formllla-CHs(CH.}.CH(CH,},
BalliD& Poiat .. --.Q'C -----.HQ'F
Appeara~~Ce-(Hor-Colorless liQUid; gasoline-like odor c 'F
Fteuln~: Point.. -152'C -242'F
Speclne Gralty-0.66 ___ c ---
Vapor Preuure lO'C (68'Fl (mmH8) .. -L1QO.....
Chemh::1.l Family-Saturated hydrocarbons Rehl Vapor Pnllue <)Ilia)... __a.g__
Vapor l"reAIU'e 46'C (115'F) (....a).. ___i.Q_
PoUutlon Catqory-USEPA - - - IMO ___JL_ Vapor Demllty (Alr = 1.0).. ____l,Q__
Applie~blt Blllk Rq. 46 CFR SllkUpter ........ ----'2....Q_ SoluiNlity in Water.. !nltl!ub!a
FlRE & EXPWSION HAZARD DATA

Grade-B or C: Flammable liquid depending on !lash point and Reid Vapor Pressure.
Electrkal Group-O
Genual-Dangerous. Keep away from sparks, heat, or open flame. Flashback along vapor trail may oocur.
Vapor may explode if ignited in an enclosed area.
F1ub Point ('FJ. -10

Flammable Limits . 1.7 to 7.0%
Autoipition Temp. ('F) .. 583
btinguisbin(l AKen1S. Carbon dioxide, dry chemical, water spray
Special Fire Proceduret .. Cool containers with water if exposed to fire. Water may be ineffective on lire.
HEALTH HAZARD DATA

Health Huard R1tinp Odor Threshold (ppm) PELITW A (ppm) TLV/TWA (ppm)
0, 0, 1 Unavailable 500 Unavailable
General-Vapor slightly irritating. Liquid causes slight skin irrttation on contact.
Symptom-lnhalation causes irritation of respiratory tract. cough, mild depression, cardiac arrhythmia. Aspiration
causes severe irritation of lungs, coughing, pulmonary edema; excitement followed by depression. Ingestion
causes nausea, vomiting, swelling of abdomen, headache, depression.
Short Exposure Toleruce-Unavailable
Expo~~un Procedurn-lnhalation: maintain respiration, give oxygen, if needed. Aspiration: enforce bed rest;
administer oxygen. Ingestion: DO NOT induce vomiting. Get medical attention or advice. Eyes: wash with
copious amounts of water. Skin: wipe off, wash with soap and water.
REACI1VITY DATA
Stability-Dangerous; keep away from spar11.s, heat, or open flame. Can react vigorously with oxidizing
materials.
Com)lltiblllty-Matertal: Usual materials of construction are suitable.
Carao: Group 31 of compatibility chart. See also Appendix 1-Exceptlons to the Chart.

Avoid contact with liquid. Secure Ignition sources. Do not flush spill into confined spaces where flammable
vapors can accumulate.
It I .,W oee.n. call tiMi Nltlonal Relpoue Cellter, BIJ0..4l4 Blfll.

Rem11rb:
n-HEXANE
S)'DOII)'-- Hexane; Hexyl hydride; Normal hexane
CHRIS Code ....
.....
Bolllna;Poltlt ....
c ___.,
___.W!'C ___J.>'F
c ___.,
A~lorlesa watery liquid; gasoline-like
Freezin11 Point .. -94'C --=.laZ'F
Spectftc Gnlrity-0.66
Vapor Preslure 20'C (68'FJ (mmH&) .. --lliL
Ote.kaJ F-lly-Saturated hydrocarbon Reid Vapor Preuure (piJa)... ____o.Q_
Vapor PreetuR 46'C (liS'FJ (ptil) .. ____:u_
Polltlcm CateaorJ-USEPA - - - !MO _l;__ Vapor Delltity (AJr = l.DJ ... ---llL
APf]bble Bait Rq. 46 CFR SubdN!pter ........ ____D...Q.._ SoluWUty In Water .. !nsoJubl
FIRE&: EXPLOSION HAZARD DATA

Gnlde-C: Flammable Hquld
Electrkal Gro..,_o
Geaerai-Fiuhbacll. along vapor trail may occur. Vapor may explode if ignited in an enclosed area.
Fa.ll PoJnt ('F) ... -7.0

..,__ble UIU .. 1.1 to 7.7%
AutoJpltl011 Temp. ('FJ . 500
EniiiJIIieldal Aaml .. Dry chemical, foam or carbon dioxide.
Spedal Pin Procedure. ... Water may ba ineffective on lire. Cool fire exposed tanks with water.
HEALTH HAZARD DATA

Health Huard ltatb!p Odor l'hnlbold (Jipm) PEL/TWA (ppm) TLV/TWA (ppm)
0,0, 1 Unavailable 50 50
GeDerai.-Minor skin Irritant. Irritation caused by vapor inhalation. n-Hexane is toxic by ingestion.
Sylll]Jtomt-lnhalation causes irritation of respiratory tract cough and mild depression. Aspiration causes severe
lung Irritation, coughing and pulmonary edema. lngeation causes nausea, vomiting, swelling of abdomen,
headache and deprassion.
SINJrt l:zponre Tohruce-30,000 ppm vapor concentration causes narcosis of rats in one hour. 0.5% vapor
concentration caused distinct dizziness and giddiness of humans in just ten minutes.
ExpoAre Proeedva-Vapor-remove from area and administer arfif1cial respiration, if necessary, and then
oxygen. Eye-wash immediately with copious amounts of water. Ingestion-DO NOT induce vomiting. Get
medical attention or advice.
REACI1VITY DATA
StllbJIIty-Stable.
CompaUbUity-Materlal: Certain plastics are unsuitable.
Cu-to: Group 31 of compatibility chart.

Wear rubber gloves, face shield and protective clothing. Have ell purpose canister mask available. Gas
leak-keep concentration of gas below exploaiva limits by forced ventilation. liquid-ab&ortl on paper and
dlacharge paper. Secure ignition sources.
H a ipiU occur., can tbe Nadoul. RelpoDR Ceater, 800-4Z4-880l.

Remuka:
172
HEXANOL
Synoay- Alcohol C-6; Amyl carbinol; 1-Hexanol;
n-Hexanol; HelCanots; Hexyl alcohol; n-Hexyl
alcohol; 1-Hydroxyhaxane; Pentylcarblnol
CHRIS Code ..
Bolli,. Point.. ____lli"C __ill"F

Appeannce-Odor-loriess liquid: mild-sweet odor c 'F
Freezbll PfNat ... - 52'C - 62'F
Speelftc Grnlty-0.82 ___ c ___ F
Chendeal FUlily-Aicohol
Vapor .._re 20'C (68'F) <mmH&).. _.d.JL
ReJd Vapor P.--e (....)... ___.Q.Z5...._
VIIJMN'rr-re 4Ci'C (115'F') (plill).. __l,.QQ_
PoUutlon c.tqory-USEPA - - - IMO _Q_ VIIJIOI' ne.ily (Ak = 1.0)... _J.52_
Appllet~ble Blllk Rea. 46 CFR S11.bcbapter ....... ____c__ Solabillly Ia Willer.. Slight
f1RE & EXPWSION HAZARD DATA

EJeetrieal Group-O
F111Sb Polat ('F) .. 140

Fllimmable Limits .. 1.2 to 7.7% (calculated)
Autoipdtlon Temp, ('F) .... 559
ExtiaguisblliR A&eats .. Carbon dioxide, dry chemical, alcohol toam, water spray
Special Fire Procedurn .. Water may be ineffective on fire.
HEALTH HAZARD DATA

HeaJtb Hazard lbtlap Odor Thruhold (ppm) PEL/IWA (IIJIIII) UV!TWA (,_)
unavailable Unavailable Unavailable Unavailable
General-Practically non-toxic. Handle as a detergent.
Symptom-Similar to alcohol intoxication.
Sltort ExpotUR Toleran-Saturated vapor not fatal.
Expo1ure Procedura-Vapor--remove victim to fresh air; il bfeathing stops, apply artificial respiration. Skin or
eye contact-remove contaminated clothing and gently flush affected areas with water lor 15 minutes.
REACTIVITY DATA
StabUity-Stable.
CompatJbUity-Mterlal: Usual materials of constructioo are suitable. May soften some paints and plastics.
CU,o: Group 20 ol compatibility chart.

Wear chemical gloves and goggles. Avoid contact with liquid. Secure ignition sources.
U IJiill oec:un, alii tile Nadoul Relpoue Center, -...:z4 IIOl.
173
HEXYLENE GLYCOL
SJIIOilJ-- 2-Methyl-2,4-pentanedlol; Ulted Nlltlon1 Number .....
Trimethyltrimethylene glycol; alpha, alpha,
alpha'-Trimethyltrlmethylene glyCOl
CHRIS Code ..
F-ula-(CHo).COHCH.CHOHCH,
Bollillg Polllt .. _____ji'C ~F
A~--Colorless liquid; slight odor c ___ 'F
Freem1 Potat... -soc
c ------=3'F
___ 'F
Spedftc GnYI.ty-0.92
V1por Preaure lO'C (68'F) (DuDH&).. . ~
a.e.kal F-Uy-Giycol Reid V!lpOr Pr..ure (ptla)... ......L.s:riL..
Vapor ~ure 46'C (ll!I'F) (]Jiia)... ____ruu_
Poll~&doll Cateaorf-USEPA - - - IMO __llL_ VlfQr Denllty (Alr = l.Ol ......................... ~
APf]kabh Bulk Jles. 46 CFR SubcUpter ....... _____.D__ Soi11NUty 1D Water.. Cqmplfllfl

Eledrlad Group-O
GeMrai-Moderate hazard, when exposed to heat or flame.
Ft..h PoUlt C'F) .. 205

F'lanunable UmJts .. 4.710100%
AulcNpltto. Temp, ('F) ... greater than SOO'F.
Extbi&WAina Aaeats ... CO..dry chemical, alcohol loam, water fog
Special FJrt Pnlc:edllrn .. Water or loam may cause frothing.
HEALTH HAZARD DATA

Healdro Huard Rafulali Odor Threlbold (Pflll) PEL/IW A (ppm) TLV!TWA (ppm)
1, 0, 0 less than 50 25 25
Geaeral-Vapor irritating to skin and eyes at high concentrations. liquid very irritating to eyes, slightly irritating
to skin.
Sylllpto....-Headache, dizziness, nausea: strong local irritation of the eyes, nose, and throat: and respiratory
discomfort.
Sltort ExpoPre Tolerance--1 ppm for 30 minutes.
Ezpo1ure Proeedww-Remove victim to fresh air. Give artificial respiration if necessary. Wash spilled liquid from
skin with water. Get medical attentiOn if rash develops or if victim has any breathing difficulty.
REAcriVITY DATA
Statllllty-Raacts with strong oxidizing agents.
Compatlblllty-Material: Usual materials of construction are suitable.
Carp: Group 20 ol compatibility chart.

H a IJilll 0111'1, eaJI the Natioul llelpoue Ceater, 800-4l4-81102,

Renwkl: t UnasSigned
174
HYDROCHLORIC ACID
SyllOIIYmt- Chlorohydric acid; Hydrogen chloride;
Muriatic acid
CHRIS Code ..
ForMula-HCI (dissolved in water)

BoW& PoJDt . .. ______lll!"C --Za2'F
Appearance-Odor-Colorless to light yellow liquid; c 'F
irritating, pungent odor FreeziD& Polat.. -ZB'C -105'F
Speeiftc Gnlty-1.01 to 1.21 c ---
Vapor Preuure lO'C <68'Fl <118).. ___212._
Cliemleal Family-Inorganic acid Reid Vapor P~re (pRII)... ~
VapM Preuure Ui'C (115'F) (f~Ma)..... ~
PoHution CateaoQ-USEPA _____Q__ IMO _JL_ V1por Oe.ity (Air = 1,0) .......................... .-..1..2_
A"lie-ble Bulk Rea;. 46 CFR Subclupter ... ... _Q__ SolubWty ill Water.... Comelt!e

Gr...e-Non-flammable. Classified as a corrosive liquid.
Electrical Group-S (based upon possible hydrogen gas (H 2) generation should a leak or spill occur)
GeneraJ-Hydrochloric acid wHI not burn. It wiH react with many metals, giving off hydrogen gas which is highly
flammable. II hydrogen Is trapped in confined spaces, it can form an explosive mixture with air. See data
sheet lor hydrogen. Toxic and irritating vapors are generated when heated.
Flub Point ("F) ... Non-flammable
Flammable Llm1ts. Non-flammable
Autoipition Temp, ('F) ... Non-flammable
Extlnpis.bina; Atn~ts .. Non-nammable
Special Fire Proeedura ... Acid tanks exposed to a lire shCMJid be cooled by a water spray. Fire parties
must wear respiratory protection in order to avoid breathing acid vapor. Full protective clothing must also be
worn.
HEALTH HAZARD DATA

Health Hazartl Ratiop Odor Thrabold (ppm) PEL/I'W A (ppm) n
v nw A <ppm>
3, 3, 2 1 to 5 5' 5'
General-Inhalation of gas results primarily in irritation of upper respiratory passages. Liquid severely irritating to
skin and eyes.
Sympt01111-Where touched by liquid, the skin may tingle or bum. Breathing the vapors will cause severe
coughing and watering of the eyes
Short Expo~~ure Toleranee-lnl"lalation of 1500 ppm in air are fatal in a few minutes.
Expo~ure Proeedurn-Vapor-remove victim to fresh air; if breathing stops, apply artifiCial respiration. Oxygen,
administered by trained personnel, is often helpful. Skin or eye contact-remove contaminated clothing and
gently flush affected areas with water lor 15 minutes. Get medical advice or attention.
REACI'IVITY DATA
Stability-Reacts with bases (caustics) to generate heat.
Comp~~tibillty-MaterW: Corrodes many metals, causing the evolution of hydrogen gas. lroo and aluminum are
corroded readily.
CArJO: Group 1 of compatibility chart.

Wear rubber gloves, sell-contained breathing apparatus, protective clothing. Have body shield available.
Secure Ignition sources. If possible, cover the contaminated surface and spill with sodium bicarbonate or a soda
ash, slaked lime mixture (50-50). Mix and add water if necessary to form a slurry. Scoop up slurry. Wash site
with soda ash solution.
If a lpJH Geelll"at eall tlte Natioaal Rapoae Cater, 100-424--81102.
ReiUI"b: PEL and TL V based upon hydrogen chloride gas.
175
(NOTE: Thl c.rgo I ~tty not pennltt.cl to be ahlppH In bulk In U.S. w.t.,.)
HYDROGEN (Liquefied)
S)'JIOIIyng-LH,; Liquid hydrogen; Protium United Natfnu Number .. compressed
relrigerat~;~d
CHRIS Code ..
Fonnu.la-H,
BoJII~tl Point .. ~c ---=.m'F
Appearuee-Odor-Colorless gas or liquid; odorless c 'F
Freezin1 Polnl.. -259"C ---=i3sF
Specific Gr~Yity-0.07 at b.p.
c ___.,
Vapor P,_re lO'C (68'F') (mmfl&) .. ..Y..llioll.
Chemical Family- Reid Vapor PnaiD'e (plla) ... ..Y..llioll.
Vapor Prealure 46'C (li!I'F') (pl.la).. ..Y..llioll.
Pollution Catqory-USEPA - - - JMO __iL_ Vapor Dellltity (Air = 1,0)... __Ml_
Applicable BuJk Rea, 46 CFR Subdulpter ....... - - - Soluhlllty In Water. Nsgljgjblt

Grade-liquefied Flammable Gas (LFG)
Electrical Group--8
Ge~teral-Will react violently wlth strong oxidizers. Will ignite easily with oxygen. Vapors form explosive or
combustible mixture with air over a wide range of concentrations. Flame is almost invisible. Flashback along
vapor trail may occur. Vapor may explode if ignited in an enclosed area.
Flub Point ('F) ..
Fllllllllable Umlts ...
Autolpidon Temp, ('F) ..
"" 4.0 to 75%
1075
ElF:tfnpl&blq Apnt& .. First stop flow of gas. CO., dry chemical, water
Spec.lal Fire Procedul'ft .. Source ol hydrogen MUST be eliminated before lire is put CHJt to prevent
accumulation of explosive vapors. If the insulation fails on a liquid hydrogen tank exposed to fire, the tank
will explode; evacuate firefighters and have them take cover.
HEALTH HAZARD DATA

Health Hazard Ratfnp Odor Thl'ftbold (ppm) PEL/TWA (ppm) TLV!TWA (ppm)
Unavailable Odorless Unavailable Unavailable
Geaerai-Simple asphyxiant. Not considered toxic. Avoid skin contact with liquid.
S)'Jdptoms-lnhalation. Drowsiness and highpitched, squeaky voice. Skin contact: Numbness and whitening of
skin at the area of contact.
Short ElF:posure Tolerance-Unavailable
EJ:PGAR Proceduru-Remove victim to fresh air; il breathing stops, apply artificial respiration. II the liquid has
damage. DO NOT RUB. Get medical attention immediately. Avoid spalks and open flames.
REACTIVITY DATA
Stability-Will ignite readily when exposed to spark source. Liquid hydrogen will !lash into vapor at temperature
above -400'F resulting in a sudden and large increase in pressure if confined.
C0111patlbU1ty-Materlal: Mild steel and most iron alloys become brittle at liquid hydrogen temperatures.
Aluminum and stainless steel (300 series) may be used.
Carao: Not shipped in bulk.

Secure all nearby Ignition SCHJrces immediately. Isolate spill area and call local fire department and the
Captain of the Port, U.S. Coast Guard. II the liquid does not catch lire, it wlll soon boil off and leave no residue.
If 1 1)1111 occurs, tall tbe Natioaal RtQOUe Ceater, IIIXI-4l4 810l.

Remarb: Bulk ~lpmenta not permitted.
176
HYDROGEN PEROXIDE
(72% or 1...}
Synonyms- Albone; High-strength hydrogen peroxide; United Nations Number ....

HiOxyl; Hydrogen dioxide; Hydroperox1de; Peroxide;
Superoxol
CHRIS Code ..
Formula-H,O,
Bollin& Point. _____.115'C _____lli'F
Appearanc:eOdor-Colorless watery liquid; slightly sharp c 'F
odor. Freezing Point. -40'C -----:4(iF
Specinc Gravity-1.29 or less
___ c ___'F
Vapor Pressure lO'C (68'F) (nunlla) ..
Chemle-1 Family- Reid Vapor Pressure (plia)... ....YmiiL
Vapor Pre.ure 46'C (115'F') (pda).. .Jlldu....
Pollution Cltegor}-USEPA - - - IMO _____Q__ Vapor Denatty (Air = 1.0)... ............. ...YidiL
Applkable Bulk Reg. 4(i CFR Subchapter __Q__ Solubility In W.ter.. Soluble

Grade-Not applicable
Electncal Group-Not applicable
General-Not flammable but may cause fire and react violently with combustibles and metals. Powerful oxidizeJ.
May cause fire and explode on contact with combustibles and metals.
tlash I'Qint ('Fl Non-flammable

Flammable l.imits Non-flammable
Aut<~i!lnili<~n Temp. CFl Non-flammable
Elltinjluishin!l Agents Non-flammable
Spt'l."ial Fire Procedures. Powerful O~tidizer Wear protective clothing including self-contained breathing
apparatus Flood discharge area with water.
HEALTH HAZARD DATA

Health tlal.llrd Ratings Odor Threshold (ppm) PEL/TWA (ppm) TLV!TWA (P!MII)
2. 3, 1 Unvailable 1 1
General-Vapor 1s 1mtat1ng
Symptoms-Vapors cause eye and nose discomfort in moderate concentrations; less than 52% causes
temporary imtallon. Above 52% can cause blisters and eye damage.
Short Exposure Tolerancc-77 ppm for 30 minutes
Exposure Procedures-Avoid contact, immediately flush with water. It ingested give water, induce vomiti"lg it
conscious. Remove contaminated clothing and shoes.
REACfiVITY DATA
Stabilit)-Pure grades are stable. but contamination with metals or dirt can cause violent or rapid
decompOSIIIOn
C<~mpatibilit)-1\taterial: Incompatible with iron. copper, trass, bronze, chronium, zinc, lead, manganese, silver,
and catalytic metals.
Car11o: Unassigned 1n compatibility chart. For compatibility assistance, call

G-MTH-1 (202-267 -1577).

Wear protective inner and outer clothing, impermeable apron, neoprene gloves. Flush area with water. Isolate
matenal from contacting flammable liquids or combustible materials. Evacuate area for at least 112 mile it fire
exists
If I _!pill occurt, call tbe National Rmpo111e Ceater, ~.
Remarks: Vapor Pressure: 5 mmHg at 86'F.
117
2-HYDROXYETHYL ACRYLATE
S)'DOIIYIIIII- Ethylene glycol monoacrylate: HEA; United Natlone: Number ....
beta-Hydroxyethyl acrylate; 2-Hydroxyethyl
2-propenoate
CHRIS Code ..
Form11la-H.C = CHCOOCHoOH
BoUiag Point .. ---"llQ'C ~F
A.ppearane41..Qdor-Colorless liquid with sweet odor
___ c _ _ _ 'F
Freezing Point .. ~c ----=.22.'F
Speclfk Gra-.lty-1.1 0 c _ _ _ 'F
Vapor P.--ure lO'C (68'F) <mmHg) .. ...~.""-.
Cbemkal Family-Monomers and polymerizable esters Reid Vapor Preuure (PIJial... ...~.""-.
Vapor Preuure 41S'C (115'F) <P'IaJ .. ...~.""-.
Pollution C.teaory-USEPA - - - IMO __a___ Vapor Density (Air = I.OJ .. --l>IL.
Applicable Bulk Reg. 46 CFR Subchapter ....... ____Q__ Solubility ba WatH .. Complete

Electrlul Group-O
General-Moderate lire hazard; however, dangerous when exposed to high temperatures due to liberation of
toxic fumes.
Flub Poi11t ('FJ .. 220

Flammable UnUts .. LEL=1.B% UEL-unavailable
AutoiiPIItlon Temp. ('F) .. Unavailable
Exdnguisldq Aaents .. CO., dry chemical, water, alcohol foam.
Special Fire ProcedllreS .. Wear eye protection, self-contained breathing apparatus, and impermeable
protective clothing.
HEALTH HAZARD DATA

Health Hazard Ratin.p Odor Tirore~~hold
(ppm) PEL/IWA (ppm) TLV/TWA (ppm)
General-Severe eye damage, irritated skin, serious "illness after ingest"1on. Class B poison.
SymptoiiUI-Watering of eyes, red or irritated skin.
Short Exposure Tolerance-Avoid inhalation of hot vapors. Irritation of skin upon short contact; burn after
prolooged contact. Animal tests show no deaths after ingestion.
Exposure Procedur-11 swallowed, induce vomiting; remove victim to fresh air if any ~I effects from breathing
vapors are felt. Flush eyes and skin immediately after contact for approximately 15 minutes. Call a doctor.
REACfiVITY DATA
Stability-No spontaneous decomposition, but can polymerize.
Compatibility-Material: Corrodes mild steel, tin plate, and polymerizes. No effect on stainless steel, aluminum,
or mild steel with phenolic resin surfaces. Swells rubber, removes paints.
Car10: Unassigned in compatibility guide. See Appendix !-Exceptions to the Chart.

Wear eye protection. Neoprene rubber or other impermeable protective clothing should be worn. Secure
ignition sources.
If a api]l oc:a~n. WI the National Re1p0111e Center, 800-424-8802.

Re....-ks: :j: Unass1gned
178
ISO* (as a prefix)
Loc* under ,...... compound
CHRIS Colle .. .
c
--.c
c ..
..
---'F
---
FreeD.. Poblt ...
VIIJICW
~c
rre..u. lO'C (61'F') {-"~) ..
==F
Reid Vapor rr-e (,.ta>...
v.,_ ~
PoUadola c.tqory-USEPA - - - IMO - - -
Apptici!We Bulk Ilea. 46 CFR S.r.ca.,ter ....... - - -
v.,... De.itJ' 46'C (115'F') (plla)
(Air = 1.0) .......................... - - -
Selllbftlty ill Waler ..

Gnde-
Elec:trical Group-
Genera.l-
F1ub Poiat ('F) ..

FJ...mable UmiU.. .
Autoipltion Temp. ('F) ..
E~:tlnpUblq; Ap:atl ..
Special Fire Proeedute11 ..
HEALTH HAZARD DATA

Healtb Huard lbdap Odor 1'llrelltohl <pp.J PEL/TWA~I TLVII'WA (ppm)
General-
Sympt-
Short Exposure Toleruee-
Exposure Proeedllf'a-
REACfiVITY DATA
SI.IIMIIty-
Com)Nitlbility-Material:
""""
If a llplll oc:cart, call tM Nadoal a.,._ CUter, 1100-424-IIOl.

ReiUJ'b: For example, if you wanted to look up iso-propyl alcohol it would be shown as iso-PROPYL
ALCOHOL under "P" not "1".
179
ISOPHORONE
s,-,.-lsoacetophenone; UnUed NM:IOIQI Number ...
3,5,5-Trimethyl-2-cyclohexeoe-1-ona
CHRIS Code .
-
Fona........C(O)CHC(CH.)CHaC(CH,)tCHI
BoUID1 PoUlt .. ~-c ______!!i'F
~Water white liquid; peppermint-like c 'F
FYeez1na: Polat ... -S'C lZ"F
S]ledfte Gr.rily-0.93
___ c ___"F
Vapm Preuure lO'C (68'F> <m-H&).. ____2.L
a.-tclll. P..Uy-Ketone Reid Vapol' Preaure (pita)... -L&L..
VllfOI' PreiiiU'e 46'C (ti5'F.I (plla)... ~
Poll.t1oa CateterJ-USEPA ___D.__ IMO ___Q__ Vapor Deul.ty {Air = 1.01 .......................... ~
A.,UC.ble B111k Jlea. 46 CFR Subdlapter ....... ___Q__ Solubility Ia Water.. Slight

~GnN,_D
Ge.en&-Moderate fire hazard when exposed to heal or flame.
Flula Point ('FJ ..... 184

F'luuWIIe IJ.Itl .. 0.84to 3.8%
A11toipltl011 T-p. ('F') .. 860
Eli:tblaallldJII AFJ~tl ... Water spray, carbon dioxide, dry chemical or foam.
Special Flre Proeed,urw .. Use water spray to diSperse vapors. Water may be used to flush spills.
HEALTH HAZARD DATA

Heald! Huard Ratiap Odor Drelllold (ppm) PEUJW A (ppmJ TLV/1WA (p..-l
GeDeral-Highly toxic, strong irritant to skin and eyes.
S,...,c-Eye, nose, and throat Irritation; narcosis.
Sllort Es.po~~~re Tolenmee-25 ppm is an irritant to most humans. Animal tests resuHed in eye injury and slight
skin irritation after 24 hours; inhalation killed 1 of 6 animals in 8 hours.
kpolure P'rotedtlre.-Remove victim to fresh air and use oxygen. Flush eyes for 15 minutes with water. Wash
off skin. Get medical help.
REACI1VITY DATA
StUWty-Stable.
eomp.tlbWty-Material.: Steel ia satisfactOI')'.
Carao: Group 18 of compatibility chart. See alSo Appendix !-Exceptions to the Chart.

Wear rubber gloves, face shield, and protective clothing. Secure ignition aources. Have all-purpose canister
mask avaMable. Keep unprotected personnel upwind. Flush spill with water.
It IJIW 0mt, Cllll tile Nlltloaal Relpoae Cuter, 8(10..424-IIOl.

RtiiW'ka: t Unassigned
180
ISOPRENE
Syaonyms- beta-Methylbivinyl; 2-Methyl-1,3-butadiene; United NK10111 Number .....
3-Methyl-1 ,3-butadiene
CHRIS Code.
Fonnala-CHo = C(CHo)CH = CH,

Bollin& PoiDt .. ~c ____.ia"F
Appearuce-Odor-Colorless liquid; mild aromatic odor
Speellie Gr..lty-0.69
Freezl.na; Point ..
c
-14fi'C
___
Vapor Pre.ure lO"C (68'F) (.aHJ} ....
c ___
-231'F
..
"F
Cbeakrol Family-Oiefins Reid Vapor Preatlre (plill) ... __lO.lL_

Vapor Pre~~are 46'C (115'F) (....) .. ....ruL
Polhatlon c.teaorJ-USEPA _____a__ IMO __c__ Vapor Density (Air = 1,0) ... ....uL
Applleallle Bulk Rq. 46 CFR SubcHptu ...... ~ Solultillty In Water .. jnQ'"h\e

Electrleal Group-O
Generl-ln a fire, polymerization may occur and violently rupture the container. II is recommended that
isoprene be stored under an inert atmosphere (preferably nitrogen) with at least 50 ppm tert-butylcatechol
present as an inhibitor. Keep away !rom sparks, heat or open flame.
Flub Point C'f1.. -65
FI-IUble U111it5 .. 2.0 to 9.0%
Autoipltion Temp. ('FJ 428
Extlnplshklg Aletlb .. Carbon dioxide, dry cherTHcal, foam
Spedal Fire Procedurea Cool exposed tanks with water spray.
HEALTH HAZARD DATA

Healtll Hazartl Ratinp Odor Threabold (ppm) PEL/TWA (ppm) TLV!TWA pp.l
1,1.1 0.005 Unavailable Unavailable
General-Isoprene is an irritant to mucuous membranes of the eyes, nose, and upper respiratOI"y passages.
Sympt-Vapor-Eye and upper respiratOI)' tract irritant. liquid may irritate eyes.
Short Expo~~ure Tolerance-No data on human exposure are available but concentrations of 5% in air are fatal
to mice.
Expo~~ure Proadur-Remove to fresh air. In case of contact with liquid immediately flush skin or eyes with
water for at least 15 minutes; remove contaminated clothing and shoes at once. Call a physician.
REACTIVITY DATA
Shoblllty-Readily oxidized, polymerized. Should be inhibited to prevent polymerization.
Comptllllllty-Materlal: May soften some types of rubber or paint.

Wear rubber gloves, face shield, protec!Ne clothing. Have all-purpose canister mask available. Avoid contact
with liquid. Secure ignition sources. Do not flush spill into confined spaces where flammable vapors can
accumulate.
If a I)IIU oecun, call the National RtlfOIIH Cuter, II00-4J4..8102.

Remarks: Vapor Pressure: 400 mmHg at 15'C.
181
KEROSENE
Syn011yms- Coal oil; Fuel oil no. 1; Illuminating oil: Ulll.ted Nations Number ....
Kerosine; Range oil
CHRIS Code ..
Fonnula-Mbch.re ol hydrocarbons
BolllntPolnt.. ~c ~F
AppeariiiJCe-()dor-Pale yellow to watet white oily liquid;
c ___ "F
strong odor freezing Point... -45'C ~F
Speclfte Gr..lty-0.81
___ c ___ "F
Vapor Preaare ZO"C (68'F) (mmH&) .. ____2..Qi_
Olemlcal Family-Petroleum oil Reid Vapor Presaure (ptla)... ___.QJ__
Vapor Prellllle 46'C (ll!I"F) (!Mila)... .......Q..1L
PoUudoa C.tegory-USEPA - - - IMO _.1__ Vapor Deuity (Air = t,m... ............ ~
Applleallle Blllk Rea, 44!i CFR Sbcbapter ....... _____Q__ SolubiHty iD Water.. Negljgjble

Electrical Group-O
Geaeni.-Fiammable, modetate risk.
FJqb Point ('F) .. too to 150

Fl-mahle UMits .... 0.7 to 5.0%
Autolp.ltiOII Temp. ('F) .. 444
E:t.tlllpithillg Ajeabl .. Confined area-CO,, dry chemical. Open area-foam, water fog.
Special Fire Proeecluret .. Tanks exposed to fire should be kept cool with a water spray. Water may be
ineffective on fire.
HEALTH HAZARD DATA

HeaJtb Huard RtiDP Odor t'brabold (ppm) PEL/TWA (ppm) TLVlfW A (ppm)
1, 1,1 1 Unavailable Unavailable
Geaeral-Moderately toxic by ingestion and inhalation.
S)'lllptollbl-lnhalation: Marked vertigo, inability to walk a straight line, hilarity, incoordination, intense burning in
throat and lungs, possibly bronchopneumonia, nausea, vomiting.
SJ.ort Eipo~ure ToletiiRCe-Unavailable
E:i;ponre Ptocedwe&-lnhalation: Remove victim from comam1nated atmosphere. If breathing is interrupted,

artificial respiration should be applied immediately. Call a doctor.
REACTIVITY DATA
Stability-Stable.
Compatibility-Material: Most metals are suitable, but kerosene causes rusting of steel.

Wear rubber gloves, face shield, protective clothing. Have all-purpose canister mask available. Secure ignition
sources. Small spills may be flushed away with water.
If 1 apUI oceun. call tlte N1tlonal ReapoDM Center, 800-4~2.
Remuka:
182
LIQUEFIED NATURAL GAS
Sy-yma- LNG; Methane, relngeraled ltquid, or United NatiOM Number ., compressed
Natural gas; refrigerated liquid refrigerated
CHRIS Code ..
ForJDviii-Mixture of CH, and C.t-k

Boillq Poblt .. -=.W. c ----=.23:'F
Appearu~ee-Odor-Colorless liquefied gas; usually c 'F
odorized to give a weak skunk like odor Freedq Point .. -182'C -2g'F
Spedftc Gnrl'ity-0.41 to 0.45 at -162'C ___ c ___ 'F
Vapor Pret~A~re lO"C (61'F) (nun.H&) .. _jjJgb_
Chekal Funlly-Paratfins Reid Vapor ~re ~) ... _jjJgb_
Vapor Pranre <M'C (ll!'F) (peia) .. .....l:llsiiJ..
PoUiltkm Cateaocy-USEPA - - - IMO ~ Vapcw ne.lty <Ail' = 1.0) .. , Mhl.l!
Aptllkable Bulk Reg. 46 CFR Subctlapter ..... ___Q._Q_ SolubHity ill Water ... lrwlubft

Grade-liquefied Flammable Gas (lFG)
Etectrinl Group-O
~11erai-Contaiflers may explode in fire. Vapor may travel to ignition SOIJfce and flash back along vapor trail.
Unless the flow of gas can be stopped, putting out an LNG lire will permit the accumulation of an explosive
concentration of vapor and subsequent explosion or rellash.
1'111111 Point ("f/ Flammable gas
Fb11am.Ule Limits 5.3 to 14.0%
Autoipaition Temp. ("1'1. 999
Extinguishing Agt"nts Stop flow of gas; Dfy chemical for small fires.
Special Fire Pr~edures Use water to cool exposed tanks. Do not eKtinguish large spiD fires. Allow to
burn While cooling adJacent equipment with water spray.
HEALTH HAZARD DATA

Health Haunt R1tinp Odor Thresbold (ppm) PEL/IW A (ppm) TLV!TWA q.p.l)
0, o. 0 Unavailable Unavailable Unavailable
Generii-Vapors are non-1rntating to eyes and throat. Uquid will cause frostbite.
Symptoms-It concentration of gas is high enough, may cause asphyxiation. No systemic effect even at 5%
concentration 1n air
Sbort E:xpo~~ure Tolerance-Data not available.
Exposure Proc:e~h1res-Vapor-remove victim to open air. Administer artificial respiralkm if necessary. If the liquid
has spilled onto the skin, points ol contact may be frostbitten; handle gently and protect from mechanical
REACTIVITY DATA
Sblbility-Stable.
Compatibility-Material: Stainless steel, nickel steel and aluminum are suitable.
Carsw. Group 31 of compatibility chart.

Wear rubber gloves, face shield, protective clothing. Have all-purpose canister mask avaHable. Secure Ignition
sources. Call lire department. For leak from faulty tank keep concentration belOw flammable limits by forced
ventilation. If the LNG does not catch lire, it will soon boil off.
If a .,UI oeeun, eall dtC! NatloDal RetpODM Center, 100--<'24-81102.

Re.....-kl!
183
LIQUEFIED PETROLEUM GAS
SynonyiU- Bottled gas; LPG; Petroleum gases, United Natiollll Number ..
r1quelied; Propane-Butane mixtures; Pyrofax
CHRIS Code ..
Formula-Mixture of CoHo's and C.H 10

Boilinl Point .. ~c
c ___
___
~F
.,.,
Appearuc:e..Odor-Co!OOess compressed gas, with faint
skunk odor
Specific Gra,-lty-0.51 to o.sa at -soc (liquid)
Freezlna: Point .. ......Jil'"C
___ c ___.,
Vapor Preaure 20"C (68"FJ (mmHK) .. __!jjgfi_
Chemical Family-Paraffins Reid Vapor Pres~~ure (IJI'Ia) .. ....l:liob....
Vapor Pres~~ure 46"C filS" F) (psia) .. __!jjgfi_
Polltlon ~-USEPA - - - IMO __....W_ Vapor DeasJty (Air = 1.0) ... -l.L-
Appllc:ahle Bulk Re11. 46 CFR Subdtapter ...... __,..Q._Q_ Solubility In Water ... !nsglub!e

Gnute-Liquefied Flammable Gas (LFG)
ElectrkaJ Group-O
GenuaJ-Containers may explode in fire. Vapor is heavier than air and may travel a long distance to a source
of ignition and flash back. Unless tile flow of gas can be stopped, putting out an LPG fire wilt permit the
accumulation of an explosive concentration of vapor and subsequent explosion or rellash.
f1uh Point {F) .. 156
~JelJmjf:t .. 2.2 to 9.5%
Alltoipffion Temp. (F) .. 871
Extlnpidllng Agentt. Stop flow of gas; Water {Let fire burn)
Special Fire Proeedura . Allow to burn while cooling adjacent equipment with water. Shut off leak if
possible.
HEALTH HAZARD DATA

Health Hu.rd Ratlnp Odor Threshold (ppm) PEL!TWA {ppm) TLV!TWA (ppm)
0, 0, 0 5000 to 20000 1000 1000
General-Not irritating to eyes, nose or throat. If inhaled, will cause dizziness. Liquid will cause frostbite.
Symptollllii-Concentration in air greater than 1O% causes dizziness in a few minutes. High concentration cause
asphyxiation.
Sbort Expo~~ure Tolef11Dee-None
E~:JI(JHre
Proeedurm-Vapor--Jemove victim to open air. Administer artificial respiration if necessary. If the liquid
has spilled onto the skin, points of contact may be frostbitten; handle gently and protect from mechanical
REACTIVITY DATA
StabUity-5table.
ComJ111tlbUity-MateriaJ: Stainless steel, nickel steel and aluminum are suitable.
Carao: Groop 31 of compatibility chart.

Wear rubber gloves, face shield, protective clothing. Have all-purpose canistel" mask available. Secure ignition
sources. Call fire department. For leak from faulty tanks, keep concentration below flammable limits by forced
venfrlatlon. If the LPG does not catch fire, it will soon boil off.
If a apW oeeurt, can the NatioaaJ Reaponse Ceatet-, 800-4U-880:Z.
184
MALEIC ANHYDRIDE
SynonYJQ- cis-Butenedioic anhydride; 2,5-Furandione
CHRIS Code ..
Apptlll'allce-04or-Colorless liquid, white sol1d (as Bollin& Point. ... __wc _w!'F
needles, crystals or fused tablets): acrid, choking c 'F
odo Freezina Point. ~c HO'F
Specific: Grnlty-Molten: 1.3 at 70'C; Sold: 1.48 at c _ _ _ 'F
15'C Vapor Preuure :ZD'C (68'F) (mmH&) .. ....Q.1L
Chemlc:al FanUiy- Reid Vapor Prasure (psla) ... ___t_
Vapor Preaure .tfi'C (115'FJ (~a) ... ___t_
Pollud011 C.tepry-USEPA ___....lL_ IMO __Q__
Applicable Bulk Rq. 46 CFR Subchapter. ___Q__
Vapor Den1ity (Air = 1.0) ..
Solubility In Water ..
~

Eleetric:al Group-O
General-Mild fire hazard. lnertion with nitrogen recommended to avoid reaction with water vapor. When heated,
can decompose and overpressurize storage tanks.
Flub Point ('FJ 215 (cc); 230 (oc)

Autoipltlon Temp. ('Fl .. 878
Etinpihina AKC!nts .. Alcohol foam, carbon dioxide
SptCial Fire Procedures .. Water and foam can cause frothing. Can react with dry chemical. Keep tanks
cool in fire by spraying water on them from safe distance. Wear self-contained breathing apparatus, and
HEALTH HAZARD DATA

Healtb Hazard Ratings Odor Tbreshold (ppm) PEL/I'W A (ppm) nv!TWA <ppm)
2, 2, 1 0.3 to 0.5 0.25 0.25
General-Will bum skin and eyes; dangerous to aquatic life.
Syrnpto11111-lnhalation: Moderately irritating, coughing, sneezing, bronchitis from chronic exposure. Skin:
Irritation, redness; dermatitis from chronic exposure. Eyes: Irritation, can be severe, tearing. Ingestion: Little
or no risk; nausea.
Sbort bposure Toleranee-limiled inhalation risk if space well ventilated.
bpopre Proeedura-lngestion: Induce vomiting. Inhalation: Remove to fresh air, give oxygen if necessary. Skin
contact: Flush with water for at least 15 minutes. Eye contact: Flush with water lor at least 15 minutes; call
physician. For skin contact with molten maleic anhydride, remove solid from skin and treat as normal
chemical and thermal burn, and wash with soap and water.
REACTIVITY DATA
SU!Itlllty-Generally stable. When heated in presence of alkali metals or amines (even in low concentrations of
200 ppm), decomposes rapidly and can overpressurize tanks. Reacts with strong oxidizers. No reactivity
except in presence of water (corrosive).
eo..,.dblUty-Materlrll: Not corrosive to metals except in the presence of water.
ClfiO: Group 11 of compatibilily chart.

Use protective equipment including goggles, face shield, rubber gloves, rubber boots, coveralls, rubber apron.
Use organic vapor-acid gas canister. Dike and let spill solidify, then dispose. Alternative, add water to dissolve
spill (forming maleic acid) and n81Jtralize with soda ash, then dispose.
If a spill oecun, c:aU tbe NMJoaal Re1p0111e Center, 800-4l4-88(12.

Rentarks: HydrOI1zes slowly with cold water: frothing With hot water
t Unavailable
....
185
MESITYL OXIDE
SyiiOJl)'--lsobuteoyl methyl ketone; United NtloRI Number ...
laopropylideneacetone; Mathy11so-butenyl ketone;
Methyl isobutenyl ketone; 4-Methyl-3-penten-2-one:
iso-Propylideneacetone
CHRIS Code ..
Fonaula-(CH.)aC = CHCOCH,
Appearuee-Odor-Oily, colorless liquid; honey-like odor

BoUia1 Po'at ..
c .,
____J_al)"C ____.zllll"F
Spedflc: Grt,,lty-0.86
-59'C
___ c ___.,-74'F
Vapor Pre.llre :ZO"C (68'Fl <mH&) .. ....ll.._

Cllemkal FaaDy-Ketones ReHI Vapor Preullf'e (JIIia>... ___.1__
Vapor Prmlure 46'C (115'F') (r-laJ .. _.!I.L_
PoUIItloa Calepry-USEPA _ _ _ IMO ~ Vapor DeQJiy Wr = 1.0).... ....a.;_
Applialtle Bulk Rq. 46 CFR Subdlllpter .. . .. _il.._ Solabillty In Water .. !jght

Electrkal Gnlup-0
G.en&-Fiammable, danQ8rous fire risk, vapor forms explosive mixture wtth air. Flashback along vapor trail
may occur. Vapor may explode if Ignited in an enclosed area.
FIMII PtNat ('F) .. 84

Flammall1e LlmU .. 1.3 to 8.8%
AuhNpltioll Temp. ('F) .. 652
ExtlnpitlaiDa Ap~~tl ... Alcohol foam, carbon dioxide or dry chemical
Sfedal Flre Procedure~ .. Wear complete protective clothing and self-contained breathing apparatus.
Cool exposed tanks with water. Water may be Ineffective on lire.
HEALTH HAZARD DATA

Huldl Haard Ratlnp Odor 'I'hrMbold (ppm) PEL/TWA (ppt~~l TLV/TWA (ppm)
3,3,3 12 15 15
~oderately toxic by Ingestion, inhalation, and skin absorption.
Sym.ptonu-lrritation of eyes, headaches, coughing, difficult breathing, nose and throat irritation, mild
intoxication.
Short Eipo1ure Toleruce-5 minutes--100 ppm predicted eye and mucous membrane irritation with difficult
breathing, headache. Similar exposure at 800 ppm. Predicted severe eye and respiratory irritation. Vapor
cone. 500 ppm lor 30-60 min. considered dangerous to IHe.
EI)IOIIUI'e Proeed....-lmmedlately remove victim from exposure and treat on symptomatic bases. Aush skin
promptly with soap and water. If swallowed, do not induce vomiting. Get medical attention.
REACfiVITY DATA
Stability-Stable. Reacts wnh oxidizing agents: strong alkalis (caustics), and mineral acids.
CompatiblUty-Material: Non-corrosive to steel.
Carto: Group 18 of compatibility chart. See also Appendix !-Exceptions to the Chart.

Wear rubber gloves, face shield, protective clothing. Have all-purpose canister masll. available. Avoid contact
If a 111W ouura, eall die Nalloaal Jtapo.R Cmtel', 800-424-IIO:Z.

Remarks: t Unavatlable
186
METHACRYLIC ACID
Sy-ymt-alphe-Methacrylic acid; 2-Melt1ylacrylic
acid; 2-Methylpropenic acid: 2-Methylpropenoic
acid; Propanioic acid, 2-methyleoe
CHRIS Code ..
-
F-..Ja-CH. = C(CH,)COOH
A~Water-white
Spedtk Gra'rity-1.015
liquid with a vinegar-like
Botllq Polat ..
Free:ziq Po'nt ..
Vapor P-re zoc <61"Fl <..a.J ..

__wc
c
__l!"C
___ c
-
___..
___..
_____5I"F
__i__
Cllelal Family-Organic acid Rad Vapor p , _ (filM) ... ....I!J!g_
V11p0r ~re .M"C (llS"F) (pda) .. ..JlJI&1...
Polllltioa c.tegory-USEPA _ _ _ IMO _Jl_ Vapor Dealt)' (Ab' = 1.0) .. .....2.L.
A,Ua~ble Bulk Re1. t6 CFR Subchapter ___Q__ Soi"PbWty b1 Water .. SQ!ub!t

Gradl'-E: Combustible 1tqu1d
Electriral Group-O
Gtonrrai-Moderate to dangerous when heated to decomposition, emitting toxic fumes.
F1uh Poiftt (Fl 171

J.lammable Limiu 2.1 to 12.6%
Autoi~t~tition Temp. ("11 . Unavailable
E"tinpishin11 A11t'nl1 .. Alcohol foam, CO,, dry chemicals or water spray.
SpKial Fiu Pr04ures High temperatures give off toxic acidic fumes. Wear self-contained breathing
apparatus, and full protective clothing.
HEALTH HAZARD DATA

Health Hazard Ratlnp Odor Thrnltold (ppm) PEL/I'W A (..,..) 1LV/IWA (ppm)
Unavailable 5 20 20
Genenli-Vapors are mildly irritating to the eyes; the liquid is strongly corrosive to the skin and eyes.
Symptoms-Irritation of eyes, nose and throat; skin may experience a slight buming sensation.
Sbort Ex~ Tolerllllce-Unavailable
E:.:...,.~ProeediU'eS-Move victim to fresh air, keep warm and quiet. Eyes-flush with water for at least 15
minutes. Skin-flush with water then wash with soap. Ingestion--do not induce vomiting. Call a physician
immediately.
REACTIVITY DATA
StabtUty-Normally stable; however, if stored above 120F for long periods of time, it can polymerize violently,
giving off heat. Reacts with oxidizers.
CompatiWIIty-Material: Corrodes steel, wood, cloth and paint. Glass, 302, 304 and 316 stainless steel are
suitable.
Carlo: Group 4 of the compatibility chart.

Wear rubber gloves, aprons, boots and acid goggles. Avoid skin contact and prolonged exposure to vapors.
Neutralize spills with soda ash and flush with water.
If sp[U occun. WI die Ndoul ae.,o.e c.ter, I00-4J4 IIIIOl

Remarlu. MethacryUc acid tS normally 1nh1bited With hydroqulnone or the methyl ether of hydroqu~none.
187
METHACRYLONITRILE
SynonymiJ-2-CyanopropellEI; lsopropene cyanide; United Natl- Number ....
MAN; 2-Propenenitrile, 2-methyl-
CHRIS Code ..
Fonnuko-CH2 = C(CH,)CN
Boillna; Point. _______aQ'C ~F
Appui'Uiee-Oclor-Ciear, colorless liquid; no c 'F
8pp'eciable odor Freezlna Point.. -3B'C -32'F
Spedne Gruity-0.80
___ c ___ F
Vapor Preaare lO"C (68'F) (mmH8).. ~
Cbeml.ul Family-Cyanides Reid Vapor Pressure (pill)... ~
Vapot Preaure 46'C {lJ!!i'F) (psla).. _!2._
PoJlutlon Category-USEPA ____.k.._ IMO _ L _ Vapor DensUy (Air = 1.01.. ---1.Jl_
Applk:able Bulk Re1. 46 CFR Subebapter ...... _Q__ SolubiUty in Water.. 2 8%

Electrieal GI'Gup-NA
General-Very flammable; tends to polymerize violently rather than burn. Decomposes to toxic products.
Flah Poiat ('F) .. 55

F1am11111ble Limlta .. Unavailable-tends to polymerize violently
Autolpltloa Temp. ("F) .. Unavailable-tends to polymerize viOlently
Extillrpalshin& Asents .. Water log, alcohol foam, CO., dry chemical
Spedal Fire Proceclures .. Wear sell-contained breathing apparatus and protective clothing. use water to
cool exposed containers.
HEALTH HAZARD DATA

Health Huard Ratlnp
Unavailable ,.
Odor Threshold (ppm) PEL/TWA (ppm)
1/Skin
TL V !TWA (ppm)
1/Skin
General-Very toxic, avoid all contact.
Sy111pto--on1y moderately irritating to eyes and skin. Inhalation: Weakness, headache, confusion, nausea,
vomiting, respiratory paralysis, convulsions.
Short Expo~ure Tolerance-
El:pos:ure Pmcedure.-Get medical attention. Inhalation: Remove to fresh air, create artificial airway if needed.
Eyes: Flush with water 101" at least 15 minutes. Skin: Wash with soap and water twice. Medical personnel
should wear protective clothing.
REACTIVITY DATA
Shlbllity-Generally stable except when heated. Polymerizes on prolonged exposure to light. Reacts with
oxidizers and reducers.
Conlpat:lblllty-Materilll: Suitable:
'"'"

Avoid all contact, indlXIing vapOf. Remove all ignition sources. Absorb with clay, earth, sawdust. Dispose by
authorized incineration or landfill. Wear gloves, goggles, rubber aprons and boots, sell-contained breathing
apparatus. Wash clothing before reuse.
If a spUI oc:cun, c:aU the NationaJ Rapoue Center, 800--4~1.
Re1111rka: NOTE: Detectable odor and TLV are the same, therefore odor IS not a reliable method of 1!190
detecting hazardous concentrations.
188
METHANE
Synony-- Marsh gas; Methyl hydride; Natural gas Unlled Nndoa NniUer .. compressed
refrigerated
CHRIS Code ..
FormuJa-cH,
Boillna PoiDI.. ---=.lZ'C ~F
Appeanmc:e-Odor-Colorless gas; mild, sweet odor c 'F
FTMziDa Point.. ~c
_ _ c ---=iiF
_ _F
Specltk Gra,lty-0.42 at -160'C (a liquid)
Vapor rra..re :zoc C61'F> cm.U&J.. ~
CM..tul F...Uy-Paraffin Reid Vapor Preuure (pita)... ~
Vapor Preaun oM'C Cll!'Fl (,.Ul ~
Pollution Cateaory-USEPA - - - IMO ____.QIL_ Vapor Dea:lty Wr = 1.0)... ................... ~
AppUe~~ble Bulk Rea:. 46 CFR Subc:bapter ....... --'2.....Q_ Solablllty Ia Water NMMgibl!

Grltde-liquefied Flammable Gas (LFG)
Electril:lll. Group-O
General-Unless the flow of gas can be stopped, putting out a methane tire will permit the accumulation Of an
explosive concentration of vapor and subsequent explosion or reflash.
Flash Point ('F) -306

Flllmmable Llmlb. 5.0 to 15%
Autolpltlon Temp. ('F) ... 1000
Extinpllhina Apnt1 .. Stop flow of gas; Water, c~. or dry chemical
Special Fire Proc:eduret1 ... Keep burning tank and methane tanks adjacent to It cool with a water spray.
Stop flow of gas.
HEALTH HAZARD DATA

Huldl Huartl Ratfnp Odor 1'b.reUoJd (JIPIII) PEL!I'W A (ppm) TLV!1WA (..,m)
0,0, 0 200 Unavailable UnavUable
GeneraJ-Simple asphyxiant. Breathing gas may cause unconsciousness without warning because of lack of
oxygen.
Symptom~-Uquid can cause froatbne on skin contact. High gaseous concentrations may cause asph~atlon.
No systemic effects, even at 5% concentration In air.
Sltort Exposure Tolerance-Unavailable
EliJIO"ure Procedura-Remove to fresh air; if breathing has stopped, apply artificial respiration. If the liquid has
spilled onto the sltln, points of contact may be frostbitten: handle gently and protect from mechanical
REACilVITY DATA
Stlibility-Stable.
Comp~~dbUity-Material: Non-corroaive to steel
Caf10: Group 31 of compatibility chart.

Have all-purpose canister maslt available. Avoid contact with liquid. Secure ignition sources. If methane dOes
not catch fire, it will soon boil off.
If a .,W ocetU'1, c:aU the Natioal Relponte ee.ter, 100-Ut IICI:Z.
189
METHOXY TRIGL YCOL
s,._,._ 2-(2(2-Mett.oxyethoxy}ethoxy)ethanol;
Trlethylene glycOl methyl ether
CHRIS Code ..
FOIWilla-CHaO(C.H.O)aH
BoUiq PoJIIt . ___2!i'C ~F
~lorle881iquid: mMd odor c 'F
Freezina Pobll ... -44'C -4ZOF
Spedfk Gl'lo.tty-1.05 c ---
__....._
a..tc.l F..UJ-Giycol ether
VllfOl" PreuiU'e lO'C (61'Fl lmH&J ..
Reid Vapor Preallft (ptia) ...
__....._
__....._
VIIJIOI' Pr-.-e 46'C (115'F> (plia) ...
Polhltloa. c.tetor"J-USEPA - - - IMO ___.1L_ V.,or Deafly (Air = 1,0) ... ...liL
A.,uawe a.ur. Jlea. "' CFR Subdlapter .. ... __c__ Soblbllity Ia Water ..... Comp!ate
--
Gr.le-E: Combustible liquid
Fllllll Poilll !'Fl ..

.......leu.itl ..
Ge.ral-Moderate flrfl hazard if exposed to heal
245
UnavaHable
.,...__.....
Aalotpldoll T-,. ('F) .. Unavailable
Alcohol foam
Special Fire ProeediiJ'el Unavailable
HEALTH HAZARD DATA

Hf:lll.tll Huud Ratmp Odor nrahold (ppm) PEL/IWA (ppm) TLV/TWA (JI(IIII)
0, 0, 0 UnavaNable Unavailable Unavailable
Geaerai-No health hazard under normal conditions of handling.
S~Unavailable
Short ElF:pGAre Toleruce-Unavailable
ElF:poA~Je Procedaret-Eye contact-flush gently with water. Get mediCal advice il any discomfort.
REAcrJVITY DATA
StUOtty-Stable.
c-,.dbOlty-Matertal: Usual materiala of construction are suitable.

U a tpQl ocean, call tbe Nadoul. llelpoQe enter, II00-4l4 8802.

Remarb: :t Unassigned
190
METHYL ACETATE
Synoar-- Acetic acid, methyl ester
CHRIS Code ..
F01111ula-CH.COCX::H,
Botllq PcNirt .. ___M"C ____JD"F
A~Odor-Color1ess liquid; fragrant odor c 'F
Freez1q Pmt... -98'C --:"i'44F
Speelft( Gra'fity-0.92 ___ c ---
V-.or Pralure lCI'C (61'F') (.....tla) .. .....lZll-
Clmnleal Family-Ester Reid Vapor Preaue (flU)... .. .. .......... ~
Va,or Pre.ure 46'C (115'F) (pita) JJ._
Poll11tlon c.tegory-USEPA - - - IMO ____lll__ V.,ar DeultJ (Air = 1.0)... ___.t_
Appllrable Blllk Rea. 4fi CFR S.bebapter ....... ~ Sol1bllitJ Ill Water... . SMqbt

Electrie-1 Group-O
Genent-Dangerous, when exposed to heat or flame. Flashback along vapor trait may occur. Vapor may
FJuh Point ("F) .. 14

Flammablr Limits .. 4 to 14%
Auto!gnltlon Temp. ("F) .. 850
Extingulshln1 Asenu ..... Alcohol loam, dry chemical, or CO,
Special Fire Procedures .. Water may ba ineffective due to low flash point, but water should be used to
keep fire-exposed containers COOl. II a leak or spill has not ignited, use water spray to dispense the vapors
and to protect men attempting to stop a leak. Water may dilute spills to non-flammable mixtures.
HEALTH HAZARD DATA

Health Huard Ratinp Odor 'lllrelhold (ppm) PEL/IWA (ppla) TLV II'WA <pp.)
General-Skin contact with liQuid causes defatting and cracking of skin. Vapor itrttatlng.
Sympto--lrritation of respiratory passages, eyes, dizziness, depression, burning of eyea.
Short E:ropo1ure Tole...-ee-400 ppm lor unknown duration.
ExpotUre Proeedun~-H the eyes are affected, Irrigate continuously with water foe' at least 15 minutes. Obtain
REACfiVITY DATA
Stllbillty-Stable.
ComiNitibillty-Materlal: Compatible with common materialS of construction.
Caf&o: Group 34 of compatibility chart.

Wear rubber gloves, lace shield, protective clothing. Have all-purpose canister mull. available.
with liquid. Secure ignition sources. - oon1oc1
........ If a .,all 0CC111'1, CIIIJ tbe Nadoaal 1lelpoale Cuter, II00-4l4 11102
191
METHYL ACETYLENE-PROPADIENE MIXTURE
S,--)'llll- Anene-methyl acetylene mixture; MAPP Unlled Nau- Nuber...
Gas: Methyl acetyleoe-lllleoe mixture;
Propadiene-methyl acetylene mixture:
Propyne-allene mixture
CHRIS Code ..
Fon11ala-cH.C-CH, H1C=C"'C~ plus other C-31

and C-4s, ..turated and unsaturated.
___c F
Apparpee-OHr-colortaaa gas with musty odor
BoUina Pohll--
c ---.F
Speclfk Gra'rity-Q.58
O..lcal F..UJ-Hydrocarbon (Olefin)

V.,or ~ zoc (68'F> CmmHa)..
---
... c --.- F
==:c ==F
~
Reid Vapor Prt~~IIJ'e (pl!a)... ......... --.l.&L..
VallO' Prelhre 46'C (115'F) (pda)... ~
PoJ111t1011 Ca~t~WJ-USEPA - - - !MO --'IlL Vapor De.ity (Air = 1.0)... ............... __l..L_
Aptlialble Bait Rea, 46 CFR Subctipter ........ ---'L_ Solblllty In Water.. Nwljglt!lfl

~Uqulfled Flammable Gas (LFG)
Elertrlcal Gro..,....C
Geaend-MAPP gas is highty flammable but not shock sensitive. Unless the flow of gas can be stopped, putting
out a MAPP gas fire will permit the accumulation of an explosive concentration of vapor, and subsequent
explOSion ()( reflaah.
P1M11 hlllt C'FJ ..... Flammable gas
Plamadrle Umlb .. 3.4 to 10.8%
Allloiaaftloa T-p. ('F) .. 850
Exdapjllda& Atem ... Stop flow of gas; Water, CO., dry chemical
SJida( Pin Prondllra .. Use water spray to cool burning tank and adjacent MAPP tanks.
HEALTH HAZARD DATA

Heald! Haard lbtl... Odor nre..bold (ppm) PEL/I'WA (ppm) UV/I'WA (ppll!)
Unavailable 100 Unavailable Unavailable
General-The toxicity of MAPP is similar to that of propane and acetylene.
Sy.ptoiU-Contact with MAPP liquid may cause frost-type burns.
Sllort Elr:~~QR~rt Toleranee-Toxicity is slight, but high concentrations (5000 ppm) can have an anesthetic effect
Elr:po~Ue ~Remove to fresh air. Give artificial respiration if breathing stops. II liquid has spilled onto
the skin, points of contact may be frostbitten; handle gently and Pfotecl from mechanical damage. DO NOT
RUB. Get medical attention.
REACfiVITY DATA
StroWUty-This cargo Is atabilized.
Comp.tfbtUt,o-Malerial.: Alloya containing over 67% copper ahould not be uaad.

If a IJIW occura, call !be Natlolllll ae.,o- Center, 800-424-88Gl.

R......u: Boiling Range: -36 to -20'C; -36 to -4'F.
"*Freezing Range: -101 to -13TC, -151 to -214'F.
192
METHYL ACRYLATE
SyD0J11--Acryllc acid, methyl ester, Methyl
propenoate; Methyl 2-propenoate; 2-Propenolc acid
methyl ester
CHRIS Code .....
Formui1-CH.=CHCOOCH.
BoUI.. Potat .. ----AQ"C ~'F
Apparuee-Odor-Coorleas liquid; sharp pungent odor c 'F
Freem.1 PoJIIt... _zc;c -t03'F
Speclftc: Grarity-0.95
___ c ___ F
VllfOT PHIIure lO'C (61'F') <-HI).. ......LL.
a.-leal Famlly-Acrylatea Reid VllfOI' Pn.un (pda)... .. ___1.L_
Va,or Preaure 46'C (115'F) (plia).... __!.L_
Polladoll Caleaor"Y-USEPA - - - IMO _jL_ Vapor Deuh:7 (Air = I.Cl)... ____a.n_
A.,Ua~We Built Rea. 46 CFR Subdlqler ....... _..c__ SolbllltJ In Wale!'.. 52%

Eleetrieal GnNp--0
GenenJ-Irritating vapors are generated in !ires. Ignited by heat, sparll:s or open flame. Fire may cause violent
rupture of tank due to polymerization. Flashback along vapor trail may occur.
Flab Polllt ('F'). 18 to 27

Flanunahle Limits .... 2.8 to 25%
AutolpltkNI Temp. ('F') .. 875
ExtiDpiU.in& Alftltl ... CO., dry chemical, foam, wat log
Speeialf1reProeed'are~ .. Cool tank with a water spray. Supply fire parties with body and respirlltol'y
protection.
HEALTH HAZARD DATA

HWtb Huard RK11p Odor 'I'IIndlold (ppm) PEL/'IWA (ppm) TLVITWA (ppm)
3, 2, 3 20 10/Skln 10/Skln
GeneraJ-Vapor t~everely Irritating. Liquid may cause severe damage from prolonged skin contact.
Sympto11111-Watering of eyes, severe burning sensation of throat and nasal passages, coughing and sneezing.
Short Expo~~ure Toleruee-25 ppm for 30 minutes.
&.;posure Prvced11ra-Vapor-remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or
REACDVITY DATA
Stability-Methyl acrylate will polymerize readily, unless inhibited, evolving considerable amounts of heat. At
high temperatures it may polymerize even though Inhibited.
Compatiblllty-Mterlal: Usual materials of construction are suitable.
C1rao: Group 14 of compatibility chart.

If 11p1U ocnn, call die Natioai a.po.e Ceatef', --..l4-810l.

Reuwb:
193
METHYL ALCOHOL
s,.-,..._Aicohol C-1; carbinol; Colonial spirits; UnJted Nat:lou Number ...
Columbian spirits; Methanol; Methyl hydroxide;
Pyroxyllc spirit; Wood alcohol; Wood spirit
CHRIS Code ..
Bolllq Polllt.. ______M'C ~F

~lorless liquid; smelts like wine or
c ___F
lhellac thinner Freezlna PoiDt.... -i8'C --=..H!'F
Spedftc Grmty-0.79
___ c ___.F
Vapor Preaure lO'C <fiii'FJ (.mlk) ___1QQ_
Cllembl '-ii)'-Aicohol Reid Vspor Pre.nre (pm).... . ........ ~
Vspor ~re 44!i'C (115'FJ (plY).. ___,Z.Q__
Polllldoll c.teaorr-USEPA _____1L_ IMO ___lll_ Vapor DeMit)' (Alr = t.OJ... ................ ___lJ,1_
A.,Hcabte Blllk R~ 46 CFR S.bebpter ....... _____IL_ SolubUit," I Water.. . Coroolate

Elettrk:.l Groa,....o
Geaerai-Methyl alcohol is a flammable liquid. At "room" temperature, gives off a vapor which is both tolCic and,
when mixed wtth air, explosive within certain limits. Flashback along vapor trail may occur. Vapor may
explode If Ignited in an enclosed area.
Flult Poblt ('F) .. 61
FJaa...we u.J.a .. 5.510 36.5%
Alltofalddoll TUIJI. ('FJ .. 676
Ezlblaal*lal A.-. ... CO.. dry chemical, alcohol loam, water fog
Special Fire Proeedllfel .. Avoid breathing vapors. Provide body and respifalory protectioo for fire
parties. Keep tanKs cool with water spray. Water may not be effective unless large quantities are used.
HEALTH HAZARD DATA

Heallb HUIIJ'd Radql Odor nr.llold {p,m) PEL/1WA (ppm) TLV/'IWA (ppm)
1, 1, 2 so to 2000 200/Skin 200/Skin
c-u.-vapor inhalation dangerous. May be absorbed through akin. Poisonous if swallowed.
s,..,.__Dizzinesa, unconsciousness, and sighing respiration.
Sltort EI)IOIIIft Toteraae-1 000 ppm for 1 hour has caused headache, eye irritation and fatigue.
EI)IOIIIl"e Proc!eduei-Remove victim to fresh air. Give artificial respiration if breathing stops. Skin Of eye
contact---f8f1"10V8 contaminated clothing. Flush affected areas gently with water lor 15 minutes. Get medical
advice or attention.
NOTE: Odor threshold is not considered adequate warning of potential dangerous vapor concentrations.
REACI1VITY DATA
SC.bftltr-Stable. Can react vigorously with oxidizing materials.
eo.,.tibDtty-M.terial: Compatible with most materials of construction.
Cuao: Group 20 of compatibility chart See also Appendix !-Exceptions to the Chart.

Wear rubber gloves, protective clothing. Have all-purpose canistel'" mask available. Avoid contact with Nquid.
Secure ignition sources.
If a .,W oce.-.. eaU the N.UO.W Re.poue ee.ter, 8110-42:4 8802.
194
METHYLAMINE SOLUTION, 40%
s , _ , . _ Aminomethane; Monometnyl amine
CHRIS Code .....
Formala-CH,NH 2
BoWa1 PIN.C ....... ~c ---llJI'F
A.ppMn~~ee-Odcw-Water white to pale straw color; c 'F
fiShy or ammoniacal odor Freedq PoJIIt... -38'C -38'F
SpecUk Gn:rity-0.897 ___ c ---
Vapor PnaiU'e lO'C (6B'F) t-HI).. __..2_
Reid Vapor ..........-e
(JIIia)... ___jg__
Vpor Pr-..n 46'C (115'F) ~-- ---1a..._
Polllltioll Catepwy-VSEPA - - - IMO----'<-
A. .icallle lhlk Res. 46 CFR Subdulpter ....... __Q__
v.,.... ne.tty (Ab' = 1,0)...
Solltllity Ia Water..
.................. ___J,&L_
Corrp!ttt

Gnlde-8: Flammable liquid
ElectriW Group--O
General-Vapor very flammable. When heated, can decompose to toxic nitrogen oxides. Flashback along vapor
trail may occur. Vapor may explode if ignited in an enclosed area.
F1aA Poiot ('FJ .. 10 (cc)

FlamDJable Umlb .. 4.4 to 20.7%
Autoipltlon Temp, ('FJ .. ............ 806
ExtfnpW.Iag Aaentl ... Alcohol loam, water spray, CO,, dry chemical
Speelal Fire Procedure~ .... Wear protective clothing, 1181f-contalned breathing apparatus and eye
protection.
HEALTH HAZARD DATA

Hellltb Huard Rlltlnp Oclor Tllrabold (ppm) PEL/IWA (ppm) TLV/1WA Cpp.)
Unavailable 0.021 10 10
Gaeral-Vapors are highly irritating and toxic.
Symptomt-lngestion: Digestive tract bums. Skin: Irritation, dermatitis, bums. Eyes: Irritation, bums, pulmonary
edema. Inhalation: Sneezing, coughing, burning chest pain.
Sltort EI)IODJ'e Tole.,..__As little as 20-100 ppm causes eye, nose. throat irritation. Vapor it so irritating that
people do not voluntarily continue hazardous exposure.
Esponre Procedllt'ei--Get medical attention. Eyes and akin: Flush with water at least 15 minutes. If akin burned,
do not covar or apply ointment lor first 24 hours. Inhalation: Remove to fresh air with mouth to mouth
resuscitation or o)(fgen if needed. Ingestion: Do not induce vomiting. If conscious, drink water.
REACfiVITY DATA
StabJllty-Stable. Can react with acids and oxidizers.
CompatiiNIIty-Materlal: SUitable: Stainless steel, mild steel, Iron. Unsuitable: Aluminum, copper, zinc,
magnesium.
Carao: Group 7 Of compatiblrrty chart.

Avoid contact including vapor. Secure ignition sources and dilute with water or uee absorbent material. weer
hard hat. safety goggles, face shield, rubber gauntlet gloves, rubber apron, rubber safety Shoes or rubber boots,
self-contained breathing apparatus, as needed. Do not flush spills into confined spaces whera flammable vapors
can accumulate. Keep from entering watei'Way.
,...
If a lplll oenn., call the Nadollal Rapoae C.., I00-4l4-8I02.
195
METHYL AMYL ACETATE
Srncmr-- 1,3-0imetnylbutyt acetate; sec-Hexyl United Nat1o111 Number ...
acetate: MMc; Methyl iso-butyl carbinol acetate:
Methyl iso-butyl carbinyt acetate; Methyllsoamyl
acetate; 4-Mettryl-2.pentanol acetate;
4-Methyt-2-pentyl acetate CHRIS Code ..
Boltt111 Potnt.. ~-c _mF

~Odor-Water white liquid; mild fruity odor c
'F
Freedq Point.. -84'C -83'F
Spedlk Graflly-Q.88
___ c ___ F
Vapor P"-re zoc 16B'FJ IHI).. ~

Cblmeat Family-Ester Reid Vapor PmHre (p!ll.l)... .....Q.2.L_
VqK~r Prell11111 46'C (115'F) (,.U).. ......2.M._
Polllltloa CateawJ-USEPA - - - IMO _.k._ Vapol' O...lty (Air = 1.0).. .. ................. -A.Q.._
A.,Uaable Balk Jtea, 46 CFR Subdlapler ....... ___Q.jL SolubWt)' 111 Wider.. Ntg!lplb!t
FlRE & EXPLOSION HAZARD DATA

Gnde-D: Combustible liquid
Eleetrleal Grwp-0
Gemerai-Fiamrnable, moderate fire risk.
Flu.h Pol:at ('F) .. 110

F1a.mable Umitl .. 0.9 to 5.7% (calculated)
A-..tcNpltloa Temp, ('F) ... 510 (calculated)
EKtiiiJidab1qAp.g .. Confined area-COt, dry chemical. Open area-loam, water spray.
Spedal Pin Proeedlll'll ... Water may be ineffective on fire. Cool exposed tanks with water.
HEALTH HAZARD DATA

Healtll Hazard Ratiap Odor lbrahold (ppm) PEL/TWA (ppm) 1LVITWA <pp.l)
General-Moderately tox'1c by ingestion and inhalation, can causa skin irritation oo prolonged exposure.
Sym"-lrritation of respiratory passages, vomiting, dizziness, depression, burning of eyes.
Sltort Exponre Toleruee-Anlmal tests: No primary skin irritation, traces of eye inflammation; 4 hour exposure
Inhalation killed 1 out of 6; a hours exposure killed 5 of 6.
Expogre Procedura-lngestion-'nduce vornting. Inhalation-remove victim to fresh air and administer oxygen
if neceuary. Eye or skin contact-flush gently with water for 15 minutes. Get medical attentiOn.
REACTIVITY DATA
StUWty-8table.
eo.,.UWIIty-Materlal: No effects on steel; will swell rubber and can dissolve certain coatings.
Cup: Group 34 of compatibility chart.

Wear rubber gloves, protective clothing, face shield. Have all-purpose canister mask available. Avoid contact
........ U aii)IW oecun, call tbe Nat:loaaJ Reapoue Cealer, 800 4:Z4 IIO:Z
196
METHYLAMYL ALCOHOL
Synony--lsobutyl methyl carbinol; Isobutyl methyl Unhed Nlltlou Nlllllber...
methanol; MACH; Methyl lao-butyl carbinol;
4-Methyl2-pentanol; MIBC; MIC
CHRIS Code ..
Formub1--CH3 CH(OH)CH 2 CH(CH 1 ~

BoUiq Point.... __!B'C ______2ai'F
AppeariUICe-Odor-Color1ess liquid; mild alcoholic Odor c 'F
FTeeWI& Polat.. --:gQc -19CI'F
Speclftc Gra,lty-0.81 ___ c ---
Chemklll Fllmily-Aicohol
Vapor Preaure zoc
<61"F> (lnH&) .... ____a.a_
Reid Vapor Preaare (pN).... J.2..._
Vapor Preaure Ui'C (115'Fl (pUll)... _____,Q.L.
Pollud011 C.teaorY-USEPA - - - IMO _____L._ V.,or Deulty (Air = 1.01... --..J.L
Applh:able Bulk Rq. 46 CFR Subchapter ....... ~ Solubillty Ill Wlller.. 1 8%

Eleetrical Group-O
Generiii.-Moderate hazard, when exposed to heat or name.
Flub Point ('Fl .. 131

Flammable Llmltl. 1.0 to 5.5%
Autolpjtlon Temp. ('F) .. 583 (calculated)
Extinpb;hinl Ajents .. CO., dry chemical, alcohol foam, water log
Specia) Fire Proeedura . Provide fire parties with respiratOtY protection if they must enter spaces to
fight the lire.
HEALTH HAZARD DATA

He1ltb HUIU'd R1tinp Odor Thnlhold (ppm) PEL/TWA~) TI.VITWA (PJIIII)
1, 1,1 50 25/Skin 25/Skin
Generll-Essentielly an anesthetic with little or no cumulative toxicological properties. Prolonged contact with
liquid may produce drying and cracking of the skin.
SymptOIDI-Burning of nasal passages and watering of eyes, burning or itching at site of skin contact, dizziness
or drowsiness.
Short Expo11ure Tolermtee-2900 ppm cause immediate irritation of the eyes, nose and throat; 2-4 hours,
narcosis: 8-10 hours, profound depression and possible death.
Expo~~ure ~eGirt~-Vapor-remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or
eye contact-remove contaminated clothing and gently flush affected areas with water lor 15 minutes. Get
medical adv1ce or attention.
REACTIVITY DATA
StlbUity-Relativety stable.
Compatibility-Material: Most mat8f'lals of construction are satisfactory.

Wear rubbef gloves, face shield, protective clothing. Have aiiP'Jrpo&e canister mask available. Avoid contact
If 1 apUI oca~n, call tbe NatlonaJ iletpoDM Ceater, IIJ0-4l4-8802.
Renw-kl:
197
METHYL BROMIDE
SyiiGny- Bromomethane; Embalume; Methane, United Natlollll N11111ber ...
bromo-; Monobromomethane
CHRIS Code ...
Fonnula-CH,Br
Boiling Point .. --->"C ___4Q"F
Appem"a~~ee-Odor-Colorless liquid; sweet, c "F
chlorolonn-llke odor Freezlna Point. -93'C -135'F
Specific: Gra:dty-1.73 at 20'C (a liquid) c "F
Vapor Prestnre lO'C (68'Fl <mmHa). .. ...H2Q_
Chemical Family-Halogenated hydrocarbons Reid Vapor Preaure (pala) ... __4L_
Vapor Pre.11re .u:c U15'Fl <,.tal .. _.oJL_
PoUution C.teawY-USEPA _..Q.._ IMO __go_ Vapor Deallty (Air = 1.0) .... ...uz._
Appllable Blllk Rea. 46 CFR Subdu!pler ....... ___Q__ Solubility In Water .. 17%

Grade-Uquelied Compressed Gas (LCG)
Electrical Group-O
General-Toxic and irritating gases are generated when exposed to heat or lire. Practically non-flammable.
and explosion hazard ia slight.
.,..
Fluh Point C'F).. Virtually non-flammable in air; burns in oxygen {Oz).
Flanunable Undtl .... 10 to 15%
AutolpltiOII Temp. ('F). 998
ExtlnpiAID& Alflltl ... Water spray, dry chemical
Spedal Fire Proeedara .. Cool tanks in vicinity of lire with a water spray. leaking tanks must not be
approached unless wearing lull body and respiratory protection.
HEALTH HAZARD DATA

He.Jth Huard Ratlnp Odor t'hrabold (ppm) PEL/TWA (ppm) TLV;TWA (ppm)
3,3,4 Unavailable 5/Skin 5/Skin
General-Suspected carcinogen. Poisonous by inhalation. Effects may be delayed. Uquid causes burns; may be
absorbed by clothing, particularly shoes, to cause delayed burns. Class B poison.
Sympt-Oouble vision, nausea, dizziness, headache. Severe exposure results in convulsions, muscular
tremors, and possibly death.
Short Expopre Toleram:e--20 ppm for 5 minutes.
E1po11ure Produre.-Remove victim to fresh air. Administer artificial respiration if unconscious. Oxygen
administered by trained personnel is often helpful. Get medical attention immediately.
REACTIVITY DATA
Stability-Forms aluminum alkyfs in presence of aluminum. Aluminum alkyls are spontaneously ignitable
materials.
Compadblllty-Mterlal: Not corrosive to most metals.

Wear rubber gloves, sell-contained breathing apparatus, protective clothing. Avoid contact with liquid.
Personnel without respiratory protection must be kept upwind of spill.
If 1 IPIU oetun, eall the N1tlonal RelpoDie Center, 800-4l4-880l.

R-~rlm NOTE. The effects of 1nhal1ng th1s material may be delayed. Exposure to potentially dangerous
vapor concentrations can occur before the prOduct can be detected by smell.
198
METHYL CHLORIDE
SynonymiJ- ChiOtomethane; Methane, chloro United Nado111 Number .....
CHRIS Code-
Formula-CH,CI
Boiling Point.. ~c --=li'F
Appeanmc:e-Odor-Colorless gas or liquid; faintly sweet ___ c 'F
Odo Free&ing Pol.nt.. _ d l ' C ----=t42-F
Speelftc Gravlty-0.92
___ c ___ 'F
Vapor Pre..Ul'e lO'C (68'F) (IIUIIH&) .. ~
CbemJeal. Family-Halogenated hydrocarbons Reid Vapor Pre.ure (p8ia).... --1l.L_
Vapor Pfeuare 46'C Ul!I'F) (PfJI).. ~
Polludcm CatfiOf)'-USEPA ____.li_ IMO -...aL.. Vapor Denllty (Air = 1,0)... .. ................. ......1..Za.._
Appllalble Bulk Rea. 46 CFR Subchapter.. .. __Q__ SolubUity In Water.. 0 5%

Eleetrlcal Group-O
Geaerai-As with a Liquefied Flammable Gas, extinguishing the fire without stopping the gas leakage may
Increase the danger by permitting the accumulation of an explosive mixture. Ignited by heat, sparks or open
flame. Toxic and irritating gases are generated in f1res.
A.la Poiat ('F) .. <32
FJua...ble Umit. .. 8.1 to 17.2%
A11toipltlon Temp. ("F) .... 1170
Eztia!PiilbiD& Allftlb .. Stop flow Of gas; c~. dry chemiCal, water fog
Spedal Fire Procedures .... Keep tank cool with water spray. Both the vapor of the product and its
combustion products are poisonous. Provide firefighters with respiratory protection and full protective
clothing.
HEALTH HAZARD DATA

Healtb Huml lbtinp Odor 'nrelboJd (PPJII) PELITWA (ppm) nvrrwA (ppm)
0, 0, 2 50 50/SI<In
General-Suspected carcinogen. Vapor very harmful. Liquid or COld gas may cause skin or eye in~ry similar to
frostbite.
Symptoag-Dizziness, staggering gait, drowsiness; recovery is slow. Frostbitten areas wilt be white. Death may
result from a single high exposure or repealed moderate exposures.
Sllort Ell;pos~~re Toluuee-300 ppm for 5 minutes.
Ell;ponre Proc:edurea-Remove victim to fresh air. Apply artificial respiration if breathing stops. lithe liquid has
spilled onto the person, points of contact may be frostbitten. Protect any frozen areas from mechanical
damage. Get medical attention.
NOTE: Detectable odor is greater than the TLV. Exposure to potentially dangeroos vapor concentrations en
occur before the product can be smelled.
REACUVITY DATA
Stability-Decomposes upon contact with moisture. AI high temperatures it may decompose to phosgene,
chlorine and carbon monoxide.
Co.paUbillty-Materlal: When in contact with aluminum, the product which forms may ignite spontaneously in
air. Do not use aluminum, aluminum alloys, zinc. die castings, magnesium or magnesium alloys.

Wear rubber gloves, self-contained breathing apparatus, protective clothing. Secure ignition sources. Small
spills will vaporize and disperse.
If I lfJII Gee:lll'l, call tlte Nat:loul Relpoue Ceatw, 800-4l4-880l,
Reaarlw Liquefied Flammable Gases are regulated by 46 CFR Part 38.
199
2METHYL6ETHYLANILINE
Syaoayllls-6-Ethy!-2-methyl benenamine; United N.t1o1111 Nllmbel', ..
Ethyl-o-toluidine~ Methylethyl aniline
CHRIS Code ...
Boillq Point.. ----.2a.l'C ~F

Appearanee-Odor-C!ear to amber liquid; mildly pungent
___ c ___.,
odor Freeana Polnt.. ~c ~F
Specltlc: Gralty-0.97
c ___.,
Vapor Prwlure lti'C (68'F) (mmHI).. .....QJliL_
Chemical Funlly-Aromatic amines Reid Vapor Preaure (peill)... _L_
Vapor Preuure .M'C (115'F) ep.ta).. ....QJHli_
Pollution C8te,ory-USEPA - - - IMO _____Q__ Vapor Dea:lty <Air = 1,0)... ................. ___!.1._
Appllu.ble Bulk Rq. 46 CFR Subdlapter .... , ___Q__ Solubility In Water.. Slight

Electrical Group-NA
Gi!Deral-Mild hazard, toxic fumes of nitrous ox1des and CO., are given off by high temperatures or combustion.
FlMb Point I'Fl. 232

Autolgnltion Temp. ("F) .. Unavailable
Extlnplsbinll Agents. CO., dry chemical, foam, water spray
Special Fire Procedure:li Water protective clothing, gloves, and goggles and self-contained breathing
apparatus.
HEALTH HAZARD DATA

Healtb Huard Ratings Odor Thre~~bold (ppm) PEL/I'W A (ppm) nv11WA <ppm>
General-Severe eye 1rntant, nonirritating to the skin.
Symptoms-Sk1n develops blue tmge from lack of oxygen in the blood
Short l-:1.posure Tolerance-Rats subject to 260 ppm !Of 4 hours produced no symptoms.
EJ.pos11re Procedure..-Fiush eyes Immediately with water for 15 minutes. Wash skin With water. Remove to
lresh a1r
REACf!VITY DATA
Stability-Stable.

Soak up spill with sawdust. sand, or incinet'ate. Wear protective clothing, goggles, have se"contained
breathing apparatus at hand
If 1 spill ocaan, call the National Reapon~e Cnter, II00-4:Z4 IIOl,

:j: Unassigned
200
METHYL ETHYL KETONE
Syno~ 2-Butanone; Ethyl methyl ketone; MEK UnJted Natlou NIIIDber ...
CHRIS Code ...
BoiiiD& Pobll.. _____JlQ'C _jl'F

Appearuee-Odor-CoiOrleas liquid with a lacquer c 'F
thinner odor FreaU&a Pelllt... -BB'C -123'F
Specific Gr.flty-0.80
___ c ___ 'F
V.,or Pre.ure lO'C (61'F) (-H&).. ____lQQ_
Cbelllkal. Family-Ketone Reid V.,or Prellllre (Jim)... _a;_
v.,_ Pnenre 46'C <U5'F) (pibl)... ~
PoUt~tiM cateaorY-USEPA ---'L__ IMO ___llL_ v..- DeUt:r <Afr ... t.OJ ......................... ___i.L_
AppHcabte lhlll Rea. 46 CFR Subc:UfUr ....... ____c__ Sotublllty 1J1 Wale!' 27%
FIRE oil: EXPLOSION HAZARD DATA

Gnde-C: Aammable liquid
Eaeetrkal Groap-0
General-DangEifOUS fire hazard, when exposed to heat or llama.
.,... Polal ('F) .......................... 30

FlaJulabk Uadtl .. 1.8 to 11.5%
Aulolpltioll T-p. ('F) .. 960
Eztblp...lq All!lla ... CO., dry chemical, alootlolloam
Speclal Ftre Proced1uw .. Water spray may be Ineffective on fife. Cool exposed tanka with water.
HEALTH HAZARD DATA

Heal.tll Haanl Ratillp Odor nre.Jw1d (pp.) PELI'IWA (ppm) 1LV/1WA (ppll)
1, 1, 2 10 200 200
GeMrai-Vapor Is lnitatlng with moderate narcotic effect when Inhaled. Vapor very Irritating to eyes. Slight akin
Irritation on contact.
Symptomt-lnitation In eyea, nose, and throat. Dizzlnen, headache, nausea and lack of communication.
Sltort Ezponre T~Umlted by Irritant properties of vapor. 30,000 ppm Is Intolerable to man because of
irritation of eyes and nasal passages; 3000 ppm is intolerable to man for more than ;ust a short period of
time.
E~:Pf*lnl Procell,..Remove any contaminated clothing promptly and flush skin with copious amounts of
water. In case of eye burna, flush with water for ten minutes.
REACI1VITY DATA
Stat!Wty-Stable.
CoiiiJIUI.biUtr-M.terlal: Softens and dissolves many plastics.
Carao: Group 18 of compatibility chart See alae Appendbc 1-Exceptlont to the Chart.

Wear rubber glovn, face llhleld, protective clothing. Have all-purpoae canister mask available. Avoid contact
with liquid. Secure IgnitiOn aouroea.
u .,m occun, call tbe Natto.l . . . , _ Center, 800-4l4-11802.
201
2METHYL5-ETHYLPYRIDINE
s,..on,._ Aldehyde-collldlne; Aldehydlne:
3-Ethyl-6-rnethyl pyridine; S.Ethyl-2-methyl pyridine;
5-Ethyl2plcollne; MEP
CHRIS Code ..
-
Appearuee-Odor-lorieu liquid; sharp penetrating
Spedftc Gnftty~.92
Cbeleal F..U,-Amine
hlhatf~M, CMeaorf-USEPA - - - IMO ____L_

Bolliq Potat ..
Fnez1q Potat...
___ll'C
c
-ZO'C
___
Vapot' ttre.are lO'C {68'F) <mmHa>..
Rehl Va,or Pnuan (pita)
Vapor rr-re 46'C (115'FI <.->..
Va,or Deality Wr = 1,0)
~F
'F
-!M'F
c ___ .F
_2.i_
___2.1_
.....QJ.L
_..UL_
Applicable Bulk Rea. 46 CFR SubtUpler ...... _____Q__ SolbWb' la Wllter .......... light

Eleetrieal Groat-0
GeMnJ-Moderate fire hazard when exposed to heat Of flame. lnitating vapora are generated when heated.
Flub Poblt ('F) .. 165

Flul-ble u.ttl .. 1.1 to 6.6"/o
Autolpit1011 Tp. ('F) ... 939
Extlnawl*lal: Apnll; ..... Alcohol foam, carbon dloldde, dry chemical, water spray
SpedaJ Fu. Proeedluw .. Wear protective clothing and self-contained breathing apparatus.
HEALTH HAZARD DATA

Health Huanl Ratlnp Odor 'l1lniiMIId C,.) PEL/'IWA Cpp.l) TI.V/I'WA <PP-!l
Geaerai-Moderately toxiC, sll:in irritant.
Sypto--Redneas and swelling from akin contact with liquid.
Short E:rpo~llnl Toleraace-1700 ppm lethal to a rat in 3.7 hours.
Expo111re Procedur-Vapor-remove victim to fresh air; H breathing stops, apply artificial respiration. Skin or
aye cootact-remove cootaminatecl clothing and genUy flush affected area with water for 15 mlnutea. A
physician must see all cases of eye contact lmmedlataly after eye wash ia completed.
REAcnviTY DATA
StaiNilty-Stable. Can react with oxidizing or strongly alkaline (caustic) materials.
eom.aWMilty-Matert.i: Polyethylene-lined containers suitable.

Avoid contact with liquid. Keep unprotected personnel away from spill area. Collect material 1o plaatlc
containers using absorbents, for amaH spilla; flush large &pills.
If a .,W oc:an. em1 tile Nadoul . _ c.ter, 800-4l4 1802.
202
METHYL FORMATE
Synonym.- Formic acid, methyl ester; Methyl United Nation Number ...
methanoate
CHRIS Code ..
Formula-HCOOCH,
Boillna Point.. __azc _____aa'F
Appearanc:e-Odor-Colortess liquid; pleasant odor c 'F
Freulna Point.. ----=Woc
___ c --=;-:iF
___ "F
Specific Grarity-0.98
Vapor Pre.ure lO'C {68'F') (mmHI) .... _JQQ__
Cbemleal FamUy-Esters Rehl Vapor Pres.ure (Ptll)... . __;::,lL_
Vapor Pnaure 46'C (115'FJ (psja).. ~
Pollutfoa C.teaory-USEPA - - - IMO ___c__ Vapor Deutlty (Air = 1,&).. .....i.1Jl_
Appllct~ble Bulk Rea. 46 CFR Subciulptel' ....... ___Q_ Solubility In Wllter .... Soluble

Eteetrical Group-O
Ge.erai-Toxic vapors are generated. Very dangerous when exposed to heat, flame or oxidizers. Flashback
along vapor trail may occur. Vapo!' may explode If ignited in an enclosed area.
Plub Point ('Fl .. -26 (cc)

F1-ruble Umltl ... 5 to 22.7%
Autolpltioa T-p. ('F) .. 853
EJ.tlquillll:ql Alftl ........ Dry chemical, alcohol foam, CO.
Special Fire Proeedare. .. Water may not be effective. Wear self..contained breathing apparatus, rubber
gloves.
HEALTH HAZARD DATA

Healtll Huard Rat:lap Odor 'lbmhold (ppm) PEL;TWA (ppm) TLV!TWA (ppm)
Geuem-Vapor and liquid are Irritating to eyes, nose, skin and throat.
Sympto~M-Irritation of mucoos membranes, narcosis, temporary visual disturbances. Uquid causes skin and
eye irritation.
Sbort Expo~~~re Tolerance-Unavailable
Expoture Procedut'a-lnhalalklo--move to fresh air, give artifiCial respiration or oxygen as necessary.

Eyes-flush with water for 15 minutes. Skin-wash with soap and water. Ingestion-Do not induce vomiting.
Get medical help.
REACIIVITY DATA
s ..bUity-Stable. Slow nonhazardoos reaction with water to form formic acid and methyl alcohol. Reacts with
oxidizers.
Compatfblllty-Material: Stainless steel, aluminum or lined carbon steel are suitable.

Secure ignition sources. RestriCt access. Disperse and flush. Do not flush spill into confined spaces where
flammable vapors can accumulate. wear self-contained breathing apparatus, rubber gloves, goggles or safety
glasses.
If a .,UI oeava, ea11 tbe National Reaponae Ceates-, 8tJ0-4l4....1J802.

Remarb:
203
METHYL ISOBUTYL KETONE
s,._,..._ Hexone: Isobutyl methyl ketone:
lsopropylecetone; 4-Methyl-2-pentanone; MIBK; MIK
CHRIS Code ..
Bollia& Polat .... _mc __2ll"F

_ _ _ "F
~orless liquid; pleasant odor c
FreeziD& Poblt.. ----::s4c
___ c ____.;;;jjj'F
_ _ _ "F
Spednc Gnrity--0.80
Vapor Preaure lO'C (68'Fl (mmH&) .. _jj)__
a.-tc.J FamUy-Ketone Reid Vapor Preaure (ptia) .. ____Q&_
Vapor Preuare 46'C (115'F') (.-Ja) .. ____u_
PoU.eto. CaleaorJ-USEPA __c__ IMO __c__ V11p0r ~ty (Air = 1,0)... ....a&_
ApflbWe Bldlr; Rea. 46 CFR S11bebapter ....... __Q__ SolabWty iD WateJ" .. 20%
FIRE ol EXPLOSION HAZARD DATA

er..te-c: Flammable liqUid
"""""' """'>--0
General-Irritating vapors are generated when heated. Dangerous fire hazard when e>eposed to heat or name;
mOderate explosion hazard when vapor exposed to heat or flame.
Flula Polat ('F) . 75

..,__ble U.ib .. 1.2 to 8.0% at 200'F
AatoJpldoa t-p. ('F') .. 858
E:.:tblrpdal;q Alftlls ... CO., dry chemical, alcohol loam, water fog
Spedal Fire Procedllrel .. Fire parties rT)Ust wear respiratory protection. Water may be ineffective on f1re.
HEALTH HAZARD DATA

Health Huanl Rati~~p Odor Tbl'elbohl (ppta) PEL/IWA (ppm) TLVnwA()I..-l
1, 1,1 0.47 50 50
GeDeral-Vapor causes eye, nose, throat irritation. Aspirated methyl isobutyl ketone may cause severe lung
damage and present a significant hazard. Repeated or prolonged skin contact may cause defatting of the
skin with Plimary irritation resuning.
SymptOIQ-Headache, dizziness and nausea.
Sltort E~:potun Toleruee-200-400 ppm for 5 minutes has produced eye irritation; 400 ppm lor 5 minutes may
pioduce nasal irritation.
EJ:)IOIUI"i! Procedur-Vapor-femove victim to fresh air; if breathing stops, apply artificial respiration. Skin or
eye contact-remove contaminated clothing and gently flush affected areas with water lor 15 minutes. II
swallowed, do not induce vomiting. Get medical attention.
REACfiVITY DATA
Stllbillty-Stable.
Co.INitlbillty-Mtlterlal: Will soften many plastics.

If a IP'U oc:eun, call the N.Uoaal Rspoue Caller, 800-4l4-880:Z.
204
METHYL METHACRYLATE
Synonym~- Crystalite; Methacrylate monomer: United Nation Number ...
Methacryllc acid, methyl ester; Methyl methacrylate
monomer, inh.; Methyl alpha-methacrylate;
Methyl-2-methyl propenoate; 2-Methylpropenoic
acid; 2-Propenoic acid, 2-methyl-, methyl ester CHRIS Code ..
Formula-CHo = C(CH~)COOCH,
Boilln1 Point .. --ll!!lc
Appearance-Odor-Colorless liquid; a~rid odor c
Free:d111 Point .. -4B'C
Spedftc Grnity--0.94 ___ c
Vapor Preaure :zoc (68'F) (mmHg) ..
Cbemlcal Famlly-Acrylates Reid Vapor PreRure (ll'if.l ... --=.I!.L
Vapor Preuure 46'C (lHi'F) (psja) .. ~
Pollution CateiJOI')'-USEPA _____c__ IMO _____Q__ Vapor Delllity (Air = 1.01 ... ___ML
Applicable Bulk Res. 46 CFR Subchapter ....... ____Q__ Solultlllty In Water .. Slight

Eleetrieal Group-O
General-Ignited by heat, sparks, or open flame. Fire may cause violent rupture of tank because of
polymerization.
F1aeh Point ('F) .. 55

Flammable Umlts .. 2.1 to 12.5%
Autolpltlon Temp. ("F) .. 790
Edlnpillllq Alents .. Foam, carbon dioxide and dry chemicals
Special Fire Procedurn ... Cool exposed tanks with water. Wear eye protection, self-contained breathing
apparatus and protective clothing.
HEALTH HAZARD DATA

Health Hazard Ratlnp Odor 'I'IIrnhold (ppm) PEL/TWA (ppm) TLV!TWA (piJIII)
3, 2, 3 0.05 100 100
General-Vapor irritating.
Symptoms--Smarting of the skin and first-degree burns on short exposure and may cause second-degree bums
on long exposure.
Sbort Expo11ure Tolenmee-200 ppm
Exposure Protedures-Vapor-remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or
eye contact-remove contaminated clothing and flush affected areas with water for 15 minutes. Get medical
advice or attention.
REACI1VITY DATA
StaiHIIty-Polymerizes readily. Methyl methacrylate will not decompose on prolonged storage if properly
inhibited.
Compatibility-Material: Noncorrosive to steel, aluminum or stainless steel.

If a ..W occurs, call tbe Nadoaal Retponaa ee.ter, 800-4l4-810:Z.
Remarlu: Vapor Pressure: 40 mmHg at 2s.sc.
205
alphaMETHYLSTYRENE
Synooyn~s-AMS; lsopropenylbenzene; United Nations Number .....
1-Methyl-1-phenylethylene; Phenylpropylene
CHRIS Code ..
Bollin1 Point .. ..l.B12'C ~F

Appeanmce-04or-Ciear yellow liquid; characteristic
aromatic odor Freezin& Point .. -23'C-9'F
Specific: Gral'ity-0.89
___ c ___ F
Vapor Pressllll.' ltl'C (68'FJ (mmH&) .. -4.l!L

O.emical Family--Olefin Reid Vapor Pressure {plia)... ___2.2L
Vapor Preaure 46'C (ltS'F) (plla). _ML
Pollution Category-USEPA - - - IMO ___A__ Vapor Denaity (Air = 1.0) .... -4.l!L
Applicable Bulk Rea- 4(i CFR Subchapter ....... ____Q__ Solubility In Water .. lnsotyb!e

Gnute-D: Combustible liquid
Electriul Group-O
General-Moderate fire hazard when exposed to heat or flame.
Flash Point ("F) .. 12510 135

Autolgnltlon Temp. ('F) .. 1066
Extlnplhlna Apnts. Dry chemical, foam, CO., water log
Special Fire Proeedures . Water may be ineffective on lire.
HEALTH HAZARD DATA

Health Hazard Ratlnp Odor Threshold (ppm) PELJTW A (ppm) TLV;TWA (ppm)
Unavailable Less than 10 50 50
General-Avoid skin contact. Not known to be absorbed.
Symptom1--Will cause skin irritation if not removed promptly. Breathing considerable quantities may cause
headache and/or dizziness.
Short Exposure Toleram;:e--Unavailable
Exposure Procedures-Skin contact-flush body splashes with plenty of water. Inhalation-remove victim to
fresh air. Administer artificial respiration if necessary.
REACTIVITY DATA
Stability-Stable. Can react with oxidizing materials
Compauibility-Material: May cause rubber to swell.
CarKO: Groop 30 of compatibility chart.

Wear rubber gloves, face shield al"ld protective clothing. Have all-purpose canister mask available. Secure all
soorces of ignition.
If a tpJII oca~n, call the National ReapoaM Center, 800-4l4-880l,
206
METHYL TERT-BUTYL ETHER
Synoay-tertButyl methyl ether; MTBE UnUed Nadmq Numbel' ...
CHRIS Code .
Bonlq Point .. ~c _mF

A~~lear. colOrless liquid; sharp, c ---
-109'C ---=.l!'F
terpene-like odor Freeziaa: Point ...
Spec:lfte Gnlrity-0.74 at 20'C c ---
Vapor Pr-.re zoc (68'F> <-a.> ..
ClemJeal F.Uy-Aikyl ethers Reid VlpOJ' Pr-.re (plill)... . _L!_
VllfOI' 1"..- 46'C (115'F) (pU) ..... .
PoUiltloa Cateaoey-USEPA - - - IMO ----'L_ Vapor Delll'ty Air ,.. 1.01 ................... ____a.t_
Applbble Blllk Rea. 46 CPR Sabdaapter ....... _Jl._ SohlbilftJ la W.ter .. ComPlete

~: Aammable liquid
Ehetrkal Grou.-G
Geaerai-Fiammabla and, when confined, explosive. Flashback along vapor trail may occur.
Flub. Pobl.t ('F) .. -14 (cc)

na...ble Liala .. 1.6 to 8.4%
Alltotpkloa Temp. ('F) . 797
Extlftald*ial: Apab ..... Alcohol foam, dry chemical, CO.
Spec.WI Fire PfoeediiJ'el .. Cool exposed tanks with water spray.
HEALTH HAZARD DATA

HaJtb. Huard Ratblp Odor 11arabo&d (ppll) PEL/IWA (ppm) TLV IIWA (pfm)
Unavailable Unavailable UnavaHable 0.25
General-Not too toxic, similar to gasoline.
S,.,._lrritates eyes, akin, mucous membranes. InhalatiOn: For prolonged exposure, coughing, shortness of
breath, dizziness, Intoxication. For short exposure, dizziness.
Sllort Ex)IOIIIJ'e Toleruce-
ExpoRre Proc:elbuw-lnhalation: Remove to fresh air, give oxygen or artificial respiration as needed. Eyes:
Flush with water tor at least 15 minutes, hold eyelids open, call physician. Skin: Wash with water. Ingestion:
Do not induce vomiting.
REAcrJVITY DATA
Sta11Wt1-Generally stable. Forms peroxides at much slower rate than most ethers. Reacts with mineral acids,
organic acids, other oxidizers.
CompadbWty-Material: Compatable with steel, iron, aluminum, copper, magnesium, zinc, neoprene,
polyethylene, polypropylene. Incompatible with viton elastomer.
Carp; Group 41 ol compatibility chart. See also Appendix !-Exceptions to the Chart.

Stop release, remove aH ignition sources. Dyke to prevent apNI from entering sewers (explosion hazard,
poUution) and waterways. Remove spill wtth inert absorbent. Wear goggles or face Shield, boots, and use
sell<entained breathing apparatus if spill large or in confined area.
,...
If .,m oceun. eaU lite NatloMJ ...,._ C.U., IIJ6.-424.1102.
207
MINERAL SPIRITS
SynonyiiUI-ligroin (in U.S.A.); Naphtha; Petroleum United Nations Number ...
spirits; Turpentine subst1tute
CHRIS Code ....
Formula-Petroleum distillate, not chemically

disting..~ishable BoiUn& Poiat .... ~c ~F
ApPearallte-Odor-Water white liquid with gasoline-like c ---.F
"F
odO<
Spedfi~;: Grarity-0.75
Cllemical Family-Hydrocarbon mixture

Freedq PMat ..
Vapw Preuun lG'C (68'F) (mmH&) ..

==:ic
___ c
==F
~
ReJd Vapor Preaure (paia) ..... ....Q.1.L
Va)Kif Preaure 46'C (ll!I'FJ C,.Ja) ... ~
PoUutton Catqory-USEPA - - - IMO ___L_ V!lpOr Deutty (Air = 1.0) ... ~
Applleahle Bulk Re1. 46 CFR Subchapter ........ __....Q.._ Solubility Ia Water ... Noo!jgjble

Eleetrlca1 Group-O
General-Moderate fire hazard when exposed to heat or flame.
Flaab Point C F) 105 to 140

Flammable Limits .. O.Bto 6.0%
Autolpition Temp. ("Fl .. 540
E:di11pi&bin1 A11ent11 .. Foam, carbon dioxide, dry chemical
SpeelaJ Fire P~edures .. Do not use straight hose water stream.
HEALTH HAZARD DATA

Health Huard Ratings Odor 1'hrefltoJd (Jipm) PEL/I'W A (ppnt) TLVITWA (ppm)
0, 1, 1 Unavailable Unavailable 200
General-
Syntptonts-lnhalation. Mild irritation of respiratory tract. Severe lung irritant. Central nervous system excitement
followed by depressiOn.
Short Exposure Tolerance-4000 to 7000 ppm for one hour
Expo~~ure Procedures-lnhalabon: Aemove victim to fresh air. Administer artificial respiration if necessary.
Ingestion: DO NOT induce vomiting. Eyes: wash with copious amounts of water
REACfiVITY DATA
Stability-Stable.
Contp~~tlbility-Materilll: Usual matenals of construction are suitable.
Cafi(l: Group 33 of compatibility chart.

Wear polyethylene gloves, lace shield, protective clothing. Have allpurpose canister mask available. Secure
Ignition sources.
If a lpill O<:Ciln, call t1te Natiomal hponae enter, ~l4 1802,
Ruaarka! t Unavailable
208
MOLASSES
Synonyms- Treacle United Natro. N111111ber....
CHRIS Code ..
Formula-A mixture of sucrose and sugars

_ _ _ 'F
Boiling Point ..
Appunmo:e-Odor-Dark brown syrupy liquid
Freeztna Point ..
---
---
_ _ _ 'F
Speclfte Gravity-1.45
Vapor Pre.ure lO'C (68'F) <-HI) .. _J.oL_
Chemical FIUII.ily-Aicohols, Glycols and Glycol Ethers Reid Vapor Preuure (pilro) ... _J.oL_
PoUution Catqory-USEPA _ _ _ IMO ____llL_

Vapor Preaun 46'C (lJS'FJ (p8U) ..
Vapor Deluilty <Air = 1.0).
~
Sm~
Applicable Blllk Rea. 46 CFR Subclupter ...... - - ' - - Solubility In Water ..

Grade-Non-flammable
Electrical Group-NA
General-Non-flammable and non-combustible.
Fbulb PoiDt ("FJ .. Non-flammable

FIUIIDioltle Ulllits .. Non-flammable
Autolpltlon Temp. ('F) .. Non-flammable
ExtllldIPI Apnts .. Non-flammable
Spedal Fire Procedlll'e!ll .. Non-flammable
HEALTH HAZARD DATA

Healtb Hazard lb.tinp Odor 'I'hnsltold (ppm) PEL/I'WA (f'PIIl) TLV/I'WA (ppJII)
General-Non-toxic. Molasses fermentation occurs when molasses is diluted with salt or fresh water and is
accelerated by heat. During fermentation ~ (with possible traces of ethanol and higher alcohol vapor) Is
given off, which will produce inhalation hazard in compartment containing molasses residue.
SymptomJ-Non-toKic
Sbort Expo~~ure Toleranee--Unavailable
Exposure Proeedures-Vapor-rernove victim to fresh air. Skin or eye contact-remove contaminated clothing
and flush affected areas gently with water.
REACfiVITY DATA
Stability-Stable. Reacts with cone. nitric acid and cone. sulphuric acid. Ferments when diluted with salt or
fresh water.
Compatibility-Material: Mild steel and stainless steel are suitable.
Cari(Y. Groop 20 of compatibility chart.

Wash area with water aftef removing bulk of spill by general means.
If I lpiU occ:ura, call the Natioaal Relpoae Center, 1100-4:Z4 IIO:Z.

Remarks: Unregulated, Tabla 2, 46 CFR Part 153.
H10 vapor only
;j: Unassigned
209
MORPHOLINE
Synonym&- Diethylene imidoxide; Diethylene oximide; United Nations Number ..
Diethylenimide oxide; Tetrahydro-1,4-oxazil"'e;
T etrahydro-2H-1,4-oKazine; T etrahydro-p-oxazine
CHRIS Code ..
Fonnula-(CH,J,ONH
Boillna Point .. _____jz'C _.zezF
Appearance-Odor-Colorless oily liquid; ammoniacal c 'F
odor Freezl.na: Point .. -4'C ~F
Specifle Grarity-1.00 c ___F
Vapor PreMure lG'C (68'F'l (mmHg) ..
Chemical Family-Amine Rdd Vapor Preaare (,.ta) .....
Vapor Pre.ure 46'C (115'F) (pda) ...
Pollution Category-USEPA - - - IMO _____L_ Vapor Density {Air = 1.0) ....
Applicable Bulk Rq. 46 CFR Subcbapter ...... ____Q___ Solubility Ia Water ..

Eledrlul Group-C
General-Moderate fire hazard when exposed to flame or heat. When heated to decomposition, it emits highly
toxic fumes of oxides of nitrogen.
Flub Point ("F) .. 100

Flammable Umits .. 1.6 to 10.6%
Extinpl,hlng Agents. CO., dry chemiCal, water fog, alcohol foam
Special Fire Procedure!l .. Prov1de fire parties with full body and respiratOI)' protection.
HEALTH HAZARD DATA

He.lth Hazard Ratings Odor Thre~hold (ppm) PEL/TWA (ppm) nv!TWA (pplll)
1, 1,1 0.01 20/Skin 20/Skin
~nerai-Vapor modefately irritating. Ltquid causes severe burns.
Symptoms-Burmng of throat and eyes; itching or burning of the skin at site of contact.
Short Jo:xposure Tolerance-Unavailable
1-:x))O!lure Procedures-Vapor-remove victim to fresh air; 11 breathing stops, apply artificial respiration. Skin or
medical ad11ice or attention
REACTIVITY DATA
Stability-This matenal is more stable than most of the other amines listed in this volume. It is a mild base.
Compatibility-Material: Copper and its alloys and galvantzed 1ron are not compatible.
Car11o: Group 7 of compatibility chart. See also Appendix !-Exceptions to the Chart.

Wear butyl rubber gloves, plastic protective apron. sell-contained breathing apparatus. Avoid contact with
liqu1d. Secure Ignition sources. Small spills may be washed away with water.
lr a spill occurs. c:al.l tbe Natiooal ReapoDH Center. 800-424-880l.
210
MOTOR FUEL ANTI-KNOCK COMPOUNDS
(conblln!ng tnc1 alkyl!)
SJIIOQ'- Lead tetraethyl; Lead tetrlimethyl; TEL; Untied NM:10111 Number ..

Tetraethyllead oompounds; Tetramethyllead
compounds; TML
CHRIS Code ..
Foranllii-(C.~),Pb, or (CHI),Pb in mixtures

__aac ------2Q2'F
--
llollbl1 Peat..
A~-Oily liquid; containing dye; musty c 'F
Preeziq Pobll ....................... ___j'C-~'F
SpecUk Gra'rity-1.5 to 1.7
___ c ___.F
V1p0r Preaare :ZO'C (A' F) Uaalll) .. ~
Qeadeal F-lly-lead alkyls Re6d Vapor Preaure (pila)..... ...o..2=l..Z..
V.,or Pr-.re 46'C 1115'F) I,.W.. ___..1..___
PoUIIt:loa CalelorJ-USEPA _.A._ IMO _.A._ Vapor llelllh:J' (Air = 1.0)... .... ....!...J.Q.L
APf)ielble Bulk Rea. 46 CFR SUidlpter ....... ----'L_ SoiWUty In Water Nagljg!b!a
--p-0 FIRE .t EXPWSION HAZARD DATA

er.s-D or E: Combustible liquid, depending upon flash poinl
Goerai.-Moderate fire hazard when exposed

emits highly toxic fumes of lead.
to heat or name. Dangerous. When heated to decomposition, It
Jllah Poblt ('F) .. 89 to 265

Fta.mUie Llndtl ... Unavailable
AlltoApl.doll Temp, ("F) .. Begins to decompose above 212'F
Esllllplalq ..,.... ..... CO., dry chemical, foam. water fog
s,edal Fire Procedllrel .. Tanks exposed to fire should be kept cool with a water spray to prevent
decomposition of the lead compounds. Bec:au8a of the high toxicity of the compound and its combustion
products, only personnel with full respiratory protection should approach burning antiknock compounds. ALL
OTHERS SHOULD BE EVACUATED AS QUICKLY AS POSSIBLE!
HEALTH HAZARD DATA

Healtll Huard Ratlllp Odor nr.IKtld <pp.l) PEL/TWA (JifiD) 1LV~A (ppm)
1, 2, 4 0.2 as lead 0.075 mg/m" as lead
o-.1.-Prolonged &kin contact, ingestion or Inhalation of high vapor may resuh In a toxlc psychosis causing
anxiety which may progress to mania and death. Class B poison.
s,..,._Nervousness. irritability, Insomnia, dreaming; emotional instability; hallucinations, anorexia, vomiting,

constipation, pallor and tremor.
Shrt Ex.-ure ToleraDee-See TLV
Ex....-re ~nnel MUST avoid lnhaMng the vapors or allowing the liquid to touch the skin.
Clothing and other absorbent material in contact with the liquid should be destroyed since they cannot be
decontaminated. Uquid spilled onto the skin should be scrubbed off with kerosene at once. Get medical
attention.
REACTIVITY DATA
StabWty-Relatively stable at ambient temperatures, but it may decompose if heated above 212'F.
eo.,atbOity-M.terial: May be carried in steel tanks. No chemical effect on common materials but will readily
permeate absorbent materials. Avoid contact with oxidizing agents or concentrated acids.
c.r.o:
Unassigned In compatibility chart. For compatibility assistance, call
G-MTH-1 (202-267-1577).

Wear nA:Iber gloves, full protective clothing, eye protection and self-contained breathing apparatus. Secure
igntion sources.
If ...... ocnn. call tile NadGaal a.,.._ ee.t........24-IIIOJ.

ltelurb: TLVITWA (ppm)--0.1 to 0.13 mg/m" as lead
t UnavaUable
211
NAPHTHA: STODDARD SOLVENT
SyniHIJJM- Drycleaners naphtha; Dry<:leanars safety Ulllted Natloq Number .....
solvent; Ligroin (In U.S.A.); Mineral spirits;
Petroleum solvent; Spotting solvent. Stoddard
solvent: White spirits
CHRIS Code ...
Formula-Mixture
BoUin&Polllt.... ~c ~F
c 'F
A~Odor-Colorless
Speclftc: Gr..lty-Q.78
liquid; gasoline-like odor
Freedni: Point.. __ rc :=:F
c ___ 'F
Vapor Prtoaure 20'C 161'F) (IIUDH&) .. ~
CU.kal FQIIIy-Petroleum oil Reid Vapor Pnulll'e (pdf.)... __Q,j__
Vapor Pnaure 44i'C (115'F) IP"-J.. __....U._
PoJiut:loa Catep~ry-USEPA - - - IMO .....J2iL Vapor Oe.taity (AJr = 1.0>... ............. ----1-
Appltcable Balk Rea. 46 CFR Sulxbapter ....... ~ Solbillty In Water ... Negljgjbla

Gnlk--0: Combustible liquid
Electrical Group-O
General-Flammable, mOderate fire risk.
Plull Point ('FJ ... 110 (cc)

F1--ble U111it1: .. 0.810 5.0%
AutoipJtiH. Temp. ('F'). 540 (approx.)
td:ttneuW.Iq Apnts. Foam, dry chemical or CO.
Spedal Fire Procedure~~ .. Cool exposed tanks with water.
HEALTH HAZARD DATA

Health Huard Ratinp Odor 'I'hrel.bold (PJIIII) PEL/IWA (ppml nVJTWA (PPJII)
Unavailable Ul'lavaitable 100 100
Gemerai-Toxic. Prolonged or repeated skin contact may cause defatting of the sll.in and may produce dermatitis
from daly contact.
Symptont~-lnhalation-lntoxication may result from high vapor concentration.
Short Ezposure Toleram:e-500 ppm lor 30 minutes.
Ezposure Proc:edures-lnhatation: Remove victim to fresh air. Administer artificial respiration if necessary.
Ingestion: DO NOT induce vomiting. Eyes: Flush with water lor 15 minutes. Call a doctor.
REACTIVITY DATA
Stability-Stable
Compatibility-Material: Solvent effects on some paints and rubber. Carbon steel satisfactory.
CrJCO: Group 33 ol compatibility chart.

Wear rubber gloves, lace shield. protect1ve clothing. Wear self-contained breathing apparatus. Secure ignition
sources.
If spill oa:an, call tbe Natloaal Reaponte Ceater, f100-..G4-.188l,
Remar~ t Unavailable
:j: Unassigned
212
NAPHTHA: VM I P
Synony-- Light naphtha: ligroln (in U.S.A.); Naphtha, Uatted Nsdona Number ....
petroleum; Painters naphtha; Petroleum solvent;
Refined solvent naphtha; Solvent naphtha; Varnish
makers' & painters' naphtha
CHRIS Code ..
Formule-Mixture
BolllqPoiDt.. ~"C ~"f
Appear~IOrless liquid:gasoline-like odor ___ c ---
Fretm1 Poiat......... ~c ---
Spedfte Gnrdty-0.74 to 0.77 ___ c ---
Vapor PreDare lO'C (68'Fl <IIUIIH&l .. __a__
Chemkal Fllllll1y-Petroleum Oils Reid VIJIOI' Prellure (ptia).... . __2.12,_
V11p0r Pre11ure 46'C (115'F) (ptla).. .....2Jjl_
Pollllti011 Cate(pll'y-USEPA - - - IMO . - L _ Vapor DeasJty (Air = 1,0)...... .. ............ ___L_.
Appliallle Bulk Rq. 46 CFR Subdlapter ....... ___jL_ Sol1llriUty ill Water.. Nft!lliqlb!t

Grade-C; Flammable liquid
Electrkal Group-O
Geaeral-Fiammable, moderate fire risk. Produces suffocating atmosphere of smoke, CO,, and fumes
Flulro Point I'FI ..... 20 to 55 {cc)

F'1uunallle LlmU1 .. 0.9 to 6.7%
AutoJpiUon Te111p. ('Fl .. 450
Extinplllllq Apnts ..... Confined area-CO.., r;y chemical Open area-foam.
Spec:lU Fire Protedaret .. Fight like gasoline fire. Water respiratory devices.
HEALTH HAZARD DATA

Health Haard Ratlnp Odor 'l'llrallold (ppm) PEL/TWA (ppm) TLV(IWA (ppm)
1, 0,1 300 300 300
General-Will remove oils from skin. Prolonged contac1 with liquid may produce drying and cracking ol the skin,
and may produce dermatitis from daily contact. Toxicity by absorption, inhalation, ingestion.
S)'Diptomt-Headache, dizziness, insomnia, coughing, diarrhea, brOnchitis and pneumonia, neNousoass and
irritability.
Short Exposure Tolera~~ce--4000 to 7000 ppm lor 1 hour results in development ol symptoms of narcosis.
ExpoNre P~lnhalalion: Immediately remove victim from contaminated area. Get medical attention. If
splashed in eyes, waSh thoroughly.
REACfiVITY DATA
StllbJIIty-Stable.
CompadbJilty-Material: Solvent effect11 on some paints and rubbers. Carbon steel not affected. Corrosive in
presence of salt water.
Car;o: Group 33 ol compatibility chart.

Wear rubber gloves, face shield, protective clothing. Wear selfcontained breathing apparatus. Secure all
Ignition IIOI.II'CEIS.
H a .,W occ:urs. call die NMfoal tte.poue Ceater, 800-424-1801.

Remarks: t Unavanable
213
NAPHTHALENE
Synony~U-Camphor tar; Naphthaline; Naphthene; Tar United Natiollll Number .. molten
camphor; White tar crude or
refined
CHRIS Code ..
Formula-C1uHo
BolllnaPoillt.. ~c _._W'F
Appearaace-Odor--Cotortess liquid or white solid; odor
___ c ___ .F
of mothballs Frentng Point. ~c ----..lZ'F
Speclftc Grarity-1.15 c ___ "F
Vapor Prellure lfi'C (68'FJ (mm.Ha).. __.::;;_.1_
Cbemk:aJ Family-Aromatic hydrocarbon Reid Vapor Pressure (pail)... ____I.QL_
Vapor Preuure 46'C (115'F) (p~~la).. ~
Pollution C.tQGry-USEPA _____a_ IMO __A __ Vapor De!Wty (Air = 1,0).. .. ............... ~
Appliable Bulk Rea. 46 CFR SubcUpter ........ ___Q_ Solubility In Water.... NaWjgjble

Grade-See "General" comments below.
Electrica1 Group-O
General-Combustible Grade E solid normally carried in the molten state. When carried molten, it presents a fire
hazard comparable to that of a Grade C flammable liquid. Naphthalene vapOI' or dust can form explosive
mixtures with air. Tmdc vapors given off in a lire.
flub Point ('F) .. 190
flammable Limits. 0.9 to 5.9%
Autolpltio!l79n Temp. ('F) ... 979
ExtlnpDshing Agents .. co .
dry chemical. foam, water fog
Special Fire Procedures Do not direct a hose into a tank of molten naphthalene. Otherwise the
naphthalene w111 be spattered about with explosive force. Water or foam must be applied carefully to mohen
naphthalene to prevent excessive frothing. Wear eye protection, self-contained breathing apparatus and
protective clothjng.
HEALTH HAZARD DATA

Helll.tb HUIU"d RatinK!l Odor Threshold (ppm) PEL/TWA (ppm) UV/TWA (ppm)
2, 1, 2 25" 10 10
General-Molten liquid is scalding on contact. Vapor is irritating to skin and eyes.
Symptoms-Eye 1rr"1tation, headache, nausea, profuse perspiration, vomiting.
Short Exposure Tolerance-15 ppm lor 5 minutes.
ExiiO'ure Procedures-Vapor-remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or
medical advice or attention. ' NOTE: Detectable odor is greater than the TLV. Exposure to potentially
dangerous vapor concentrations can occur before the product can be smelled.
REACTIVITY DATA
Stability-Stable
CompatibUJty-Materlai: Noncorrosive Most materials of construction are satisfactory.
Car110: Group 32 ol compatibility chart.

Wear rubber gloves, face shield, protective clothing. Have all-purpose canister mask available. Upon spilling,
the material will solidify and can be scraped up with nonsparking shovels into a waste container. Naphthalene
spilling into water will either solidify and smk, or solidify into a foam and float.
If 1 spill oecun, call tbe National Reaponae Ceater, 800-4l4-8tiOl.

Remarlu: Normally transported at elevated temperatures. See 46 CFR 36-Eievated Temperature Cargoes.
214
NAPTHENIC ACIDS
Synonyms- No common synonyms.
CHRIS Code ..
Fonnua.-Cnli,n~COOH to C.H.n-toCOOH where

0=13-28 Bollbtt:Po&nt.. ~c ~F
A~-Gold to dark red to black liqUid; c 'F
penetrating, perSistant, putrid odor Freulq PcN11t..... ~c <O'F
S,edfle Gralit)t-0.98 at 20'C
___ c ___ .F
Vapor ~ lO'C (61'F) l-Ift) ......... .....s:u_
Cheleal Family-Organic acids Reid Vapor Pre.ue (. .).......................... ~
Vapor ""-re 46'C (115'F) ~-- ~
PollutiH C.~qory-USEPA __fL_ IMO ._..A_ Vapor Deae1tJ (Air 1.01... ..... __2.L_
Applleallle Balk R ... 46 CFR Subdlapter ....... -..ll....Q_ SotubWty Ill Water lnag!ubl

Electriell Group-NA
General-Combustible liquid.
F'lulll PoJ11t ('F) .. 300

Flammallle Umltl .. LEL=1% UEL-Unavlilable
Allloipjtiola T-p. ('F) .. Unavailable
EitillpiUiaa Aaena ..... Foam, dry chemical, carbon cloxlde
Special Fire Proeedllnll .. Water may be ineffeCtive; cool exposed tanks with water to prevent over
pressurization and rupture.
....................
UnavaHable
HEALTH HAZARD DATA
Odor nreMehl <pp.l) PEL/TWA~)
Unavailable
TLV/I'WA~)
10 mgtm
Geaerai-Mlldly hazardous to man; hazardous to aquatic Ufe In low concentrations.
S)'lllptoma-lrritating to eyes, nose, throat Inhalation: coughing, dlfficulty in breathing. Skin contact: irritating.
Ingestion: nausea.
Sbort i:spoAU"e Toleruee-
Proced..--Jnhalatlon: remove to fresh air. Ingestion: give large quantlfl88 of trash water. Eye contact:
i:s)IOIIIU'e
flush with water until irritation stops. Skin contact: flush with water and soap.
REAcnVITY DATA
StiiNiity-Stable.
eom,.Ubillty-Materi..: Generally corroSive to metals.

Avoid contact, wear safety glaaaes or lace maak. Dike and remove spilled material. Prevent !rom reaching
bodies of water. since it louis beaches, and taints aquatic lite.
ae..-ka: Otten odorless after

t Unavailable
If a all1 occun, aDdle Natlellal
processing.
a - c..ter, I00-4l4 1102,
....
21S
NEATSFOOT OIL
Sr-YIIIt- Be.butum oil; Hoof oil United Natl- Number ..... .
CHRIS Code ....
-
Fonau.ta-lndefinlte mixture
&ilia1 Poiat .. . ~c ....Y....J:!lgb'F
Appeuuee..Odor-Pale yellow oily liquid with a peculiar c 'F
FreezJna Potnt.... -10-0'C 14-32'F
Specllk Gra~Uy-0.91 to 0.92 c ___ "F
Vapor Pralllf'e 20'C (68'F) <nunHa) .. -.2.Q!_
Cieleal F..uy-Esters Rdd Vapor Preuure (plla)... __JU__
Vapor ~re <M'C (115'F> (JIIIa).... -....l2...1L.
PoJiatloa CateJ(lry-USEPA - - - IMO _____D_.. Vapor Dellllt)' (Air = 1.0)... ............ __.1__
Applleabk Bulk Rea. 46 CFR Subcha,ter ....... -----'L_ Soi111NUty Ill Watel'.. NapUglb!t
FlRE .t EXPLOSION HAZARD DATA

Electrical Gr011p-D
General-Moderate fire hazard il exposed to high heat.
Flh Point ('F) ....

FlaM~~~able UIU ....
.,.
Unavailable
AutoJpltloa Temp, ('F) .. 820
ExtlaiUitblll& Aeents ... Dry chem'lcal, foam or carbon dioxide
Speclal. Flft Proeed~~rq .. Water may be ineffective on fwe.
HEALTH HAZARD DATA

Heald! Huard Rtltlnp Odor 'l'brnllold (ppm) PEL/IWA {pJIIII) UV/TWA (ppm)
General-Not harmful
Symptom.-None
Short EJ:po!JUre Tolerance-LDso above 15 g/kg.
Exposure Procedur"-Wash thoroughly with soap and water.
REACI"IVITY DATA
StahWty-Stable.
Colnpatibility-Materilll.: Usual materials of constructicm are suitable.

Waar rubber gloves, taca shield and protective clothing.
If a IPlll OCCVI, eall tile Nlll"-aa Reepoaae Ceater, 800-4l4-880Z.

Remarb: t Unavailable
* Unassigned
216
NITRIC ACID (56 to 68%)
Syaoay-- Aqua fortis: Azotlc acid; Engravers acid: United Nat'- Nuber.....
Engravers oil; Hydrogen nitrate
CHRIS Code ...
BoUID& Pobll .. ____J,Z2'C ---...2ll'F

Appnranee-Odor-Colorless to yellow liquid, fumes in c 'F
moist air; characteristic, choking odor Freezina Point... -iWC -30'F
Speelfte Gra-.ity-1.35 to 1.41 c ___ F
Vapor Prellure ZO'C (68'F) (-"IJ.. ___l.l___
Qudcal Family-Inorganic acid Rehl Vlp(n' Prea.re (....)... _z.z..._
Vapor Preaure 46'C (115'F) (pUa) ___l.L_
Polllltkm Catqory-USEPA ____.c.__ IMO ____.c.__ Vapor DeUty (Air "" 1.0)... . ........... ___2.!L_
Appllable Blllk Rea. 46 CFR S.bebapter ....... _Q__ SolubOity Ia Wllter .. Comp!att
F1RE It EXPLOSION HAZARD DATA

Grade-Non-flammable. Classified as COI'I'Osive liquid.
EtectrkaJ Grour-8 (based upon possible hydrogen gas (H2) generation should a leak or spill occur).
General-Nitric acid will not bum. It will react with many metals, giving off hydrogen gaa which is highly
flammable. If hydrogen is trapped in confined spaces, It can form an explOSive mixture with air. See data
sheet for hydrogen. May give off toxic O)(ides of nitrogen and acid fumes when heated in a fire.
Flail Potld ('F) ... Non-nammable
FWuaU1e UmUa ... Non-flammable
Alltoipjtloa Temp. ('F) .. Non-flammable
~tiJipjiii1Jq Asem .... Water
Spedal Fire Proeedara .. If fire results, water will absorb the toxic oxides generated. Are fighters should
wear lull protective clothing including respiratory protection.
HEALTH HAZARD DATA

Healtk Huanl Ratinp Odor 'I'IIrabold (ppm) PEL/IWA (ppm) TI.VIJWA~)
Geaerai-Brealhing o1 vapors Is extremely dangerous. Utile warning ol danger Is at first apparent and initial
symptoms are obscure. Liquid bums the skin forming deep ulcers which leave leathery scars.
S)'lllpto-Vapor: immediate severe skin and lung bums. Uquid: smarting, itching, and yellow discoloration
upon skin contact.
Sltort Expo1ure Toleramee-15 ppm for 5 minutes.
Expoure Proce~~ue~-Remove the affected indiVidual trom the contaminated atmosphere and call a Ph)'slclan at
once. Keep patient at rest until seen by the physician. In case ol eye or skin contact, flush Immediately with
copious quantities ol water while removing contaminated clothing. The eye irrigatiOn should be continued for
15 minutes. Cases Involving eye contact and inhalation MUST have medical helpl
REAcriVITY DATA
Sr.bnlty-Reacts violently with numerous organic materials. Decomposes at temperatures near boiling. Soda
ash will neutralize residual acid from spills.
eo..-tlbtllty-Mmrlal: Attacks aluminum; compatible with stainless steel and high Chrome iron allOyS.

Wear rubber gloves, face shield, protective clothing. Body shield and self-contained breathing apparatus
should be available. Secure ignition sources. Flush cautiously with water. Avoid directing stream Into larger pools
or pockets ol concentrated acid. If possible, cover contaminated surfaces and spill with large quantities o1 soda
88h or sodium bicarbonate. Mix and add water if necessary to effect good mixing. Scoop up slurry. Wash site
If .,01 oecun, Cllll tbe National Rapoae Cellter, 800-424 11102.
217
(NOTE: Thla Cllrgo Ia currenUy not jMnnttled to be ahlpped In bulk In U.S. watera)
NITRIC ACID (95%)
SynORy-Aqualortis; Azotic acid: Engravers acid: Uaitecl N1do1111 Numbes-...
Engravers oil; Hydrogen nitrate; Red fuming nitric
acid; White fuming nitric aCid
CHRIS Code ..
Fonnua.-HNOs
BoUiq: Paint.. ~c ----....2Q2'F
Appearuee-Odor-Water-white to light brown liquid; c 'F
acrid odor F'reezbll PcNat... -52'C -B1'F
Spedfte Gnnity-1.50 c ___ F
v... Prellare :wc <U'F> <lllllllfa) .. ---1L
Rekl VlfOJ" Preuure (JIIIa)... ---l..i...._
V11p0r f"reaun 46'C (115'F) (pWIJ.. ____2.Q__
Pollutro. C.tqory-USEPA _..c.._ IMO _..c.._ V11p0r DeD.ity (Air = 1.6) .................... -lJ..Z._
Applkable &.lk Re~o .W CFR S.bcbapter ....... - - - Solubility In Wat.. Comp!ett

Grade-Non-flammable. Classified as corrosive Nquid.
EJeetrieaJ Group-Nonllammable
Gclaerai-Nitric acid wMI not burn. It will react with many metals, giving oft hydrogen gas which is highly
flammabla. If hydrogen is trapped in confined spaces, it can form an explosive mixture with air. See data
Sheet lor hydrogen. May give off toxic oxides of nitrogen and aCid fumes when heated in a fire.
Flub Polllt ('JI) .. Non-flammable
..,__.. Utaltl .. Non-flammable
AutoJpltro. Temp. ('F) .. Non-flammable
Estla~. AJutl ... Water
Spedal Fire Proeedtlrel .. If fire resuns, water will absortl the toxic oxides generated. Fire fighters must
wear lull protective clothing including respiratory protection.
HEALTH HAZARD DATA

Healtll Haunl Radnp Odor lbresltold (ppm) PEL/IWA (PJIIII) TLV/lWA (ppm)
GeDtrai-Breathing of vapors is extremely dangerous. Utile warning of danger is at first apparent and Initial
symptoms are Obscure. Liquid bums the skin forming deep ulcers which leave leathery scars.
Sympto--Smarting, itching, and yellow discoloration upon skin contact If acid is not removed at once, intense
pain and severe burns resuH.
Sbort !:spoAR Toleranee-15 ppm for 5 minutes.
&)IORI"e Pl"oeedur"-Upon skin contact, wash with large amounts of water at once. Aemove the affected
individual from the con1a.minated atmosphere and get medical help. In case of eye or skin contact, flush
immediately with copious quantities of water while removing con1Bminated clothing. Eye irrigatiOn should be
continued tor at least 15 minutes. All cases involving eye contact and inhalation MUST be seen by a
physician.
REACTIVITY DATA
StaWUty-Aeacts violently with numerous organic materials. Decomposes at temperatures near boiling. Sodo
ash will neutralize residual acid from spills.
CollltJ11dbillty-M.Iterial: Compatible with stainless steel or aluminum.
Carao: Unassigned in compatibility chart. For compatibility assistance, call

G-MTH-1 (202-267-1577)

Wear rubber gloves, lace shield, protective clothing. Body shield and self--contained bntathing apparatus
should be available. Secure ignition sources. Flush cautiouSly with water. Avoid directing stream into larger pools
or pockets of concentrated acid. If possible, cover contaminated surfaces and spill with large quantities of soda
ash or sodium bicarbonate. Mix and add water If necessary to effect good mixing. Scoop up slurry. Wash lite
u.,w oean. ea11 t1te Nlltloul a.,._ C.ter, soo-u
88112.
Rtawb: Bulk lhipment of thle concenlnltton Ia not permitted In U.S.........
218
NITROBENZENE
S)'liOIIr-- Essence ol mirbane; Benzene, nitro-;
Mononitrobenzene; Nltrobenzol; Oil of mlrbane
CHRIS Code ....
Boillaa; Polnt .. ___2ll'C __!1,2'F

Appearanee-Odor-light yellow green to brown liquid;
___ c ___F
similar odor to oil of bitter almonds Freezin& PoilU... ____]'C ___!l'F
Spedflc Grafity-1.20
___ c ___"F
VlfOI' Pr-.u't :zoc <68'F> <mmHa> . ____Q.2Q_
CbeDUcal FamUy-Nitrocompounds Reid Vapor Pre.ure (. .)... _Q.Q1_
Vapor~ 46'C (115'F) (pm)... --.2..QL_
PoUutlon c.tqory-USEPA _k._ IMO _a__ Vapor Dealtty (AfT = 1.01... ____!.2!...._
Applluble S.lk Rea, 46 CFR S.IM:bapter ....... ~ Solltllfty In Water.. Ntqljgjb!e

E1eetrtca1 Gfo.p-D
GeDeni-Moderate flre hazard; at elevated temperatures, flammable, toxic vapor may be given ott.
FIMII Pofat !'Fl .. 190

~IJmJts .. LEL=1.8% UEL-onavailable
Aulolpitioll Te!IIP. I'F) .. 900
Exl:l:apta~q;Apaa .... Confined area-CO., dry chemicals. Open area-foam.
Spec1al Fire ProcedUJW .. Use water to keep fire exposed containers cool. Wear complete rubber
protective clothing including eye protection and self-contained breathing apparatus.
HEALTH HAZARD DATA

Heal.tll Haanl Ratbtp Odor 'I1Irelbohl ~) PELITW A (ppm.l TL V/IWA (ppm)
3, 2. 4 0.0047 1/Skln 1/Skin
Ge.nl--Highly toxic when absorbed thru the skin, inhaled as vapor, or swallowed. This Is a blood poisoo and
a nerve poison which is readily absorbed by the body.
S)'111ptofu-"Blue lip" or bluish tinge seen in fingernail beds, lips, lobes of ears; conjunctive, mucous
membranes and tongue. Fatigue, headaches, vomiting, geoeral weakness and signs of nervous system
involvement.
Sltort Expollll'e Tolerutee-200 ppm for one hour-no serious disturbance; 40-80 for a few hours--slight
symptoms. Absorption may cause death due to nervous system poisoning.
Ex,.......e Proeectura--Remove all contaminated clolhing, wash skin with soap and water, flush skin for approx.
15 minutes. If swallowed, Induce vomiting until vomit fluid is clear. II inhaled, remove victim to fresh air and
start oxygen inhalation. Contaminated clothing should be thoroughly washed in soap and water before using
again. Get medical help.
REACfiVITY DATA
s ..blUty-Stable.
CompatibtlltJ-Millerilll: Usual materials of construction are suitable.

Flush areas with large quantllie8 of cold water. Ventilate freely. Hot water can be used to remove some
absorbed material. Wear complete protective clothing including eye and respiratory protection.
If a .,W oc:aaw, call die Nadoul -ae.,o- ee.ter, II00--4lt 8101.
219
o-NITROPHENOL
Synony- 2Hydroxynitrobenzene; 2Nitrophenol; ONP United Natloa1 NuMber ...
CHRIS Code ..
Formula-HOC.H,NO,
Bollin& Point .. ___....Z1j"C _____ill'F
Appearance-Odor-Ctystaline yellow solid; aromatic c "F
sweet odor Freezin& Point .. ____M"C __ill"F
c _ _ _ "F
Specltk GraYity-1.49 (solid)
Vapor Preuure lO'C (68'fl lmmH&) .... ----<.1.._
Cbekal Family-Aromatic nitro compounds Reid Vapm" Preuure (p&la)... --"'l.L
Vapor Preuure 46'C lllS'F) (plia) .. --"'l.L
Pollution Cate&m'Y-USEPA _____ll_ IMO _ L . Vapor Desl1lty lAir = 1.0) ..
Applicable lhllk Reg. 46 CFR Subebapler ........ ___Q_ Solubility la Water .... 025%

Gr..te-E: CombtJstible liquid
Elettrinl Group-NA
General-Violently decomposes above 180'C. Can give off toxic nitrogen oxides and unburned vapor when
heated or burned.
Flalll Point ('Fl. 215

FlamabJe Umlts .. Unavailable
Autolpltion Temp. ('F) .. Unavailable
Elr:tl11811illlina Apnn .. Water, foam, dl'y chemical, carbon dioxide, Halon
Special Fire Prondures .. Cool exposed tanks with water spray. Wear sell-contained breathing
apparatus and full protective clothing.
HEALTH HAZARD DATA

Health Haqrd Ratlnp Odor Thrahold (ppm) PEL/TWA (ppm) TLV /TWA (ppm)
Gesteni-Liquid, solid, dust are toxic. When heated or burned, toxic nitrogen oxides and unburned material
~oduced. Harmful to a~J.~atic tile even in very low concentrations. Molten material will burn tissue.
Symptoms-Ingestion-headache, nausea, unconsciousness, drowiness. Inhalation-headache, nausea,

unconsciousness, drowsiness, cyanosis, breathing diflicufties. Skin-irritation, headache, nausea,
unconsciousness, drowsiness (absorbed through skin). Eyes-irritation.
Short Exposure Toleran-
E~:.,.,.ureProc:edura--lngestion-11 conscious, drink water or milk; induce vomiting. If unconsciOtJs. do not give
liquids or induce vomiting, but keep victim warm. Eye contact-flush with excess water lor at least 15
minutes, call physician. Skin contact-wash thoroughly with soap and water-quickly remove material.
Inhalation-remove to fresh air, give oxygen or artificial respiration, as necessary.
REACfiVITY DATA
Stability-Stable below 180"C. Keep away from caustics to avoid formation of unstable products. Reacts
violently with potassium hydroxide (caustic potash).
Compatibility-Material: Softens rubber and paint. Compatible with mild steel. stainless steel, and polyethylene.
Carao: Unassgned in the compatibility chart. See Appendix !-Exceptions to the Chart.

Avoid ltquid, solid, dust. Wear rubber gloves and goggles. If fumes present, use self-contained breathing
apparatus. Keep upwind. Stop discharge if possible, dike (including life lighting water) and prevent from entering
waterways.
Remarks:
If 1 aplll occ:n. call t1te National llnpoaR C.:nter, 800-414 8801.
....
220
2-NITROPROPANE
Synonyms-lsonitropropane; 2-Nitropropane: United NatioDs Number ....
Nitropropanes; sec-Nitropropane: 2-NP; Propane,
nitro-
CHRIS Code ...
Formula-C,H,NO.
Bol:lin& Poiat .. ---1.2..1 'C ~-F
Appeanmce-04or-Color1ess liquid; odorless c 'F
Freezing Point.. _g;]'C -135'F
Specific Grnlty-0.99
___ c ___ .,
Vapor Preuure :zoc (68'FJ <HK> .. . ___1ZL
Chemical Family-Nitro compounds Reid Vapor Puuure q.ia)... _1__
Vapor Preuure 46'C <U5'FJ (peja). ~
Pollution Cateaory-USEPA ----A_ IMO ___D__ Vapor Deattty (Air = 1,0)... .....aJllt._
Applicable Bulk Reg. 46 CFR Subebapter .. . ____Q__ Solublllty In Water.. $1jght

Grllde-D: Combustible flquid
Electrlcal Group-C
General-Toxic oxides of nitrogen may form in fire. Moderate lire hazard. Decomposes when subJected to high
temperature.
Flub Point ('F) ... 103

FlaaJiqJe Umits .. LEL=2.6% UEL-unavailable
AutoiaDitlon Temp. ('F) .. 802
Extillp.isbll'lg Ageats .. Alcohol foam. water spray, CO... dry chemical, foam
Special Fire Procedures .. Water protective clothing and self-contained breathing apparatus.
HEALTH HAZARD DATA

Hulth Hazard Ratinp Odor Threshold (ppm) PEL/TWA (ppm) nvnwA (ppm)
1,1, 1 300" 10 10
General-Suspected carCinogen. Slight irritation !rom liquid contact with skin and eyes. Vapor inhalation is
irritating to respiratOI)' tract with moderate systemic effect.
Symptoms-Headache, dizziness, nausea, vomiting, diarrhea.
Short Expo~~ure Toler~Utte-500-1000 ppm for up to one hour.
Es.po1ure Procedurea-ln case of pulmonary symptoms or cyanosis, remove workers !rom contaminated area at
once; place in bed, rest, use oxygen, if respiratory distress is present, and obtain medical anenlion.
*NOTE: Detectable odor is greater than the TLV. Exposure to potentiallY dangerous vapor concentrations can
occur before the vapor is detected by smelt.
REACTIVITY DATA
Stablllty-Stable under normal conditions. Decomposes when subjected to high temperatures. Rapid heating to
high temperatures may cause an explosion.
Compatibility-Material: Copper and its alloys, wet mild steel, and lead and its pigments are incompatible.
CaJ-ao: Group 42 of compatibility chart.

If possible, wear neoprene gloves, plastic protective apron or coat and seHcontained breathing apparatus.
Provide good ventilation. Secure ignition sources. If possible, cover with soda ash and mix and spray with water.
Scoop up. Wash site with soap solution.
If a .pll oecllftl, eall tbe National llapoa1e Ceater, 800-4l4-8102,
Rearks: t Unavailable
221
oNITROTOLUENE
SyDOnyms- 2-Methy! nitrobenzene; 2-Nitrotoluene, United N1tions Number ...
Orthonitrotoluene: o-Nitrotoluol: Toluene, orthonitro-
CHRIS Code
Fonnui11-C,H,NO,
BoillnK Point .. ____mc ~F
AppearaDceOdor-OIIy light yellow liquid; bitter almond ___ c "F
odo Freezing Point .. ~c _____2li"F
c _ _ _ "F
Speeiftc: Gra.-lty-1.16
Vapor Preuure lOT (68"F) (mmHg) ..
Chemical Famlly- Reid Vapor Presaure (pllla) ... ----l.olL
Vpor Pressure 46"C (l15'F) (psiaJ .. __Q.QL
Pollution Cteaory-USEPA _Q__ IMO ......____Q__ Vapor Deaaity (Air = 1.0). ___flL
Applicable Bulk Reg. 46 CFR Subchapter.. .. ____Q__ Solubility in Water .. Nea!jqlble

Electrical Group-O
Gener..-low hazard to heat or open flame: combustible, poisonous gases may be released in fire.
Flub Point ("F') . 223 (cc)

Flammable Limits . LEL=2.2% UEL-unavailable
AutoiKDit:lon Temp. ("F). Unavailable
ExtinfUishing Agents Water fog, CO.. dry chemical
Spial Fire Procedure!~ .. Wear goggles, self-contained breathing apparatus, rubber gloves. Cool
exposed tanks with water spray
HEALTH HAZARD DATA

Health Hll.Zilrd Ratings Odor Thresbold (ppm) PEL/TWA (ppm) TLVITWA (ppJn)
3, 2, 3 3 2/Skin 2/Skin
General-Tox1c by Ingestion, mhalation or absorption through skin.
Symptoms-Headache, dizziness. difficult breathing, nausea, vomiting, convulsions, imtability Sktn becomes
"ntated
':ih<Jrt ~.xpo'>'<ure T<~lerance-200 ppm lor 30 minutes.
Exposure Procedure!l-Remove v1ctim from source of exposure and give rest. II breathing stops give artificial
resp1rat1on. Remove contaminated clothing and shoes; flush affected areas with water. Call a physician.
REACTIVITY DATA
Stahillty-Siable Reacts wrth sufluric acid. oxidizers.
Compatibility-Material: Usual materials of construction are su1table
CIII"IIQ: Gmup 42 of compatibility chart.

Wear protecllve clothing, sell-contained bfeath1ng apparatus, butyl rubber gloves. Avoid absOI"ption through
the skin
If a spill OCCIII"Il, call the Natl011al Re.ponse Center, 800-424-8801.

Remark.l: These data are lor the ortho form; the para and meta forms of N1trotoluene may differ somewhat 1n
specific physical properties.
Vapor Pressure: 1 mmHg at soc
222
NONANE
S)'JIOIIyms-1-Nonane; n-Nonane Un.lted Natlou Number ...
CHRIS Code ..
Boillll& PoJ.t .. ~c __JQQ'F

AppellnllCe-()do-Colorless liquid; gasoline-like odor c 'F
Freez1D1 Poblt... -S4'C
-85'F
Spedfk GraTity-0.72 ___ c ---
VapoT Pre.un: lO"C (61'F) <-HaJ ......... ___lQ__
Otemkal FlUidly-Saturated aliphatic hydrocarbon Reid Vapor '"'-ure (plia)... .. ............. ____2.2.._
VllpO!' Pre.ure 46'C (115'F) (pl1a) ........... ___2.!__
PoUIItloa Cateaory-USEPA - - - IMO ____c.:_ VIIJMW Dea.lty (Air = 1.0)..... ____!.!!_
Afp~tc:UJ, Blllk Rea. 46 CPR SbdaapteT ........ ---'2....Q_ SolubWiy ill Water.. . Nmllplblt

Electrtad Grolap--0
Ge.ral-Moderate fife hazard when exposed to heat or flame.
F1uh Poi:at ("F) .. 86 (cc)

ma-bleu.u. ...
Alltoipltlon r-,.
<"F> .......
Extlnpidliaa Apnb ...
0.74 to 2.9%
545
Dry chemical, foam, CO,
Spee1al Flft Proeedlara ..... Tanka exposed to fire shot.lld be kept cool with a water spray. Water may be
HEALTH HAZARD DATA

Health Hazard Ratinp Odor 'I'hrelhold (ppm) PEL/IWA(WJII} TI.V!TWA <Jt-)
General-low toxicity; Irritant, narcotic in high concentrations.
Symptomt-lrritation of respiratory tract. Narcotic in hiQh concentrations.
Sltort Expo111u Totennee-Unavailable
I:Kpo11un Proc:edur-Remove viCtim to fresh air. Apply artifiCial respiration If breathing stops. Get medical
attention.
REACfiVITY DATA
SUbititJ-Stable.
CompatlbWty-Malerlal: Compatible with most materials of construction.

Have all-purpose caniSter mask available. Secure ignition sources.
If .,W oean. cd tlte Nltloalll ....... Ceater, 11(10..424 11102.

R.....U: Pollution category C oll-llka, 33 CFR 151.49.
223
1NONENE
Synonylllll- n-Heptylethylene, 1-Nonylene United Nations Number ....
CHRIS Code ..
Fonnula-CH,(CH,).CH = CH,
BoUin1 Point ..
AppeanlllCe-Odor-Colorless liquid with a pungent
hydrocarbOn odor Freezina Poiat ..
Specifh: GraYity-0.73
Vapor Preaure lO'C (68'F) (mmH&) .. ~
Cbemk:al F11111lly-Oielin Reid Vapor Preaure (pliaJ... ......2.Z.1..._
Vapor Pre.ure 46'C (llS'F) <p.ia).. ~
Pollution Catqot')'-USEPA - - - JMO _____a___ Vapor Deaalty (Alr = 1.0) .......................... __4.J.._
Applicable Bulk Rea,. 46 CFR Subeb.apter ....... ____Q,_Q_ Solubility in Water.. Negljgjble

Grade-D: Combustible ltquid
Electrical Group-O
General-Moderate lire hazard when exposed to heat or flame.
F1asb Point CF).. 85

Flammable Limits. 0.7 to 3.9%
Auto!IP'itlon Temp. ("F). Unavailable
El;tinpishing AJents .. Confined space-dry powder, CO.. Open area-foam.
Special Fire Proeeduret . Water may be ineffective on fire. Cool exposed tanks with water.
HEALTH HAZARD DATA

HeaJtb Hazard Ratings Odor lbnsbold (ppm) PEL!lWA (ppm) TLVITWA (ppm)
General-Low tQ)ricity. Effects similar to gasoline and kerosene.
Symptoms-High vapor concentration Irritates eyes and respiratory tract; acts as an anesthetic.
Short Exp~.~sure Tolerance-Unavailable
Exposure Procedurecs-11 ingested do NOT induce vom1ting. Vapor-remove v1ctim to fresh alr, if breathing stops,
apply artil1c1al resp1rat1on. Skin or eye contact-remove contaminated clothing and gently flush affected
areas w1th water lor 15 m1nutes. Get medical adviCe or attention
REACTIVITY DATA
Stability-Stable.
Compatibility-Materials: Mild steel is suitable; may soften some rubbers, paints, or plastics.
Cargo: Group 30 ol compatibility chart.

Wear rubber gloves, face shield, protective cloth1ng. Have all-purpose canister mask available. Avoid contact
Ir "'II uc:eun, ea.ll the Natl...t Respoqe Cellter, 1100-4l4-880l.

Remarb: :t Unass1gned
224
NONYL PHENOL
Synonyms- No common synonyms. United NatioiUI Number ....
CHRIS Code ..
Formula-C,;H,OHC,H,~
Bollin& Point.. ~c ______2li'F
Appeua~~~:e-Odof-Ciear, straw.colored syrupy liquid; c 'F
phenolic odor, like disinfectant Fl"ftZlng Point.. -20'C -4'F
Specific Gral'lty--0.94 c ---
Vapor Preuure :ZO'C (68'Fl (mmH&) . ____Lmt_
Chemical Family-Phenol Rekl Vapor Preuure (plja)... ~
Vapor Preuure 46'C (ll5'JI) (psla).. ___Lmt_
Pollutloa Cateaory-USEPA - - - IMO _.A_ Vapor Dentity (Air = 1.0) ......................... _z.a_
Applicable Bulk Rea. 4fi CFR Subebapter ....... _Q._Q_ Sol11billty In Wales'.. NM!jgjbtft

EJeetrieal Group-O
General-Slight hazard, when exposed to heat 01' flame.
Fluh Point ('F) .. 300

Ftammable Limitlil .. LEL=1% UEL-unavailable
AutcHpjtion Temp. ('F) .. Unavailable
Extingui&bJDII Apnts .. CCh, dry chemical, alcohol foam, water fog
Special Fire Procedure~ ... Water or foam may cause frothing. Firefighting parties should be provided with
full body and respiratory protection.
HEALTH HAZARD DATA

Health Hazard R1tlnp Odor Thrnhold (ppm) PEL/TWA (ppm) TLV;TWA (pp111)
1, 2. 1 Unavailable Unavailable Unavailable
GeneraJ-Liquid irritating to skin and eyes.
Symptoms-Skin contact may cause burns and blisters.
Short Expoaure Tolei'IUICe-Breathing the vapors in a state approaching saturation in room air was not fatal to
animals nor was a 4-hour exposure to mists, generated from the chemical heated to 170"C. Eight hours
exposure to the mist killed 2 of 6 animals.
EJ:potgre Procedu~Remove victim to fresh air; if breathing stops, apply artiftcial respiration. Skin or eye
contact-immediately flush affected areas gently with water for 15 minutes. Remove contaminated clothing.
Get medical attention.
REACllVITY DATA
Stability-Stable.
Compatibility-Material: Should be stored in stainless steel. Nonyl phenol picks up iron in plain steel. Copper
and its alloys promote color formation.
Clrgo: Group 21 of compatibility chart.

Wear rubber, face shield, protective clothing. Have all-purpose canister mask available. Avoid contact with
liquid.
If 1 .,UI occun, e.U the National Re1p0111e Ceater, IIOO-U4 8802.
Relllll'b: +Un&SSIQned
225
NONYL PHENOL SULFIDE
Synonyms- No common synonyms United Nations Number ..
CHRIS Code ..
Formula-Mixture
Appearance-Odor-Dark brown liquid with mild

Bolling Point.. ~c
c ___.,
___QQ"F
petroleum odor
Specific Gravlty-0.97
Freezing Point
c ___.,
-12"C ____j.Q'F
Vapor Pressure lO"C (68'F.l lmmHg) .. ..'L.l.ow..

Chemic:~! Family-Petroleum oils Reid Vapor Pressure (psia) ... ..'L.l.ow..
Vapor Pressure 46"C (115'F) (psia) .. ..'L.l.ow..
Pollution Cate110ry-USEPA - - - IMO ____jj____ Vapor Deuity (Air = 1.6) .. __];f_
Applluble Bulk Reg. 46 CFR Su~hapter. ... ____Q__ Solubility In Water. Negljgjb!e

Grade-E Combustible liquid
Electrical Group-NA
General-Moderate lire hazard when exposed to high temperatures. Combustion produces some sulfur dioxide
and carbon monoxide. Above 140"F, hydrogen sulfide, a poisonous gas is g;ven off.
flash Point ('FJ greater than 200 (cc)

Flammable Limits. Unavailable
Autoignition Temp. ("F). Unavartabte
ExtinguishinK Agents. Carbon dioxide, dry chemicals, water spray or foam.
Special Fire Procedures .. High temperatures create toxic fumes. Keep tanks coot with water spray.
Firefrghters should have sell-contained breathing apparatus and protective clothing.
HEALTH HAZARD DATA

Health Haz.ard Rating<> Odor Threshold (ppm) PEL/lW A (ppm) TLV!TWA {ppm)
Unavarlable Unavailable Unavailable Unavailable
Generai-Negligrble ellecls from inhalation, rngestion or skin absorption. Persons hypersensitive to amine
denvatlves should avoid all exposure.
Symptllms-Mrld skin rrritation and reddening of skrn will occur after prolonged contact with skin.
Short 1-:~p.osure Tolerance-No cumulative toxic or sensitization effect results from repeated exposure.
Expll\ure Proct!dures-Sk'rn-wash affected area wrth water. Eyes-flood eyes with cop10us amounts of water.
Vapor-no particular hazard at room temperature. but toxicity increases with increase in temperature. If
exposed lo odorous fumes, get medical help
REACTIVITY DATA
Stability-Avoid high temperatures (140"F) and prolonged or repeated heating srnce one component will
decompose and give off poisonous hydrogen sulfide
Compatibility-Material: Has no corrosive or destructive elfects on steel, wood or cloth. May soften natural
rubber and some parnts
Cargo: Group 33 of compatrbilrty chart

Wear rubber gloves, face shield and sell-contained breathing apparatus. Avoid contact with liquid. Secure
rgmtion source.
If a spill Ounr, call the NatiODal Response Center, IIOII-4U-8802.
Remarks~ Thrs ser~es of prcducts contams about 50% lubncabng oris. The remarmng compounds, whtch rnclude
nonyl phenol sulfide at concentrations of less than 6%. are oxidation inhibitors or detergent additives.
# No Determ~nation
'I' Unassigned
226
lso-OCTYL ALCOHOL
s,._)'liiii-Aicohol C-8; Oimethyl-t-hexanol; UDJied N.Umq Nmnber .... ... ____;___
lsooctanol; lsooctyl alcohOl: 6-Methyl-1-
heptanol; Octanol; iso-Octanot; Oxooctyl
~-' CHRIS Code .... ....... __JQA__
BcNIIna PoiD.t .... ........ --lll'C ____aaF

APIIMI'Uee-Odor-Ciear liquid; mild odor c 'F
Freezana: Pobat ........ ~c ~F
___c ---
Vapor Pre.wre lO'C (61'F) C..ll&) -...aa.._
a....teal F...Uiy-Aicohot Rdd V1p0r ~ (11111).......... ........Q.Q2._
Vapor Pre.ue 46'C (115'F) (IIIia). _1WlL._
PolhatkNI Calqoey-USEPA--- IM().___..c._ Vapor De..lty (Air = 1.0)............. ~
AppHeP1e &.lk Jtea. 46 CFR Sabct.pter ........ ----t2.JL SolaldUI)' Ill Water......... . ......ij.. 1J tt

-G....,....<l
Geaerai-Moderate fire hazard if exposed to heat or flame.
Ft.di PGfJit (" F').. ... 180

~U..Its ... .......... 0.9 to 5.7%
Alltofpltioa T-p. ('F) .. 530
ld:~ Aaeats... Confined area---eo.. dry chemical. Open-foam.
s,ecw Fire Proeedarel .. Use water to cool fire exposed tanks.
HEALTII HAZARD DATA

IINJth Huanl Ratblp Odof' 1'llraltold {Jifm) PEL/I'W A C,.) TLV/TWA~
0, 0,1 Unavailable 50/Skin 50/&ln
GeaeNJ.-Low toxiCity; Irritation of skin and mucous membranes.
Sym,m..-Jrrttates akin and eyes.
St.ort E%,.,....-e Toleruee-UnavaHable
Ex~M*U'e Proeeclars-Vapor-remove victim to fresh air. Skin or eye contact-remove contaminated clothing
.......,_.,..... REACTIVITY DATA
~lltJ-Matert.l: Usual materials of construction are suitable.
Cargo: Group 20 of compatibility Chart. See also Appendix !-Exceptions to the Chart.

Wear 1\tJber gloves, faoe shield, protective clothing. Have aJI..purpose canister mask avaNable. Avoid contact
with liquid. Secure ignition SOUI'C88.
H a .,W ocan, callllle Natlaul . . . . . . c:.tar, 10042t 1102
227
OLEUM
(20 to 66% SO.)
Synonyms- Fuming sulfuric acid; Sulfuric acid, fuming United Nadons Number ...
CHRIS Code ..
Formu11-H.SO,SO,
Bolllng Point .. ... .Qm:CUIKi~S2BJ.. c___.F
Appean.~~ee-Odor-Colorless, oily liquid; sharp, c 'F
penetrating odor Freezin1 Point' ..................... ~4 oo up'C ~F
Speelfte Grarity-1.88 to 1.98 c ___F
Vapor Preuure lG'C (68'FJ (DIIIIH&).. ----l.mL_
Chemical Family-Inorganic acid Reid Vapor Presaure (plla)... ----'-'M..._
Vapor Preuure 46'C (115'F) lll'lal.. __L2L_
Pollution C.te&OQ-USEPA - - - IMO _____Q__ Vapor Demlty (Air = 1.&)... .......... --.U_
Appllc:able Bulk Reg. 46 CFR SubcbapteF. ~ Solubility In Water.. Comp!tta

Grade-Non-flammable. Classified as a corrosive liquid.
Electrical Group-B (based upon possible hydrogen gas (H,) generation should a leak or spill occur)
General-Oleum will not burn. It will react with many metals, givillg off hydrogen gas which is highly flammable.
If hydrogen is trapped in confined spaces it can form an explosive mixture with air. See data sheet for
hydrogen. May cause fire on contact with combustibles.
Flub Poillt tF) .. Non-flammable
F1ammable Limits .. Non-flammable
Autolpition Temp. ("F') .. Non-flammable
EdinpisJiing Agents. Not applicable
Special Fife Procedure~~.. DO NOT USE WATER to put out a fire if the water can get into oleum. If fire
is next to an oleum tank, wear respiratory protection against fumes. Wear full protective clothing.
HEALTH HAZARD DATA

Health Hazard Ratings Odor Threshold (ppm) PEL!TW A (ppm) TLV!TWA (ppm)
4, 4, 3 1 mg/m 1 mg/m 1 mgtm
General-Vapor extremely irritating. Liquid causes severe burns.
Symptoms-Severe respiratory irritation. Skin burns will result from contact with the liquid.
Short Exposure Tolerance-S ppm can be tolerated for 5 minutes without permanent damage. Individual
sensitivity varies from unpleasant to unbearable from 0.2 to 20 ppm.
Exposure Procedures-Vapor-remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or
eye contact-remove contaminated clothing and gently flush affected areas with water for 15 mirn.~tes. Get
REACTIVITY DATA
Stability-Reacts violently with water, producing a great deal of heat
Compatibility-Oleum reacts vigorously with many metals releasing hydrogen. Extremely hazardous in the
presence of many materials. Oleum destroys many plastics and rubbers after brief contact Glass and
Teflon, however, are completely compatible
Clf10: Unassigned in compatability chart. Compatibility assistance available from
G~MTH~t {202~267-1577). See Appendi:w: !-Exceptions to the Chart.

Wear rubb8f gloves, self-contained breathing apparatus, protective clothing. Have body shield available.
Cover contaminated surface and spill with sodium bicarbonate or a soda-ash-slaked lime mixture {5050).
scoop up until neutraltzation is completed. """"'
If a !!Pill oa:un, can the National Response Center, 800-4l4-81102.
Re.arb: The freeztng potnt for 20% SO. IS about 25 F. It nses w1th so, concentration to about 95 Fat
45%, then falls off to about 30"F at 66%.
228
OLIVE OIL
Synonyms- Sweet oil United N1tio1111 Number ...
CHRIS Code ..
Fonauii-Mixture including oleic, palmitic and linoleic

acids BoUiq PoJat.. ....Y.....l::ij'C _ _ F
Apparaaee-<Hor-Pale yellow or greenish-yellow liquid, c 'F
slight characteristic odor. Freezbl& Polat... _____j'C = = F
Speclnc Gn'lty-0.91 to 0.92 c ___.F
VlliKJr Prelllllre lO'C (68'F) (mmfla) .. .....2JI:i.._
Chemical Family-Esters Rehl Vllfllr Preaure (pik)... ____2.1___
Vapor Preaure 46'C (115'11) (ptla)... _QJ,L
Pollution Catepry-USEPA - - - IMO ___c__ V"ffl' Deulty (Air = 1.0)... ..................... ~
AppllCIIble Bulk Rq. 46 CFR Sllbdlapter ....... _.Q__ SelubWty iD Water.. Ntp!!rjtJit

Elec:trical Group-O
Genetal-SIIght fire hazard when exposed to heat or llama.
Flub Point ('F) ..

Ji'lalllm.ble U111IU ..
Autoiplltlon Temp, ('F) ..
"'
Unavailable
650
Extlll~ Aaeats .... Dry chemical, loam or carbon dioxide.
Speclal Fire Procedu~ .. Water may be ineffective on fire. Cool exposed tanks with water.
HEALTH HAZARD DATA

Health Hazard RatiDp Odor 'lbresllold (ppl) PEL/IWA (ppm) TLV/TWA {Hill)
0, 0, 0 Unavailable Not pertinent Not pertinent
Geoerai.-Not harmful
Sympt-None
Sllort Expo11ure Toleranee-NontOxic
Expo~UR Proeedlll"N-Non.toxic. Wash ltloroughly with soap and water.
REACfiVITY DATA
St.bnlty-Stable.
CoJapatlbiUty-M.terial: Usual materials of construction are suitable.
Caratr. Group 34 of compatibility chart.
If a .,W oeam. eaU dte Natloul Rnpoue Center, 800-4l4-180l.

Re.arb: t Unavailable
* Unassigned
229
(NOTE: This CllfVO Is currently not permitted to be shipped In bulk In U.S. waters)
OXYGEN (liquefied)
S,--)'1111- Uquid oxygen; LOX Unlte4 Nadollfl Number .. compressed
refr'lgerated
CHRIS Code ..
BolliDI Point ..
Appearuee-Odor-Light-blue liquid; odorless
Freezine Point ..
Speellle Gn"t"lty-1.14 (at bp)
Vapor PnuiD"e lfi'C (68'Fl (mmHI) ....
Chemkal Family- ReHI Vapot Preaure (paia)...
Vapor Preaure 46'C (115'Fl (paia) ..
Polllltlon Cateaory-USEPA - - - IMO __go__ Vapor DeaJty (Air = 1.0) .....
A.,Ucahle Balk Reg. 46 CFR Subcbapter ...... - - - Solubility In Water ...

Grade-Liquefied Compressed Gas (LCG). Classified as nonflammable.
Eleetrieal Group-Not applicable
General-Oxygen does not bum but supports combustion vigorously. A combustible material onto which LOX
has spilled will burst into flame or eKptode If exposed to a spark source.
Flub PoUlt ('Fl .. Non-flammable, but supports combustion.

Flammallle Limits .. Non-flammable
Autoiplt&on Temp, ("Fl .. Non-flammable
ExUapilhlae Agent& .. Use media suitable lor substance which is burning.
Spedal F1Te Proeedura .. If the insulation fails on a LOX tank eKposed to fire, the tank will explode.
Evacute firefighters to a sale distance and have them take cover.
HEALTH HAZARD DATA

Healtb Hazanl Ratinp Odor Tbrabold (ppm) PEL;TWA (ppm) nvnwA <ppmJ
Unavailable None Unavailable Unavailable
Geneni-No hazard IOf gas. Liquid can cause severe "bums" and tissue damage on contact with skin.
Syptoma-Skin contact with liquid willlreeze tissue.
Sbort EJ:posure Tolenmce-Unavailable
EJ:ponre Procedul"ft-lf the r1quid has spilled onto the skin, points of contact may be frostbitten; handle gently
and ptotect from mechanical damage. DO NOT RUB. Get medical attention without dalay. AVOID SPAAKS
AND OPEN FLAME.
REACTIVITY DATA
StabiUty-LOX will flash into vapor at temperatures above -tBO'F. If unconfined. the vapor will occupy about
860 times the volume of the liquid. If confined, a sudden and large pressure increase will result.
Compatibility-Material: LOX causes all combiJS!ible materials to burn vigOfously. A spark is not always needed
to ignite such a mhcture.
Car110: Unassigned in compatability chart.

Secure ignition SOUf"CSS, rope off the spill area and call the lire department. Oxygen will quickly boil off.
Extreme precaution against sparks must be ob88f'Yed before re-entering the spill area because, unless the spill
is in tile open with a good breeze blowiog, the area will be oKY99n-rich for a long time.
H .,W occtll'l, eal1 tbe Ntlonal Reapo~~~e Cl!llter, 800 41:4 8802.
Remarb: Not lOwed to be stllpped In butk.
230
PARAFFIN WAX
Synony-- Hard wax; Paraffin; Paraffin scale; United Natklm Number ...
Petroleum wax
CHRIS Code ..
Formula-High weight hydrocarbons (for

example: C,.~d Bolling Point.. ----=..aiQ'C ............:::F
Appearaace.Qdor-White to yellow translucent c 'F
practically odorless, solid Freuln1 Point.. 42-SO'C t0A-14P'F
Sp.x:llk: Gn.,lty-0.80 to 0.88
___ c ___.,
Vapor Preaure lO'C (68'F') (mmHR) .. ...Y.....LmL
Chemk:al. Family-Saturated hydrocarbon Rdd Vapor Prtaare ((IIlii)... ...Y.....I.a
Vapor Pnullre 46'C (115'FJ (pebi)..... ...Y.....LmL
PoDtlon C.tqory-USEPA - - - IMO __lll_ Vapor Dm.lty (Alr = 1.0).. ____Jjf_
Applluble B11lk Rea. 46 CFR Subcbapler .. . ... ----'L_ Solubility Ia Water.. Negl!gjblt

Grade-E: Combustible
Electrical GI'Gup-D
General-Slight fire hazard if subjected to heat or flame.
380 to 465
,.__bie Umits ..
Flub Point t'FJ.
Unavailable
Autolpldoa r-p. t'Fl .. 473 ~
Ex~A.,ms .. Coofined area-CO,, dry chemical pen area-foam, water spray.

Special Flre Proeedure11 . Water or foam may cause frothing.
HEALTH HAZARD DATA

Health Haurd Ratlnp Odor Tlaretbold ,,.., PEL/IWA (ppm) nv!TWA (ppm!
Unavailable Unavailable 2 mglm' as a fume 2 mg/m 1 as a fume
Generai.-Non-tolCic, but possibility of thermal bums from hot liquid.
S)'IIIIJI:omt-NontOlCiC
SboJ1 EJ:PQAre To&enu.te-Non-toxic
EJ:poa~re ProeedUJ"S-Uquid on skin---~move W8l( and contaminated clothing and cool affected areas with
water. Liquid in eye-flood eyes gently with clean sea or fresh water. Continue washing for at least 15
minutes. Get medical attention.
REACI1VITY DATA
StallllJty-Stable.
eo.,.tfblllty-Miterlal: Usual materials of construction are suitable.
Clrao: Group 31 of compatibHity chart.

Avoid contact with hot liquid. Wear goggles or face shield, protaciiYe clothing for hot liquid. Clean or scrape
up into containers.
H 1 1p'H OCCID'It eaU tiM Nltloul. .....,_ Cuter, IIJ0...4l4 8102.
Relllllb: Normally transported at elevated temperatures. See 46 CFR 36-Eievated Temperature cargoes.
+Unassigned
231
PARALDEHYDE
SyooayiiQ- p-Acetaldehyde; Paracetaldehyde; Vatted NltiORI N11111bel' ...
2,4,6-Trimethyl-1 ,3,5-trioxane: 1,3,5-Trioxane,
2,4,6-trimethyl-
CHRIS Code ..
Ap~Odor-Colortess liquid; aromatic odor

Bolllna PoiDt ..
Freezlna PoiDt .
__l2l!'C
c --=
'F
____ta'C ----'fi'F
Speetnc Gra'flty-0.994 ___ c _ _ _ 'F
Vapor PreAIU'e lO'C (68'F) tmmH&) .. ____1.__
lllemk:al Family-Aldehydes Reid V.,or Prelhre ep.ia) ... ____1.__
Polluti011 C.tqory-USEPA __Q__ IMO __Q__

v_,....Preaure 46'C (115'F) (ptia) ... __u_
VIJIO' Dellllty (Air = 1.0) .. ~
Applicable Bulk Reg, .S CFR S11bdlapter ....... _..o__ SolubWty Ia W1ter .. Slight

Eleetrka! GriMip-C
Genend-Toxic fumes 8fe given off when heated. Oangetous when exposed to heat, flame, or oxidizers.

Flammable Umit. .. LEL= 1.3% UEL-uoavailable
Autoiplti011 Temp, ('F) .. 460
ExtinpiHin& A&eJ~ta ... Alcohol foam, ~ or dry chemical
Special FIR Procedures . Water may be ineffective on fire. Wear full protective clothing and respiratory
protect'1on.
HEALTH HAZARD DATA

Healtb Huard Ratlnp Odor nTelltoJd (ppm) PEL/IWA (ppm) lLV!I'WA (,_)
1, 1, 2 Unavailable Unavailable Unava~able
Generai-Vaptt harmful if inhaled.
Symptoms-lmtation, headache, bronchitis, incoordination, drowsiness, digestive disturbance. Can cause serious
eye !njury
Sltort E,.;posure Tolei1Uice-4000 ppm fatal to 3 ol 6 rats in hours. The lowest toxic dose for humans is 14
mg/kg.
Exposure Procedures-Remove from exposure: give artificial respiration or oxygen II needed. Flush eyes with
water for 15 minutes, wash skin with soap and water. Remove contaminated clothing and shoes.
REACTIVITY DATA
Stllbillty-Dangerous when exposed to heat or flame. can react vigorously with oxidizing materials.
Compatlblllty-Mterial: Usual materials of construction are suitable.

Wear protective clothing, goggles and self-contained breathing apparatus. Avoid contact with "QUid. Seoue
ignition sources.
If I lpW oenrs, ea1J tile Nlltlou.l Relpoae Centa', 800-424 1182.
232
PEANUT OIL
Syno~ Arachis oil; Earthnut oil: Groundnut oil; Vatted Nltlo... NP~ber ...
Katchung oil
CHRIS Code .
Formu.la-Mixture
BcHIIDa; Polnt ... ....Y.....tilgb'C _ _ 'F
A.ppeanmce-Odor-Yellow to greenish-yellOw liquid with c 'F
a peanut-like odor Freeziq PcHat... ______J'C ---vF
Spedfk: Gravtly-0.92
___ c ___'F
Vapor~ :ZO'C (61'Fl <-H&).. .....lJlL..
C'llem6cal Fudly-Ester Reid Vapor Prf:IIIO't (peia)... ___QJ_
Vapor Prf:lllll't 46'C (115'F) (pda)... ......QJ.i._
PolluUon CateawJ-USEPA - - - IMO ___j)_ Vapor De.-ty Wr "" 1.0) .......................... __liE._
A.ppHcUae Bulk Rq. 46 CFR S11bclaapter ....... _c.._ Solltillty Ia Water.... Ntg!lp!bla

Eledrlcal Group-O
Ge..eral-SHght fire hazard if exposed to heal and flame.
Flah Poiat ('F) .. 540

Fllmuaable Undb .. Unavailable
Aalolpido. Telll)l. ('FJ .. 833
Eitlquilb.illl Aa-u ... Dry chemical, loam, or carbon dioxide
Spedal Fire Proeedvel .. Water may be ineffective on fire. Cool eJCpOSed containers with water.
HEALTH HAZARD DATA

Healtll 11-.1 Ratlnp Odor 'I'IaretboW <pp.) PEL/TWA(,_) nvITW A (pta)
"""'"'labia
General-Not harmful
Unavailable Not pertinent Not-
s,...,...__None
Sbort Eipotllft Toleruee-Not harmful
Elr..-ure Proeedua-Non-toxic. Wash thoroughly with soap and water.
REACfiVITY DATA
StabWty-Stable.
Com.)llltiiiWty-Material: Usual materials of construction are suitable.
Carao; Group 34 of compatibility chart.

Wear rubber gloves, face shield and protective clothing. Avoid contact with hot liquid.
If a tp111 oa:vn, ealllbe N.UO.W a.,._ Ce:a.ter, ~
233
PENTACHLOROETHANE
S)>HaYJQ- Ethane, pentachloride; Ethane,
pentachloro-; Pentalin
CHRIS Code ..
Fonaula-CHChCCb
BoJII.na; Polllt .. --.12"C ~F
Appeanuaee-Odor-Liquid with sweetish chloroform-like ___ c ---
odO< Flwzin& PoiDI .. -.=nc ---=.2!:!"F
Spedflc Q-a,lty-1.67 ___ c ---
Vlpol' Pre.are lO"C (61'Fl (DIIIIHI) ..
Chemical FU~Uy-Halogenated hydrocarbon Reid Vapor ~re (peW ...
Vapor ~ t6"C (115"F) (pita) ..
:::::c
__i_
Poll11tl011 Cateaory-USEPA ---A.._ IMO ___a___ Vapor Deaslty (Air = 1,0) ... __LQ_
Applleable BuJk Rea. 46 CFR Subdlapter ........ ____Q_ SolbUity ln W.ter .... !n!!Qiublt

Grade-Non-flammable
EJKtrical Group-NA
General-Dangerous when heated to decomposition; dehaloganation will prOduce spontaneously explosive

chloroacety1enes.
FJqb Point r FL. Non-flammable

Flammable UmiU .. Non-flammable
AutoJpltl011 Temp, ('FJ .. Non-flammable
Ed.inpilhilll Apnb .. Non-flammable
Special Fire Procedura . Non-flammable
HEALTH HAZARD DATA

Healtb Huard lbtings Odor 1bftlllold (,..) PEL/IWA {pp~) nvnwA {pfm:)
General-Highly narcotic. Eye and upper respiratory tract irritant.
Symptoms-Has been indicated as being more narcotic than chloroform. Exposure to this material may cause
intury to liver, lungs and kidneys. Has alcohol irritaf1ng affect on eyes and upper respiratory tract.
Short Exposure Tolenuace--Lethal oral dose of 1.75 g/kg of body weight in dogs.
Expo~~ure Proeedu~Vapor-remove vicflm to fresh air and administer artificial respiration If necessary.
Skin-flush affected areas with water. Eyes-flush with water for 15 minutes. In all cases call a doctor.
REACilVITY DATA
St.hlllty-Stable.
Comp~~tlbUity-M.terlal: Usual materials of construction are satisfactory.
Carao: GrOup 36 of compatibility chart.

Wear rubber gloves, self-contained breathing apparatus and protective clothing. Secure all Ignition sources.
If a Ifill ocet1n, eall the NatioDal Rea,oa. Cater, 1100-4:14 IIOl,

Remark.l: Vapor Pressure. 3.4 mmHg at25 C.
t Unavailable
234
1 3-PENTADIENE
s,-,.__ alpha-Methylblvlnyl; cia-Pantadlene-1,3; United Nadal N11111ber ....
trans-Pentadiene-1,3; 1-Methylbutadlene; Plperylene
CHRIS Code ..
Fon~ula~=CHCH=CHCHt
BoH'-1 Point.. ~c --.l.Q'F
A~lor1ess liquid; faint odor. c 'F
Freea111 PfNat... -88'C -l?S'F
Spedfk Gra\'fty-0.88 ___ c ---
Vapor Preaare lO'C (68'F) (llun}ll) ___a_
ReW Vapor Pre.1are (pl1a) ....J2.L_
VllfOJ' PnMwe .uc msF> (plla) -.ll.QL_
Pollutioll Cdeaorf-USEPA ___a____ IMO .......k....... V1p0r Dentlty (Air = 1.0) .......................... ......i.m.....
Appllealde Btdk R... 46 CPR S.bdlaptw ....... _.Q_ Solabllity Ia Water 1!ll!?!yb!t

Gr.de-8: Flammable liquid
-G.oop-0
GeDenll-Highly flammable, dangerous fire risk .
..... Poblt ('F)., ~20

n.-.we UmUa ... 1.5 to 8.0%
Aalolpltioa TeBlp. ('F) .. Unavailable
EI~Apaa ... Foam, dry Chemical, CO.
SpecW Fire Proc:edars .. .. Water may be ineffective on fire but may be used to cool tanl<s. Vapor may
accumulate In an aoclosed area presenting an explosion hazard. Wear self-contained breathing apparatus.
HEALTH HAZARD DATA

HIIIII.Oi 11u:1n1 lbtiql Odor nrew.Icl (ppiO) PELI'IWA epp.) n.vrrwA <,..J
2, 1, 3 UnavaHable Unavailable UnavaMable
GeDend-Modarate hazard for vapors, slight fOf liquid contact, and acute for ingestion.
S)'lllptolu-Dizzlness, headache. Irritates ayes, nose and upper respiratory passages.
Sbort EI~~Q~Ve Tolenmcre-Unavailable
Exponre Proeedara-Aemove victim to fresh air. Give artificial respiration or oxygen as necessary. Eyes--flush
with water for at least 15 minutes. Remove contaminated clothing Immediately.
REACfiVITY DATA
SbblllltJ-Polymerization may occur. Must contain Inhibitor. Reacts wHh oxidizers viOlently.
.........
eo.,.tlbilltr-Materlal: Dissolves rubber and paint Stainless steel, aluminum, lined steel and carbon steel are
Carao: Group 30 of compatibility che.rt.

Stop dlacharge It pouible. Evacuate areL Secure Ignition 8001'088. Stay upwind and use water spray to knock
down vapors. Wur self-contained breathing apparatus, rubber gloves and shOes. Do not flush spill Into confined
spaces where flammable vapors can accumulate.
H .,m ocean, call lhe Natloul ...,.,_ Cater II00-4J4..1102.

I
235
lao-PENTANE
S)'DH)'lnl- Ethyl dimethylmethalle; Isoamyl hydride; United Nations Number ...
lsopentane; 2-Methylbutane
CHRIS Code ..
-
Formllla-(CH,}2CHCH.CH,
Boiling Point ..
___.,
__JJtF
Appearaee-Odof-Color1ess, motif, liquid; pleasant
Speclth: Grarlty-0.62
free:dna Point.. ___.,
~F
Va)IOI" Pressure 20'C (68'F) (mmH&) .. _MQ_

ct.e.lcal F11111lly-Saturated hydrocarbons Reid Vapor Pressure (p&la)... ___zt_
Vapor Pressure 46'C (liS'FJ (psia) ... ___21_
Pollution Catetory-USEPA - - - IMO _Q:_ Vapor Denalty (Air = 1.0).. ____2AL
Applbble Blllk Res, 46 CFR Subchapter . . --'2.....Q_ SolubUity In Water .. tnsotybte

Etec:trieaJ Group-O
General-Severe explosion hazard in enclosed space in presence of a source of ignition. Electrostatic

generation likely. Flashback along vapor trail may occur. Vapor may explode if ignited in an enclosed area.
Flqb Point ('F) .. -70

Flammable Umibl .. 1.410 7.6%
Autolpitfon Temp, ("FJ 788
Extlaplsblnl AKenls Foam, CD:,, dry chemical
Special Fire Procedura .. Water may be ineffective on fire. Cool exposed tanks with water. Use water
spray to "'knock down" vapots.
HEALTH HAZARD DATA

Health Hau.rd Ratinp Odor ThruboJd (ppm) PEL/TWA (ppm) TLV!TWA (ppm)
General-Liquid 1rrrtatmg to skin and eyes. Inhalation causes slight local irritation. An asphyxiant, also a narcotic
in high concentrations resulting in diZziness and drowsiness.
Symptoms--Breathing h1gh concentrations of vapor for some time may cause dizziness, drowsiness.
Short Ell"posure Tolerance-Unavailable
Procedures-Remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or eye
Ellpo~~ure
contact-remove contaminated clothing and g8lltly flush affected areas with water for 15 minutes. Got
REACTIVITY DATA
Stability-Stable. DangefOOS reaction possible with oxidizing agents.
Compatibility-Material: Certain plastics are unsuitable.

Wear polyethylene gloves, face shield, protective clothing. Have all-purpose canister mask available. Avoid
contact with liquid Secure ignition soorces. Do not flush spill into confined spaces where flammable vapors can
accumulate
If a apill occurs, call tbe NatiODII Re.poase Center, 800-424-8802,
Remarb: Pollution Category COil-like, 33 CFA 151.49.
236
PENTANE
Syaooy- Amyl hydride; Normal pentane; n-Pentane Ullited Nlltlomi N11111t.er ...
OIRIS Code ..
Fo...la-CH~(Ctit)tCHa
-
BoUiq; Poiat.. ~c ____iZ"F
A.ppMrUce-Odor-Colorless liquid with gasoline-like ___ c ---
Freezlna: Pobll... --=.!JQ"C ~F
Speeitk Grarity-0.63 c ---
Vpor ~ 20"C (68"F) (.aiJqlfl) .. ___jll_
~ Faally-Saturaled hydrocarbon Reid Vapor Pr-.n (!llil)..... . ~
Vapor Pr-.re 46"C (115"F) (pda) ............ --2lJL
PeUutloa c.tqory-USEPA--- JM().__ V1p0r DeJ111tJ (Air = 1.0). ................. ~
Appllable Bulk Rq. .t6 CFR Subdlllpter ........ ----'2..JL. Solubility t. Wider.. Slightly ag!ybtt
FIRE lc EXPWSION HAZARD DATA

Grade-A: Aammable liqUid
Eledrleal Grou,-D
Ge.end-Highly dangeroUs when exposed to heat or flame. Flaehback along vapor trail may occur. Vapor may
F1uh Pohll ("F) .. -56

JllaaltaaWe UmJbl .. 1.4 to 8.5%
A11tcNp.ltiH Temp, ("F') .... 544
E~Apatl ....... Foam, dry chemical, carbon diOxide
Spedal Fire Proeedlll'el .... Water may be lneffacttve on flre. Cool exposed tanks with water. Use water
spray to "knock down" vapot'S.
Hal.tla Huanl Ratblp .,..............,_

HEALTH HAZARD DATA
PEL/TWA (ppal) TI.VITWA Cpp.l
0, 0, 1 10 600 600
Geaeni-Vapors may cause dizziness or difflcolt breathing. Liquid iS harmful If swallowed.
Sy.nptOIDI-Low toxicity. Very high concentration of vapors may cause narcosis.
Sllort EipotiU"e Tolenmee-Unavailable
Ezpotlll'e Proc:edUJW-Vapor Inhalation-move victim to fresh air. if breathing stops, adminiSter artificial
respiration. liquid-have victim drink plenty of water or milk. DO NOT INDUCE VOMITING. Call a doctor.
REACTIVITY DATA
StsiHUty-Stable. Dangerous reaction possible with oxidizing agents. Keep away from heat, sparks, or open
flame.
eom,.ublllty-Material: Mild steel and stainless steel are suitable. Natural rubber will solteo and deteriorate
rapidly.
Carp: Group 31 of compatibility chart

Wear polyethylene gloves, face shield, protective dothlng. Have all purpose canister mask available. For gas
leaks keep vapor concentration below explOSive mixture range. Secure Ignition sources. Do not flush spill into
conftned spaces where flammable vapors can accumulate.
U a tpiJl ocan, call tile NMioMJ. a.,_ C.., IJ00..4lt-110l.

ae..rkc Ponution Category Coil-like, 33 CFR 151.49.
237
PERCHLOROETHYLENE
Synony-- Ethane, tetrachloro-; Ethylene tetrachloride;
Perchlorethylene: Tetrachlorethane;
Tetrachlorethylene; Tetrachloroethylene
CHRIS Code.
Formula-Ci,C = CC!1, or C.CI,

Bollin& Point .. ____ruc ~F
Appearana:..Qdor-Color1ess liquid; chiOfOiorm-like odor ___ c ___ 'F

Freezing Point .. __:::.22'C ----=..'F
Spec:ifle Gn~rity-1.62
___ c ___ 'F
Vapor PreAun lG'C (68'FJ (mmHaJ ..
Olemkal Family-Unsaturated halogenated Reid Vapor ~re ((11{.1) .. ~
hydrocarbon Vapor Pre.Are 46'C (ll!I'F) (pelaJ .. --.L.2L
PGIIution C.teaorf-USEPA _____a__ IMO ____a__ Vapot" De-.ity (Air = 1,0) .. ---UL
Applkable S.lk Reg. 46 CFR Subchapter ........ ____Q__ Solubility In Water ... NAQijglble

Grade-Non-flammable
Electrleal Group-NA
General-Does not burn. The liquid or vapor in contact with a hot surface or a flame can decompose to form
phosgene, which is highly toxic
Fla&b Point ("F) .. None

F'lulmable Umits . None
Autolpitlon Temp. ('FJ .... None
Extinguishing Aaentli .. None
Special Fi~ Procedures .. In case of fire near a perchloroethylene tank, cool the tank with water. Wear
sell-contained breathing apparatus.
HEALTH HAZARD DATA

Healtb Hazard Ratinp Odor Tbretltold (PPJD) PEL/I'W A (ppm) TLV/IWA (PPJII)
1, 1, 2 20 to 40 25 50
General-Suspected carcinogen. Prolonged, excessive, or repeated exposures to the product in any form are
hazardous. Can defat the skin and may produce dermatitis from frequent daily contact.
Symptoms-Headache. dizziness, blurred vision, tears, burning of the eyes, irritation of nose and throat.
Sbort EJ~posure Tolerance-200 ppm
Exposure Procedures-Vapor-remove victim to fresh air; ,f breathing stops, apply artificial respiration. Skin or
medical advice or atlention
REACTIVITY DATA
StabiUty-Stable up to 258"F; at this temperature the product decomposes and gives off poisonous fumes.
Compatibility-Material: Compatible with galvanized iron, black iron or steel
Car(lo: Group 36 of compatibility chart

Wear rubber gloves, protective clothing. Avoid contact with liquid.
If a 'frill OCCIU"8, call tbe National Re1p0111e Ceuter, 81J0.-..tl4 880l.

Remark&: Vapor Pressure. 15.8 mmHg at 22"C.
238
PETROLATUM
Syn011ym- Paraffin jelly; Petrolatum jelly; Petroleum United Nations Nuber ...
}ally; Vaseline; Yellow petrolatum
CHRIS Code ..
Formula-Mixture of liquid or semiliquid aliphatic

hydrocarbons BoU11111 Point .. ~F
Appearanee-Odor-Colorless to amber, oily translucent; _ _ _ 'F
ooodo< ~'F
Spedflr Gravity-0.82 to 0.85 _ _ _ 'F
Vapor Pressure :ZO'C (68'F) <mmHI) .. L.Limc
CltemlcaJ Family-Saturated hydrocarbons Reid Vapor Pre..ure ((Ilia)... L.Limc
Vapor PreMure 46'C (115'F) 111'111) .. L.Limc
PolluUoa C.tqory-USEPA _ _ _ IMO ___llL_ VqKJr Dentfty (Air = 1.0) ... ___tif_
Appllcroble BuJk Rea. 46 CFR Subchapter ........ ~ Soluhlllty ln Water .. Negljqjble

Grade-D: Combustible
Eleetrical Group-NA
Geaerai-Moderate fire hazard when exposed to heat or flame.
~ Polat I'Fl .. 136

Flammallle LlmJtl ... Unavailable
Autoipldoa Temp, ('F) .. Unavailable
Extilllllitltln& AIJl!llb .. Confined area-CO., dry chemical. Open area-water spray, foam.
Spedlll F:lre Procedu~ .. Water or foam may cause frothing.
HEALTH HAZARD DATA

Healtb Hazanl Ratlnp Odor Tlrahold (ppm) PEL/IWA((IIMII) TI.VIIWA (ppm)
Unavailable None Unavailable Unavailable
Gemeral-Non-toxic, but possibility of thermal burns from hot liquid.
Sympt_,_Nox-toxic
Sllort Expollll'e Toleranee-Noo-toxic
Eli:poiJIIre Pnlc:edura-Liquid on skin-remove contaminated clothing and cool affected areas with cold water.
Uquid in eye-flood eyes gently with clean sea or fresh water. Continua washing for at least 15 minutes.
REACI'IVITY DATA
Sbbillty-Stable.
CompadbUity-M..terlal: Usual materials of construction are suitable.

Avoid contact with hot liquid. Wear goggles or face shield, protective clothing for hot liquids. Wash away with
water. Secure ignition sources.
If a Ifill fiCC1ln, call tlte National ~ Center, 100-424-IIOl,
Remarks: Normally transported at elevated temperatures. See 46 CFR 36-Eievated Temperature cargoes.
+
Unassigned
239
PHENOL
SynonyiiQI- Benzene, hydroxy-; Carbolic acid; United Nation Number .. molten
Hydroxybenzene; Monohydroxybenzene; solid
0)(}'benzene; Phenic acid; Phenyl hydroxide;
Phenylic acid
CHRIS Code ..
Fo.-mula-C.HoOH
Bollln1 Point . ____uzc ~F
Appearance-04m-Colorless-to-pink solid Of thick liquid: c F
sweet, disinfectant-like odor (like Lysol) Freezinl Point.... =:=iic
c ==::iQF
___.,
Specific Graity-1.07
Vapor Pralure 20'C (68'F') CmmH&) ..
Chemical Family-Phenol Reid Vapor Preuure {paia)... .......2.L
Vapor Preaure oH'C CIIS'F> (]*Ia).. _.2&_
Pollutlot1 Category-USEPA __Q__ IMO ____fL_ Vapor DeuUy (Air = 1.0).. ................... _j.2i.._
Applicable Bulk Rea. 46 CFR SubcUpter ...... _____Q_ Solubility In Water.. at 16'C 6 7%
at 66'C complete

Gnule-E: Combustible
ElectrlcaJ Group-O
General-When heated, it emits toxic and irritating fumes. Moderate tire hazard when exposed to heat Of !lame.
F1uJa Point ("F) 185

Flammable Limitli .. 1.710 8.6%
Autoipition Temp, ("F) . 1319
Extlnguiallina A1ents .. CO., dry chemical, alcohol foam, water fog
Special Ftre Procedures . Where there is danger of skin contact, provide full body protection. Full
resprratory protectron should be wom by fire parties at all times.
HEALTH HAZARD DATA

Health HII.ZIIrd Ratings Odor Thrallold (ppm) PEL/TWA (ppm) TLV!TWA (ppm)
2. 3, 3 0.047 5/Skin 5/Skin
General-Causes severe bums. Poisonous by skin absorption. Class B poison.
Symptoms-Headache, weakness, ringing of the ears, and irregular breathing. Skin contact will cause white,
wrrnkled. soft sk1n at site of contact. Absorption through skin is rapid and can cause death within 30
minutes alter exposure
Short f:xprniure Tolerance-Unavatlable
Exposur~ Procedures-Vapor-remove victim to fresh air: if breathing stops, apply artificial respiration. Skin or
eye contact-remove contaminated clothing and gently flush affected areas with water for 15 minutes. Ge1
v1ct1m to a hospital or treatment center as soon as possible. All exposure victims should get medical
a"ent1on
REACI'IVITY DATA
Stability-Stable.
Compatibility-Material: Rubber, aluminum and its alloys, zinc and lead are allacked by phenol.

Wear rubber gloves, face shield, protective clothing. Have all-purpose canister mask available. Do not permit
anyone near spill unless suitably protected.
If a spill oc:cun, caU the National RetpOn.e Ceater, 1100-4l4-810l.
Remarks: Normally transported at elevated temperatures. See 46 CFR 36-Eievated Temperature Cargoes.
Vapor Pressure: 30.6 mmHg at 25"C.
240
PHOSPHORIC ACID
SyDOayms- Metaphosphoric acid; Orthophosphoric United Natlont Nu111ber ...
acid; meta-Phosphoric acid; ortho-Phosphoric acid;
White phosphoric acid
CHRIS Code ...
Fonnula-H,PO,
Appeanmee-Odor-Ciear. syrupy liquid; practically

Boillq Point..
___.,
~F
odorless
Specific Gravity-1.83
Free:dlla PoiDt ..
___.,
____j_Qj!F
Vapor Pretllllf'e :zoc (68'F> (mmlfa) .. ___LQlL_

Chemical FIUilily-lnorganic acid Reid Vapor Prelsure (Pilla) ... ___LQlL_
Vapor f're.lli'C! 46'C (115'F) (peUI) .. ___LQlL_
Pollution Category-USEPA ____Q__ IMO ____Q__ Vapor Density (Air = t,O) .. __ilL
Applicable Bulk Reg. 46 CFR Subehapter ...... ____Q__ Solubility iD Water .. Complete

Grade-Non-flammable. Classified as corrosive liquid.
Electrlclll. Group-S (based upon possible hydrogen gas (H$) generation shoold a leak or spill occur)
Gellera1-Phosphoric acid will not bum. tt will react with many metals, giving off hydrogen gas which is highly
flammable. If hydrogen is trapped in a confined space, it can form an explosive mixture with air. See data
sheet for hydrogen.
Flub PoJnt ('F) .. Non-flammable
Flammable Undts .. Non-flammable
Autoignition Temp, ("F) ... Non-flammable
Elr:tlnplsbing Agents .. Non-flammable
Special Fire Proeediii1!S ... Keep tank cool with water spray. Since toxic fumes of oxides of phosphorous
are evolved when phosphoric acid is heated to decomposition, fire fighters should be provided with
self-contained breathillQ apparatus.
HEALTH HAZARD DATA

Healtll Hazard Ratlnp Odor 1'1u-e.bold {ppm) PEL/TWA (ppm) nvnwA CPfllll)
0, 3, 1 Nooo 1 mg/m" 1 mg/m 3
General-Causes burns.
Symptoms-Irritation of skin in contact with liquid; burnillQ of eyes.
Short Expoaure Tolerance-Unavailable
Expo~~w-e
Proc:edures-Skin contact-remove contaminated clothillQ and flush affected areas gently with large
amounts of water. Eye contact-immediately flush eyes gently with water; continue to flush for 15 minutes.
REACTIVITY DATA
Stability-Stable over a wide temperature range
Compatibility-Material: V9f'/ corrosive to ordinary ferrous metals and alloys particularly at temperatures above
160"F.

Wear rubber gloves, protective clothing. Have body shield available. Avoid contact with liquid. Secure ignition
sources. Flush spills with large amounts of water or, if possible, COV9f contaminated surface and spill with
sodium bicarbonate, or a soda ash-slaked lime mixture (5Q-50). Mix and add water, If necessary to form a slurry.
Scoop up slurry. Wash site with soda ash solution.
In the neat of a IQjOl" spiU. eall the Nau-t Rnpo~~M Center, 800-4l4-810l.
Remarks: The information provided is for 100% phosphoric acid.
241
PHOSPHORUS (White)
5)'11011flll8- White phosphorus: WP; Yellow phosphorus United Natlo... Number ...
CHRIS Code ...
_,
Appearllllce-Odor-Waxy, pale-yellow solid; garlic-like
BoU1a1 PoUlt...
Freezil Pofat..
--..2Zi'C ~'F
c 'F
____M'C ___.lll'F
___c ___.F
Specific Gra'fity-1.82
Vapor ~re :zoc (68'F> (DunH&).. ~
Reid V~~p~~r Preuun (pN.).... ~
Vapor ~re 46'C (115'F) (pala).. ~
Pollutfoa Catei}Ory-USEPA ____x__ IMO ----A_ Vapor Denalty (Air = 1.0).. ........................ ~
AppJh:able Bulk Res;. 46 CFR Subcbpter ..... __Q__ SolubUity In Water.. Nag!jglblo

Grade-Pyrophoric solid
EJeetrical Group--NA
Generai-Pyrophoric-ignites spontaneously when exposed to air and burns vigorously. When shipped In bulk,
air is kept away by a water blanket. Burning releases dense irritating fumes; intense white smoke Is fonned.
F1uh Point ('F') .. Ignites spontaneously in air

Flammable Limits Ignites spontaneously in air
Autoignition Temp. ('F) .. 86
E:ottingui!hing Agenb .. EXCLUDE AIR: use water spray, sand, or earth
Special Fire Procedures. Use suitable respiratory protection. DO NOT use high-pressure water stream.
as it may spread molten phosphorus over a wider area. Do not use carbon dioxide e)(tingulaher. Try to
smother ,n lne with sand. Wear full protective clothing.
HEALTH HAZARD DATA

Health Hazard R1tings Odor Tbrabold (pplll) PEL/IWA (ppm) nvnwA <ppml
NA. 4, 4 Unavailable 0.1 mgtm 0.1 mgtm
General-Causes severe burns. Vapor inhalation is very dangerous. can be absorbed through the skin.
Sympto~M-Weakness and unusual sensitivity of eyes to light. Vapor of burning phosphorus is irritating to nose,
throat and lungs. Sktn contact causes burns and ulcers.
Short E~~:posure Tolerance-Unavailable
Expo$Ure Procedures-Skin contact-immediately plunge infected area into water or get victim under a
flood-type shower and deluge contacted parts. Large amounts of copper sulfate solution (10-15%) should
be applted. Continue this for 3 minutes and then try to wash away the phosphorus particles. Contact a
doctor.
REACTIVITY DATA
Stalhility-Phosphorus must be shipped covered wtth water, because on exposure to air it ignites
spontaneously. Reacts vigorously with oxidizing agents Incompatible with dry air.
Compatibllity-Miterial:
Cargo: Unassigned in compattbility chart For compatibility assistance, call

G~MTH~1 (202~267~1577).

Wear rubber gloves, protective clothing, large face shield. Avoid contact with the spilled material. Cover with
wet sand. Spray with water to keep sand wet Scoop into buckets or barrel of water. After standing overnight,
recover and repackage. Secure ignition sources.
If II spill OCellrt, all the N11ti01111l RelpOUC Ce11ter, 100-41:4 1101:.
Remarka:
242
PHTHALIC ANHYDRIDE
s,._,__ 1 ,2-BenzenedlcarboKYtic acid anhydride;
1,3-0ioxophalan; 1 ,3-laobenzofuandione; PAN:
Phthalandione; Phthalic acid anhydride
CHRIS Code ..
Bollilla POU.t.. ~c ~F
~r-Whlte or colorless crystals with a c 'F
mild odor Freedq Point... ~"C
___ c =:2iF
___F
Spedftc Grutty-1.53
VllpOI' PreRure lO'C (68'F) (mmll&).. . ____l,gL_
a-ucaJ FunDy-Acid anhydride Rdd Vapor Pr-.re (pall!)... ~
V1por ~ 46'C (115'F) (peia)..... ____I.D_
PoUudoll Calepry-USEPA __.l;L_ IMO ~ Vapor Delllity (Air = 1,0)... . .......... ~
Appllalble Bulk Rea. 46 CFR Subeha,ter ....... __Q__ SolbWty Ia w.w.. .. Slight

Grade-E: Combustible
ElodriaoiGroap-D
General-Mohen phthalic anhydride will bum if ignited and its vapor may form an explOSive mixture with air.
FlMII Poo.t ('F) .. 304

n....we Umils .. 1.7 to 10.4%
Alltoipltloa T-p. ('F) .. 1083
Es.~Apa.ts ... Water fOg, CO:=. dry chemical
Spedal Fire ProeePrel .. Water stream may causa frothing. Steam is an effective extinguishing agent
for fighting mohen phthalic anhydride fires in tanks.
HEALTH HAZARD DATA

Heald! Huanl Ratillp ~ nresllold {pfm) PEL/TWA (pplll) TLV;TWA (ppm)
2, 3. 1 UnavaHable 1 1
Geaerai-Locallrrltant to body tissues, especially moist skin. Vapor irritating to skin, eyes, nose, throat and
upper respiratory tracl Molten material causes severe bums.
S)'11111t01111-Cng, sneezing, burning sensatiOns in nose and throat, increased mucous secretion: on contact,
phthalic anhydride is very irritating to wet skin.
Short E:i:polllnl Toleruc:e--25 mgtm in air produced some signs of mucous membrane initation with 30 mgtm
causing definite eye initatlon.
E:r;pmare Procedllra-Vapor-remove victim to fresh air: spraying or gargling with watef will help relieve nasal
or throat Irritations: if respiratory distress or violent coughing occurs, administration of oxygen is helpful; call
a physician immediately. Skin contact-ash affected area thoroughly with soap and water; remove
contaminated clothing and launder ba1ore reuse. Eye contact-flush eyes thoroughly with water and Irrigate
for 15 minutes or more. Cell a physician.
REACTIVITY DATA
StlibWty-Stabte.
O.patlbWty-Material: Compatible with most materials when dry: howeVer, when wet, phthalic anhydride
forms a solution of phthalic acid which attacks ordinary iron and mild steel.
c.rao: Group 11 of compatibiUty chart.

Wear rubber gloveS, face shield, protective clOthing. Body shield and selt~ntained breathing apparatus
should be available. H possible, cover spill with soda ash or sodium bicarbonate. Mix, and add water if
necesaary to effect good mixing. Scoop up slurry and wash site with soda ash solutiOn. Secure all ignition
"""""'' If a .,W otean, call the Nadoul Reapoue Ceater, 800-4l4-180l.

Remub: Normally tranaported at elevated temperatures. See 46 CFR 36-Eievated Temperature Cargoes.
243
POLYBUTENE
s,._,_ Butene resins: Polybutylene: Polylsobutene; UlliQid N.UO. N_.,_,.,
PolyiaobUtylane, plastiCs, reline & waxes
CHRIS Code ...
Fonnla-C(CH.)ICHa-
~~. odorless, oily liquid

BoWq Poblt ..
Preealaa Poblc ..
~c
c
........ ___!'C
_ _ c
===F
- ..
"F
"F
Spedfh: Graflty-0.81 to 0.91 at 15'C
v-,or Pr-.re :wc <A'F> (111111HaL ~
a.e.ical Fa.lly--Oiefin Reid VapcH'Pre.ure (plfa)..... ~
vapor rr-. we msF> (plfa)... ...Y....L.mr...
Polludoa CateaorY-USEPA--- IM().___liL_
A..,Ibble Balk Rea. 46 CFR Sabdaapter ....... ___D__
v.,.. Deuif;J (Air = 1.0)..
SolublUty bl Waer .......
.
....... ~
Nm:!l!gl'!la

E1eetrbl Groap-NA
General-Mild fire hazard when exposed to heat or flame.
P1ab PoUlt ('F) . 215 to 470

na-aa.~cl..bail8 ........ Unavailable
AulolpJdo. r-.. <'Fl .. Unavailable
Extbrpilbhq Apatl ... CO:!, dry chemical or foam
Spec.lal Fire ~ .. Water may be Ineffective on fire. Cool exposed tanks with water.
HEALTH HAZARD DATA

Haiti! Huard lbtiqt Odor 'nlrelllold (ptllll) PEL/TWA~) nvII'WA epp.u
Unavailable None Not pertinent Not pertinent
GeauaJ-Non-toxic. Vapor may act as a simple asphyxiant in high concentration.
Sympt.,.._Non-toxiC
Sltort Ex)IOIIII'e Toleruc:e-Non-toxic
Elr:po1un Proeed~Aemove to fresh air, apply artificial respiration if needed.
REACfiVITY DATA
StllbWty-Stable.
Co..p~tlbWty-Material.: Usual materials of construction are suitable.

Wear rubber gloves, face shield and protective clothing. Secure ignition sources.
If 111111 oc:e.n. call tile N.uoul ae.,.oue ee.ter,I00-424 IIUl

a-b: t Unavailable
t Unuslgned
244
POLYMETHYLENE POLYPHENYL ISOCYANATE
Synonyml- PAP! United Nlltion1 Number ...
CHRIS Code ...
Formula-C,,H,,O.N.
Appearance-04or-Dark brown liquid; no appreciable

Boiling Point ,..
___ .,.,
-=.!5Q'F
odo.
SpedOt Gra-.lty-1.2
ChemiCII Famlly-lsocyanates
FreeDng Point ..
Vapor Prelsure lO'C (68'F) (mmH&) ..

==F
.Y..W<.
Reid Vapor Pre.llre (,.ll.) ... .Y..W<.
Vapor Preaure 46'C (ll!I'F) (p~~la) ... ~
Pollutloa CatetorY-USEPA - - - !MO _ Q _ Vapor Deatlty (Air = 1,0)... JL
Applicable Balk Rea- 4Ci CFR Subebapter . . ____Q___ SolubiHty hi Water .. AoaG'R

Electrical Group--NA
Genen.I-Minor to moderate file risk due to high flash point. Somewhat sell-extinguishing as CO. is given off.
Flub. Point ('F) .. 425

Flam.,.ltle Umltll .. Unavailable
Autolpltlon Temp. ('FJ .. Unavailable
Extlquillllq Apntl. Confined area-CO,: saH-extinguishing.
Special F1re ProeedURS .... Wear protective clothing and respiratory protection. Seif-eKtinguishlng. Reacts
with water to evolve CO. and form solid polymer.
HEALTH HAZARD DATA

Health Haurd a.dqs Odor Tlarelhold (ppm) PEL/1WA (ppm) TLV!1WA (ppm)
Unavailable 0.4 Unavailable 0.01
General-Will discolor skin to brown color, reacting slowly and painlessly if not promptly removed. Additives
used are extremely toxic.
Symptoms-Labored breathing, watering of eyes.
Sbort Exposure Tolerance-Animal tests showed Inhalation of 2.2 ppm were fatal to 4 of 6 rats. No toxic effects
wOfe observed on sll.ln contact; eye distress was temporary. LD.., was 10,000 mg/kg.
Exposare Proc:edura--Remove victim to fresh air; administer oxygen if breathing is labored. Flush skin with
water after removing contaminated clothing. Wash eye with water for at least 15 minutes. Ingestion-induce
vomiting 3 times, follow with quart of milk and a mild cathartic. Get medical help.
REACTIVITY DATA
Stliblllty-Stable. Heat, watOf, and acids will react to evolve CO,.
Compatibility-Material: Not corrosive to mild steel, however, aluminum cannot be used.

Cover spill with water spray. Cleanup. Secure all ignition sources. Wear protective clothing and possibly
respiratory protection.
If a .,UI oecwn, QIJ tH Natloaal Raapoue Ceater, 800-4l4 llliOl.

Rnaark Storing under a dry 1nert atmoaphere at slight poslttve pressure to el1rmnate traces of mo1sture
contamination is imperative.
t Unavailable
:t Unassigned
245
PROPANE
S)'DOIIyma- Dimethyl methane; Propyl hydride
CHRIS Code ...
Form.ula-C.Ho
Bo1Un1 Potnt.. . ~c ----=M'F
Appc!U'allce-Oclor-Color1ess gas or liquid; natural-gas c _ _ _ "F
ode Freezina Polat ..... -187'C ---=..32'F
___ c _ _ _ "F
Spedfk Grnity-0.53 (liquid)
Vapor Preaw-e lO'C (68'P) CmmH&) .. _ll!!Q!L
Chemical Family-Saturated hydrocarbon Reid VIJIOl Pre.ure <Pilll) ... --1i!L
Vapor PN..re 46'C 1115'F) (,.ta) .... .....2.2lL
Pollution Catesory-USEPA - - - IMO ___gu__ Vapor Dellllty Wr = 1.0) .. ---UL
Appllabk Bulk Rea, 46 CFR S11bcllapter ........ -'2...Q_ SolINilty In Water .. Naqljg!ble
FIRE II EXPWSION HAZARD DATA

Electrical Group-O
Geaerai-Unless the flow of gas can be stopped, extinguishing a propane fire will permit the accumulation of an
explosive concentration of vapor, and subsequent explosion or rellash.
A.~~ Point ('F) .. less than -64

Ftam...ble Umits .... 2.210 9.5%
AutoipitiOD Temp. ("F) .. 842
Extin(fllihinl Apnts .. Stop flow of gas; CO., dry chemical, water fog
Special Fire Procedures .. Tanks exposed to fire shoold be kept cool with a continuous spray of water.
HEALTH HAZARD DATA

Heltb Hu.rd Rtinp Odor lbrabold (ppm) PEl.J'IWA (ppm) TLV!1WA (ppm)
0, 0, 0 5,000 to 2o,ooo 1000 Unavailable
GenerI-Loquod cause~ frostbote on skin contact. Cold vapor causes skin damage. Inhalation can lead to
asphyxoatoon
Syrnpl<>m,._H~,arJw,h<:, rJoum<J'>~. drowsmess. Contact woth the l1qu1d will cause lrostbite.
Short t.xp<,.ure "I r,hnnv-A vapr1r concentratoon ol 10,000 ppm lor bnel peroods has been reported as
prod11r.onq '"' .,,,r,pl,rw,
t:xp<Miurc f'rrlttdur~H<"'"'"" ~.tom to lre!!h aor. Gove artolic1al resporabon of breathong stops. Get medical
anentorJn If hqWl '"''' ""'"'''J rmtr; tho !:Ikon, poonts of contact may be lroslbollen; handle gently and protect
from mlf.h:uw.al ''"'"'"'fl" [)r; NOT RUB Get modtcal attontoon "NOTE. Exposure to potentially dangerous
vapor r.onumtra!Of;n, '"'" ''-'''' tmfrJr<J tho product can be dotoctod by s'floll.
REACHVITY UA'fA
Stability-Stable
Compatlbility-Materlal: Usual malmoals of r.onlllrudion aro ~;~wtable
Car11o: Group 31 ot compalitJihly (.hart

Wear rubber gloves, lace shield, protective clothoog. Have all-purpose canister mask available. Secure all
possible sources of ignition and call the ltre department. The spilled liquid will boil away rapidly, leaving no
residue
If apill OCCW11, call tbe Ntlo..J R~ Cnter, 800-4l4-8110l.
246
lso-PROPANOLAMINE
SyllOlly..-1-Amino-2-prope.nol: 2-HydfOxypropylamina; United Nlltlont Nwnber ...
lsopropanolamine; MIPA: Monoisopropanolamine
CHRIS Code ..
-
Pormula-CH,CHOHCH,NHa
BoUiq Point.. -lQ'C ~'F
A~lorless liquid: slight ammoniacal c 'F
FTeezina Poblt... ____l'C 34'F
Spedftc Gra'ity--0.96
___ c ___F
Vapor Preaue :zoc (61'F> <IIUIIHJ) . _Q.,51_
Cbelnic:al FlUidly-Amine Refd Vapor Prelaare (plia)... .........Q.Q2..
Vapor Preaure 46'C ClU'F) (plla)... .....2.QL._
PoUudoa Catqoey-USEPA--- [M().____Q_ V"JJIO' Deal.lty (Air = 1.0)... .....2.a.....
Applteallle &.lk Rea, 46 CFR Sabehaptcr ...... __Q__ Sohablllty Ill Water.. Corrp!alt

EJedrh:al Group-O
Gtillet'lll.-lrritating vapors given off when heated. Moderate fire hazard when exposed to heat or flame: can
react with oxidizing materials.
Flub PoUlt ('F) . 165

n-ble Uadb .. 2.2 to 12% (approximate)
Autolpltlou T-p. ('Fl .. 706 (estimated)
Es;tbqplillllilla A&eDb ... Dry chemical, water spray, alcohol foam, or carbon dioxide
Special FiR Procecturn .. Wear goggles, se"contained breathing apparatus and protective clothing.
HEALTH HAZARD DATA

Healtb Hazan! Ratlnp Odor lbresbold (ppm) PEL/IWA q,p.) TLV /l'W A (fpm)
Ge.nl-Single short exposure to skin may cause considerable if'rttatlon. Liquid expected to bum eyes.
Inhalation causes very slight respiratory irritation.
Sy..,._Noae and throat irritation.
Short EJ:posure Tolerance-Unavailable.
Procedurel-ln case of skin contact, wash well with soap and water. For eye contact. wash with large
Ell:pl*lH
amounts of water.
REAcriVITY DATA
Stalilltty-Stable; forms soaps with organic acids.
Compatibility-Material: Will remove paint, swells rubber; recommend type 304 stainless steel clad tanks.
Carao: Group B of compatibility chart

Avoid contact with Hquid.
If a lpiU oecun, call the NatiouJ R..-.e Cealer, 100-4:Z4 IIO:Z.
Remark~: :t Unas~~~gned
247
PROPANOLAMINE
S)'Donyms- 3-Amino-1-propanol; 3-Hydroxypropylamlne; United Natl- Nu..ber...
3-Propanolamine; !-Propanol, 3-amioo-
CHRIS Code ..
Bolllq Point.. ------l'C ~F

Appearance-Odor-Light yellow to colorless liquid; fishy c 'F
Freezbla Point.. ----...12'C ~F
""'"
Specifk Gnvity-0.982 _ _ c _ _F
Vapor Preaure lO"C (68'F) <nunfla) ... --..2.1..._
Cbemkal Family-Amino-alcohol Reid Vapor Presaure (PIIaL. __!__
Vapor PraiUTe 46'C (ll5'F) (P'Ia).. _L_
PoUuUoa Calqory-USEPA - - - IMO ____Q__ Vapor Dentl.ty (Alr = 1.0).. . ............... ____2.a..._
Applleable Bulk Rea. 46 CFR SubcUpter ....... ____Q__ Solubility bl Water.. . Sn!yb!a

Elertrlcal Group-NA
GeneraJ-Moderate fire hazard when exposed to heat or flame.
Flub Poillt rF> .. 175

F1. .mabk! UmJts .. Unavailable
AutoiplUoe Temp, ('F) .. unavailable
Ell.daiJIIilb.ial Aaenb .. Alcohol foam, dry powder, CO,
Special Flf'e Pro!:eduret .. Water may be ineffective on fire.
HEALTH HAZARD DATA

Healtb Huard Ratinp Odor Thredlold (Jipm) PEL/TWA (p)d) TLV ;TWA (ppm)
Gmerai-Moderately irritating to skin and eyes.
SymptoiiUI-Irritation of mucous membranes and respiratOfy tract. Severe exposure results in blisters and burns.
Short Expo~ure Toleranee-Unavailable
Expo11ure Protedures-Remove victim to fresh a1r. Give artificial respiration or oxygen as necessary. Flush eyes
alld skin well with water. Remove contaminated clothing. Wash out mouth with water if Ingested.
REACTIVITY DATA
Stability-Stable.
CompatfbUity-Mterlal: Copper and copper alloys are readily corroded.

Wear self-contained breathing apparatus and rubber gloves. Absorb material on vermiculite, sweep up, mix
with dry caustic, wrap in paper and burn in an incinerator. Wash spill site.
If 'PW ocan. atU tbe National ReapoiiM Ceater, 11100-4Zt 8802,

lleaarka: t Unava~lable
t unassigned
248
(NOTE: This cargo Is currently not jMrmmed to be shipped In bulk In U.S. wsters)
beta-PROPIOLACTONE
Synonyms- Hydracrylic acid, betalactone; United Nations Number ...
2-0xetanone; Propanolicle; beta-Propionolactone
CHRIS Code .
Formula-OCH.CH,CO
BoU1n1 Point .. _____125'C _____J_U'F
AppearallCe-Odor-Colorless liquid; irritating odor c 'F
FreeUna Poblt .. -33'C -28'F
Specific Grnity-1.15 c ---
Vapor Preaure lO'C (6$'F) <-HI) .. ..Y..I.oi!.
ChelnleaJ Family-Ketones Reid Vapor PreMure ((Ilia) ... ___!__
Vapor Prelaure 46'C (115'F) {plill) ~
Polllltion Cateiory-USEPA - - - IMO _____I2__ Vapor IJeajty (Air = 1.0)... ....li_
AppUcsble Bulk Reg, 46 CFR Subchapter ....... - - - SolubUity i1 W1ter .. o!ub!a

EleetriCII Group-Not applicable
General-Combustible; containeJs may explode in fire. VapOfS of unburned material are very toxic.
Flub Poblt ('F) .. 165 (eel

Fla.-ble Limits .. LEL=2.9% UEL-unavailable
Alltoipltion Temp. ('F) .. Unavailable
Extfn8uilblna Agents .. Water, dry chemical, foam, CO,
Special F1re Proceduret~ .. Wear self-contained breathing apparatus, full protective clothing, rubber
gloves to prevent all contact with liquid. Cool exposed tanks with water.
HEALTH HAZARD DATA

Health Huard Ratinp Odor "Ilu-e:dtold (ppm) PEL/I'W A (ppm) 11.V1TWA (pplll)
3, 3, 4 Unavailable 29 CFR 1910.1013 0.5
GeDend-Suspected carcinogen. Vapor moderately irritating. liquid is a fairly sevare skin irritant. Poison. Get
medical attention afteJ all exposures to this compound.
Symptol!ll-lnhalation-irritation of nose, throat and respiratory tract. liquid causes eye irritation and tears. Skin
contact resufts in irritation and blistering. Ingestion-mouth and stomach burns.
Sllort Exposure Tolerance-Unavailable
Expoure Procedu~lnhalation-move victim to fresh air. Give artificial respiration or oxygen as necessary.
Eyes-flush with water for 15 minutes. Skin-flush with water. Fluid from blisters will cause additional
blisters. Ingestion-give large amounts of water, induce vomiting.
REACTIVITY DATA
StsbUity-Stable but at elevated temperatures can polymerize.
Compl.tibility-Miterial:
Cup: Groop 18 of compatibility chart.

Wear full protective clothing. AvOid any contact whatsoever. Wear self-contained breathing apparatus and
rubber gloves. Disperse and flush large spills.
If a .,Ul occun, c:lll the Nltlonal Re1p0111e Cuter, 800-4l4-1110l.

Reaw-kl: Bulk ahtpment not permiHed.
t Unavailable
:t: Unassigned
249
PROPIONALDEHYDE
5)'11011)'1111- Methyl acetaldehyde; Propanal; Propionic United Natiollll Number ...
aldehyde; Propyl aldehyde; Propyllc aldehyde
CHRIS Code ..
___"C ___lU"F
A,...._.Odor~esa liquid with suffocating and _ _ c _ _ _ "F
fruity odor FreeDq; Poblt .. -----=:.Zi'C -=.1.1.2:'F
Spedlle GnYity-0.80
___ c _ _ _"F
Cl&e.teal Fandly-Aidehyde
Vapor Pra.Jure lO'C (68'F) (mmH&) ..
Reltt Vapot Preaure (p~lro) ...
Vapor Pre~~~~re 46'C (ll!I'F) (p&la) ..
-=--
_u_
__ji_
Pollatloa CatetOQ"-USEPA - - - IMO _____JJ__ Vapor Deutity <Air = 1.0) ... -Z.lL
Applk:allle 8tdk Rea. 46 CFR Sabc:bapter ....... ___Q_ Solubility iD Wmr ... 22%
---
c..--c: Flammable liquid
Geneni-Extreme lire hazard due to low flash point. Flashback along vapor trail may occur. Vapcll' may explode
H ignited in an enclosed area. Reacts vigorously with oxidizers.
Ft.dl Poblt ('F) ..

Plam.aWe u.ttl ..
15 to 19
2.9 to 17%
AldolpitiOJI Temp, ('F) .. 405
Extiapldllq Aldtl .. Carbon dioxide, dry chemical and alcohol foam.
Spedal Fire Procedww .. Keep tanks cool with water spray. Provide fire f~ghters with seH-contained
breathing apparatus and protective clothing. Fire may be difficun to control due to ease with which vapor Is
re-ignited. Water may be ineffective on fire.
HEALTH HAZARD DATA

Heald! Haanl Ratiap Odor Tbre~hold (ppm) PEL/TWA (ppm) TLV /I'WA <pp.l)
2, 1, 2 1 Unavailable Unavailable
Gaeral-Uquid irritating to skin and causes eye injt.Jry. Vapor inhalation dangerous.
Sypto~N-Dizzioess, drowsiness.
Sltort Expon"' TolerU---8,000 ppm
bpoiW'e Proeedur-skin cootact should be thoroughly washed off with soap and water. In case of liquid
contact of the eyes, flush eyes with water for at least 15 minutes then obtain medical treatment.
REACllVITY DATA
Statdllty-Highly reactive. Normally stored under nitrogen blanket. Reacts vigorously with oxidizers.
CompatlbJIIty-Materlal: Either stainless steel or aluminum are suitable materials. Tanks may be coated with
phenolic resin.

Wear rubber gloves, seH-contalned breathing apparatus, protective clothing. Avoid contact with liquid. Secure
ignition IIOUI'C8S. If possible, cover with sodium bisulfite (NaH~). Add small amount of water and mix. Scoop
up. Wash site with soap solution.
If Ifill oec:lll'l, call the Natioaal RtlpOIIM Ceater, 800-tl4-880l.

.........
250
PROPIONIC ACID
s,--y....- Ethane carboxylic acid; Ethylformic acid; United Natioa Nuber...
Methacetonic acid; Methylacetic acid; Propanoic
.,~
CHRIS Code ..
Formula-CH,CH.COOH
Bolliq Poblt.. ____lil'C ______29'F
Appeannee-Odor-Ciear, colorless liquid; p!Jngent odor
___ c ___.F
Fnezlq Poblt... __.,;;;;,lJ'C ---=.'F
S]leelfte Gra-rlty-0.995
___ c ___F
Vapor Preuure lO'C (Iii' F) <mmH8) .. ____.2j__
CbeaUc:al Family-Organic acid Reid Vapor l'relhre (pita)... ___2.2..._
VllpOJ' Pr-ure 46'C (115'F) (]IN)... --2.L
Polludoa C.teaorY-USEPA ___1L_ IMO ___12__ Vapor Deulty (Air = 1.01 .......................... ____2.a_
Applleab&e Bulk Rea, 46 CFR Subcbapter ....... ___Q__ Solubility bl Water.. .. ComDfeta

Eleetrieal Group-O
Geuend-lgnited by heat and open flame.
Flub PoiDt ('F) .. 14{)

..,__hie IJJIII.ts .. 2.9 to 14.8%
Alltofpidoll Te~~~p. ('F) .. 955
Elr:tiqlt~a~Da Ap~~t. ... Alcohol foam, water spray, CO., dry chemical
Special Fire Proeedllra .. Provide fire fighters with goggles, self-contained breathing apparatus and
protectiYe clothing.
HEALTH HAZARD DATA

Health Hazard Ratlnp Odor 'lbrelllold (ppm.) PEL/TWA <pp.l TLVITWA (ppm)
General-Vapor extremely irritating. Liquid causes severe burns.
Symptom.--Causes bums on the skin, particularly mucous membranes (mouth, nose) and eyes.
Sllort Es:poeure Toleruce---Unavailable.
EJ:~~GRR Proc:edura-Vapor-remove victim to fresh air, if breathing stops, apply artifiCial respiration. Skin or
eye contact---remove contaminated clothing and gently flush affected areas with water for 15 minutes. Get
medical attention.
REACTIVITY DATA
Stabllity-Stable. When heated, emits acrid fumes.
Co.pUibllity-Malerial: Corrosive.
c.r.o: Group 4 of compatibility chart.

Wear rubber gloves, face shield, protective clOthing. Body Shield and sail-contained breathing apparatus
should be available. Avoid contact with liquid. Secure Ignition sources. If possible, cover spill with soda ash or
sodium bicarbonate. Mix and add water if necessary to effeCt good mixing, scoop up slurry and wash site with
soda ash solution.
If a .,W OCC1Irt, caU die Nattc.al a..- Cater, 1100-424 1101,
Remarks:
251
PROPIONIC ANHYDRIDE
SJDDDYmt- Methytacetic anhydride; Propanoic acid United Natlou Number ...
anhydride; Propanoic anhydride; Propionyl oxide
CHRIS Code ..
Formllla-(CH,CH.C0)1 0
BoiliD& Point .. ~c ____m!"F
Appearmee-Odor-Colorless liquid; pungent odor ___ c _ _ _ "F
FTeeUn1 Poillt .. ~c ----=.:'F
c _ _ _ "F
Speclftc Gra.,lty-1 .01
Vapor Prtlllll'e lO'C (68'F) <-H&J .. __l.lL_
Olelnk:al FIUIIIIy-Organic acid Reid Vapol' Preuare (piU) ... ~
Vapor Preuure 46'C (115'F') (plla) .. ~
Poll11tto. c.tqory-USEPA__Q__ IMQ.--'L._
Allf]k:Ule Bulk Rea. 46 CFR SubdYopter ....... __Q__
Vapor Delll.lty (Air = 1.0) ...
SolubWty !11 Wllter ..
.,..w.-

Electrical Group-O
Geaerai-Moderate lire hazard when exposed to heat Of flame; mOfe of a health hazard than a fire or stability
hazard.
Flail Point ('F). 165

f'luiUDIIble lhnltll .. 1.48 to 11.9%
Autoipltlon Temp. ('F) .... 600
Estlnpllblq Aaents. Carbon dioxide Of dry chemical
Special Ftre Procedure~ .... DO NOT USE WATER as extinguishing media; propionic anhydride reacts
slowly with water to form propionic acid-reaction rate Increases with temperature.
HEALTH HAZARD DATA

Health Huanl Rattnas Odor Tbreallold (,....) PEL/IWA (pr-) nv!1WA <pp.al
GeneraJ-Vapors irritating when inhaled. liquid irritating to skin on contact. May produce sensitization effects.
Symptonu-Resp1ratory 1rritation, skin irritation.
Sbort Expowre Tolerance-Unavailable
Ex,_.-e Pn:N:edur-Vapor-remove victims to fresh air, apply artificial respiration if breathing stops. Skin or
eye contact-remove contaminated clothing and gently flush affected areas with water. Get medical
attention if discomfort persists.
REACI"IVITY DATA
StaiHIIty-Decomposes on contact with water. Can react with oxidizing materials.
Co.patlbiUty-Mater:lal: Noncorrosive to aluminum or stainless steel.

Have self-contained breathing apparatus available. Avoid contact with liquid. Secure ignition sources.
If a spill oeeura, can tbe NaUoal. Rapoue Centu, IJ00-4:Z4 IBO:Z.

Remarks: Reacts with water to form propioniC acd.
252
PROPIONITRILE
S)'11011yma-Cyanoethane; Ether cyanatus; Ethyl United N.ti01111 Null
cyanide: Hydrocyanic ether; Propanenitrite;
Propionic nitrile
CHRIS Code ..
BoJIIq Pelnt ... __arc ~F

Appeanmee-Odor-Brown liquid; pungent odor c "F
Freeziq Point .. -92'C -133'F
Speeltlc Gn.rity-0.78
___ c _ _ _"F
VIIJIOI' ""-re lO'C (QI'F) (..tlaJ.. __a_

Cbendcal. Fllmily-Nitriles Reid V.,or ~ (fda)... ___!.L_
Vapor ~ 46'C (115'F') (plia) ............ ---..2..4._
PGUutto. c.teaorr-USEPA - - - IMO ____&____ VllfO!' Denal.tJ (Air = 1.0).. ..... ___1.!_
App]k:able Bulk Rea. 46 CFR Subchapter ....... ____Q__ SolaiNHty Ill Water.. Snlublt

Electrical Group--O
GeJierai-Produces toxic gases of hydrogen cyanide, nitrogen oxides, and carbon monoxide when heated or
near open flame.
FJ.dl Point ('F) .. 54

Flammable LlmUs .. 3.1 to 14.0%
AutcNpltto. Te111p. ('F) .. Unavailable
Ezlhlpilllbl& AJNU ... Alcohol foam, dry chemical, CO,
S,edlll Fire Proeedurel: . Cool exposed tanl<s with water. Wear self-contained breathing apparatus and
full protective clothing including boots.
HEALTH HAZARD DATA

Healtb Hazard Ratlnp CHor TJu-edtold (ppm) PEL/I'WA (Pfllll) 1LV/I'WA (IIPIII>
General-May be fatal if absorbed through skin. Liquid causes bums.
Sympt..........Oizziness, nausea, rapid pulse, respiratory distress, cyanosis, coma. May be fatal If inhaled,
swallowed or absorbed through skin.
Sbort Exposwe Tolerance-LO.. for rats in a 4 hour period was less than 1.6 gm/1.
Expo~~ure Proced~Antidote is amyl nitrite. Always have a cyanide kit at hand. Aemove to fresh air.
Administer artificial respiration or oxygen as necessary.
REACfiVITY DATA
StabWty-Stable. Incompatible with strong acids and alkalies.
Compati.biUty-Material:

Keep people away. Secure sources of lgnltloo. Shut off leak if without risk. Stay upwind. Wear sen-contained
breathing apparatus and full protective clothing including boots. For large spills, dike and pump into salvage
tanks. Use water spray to knock down vapors. Prevent run off to sewers.
If a .,W 0CC11r1, ea1J the NUloaal Relpoale Cnler, I00-4:z4-110l.

Remarb:
253
Iso-PROPYL ACETATE
Synonyms-Acetic acid, isopropyl ester; Isopropyl United Nations Number ...
acetate: Isopropyl ester of acetic acid; 2-Propyl
acetate: sec-Propyl acetate
CHRIS Code ..
Formut.--CH,COOCH(CH,) 2
______i2'C __lii'F
Appearance-Odor-Colorless liquid; pleasant, fruity odor c ---
- 73'C -----=ii'F
Freezln1 PoJnt ...
Specll'ic Grarity-0.88 c ---
Vapor Pressure 20'C (68'F) (mmHI) ..
Cbemical F...Uly-Ester Reid Vapor Pl'eaun! (ptja) ...
Vapor Pre.111e 46'C (tlS'FJ lll'la) ..
PoUution Cateaory-USEPA - - - IMO __m__ Vapor Density (Air = l,IJ) ...
Applicable Bulk Re~o 46 CFR Subdupter ..... ____Q__ Solubility 111 Water ...

EJettrieal Group-O
General-Dangerous. Keep away from heat and open llama. Flashback along vapor trail may occur. Vapor may
eKplode if ignited in an enclosed area.
Flab Point ('F). 60

Flammable Umih 1.6 to 7.8%
Autoipltlon Temp. ("F) 860
Extlnaullbina Aseatli .. co.,dry chemical, alcohol foam, water log
Spec:illl. Fire Proeedures .... Use of dry chemical where It can get into a tank of isopropyl acetate is not
recommended. Fires involving spills outside of tanks can be extinguished with dry chemical.
HEALTH HAZARD DATA

Health Hazard R1tinp Odor Tbrnbold (ppm) PEI.../I'WA (ppm) UVITWA (ppm)
1. 1, 2 100 250 250
General-Vapors harmful.
Symptoms-Dizziness and drowsiness.
Sbort Exposure Toleru::e-Unavailable
Exposure Procedures-Vapor-remove victim to fresh air; if breathing stops, apply artifiCial respiration. Skin or
eye contact-remove contaminated clothing alld gently flush affected areas with water for 15 minutes. Ge1
REACTIVITY DATA
Stability-Hydrolyzes (reacts with water) on standing to form acetic acid and isopropyl alcohol. The presence of
bases (alkalis) speeds up the reaction. Reacts vigorously with oxid"1zing agents
Compatlbility-Mter'-1: Softens or dissolves many plastics
C11110: Group 34 of compatibility chart

Wear rubber gloves, face shield, protective clothing Have all-purpose canister mask available. Avoid contact
U 1 spill ocrurs. 1:111 the Ntional Response Center, 800-424-8802.

Rem1rks: Vapor Pressure. 49 mmHg at 17 C.
254
nPROPYL ACETATE
Syaony~ Acetic acid, n-propyl ester; Propylacetate United Nat:101111 Number ...
CHRIS Code ..
BolliD& Point .. ______jQZ'C ---.2.1..:!'F

Appeanmc:e-Qdor-Colorless liquid; pleasant, fruity odor
___ c ___"F
Spedfk Gral'lty-0.87
___ c ~F
-----=iZ'C
___"F
Vapor Prea.re lO'C (68'F) (.all&) ....
Cbelllkal Family-Ester Reid Vapor Pre.ure (psUI)... ----1.L
Vapor Preavre 46'C (115'FJ C.,.U).. ___!.i_
PoUation C.tqory-USEPA - - - IMO ___o__ Vapor Density (Air = 1.0)... .......... ____a..52...._
Appllable Blllk Rea. 46 CFR Subdlapter ....... ____Q__ SolubiUty In Water.. S!iAh!

Gr.de--C: Flammable liquid
Eleetrleal Group-O
Gaend-Oangerous, when exposed to heat or flame.
F1uh Point ('F) .. 70

n.-ble U.ib .. 1.7 to 8.0%
A11toiplt:l011 Temp. ('F) .... 842
Extlnpillllna; Alent& .. CO., dry chemical, alcohol foam, water fog
SpedaJ Fire Pnxedura .. use o1 dry chemical where it can get into a tank of propyl acetate is not
recommended. Fires involving spills outside of tanks can be extinguished with dry chemical. Water may be
HEALTH HAZARD DATA

Health Hazan~ Ratlnp Odor 'I'Iuwhold (ppm) PEL/fWA (ppm) TLV/fWA (IIPJII}
General-Liquid causes slight irritation on contact Vapor inhalation results in irritation of mucous membranes
with moderate systemic effect.
Symptoms-Sleepiness, fatigue, and retarded respiration rate.
Short E:xponre Toleraace-Unavailable
E:xpo.ure Procedlll"ei-Vapor-remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or
REACI"IVITY DATA
StdillUy-Hydrolyzes (reacts with water) on standing to form acetic acid and n-propyl alcohol. The presence of
bases (alkalis} speeds up the reaction. Reacts vigorously with oxidizing agents.
eom,.tlbWty-Material.: Softeos or dissolves many plastics.

Wear rubber gloves, lace shield, protective clothing. Have all-purpose canister mask available. AvOid contact
with liquid. Secure ignition sources. Small spills may be washed away with water.
If a pill oecun, ealJ lite NadouJ Relpoae CeD.ter, 800-4:Z4 IIO:Z.

Re.arU: Vapor Pressure: 30 mmHg at 28.ec.
255
Iso-PROPYL ALCOHOL
S)'llOIIy- Alcohol C-3; Dimethyl carbinol; IPA: UIIJted Natl01111 Number ...
Isopropanol; Isopropyl alcohol; Petrohol;
2-Propanol; sec-Propyl alcohol; Rubbing alcohol
CHRIS Code ..
Fonnula-(CHs).CHOH
BoUiq Po6nt .. ~c ___1&2'F
Appeuuc:e-Odor-Colorless l~id; sharp, somewhat c F
unpleasant odor Freeda1 PolaL -BB'C -12B'F
Speclftc Gn'fity-0.79 c ---
Vapor Pre.lll'e lO'C (68'Fl <mHaL. __aL_
Chemic:al. FamUy-Aicohol Reid Vapor ~re (IJiia) ... ....l.L..
Vapor Pre.ure 44i'C (115'F) (pl:ll.) .. -4.lL..
PoUutioa C.teaorJ-USEPA - - - IMO ____liL_ Vapor Dealty (Air = 1.01 ... ....zJlL
Applkable Bulk Re,. 46 CFR Subcldpter ....... _.c.._ SulubWty ill W.m .. Complete

Electrbl Grwp-0
Geaeni.-Dangerous. Keep away from heat and open flame. Flashback along vapor trail may occur. Vapor may
Flub Polat ("F) .. 53

Flam~UbJe Ullllb .. 2.0 to 12.0%
Autolpltion Temp, ('F) .. 750
E~:dqal:dUna Aaeats .. CO., dry ch&mical, alcohol foam, water fog
Speelal Ftre Procedue1 ... Cool tank with water spray. Water may be ineffective on fire.
HEALTH HAZARD DATA

Healtb Huard lbtiap Odor 1brelllold (pplll) PEIJIWA~l TLVII'WA ~~
1, 0, 2 200 400 400
General-Acts as a local irritant and in high coocentrations as a narcotic. Prolonged or repeated skin contact
may cause defatting of the skin and may produce detmatitis from daHy contact. Severely irritating to the
eyes and may cause eye injury it not removed promptly.
Symptoms-Dizziness and sleepiness: eyes, nose, and throat irritation.
Sbort Ex~un: Toleranee-400 ppm lor 30 minutes.
Ex~ure Proeedura-VBI)Of-femove victim to fresh air. Appty artificial respiration it needed. Eye
contact-wash eyes geotly lor 15 minutes with fresh water. Get mediCal attention for eye contact.
REACI1VITY DATA
StabiHty-Stable.
CapadbiUty-Material: Aluminum, especialty at elevated temperatures is un&uilable.
c.r.o: Group 20 ot compatibility chart. See also Appendix 1-Exceptions to the Chart.

WeBI rubber gloves, face shield, protective clothing. Have all-purpose canister mask available. Avoid contact
If a Ifill ocean, call tbe Nadoaal Reaponae ee.ter, llllll-4l4-880l.
Remarb:
236
nPROPYL ALCOHOL
Synonyme-Aicohot C-3; Ethyl carbinol; Propanol; UnJted Natiou N11mber ...
1-Propanol; n-Propanol; Propyl alcohol; Propyl
alcohol normal; Propylic alcohol
CHRIS Code ..
Formu.la-C,H,OH
BoUiq Point .. ------iZ'C ---.22Z'F
Appearaaee-Odor--Colorless liquid; alcohol-like Odor ___ c ---
Freeana Point .. ---=.lZZ'C --=ill'F
Speclfk: Grnity-0.80 ___ c ---
Vapor l"ra.IIJ'e 29'C (68'F) IH&) ..
Chemical F-lly-Aicohol ll4ild Vapor Pnllure (plla)...
VllPOJ' Preslllft 46'C (115'F) (plia) ..
Pollution Category-USEPA--- JM().___jjl__ Vapor IJrelqlty (Air = l.Ol..
Applkllble Bulk Rea. 46 CFR Subetlapt ....... _Q__ SolubWty bl w.wr ....

GriMie-0: Combustible liquid
Electrkal Graup--0
Generai-Dangeroos, when exposed to heat or flame.
Flab Point ('F) .. 85

Flammable LimiU .. 2.0 to 13.5%
Auhllpjdon Temp. ('F) .. 700
ExUnsaillllaa: Asentl .. CO..dry chemical, alcohol foam, water fog
Spedal Fire Procedure. .. Water may be ineffective on fire. Cool exposed tanks with water.
HEALTH HAZARD DATA

Healtll Huant Rattnp Odor nre.bo&d (ppm) PEL/I'WA (ppm) TI..V/I'WA (ppm)
1, 0, 2 Unavailable 200 200/skln
General-Vapor inhalation causes slight irritation of mucous membranes with moderate narcotic effect resulting
in dizziness, drowsiness.
Symptomli-Salivation, retching, vomiting.
Short Expoare Toteran&:e-400 ppm to 30 minutes.
Expo111re Procedara-Vapor-remove victim to fresh air. Apply art\flcial respiration H needed.

contact-wash eyes gently for 15 minutes with water.
.,.
REACfiVITY DATA
StablUty-S1able.
Cop~~tibWty-Matffial: Usual materials of construction are suitable.
CarBG: Group 20 of compatibility chart. See also Appendix !-Exceptions to the Chart.

If a .,W ocean. call the Natioul.1lelpoale Cuter, 81)1)..4l4 BIOl.
Remarlu: Vapor Pressure: 10 mmHg at 14.7"C.
257
lso-PROPYLAMINE
S~2-Aminopropane; laopropylamine; Uldted N.doml Nvmber ...
Monolsopropylamlne; 2-Propanamine
CHRIS Code ..
F-ula-(CH,).CHNH,
Boillll& PtNat .. ___azc ~F
~orless liquid; pungent, Irritating, c F

typical amine odor FreeDq Pohlt .. -95'C -139'F
Spedflc: Grm.ty-0.69 c ---
Vapor ~re ZO'C (68'F) (JUIH&) ..
Che.teal F..Uy-Amine ReJd Vapor ~ (ptla) ... ....1U...
Vapor ~re 46'C (115'F) {pU) .. ..AL
Pollution c.tqory-USEPA - - - IMO ---"-... VtiJIOI' ne.dty (Air = 1,0)... ....2.li:L
Applicable &.Dr. Rea, 46 CFR S11bchapter ...... __Q__ Solulrillty t. Wllter .. So!ubla

Gnde-A: Flammable liquid
Electrical Gro.p-0
General-Toxic ())!;ideS of nitrogen may form in lire. Readily forms explosive mixtures with air. Ares are difficult
to control because of the ease of re-igoition of the vapor.
Flub PoUlt ('F) .. -35

Flammable IJmJis ..... 2.3 to 10.-4%
A.toipl.doa Temp, ('F) .. 756
E:Ktinpldibta: Allfttll. Water spray is particularly effective, CO.
Special Fire~--. Considerable caution is indicated in approaching iso-propylamine fires and
particularly in extinguishment as an explosive mixture may exist immadlately following elCtingulshment and is
readily re-ignited. SeH-contained breathing equipment with full face piece is required.
HEALTH HAZARD DATA

Health Huanl Ratblp Odor Threlhold (IIPJII) PEL/IWA q.p.) TLV!lWA (ppiB)
Gaeral-lsopmpylamine liquid and vapor are irritating to the sl<in, producing typical alkaW bums. Vapors will
irritete eyes end lungs.
Symptom.-Vapor-nose, throat, and lung irritation; sevare eye irritation or burns.
Short bponrc Tolenuu:e-Unavailable
Expoore Proeedura-Skin contact-remove all contaminated clothing, flood affected areas with large quantities
of water, wash all affected skin thoroughly; if any evidance of skin burning is noted, a physician should be
seen. Inhalation-remove patient to fresh air; nose and throat irritation may be relieved by spraying or
garling with water. If patient is unconscious, apply artificial respiration.
REACllVITY DATA
StabWty-Unstable-highly flammable, readily ignited by static sparks of relatively low energy.
CompatiiNHty-Materlal: Can be handled safely in steel equipment; severely corrodes aluminum, copper, and
copper-baSed alloys (except Monel).
Carie: Group 7 of compatibility chart.

Wear butyl rubber gloves, all-purpose canister respirator, and protective clothing. Secure ignition sources. If
possible, cover spill with sodium bisulfate. Spray with water and wash up with large exoass Of water.
u .,m ocean, can t11e Natkmal Re~poQe ee.cer, 800-4l4-IIOZ.

JleJurlul: . Vapor Pressure: 500 mmHg at 22'C.
258
PROPYLAMINE
Syno.)'lllt--1-Aminopropane; Monopropylamine;
1-Propanamine: n-Propylamine; mono-n-Propy1amine
CHRIS Code ...
Formula-CH.(CH,j,NH,
BoWq Poiat .. ____C -..lZ!!F
Appelll'liiiCe-Odor-Colortess Hquid with a pungent
ammoniacal odor when concentration Is high
Spedlk Graflty-0.72
Fl'elizlq Pobrt .... -B2"C
_ _ c
c
___..
-11B'F
Vapor Plwore lO'C (61'F) (...tlcJ.. ~

ChemJcal F.Wiy-Amine Reid Vapor Pnllllre (plia). .......1QL
V-.or ~ 46'C (115'F) (,.._,___ --l!J.._
PoUutioll C.tqory-USEPA ___.1L_ IMO ___Q__ Vapor Dnlll)' Wr ... 1.0) ......... ___i.L
AppllcOle Blk Rea, 4Ci CFR Subdnapter ....... ___Q__ SoJbfllty 1a w.m.. .. SoUJII

Grade-S: Flammable liquid
Eleetrlcal Group-O
General-Quite flammable. Emits tmcic and irritating vapors when heated. Vapor is heavier than air and may
travel to a source of ignition and flash back.
F'lalll. Poblt ('F) .. -35

~bieUtalb .. 2.0 to 10.4%
AlltolpitiOD T-p. ('F) .. 604
Es~Apub ... Garbon dioxide, dry chemical or alcohol foam.
Specilll. Fire Procedure~ .. Water may be ineffective on fire. Cool exposed tanka Wlth water.
HEALTII HAZARD DATA

Heal.tlro Hazard Ratlnp
3, 3, 0
Odor 1'hrellao&d (pplll)
Unavailable ,.
PEL/lW A (pplll)
,.
TI.V/I'W A <PP-l
Gelteral-A severe eye, skin and respiratory irritant. Highly toxic when ingested or inhaled.
Sympt-Severe irritation of skin, eyes and respiratory tract.
Short E11.poeure Tolert~~~re-Unavailable
EI,.,.ure Proc:edaree-Skin-wash with soap and water, then flush area with water. Eyes-flush with copious
amounts of water. Vapor-remove victim to fresh air. Administer artificial respiration if necessary. In all
cases call a doctor.
REACfiVITY DATA
SUbillt:y-Stable.
CompatibWty-MIIkrial: Glass and stainless steel.
Carp.: Group 7 of compatibHity chart.

Wear lull skin protection and self-contained breathing apparatus. Secure Ignition sources. Add IOdlum
bisutfate and spray with water. Then clean up.
U a .,W oeewa, '*I tile Natioaal . . . . . . c.cer,I00-424 11101.

ltemarb: PEL and TLV based upon lso-Propylai"Oine.
259
PROPYLENE
S,.-y-- Methyletllene; Methylethy1ene; Propene
CHRIS Code ..
BolllnaPoillt. ~c ~F
AppearuceOdoi'-Colorless gas, liquid under pressure; c 'F
characteristic olefin (gassy) odor Freeziq Point.. -185'C -301'F
Spedtk Gn,lty-0.52 at 20'C
___ c ___ F
Vapor Preuure :ZO'C (68'FJ (maaHal .. ~
Reid Vapor Preulll1! (,.Ia).. ....22Z.2.....
Vapor Pnuure 46'C (115'FJ (JI'ia}.. ....zza.2._
Polludo. C.tqory-USEPA - - - IMO ----'HlL..... Vapor Delllity (Air = 1.0).. ---1.dl_
Applkdde Balk Rea. 46 CFR Subcbapter ....... ----C..Q... SohdHIIty In Water.. ... 45 ml Ql&/100 ml watar

Grade-liquefied Flammable Gas (LFG)
Electr:ieal. Group-O
Geaen:I-As with all gas fires, the only effective method of extinguishing is to shut off the fuel supply.
Otherwise a more dangerous situation, the formation of an explosive mixture can result
F'-l Point ('FJ .. -162

Flam-bk U.Ub .. 2.0 to 11.0%
Alltoiplt:IOD Tep. ('F) .. 927
Elltinpillllna; Ap:nb .. Stop flow of gas; water fog
Speelal Fire Proc:edure. .. Tanks exposed to lire should be kept cool with a water spray.
HEALTH HAZARD DATA

Healtll Huanl Radap Odor 'Illrelllold (ppm) PEL/TWA (ppm) 1LV!I'WA (ppm)
0, 0, 1 Unavailable Unavailable UnavaHable
GNeni.-Simple asphyxiant. Absence of adequate warning iOOicaflons such as strong odor or pronounced
irritation of mucous membranes of eyes and nose introduces possibility of exposure to hazardous
concentrations. Contact with the liquid may cause frostbite.
s 1111pt-Dizziness, sleepiness
Sltort Expo~ure Toleramte-Mixture of 6.4% propylene and 26% oxygen inhaled for 21/4 minutes produces mild
Intoxication, drowsiness, tingling of the skin, and inability to concentrate.
ExfiOiure Proeed~U"a-Aemove victim to fresh air. Apply artificial respiration if breathing stops. Contact with
liquid may cause frostbite. If the liquid has spilled ooto the skin, points of contact may be frostbitten; handle
gently and protect from mechanical damage. DO NOT RUB. Get medical attention.
REACTIVITY DATA
StabWty-Stable at ordinary temperatures.
Co~llty-Material: Usual materials of construcboo may be used.

Have all-purpose canister mask available. Shut off ignition sources. Call the fire department. If product does
not catch fire, it will soon boil oft.
If a ipill oeeUJ"II, call the National RelpllaM Cetlter, 800-424-8102,
260
PROPYLENE OXIDE
Synony--1 ,2-Epoxypropane; Methyloxirane; Propene
oxide
CHRIS Code ..
Formui1-CH,OCHCH1
BoJiln& Polllt .. _____M"C ~F
Appelll'aDCe-Odor-Color1ess liquid; ather-like odor c F
Freeziq Po'nt .. -112"C -1ZO"F
Spedfk: Grarity-0.86 c ---
OlemJeaJ FunJiy-Aikalene O>Cide
PoUutlon c.tqory-USEPA____a__ IMQ.__o__

Appllnble lkllk Rea. 46 CFR Subebapter ....... ____Q___
Vapor '"'-orr lO"C (68'Fl (-HI) ....
Reid VIJIOI' Prellllft (pita) ....
Vapor '"""-'e 46"C (115"F) (pda) ..
Va,or DeDIIty (AJr = 1.0)...
Soi111NIIty ID. Willer .
----
___j.aJL_
~
_2.l!!L
59%

Gr.de-A: Flammable liquid
Eleetrlcal Group-B
Qmerai-An extremely reactive, flammable liQUid with a wide explosive range. Ignited by heat, spa~s or open
flame. Flashback along vapor trail may occur. Fire or contamination may cause violent rupture of tank.
~ Potat ('FJ .. -35

F1llnunahle LJmjtl; .. 1.8 to 38.5%
AutcNpidoll Temp, ('F) . 889
EJ.tlquiAina AaeaU ... Stop flow of gas; large volumes of water, CO., alcohol foam.
Spedal Fire Prooedurell .. If a fire breaks out near a propylene oxide tank, keep tank cool with a water
spray. Explosion hazard requires approaching a burning tank with caution.
HEALTH HAZARD DATA

Healdl Huard Ratlnp Odor 1brelbold (ppm) PEL/IW A (ppnr.) n vnw A <Pflll)
3, 2, 2 200' 20 20
Gelleni--Suspected carcinogen. Vapor harmful. Uquicl causes eye bums. LIQUid or water solutions absorbed
into clothing, partiCularly shoes, cause delayed skin burns.
Symptonii-Nausea, vomiting and irritation to eyes and respiratory passages.
Sllort ExJIOIIlft ToleraDce-2000 ppm for 4 hours.
EJ:posure Procedare.-Vapor-remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or
eye contact-remove contaminated clothing and gently flush affected areas with water tor 15 minutes. Get
*Note: Detectable odor Is greater than the TLV. Exposure to potentially dangerous vapor concentration can
occur before product can be detected by smell.
REACI'IVITY DATA
Sl.lbiHty-Polymerizes violently with catalysts such as acids, bases, and certain salts. Reacts violently with
chlorine and with ammonia.
Compatibillty-Malerlal: Avoid copper and other acetylide-forming metals.
Clrxo: Group 16 of compatibility chart.

Wear rubber gloves, large heavy face shield, (If in doubt, LtM body Shield also), self-contained breathing
apparatus. Avoid contact with Uquld. Secure ignition sources. Do not HuSh spill into confined spaces where
flammable vapors can accumulate.
If .,W OCleiU'f, call the Natioul. Re1poue CellteJ', 800-424 110%.

Rnlarb: Must be shipped with 1nert pad.
261
Iso-PROPYL ETHER
SynonyiU- Diisopropyl ether; Oiisopropyl oxide; United Natloas Number ...
2-lsopropoxypropane; Isopropyl ether;
2,2'0xybis[propane]
CHRIS Code ...
Fonnula-(CH,).,CHOCH(CH,h
BoiiiDI Pobst .. ____c ~F
Appearance-Odor-Colorless, volatile liquid with an
_ _ c F
ethereal odor Freedn1 Point ... ----=.e'C -126'F
Specific: Grulty--0. 72 c _ _ _ F
Vapor Pn.ure :W'C (611'Fl (mmHR) .. ____l!L
Cbentlcal Family-Ether Reid Vapor Pressure (pda) ... ..llilllL
Vapor Pre&~ure 4Ci'C (ll!'F) (psJa) ... __.jjL
Pollution Category-USEPA - - - IMO __Q__ Vapor Denalty (Air = 1.0) ... _ll_
Appllable BuJk Rq. 46 CFR Subc:Upter .. . ... __Q__ SolubiUty iD Water .. Negljgj'p'ta

Gnule-C: Flammable liquid
Electrieal Group--O
Geuenl-Highly flammable, dangerous fire risk. Severe explosion risk when exposed to heat or !tame.
Flub Point ('F) .. -18 (cc)

Flammable Umib .. 1.410 21%
Autolpltion Temp. ("f) .. 630
Extlnplsblna; Aaentt ... Carbon dioxide, alcohol foam, water log, dry chemical
Speeial Fire Procedure~ .. Cool tanks with water spray. Keep surroundings cool to reduce the amounts
of vapors produced. The dangEif of reignition is high.
HEALTH HAZARD DATA

Healtb Hazard lb.tinp Odor Threshold (ppm) PEL/TWA (ppm) TLV1TWA (ppm)
1. 1,1 Unavailable 500 250
General- Toxic by ingestion and inhalation. Strong irr.tant. Prolonged or repeated skin contact may cause
dermatitis.
Symptom-Unavailable
Short Exposure Toterance-Animaltests showed 8000 ppm lor 4 hours resulted in a 0% death rate, a trace of
eye injury. and no skin irritation.
Exposure Procedures--Vapor-remove victim to fresh air; if breathing stops, administer artificial respiration. Skin
or eye contact-remove contaminated clothing and gently flush affected areas with water for 15 minutes.
REACTIVITY DATA
Stabtlity-ln presence of air, may form peroxide which will explode if heated, or on impact.
Compatibillty-Materiabi: Steel is not affected.

Wear rubber gloves, large heavy face shield (body shield if necessary). Have sell-contained breathing
apparatus available. Avoid contact with liquid. Secure ignition sources. Notify police, harbor master, and lire
department. Ether will float downstream or spread out and create severe fire hazard.
If a spill oeaan, call the National Rnponte Center, II00-4l4 81101,

Remarb:
262
PYRIDINE
Synonyms- Azabenzene: Azine United Nations Numbe!' ...
CHRIS Code ..
Fonnulf.-HCN(CH),
BoilinJ Point.. _____ill"C
Appearuw:e-Odor-Yellow to colorless liquid; c
nauseating, unpleasant odor Freezin1 Point. -42"C
Speclftc GraYity-0.98 c
Vapor Pranre 20'C (68'F) <mHJl..
Cbetnkal Family-Amine Reid Vapor Pre~~~~re (psia) ...
Vapor Preaure 4CI"C (115"F) (psia) ..
Pollution C.tegory-USEPA _____k__ IMO _____1L_ Vapur Deuity (Air = 1.0) ...
Applicable Bulk Re1. 46 CFR Subclupter ....... ____Q___ SolnbJIIty In Wlter ..

Electrical Groap-D
GeDerai-Highly toxic fumes given off upon decomposition. Fife hazard high, when exposed to heat or flame.
Explosion hazard severe, in the form of vapor, when exposed to flame Of spark. Flashback along vapor trail
may occur. Vapor may explode if ignited in an enclosed area.
Fladl Point ("F).. 68
Flammable Umlh .. 1.8 to 12.4%
Autolpition Temp. ("F') .. 900
Extinphlhln& Aseoc. ... Alcohol foam, dry chemical, CO.
Special Fire Procedures .. Keep tanks cool with water spray. Provide fire fighters with self-contained
bfeathing apparatus.
HEALTH HAZARD DATA

Health Hazard Ratlnp Odor Threshold (ppm) PEL/J'W A (ppm) TLV!TWA (ppal)
2, 2, 1 0.021 5 5
General-liquid mildly irritating to the skin and can be absol"bed through the skin. Vapor inhalation resuns in
slight irritation of airway with slight anaesthetic effect.
Sympto11111-Nausea, headache, insomnia, nervous symptoms, low back or abdominal discomfort.
Short Ell:po111re ToterllllCe-Very disagreeable odor at 30 ppm. Exposure averaging 125 ppm, four hours per day
for one to two weeks give rise to symptoms.
Expoaure Procedures-Vapor-remove from exposure, use artificial respiration if necessary, and obtain medical
attention. Skin contact-remove contaminated clothing and wash skin thoroughly with large amounts of
water. Eye contact-irrigate eyes with water for at least 15 minutes.
REACfiVITY DATA
Stability-Stable. Possibility of a dangerous reaction with acid anhydrides.
Compatibility-Material: Copper and its alloys and some synthetic rubbers are unsuitable.
Cargo: Group 9 of compatibility cnart.

If possible, wear boots, rubber gloves, rubber or plastic coat, and self-cootained breathing apparatus.
Extinguish sources of ignition. If possible, cover large spills with sand and soda ash mixture (90-10). Mix and
shovel into a carboard box.
If a spjll occurs, c:all the National R.,.._ Ceater, IIIJ0-4l4-810l.

Remarka: Vapor Pressure: 20 mmHg at 25"C.
263
ROSIN OIL
Synony1111- Codoil; Resin oil; Retinol: RoSinol United Natiou Number...
CHRIS Code ..
Formula-Mixture
Bolllq Polnt .. -
__c
c
~F
_ _ _ F
Appearuce-<Hor-White to bfown liquid with a piMtree
pitch odor Freezia& P!Nat .. ___j"C _ _ _ "F
Specltk Gra~lty-0.98 to 1.11 c _ _ _ "F
Vapor Preaure lO'C <68'FI <Ha). .. ....ll.ll.L
CltemlcaJ Family-Hydrocarbon mixture Reid Vapor Pr-re q.Ja) ... . _LmL._
Vapor PrNiure 46'C UU'F) (plla) .. -l!.1L
Pollution Cateaory-USEPA - - - IMO _____a__ Vapor Dnllty (Air = 1.0) ..... __ljf'._
Applleable Bulk Rea. 46 CFR Subdllapter ....... ----'2...Q_ SoiINIIty Ill Water ... Nag!lq!bla

Electrkal. Group-O
GeDenl-SHght fire hazard when exposed to heat or flame.
Flub Point ('F) " 255 to 390

FlaM-We u ..tu .. Unavailable
Autoipltlon T-p. ('F) .. 648
Extlnplltllna Aaenta .. Dry chemical, foam or CO.
Spedal Fire Prveed~ .. Water may be ineffective on fire.
HEALTH HAZARD DATA

Heald!. Huard Radnp Odor 'l'llrallold (pill") PEL/I'W A (ppm) nv!TWA <ppm>
General- TOKicity unavailable
Symptoms-Unavailable
Short Exponre Tolei'Uiee-Unavailable
Eli:potUre Proc:edur-Uoavailable
REACfiVITY DATA
StabUity-Stable.
Com.,.ttbUity-Mater:llll: Usual materials of construction are suitable.
c.rso: Group 33 of compatibility chart.

Wear rubber gloves, face shield and protective clothing. Secure ignition sources.
If a lpiU oeears, adl dte Natlmlal Rapoue enter, IIOO-tl4410l.

Remarka: t Unavailable
264
SODIUM CHLORATE SOLUTION, 50%
S)'llony...- Chlorate of soda; Soda chloric acid,
sodium salt
CHRIS Code ..
Formula-NaCI~
_____.lll!"C _____mF
c _ _ _.F
Appearanee-Odor-Yellow Hquid; Odorless
Free.diiJ Point... . ____1li"C ~F
c _ _ _ F
Specltk Gfal'lt)'-1.5
Vapor ~re ZO'C (61'JI) IINDHI) .. _!__
Chemie~;l Fa~~~lly- _!__
ReJd Vapor Pretare I,.Ul ...
v.,.... Pre.ure 4Ci'C (ll5'JI) (pU) ... _!__
Pollution CateaorJ-USEPA - - - IMO ___.lll_ Vapor Dealt)' lAir = 1.0) ... _!__
Applkable Ballr. Rea. 46 CFR Sabchapter ....... ____Q__ SolubWty Ia Water .. Sotyblt
FIRE ol: EXPWSION HAZARD DATA

Grade-Non-flammable. Classified as an oxidizer.
Eleetrlc:al Group-NA
ee.ent-Decomposes at high temperatures. Acts as an oxidizer. Not flammable but supports combustion.
Flula Polat ('F) ..

F1--ble UIU .. Non-flammable SOlutiOn
AlltolpltiOII T-.. ('F) ..
Eitlnpit!ltna Apna ...
Special Fire Procedllf'el .. Contact with organic substances, suHur, suHides, powdered metals,
phosphorous or ammonium compounds can cause fire and e)(J)Iosion. Sodium chlorate supplies its own
oxygen lor combustion. Usa copious amounts ol water.
HEALTH HAZARD DATA

Healtla t1uan1 Ratlllp Odor Dr'elllold ,,..) PEL/TWA (ppm) TI.V/TWA~)
Geaeral-lrritating to the skin and ayes. No hazard from vapors. Not absorbed through the skin.
Sfpt-lngestion results in abdominal pain, nausea, vomiting, and cyanosis.
Short Expoure Tolennce-LD.o for rats Is 1200 mg/kg. Ingestion of 15 to 30 grams may be fatal.
Expollll'fl Pnxedura-For ingestion induce vomiting if victim is conscious. Flush skin and eyes with large
amoonts of water.
REACI1VITY DATA
StliWHty-Stable, but product deComposes at 300F and liberates oxyven.
Compatfldllty-Malerial: Stainless steel or lined steel are preferred; carbon steel and aluminum are suitable lor
several years service.
Carao: Unal8igned in compatibUily chart. See alsO _ApPendix !-Exceptions to the Chart.

Coveralls and rubber boots should be worn. ClOthing becomes dangerouaty flammable when 80k8d with
chloratee:. Usa no leattler. Dried leather, such as shoes, become highly flammable In contact with sodium
chlofate. Secure an sowces of ignition. Flush spills or leaka with water. Do not let spill area dry until it has been
determined that there is no Chlorate left in the area.
If .,W OCCIIfat eaU die NlltloMI a.,.._ Caler, 100-424 IIO:Z.
ae-b: t Unavailable
265
SODIUM DICHROMATE SOLUTION, 70%
Synonyms- Sodium bichromate; Sodium bichromate United Natlollll Number ...
solution
CHRIS Code ..
Appearance-Odor-Clear, red-orange hquid; no odor

Boiling Point ..
Freezing Point ..
__lli"C
___ c
~c
___
~.,
~F
Specific Grnity-1.69 ___ c _ _ _ "F
Vapor Preau.re 20'C (68'F) (mmHg) ... _i_
Chemical Family-Oxidizer Reid Vapor PTesaure {plia)..... _i_
Vapor Preau.re 46'C (115'F.l lp~laJ .. _i_
Pollution Cate11ory-USEPA _ A _ IMO _____&.__ Vapor Dentity lAir = 1.0)... _i_
Applicable Bulk Reg. 46 CFR Subchapter ...... ~ Solubility In Water .. Compleffl

Grade-Non-flammable Classified as an oxidizet.
F.Jectrical Group-NA.
Gener~I-Non-llammable, but releases oxygen wnen heated. May ignite combustible materials upon contact.
Flash Point CF). Non-flammable

Flammable Limits .. Non-flammable
Autoignition Temp. ("F) Non-flammable
Extlnplshing A1enta. Non flammable
Special Fire P1'11Ct!dures .. Non flammable
HEALTH HAZARD DATA

Health Hazard Ratinp Odor Thre~~hold (ppm) PEL/TWA (ppm) TLV !TWA {ppal)
Unavailable Nooe-No odor 0.05 mg/m" as 0.05 mg/m as
chromium chromium
General-Even small quantities are highly toxic if ingested or absorbed through the skin. If heated to the boiling
po1nt wll generate toxic spray. Some allergic responses. May cause lung cancer.
Sy111pto111s-Contact-Extremely irritating to eyes and skin. Mist-Damage to miJCOUS membfanes, irritation to
respiratory system
Short t:xposure Toleranc..-Very irritating at low concentratioos of mist.
Exposure Procedures-Get medical attention. Skin-Flush witl"l soap and water for 15 minutes, remove
contaminated clothing. Eyes-Flush with water for at least 15 minutes. lngestion-Dfink a quart of water,
mduce vom1tting. If unconscioos, do not attempt to give victim liquids or attempt vomiting.
REACfiVITY DATA
Stability-Generally stable. Oxidizer reacts with reducing agents and many organics and inOfganics. May ignite
finely divided combustibles.
Co111patiblllty-Materlal: Suitable: Mild steel, stainless steel, aluminum. Unsuitable: Copper, zinc, tin, brass,
bronze, organic linings.
Carao: Unassigned in the compatibility chart. See Appendix 1-Exceptions to the Chart.

Avoid all contact, including breathing mists. Dike area, absorb on vermiculite or sartd, place in a sealed metal
container, dispose. Flush area with water. Don't allow into waterways. Wear protective clothing including
goggles, gloves, boots and, if mists present, resp~rator.
Re111arks: t unavailable
If pill occun, eall the Nticmal Rnpoo~~e Centu, 800-4l4-810l,
....
266
SODIUM HYDROSULFIDE SOLUTION, 45%
Synonym~- Sodium bisulfide; sodium hydrogen sulfide; United Nlti0111 NIDilber ...
Sodium mercaptan; Sodium sulfhydrate
CHRIS Code ..
-
Fonnllla-NaHS/N&c~SIH.O
BolliD& Point.. ~c _______2M"F
A~-Oark amber liquid with a rotten egg ___ c ___F
Freez1na Point... ~c
Speclne Grnlty-1.26 to 1.26
___ c ____lM'F
___.F
Vapor Prn.ure lO'C (68'F') {IIUIIHI).. ---lL.a...._
Chelllieal FamUy-Caustics Rdd Vapor Preuure (psla)... . ~
Vapor P..-an 46'C Ul!!'F) (pita).. ~
Polludoa Cateaoey-USEPA____Q__ IMQ.__JL_ Vapor Oe-'ty (Air = 1.0) ......................... ___1.lL_
Applk:ahle &.111. Rea, 46 CFR Subchapter ....... ____Q__ Solubility In Wlter.. Comgtata

G...--c: Flammable liquid
Elettrlcal. Group-NA
Geurai-Moderate fire hazard due to hydrogen sulfide, a poisonous, highly flammable gas liberated when
exposed to heat or flame.
....... Pot.t ('F) .. 73

Flanuullle LbnJD .. 4.310 45.5%
AulcNpiU. Tenq~, ('F) .. Unavailable
Extfqailldq Aeeab ... Carbon dioxide
S,edal Fire Pnleed- .. Wear self-contained breathing apparatus and protective clothing.
HEALTH HAZARD DATA

Heald~Huard Ratiap Odor 'I1Irahold (ppnt) PEL/TWA (ppm) TLV/TWA {ppnt)
Unavailable Unavailable' Unavailable Unavailable
GeDel'lii.-Poisonous hydrogen sulfide may be evolved; this evolutiOn increases with temperature. Solution itself
is a skin Irritant.
Sy.~apid Of Irregular breathing, coughing, throat irritation, bluish color, dizziness, faintness. and weak
irregular pulse. Skin contact will cause a caustic type burn.
Short Ezpollln! Toleruee-Unavailable
EJ:poare Proeed-Vapor-remove victim to fresh air. 100% oxygen inhalation is recommended. Skin-flush
area with water. Eyes-flush with copious amounts of water. In all cases call a doctor.
NOTE: The odor (rotten egg) of hydrogen su"lde gas should not be used as a warning, since its presence
may deaden 1he sense of smell.
REACJ1VITY DATA
Sbbllfty-5table. Solution is mHdly alkaHne.
Com,.ribWty-Material: Corrosive to steel above 150'F. Avoid use of aluminum.
Carao: Group 5 of compatibility chart. See also Appendix 1-EICceptloos to the Chart.

Wear rubber gloves, boola, and goggles, and lull skin protection. Avoid contact with liquid. Secure ignition
"""""''
If .,W ocan, tall tile Nadoul a.,._ Ceater, 800-4l4 1101.
267
SODIUM HYPOCHLORITE SOLUTION, 15%
Synonyms- Chlorox: Hypochlorite, solutions; Javelle United Nations Number ...
water; Liquid bleach: Sodium hypochlorite
CHRIS Code
Formula-NaOCI
_ _ _.. F
Boiling Point . ---c
Appurance-Odor-Green to yellow watery liquid; c _ _ _ "F
bleach1ng liquid odor Freezing Point -9'C ~F
c _ _ _ F
Specifte Grnity-1.21 to 1.24
Vapor Pre!lllure lO'C (68'F) (mmH&). _.:t_
Chemical Family-Caustic Reid Vapor Preaure (p!iia) ... _.:t_
Vapor Pressure 46"C (liS'FJ (psia) .. _.:t_
Pollution Cate10ry-USEPA ____a_ IMO _____Q__ Vapor Deatity (Air = 1.0) .. _.:t_
Applkable Bulk Reg. 44S CFR Subchapter ..... _5L_ Solubility In Water .. So!yb!e

Grade-Non-flammable. Classified as an oxidizer.
Electrical Group-NA.
General-May decompose in fire generating irntating chlorine gas. Containers may explode in lire due to
pressure buildup.
flub Point ('F) .. Nonflammable

Flammable Umlts .
Autolpitlon Temp. ('F) .. Not pertinent
Extinplthlng Agents. Water spray, fog, foam, dry chemical, co. or agents suitable for materials in
surroondillQ f1re.
Special Fire Procedures .. Cool tanks with water. Wear full protective clothing and self.contained
HEALTH HAZARD DATA

Health Huard Ratlnp Odor Threshold (pPm) PEL/TWA (ppm) nv /TWA (ppm)
General-Severe irritation, burns, and/or cOirosion from liquid. Vapor may cause severe respiratory tract
imtation and pulmonary edema
Symptoms-To)(icity and corrosivity depend upon concentration. Higher concentration of Industrial grades are
more damaging than concentration of household bleach (appro)(. 5.25% min.)
Short Exposure Tole111nce-
Exposure Procedures-It 1ngested. DO NOT INDUCE vomiting, give large quantities of milk. Skin or eye contact:
Flush areas with water lor 15 minutes and consult physician.
REACTIVITY DATA
Stability-Stable, but stab1lity decreases with concentrat1on, heat. light, decrease 10 pH and contamination by
metals. Strong o)(ldizer.
Compatibility-Material: Incompatible with steel, cast iron, 12 and 17% chrom1um steel, monel, mckel, inconel,
aluminum. brass, silicon, bronze

Wear rubber gloves and rubber safety shoes, goggles or lull face shield, and respiratory protection. Disperse
and !lush sp1!1ed or 1eak1ng material.
If a spill oceuriJ, eall the National Response Center, 800-4:Z4-880:Z.

Remarks: Decomposes above 110 C (230"FI.
t Unava1lable
268
SORBITOL
Syaony-- 0-GIIJCitol: LGulitol; UJdted Natlou Nanaber ...
1,2,3,4,5,6-Hexanehexol; Sorbicolan: Sorbit: Sorbo:
Sorbo!; Sorbostyl
CHRIS Code ..
Formllla-CHoOH(CHOH),CH,OH
BoWq Point.. ~c ___ 'F
Appearance-Odor-White, odorless crystalline powder c 'F
with a faint sweet taste. Freezbl& Polat... _____lli'!'C ---.23Q'F
Speclftc Graflty-1.49 at 150'C. (liquid) c ___ 'F
Vapor Preaure lO'C (68'F) <m~ .. ____LQw_
C'hembl Fanilly-Giycol Reid Vapor Preaure (pajl)..... __J,rm:_
Pollutto. c.tqory-USEPA--- IMO-___lll_

Applleahle BIIIJr. Rea. 46 CFR Subchapter ...... - - -
Vapor J>rw.IU'e 46'C (115'F) (ptla)...
Solabillty Ia W.ter ..
.....u-
Vapor DelllftJ" (Air = 1.0)..........................
____l.gyt_

Electrieal Group-O
GeDerai.-SIIght fire hazard II exposed to heat or flame
Flub Polat ('F) .. greater than 150

FlaaaUie Undts .. Unavailable
A.tolpltlon Tp. ('F) . Unavailable
Eitla.raillllq Aaentl .... Water
Speelal Fire Proc::edures ... Use water to cool life exposed tanks to avoid combustion.
HEALTH HAZARD DATA

Heald! lkzant RatiDp OdoT 1'brelltold (p~) PEL/IWA (lila) TLV lfW A (ppm)
Unavailable No"" Not pertinent Not pertinent
Gaeral-No threat of damage from vapor inhalation since the volatility of sorbitol is so low.
Sympt-tiot liquid will bum skin.
Short E:.:r:-re Toleruce-Not applicable.
EipoiW'e Procedures-Treat for bums resulting from contact with hot liquids.
REACTIVITY DATA
Stability-Stable.
Com.,.t!bWty-Materlal: Mild or stainless steel is acceptable.

Avoid contact with hot liquid. Wear goggles or face shield, protective clothing lor hot liquid. Stop discharge if
possible.
If a .,m oecun, ~ tbe Natfoaal Relpoale Ceater, 800-4Z44802.

Relnarb: " Unregulated, Table 2, 46 CFA Part 153.
.. Very soluble in hot water
t Unassigned
269
SOYBEAN OIL
Synony..,._ Chinese bean oil; Soyabean oil; Soy oil United Natiom Nuber ...
CHRIS Code ..
FormW.-Mixture
Bollbll PWat.. ~c _ _ "F
A~Odor-Pale yellow liquid; weak odor c 'F
Free.r.:lq Point.. -?O'C -4'F
S~lne Gra..tty-0.92 to 0.93 ___ c ---
Vapor PreAure lti'C (61'F) (mmll&) .. _..2.2L.
Cbemieal Fually-Esters Reltl V1por Preaure (piU)... __QJjL_
vapor Preallft .w;c <U5'Fl (pita).. ___QJL
Pollud1111 C.teaorr-USEPA - - - IMO ......1L_ Vapor Dellllty (Air = 1.0).. ____1:_
Applicable Bulk Rea, 46 CFR Subtbapter ....... _____Q__ Sol111Nilty In Water.. SUgbt

Electrieal Group-O
Geaerai.-Siight fire hazard when exposed to heat or flame.
Flqb Poillt ("FJ .. 540

Flanemable Limlb ..
Autoipidon. Te~~~p. ('F) ..
ExtiJigWb.iDII Apnb ..
.,
Unavailable
Dry chemical, foam or carbon dioxide

Special Fire Proeedut'el .. Water may be ineffective on fre. Cool exposed containers with water.
HEALTH HAZARD DATA

Health Huanl Rattnp Odor 'I'Iuwlaold (ppm) PEL/fWA (ppm) UVIIWA(Hm)
Ull8.vailable Not pertinent Not pertinent Not pertinent
General-Not harmful.
Symptoms-None
Short ~xpo~~ure Tolerance-Does not penetrate skin in harmful amounts.
Exposure Procedures-Non-toxic. Wash thoroughly with soap and water.
REAcrJVITY DATA
SUibllity-Stable.
Compatibillty-Mtlterla1: Usual materials of construction are suitable. Will soften some paints and rubber.
CaJ-ao: Group 34 of compatibility chart.

Wear rubber gloves, face shield and protective clothing. Secure all ignitiOn sources.
If 1 apjll 01X11r1o call die Natiollal RelpoMe ee.ter, 800-4l4-1110l.

ReiiUU"ks: :t: UnasSigned
270
SPERM OIL
Synonyms- Whale sperm oil U11lted Natiou Nuber...
OIRIS Code ..
---.,.,
Formula-Indefinite
-
Bollina: Point ... ~c
Appearuce-Odor-lighl yellow oily liquid; characteristic
Speelfh: Grarity-0.87 to 0.88

Freezlq Polat ...
c
____J"C
___ c ==F
___..
__2.Q_
Vapor Preuure 20'C (68'F> (mmH&) ...
Reid Vapor ~re (pillro! ... __Jl.1_
V1por Pnuure .M'C (115'F) ~ ...J!JL
Pollution C.tepry-USEPA - - - IMO _c.._ Vapor Dellll.ty (Air = l.ltL ..
ApPlkatllt Bulk Rea. 46 CFR SubeUpter ....... _c.._ Solubility In Water .. lnso!~

Electrkal: Groap-D
Gellerai-Siight fire hazard when exposed to heat or flame.
Flub. Point ('F) .. 428

F'IMullllhle LimJts .... Unavailable
Autoipitloa Ttlll(l. I'F).. ... 586
ExtiapW!lq Aaents ... Carbon dioxide, dry chemical
Spedal F1re Proceduret~ " . Water foam may cause frothing.
HEALTH HAZARD DATA

Heald! Hazard Ratl11p OdcN' Thresllo1d (ppm) PEL/TWA (Jipm) TLV!TWA (ppm)
General-Toxicity probably low. Details unavailable.
Short Exposure Tolera~~ce--Unavailable
Ellpotlln! ProcNuret-Fiush affected areas with plenty of water. wash thoroughly with soap and water.
REACfiVITY DATA
StabUity-Stable.
Comptibillty-Material: Usual materials of construction are suitable.
Cuao: Group 33 of compatibility chart

Wear rubber gloves, face shield and protective clothing.
H a lpill oceun, ctll llle Natfoaal Relpoate Cater, I00-4l4-1801.
Renwb: t Unav811able
*Unassigned
271
STYRENE MONOMER
Synonyms- Cinnamene; Cinnamol; Ethenytbenzene: United Natiom Nn111ber ...
Phenylethylene; Styrene; Styrol; Styrotene;
Vinylbenzene
CHRIS Code ..
Formula-C 0 H,CHCH,
Bollin& Point .. ~-c~F
AppearaJtceOdor-Colorless liquid; sweet odor when c 'F
J)tlre; sharp disagreeable odor when impure Freema Poiat .. -30'C -23'F
c ___ 'F
Specific: Gra-.ity-0.92
Va)IOI" ~re lO'C (68'F) (mmHa).... __M__
Cbeminl Fllmily--Otefin
Pollution C.teaory-USEPA ____Q__ IMO _.a__

Reid Vapor Pn.u.re (pllla) ....
Vapor Pnaure 46'C (ll5'F) (p~~la) ..
---=---
_M_
Vapor Detltity {Alr = 1.0) .... ___1L_
Applicable Bulk Rea;. 46 CFR Subehapter ..... __Q__ Solubility in Water .. Neg!jglt!!e
F1RE & EXPLOSION HAZARD DATA

Eleetrial Group-O
General-Ignited by heat and open flame. Fire or contamination may cause violent rupture of tank.
flqb Point ('F). 100

Flammable LimibJ .. 1.1 to 6.1%
Autolpltioo Tep. ('F) .. 914
EitinRUisllin& A~mu .. co,, dry chemical, water fog, loam
Special Flre Proeeclures . Avoid breathing vapors. Provide body and respiratory protection. Keep tanks
cool with water spray.
HEALTH HAZARD DATA

Health Haurd Ratings Odor 1'hraboJd (ppm) PEL/TWA (ppm) nvrrwA <ppm>
2, 2.2 0.15 50 50/Skin
General-Suspected carcmogen. Vapor very irritating to eyes, moderately irritating to respiratory tract with
moderate systemic effect. Liquid irritating to skin.
Symptoms-Weakness, diz:zmess. nausea. and sleepiness.
Short EltJ!OfJure Tolerance-10,000 ppm may be fatal in 30 to 60 mmutes.
EltJ)(t!Jure Procedures-Vapors-remove vicf1m to fresh air; if breathing stops, apply artificial respiration. Skin or
eye contact-remove contaminated clothing and gently flush affected areas with water for 15 minutes.
Soap, 1f available, should be used on affected skin areas. Get medical attention.
REACTIVITY DATA
St11billty-W~I readily form peroxides which catalyze polymerization unless inhibited. Heat. ltght, and strong
acids also catalyze polymerization reaction.
CompatlbiHty-Material: Most materials of construction are suitable. Do not use copper or its alloys. Styrene
can be polymerized at explosive rates by certa1n contaminants.

Wear rubber gloves, face shield, protective clothing. Have all-purpose camster mask available. Avoid contact
w1th hqu1d. Secure ignition sources.
If a 'fill oceun, call the National. llelpo.e Center, 800 4l4 IIKll.
Remarks: Even the 1nh1brted product, when healed above 125 F, can polymerize with the generation of so
much heat that ignition is possible.
272
SULFUR (molten)
Synony-- Brimstone; Sulfur; Sulphur United Natm. Number ... molten
""~
CHRIS Code ..
Formula-S
Appearanu-Odor-Yellow-to-bfown solid; amber liquid BoUina Pobat... ~c ______32'F
above 238'F; sharp choking SO. hJmes usually c 'F
FreeziK Polat.. __j,H'C 238'F
"'""'"'
Specific GraYity-1.80 at 265'F (liquid); density ol solid
sulfur is 2.07 glee
___ c ___ 'F
Vapor Pre.ure lO'C (68'F) 1-H&).... ~
Chemical FamUy-Element Reid Vapor Pre.ure lplia)... ...Y....l.2tL
Vapor Pralure 46'C (ll!I'FJ (,-.)... ~
Pollutloa Catepy-USEPA - - - IMO _.J1L_ V.,or Dnlllty (Air = 1.0) ...
AppUcabte BuJk Jles, 46 CFR Subcbapter ....... ____Q__ SolubiUty b1 Water.. Nagiiijibj@

Grade-E: Combustible liquid (when carried in mohen state)
Eleetl'ical GrOUip-C
General-Sulfur in the mohen state gives off hydrogen sulfide (HoS) gas, which is poisonous and highly
flammable. The rate of gas evolution depends on conditiOns, particularly the amount of hydrocarbon
impurities present.
Flub Point ('F) .. 335 to 370
Flam-ble Umta .. Unavailable
Autolp.ition Temp. (F) .. 374 to 428
Extlaphlhing AI]OU .. COa, dry chemical. steam, water tog
Special Fire Proeedures ... Do not direct a solid stream of water into burning liquid sulfur or a steam
explosion may result. When sulfur bums, sulfur dioxide (SO.) is given off. This gas is highly toxic, so
firelighting personnel must be provided with respiratory protection.
HEALTH HAZARD DATA

Healtll Huard IW.Iap Odor Tbres~ld (ppm) PEL/I'W A (ppm) TLV tTW A (ppm.)
1,1, 1 TLV for H,:S, 10 TLV for H,S, 10
General-Liquid causes severe thermal bums. TLV for SO., 2 TLV lor SO., 2
Gas is poisonous by inhalation.
SymptoJn.--HoS-headache, nausea, dizziness: loss of sense of smell. SQ.-severe eye and respiratory
Irritation.
Short E~:posure Toleraaee-200 ppm lor 10 minutes. 100 ppm for 30 minutes. 50 ppm for one hour.
Ex!IO'ure Procedura--Remove victim to fresh air. If breathing stops, apply artificial respiration. Oxygen,
administered by trained personnel, is often helpful. Body contact with hot liquid sulfur can cause severe
scalding. Do not try to remove the solidified sulfur from such a burn. Get medical attention.
"NOTE: Odor alone does not give adequate warning of dangerous H,S concentrations.
REACTIVITY DATA
Stability-Stable except in contact with oxidizing agents or reactive metals. The rate of H.S gas evolution from
moften sulfur increases with agitation.
Compatlbutty-M.terlal: Liquid sulfur is not corrosive to steel, but corrodes copper and its alloys. Moist sulfur is
corrosive to steel.
Carp: Unassigned in compatibility chart.

Avoid contact with hot liquid. Wear heavy work gloves, goggles or lace ~laid, protective clothing for hot
liquid. Have self-contained breathing apparatus available. Secure Ignition sources. A major spill of liquid sulfur
into navigable waters will solidify and sink, presenting no unusual hazards.
U a ipiU oeevn, eall the Nadoul. Rapoue Ceater, 800-4~
Remarb: See 46 CFR 36-Eievated Temperature Cargoes.
273
SULFUR DIOXIDE
Synoaym- Sulfur dioxide, liquefied: Sulfurous United Nati01111 NuMber ...
anhydride: Sulfurous oxide
CHRIS Code.
Formula-~
8ollia1 PoilU.. --=..l.Q'C -----ti'F
Appeat11Dc:e-Odor-Compressed liquefied gas with sharp c 'F
irritating odor. Freezi11 Point.. -ZS'C ----=-w4"F
Spectne Grarity-1.45 (at -10'C) ___ c ---
Vapor Pralure 20'C (68'F) <HI) .. . ~
Chemieal Family-Acid anhydride ReW Vapor PrNIW'e (pita)...... -.M.._
Vapor Preu~~q <N'C (115'F) (plia).. ___j.2L._
Pollution Catepry-USEPA - - - IMO .......Jilll_ Vapor Deaelty (Air = 1.0)..... .......2.2.....
Applit'llble Bulk Rea. <M CFR Subc... pter ....... _Q__ SelubUIIy Ill W.ter ..

Grade-liquefied Compressed Gas (LCG)
Electrical Group-NA
General-Non-flammable, but in a lire, tanks may rupture and release irritating, toxic sulfur dioxide.
Flash Point ('F) .. Non-flammable

Flammable Limits. Non-flammable
Autolpition Temp. ('F) .. Non-flammable
Extinplsbina Agents Non-flammable
Spedal Fire Procedure& .. Cool exposed tanks with water. Wear eye protection and sell-contained
HEALTH HAZARD DATA

HWtb Hu.ar4 Ratinp Odor Threshold (ppm) PEL/TWA (ppm) TLV!TWA (p,_)
4, 1, 4
' 2 2
Geneni-Liquid can cause frostbite. Vapor is very irritating to the eyes and lungs even at low concentrations.
Sy111ptoma--Vapor-causes irritation of eyes and lungs with severe choking. Liquid will cause frostbite.
Short Exposure Toleranee-20 ppm for 5 minutes.
F,xposure Proced.uru-Vapor-remove victim to fresh air. Administer oxygen if possible. Skin-flush skin with
water. Eyes-wash with water for 15 minutes. If the liquid has spilled onto the skin, points of contact may
be frostbitten; handle gently and protect from mechanical damage. DO NOT RUB. Get medical attention.
REAcriVITY DATA
Stability-Reacts with water to form sulfuroos acid, HaSO..
Compatibility-Material: The acidic reaction with water corrodes aluminum and some other metals.
<:arao: Unassigned in compatibility chart. For compatibility assistance, call

G-MTH-1 (202-267-1577).

Wear rubber gloves, eye protection, self-contained breathing apparatus, and protective clothing. Try to shut
off teak.
If a lpfU occun, call die Natioaal Reapoaae ee.ter, 1100-4l4-880l.

Re-.-b: Reacts with water to form sulfurous aCid, HaSO..
274
SULFURIC ACID
SynonyiDI- Batt8f)' acid; Chamber acid; Fetilizer acid; United Natiou Number ...
Oil of vitriol
CHRIS Code ..
Fonnula-H.so.
BolltnaPoiDt.. ~c ~F
Appearanee-Odor-Colorless-to-brown oily liquid; no c 'F
odor unless hot, then the odor is choking Freezlna Poilat..... _____l.Q'C ~F
Speclftc Grnlty-1.56 to 1.84 ___ c ---
V~qt~~r Pr!$1ure ZO'C (68'F) (,....H&) .. ____l.2tt_
Cbemleal Family-Inorganic acid Reid Vapor PTe.l&re (pllia)... ____l.!m_
Vapor Preuure 46'C U15'F) (plia)... ~
PoUvtlon Cateaory-USEPA __Q__ IMO ____Q__ Vapor De:lty <Air = 1.0)... ~
AppUable Bulk Reg. 46 CFR Subehapter ....... ____Q__ SolubUity In Wlter.. Cgmc!ete

G~on-llammable. Classified as a corrosive liquid.
Electrlc:al Group-B (based upon possible hydrogen gas (H.) generation should a leak or spill occur)
General-Sulfuric acld will not bum. It will react with many metals, giving off hydrogen gas which is highly
flammable. If hydrogen is trapped in confined spaces, it can form an explosive mixture with air. See data
sheet for hydrogen.
F1ub Point ('F) .. Non-flammable
FbuniQble Uit. .. Non-flammable
Allloipjtlon Tea~p. ('F) .. Non-flammable
Eitl~~pilhl111 Aaent. .. Non-flammable
Special Fire Proeectura .. DO NOT USE WATEA to put out a fire if the water can get into concentrated
sulfuric acid. In case of a lire next to a sulfuric acid tank, use respiratory protection against fumes.
HEALTH HAZARD DATA

Healtb Hazant Ratlnp Odor 'I'hrelllold (ppm) PEL/TWA (ppm) TLVJTWA (ppla)
2, 4, 2 Greater than t mg/m 3 1 mgtm 1 mg/m 1
Geauai-Liquid causes severe bums with destruction of tissue. Vapor very irritating.
Symptoms-The inhalation hazard is slight at ordinary temperatures. The sltin on which acid is spilled may feel
hot or it may sting or itch.
Sbort Exposure Tolenuu:e-10 mg/m' lor 5 minutes; 5 mglm' for 10 minutes; 2 mg/m' for ,30 minutes.
Exposure Protelbara-Drench with water. Remove contaminated clothing and flow water onto affected area lor
15 minutes. For eye contact, immediately flush eye with large amounts of water for 15 minutes. Get medical
attention.
REAcrJVITY DATA
Stability-Stable, but can react very easily with many other materials.
Compatibility-Material: Highly corrosive to most metals; particularly at concentrations below 60'Be. May cause
wood or cellulose to ignite.

Wear rubber gloves, self-contained breathing apparatus, protective clothing. Have body shield available. Avoid
contact with liquid. Secure ignition sources because of the possibility of hydrogen gas generation. If possible,
cover spill with sodium bicarbonate or soda ash-slaked lime mixture (50-50). Mix and add water to form a slurry.
Scoop up slurry. Wash site with soda ash solution. Otherwise flush cautiously with water. Avoid directing stream
into larger pools or pockets of concentrated acid.
If a .,W oecurt. alll tbe NHioaal Re1poue Cnter, 100-tU--81102,
Remarks: CAUTION-Never add water to the acid, otherw~se spattenng w1ll occur. If dilution Is req~.~~red, always
add the acid very carefully to the water. The acid Is heavier than water. Thus, the heat of solution will be
more uniformly dissipated, and spattering will be avoided.
275
TALL OIL
Ulllted NMIOIQI NUJber ..
CHRIS Code .....
F-llla-Mixture of rosin acids
Appeuuee-Odor-Yallow, oily liq!.id; acrid odor

BoW.,PWIIt.....
___ c ___
~c F
___.,
Freezl& hlllt ....................... _____j'C _ _ _"F
Speelfk Gra'fity-0.95 to 1.00 ___ c ---
v.,.. ~re lO'C t68'F> {.aunHI) .. --1..L....
a.-M:.J Fandly- Reid Vapor Pr_.-e (pila)... .. ............ .........Q..1..
V.,or ~ 46'C (115'F) (pila) ............ ~
Poli.UO. Catqory-USEPA - - - IMO ___a_ Vapor l>enltt)' (AJr - 1.0).......................... ____Me__
Applbble Bulk Rec. 46 CFR S.k:bapter ....... ---'2.....Q._ SolaiNUty ba Water .. Neg!jgibf!

Gr.le-E: Combustible liquid
Eledrlcal Groap-0
GeaeraJ-SIIght fire hazard when exposed to heal or flame.
Flalll I"Wnt ('F) .. 380

FlaaaUie Ualtl .. UnavaWable
Alltolpld011 y_,, ('Fl .. Unavailable
Estblpllllilll Aeem ..... Foam, dry chemical or CO.
Spedal Flre Proeed- .. Water may be ineffectlya on fire. Use water to cool exposed tanks.
HEALm HAZARD DATA

He.l.di Huard Ratlap Mor 11uabold ,..,..) PEL/TWA <pp.ll TLVITWA <pp.ll
Unavailable UnavaNable Unavailable Unavailable
Geaerai-Avoid contact with liquid.
Sfll\pto!M-Skin contact will cause minor reddening.
Sllort Expopre Tolennee-Not pertinent
Elt.-ure Proeechrs-Skin-flush affected areas with plenty of water: wash thoroughly with soap and water.
REACfiVITY DATA
St0illty-5table.
C:O.patiiNUty-Matert.l: Usual materials ol construction are suitable.
Car)o: Group ~ ol compatibNity chart.

Wear butyl rubber gloves, lace shield and protective clothing.
If a "'II occurs, calllk NIU.._. ......... C..ler, I00-4l441Ql,

Re.arka: t Unavailable
*
Unassigned
276
TALLOW
Syaoay--Edible tallow; ined'ble tallow; Tallow oil
CHRIS Code ..
Formula-fats containing C,. to c,.

Boillna Point.. . . __Y.._l:llgb'C _ _ _.,
Appearance-Odor-Dark yellow liquid with a waxy odor
___ c ___.,
Freezin1 Polllt... __l'C ~F
Spedftc Grarity-0.85 to 0.89 at 70'C
___ c ___.,
Vapor Pre.ure 29'C (68'FJ (mmHg) .. ____2.lL_
Cltemleal FamUy-Esters Reid Vapor Prasurt (IJIIIa).... _2.,1___
Vapor Preaure ik!i'C lll!I'FJ lplbi).. ____2.L.
Pollution C.teaorY-VSEPA - - - IMO __Q_ Vapor DeJIIIty (Air = 1.0)... . ............... ____Hf__
AppUcUie Blllk Rq. 46 CFR Subdlllpter ....... _____1L__ SoiMINIIty ln Water.. . Nagljcjble

G..--E: Combustible liquid
Eleetrkal Group-O
General-Slight fire hazard when exposed to heat or flame.
Flub Polnl ('F) .. 509

Flaln..we Ultl .. Unavailable
Autoipttloa T em,_ ('F) .. Unavailable
E:dlquisb.hl& Apntl ... Foam, water, CO., or dry chemical
Special Fire Procedlll'ell .. Water may be ineffective. Cool exposed containers with water.
HEALTH HAZARD DATA

Health Hazan! Ratbap Odor Threellold (ppm) PEL/I'W A (ppm) TLV/1WA (ppm)
Not pertinent Unavailable Not pertinent Not pertinent
<>-a~-Non-toxic, but possibility of thermal burns from hot liquid.
S,..,con.-Non-toxic.
Short Exponre Tolerance-Hot liquid can bum eyes and skin.
Esponre Proeedura- Treat buns caused by hot liquid.
REACfiVITY DATA
StUillty-Stable.
ColllpatiiHUty-Mtierial:

Wear rubber gloves, face shield and protective clothing for hot liquid.
If a .,UI occun, calllbe ~ ....... Ceater, ~

a-t.: +Unassigned
277
1, 1,2,2TETRACHLOROETHANE
SynoayiiUI-Acetylene tetrachloride; Ethane,
1,1,2,2-tetrachloro-; Tetrachloroethane:
sym- Tetrachloroettlane
CHRIS Code ..
Formula-CI,CHCHCI,
Bollin& Point .. ---.H'C __mF
Appearuce-Odor-Ciear to slightly yellow liquid with
___ c _ _ _F
chloroform-like odor Freezln1 Point ... ___;;;:M'C ~F
___ c _ _ _ "F
Vapor PreMure Z9'C <68'F) (mmH&). __l1,L
Cltell'lic:.l Family-Halogenated hydrOCarbons Reid Vapor PrMUre (JII.Ia) .. __.II.L_
Vapor Pressure 46'C (115'Fl (ptia) .. ......l.lL
Pollution Cateaory-USEPA _____a_ IMO _____a_ Vapor Dentl.ty (Alr = 1.0) .. _M_
Applicable Bulk Rq. 46 CFR S.bcbaptu ....... ___Q_ SolultUity iD Water .. $!i9ht

Grade-Non-flammable
Electrical Group-NA
General-Non-flammable, corrosive liQuid. When heated, it emits highly toxic decomposition products.
fluh Point ("F) Non-flammable

flammable Limits .. Non-flammable
Autoipltlon Temp. ('F) .. Non-flammable
Extinguishina Agents. Non-flammable
Special Fire Procedures .. Wear self-contained breathing apparatus.
HEALTH HAZARD DATA

Health Huard Rlltinp Odor Threshold (ppm) PEL/TWA (ppm) TLV/'IW A (ppm)
Unavailable 0.5 1/Skin 1/Skin
General-Suspected carcinogen. A powerfi.J narcotic and r1ver poison.
Sympto~~t~-lngestion-vomiting, diarrhea. Acute intoxication with unconsciousness, cyanosis, loss of reflexes

and death. Inhalation-can be absorbed by lungs. Fatal after repeated inhalation.
Short Expo;~~~ure Toleranc:e-1 0 ppm for 30 minutes.
Expo;~~~ure
Procedures-Inhalation-remove to fresh air and, if necessary, administer artificial res~tion.
Ingestion-induce vomiting. Eyes-flush with water for 15 minutes. Skin-remove clothing and wash skin
with soap and warm water. In all cases call a doctor.
REACTIVITY DATA
Stability-Stable.
Comp~tibility-Materlalll: May attack some forms of plastics.
Carao: Group 36 of compatib~ity dlart.

Wear rubber gloves, self-contained breathing apparatus and protective clothing. Secure all sources of ignition.
Absorb with vermiculite and clean up. Wash site with soap and water.
U a 1p6U Otcllll, WI tlte NatiOIJII] lletponte Center, 800-414 880l.
278
TETRAETHYLENE GLYCOL
Synonyms- bis[2-(2-Hydroxyethoxy)ethyl]ether; TEG; United Nldo1111 Number ...
3,6,9-TrioKaundecanol, 11-diol
CHRIS Code ..
Formula-HO(C.H.O).C.H.OH
Bollina Point.... ___ azrc ~F
Appearanee-Odor-Colorless to pale-straw colored c F
liquid; sweet odor FreezJa11 Polld.. -sc -21"F
Spednc Grarity-1.13 c ___ F
Vapor Pre.u" lO"C (68"F) (mHJ) ... . ~
Chemical Family-Glycol ether Reid Vapor Pre.ure (pN)... ~
Vapor Preuure 46"C (115"F) (ptla).. ~
Pollutlm~ Cateaory-USEPA-___ IMO-___l!L_ Vapor OeD.Ity (Air = 1.0)......................... ___.L_,
AppHcable B11lk Res. 46 CFR Sabclupter ....... ___Q__ Soh1blllty 1ft WateT.. CorM!ttt

Electrical Group-C
General-Slight fire hazard when eKposed to heat or flame.
Flub Pot.t ("F) .. 345

FIIIIUIIal!le Limits .... Unavailable
Autoipidoa Temp. (F) .. Unavailable
Extblpislala& A,ots .. Alcohol foam, CO., water, dry chemical
Special Fi" Procedlll'e& ..... Water may cause frothing. Cool exposed tanks with water.
HEALTH HAZARD DATA

Heald! Hazard Ratlap Odor 'Illrabold (ppm) PELITW A (ppm) TLV/TWA (ppm)
General-Low to no toxicity; no skin, ingestive or inhalation effects.
Sympto.s-Unavailable
Short Exposure Tolerance-Unavailable
Exposure Proeedul'n-Vapor-remove victim to fresh air. Skin or eye contact-remove contaminated clothing
REACTIVITY DATA
Stability-No spontaneous decomposition, not dangerously reactive.
Compatibility-Material: Steel or stainless steel recommended.

Avoid contact with liquid. Secure Ignition sources.
If a lpi]l oee--. aill tbe Natloaal ~ Cea.teT, 800-4l4-880l.

Relllll'b: + Unasstgned
279
TETRAETHLYENE PENTAMINE
Synonynss-1,11-Diamino-3,6,9-triazaundecane United Nations Number ..
CHRIS Code ..
Fonnula-NH,(CH,CH,NH).CH,CH,NH,
Boiling Point. ~c ______jbil"F
AppeallUice-Odor-V'Iscous liquid; amne odor
c ___.,
Freez.ln11 Point.. -30"C ~F
Spedflc Grnlty-1.00 c ___.,
Vapor Pressure 20"C (68"F) (mmHg) .. . ____LQw_
O.emical Family-Amine Reid Vapor Preaure (psia)... ~
Vapor Preaure 46"C (ll5"F) (psia). ~
Pollution Category-USEPA - - - IMO _____Q__ Vapor l>eJiaUy (Air = I.OJ ........................ ~
Applieahle Bulk Re11. 46 CFR Subchapter ,__ ... __.Q.__ Solubility in Water.... Aoprecjable

Elec"trial Group-C
General-When heated to decomposition. 1! emits toxic fumes of nitrogen compounds.
flash Point ("F). 325

Flammable Umlts .. Unavailable
Autolp!tion Temp. ("F) .. 572
Extlnplshing Agents. CO., dry chemical, alcohol foam
Special Fire Procedures .. Firefighters should wear full-protective clothing and self-contained breathing
apparatus
HEALTH HAZARD DATA

Health Huard Ratings Odor Threshold (ppm) PEL/TWA (ppm) TL V JTW A (ppm)
General-Liquid causes severe eye and skin burns
Symptoms-Burnmg eyes and skm
Short Exposure Tolenonce-An 8 hour exposure to a saturated vapor-air m1xture caused no deaths.
Exposure Procedures-Skin or eye contact. Remove contaminated clothing and gently flush affected areas with
water for 15 minutes. Get medical attention as soon as possible.
REACTIVITY DATA
StabUity-Stable.
Compatibility-Material: Avoid copper and copper alloys.

!I possible, wear butyl rubber gloves. face shield or all-purpose canister respirator, Pfotectllle clothing. If
possible cover spill with sod1um bisulfate. Spray with water and wash up.
If 1 spill occurs. call the National Response Cellter, 800-4Z4-880l.
Remarks:
280
TETRAHYDROFURAN
s,._,.._ Dlethy1ene oxide; Furan, tetrahyclro-; ....2!!iL
Tatramethylene oxide; THF
CHRIS Code ......................
........... ........ ___ji'C ~F

tppe1 au Ollar Colorless liquid; ether-like odor
Spedlle Gnrity--0.89
............. ......
c
_-1Q8"C
'F
_ c _-lH"F
_F
Vapor PI'-. lO'C (61'P) <-lfl) .......... __l.!2..._
a-deal Fa.lly-Etnar Reid v., ~(pita)........................... ....J.L..
VqiOI' m-an 46'C (115'F) (plia) ............. __8.5._
PoU.uc. Cateaorf-USEPA ____&.._ IMO ____.ll_ Vapor De!111tJ Wr - LO).... . ....... ....J.aL_
Appllalde 8tllk Rea. 46 CFR Sube!aaptw ....... _____Q_ SoblbflltJ" m wmr ........... . Amrec:ieble

,_.,..........,
~ flre hazard: moderate explosion hazard. Flashback along vapor trail may occur. VllfKJ( may
explode if ignited In an enclosed area.
--
FbM Pomt rFJ .............. 6
~u.dtl ... ..................... 2.0 to 11.8%
A'Atoipldoa Temp. ('F) ............... 610
.......... CO.,
dry chemical, alcohol foem, water spray.
Spedal Fire Procedanl .. Gives off toxic fumes when heated. Provide respiratory protection for
firefighters. Water may be ineffective.
............. ...._
Unavailable 400"
HEALTH HAZARD DATA
Odor 11lrelbold (.,m) PEL/TWA-
200
nvIJ'WA w->
200
~-Uquid Irritating on contact Vapor inhalation causes aevere irritatiOn of mucous rnembrann wiltl strong
narcotic action resulting in severe headache and drowsiness.
~Irritation of eyes and mucous membranes; headache or drowsiness.
Sllort Eipoeare Toleruee-500 ppm for 30 minutes.
Ea,...re ~Vapor-remove victim to fre8h air; If breathing stops, apply artlfici8J reepiration. Skin or
eye ~-remove conte.mlnated clothing and gently fluSh affected areas with water for 15 minutes. Get
medical advice or attention. Exposure to a potentially dangerous vapor concenb'atlon can occur before the
product is detected by smell.
REACJIVITY DATA
sa.IIIIII)'-May fonn explosive peroxides upon storage or exposure to light Should be stabllzed to prevent
peroxide formation.
~-MaterW: This compound dissolves rubber.
c.rao: Group 41 of compatllility chart

Wear polyethylene glOves, protective clothing and face Shield. Have all.purpose cani&t.- muk avdable.
u ..... OCCIII'I, all tile Nauo.I . . , _ c-ter, 100-424 11111.2

a - D NOTE: Detectable odor is greeter than the TLV. Exposure to a potentially dangerous vapor
COl...., ib alioi can occur before the product is detacted by smell.
281
TETRAHYDRONAPHTHALENE
Synony-1 ,2,3,4-Tetrahydronaphthalene; Tetra! in; United Nations Number ...
Tetraline; Tetramp; Tetranap
CHRIS Code ..
Boiling Point. --ZQ'C --4QZ'F

AppearaDee-Odor-Colorless liQuid; odor similar to
___ c ___ 'F
Freezing Point .. ,.. ~c
turpentine
___ c ------=.ll'F
___'F
Vapor Pressure lO'C (68'F) (mmHK). ~
OleJnicaJ Family-Aromatic hydrocarbons Reid Vapor Preaure (,.Ia).. __Q.Q2_
Vapor Preuure .tfi'C (11.5'Fl <.-ial. ~
Polluti011 Calqory-USEPA - - - IMO ~ Vapor o-..ity (Air = 1.0)... ~
Applkable Bulk Rea. 46 CFR Subchapter ........ __Q._Q_ Solubility In Water.. lngluble

Gnde-E: Combustible liQuid
Electriea1 Group-O
Ge.eral-Moderate lire hazard when exposed to heat or !lame.
Flash Point ('F) .... 172

FlanunabJe Umltll .. LEL=O.B%, at 100'C. UEL=5.0%, at 150'C.
Autalpitlon Temp, ('F). 722
Extlngultbiq Agents .. Foam, carbon dioxide, dry chemical
Special Fire Procedure~J .. Water may be ineffective on fire.
HEALTH HAZARD DATA

Health Hazard Ratlnp Odor lbrelitold (ppm) PEL/TWA (ppm) TI..V fTW A (ppm)
General-Vapor irritating at high concentrations.
SymptomiJ-Vapor causes headache, vomiting, eye irritation, and coughing. Skin contact is irritating.
Short Exposure Toleran(e-Unavailable
Expoaure Procedures-lngesflon-lnduce vomiting. Vapor-remove victim to fresh air: if breathing stops, apply
artificial respiration. Skin or eye contact-Jemove contaminated clothing and gently flush affected areas with
water for 15 minutes. Get medical advice or attention.
REACI'IVITY DATA
St.lbillty-Fairly stable but will, however, polymBfize and OKidize giving rise to discoloration and resinous
material
ComjNitibtlity-M~~terill: Some nbber and plastics unsuitable.
Carto: Group 32 of compatibility chart.

Wear polyethylene gloves, lace shield, protective clothing. Have all-purpose canister mask available. Avoid
If a 1pW octura, eall tbe National Retponse Cellter, 800-4~1.

Remarkl: *Pollution Category C o1l-flke, 33 CFR 151.49.
+
Unassigned
282
TOLUENE
Synony- Benzene, methyl-; Methacide; Ualted NatioM N111Dber ...
Methylbenzene; Methylbenzol; Phenylmethane:
Toluol
CHRIS Code ..
Bolllq Polat.. ______lll'C _____2.31'F

Appearance-Odor-Colorless liquid; benzene-like odor ___ c ---
Freez~Da Poblt ... ---=.i5'C -=.lD'F
___ c ---
VltfOl' Plwnre lO'C (61'F> <mmHI) ..
Clle..tul F...Uy-Aromatic hydrocarbon ReW Vapor Preaure (plla)........ ___l.l__
VllfOrPr-.are 46'C 1115'FJ (,.Ill)... . ~
Pollutloa c.tqory-USEPA-_____..c.._ IMO-_&:.._ Vapor Deultf CAJr .. 1.0) ......................... .....1.1!.....
Applkable Bulk Res. 46 CFR S.bcbapter ........ -'2.....Q_ Sol11b1Hty Ill Water.. NtcJ!Ig!bla

Grade-C: Flammable Wquid
Eleetrkal. Group-O
Gelteni.-Dangeroua life hazard when exposed to heat or flame: moderate explosion hazard when exposed to
flame .
..,..... PoiJI.t ('F) .. 45

FJa...ble IJaitl " 1.27 to 7.0%
Alltoipltloa T-.. ('F) .. 1026
Estiapilldq Apall ... COt, dry chemical, foam, water fog
Spedal Fire Proeed- .. Fight the same as a petroleum fire. The vapors are more toldc than those of
petroleum and should be avoided. A fife should be fought in the same manner as any Grade C flammable
petroleum product
HEALTH HAZARD DATA

Hellltt. Huanl Radnp Odor 'l'llrelbold (ppnl) PEL/IWA (ppm) TLVll'WA {Jfm)
1, 1, 2 0.17 100 100
Geaeral-Uquid slightly irritating, Vapor inhalation has moderate narcotic effect causing dizziness and headache,
with sevef8 fatigue and mental confusion.
Sy.lpt_._Nausea, dizziness and headache. The victim may appear to be drunk.
Short Expo~~~re Toleruce-lnhalation of 600 ppm for 30 minutes has caused severe fatigue, meotal confusion,
nausea. dizziness and headache.
Expollll"e Proced.r-lngestion-do NOT induce vomiting. Vapor-remove victim to fre8h air; If breathing stops,
apply artificial respiration. Sl<ln or eye contact-remove contaminated clothing and genUy flush affected
areas with water for 15 minutes. Get medical advice or attention.
REACI1VITY DATA
StiiWIIty-Stable.
Compatibillt)'-Milterial: Rubber exposed to toluene will swell, soften, and deteriorate. Most metals are
compatible with toluene.
SPIU. OR LEAK PROCEDURE

Wear plastic gloves, lace shield, protective clothing. Have all..purpoae canister mask available. Avoid contact
If I .,ill oec-n, adl tile NildoMia.,._ Ceallr, 800-4l4-110l.

Remub: *Pollution Category C od-l1ke, 33 CFA 151.49.
*" Vapor Pressure: 28 mmHg at 25"C.
283
TOLUENEDIAMINE
Sy-ymt- Benzenediamine, ar-methyl-; United N1tloa Number...
2,4-0iaminotoluene; 2,4-Tolamine;
2,4-Toluenediamine; 4-m-To!uenediamine;
m-Toluenediamine; Tolylenediamine:
2,4- Tolylened~amine; m- Tolylenedlamine CHRIS Code.
Bollin& Point .. ______mc

Appeal1Uice-Odor-Color1ess crystals; ammonia-like ___ c
odo Freezln& Point .. ___ wrc
___ c
Specific G1'11ity-Unavailable
Vpor Preuure ;wc (68"FJ (mmH8),
Claelcal Flly-Aromatic amines Reid V1por Preuure (psia) .. __!__
V1por Preuurr 46'C (liS'F) (pt!a) .. __!__
Pollutloa CateiJOI')'-USEPA ___A_ IMO ____c__ V1por Deas.Jty lAir = 1.0) .. __!__
Appllable B11lk Re&. 46 CFR Subchapter ...... _Q__ SolubUity in W1ter .. Solyb!e

Eleetrical Group-NA
GeDeraJ-Toxic gases, NH CO, oxides ol Nitrogen, released by high temperature or combustion.
PiaU P!Hnt ("FJ ... 284

Flam-ble Limits. Unavailable
El:Unauilhlq Apnb .. Water, CO,, foam
Special F1re Procedlll'el Use complete protective clothing and self-contained breathing apparatus.
HEALTH HAZARD DATA

Hulda Huard lbtiap Odw- Thrqhold (ppm) PEL/IW A (ppm) 1LV!fWA (ppm)
Ge.en~l-Suspected carcinogen. causes thermal bums in molten state. Toxic to the frver and central nervous
system.
Symptoms-Irritation and blisters upon contact.
Short Exposure Tolennce-LC.o for rats in 1 hour was 5.3 mg/1.
Expo1ure Prodw-a-Remove to fresh air, administer artificial respiration or oxygen as necessary. Flush eyes
thoroughly with water tor 15 minutes. Wash skin with luke warm, not hot water.
REACI1VITY DATA
Stability-
Compatibility-Material: Incompatible with aluminum, copper, zinc, brass and btoru:e.

Evacuate area. Avoid contact with hot liquid. Wear lull protective equipment and self-contained breathing
apparatus. Contain spill and allow to solidify. Scoop into drains. Rinse down area with water. Prevent entry into
sewers or water courses.
If a lpill occun, eall die National R~ Center, 800-424--8802.

Re.arks: 0
Vapor Pressure. 1 mmHg at 107 F.
t Unavailable
:t: Unassigned
284
TOLUENE DIISOCYANATE
SynonyiiUI- Benzene, 1,3-diisocyanatomethyl-;
2,4-Diisocyanatotoluene: TDI; 2.4-Toluene
diisocyanate; Toluene-2,4-diisocyanate: 2,4-Tolulene
diisocyenate; 2,4-Tolylene diisocyanate; m-Tolylene
dlisocyanate
Fonnula-H,(;4H3(NC0).
~-c~F
Appeannee-Odor-Ciear, faintly yellow liquid; strong c 'F
pungent odof F'ree.z.1111 Point.. ~c srF
Spec:lftc Gru:ity-1.21 ___ c ___ "F
VqK~r PraHre zoc (68'F> (nuaHI).. ......L.2tL..
Cbemk:al Funlly-Aromatic isocyanate Rehl Vapor PreRure (plia).... ---LI:n!...._
V~~p~~r Preaure 46'C (115'F) (,.W.. ......L.2tL..
Pollutiou C.teaory-USEPA _.a_ IMO _____Q__ VapoT Demilty (Air = 1,0)... __.Q__
Applicable Bulk Rq:, 46 CFR Subcbapter ...... ___Q_ Solubility bl Water.. React!

Electrical Group-O
General-Highly toxic nitrogen dioxide gas is produced when this prOduct burns.
Flash Poiat ('F). 270

Flaaunable limits .. 0.9 to 9.5%
AulolpUion TeJIIP. ('F) .. above 300
ElldaJUilbjDI Apnb .. CO:!, dry chemical, water log
Spedal Fire Procedure~ ...... Provide firefighters with lull body and respiratory protectiOo. Do not allow
water to get into a tank of toluene dlisocyanate.
HEALTH HAZARD DATA

HeaJth Huard Rltinp Odor lbresllold (ppm) PEL'TWA (ppm) TLV!lWA (liPID)
3, 3, 4 0.4 0.005 0.005
General-5uspected carcinogen. Uquid extremely harmfUl by skin absorption. Vapor inhalation severely irritating
to nose and throat. Repeated exposure to low concentration can lead to respiratory problems and severe
dermatitis.
Symptoma-Burning at site of contact. Vapor inhalation causes intense irritation ol nose and throat. Inhalation
can also cause asthma-like symptoms, which may not appear for several hours after exposure.
Short Exposure Tolei'U&:f:-0.5 ppm are irritating to nose and throat for brief exposures.
Eli:posure Procedures~-lngestion--do NOT induce vomiting. Vapor-remove victim to fresh air, if breathing stops,
apply artificial respiration. Oxygen, administered by trained personnel, is often helpful. Skin or eye
contact-immediately flush affected parts gently with water while removing contaminated clothing. Continue
to flush for 15 minutes. Get medical help promptly.
See Medical Kit lnfonnation, Appendix 8
REACTIVITY DATA
Stllbillty-Product will react with water and even the moisture in the air in excess of 100 ppm, evolving CO.
and heat. Can react violently with amines, alcohols and acids.
Compatiltlllty-Meria1: Stainless steel, nickel and aluminum are satisfactory construction materials. Avoid
copper and copper alloys. Mild steel may be used il it is clean and entirely free of rust and moisture.

Wear butyl rubber gloves. protecliva clothing, seN-contained breathing apparatus, protective shoes. Avoid
contact with the liquid. Keep unprotected personnel away from spill area. May mix with venniculite, sodium
bicarbonate, or saJ"Id. Pack in cardboard box and burn in open pit uSing crumpled paper and wood splinters as
fuel. Wash si\e with soap solution.
If I .,W OCC1IJ"t, atU lite Nlti.OIIII ~ Cealer, I00-4l4-8110l,
Rem1rb:
285
1,2,4TRICHLOROBENZENE
Synony~M- Tlichlorobenzenes, liquid; United Nlltlons Number..
unsym-Trichlorobenzene: 1,2,4Trichlorobenzol
CHRIS Code ..
Bollin& Point ... _mc __ilO"F

_ _ _ F
Appearll!lee-Odor-Colorless liquid; aromatic odor c
Freedna Point .. 18'C ____eaF
Speeirie Gral'ity-1.45 c _ _ _ "F
Vapor Preuure :zti"C (68"F) (mmHR) .. ~
Cbemical Family-Aromatic halocarbon Reid Vapor Preuu:re (plia) ... ....l.O!L_
Vapor Prnwre 46'C (llS'F) (p~~if,) .. ....l.O!L_
Pollution C.tegory-USEPA _.e.__ IMO _____e__ Vapor DeaJty (Air = 1.0) ... .....2_
Appllcatlle Bulk Reg. 46 CFR Subchapter ........ ____Q__ Solubility In Water .. !OSQilJble

Elec:trieal Group-O
General-Slight lire hazard when exposed to heat or flame. Gives off hydrogen chloride gas.
F1-.b Point ('FJ .. 230

Flammable Limltt .. 1.3 to 7.1%
Autolp.idon Temp. ("F) 1180
E:r.tinKUillhiD& Allfllb .. Carbon dioxide, dry chemical or loam
SpeciaJ F:lre Proeedures .. Water spray may be used to control small fires. Cool exposed tanks with
water. Wear self-contained breathing apparatus.
HEALTH HAZARD DATA

Health HIWird Ratinp Odor lbrabold (pp111l PEL/TWA (ppm) TLV /TWA (ppM)
1, 1, 2 3 5 5
General-Moderately tox1c by ingestion and inhalation, superficial burns to the skin.
Symptomt-Aepeated expost.~re can lead to liver, kidney, spleen damage. Coughing, watering eyes.
Short Expo~~~ure Tolei1Uice-Animal studies have shown that 756 mg/kg killed 50% of the population, effecting
the liver, kidney and spleen
Expo111ure Procedurn-Ski!l and eyes-flush affected areas with plenty ol water. VapOf-remove victim to fresh
air. If conscious, have victim take water Of milk and induce vomiting if swallowed. Administer artificial
respiration If necessary. Call a doctor.
REACTIVITY DATA
StabiUty-Stable.
Comp~~tlbiUty-Materlld: Most rubbers are not compatible

Wear plastic gloves, se"-contained breathing apparatus, protective clothing. Absorb spill with vermiculite,
sodium bicarbonate, Of soda ash-sand mixture (10-80). After absorption of spill the mixture may be packaged in
cardboard containers and burned in an open pit. Wash site thoroughly with strong soap solution.
If a spJII occun, eall the National Re1p0n.e Cnter, 1100-4l4-810l,

Remarlu:
286
111TRICHLOROETHANE
Synony$8-- Chlorothene; Ethane, 1,1, 1-ttichloro-;
Methyl chloroform; 1,1,1-TCE
CHRIS Code ...
Formula-CH,CC!,
Bolllq Point.. _____:z!'C ______11m'F
Appearance-Odor-Colorless liquid; sweetish, c 'F
chloroform-like odor Freezill& Poillt .. , _____2'C __;J'F
Speclftc GraYity-1.46 ___ c ___F
Vapor Prea.re 20'C C68'F) <-HW .. ___1QQ_
Cbemical F...Uiy-Halogell8.ted compound Reid Vapor Preallre (,.U)... ~
Vapor Pre.~re 46'C U15'F) (pala).. ____!.i_
PoUudon C.teaory-USEPA--L- IMO-~ Vapor Deal:lty (Air = 1,0).. ___i.L.
Applleallle Balk Rea. 46 CFR Subcllapter ....... ~ Solabillty Ia Water.. Nagljg!blt

Gl'lllle-None assigned.
Eledrkal. Gro11p-O
GeDeral-Does not bum readily but can produce a dangerous "flash" when vapors are exposed to a
high-energy spark sources in a confined space. When in contact with hot metal or a flame, methyl
chlorOform can decompose to form phosgene, which is highly toxic.
Ftuh Poillt ('F). .. Unavailable
Flam-bte UmitJ .... 7 to 16% (approximate value for flash described above)
Alltoignjdon Temp, ("F). 932
bdquisbilq Aaeatl ... Dly chemical, loam or COt
S]leclal Ftre Proeedres .. Wear eye protection, sell-contained breathing apparatus and protective
clothing.
HEALTH HAZARD DATA

Healtk Huanl Ratlnp Odor Tbreslaold (ppm.) PEL/TWA (ppm) TI.VIIWA (ppm)
1, 1, 2 100 350 350
General-Vapor inhalation gives moderate irritation of air passages plus moderate narcotic effect. Prolonged or
repeated skin contact may cause defatting of the skin and may produce dermatitis from daily contact.
Symptoms-Dizziness, headache, nausea, and drowsiness.
Sltort E~:potiU'I.! Tolerute-1500 ppm
Exposure Proeedu~Vapor-remove victim to fresh air; if breathing stops, apply artificial respiration. Skin Of
eye cootact-remove contaminated clothing and gently flush affected areas with water lor 15 minutes. Get
REACfiVITY DATA
St.IMUty-Begins to decompose at 350'F. May decompose to hydrogen chloride and other toxic products.
Compadbutty-Materlal: The uninhibited grade is corrosive to aluminum, although the inhibited grade may be
used with aluminum and any common construction metals at temperatures up to 175'F.

Wear rubber gloves and protective clothing. Avoid contact with liquid. Secure ignition sources.
If a IP'II occun, caiJ. tile National Re1poMe Cealer, II00-4l4-880Z.

Remarka: The comrnerc1allnhiblted product has a boiling range of 160-190"F.
.. Unregulated, Table 2, 46 CFR 153.
287
1,1 ,2-TRICHLOROETHANE
Synonym5- Ethane tnchloride: Ethane, 1,1 ,2-trichloro-; United Natio1111 Number ..
beta-T; 1,1,2-TCE; beta-Trichlorethane; Vinyl
trichloride
CHRIS Code ..
Formula-CH 2 CICHCI 2
Boiling Point _ _1_1_4'C ------Zll'F
Appearance-Odor-Colorless liquid; sweet, c 'F
chloroform-like odor Freezing Point. -38'C -36'F
Spedftc Gravlty-1.43 at 25'C ___ c ___ "F
Vapor Pres!Jure 20"C (68'F) (mmH&).. ~

Chemical Family-Chlorinated hydrocarbon Reid Vapor Pressure (paltl)... ____.1.__
Vapor Preuure 46'C (115'FJ (JI'ia). ____1__
Pollution Category-USEPA_e...._ IMO-___IL_ Vapor Density (Air = 1,0).. . ........... ~
Applicable Bulk Res. 46 CFR Subchapter ...... ____Q__ Solubility In Water.. 0 45% at ?O'C

Grade-None assigned
Electr:lcal Group-O
General-Very low degree olllammability. Normally will not bum, but will in lire of other fuel or with strong
initiator (large spar1c., welding torch), will give off toKic and irritating gases, including hydrogen chloride,
chlorine, and/or phosgene.
Flub Point ('F) None measurable due to low degree of combustibility
Flammable Limits 6to 15.5%
Autoipitioo Temp. ("F) Unavailable
Extlngulsblna Aaents .. Dry chemical, loam, CO.
SpeclaJ Fire Procedures Cool eKposed tanks with water. Provide respiratory protection for fire parties.
HEALTH HAZARD DATA

Health Haz.11rd Rating:~~ Odor Threshold (ppm) PEL/TWA (ppm) TLV /fW A {ppm)
Unavailable Unavailable 10/Skin tO/Skin
General-Suspected carcinogen. Very toKic, much more so than 1,1,1-trichloroethane. Central nervous system
depressant TOJuc to liver and kidneys. Prolonged or repeated skin contact may cause defatting of the skin
and may produce dematitis from daily contact.
Symptom.-Eyes-rmta\lon, drscomfort. soreness. Skin-irritation. Inhalation-irritation, drowsiness,
unconscrousness. tngestron-headache, lassitude, coma.
Short 1-.xposure Tolerance-Short term eKposures near 2000 ppm cause central nervous system depression,
drstorts equrhbrrum
Expos11re Proudures-Eye-llush with water for at least 15 minutes, call physician. Skm-wash wrlh soap and
water tor at least 15 minutes. Inhalation-remove to fresh air, give oKygen or artificial respiration as needed.
Ingestion-call physcran.
REACfiVITY DATA
Stability-Generally stable; decomposes when heated. Reacts with strong oKidizers, stroog caustics, and active
metals to cause fires and eKplosiQns.
Compatlblllty-MateriaJ: Attacks some plastics, rubbers, coatings. Reacts with aluminum.
Car11o: Group 36 of the compalibility chart

Wear protectve clothing, self-contained breathing apparatus, and full face shield. Stop release, dike spill,
collect wrth rnert absortlant, d1spose rn sanitary landfill
If a spill oun, call the National Reaponae Center, 800-424-8802.

Remark&: t Unavarlable 1090
288
TRICHLORETHYLENE
Synony-- Chlorylen; Ethene, trichloro-; Ethinyl
trichloride; Ethylene trichloride; Tri; Trichloroethane
CHRIS Code ..
Fonaui1-CIHC=CCI,
Bollin& PoiDt.. ____R'C ____jji'F
Appeai'IUICeOdor--Colorless liquid; chloroform-like odor
___ c ___F
Freedq Point.. --=Al"C
___ c --=..!M'F
___.F
Specific Grulty---1.47
Vapor Preaure lO'C (61'F> <nunHI) ......a.t.._
Chem.ic:al FlliiiUy-Halogeoated compound Reid VIPGT Pre.ure (pita)... __2.L
V1pw Prslure 46'C (115'F) (pita).. _____a.L_
PoUutlon Cafeaory-USEPA _____a___ IMO ____jL_ Vapor Deual.ty (Air = 1.0) ......................... ~
AppUe~ble Blllk Rea. 46 CFR Subchapter ........ ___Q__ SolubWty t. Water.. Ntgt!g!b!t

Grade-None assigned.
EleetrieaJ Group-O
Geaera!-Aithough trichloroethylene does not ignite readily, It can flash under certain conditions. A high-energy
ignition source is one of the necessary factors. The liquid or vapor on contact with t-ot metal or a flame
can decompose to form phosgene, which is highly toxic.
Fluh PoiDt ('F) .. Practically non-flammable
F1......bleUID .. Variable at high temperatures
AutoJpltiou Te111p. ('F) . 770
E:.:tblpllhllll Aaents .. Dry chemical, carbon dioxide, or foam
Speelal F:lre Procedure~ .. Tanks should be cooled by a water spray to prevent vaporization. Wear eye
protection, self-contained breathing apparatus and protective clothing.
HEALTH HAZARD DATA

Health Huanl Ratinp Odor "lllrelllold <...-> PEL/lWA (ppm) TI.VITWA(JIIIIIl)
1, 1, 2 50 50 50
GeneraJ-Suspected carcinogen. Vapor inhalation leads to slight irritation of airway with moderate systemic
effect. Prolonged or repeated skin contact may cause defatting of the skin and may produce dermatitis from
daily contact
Sym~Headache, nausea, eye and throat irritation, drowsiness.
Short Exposure Toleralu:e-150 ppm for 30 minutes.
ExJIO'IU"e Procettun.-Vapor-remove VIctim to fresh air; if breathing stops, apply artificial respiration. Skin or
REACI1VITY DATA
StDillty-ln the presence of a strong alkali it reacts to form a gas which will ignite or explode spontaneously.
CompatfiNtlty-Materlal: Stabilized trichloroethylene may be used in the presence of air, water and Wght with
any of the common construction metals at temperatures up to 248'F.
Car-so: Group 36 of compatibility chart. See also Appendix !-Exceptions to the Chart.

Wear rubber gloves, protective clothing, self-contained breathing apparatus. AVOid contact with liquid.
HI .,W ocart, eall tile Nadoul . . . . . . ee.ter, IQO.....U4 IIOl.

Remarks:
289
1,2,3-TRICHLOROPROPANE
Synony1111- Allyl trichloride; Trichlorohydrin; U.Uted Natio... Number ....
Trichloropropane
CHRIS Code ..
Fonaula-C~CI-CHCI-CH 3 CI
Bollin& Point.. ______l.QI'C ______ll:'F
Appeannc:e-Odor-Amber liquid; chloroform-like odor
___ c ___.,
Freedq Point.. ~c
Spedfk: Grflfity-1.39
___ c ---...5B.'F
___.,
Vapor Premlrt lO"C (68'F) (mmHJ) . ----l..L_
Reid Vapor Preuure (plja).. _QJ1_
VQOr Preaure 4Ci'C (115'F) (pl.la).. ~
Pollutioa C.teaorr-USEPA - - - JMO _____a__ VllfCW Demilty (Air "" 1.0).. ____..____
Applicable Bulk Rea- 46 CFR SubcUpter ....... ____Q__ SolaiHUty in Water.. <0 5%

Eledr:lcal Group-O
GeMrai-Moderate lire hazard; releases toxic HCI and other chlorides when heated.

Flamalable Uadb .. 3.27 to 12.6%
Autolputon Temp. ('F) .. 519
Ext:lllpillbbll Apilb .. Water log, water blanket, C(h, foam, dry chemical
Special Fire Procedllra ... Wear self-contained breathing apparatus.
HEALTH HAZARD DATA

Heal~ Huard Ratlnp OdOl' Tbrelltold (ppm) PEL/TWA (ppll!) UVIIWA (pp!a)
Unavailable 5 10 10/Skin
General-Can cause permanent Injury.
Symptoma-Skin-irritation, dermatitis, blistering. Eyes-watering, permanent injury. Inhalation-anesthesia,

irritation of respiratory tract, moderate narcotic effects, drowsiness, dizziness.
Short Exposure Tolel'lUICe-
Exposure Proeedura-Get medical attention. Contact-flush eyes and skin with water. Inhalation-remove to
fresh air. Ingestion-induce vomiting if conscious.
REACI'IVITY DATA
Stability-Generally stable. Decomposes when heated, may decompose in contact with aluminum, reacts
vigorously with oxidizing materials.
Comp~~tiblllty-Materlal: Swells rubber. Suitable: Steel. Unsuitable: Aluminum.
Carao: Group 36 ol compatibility chart

Avoid contact. Wear goggles, rubber gloves, and self-contained breathing apparatus. Absorb with sand.
If a .,W oea~n, ea11 tile Nadoeal R.,oute ee.te-r, 800-4l4-810l.
Remarb: t Unav111lable
290
TRICRESYL PHOSPHATE
Sfllony11111- o-Cresyl phosphate; Phosphoric acid, Ualted Nations NIUIIber .. >3% ortho ~
tris(methy1phenyl)ester; TCP; TOCP;
Tolylphosphate; Tri-o.cresyl phosphate; Tri-o-tolyl
phosphate: Tritolyl phosphate
CHRIS Code ............ <1% ortho isomer ~
1 % Of' more ortho isomer _.IW._
Formula-(CH,C.H,),PO,
Bolllna Point .. ____ill'C ----ZZD"F
AppearaDt:eOdor-Colorless liquid; slight odor c 'F
Freezbl& Poblt.. -;J2'C -25'F
Speclft( Gravlty-1.17 ___ c ___ 'F
Vapor Pretlllll'e zoc (68'F') <mmHK) .. ~
Cbemlcal Family- Reid Vapor PreMiare (p!lia)... _L_
Vapor Pretlllll'e 46'C (115'F) <...a>.. ...Y...J.a..
Pollution C.tqory-USEPA - - - IMO ___A__ VI)IOf' Deuity (Air = 1,0)... ................... .....l2.Z._
Applicable Bulk Rq:. 46 CFR Subchapter ....... ____Q__ SolabUity Ia Water.. N'Aijglz!A

Eleetrical Group-O
General-Slight hazard when exposed to heat or flame. Will decompose at extremely high temperatures
releasing toxic PO, gases.
Fluh PoiDt ("F) .. .,

fobmmable Um.lb .. Unavailable
Autolp.idon Temp, ("F) ... 725
ExtiaRUisblng Aaents .. COa, dry chemical
Special Fire Procedure~~ .... Water may be ineffective on fire. Cool exposed tanks with water. Wear
protective clothing, goggles or face shield and self-contained breathing apparatus.
HEALTH HAZARD DATA

Haiti!. Hazard Ratiap Odor 'lbredlold (ppm) PEL/I"WA (ppm) TLV/fWA (ppm)
1, 0, 4 Unavailable Unavailable 0.01/Skin
Getlerai-Vapor slight hazard due to low vapor pressure. Liquid extremely toxic when ingested.
Sylllpt-Vapors may irritate eyes at hiQh temperatures. Ingestion causes sevEH"e damage to central nervous
system.
Sbort Exposure Tolerance-Unavailable
Ellposare Procedure~~-lngeslion--induce vomiting and call a physician. Skin or eye contact-for eyes flush with
water for 15 minutes; for skin, wash with soap and water.
REACTIVITY DATA
Sbbillty-Stable. Can react with oxidizing materials when heated to decomposition.
Compatiblllty-Materllll: Usual materials of construction are suitable.

Wear protective clothing, goggles or face shield. Remove ignition sources.
If a "'U oc:cun, eall.tlte Nadoaal Rapoaae Cellter, 800-424-1101.
ReJIIIIJ"b: t Unava1lable
291
TRIDECANOL
sy-yn~~-Aicohol C-13; lsotridecanol: lsotridecyl United Nation Number ...
alcohol; Oxotridecyl alcohol; t-Tridecanol; Tridecyl
alcohol
CHRIS C'ocle.
Fonnula-C11H~sCHaOH
Boiling Point .. ~c _____;z;F
Appelli'Uiee-Odol'-Water-white liquid with pleasant _ _c _ _ _F
alcoholic aroma Freezin& Point .. ----..3.!'C _____IF
c _ _ _ F
Speelfte Gralty-0.85
Vapor Pra.ure lO'C (68'F) (mmfla) ... --.l.mL.
Oaeleal Family-Alcohol Reid Vapor Preuure ((NIIa) ... --.l.mL.
Vapor Pnuure 46'C (115'F) (.,.Ja) .. --.l.mL.
PolhadiMI Cateaory-USEPA--- IMQ.____lll_ Vapor Demilty (Air = l.G) .... __u_
Applicable Bulk Rea. 441 CFR Subebapter ....... _____Q__ Solubility In Water. NM!jgjpla

Eleetrieal Group-O
Gelluai-Siight fire hazard when exposed to heat or flame.
FIMh Poiat ('F) .. 250

Autolpitlon Temp. ('F) .. Unavailable
Extlqulab.lng Apats ... Alcohol foam, water spray, dry powder, CO.,
Special Fire Procedures . Water or foam may cause frothing.
HEALTH HAZARD DATA

Health Huard Rat:lnp Odor Threshold (ppns) PEL/TWA (ppm) TLV!TWA (ppm)
Getlerai-Possibility of some adverse effects from liquid contact with skin.
Sympto..--lnhalation hazard is slight. Skin contact causes minor irritation. Eye contact causes severe irritation.
Short Eposure TolerllllCe-Unavailable
bpo~ure Procedure!i-Vapor-remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or
eye contact-remove contaminated clothillQ and gently wash affected areas with water.
REACTIVITY DATA
Stability-Stable
Co~ajllltibllity-Materlal: Aluminum unsUitable
CarRO: Group 20 of compatibility chart

It a apjll OCCIItll, call the National Re~~ponse CeDter, 800-4U-8802.
Remarb: :t: Unass1goed
292
1TRIDECENE
Syno11yms- Olefin C-13; Undecylethylene United Nations Number ...
CHRIS Code ..
-=--
Boillna: Point. _____mc
___ c __l'F
Appelll'nee-Odor-Colorless liquid with a mild pleasant 'F
odo< Freeztna Point .. ~c -11'F
Specifle Grat'ity-0.77 c _ _ _ 'F
Vapor Pressure 20'C (68'F) (nunH&) ..
Chemieal Family-Olefin Reid V1por Pres~ure (pUa) ...
Vapor Preuure 46'C (115'F) (p~~LI) .. ------
------
Pollution Catepry-USEPA - - - IMO _____ill__
Applitable Bulk Reg. 46 CFR Subdlapter ....... _____Q__
Vapor Demllty (Air = 1.0)
Solubility ill Wilt...
------
...................... jiilo!~

Eloctrieal Group-O
GeneraJ-Moderate fire hazard if exposed to heat or flame.
Flub Point ('F). -175

Flm-ltle U~alts .. Unavailable
Autoignltlon Temp, ('F) .. Unavailable
Extlnplslllng Alellts .. Dry chemical, foam or CO.
Speeial Fire Procedures .. Water may be ineffective on f1re. Cool exposed tanks with water.
HEALTH HAZARD DATA

Health Hazard Ratinp Odor Tlrnshold (ppm) PEL/1WA (ppm) TLVITWA (ppm)
UnavaHable Unavailable Unavailable Unavailable
GeneraJ-Data are lacking; however, it appears that the t-Tridecene is relatively non-hazardous.
Short Ellposure Tolenmce-Unavailable
Ellposure Proeedures-Uquid may irritate the eyes. Aftm skin or eye contact, flush with water for 15 minutes.
REACfiVITY DATA
Stlllhillty-Stable.
Cempadhillty-Materlal: Usual materials of construction are suitable.

Wear rubber gloves, face shield. protective clothing. Have aU-purpose canister mask available. Secure ignition
sources.
If a !lpill occurs, eaU tlte NatloDill Respone Center, 800-424-8801.
293
TRIETHANOLAMINE
SynllllyiiUI- 2,2',2"-Nitrilolriethanol: TEA; United Natlollll Number ...
Triethylolamine: Tri(hydroxyethyl)amine:
Tri(2-hydroxyethyl)amine; Trihydroxytriethylamine:
Tris(hydroxyethyl)amine; Trolamine
CHRIS Code
Fonnula-(HOC.H.).N
~"F
Dolling Point .
Appeannc~Odor-Colorless,
ammonia-like odor
Speclftc Grnlty-1.13
oily liquid; slight
Freezing Point ..
Vapor Pressure 20"C (68'F) (mmH&) ..

___
__2"F
....l.oYL
..
Chemleal Family-Amine Reid Vapor Pre~~~~~ure (psia) ... ....l.oYL
Vapor Preaaure 46'C (llS'F) (pdal .. ....l.oYL
Pollution Category-USEPA - - - IMO ____Q_ Vapor Density (Air = 1.0) ... ...llL
Applleable BuJk Reg. 46 CFR Subthapter ___Q__ Solubility In Water .. Complete

EJeetrieal Group-C
General-Slight hazard, when exposed to heat or !lame. The oxidation products are poisonous.
F1ub Point ("F). 365

Flammable Limits. Unavailable
AutoliPJition Temp. ('F) Unavailable
Extinplshhll AKeDtli .. co dry chemical, alcohol foam, water fog
Spedal Fire Procedures Keep tanks cool with a spray of water. Provide respiratory protection tor fire
parties.
HEALTH HAZARD DATA

Health Huard Ratings Odor Threshold (ppm) PF-LJTW A (ppm) TLV/TWA (ppa~)
0, 1, 1 Unava1lable Unavailable Unavailable
General-Liquid causes irritatiOn and burns to skin and eyes on contact
Symptmm-ltchtng or burntng of skin at Site of contact If mhaled, the resptratory passages will be irritated.
Sbort Ex)IO"!lure Tulerance-Una,.atlable
Exposure ProcedurH-Wash sp1ll from the skin with water. If liquid has splashed in the eyes, wash them with
water for 15 mmutes and get medtcal anentton.
REACTIVITY DATA
StRbility-Begins to decompose at 450"F
Compatibility-Material: Copper and its alloys are corroded.
Cargo: Group B of compatibility chart. See also Appendix !-Exceptions to the Chart.

Wear butyl rubber gloves, protective clothing. A"oid contact with liquid Cover spill with sodium bisulfate.
Spray with excess water and wash up. Wash area with soap solution
Remarks: Partly to lower the high freezing point, the commercial product is a mixture of triethanolamine with up
to 25% diethanolamine and 5% ethanolamine The resultmg mtxlure will ha"e properties that "ary
somewhat from those shown.
:j: Unassigned
294
TRIETHYLAMINE
Sy-ym- N,N-Oiethylethanamine; TEN United Natlo1111 Number ....
CHRIS Code.
Form~~ola-(~H 0 )3N
Bolllq: Point... ~c ______ti2'F
AppearanceOdOl'-Colorless liquid; ammoniacal odor ___ c ___ .F
FTMzine Point.. ~c ---=.llQ'F
SpedRc: GraYity--0.73 c ___F
Vapor Pra.ure :z&'C (68'F) (mmHI).. ~
Cltemic:al Family-Amine Reid Vapot' Pr-Uf'e (plla)... ____2.L_
Vlilpor Preuure 46'C (115'F) ((lila).. ~
Polllltlon Catepry-USEPA _Jl._ IMO ~ Vtq10r De:all.ty (Air = l.Ol .......................... ~
Applbble Bulk Rea. 46 CFR Subcllllpter ....... _.Q._ Solulllllty bl Water.. $light

Eleetrlcal Group-C
General-Dangerous, keep away from heat or open flame. Flashback along vapor trail may occur. Vapor may
FladiPolatC'F> .. 25
Flammable Um.ib ... 1.210 8.0%
AuhNpiUOII Tep. ('F) .. 842
Es:tblpitbiD1 Aput. ..... Alcohol foam, CO:z, dry chemical
Spedal Fire PI'Gc:edarn ... Use water to keep fire-exposed containers coot. If a leak or spilt has not
ignited, use water spray to disperse the vapors and to protect personnel attempting to stop leak. Water
spray may be used to flush spills and to dilute, rendering non-flammable.
HEALm HAZARD DATA

Heallb Hazard Rallnp Odor Tlrabold (ppm) PELJTW A (ppm) TLV/TWA (ppm)
General-liquid dangerously absorbed through skin. Vapor inhalation harmful. It is one of the most severe eye
irritants and permanent injury may follow eye contact despite prompt treatment efforts.
Sypt-Uquid causes eye injury and skin irritation.
Sborl ExiJO'IIre Toleranee-less than 100 ppm for humans for 30 minutes. A 4 hour exposure was lethal to 1/6
of rats tested.
Es.JMIIIIte Procedures-In case of contact with eyes or skin, imm&liately ft.Jsh with plenty of water for at least 15
minutes: for eyes, gel medical attention. Remove contaminated clothing and shoes at once.
REACllVITY DATA
StabUity-Stabte.
Comp.tibillty-Materilll.: Copper and Its alloys are incompatible with triethylamine.

If possible, wear butyl rubber gloves, face shield or all-purpose canister respirator, and full-protective clothing.
Secure Ignition sources. Cover spill with sodium bisulfate. Spray with water and wash up.
If a .,W oean, eaU lite Natioul R.,oue ee.ter, 800-4l4-8110l.

Remukl:
295
TRIETHYLBENZENE
Synonyms-1,3,5-Triethylbenzene; sym- United Natlolll Number, ..
Triethylbenzene
CHRIS Code ....
Formula-C.H,(CH,CH,).
Bollin& POint .. ______zj'C ___ID'F
Appearance-Odor-Clear, colorless liquid; weak aromatic c F
odo Freezi111 Point .. -ZO'C -94'F
Specific Grnity-0.86 c ---
Vapor PreMure lO'C (68'F) (IIUilH&) .. JQL_
Chemic.l Family-Aromatic hydrocarbon Reid Vapor Preaure (piU) .. ___ML
Vapor Pnillure 46'C (115'F) ((MI..) . _2.2L
Pollution CJiteaory-USEPA - - - IMO ___A__ Vapor Denalty Wr = 1.1)) ... ---'L..
Applicable Bulk Rea. 46 CFR Subchapter .. . .. __ll...Q_ SolubWty ill Wlter .. !DQiubla

Electrieal Group-O
General-Moderate fife haZard wheo exposed to heat or flame.
Flub Point ("F) .. ,.,

Flunmlble Umibl .. Unavailable
AutoipitiOII Temp. ('FJ Unavaiiable
Ell;tlllfUisblq; Apntl ... Foam, carbon dioxide or dry chemical
Speellll Fire Procedure~-- Water may be ineffective on fire. Cool exposed tanks with water.
HEALTH HAZARD DATA

Health Hazard Rating~~ Odor 'llroreshold (ppm) PEL/I'W A (ppm) TLV/TWA (ppM)
1,1. 1 Unavailable Unavailable Unavailable
Genenl-
Symptoms-Slight smarting of the eyes or respiratory system if presen1 in high concentrations.
Short Exp011ure Tolerance-Unavailable
Exposure Procedure~~-Vapor-remove victim to fresh air. Skin or eye contact-remove contaminated clothing
and gently flush affected areas with water.
REACfiVITY DATA
Stability-Stable Can react with oxidizing materials.
C11r11": Group 32 of compatibility chart.

Avo1d contact w1th hqu!d Secure Ignition sources.
If a spUI occun, a.ll tbe National Re1poa1e Center, 800-414 BBOl,

Re11111rkli: :f: Unass1gned
296
TRIETHYLENE GLYCOL
s , _ , _ Di-beta-hydroxyethoxyethane: 2,2'-Ethylene
dioxybis(ethanol): 2,2'-Ethylene diOxydiethanol;
Ethylene glyCol dihydroxydlethyl ether: Glycol
bis(hydroxyethyl}ather, TEG; Trlglycol
CHRIS Code .
-
Fonn11a.-(CH.OCH.CH.OH}a
BcNIInc Polat.. ____2ZI'C ______saa'F
A~ss liquid with a slight, sweat "C
Free&DI Polat... -zoe lii'F
Spedne Grll'f'lty-1.12 ___ c ---
Vapor Pre.are 20'C (AI'P:I l..tfs) .. .... ...Y.....Lml..
Cllemkal FUIJiy-Giycol ether Re6d Vapor '""-re (flia)... ~
Vapor Pr-.re 46'C U15'F) (IIIia) ..Y.....L.IM.
PolllldOD Cateaocy-USEPA - - - IMO _J!L_ Vllf!Ol' DMI'IJ Wr = 1.0) .............. ....AJL..
A,Ue.b&e Blllk Rea. 4Ci CFR S.bdlapter ........ ____1L_ SoiWittJ m w.- .. Cgmp!ete
--.-c
Grwle-E: Combustible liquid
Gaterai.-SIIght fire hazard when exposed

to flame, spark or heat source.
........ Polat ('F) .. 350 (cc)
to heat or flame. Moderate explosion hazard when vapor Is exposed
l'1aJuWJie U..tb .. 0.9 to 9.2%

A11tofp1Uoa T-p. ('F) .. 700
Extlllplllllq; Age~~ts ... Carbon dioxide, dry chemical, or alcohol loam
Spedal Fire l'nlc:eduell .. Water or foam may cauae frothtng.
HEALTH HAZARD DATA

Healtll Huard lbd... CNor 1'llnlltold ~) PEL/TWA (..,., TLVnwA (PfiD)
Gueral-Considered non-toxiC under normal handling conditiOns.
Sy~liquid is a skin irritant. Vapor Is a lung and upPer respiratory tract irritant.
Aort EI]IOIIU'e Tolenulee-Unavailable
EK)IOhl'e ~kin-flush eyes and skin with water. Vapor-remove viCtim to fresh alr and administer
artificial respiration. Call a doctor.
REACTIVITY DATA
Stdllltty-Stable. can react with oxidizing materials.
ColllpU!bWty-Matertal: Usual materials of construction are suitable.

If a .,W octllrl. alii tile Natioala.,.... Cater,II00-424-II01
297
TRIETHYLENETETRAMINE
Syaonyms- N,N' -bis(2-Aminoethyl)ethylenediamine; United Nations Number ..
TETA; Trien
CHRIS Code ..
Formula-H,N(C.H.NH),H
Bollln11 Point. ~C ~'F
Appearance-Odor-Moderately viscous, amber liquid; c 'F
ammonia-like odor Freez:in& Poi11t.. -35'C -31'F
Specific Gra,-lty--0.98 c ---
Vapor Preaure lO'C (68'F) (mmH&).. ~
Chemica] Family-Amine Reid Vapor PreuUTe (plla)... ~
Vapor Pres.ure 46'C (lt!I'F) (pill.)... ____l.gyt_
Pollution Cateaory-USEPA - - - IMO ____Q_ Vapor De111Uy (AJr = 1.0) ......................... ~
Applicable Bulk Re11. 46 CFR SubcU.pter ....... ____Q__ Solubility in Water.. Complete

Electrical Group-C
~nerai-Siight fire hazard when exposed to heat or flame. No spontaneous heating.
flash Point ('F) .. 290

Flammable Umits .. Unavailable
Extingulsbiq Aaenh .. Alcohol foam, carbon dioxide or dry chemical
Speelal Fire Procedures .. Water or loam may cause frothing. Fire fighters to wear sell-contained
breathing apparatus, goggles and protective clothing.
HEALTH HAZARD DATA

Hell1tb Huard Ratlnp Odor Tbreslaeld (ppm) PEL/TWA (ppm) TLV!1WA (ppm)
General-Liquid causes severe burns to skin and eyes with only slight contact. Vapor causes primary skin
1rritation and dermatitis.
Symptoms-Vapor-skin irritation, dermatitis: nausea, faintness, anKiety. Liquid-severe skin bl.lrns.
Short Exp0sur~ Tolerance-Unavailable
Exposure Procedur-Vapor-remove victim to fresh SJr; if breathing stops, apply artificial respiration. Skin or
medcal advce or attention
REAcrJVITY DATA
Su.bility-Stable Can react wrth oKidizing materials
Compatibility-Material: Aluminum or stainless steel are suitable.
Cargo: Group 7 of compatibility chart. See also AppendiK 1-Eceptions to the Chart.

Wear butyl rubber gloves, face shield or all-purpose canister respirator, protective clothing. Avoid contact with
hquod Cover spill w1th sod1um bisulfate Wash up with water. Wash site with soap solution.
If a spill occurs, call the Natioul Responae Center, 800-4l4-880:Z.

Remsrka:
298
TRIPROPYLENE GLYCOL
s,-,..._ No common synonyms. ................ ----'----
CHRIS Code ........................... . ................ __Ili!;_
Fonnla-HO(~He0)1CaH.OH
Bom.na Point ......................... _____2l'C ~F
c ___'F
==F
Appearuce-Odor-lorless liquid; odorJess
Frenlna Palnt .....................Suotr copls'C 'F
Spedfk Graflty-1.02 ___ c
Vpor Prellure lO'C (QJ'F) (DuaH&) ......... ~
Cbemkal Fudly-Giycol ether Re1ll V.,or Prelllare (plia)... . .............. ~
VIIJIOI' Pre.ure 46'C (115'F') (pita) ........... ____Lmt_
PoH.Uoa Cafe80i'y-USEPA - - - IMO _Ill_ Vapor Dealty (Air = 1.0).... . ............ ____,L_
A.,Uable Blllk Rea. 4Ci CFR Su.~ ....... ____.c._ So11lblllty Ia Water Cgmp!atl!
FIRE .t: EXPWSION HAZARD DATA

-Gnoop--C
GeDeral-Siight fire hazard when exposed to heat or flame.
-u.J.
FIMh Poiat ('F) ......
......
Avtolpmo. T-... ('F) ...
Exlla&ui*lq Apn ...
............ 285
Spedal Fire Proeed1U'ell .. .

Unavailable
UnavaNable
Water, foam, carbon dioxide or dry chemical
Water or foam may cause frothing.
HEALTH HAZARD DATA

Healtll. ~bard Ratblp Odor nr.hoW (,m) PELII'WA~) TLVnwA (ppm)
0, 0, 0 None Unavailable Unavailable
Geaerai-No hazard under ordinary conditions of handling.
S)'mptomt-Unavailable
Short Ex~ Tolenmce-Unavailable
Esponre Ploc:edUI-Unavailabla
REACI1VITY DATA
StUWty-Stable. can react with oxidizing materials.
O.,.tibWtJ-Malerial: Ueual materials of construction are suitable.
ear,o: Group 40 of compatibility chart

It ..W ocnn, adl tile N---.llelpoue Cater, 800-4l4-IIIOl.
299
TURPENTINE
SyDOaymt- D.O. turpentine: Gum spirits; Gum United Natlollll Number ...
turpentine: Oil of turpentine; Spirits of turpentine;
Steam distilled turpentine; Sulfa!& turpentine;
Sulfate wood turpentine: Turps: Wood turpentine
CHRIS Code ..
Formula-Mostly C,.H,~
Bollln& Point .. ..lli8.Q'C ~F
Appeannce-Odor-Colorles:. liquid; smells like oil-base
paint
Spcelfte Gruity-0.85 to 0.87
Free:dtlg Point ..
c
c
---.c ==F "F
_ _ _ "F
Vapor PreMure :zoc (68'F') <nunHg) ..
Chemical Family-Olefin Reid Vapor Preuure (p~~la) ... ..Jl.2L
Vapor Preuure 46'C lll!I'FJ (,.ta) .. ~
Pollution C.tqory-USEPA - - - IMO ~ Vapor DeDalty {Air = 1.0) .... ~
Applicable Blk Rea. 46 CFR S.bcbapter ..... .-ll...Q_ Solublllty Ia Water .. Neg!jgjble

Grwle-0: Combustible liquid
Electrical Gr011p-O
General-Gtves off acrid fumes when heated. Moderate lire hazard. Forms heavy black smoke and soot
Flashback along vapor trail may occur. Vapor may explode in an enclosed area.
Flub Point ("F)., .. 95

FlammUie Llmib .. LEL=O.S% UEL-Unavailable
Autolp.idoa Temp. ("F) .. 488
E:~.tiDpidllng Aaentl ... CO., dry chemical, water fog. foam
SpedaJ Fire Procedures .. A tank exposed to fire should be kept cool with s spray of water.
HEALTH HAZARD DATA

HeaJtb Hu:ud Ratinp Odor Thrahold (ppm) PELffWA (ppm) TLV ffW A (ppm)
1,1.1 Unavailable 100 100
General-Vapor inhalation harmful. liquid irritating on contact.
Symptoms--Prickling sensation of eyes, dizziness, acceleration of pulse, respiratory irritation and nausea.
Short E:~.po~~ure TolefliJICe-750 to 1000 ppm for several hours caused eye irritation, headache, dizziness,
nausea and acceleration of pulse; 1878 ppm for one to four hours is toxic to man.
Ell.po~~ure Pr~~durn~-Remove victim to fresh air: if breathing stops, apply artificial respiration. Skin Of eye
REACTIVITY DATA
Stability-Under certain conditions (large surface area exposed to air) turpentine can undergo spontaneous
heating.
Compt~tlbllity-Material: Almost any metal is suitable. Ordinary rubber is attacked and should not be used for
gaskets or fittings.

contact with liquid. Secl.lre ignition sources.
If a jMU oc:cun, call the Natklaal RafiOIIIN! Center, 800-4~1.

Re.arks: Vapor Pressure: 5 mmHg at 25'C.
300
UREAAMMONIUM NITRATE SOLUTION
(more liNin 2% tree mmonfll)
S)'IIOIIy11111-SOiar nitrogen solution; UAN-Nitrogen
solution; UAN solution
CHRIS Code ..
Formula-NH.CONH.,NH,NO,,NH,,H,O mixtures
Bolllna Point .. ______lOO'C __2..l2'F
Appearance-Odor-Colorless liquid; slight ammonia-like ___ c ___F
odo' Freezl.na; Poillt ... ____J!'C ----..a2'F
Speelnc Gra-rlty-1.3 ___ c ___F
V1por Preaun lft'C (68'F) (111111HR) ..
Ciemk:al Family-
Rdd v,,.. "'-" (poU)...
V1por Preaure 46'C (tlS'F) <p.la)...
.:11!iU_
...YadiL.
Polbltion C.tepwy-USEPA - - - IMO _c__ V1por Dealty (Air = 1.0) .......................... ..:t.l!:iD....
Applleable Bulk Rea. 46 CFR Subchapter ....... __Q__ Solublllty iD Wider.. Sp!ub!e

Grade-None assigned.
Eledrieal Group-O
Geaeral-No direct lire hazard until water evaporates. Thermal decomposition yields toxic ammonia, carbon
monoxide, and nitrogen oxide gases.
Flu.b Poillt ('F) .. pure ammonium nitrate-urea solution is not flammable.

Flanunallle lhnitl .. lor ammonia 16 to 25%
Aut"'IPIIUoD Temp. ('F) .. fOr ammonia 1205
ErtiIP!ithbll Apntl .. w...
Speda( Fire Proc:ell-. .. Do not use CO,, dry chemical, foam extinguishers. Dry ammonia in contact
with combustibles increases potential for fire. If confined an explosion will result. Use se"contained
breathing apparatus and stay upwind.
HEALTH HAZARD DATA

H.W. Huard Ratiap Odor 'l'llnlllold {Jt~Nn) PEL/TWA (ppm) TLV!TWA (ppm)
0, 1. 1 -45 for NH,, NH, OH
Geaerai.-Urea itself Is non-toxic. Solution will produce irntation due to ammonia being present.
Symptomi-Prolonged contact will produce mild irritation, blisters or rash. Eyes will become painful. Ingestion
results in nausea, vomiting, intestinal bleeding, coma, convulsions, and or death.
Sbort Eli:pot~~re Tolerance-tOO ppm for 30 minutes (ammonia gas). Lethal dose of ammonium nitrate ts 10-15
grams.
Expos~~re Procedura-Wash skin or eyes with water. For ingestion seek medical assistance promptly. Induce
vomiting after two glasses of water only if conscious. Monitor breathing. Remove to fresh air.
REACTIVITY DATA
Stabllity--8table. Reacts with oxidizing material, combustible material, wood chips, organic materials, sulfur,
metal, finely subdivided lead, zinc, galvanized iron, or acids.
Com,.tjblllty-Malerial:
CllfiO: Group 6 of compatibility chan.
- SPILL OR LEAK PROCEDURE

Contain material to prevent contamination of land or water. Allow water to evaporate, scoop up remaining
residue. Rush area with water to remove remaining traces. Avoid mixing or contact with organic or combustible
materials. Spontaneous combustion may occur.
If a lpiU oecun, eaU lhe National lkilfmqe Cater, 800-4:Z4 8801.
Rnlarb: The more than 2% free ammonta normally requ1res shipment under pressure (0-30 psia at t04'F).
Vapor Presaure: 15 mmHg at 77'F.
N0.-5 ppm; C0-50 ppm; NH,-25 ppm; NH.OH-1 ppm
:t Unassigned
301
lso-VALERALDEHYDE
Synonyma-lsovaleral; lsovaleraldehyde; Isovaleric
aldehyde; 3-Methylbutanal; 3-Methytbutyraldehyde
CHRIS Code ..
Formula-CH 3 CH,CH(CH,)CHO
Boiling Point .. ~c ____l.il!"F
AppearaJiceOdor-Colorless liquid; weakly suffocating c "F
odO< Fffi:ziD11 Point ... -51'C -SO'F
Specific Gnvity-0.60
___ c _ _ _ "F
Vapor Preuure lG'C (68'FJ (mmHR) ...

Chemi~:al Family-Aldehyde Reid Vapor Prelnre (p&ia) ... ___i__
Vapor Prell&tre 46'C (115'F) (p8ia) .. _JjJgb_
Pollution CateaorY-USEPA - - - IMO ____Q__ Vapor Deashy lAir = 1,0) .. .....z.JI!L.
Applie.ble Bulk Reg. 46 CFR SubeUpter ....... __Q__ SolubWty Ia. Willer .. ln!Kllybl!

ElectriCII Group-C
General-When heated, it emits acrid fumes. Ignited by heat, sparks or open flame. Vapor forms exploSive
mixtures with air. Flashback along vapor trail may occur. Vapor may explode if ignited in an enclosed area.
F1uh Point ('F) 49

Flammable Umltll .. Unavailable
Autolgnition Temp. {'F) .. Unavailable
Extinguishing Aaents. co., dry chemical, water log, alcohol loam
Specil F"u-e Pnx:~uret .. Water may be ineffective on fire. Wear seH-contained breathing apparatus and
HEALlli HAZARD DATA

Health HP.IIrd R11tinp OdOI" lbrabold (ppm) PEL/IWA (ppm) TL VII'W A (p!*)
General-Vapor irritating to skin an-d mucous membranes.
Symptoms-Include coughing, sneezing, burning and tearing of eyes, salivation, and all signs of irritation of the
mucous membranes.
Short Exposure Tolerance-Unavailable
Exposure Procedures-Wash immediately with soap and water after skin contact. Contact of the liquid with the
eyes can cause permanent 1njury if prompt treatment is not given. Wash eyes with clear water; obtain
med1cal treatment.
REACTIVITY DATA
Stability-Reacts with itself and also undergoes the condensation reaction in the presence of strong bases.
Compatlblllty-Materilll: Compatible wllh stamless steel or aluminum.
Crgo: Group 19 ol compatibthty chart.

Avoid contact with liqu1d Wear rubber gloves, goggles or face shield, and protective clothing. Secure ignition
sources
If 11 spill occun, nil the Ntionlll RlilpOIIR Ceater, 800-4l4-8110l.

Rem11rkH: Vapor Pressue: 50 mmHg at apprOIL 25"C
1 Unavailable
302
nVALERALDEHYDE
Sy~t~~ay- Amyl aldehyde; Pantanal; Valera!: Valerie Ualted Natlou Number ...
aldehyde
CHRIS Code ..
BoUiq Point.. . --..l.Qa'C ______21Z'F

Appearanu-()dor-ss liquid with a fruity odor c 'F
Frentna: PoJat... -!WC -132'F
Speelfk Graflty-0.81 ___ c ___ "F
Vapor Prellure lO'C (68'F) <-Hal... ____2__

CMmkal Fually-Aidehyde Reid Vapor Preaure (pita)... .. ____1.2__
Vapor Preuure 46'C (115'F') (plia).. ___!&___
Pollutioll Catepy-USEPA - - - IMO ___jL_ Vapor Deulty (Air = 1.0)... . ____2J!_
AppUcable Bulk Reg. 46 CFR Subdlaptu ....... _.Q__ Sol11billty In Water.. S!jpht

Gnlde-C: Flammable liquid
Eleetrieal GrO'IIp-C
~-Flash back along trail may occur. Vapor may explode in a closed area.
..,.. Pobat ('F) .. 54

Flammallle Umitl .. Unavailable
Autpldoa Tep. ('F) .. Unavailable
ExtblpldiiDa; A&Wt ....... Garbon dioxide, dry Chemicals, foam, water spray
s,eclaJ Fire Procedure~ .. Wear seH-contained breathing apparatus and protective clothing as protection
against acrid fumes. Water may be ineffective on lire.
HEALTH HAZARD DATA

Heal.dl Huud. Ratinp Odor 'I1Irallold (Jipm) PEL/IW A (ppm) TLV!TWA (pJIIII)
c-.J.-Vapor is flammable and very irritating. Liquid causes severe bums.
Sy.,._vapor-severe irritation of air passages with headache and rapid heart beat, eye irritation. Liquid
causes S8Vef8 skin and eye irritation on contact.
Sllort E:.:potUre Toteraace-Unavailable
El:pt~~Ve ~Vapor-remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or
eye contact-immediately flood affected area with water for at least 15 minutes. Remove contaminated
clothing.
REACfiVITY DATA
StUJIIty-Stable.
Compadbtllty-M1terial: Stainless steel 01 aluminum ara recommended.

Wear rubber gloves, self-contained breathing apparatus, protective clothing. Avoid contact with liquid. Secura
ignition sources. CoVEif spWI with SOdium blsuHite (NaHSO,). Add small amount of water and mix. Scoop up.
Wash site with soap solution.
U I .,W ocean, ed lbe N.tto.al R..-- Cuter, 1100-424-8802,
303
VINYL ACETATE
SyiHlnyms- Acetic acid, ethenyl ester; Acetic acid, vinyl United Natt- N11mber...
ester; VAM; Vinyl acetate monomer; Vinyl A
monomer; Vy Ac
CHRIS Code ..
fol'lllula-CH,COOCH = CH,
BoUIDa PoJnt .. _____.13'C ~'F
Appearance-Odor-Colorless liquid; sweet odor c 'F
FreeziqPoiDL -lOO'C -148'F
Specific Gravity-0.94 ___ c ___ 'F
Vapgr Preuure lO'C (61'Fl <-HI).. ~
Chemb;_. Family-Vinyl acetate Rdd Vapor Preuare (plia)... -...3.L_
Vapor Preuure 46'C (115'F) (pila)... ~
Pollution Catepry-USEPA ___jL_ IMO ~ Vapor Deatlty <Alr 1.0)... .....i.iL_
Appllultle BuJk Rq. 46 CFR Subcbllpler ....... ___jL_ Solubility .. Water.... 2%
FIRE II: EXPLOSION HAZARD DATA

Electrical Group-O
Gertenii-When heated, acrid vapors are given off. Ignited by heat, sparks or open !lame. Fire may cause
violent rupture of tank due to polymerization.
FlNb Poilllt ('FJ .. 18

Flllllllllable Limits .. 2.610 13.4%
Autoipitioa Ten1p. ('F) .. 801
Extblauisb.in& Ap~~b .. CO.. dry chemical, alcohol loam, water spray.
Special Fire Procedures .. If fire parties must wor11. in confined quarters, provide respiratory protection.
Keep tank cool with a water spray.
HEALTH HAZARD DATA

Health HIWird Ratinp Odor Tbrabold (ppm) PELJTW A (ppm) TI.V IJW A (.,.)
1. 1, 2 0.12 10 10
Genenli-Liquid irritating to skin and eyes. Vapor inhalation causes slight narcotic effect.
Symptoms-Dizziness, drowsiness.
Sbon ExpOSure Tolerance-Unavailable
Expo5ure Procedures-Vapor-remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or
eye contact-remove contaminated clothing and gently flush affected areas with water for 15 mioutes. Ge1
REACTIVITY DATA
Stability-Polymerizes readily if not inhibited. Heat can start the reaction. Emits acrid fumes when heated to
decomposition. Can react vigorously with oxidizing materials.
CompatlbUity-Material: Most of the usual materials of construction are suitable.
CarJO: Group 13 of compatibility chart.

with liquid. Secure ignition sources. Flush area with water spray.
If 1pUI oecun., eall t1te Nldlcmal Reaponae Ce.ter, 1101J-4l4..8110.
Remarkl:
304
VINYL CHLORIDE
s,_,__ Chloroethene: Chloroethytene; Ethene, UaUed NatioM N. .ber...
chloro-; Ethylene monochlorlde; Monochloroethene:
Monochloroethylene; VC; VCL; VCM; Vinyl chloride
monomer; VInyl C monomer
CHRIS Code .............................. .
Porm~H,=CHCI
BoWq Pohll ......................... ---=.U'C ____IF
Appearanc:e-Odo-Color1ess liquid or gas: sweet odor c 'F
Freed~~& Potat... -lftO'C -24!!!'F
Specllk Gnml)'-0.91 ___ c ---
a-deal F..Uy-Vinyl halide
v.,.,.. ~ 20'C (61'FJ (mall&) ......... .....258Q._
Reid Vapor ~ CpU). .. .... ___lL
VIIJIOI' Pn.are 46'C (115'FJ (pda)..... ---iL.
PoUIIdoll Caleaorr-USEPA _x__ IMO ~ V.,or DeMit)' Wr = 1.0)........ ......... --.2.J.A.....
A,.uc.ble Bulk Rea. .tci CFR Subdlapler ....... ___Q_ SoJuldlitr .. waer S!lpht

Gnlde-liquefied Flammable Gas (LFG)
-Group-O
~-Oar1Q9r0ue fire hazard. Unless the flow Of gas can be stopped, putting out a vinyl chloride fire will
permit accumulation of an explosive vapor concentration with Increased danger of reflaah. Heat
decomposes vinyl chlorkle to form highly toxic phosgene gas. Heat can also cause vinyl chloride to
polymerize with exploSive force.
I'IMII Poblt ('F') ..
--
-108
~IJmttl .. 3.6 to 33%
A1llciJpltiH Temp, rFJ ..... 882
Stop flow of gas; CO.. dry chemical. water fog
SpedaJ. Fire Proc:edv. ..... Cool tank with water spray. Provide self-contained bfeathlng apparatua and
protective clothing for fife-fighting personnel.
...................
2, 1, 2 260"
HEALTH HAZARD DATA
Odof' 1'llreiiMIId (p~) PEL/IWA(JIIIIII)
29 CFR 1910.1017
n.vllWA (ppm)
5
c--.t-Human carcinogen. Vapor harmful. Uquld or cold gas may cause akin or eye Injury similar to froatblte.
~ness and drowsiness. Frostbitten areas will look white.
Sllort Ezpogre Toleranee-~00 ppm tor 5 minutes.
~~Remove victim to fresh air. If breathing stops, apply artificial respiratiOn. If the liquid has
spined onto the skin, points of contact may be frostbitten; handle gently and protect from mechanical
damage. 00 NOT RUB. In case of eye contact, flood eye gently with water for 15 minutes. Get medical
attention."
REACI1VITY DATA
StUHit:J-Polymerlzes in presence of air, sunlight or heat.
eo.,.tlbmty-MUerlak Steel is satisfactory. However, contact with copper or other acetyllde-fonning metals
may tonn explosive compounds.
Cup: Group 35 ol compatibility chart.

War rubber gloves, self-contained breathing apparatus. protective clothing. AVOid contact with liquid.
Ignition sources.
.......
If a .,W om..., all Ole NMioul ..,.,._ Cealer, lfl0.-4lt 11101.
R-.rb: 0 NOTE: Detectable odor Is wester than the TLV. Exposure to potentially dangerous vapor
concentrations can occur before the vapor is detected by smell.
JOS
VINYL ETHYL ETHER
Synonylllll- Ethoxyettlene; Ethyl vinly ether; EVE;
Vinamar
CHRIS Code ..
Formula-CH, =CHOC.H.
aonlaa; Point.. ___ arc ----ii'F
A.p~arnee-Odor-Colorless liquid; disagreeable odor ___ c ---
Freezlna Polllt.. ---=.1.1.5'C ~F
SpeciOc Gruity--0.763 ___c ---
VllfO!' PreMure lO'C {68'F') lmHaJ .. ........!2:11..
Che~~~kaJ Family-Ethers Reid VPGT Preaun (]lila).. _L_
Vpor P'reDun 46'C (115'F') (plla)... ___.1.__
PollutiOII C.tqory-USEPA - - - IMO ~ Vapor De.:lty (Air = 1.0) .......................... --2...4i._
Applicable Bulk Reg. 46 CFR S111xbapter ........ _.Q__ Solubility t. Water S!isiDt

Electric:aJ Group-C
Geneni.-Extremely flammable; may form explosive peroxides. Flashback along vapor trail may occur. Vapor
may explode if ignited in an enclosed area.
Flub Point ('F) .. less than -50 (cc)

flammab&e Umlb .. 1.7 to 28%
Autoipldon Te111p. ('F) . 395
Extin&UbbiDR Aaet~b- .. Alcohol foam, foam, CO.. dry chemical.
Special Fire Proc:edura ... Wear goggles and sen-contained breathing apparatus. Water may be
ineffective on fire. Cool e11posed tanks with water.
HEALTH HAZARD DATA

Heald! }faqrr( Ratiap OdOI" Thra.hold (ppm) PEL/IWA <pp.l) TLV/IWA (IIIJIII)
General-Vapor or liquid may be irritating to skin and eyes. Concentrated vapors resuh in rapid anesthetic effect
and loss of consciousness.
Symp1oms-E11cltement followed by unconsciousness and respiratory paralysis. Prolonged Skin contact causes
dermatitis.
Short Exposure Tolerance-Data not available.
Exposure Procedurer~-Remove from area and administer artificial respiration Of oxygen if necessary. A"oh
affected areas with large amounts of water.
REACfiVITY DATA
Stflbility-Can react vigorously with o11idizing materials.
CompatibUlty-Mterial:

Wear goggles, sell-contained breathing apparatus, rubber gloves. Stay upwind, knock vapors down with water
spray. Secure ignitioo sources as dangerous permddas form upon heating.
If P'U oceu...., eall tile N~ ae.,.- Cater, 800-424-IIOl.

Relltalb: t Unavmlable
306
VINYLIDENE CHLORIDE
Sy-yma- 1 , 1-DichlorOethene; 1, 1-0ichloroethyleoe;
asym-Dichloroethylene; Ethene, 1,1-dlchloro-
CHRIS Code ...
Formula-C4:H.cl.
BolliD& PolDt .. _azc --B'F
Appearance-Odor-Colorless ftquid; sweet odor
___c ___F
Frenlna Polat... ----=..l.23'C ~'F
Speelftc Grarit)'-1.21
___ c ___F
Vapor Preaare lO'C (611'FJ <mHII) ..
Chemlatl FllllliJy-Vlnyl halide ReJd Vapor Pre.ure (,.ta)...
Vapor Preaure 46'C (115'F) (IJ'Ia) ...
Polludoa C.te&WY-USEPA ____IL_ IMO ____L_ VIIJIOI' Deu.lty (Air = 1.0) ...
Applk:able lkdk Ret- 46 CFR Subc:Upter ....... ____2__ SolubWty ill w.._ ..

Electrical Gro~D
General-Dangerous tire hazard; extremely flammable. Combustion products include hydrogen chloride and
poisonous phosgene. Fire may result in violent rupture ol tank due to polymerization.
F1ada Poblt ('F) .. 0

Jllammallle lJmJtl .. 5.6 to 16.0%
A11tolpidoll Temp. ('F') .. 1058
ExtlllplllliD& AllftU ....... Carbon dioxide, dry chemical, foam, water fog
s,eew Fire Proeedarell .... Keep tank cool with water spray. Wear eye protection, self-contained
HEALTH HAZARD DATA

HealOI Huard Rati~~p Odor n.reuow q,p.J PEL/IW A (ppm) TLV;rw A (ppm)
2, 2, 3 500 to 1000 1 5
Geaerai-Suspected carcinogen. Liquid irritating on contact. Vapor harmful and has narcotic effect.
s,...p~oms-Dizziness, nausea, and Sleepiness. Uquid causes skin bums and eye Irritation.
Sltort EllJIOIW't Toleruc:e-lnhalation of 4000 ppm rapidly produces symptoms ol drunkenness:

unconsciousness may follow shorUy afterward.
Eli:,....-e PrGc:ecturs-Vapor-remove vJctim to fresh air; if breathing stops, apply artifiCial respiration. Skin or
REACllVITY DATA
StUJIIty-Will polymerize if exposed to heat and air. This commodity must be inhibited for shipment.
eom,.tllrilhy-Malerial.: Copper and copper alloys are unsuitable.

Wear rubber gloves. self-contained breathing apparatus, and protective clothing. Avoid contact with liquid.
Secure Ignition sources. Do not flush spill into confined spaces where flammable vapors can accumt.~late.
If .-lpW occun, c:a11 tke Natloul Relpoue Ceoter,IIJO.-.t24-810l,
a-u Vapor Pressure-. 400 mmHg at 14.4'C.
307
VINYL TOLUENE
S~ Methylstyrene; para-Methylatyrene;
Tolylethylene
CHRIS Code ..
-
A~ss
Spec:lfte Gra-rity-0.90
~ FamilY-Olefin
liquid with a d"1tagreaable
PolludH C.le&Orr-USEPA - - - IMO _ A _

Boillll& PoilU..
FreezlllaPobtt...
----..l9'C --...aa!'F
_ -ZZ"C
___
Vapor Pre.ure lti'C (61'Fl <.aHa~ ...
Rekl Vapor ~re (. .)...
V..,or ~ <M'C (115'Fl (,.W..
Vapor DenRI)' Wr = 1.0)...
c
.
-10]"F
c ___
'F
'F
__J.i,_
___2.2L
.....QJL.
__!.2ll_
Applkatlle Bulk Rea. 46 CFR Subdulpter ....... ____Q_ SolaWUty Ill Water.. S!jght

Fledrica1 Groa,_o
Geaerai-Combuslion may evolve toxic gases such as carbon monoxide. Moderate fn hazard when exposed to
heat Of flame. Fire may cause violent rupture ol tank due to polymerization.
Flub Polat ('FJ .. 127

Flam-ble Ultl .. 0.8 to 11%
Awtoipltloa T-p. ('F) .. 914
Extinpldilq Ap.t. ... CO.. foam, water log
SpMJal Are Procedura .. Wear goggles and seH-contained breathing apparatus. Cool fire exposed tanks
with water.
HEALTii HAZARD DATA

Heald~ Haanl lbtiap Odor ThraboW. Qlpm) PEL/I'WA <Pf'll) TLVITWA (ppm)
2, 1, 1 above 10 100 50
General-Irritation; narcotiC.
Sympto-liquid-skin Irritation. blistering. Vapor-eye and nasal irritation.
Short Exposure Toleraare-400 ppm lor 5 minutes.
Ka:ponre ProeedW"-Vapor-remove vtctim to fresh air, if breathing stops, apply artificial respiration. Skin or
eye contact-remove contaminated clothing and gently wash affected areas with water.
REACIIVITY DATA
StabWty-Mey polymerize if exposed to heat and uninhibited. can react with oxidizing materials.
Com,.dbillty-Materilll: Usual materials of construction are suitable.
Caract: Group 13 of compatibility ct\art.

Weer rubber gloves, face shield, protectiYe clothing. Have all-purpose canister mask available. Avoid contact
If a .,W ocean. caU tile Natioaal aea,o- Cater, IJ00-4:Z4 1102.
308
o-XYLENE
Synonyms-Benzene, dimethyl-: 1,2-Dimethyl benzene: United Nat!ona Number ...
Orthoxylene; ortho-Xylene; Xylol
CHRIS Code ..
Fonnula-C.H,(CH.,),
Bollin11 Point .. ~-c_mF
Appurance-Odor-Colorless liquid; benzene-like
___ c ___.F
aromatic odor Freezing Point .. ~c~F
Spedfic GraYity-0.89 c ___ "F
Vapor Pre.ure lO'C (68'FJ (mmHg)..
Chemical Family-Aromatic hydrocarbons Reid Vapor Pressure (pail) ... _.Q.2L
Vapor Pressure 46'C Ul!I'FJ (psla) ... ~
Pollution Category-USEPA _____Q_ IMO ___Q:_ Vapor Dentlty {Air = 1.(1) ..... __a._
Applicable Bulk Re11. 46 CFR Subchapter.. _Q._Q_ Solubility In Water .. NeqliRjble

Grade-D Combustible liquid
Elec:trital Group-O
General-Moderate fire hazard, when exposed to heat or flame. Flashback along vapor trail may occur. Vapor
may explode 11 ignited in an enclcored area.
F1uh Point (" FJ .. 9{)

F1ammable Limits 1.1 to 7.0%
Autoignition Temp. ("FJ 867
ExtiniJillsblna Aaenb .. C0 2 dry chemical, loam, water log
Special Fire Procedures ... Water may be ineffective but water should be used to keep lire-exposed
containers cool. 11 a leak or spill has not ignited, use water spray to disperse the vapors and to protect
personnel attempting to stop a leak. Water spray may be used to flush spills away from exposures.
HEALTH HAZARD DATA

Health Hauord Ratinp Odor Threshold (ppm) PEL/fW A (ppm) TLVITW A (ppm)
1, 1, 2 0.05 100 100
General-Vapor inhalation harmful. Liquid irritating.
Symptoms-Headache. d1n1ness. staggenng, nausea, and drowsiness.
Short Exposure Tolerance-NarcosiS In ammals begins with inhalations of 2300-3500 ppm. Instances of
unconsciousness in humans from severe exposures have been described, but the specifiC concentrations
were unknown.
Exposure Procedures-Vapor-remove v1ct1m to fresh air; if breathing stops, apply artificial respiration. Skin or
eye contact-remove contaminated clothing and flush affected areas with water lor 15 minutes. Get medical
adv1ce or attention.
REACTIVITY DATA
Stability-Stable
Compatibility-Material: Most matenals of construction are satisfactory Rubber will swell and soften alter
prolonged exposure

Wear polyethylene gloves. face shield, protective clothing. Have all-purpose canister mask available. Avoid
contact w1th hquid. Secure ignition sources
If a spill oc:cun, call the Nat1011al Rnpon-e Center, 800-4U-880l.

Remarks: Po\lut10n Category C 011-hke, 33 CFR 151.49.
Vapor Pressure: to mmHg at 32.t'C.
309
mXYLENE
Syn011yms- Benzene, dimethyl-; 1,3-0imethyl benzene; United Nations Number ...
Metaxylene; meta-Xylene; Xylol
CHRIS Code ..
Appeanmce-Odor-Color!ess liquid; benzene-like

Bolllna PoiJit ..
___ c ___zaz'F
~c
___F
aromatic odor Freezlna Point .. --=~rc ~F
Spec:ltic Grnity-0.87 c ___.F
Vapor PrntUre lO'C (68'F') (mmH&) ..
Cbemleal F&mily-Aromatic hydrocarbons Reid Vapor Preaure (pill.) ... ..J!.aL
Vapor PreiiUre 46'C (ll!!'FJ (~a) .. ___M1_
Pollution Catqory-USEPA _____Q__ IMO ~ Vapor Density (Air = 1.0) .. ___a._
Appliuble Bulk Re11. 46 CFR Subchapter ........ ____ll._Q_ Solubility In Water .. lnsolyble

Electrical Group-O
General-Dangerous fire hazard and moderate explosion hazard when exposed to heat or flame. Flashback
along vapor trail may occur. Vapor may explode if ignited in an enclosed area.
Flash Point ('F) .. 77

Flammable U111itli .. 1.1 to 7.0%
Extinplahlng Agents .. Foam, co,, dry chemical
Specla1 Fire Procedures .. Water may be ineffective but water should be used to keep lire-e)(posed
containers cool. if a leak or spill has not ignited, use water spray to disperse the vapor and to protect
personnel attempting to stop a leak. Water spray may be used to flush spills away.
HEALTH HAZARD DATA

Health Huard Ratlnp Odor Threshold (ppm) PELifWA (ppm) TLVifWA (ppm)
1, 1, 2 0.05 100 100
General-Vapor inhalation has moderate systemic effect resulting in possible loss of consciousness.
Symptoms-Headache, confusion, nausea, dizziness. Dermatitis may result from repeated skin exposure.
Short Expo~~ure Tolerance-Narcosis in animals begins with inhalations of 2300-3500 ppm. instances of
unconsciousness in humans from severe exposures has been described, but the specific concentrations
were unknown. 300 ppm is the suggested short term inhalation limit.
Expo~~ure Procedu~Aemove from exposure; remove contaminated clothing, cleanse skin, and eyes. Artificial
respiration should be started immediately if breathing has stopped.
REACTIVITY DATA
Stllbillty-Stabie.
Compatibility-Materla1: Softens rubber; not corrosive to most metals.
Carsu: Group 32 of compatibility chart

Wear polyethylene gloves, face shield, protective clothing. Have ail-purpose canister mask available. Avoid
contact with liquid. Secure ignition sources. Wash up with water.
U a piU occurs, c:all the NatloDal Response Center, 800-4Z4-880l.
Remarks: Pollution Category C 01ll1ke, 33 CFA 151.49.

Vapor Pressure: 10 mmHg at 28.3"C.
310
pXYLENE
Sy110nys- Benzene, dimethyl-; 1,4-Dimethyl benzene; United NlltiOilll Nwnber ....
Paraxylene: para-Xylene: Xylol
CHRIS Code ..
Bolllq Pobat .. ---.mc __arF

Appearanee-Qdor-Colorless liquid; benzene-like c 'F
aromatic odor _____nc
___ c ~-F
___'F
Specific Gravlty-0.86
VllpOJ' Prellllure lO'C (68'F) <mmHI) ..
Chemical Fanrily-Aromatic hydrocarbons Rehl VQOr ~ (ptla)... ......Q.H_
Vapor~ 46'C (ll!I'Fl (plia).. ~
Pollution C.tqory-USEPA ~ IMO ~ Vapor Deuity (Air = 1.0).. .. .......... ~
Applluhle Bulk Rea. 46 CFR Subchapter ........ ____D._Q_ Solu.WI)' ill Water... Naq!jpjbla

Grlde-0: Combustible liquid
Electrical Group-O
GeneraJ-Moderate fire hazard, when exposed to heat or flame
Flul:r. Point ('F) .. 81

Flammable Llmib .. 1.1 to 7.0%
Autoiplt!OB Temp. ('F) .. 870
ExtinpiahiliK A~ab .. co,, dry chemical loam, water fog
Special Fire Procedures . Water may be ineffective but water should be used to keep lire-exposed
containers cool. If a leak or spill has not ignited, use water spray to disperse the vapoi'S and to protect men
attempting to stop a leak. Water spray may be used to flush spills away from exposures.
HEALTH HAZARD DATA

Health Hazard RltiDp Odor Thrubold (ppm) PEL/1W A (ppm) TLV/fWA (ppm)
1, 1, 2 0.05 100 100
General-Vapor inhalation harmful.
Symptoms-Headache, dizziness, nausea.
Sbort Ex)IOIIure Toleraace-Narcosis in animals begins with inhalation of 2300-3500 ppm. Instances of
unconsciousness in humans from severe exposures have been described, but the specific concentrations
were unknown.
Expo~~ure Procedures-Vapor-remove victim to fresh air; if breathing stops, apply artificial respiration. Skin or
REACTIVITY DATA
Stability-Stable.
ComplltibiUty-Mtlterial: Most materials of construction are suitable. Rubber exposed to xylene will swell, soften
and eventually deteriorate.

If '"'II occun, Cllll tlle NUoul RetpOIIM Ce1ter, IMJ0.-4l4 11801.

Remlrka: PollUtiOn Category C Ollllke, 33 CFR 151.49.
Vapor Pressure: 10 mmHg at 28.3C.
311
ZINC DIALKYLDITHIOPHOSPHATE
Synonyma- Zinc dihexyldithiophosphate; Zinc United Nations Number ...
dihexylphosphorodithioate
CHRIS Code ..
Formula-Indefinite
Rolling Point. .......... ~cm!li2Q.lU'C F
---.F
c ---.F
Appearance-Odor-Ugh! yellow liquid; sweet odor
Specific GraYity-1.10 to 1.12 at 20'C (liquid); 1.6 at

20'C (solid)
Olemieal Family-Unassigned
Freezing Point .. ............ P.!M oojnt 18'C
Vapor Preaure ZO'C (68'F) (mmHg) ..

c ==F
----"'"---
Reid Vapor Preaure (Pilla).. .. ----"'"---
Pollution Category-USEPA - - - IMO _____A__
Vapor Pressure 4(1'C (115'F) (ps'-l ...
Vapor Density (Air = 1,0) ..
----"'"---
AppUuble Bulk Rea. 46 CFR Subcbapttr ....... _Q._Q_ Solubility In Water .. Negj";jiibje

Grade-D or E: Combustible liquid
E1ectrlcal Group-NA
General-Hydrogen sulfide vapors may be evolved if the material is heated in excess of 150'F.
H.h Point ("F) .. -150

Flammable Llmltl .. Unavailable
Autolpltlon Temp. ("F) .. Unavailable
Extinplahln.g Agentl .. Dry chemical, CO.
Special Fire Proeedures .. Fire fighters should be equipped with self-contained breathing apparatus.
HEALTH HAZARD DATA

HeaJtb Huard Ratlnp Odor Thrabold (ppm) PEL/fWA (ppm) TLV/TWA (Jipm)
Unavailable 0.7 10 ppm (H.S) 10 ppm (H-,5)
General-Irritating on prolonged contact with the skin; severe swelling and destruction of tissue may result in a
few hours. There is tlO inhalation hazard at room temperature. Sk"1n penetration is high, but there "1s tlO
hazard.
Symptoms-Red, swollen skin: coughing.
Sbort E:~l"l'ure ToJeranee-Skin penetration at toxic levels-3.16 milliliters per 1000 grams of body weight; no
illness in 6 hour exposure. Minimum concentration found fatal after one hour exposure-600 ppm (H.S).
E:~IIO'ure Proceduree-Unavailable.
REACI1VITY DATA
Stllhlllty-Antioxidant, may decompose with evolution of H.S if heated about 150F. Contamination by acid may
set up conditions for evolution of H.S. Contamination by water effects stability.
Con~p~~tlhUity-Miterlal:No corrosive or destructive effect on steel, wood or cloth. Normal matmials may be
used; may soften natural rubber and some paints.

Rubber protective clothing, self-contained breathing apparatus, etc. Cover with soda ash. Clean up and
neutralize with diluted hydrochloric acid and wash with excess water.
If 1 qHII oteun, eall tbe NMJoaaJ RelpOIIM Center, 800-414 1801.

Re.arks: ; Unassigned
312
SYNONYM INDEX
Many chemicals have several names. Of these, one may be a

common name and several are chemical names. Many chemicals also
use trade names.
In this book an attempt was made to list the data sheets by the
names most likey to be used. Trade names were omitted in most cases.
An attempt was made to list every synonym likely to be in use in
the bulk shipping industry.
In listing these chemicals, a single-letter, greek-letter or a numeri-
cal prefix was ignored in alphabetizing.
To Find Look Up
A
p-Acetaldehyde Paraldehyde
Acetic acid anhydride Acetic anhydride
Acetic acid, butyl ester n-Butyl acetate
Acetic acid, iso-butyl ester iso-Butyl acetate
Acetic acid, ethenyl ester Vinyl acetate
Acetic acid, ethyl ester Ethyl acetate

Acetic acid glacial Acetic acid
Acetic acid, isopropyl ester iso-Propy I acetate
Acetic acid, methyl ester Methyl acetate
Acetic acid, 1-methylpropyl ester sec-Butyl acetate
Acetic acid, n-propyl ester n-Propyl acetate

Acetic acid, sec-butyl ester sec-Butyl acetate
Acetic acid, vinyl ester Vinyl acetate
Acetic aldehyde Acetaldehyde
Acetic ester Ethyl acetate
Acetic ether Ethyl acetate

Acetic oxide Acetic anhydride
Acetylene tetrachloride I, I ,2,2-Tetrachloroethane
Acetyl oxide Acetic anhydride
Acroleic acid Acrylic acid
Aery lamide monomer Acrylamide solution
313
To Find Look Up
Acrylic acid amide Acrylarnide solution

Acrylic acid, iso-butyl ester iso-Butyl acrylate
Acrylic acid, n-butyl ester n-Butyl acrylate
Acrylic acid, ethyl ester Ethyl acrylate
Acrylic acid, 2-ethylhexyl ester 2-Ethylhexyl acrylate

Acrylic acid, isodecyl ester iso-Decyl acrylate
Acrylic acid, methyl ester Methyl acrylate
Acrylic amide Acrylamide solution
Albone Hydrogen peroxide
Alcohol Ethyl alcohol

Alcohol anhydrous Ethyl alcohol
Alcohol C-1 Methyl alcohol
Alcohol C-1 0 n-Decyl alcohol
Alcohol C-13 Tridecanol
Alcohol C-2 Ethyl alcohol

Alcohol C-3 Propyl alcohol, iso- or n-
isomers
Alcohol C-4 Butyl alcohol, iso-, n-, sec-
or tert- isomers
Alcohol C-5 n-Amyl alcohol

Alcohol C-6 Hexanol
Alcohol C-8 2-Ethyl hexanol or iso-Octyl
alcohol
Aldehyde Acetaldehyde
Aldehyde-collidine 2-Methyl-5-ethylpyridine
Aldehydine 2-Methyl-5-ethylpyridine
Alkylbenzene Dodecylbenzene
Alkyl (C7-C9) nitrate 2-Ethyl hexyl nitrate
Allene-methyl acetylene mixture Methyl acetylene-Propadiene
mixture
Allyl trichloride 1,2,3-Trichloropropane

Aminobenzene Aniline
1-Aminobutane n-Butylamine
2-Aminobutane sec-Butylamine
2-Arninoisobbtane tert-Butylamine
314
To Find Look Up
An Acrylonitrile
Anesthesia ether Ethyl ether

Anesthetic ether Ethyl ether
Aniline oil Aniline
Anprolene Ethylene oxide
Ant oil, artificial Furfural
Aqua ammonia Ammonia solutions

Aqua fortis Nitric acid (56 to 68%)
Aqua fortis Nitric acid (95%)
Arachis oil Peanut oil
Artificial oil of ants Furfural
Asphalt bitumen Asphalt

Asphalt cement Asphalt
Asphaltum Asphalt
Asymmetrical Dichloroethane 1,1-Dichloroethane
Azabenzene Pyridine
Azacyclohelane Hexamethyleneimine
Azine Pyridine
Azotic acid Nitric acid (56 to 68%)
Awtic acid Nitric acid (95%)
B
Babulum oil Neatsfoot oil
Banana oil iso-Amyl acetate
Battery acid Sulfuric acid
BBP Butyl benzyl phthalate
Benenamine Aniline
Benzenamine Aniline
Benzene carbinol Benzyl alcohol
Benzene chloride Chlorobenzene
Benzene, chloro- Chlorobenzene
Benzene, chloromethyl- Benzyl chloride
Benzene concentrate Benzene, Toluene, Xylene

mixtures
Benzenediamine, ar-methyl- Toluenediamine
316
To Find Look Up
1,2-Benzenedicarboxylic acid Phthalic anhydride
anhydride
Benzene, 1,2-dichloro- o-Dichlorobenzene

Benzene, 1,3-diisocyanatomethyi- Toluene diisocyanate
Benzene, dimethyl- Xylene, o-, m- or p- isomers
Benzene, hexahydride Cyclohexane
Benzene, hexahydro- Cyclohexane
Benzene, hydroxy- Phenol

Benzene, methyl- Toluene
Benzene, 1-methylethyi- Cumene
Benzene, nitro- Nitrobenzene
Benzin Gasoline, motor
Benzinoform Carbon tetrachloride

Benzol Benzene
Benzole Benzene
Benzyl n-butyl phthalate Butyl benzyl phthalate
Bicarburetted hydrogen Ethylene
Biethylene Butadiene
Bimethyl Ethane
Biphenyl-diphenyl ether mixture Diphenyl-Diphenyl ether
mixture
Bis(2-chloroethyl)ether 2,2' -Dichloroethyl ether
Bitumen Asphalt
Bivinyl Butadiene
Blue oil Aniline
Bottled gas Liquefied petroleum gas
Brazil wax Carnauba wax
Brimstone Sulfur, molten
Bromofume Ethylene dibromide

Bromomethane Methyl bromide
BTX mixtures Benzene, Toluene, Xylene
mixtures
1,3-Butadiene Butadiene
alpha, gamma-Butadiene Butadiene
317
To Find Look Up
Butaldehyde n-Butyraldehyde
Butanal n-Butyraldehyde
n-Butanal n-Butyraldehyde
1-Butanamine n-Butylamine
2-Butanamine sec-Butylamine
1-Butanamine, N-butyl- Dibutylamine
Butane n-Butane
Butane-1,3-diol 1,3-Butylene glycol
1,3-Butanediol 1,3-Butylene glycol
Butanic acid n-Butyric acid

Butanoic acid n-Butyric acid
Butanol n-Butyl alcohol
!-Butanol n-Butyl alcohol
2-Butanol sec-Butyl alcohol
2-Butanol acetate sec-Butyl acetate

n-Butanol n-Butyl alcohol
Butanols Butyl alcohol, n-, sec- or
tert- isomers
sec-Butanol sec-Butyl alcohol
tert-Butanol tert-Butyl alcohol

2-Butanone Methyl ethyl ketone
2-Butenal Crotonaldehyde
trans-2-Butenal Crotonaldehyde
Butene Butylene
cis-Butenedioic anhydride Maleic anhydride

Butene resins Polybutene
1-Butoxy butane n-Butyl ether
Butoxydiethylene glycol Diethylene glycol butyl
ether
2-Butoxy ethanol Ethylene glycol butyl ether
2-(2-Butoxyethoxy)ethanol Diethylene glycol butyl
ether
Butyl acetate iso-Butyl acetate
Butyl acetate n-Butyl acetate
normal-Butyl acetate n-Butyl acetate
318
To Find Look Up
Butyl alcohol n-Butyl alcohol

Butyl aldehyde n-Butyraldehyde
iso-Butyl aldehyde iso-Butyraldehyde
n-Butyl aldehyde n-Butyraldehyde
Butylamine Butylamine, iso-, n-, sec- or
tert- isomers
Butylamine n-Butylamine
N-Butyl-1-butanamine Dibutylamine
n-Butylcarbinol n-Amyl alcohol
Butyl Carbitol Diethylene glycol butyl
ether
Butyl Cellosolve Ethylene glycol butyl ether
Butyl diglycol Diethylene glycol butyl

ether
Butyl dioxitol Diethylene glycol butyl
ether
!-Butene Butylene
alpha-Butylene Butylene
beta-Butyleneglycol 1,3-Butylene glycol
Butylene hydrate sec-Butyl alcohol

1,2-Butylene oxide, stabilized 1,2-Butylene oxide
alpha-Butylene oxide 1,2-Butylene oxide
Butyl ethanoate n-Butyl acetate
Butyl ether n-Butyl ether
Butyl 2-methacrylate Butyl methacrylate

n-Butyl methacrylate Butyl methacrylate
n-Butyl alpha-methacrylate Butyl methacrylate
tert-Butyl methyl ether Methyl tert-butyl ether
Butyl 2-methyl-2-propenoate Butyl methacrylate
Butyl oxitol Ethylene glycol butyl ether

n-Butyl-2-propenoate n-Butyl acrylate
Butyraldehyde n-Butyraldehyde
Butyric acid n-Butyric acid
Butyric alcohol n-Butyl alcohol
Butyric aldehyde n-Butyraldehyde
319
To Find Look Up
c
Camphor tar Naphthalene
Capric alcohol n-Decyl alcohol
epsilon-Caprolactam Caprolactam solution
Carbinol Methyl alcohol
Carbitol solvent Diethylene glycol ethyl
ether
Carbolic acid Phenol

Carbon bisulfide Carbon disulfide
Carbon bisulphide Carbon disulfide
Carbon disulphide Carbon disulfide
Carbon tet Carbon tetrachloride
Cellosolve Acetate Ethylene glycol ethyl ether

acetate
Cellosolve Solvent Ethylene glycol ethyl ether
Chamber acid Sulfuric acid
Chinese bean oil Soybean oil
Chlorallylene Allyl chloride

Chlorate of soda Sodium chlorate solution
2-Chlorethanol Ethylene chlorohydrin
Chlorex 2,2'-Dichloroethyl ether
Chlorinated hydrochloric ether I, 1-Dichloroethane
Chloroacetic acid, liquid Chloroacetic acid

alpha-Chloroallyl chloride I, 3-Dichloropropene
gamma-Chloroallyl chloride 1,3-Dichloropropene
Chlorobenzol Chlorobenzene
1-Chloro-2,3-epoxypropane Epichlorohydrin
3-Chloro-1 ,2-epoxypropane Epichlorohydrin

Chloroethane Ethyl chloride
2-Chloroethanol Ethylene chlorohydrin
Chloroethene Vinyl chloride
2-Chloroethyl alcohol Ethylene chlorohydrin
Chloroethylene Vinyl chloride

Chloroethyl ether 2,2'-Dichloroethyl ether
320
To Find Look Up
bis(2-Chloroethyl)ether 2,2' -Dichloroethyl ether

bis-beta-Chloroethyl ether 2,2' -Dichloroethyl ether
Chlorohydric acid Hydrochloric acid
bis(2-Chloroisopropyl)ether 2,2'-Dichloroisopropyl ether

Chloromethane Methyl chloride
(Chloromethyl)benzene Benzyl chloride
Chloromethyloxirane Epichlorohydrin
1-Chloro-2-nitrobenzene o-Chloronitrobenzene
2-Chloro-1-nitrobenzene o-Chloronitrobenzene
Chloronitrobenzenes o-Chloronitrobenzene
Chlorophenols, liquid 2,4-Dichlorophenol
1-Chloro-2-propene Allyl chloride
3-Chloropropene Allyl chloride
3-Chloro-1-propene Allyl chloride

3-Chloropropylene Allyl chloride
alpha-Chloropropylene Allyl chloride
2-Chloropropylene oxide Epichlorohydrin
gamma-Chloropropylene oxide Epichlorohydrin
Chlorosulfuric acid Chlorosulfonic acid

Chlorothene I, I, 1-Trichloroethane
alpha-Chlorotoluene Benzyl chloride
omega-Chlorotoluene Benzyl chloride
Chlorox Sodium hypochlorite
solution
Chlorsulfonic acid Chlorosulfonic acid

Chlorsulfuric acid Chlorosulfonic acid
Chlorylen Trichloroethylene
Cidex Glutaraldehyde solution
Cinnamene Styrene monomer
Cinnamol Styrene monomer
Coal naphtha Benzene
Coal oil Crude oil
Coal oil Kerosene
Coal tar creosote Creosote, coal tar
321
To Find Look Up
Coal tar distillate Coal tar
Coal tar light oil Benzene, Toluene, Xylene
mixtures
Coal tar naphtha Benzene
Cod oil Rosin oil
Coke oven light oil Benzene, Toluene, Xylene

mixtures
Colamine Ethanolamine
Cologne spirit Ethyl alcohol
Colonial spirits Methyl alcohol
Columbian spirits Methyl alcohol

Creosote from coal tar Creosote, coal tar
Creosote oil Creosote, coal tar
Cresol (2-, 3-, 4-) Cresols
Cresylic acid Cresols
Cresylol Cresols
o-Cresyl phosphate Tricresyl phosphate
Crotenaldehyde Crotonaldehyde
Crotonaldehyde, stabilized Crotonaldehyde
Crotonic aldehyde Crotonaldehyde
Crude coal tar Coal tar

crude Epichlorohydrin Chlorohydrins (crude)
Crude solvent coal tar naphtha Coal tar naphtha solvent
Crystalite Methyl methacrylate
Cumol Cumene
Cyanoethane Propionitrile
2-Cyanoethanol Ethylene cyanohydrin
Cyanoethylene Acrylonitrile
Cyanomethane Acetonitrile
2-Cyanopropene Methacrylonitrile
Cychlohexanamine Cyclohexylamine
Cyclohexatriene Benzene
Cyclohexyl alcohol Cyclohexanol
Cyclohexyl ketone Cyclohexanone
Cyclopentadiene Dicyclopentadiene
322
To Find Look Up
1,3-Cyclopentadiene Dicyclopentadiene
1,3-Cyclopentadiene dimer Dicyclopentadiene
Cymol p-Cymene
D
DCEE 2,2'-Dichloroethyl ether
D.O. turpentine Turpentine
DEA Diethanolamine
Dead oil Creosote, coal tar
DEAE Diethylethanolamine
Deanol Dimethylethanolamine
1-Decanol n-Decyl alcohol
decylbenzenesulfonic acid; Un-, Alkylbenzenesulfonic acid
Do-, Tri-, Tetra-, Penta- or
Hexa-
DEG Diethylene glycol

DEN Diethylamine
Denatured alcohol Ethyl alcohol
Detergent alkylate #2 Dodecylbenzene
0-Glucitol Sorbitol
Diacetone Diacetone alcohol

2,4-Diaminotoluene Toluenediamine
2,2'-Diaminodiethylamine Diethylenetriamine
1,2-Diaminoethane Ethylenediamine
I, 11-Diamino-3,6,9- Tetraethlyenepentamine
triazaundecane
Diammonium sulfide solution Ammonium sulfide solution

DIBK Diisobutyl ketone
1,2-Dibromoethane Ethylene dibromide
sym-Dibromoethane Ethylene dibromide
Di-n-butylamine Dibutylamine
n-Dibutylamine Dibutylamine
Di-(n-butyl)amine Dibutylamine
Dibutyl ether n-Butyl ether
Di-n-butyl ether n-Butyl ether
n-Dibutyl ether n-Butyl ether
323
To Find Look Up
Dibutyl ethers n-Butyl ether

Dibutyl oxide n-Butyl ether
I ,2-Dichlorobenzene o-Dichlorobenzene
o-Dichlorobenzol o-Dichlorobenzene
2,2'-Dichlorodiethyl ether 2,2'-Dichloroethyl ether
I ,2-Dichloroethane Ethylene dichloride

sym-Dichloroethane Ethylene dichloride
I, 1-Dichloroethene Vinylidene chloride
Dichloroether 2,2'-Dichloroethyl ether
I, 1-Dichloroethylene Vinylidene chloride
asym-Dichloroethylene Vinylidene chloride

Dichloroethyl ether 2,2'-Dichloroethyl ether
beta, beta' -Dichloroethyl ether 2,2' -Dichloroethyl ether
sym-Dichloroethyl ether 2,2'-Dichloroethyl ether
Dichloroethyl oxide 2,2'-Dichloroethyl ether
Dichloroisopropyl ether 2,2'-Dichloroisopropyl ether

Dichlorophenol 2,4-Dichlorophenol
Dichloropropane I ,2-Dichloropropane
Dichloropropene I ,3-Dichloropropene
1,3-Dichloropropylene I ,3-Dichloropropene
alpha, gamma-Dichloropropylene I ,3-Dichloropropene

Dicy; 3a, 4, 7, 7a Dicyclopentadiene
I ,4-Dicyanobutane Adiponitrile
Dicyclo-1 ,4-pentadiene Dicyclopentadiene
Diesel fuel Diesel oil
Diethyl n-Butane
Diethylaminoethanol Diethylethanolamine
2-Diethylaminoethanol Diethylethanolamine
2-N-Diethylaminoethanol Diethylethanolamine
2-Diethylaminoethyl alcohol Diethylethanolamine
beta-Diethylaminoethyl alcohol Diethylethanolamine

Diethylbenzene (1,2-, 1,3- or 1,4-) Diethylbenzene
Diethylbenzene; m- or o- isomers Diethylbenzene
Diethylene dioxide I ,4-Dioxane
1,4-Diethylenedioxide I ,4-Dioxane
324
To Find Look Up
Diethylene ether 1,4-Dioxane

Diethylene imidoxide Morpho line
Diethylene oxide 1,4-Dioxane
Diethylene oxide Tetrahydrofuran
Diethylene oximide Morpholine
Diethylenimide oxide Morpholine

N ,N-Diethy lethanamine Triethylamine
N,N-Diethylethanolamine Diethylethanolamine
Diethyl ether Ethyl ether
Di-(2-ethylhexyl)phthalate Dioctyl phthalate
Diethyl-(2-hydroxyethyl)amine Diethylethanolamine
Diethylolamine Diethanolamine
Diethyl oxide Ethyl ether
Difluorochloromethane Chlorodifluoromethane
Difluorodichloromethane Dichlorodifluoromethane
Difluoromonochloromethane Chlorodifluoromethane
1,3-Diformylpropane Glutaraldehyde solution
Diglycol Diethylene glycol
Diglycol monobutyl ether Diethylene glycol butyl
ether
1,3-Dihydroxybutane 1,3-Butylene glycol
2,2'-Dihydroxydiethylamine Diethanolamine
Dihydroxydiethyl ether Diethylene glycol
2,2'-Dihydroxydipropylamine Diisopropanolamine
2,2-Dihydroxydipropyl ether Dipropylene glycol
1,2-Dih ydroxyethane Ethylene glycol
Di-beta-hydroxyethoxyethane Triethylene glycol

Di-(2-hydroxyethyl)amine Diethanolamine
2,2'-Dihydroxyethyl ether Diethylene glycol
2,2'-Dihydroxyisopropyl ether Dipropylene glycol
Diisobutene Diisobutylene
Diisobutylene, isomeric camp's Diisobutylene

2,4-Diisocyanatotoluene Toluene diisocyanate
4,4-Diisocyanodiphenylmethane Diphenylmethane
diisocyanate
325
To Find Look Up
sym-Diisopropylacetone Diisobutyl ketone
sym-5-Diisopropylacetone Diisobutyl ketone

Diisopropyl ether iso-Propyl ether
Diisopropyl oxide iso-Propyl ether
Dimethyl Ethane
Dimethylamine, anhydrous Dimethylamine
2-(Dimethylamino)ethanol Dimethylethanolamine
beta-Dimethylaminoethyl alcohol Dimethylethanolamine
Dimethyl benzene Xylene, o~, m- or p- isomers
1,2-Dimethyl benzene o-Xylene
1,3-Dimethyl benzene m-Xylene
1,4-Dimethyl benzene p-Xylene

1,3-Dimethylbutyl acetate Methyl amyl acetate
Dimethyl carbinol iso-Propyl alcohol
Dimethylene oxide Ethylene oxide
Dimethyl ethylamine tert-Butylamine
1,1-Dimethylethylamine tert-Butylamine
N,N-Dimethylformamide Dimethylformamide
2,6-Dimethyl-4-heptanol Diisobutyl carbinol
2,6-Dimethyl-4-heptanone Diisobutyl ketone
Dimethyl-1-hexanol iso-Octyl alcohol
N,N-Dimethyi-N-(2- Dimethylethanolamine
hydroxyethyl)amine
Dimethyl ketone Acetone
Dimethylmethane Propane
Dioxan 1,4-Dioxane
Dioxane 1,4-Dioxane
p-Dioxane I ,4-Dioxane
1,3-Dioxophalan Phthalic anhydride
DIPA Diisopropanolamine
DIPA Diisopropylamine
Diphenyl-diphenyl oxide mixture Diphenyi-Diphenyl ether

mixture
326
To Find Look Up
4,4' -Diphenylmethane Diphenylmethane
diisocyanate diisocyanate
Diphenylmethane-4,4'- Diphenylmethane
diisocyanate diisocyanate
Diphenyl oxide-diphenyl mixture Diphenyl-Diphenyl ether

mixture
Dipropylamine Di-n-propylamine
Dipropy!methane Heptane
Dithiocarbonic anhydride Carbon disulfide
Divinyl Butadiene
DMA Dimethylmethyl amine
DMF Dimethylformamide
DMFA Dimethylformamide
n-Dodecylbenzene Dodecylbenzene
Dodecylbenzenesulfonic acid Alkylbenzenesulfonic acid

alpha-Dodecylene Dodecene
Dolcymene p-Cymene
DOP Dioctyl phthalate
Dowanol DB Diethylene glycol butyl
ether
Dowanol DE Diethylene glycol ethyl

ether
Dowanol DM Diethylene glycol methyl
ether
Dowanol EB Ethylene glycol butyl ether
Dowanol EE Ethylene glycol ethyl ether
Dowanol EM Ethylene glycol methyl

ether
Dowtherm A Diphenyl-Diphenyl ether
mixture
Dowtherm E o-Dichlorobenzene
DPA Di-n-propylamine
Dripolene Benzene, Toluene, Xylene

mixtures
Drycleaners naphtha Naphtha: Stoddard solvent
327
To Find Look Up
Drycleaners safety solvent Naphtha: Stoddard solvent
Dutch liquid Ethylene dichloride
Dutch oil Ethylene dichloride
E
Earthnut oil Peanut oil
EB Ethylbenzene
EDB Ethylene dibromide
EDC Ethylene dichloride
Edible tallow Tallow
EE Solvent Ethylene glycol ethyl ether

Ektasolve DB Solvent Diethylene glycol butyl
ether
Ektasolve DE Solvent Diethylene glycol ethyl
ether
Ektasolve DM Solvent Diethylene glycol methyl
ether
Ektasolve EB Solvent Ethylene glycol butyl ether

Elayl Ethylene
Embafume Methyl bromide
Engravers acid Nitric acid (56 to 68%)
Engravers acid Nitric acid (95%)
Engravers oil Nitric acid (56 to 68%)

Engravers oil Nitric acid (95%)
EO Ethylene oxide
1,2-Epoxybutane 1,2-Butylene oxide
Epoxyethane Ethylene oxide
1,2-Epoxyethane Ethylene oxide

1,2-Epoxypropane Propylene oxide
Erythrene Butadiene
Essence of mirbane Nitrobenzene
Ethanal Acetaldehyde
Ethane carboxylic acid Propionic acid

1,2-Ethanediamine Ethylenediamine
Ethane, I ,2-dibromo- Ethylene dibromide
328
To Find Look Up
Ethane, I, 1-dichloro- I, 1-Dichloroethane

Ethane, I ,2-dichloro- Ethylene dichloride
1,2-Ethanediol Ethylene glycol

I ,2-Ethanediol diacetate Ethylene glycol diacetate
Ethanenitrile Acetonitrile
Ethane, 1,1'-oxybis- Ethyl ether
Ethane, I, I' -oxybis[2-chloro- 2,2'-Dichloroethyl ether
Ethane, pentachloride Pentachloroethane

Ethane, pentachloro- Pentachloroethane
Ethane, I, I ,2,2-tetrachloro- I, I ,2,2-Tetrachloroethane
Ethane, I, I, !-trichloro- I, I, 1-Trichloroethane
Ethane trichloride I, I ,2-Trichloroethane
Ethane, 1,1,2-trichloro- I, I ,2-Trichloroethane

Ethanoic acid Acetic acid
Ethanoic anhydride Acetic anhydride
Ethanol Ethyl alcohol
Ethanol, 2-butoxy- Ethylene glycol butyl ether
Ethanol, 2-ethoxy- Ethylene glycol ethyl ether

Ethanol, 2-ethoxy-, acetate Ethylene glycol ethyl ether
acetate
Ethanol, 2-methoxy- Ethylene glycol methyl
ether
Ethene Ethylene
Ethene, chloro- Vinyl chloride

Ethene, I, 1-dichloro- Vinylidene chloride
Ethene, tetrachloro- Perchloroethylene
Ethene, trichloro- Trichloroethylene
Ethenylbenzene Styrene monomer
Ether Ethyl ether

Ether, bis(2-chloro-1-methylethyl) 2,2'-Dichloroisopropyl ether
Ether cyanatus Propionitrile
Ether, hydrochloric Ethyl chloride
Ethinyl trichloride Trichloroethylene
Ethoxyethane Ethyl ether
329
To Find Look Up
2-Ethoxyethanol Ethylene glycol ethyl ether

Ethoxyethene Vinyl ethyl ether
2-Ethoxyethylacetate Ethylene glycol ethyl ether
acetate
Ethylacetic acid n-Butyric acid

Ethyl aldehyde Acetaldehyde
Ethylamine, anhydrous Ethylamine
Ethylamine, aqueous solutions Ethylamine solution
Ethylbenzol Ethylbenzene
2-Ethylbutanol Ethyl butanol

2-Ethyl-1-butanol Ethyl butanol
2-Ethyl butyl alcohol Ethyl butanol
Ethyl carbinol n-Propyl alcohol
Ethyl cyanide Propionitrile
Ethyl dimethylmethane iso-Pentane

Ethylene acetate Ethylene glycol diacetate
Ethylene alcohol Ethylene glycol
Ethylene bromide Ethylene dibromide
Ethylene carboxylic acid Acrylic acid
Ethylene chlorhydrin Ethylene chlorohydrin

Ethylene chloride Ethylene dichloride
Ethylene diacetate Ethylene glycol diacetate
Ethylenediamine, anhydrous Ethylenediamine
Ethylene dihydrate Ethylene glycol
2,2'-Ethylene dioxybis(ethanol) Triethylene glycol

2,2'-Ethylene dioxydiethanol Triethylene glycol
Ethylene glycol monoacrylate 2-Hydroxyethyl acrylate
Ethylene glycol dihydroxy- Triethylene glycol
diethyl ether
Ethylene glycol monoethyl ether Ethylene glycol ethyl ether

Ethylene monochloride Vinyl chloride
Ethylene tetrachloride Perchloroethylene
Ethylene trichloride Trichloroethylene
N-Ethylethanamine Diethylamine
330
To Find Look Up
Ethyl ethanoate Ethyl acetate
Ethylethylene Butylene
Ethylformic acid Propionic acid
2-Ethyl hexanal 2-Ethyl-3-propylacrolein
2-Ethyl-2-hexanal 2-Ethyl-3-propylacrolein
2-Ethyl-1-hexanol 2-Ethyl hexanol

2-Ethylhexyl alcohol 2-Ethyl hexanol
bis(2-Ethylhexyl)phthalate Dioctyl phthalate
2-Ethylhexyl, 2-propenoate 2-Ethylhexyl acrylate
Ethyl hydride Ethane
Ethyl hydroxide Ethyl alcohol

5-Ethylidene bicyclo(2,2, 1)-hept- Ethylidene norbornene
2-ene
Ethylidene chloride I, 1-Dichloroethane
Ethylidene dichloride I, 1-Dichloroethane
I, 1-Ethylidene dichloride I, 1-Dichloroethane

Ethylidene norbornylene Ethylidene norbornene
Ethylidene norcamphene Ethylidene norbornene
Ethyl 2-methacrylate Ethyl methacrylate
Ethyl alpha-methacrylate Ethyl methacrylate
6-Ethyl-2-methyl benenamine 2-Methyl-6-ethylaniline

Ethyl methyl carbinol sec-Butyl alcohol
Ethyl methyl ketone Methyl ethyl ketone
Ethyl 2-methyl-2-propenoate Ethyl methacrylate
3-Ethyl-6-methyl pyridine 2-Methyl-5-ethylpyridine
5-Ethyl-2-methyl pyridine 2-Methyl-5-ethylpyridine

Ethyl nitrile Acetonitrile
Ethylolamine Ethanolamine
Ethyl oxide Ethyl ether
5-Ethyl-2-picoline 2-Methyl-5-ethylpyridine
Ethyl propenoate Ethyl acrylate

Ethyl 2-propenoate Ethyl acrylate
2-Ethyl-3-propyl acyraldehyde 2-Ethyl-3-propylacrolein
Ethyl sulfate Diethyl sulfate
Ethyl-o-toluidine 2-Methyl-6-ethylaniline
331
To Find Look Up
Ethyl vinyl ether Vinyl ethyl ether
Ethoxy diglycol Diethylene glycol ethyl
ether
2-(2-Ethoxyethoxy)ethanol Diethylene glycol ethyl
ether
2-[2-(2-Ethyoxyethoxy)- Ethoxy triglycol

ethoxy]ethanol
Ethyoxytriethylene glycol Ethoxy triglycol
EVE Vinyl ethyl ether
F
F 12 Dichlorodifluoromethane
Fermentation alcohol Ethyl alcohol
Fermentation butyl alcohol iso-Butyl alcohol
Fetilizer acid Sulfuric acid
Flourocarbon 22 Chlorodifluoromethane
Formalin Formaldehyde solutions

Formalith Formaldehyde solutions
Formic acid, methyl ester Methyl formate
Formic aldehyde solution Formaldehyde solutions
Formal Formaldehyde solutions
Formylic acid Formic acid

Formyl trichloride Chloroform
Freon 12 Dichlorodifluoromethane
Freon 22 Chlorodifluoromethane
Fuel oil no. I Kerosene
Fuel oil no. 1-D Diesel oil

Fuel oil no. 2-D Diesel oil
Fuel oil no. 6 Bunker C
Fuming sulfuric acid Oleum
Fural Furfural
2-Furaldehyde Furfural
2-Furancarbinol Furfuryl alcohol
2-Furancarbonal Furfural
2-Furancarboxaldehyde Furfural
2,5-Furandione Maleic anhydride
332
To Find Look Up
2-Furanmethanol Furfuryl alcohol

Furan, tetrahydro- Tetrahydrofuran
Furfuralcohol Furfuryl alcohol
Furfuraldehyde Furfural
Furfuran carboxylic aldehyde Furfural
Furfurole Furfural
Furole Furfural
Furylcarbinol Furfuryl alcohol
2-Furylcarbinol Furfuryl alcohol
alpha-Furylcarbinol Furfuryl alcohol
2-Furylmethanol Furfuryl alcohol

Fyde Formaldehyde solutions
G
Genetron Freon
Glacial acetic acid Acetic acid
Glutaral Glutaraldehyde solution
Glutaric dialdehyde Glutaraldehyde solution
Glutarol Glutaraldehyde solution
Glycerol Glycerine
Glycol Ethylene glycol
Glycol alcohol Ethylene glycol
Glycol bis(hyroxyethyl)ether Triethylene glycol
Glycol chlorohydrin Ethylene chlorohydrin
Glycol cyanohydrin Ethylene cyanohydrin

Glycol diacetate Ethylene glycol diacetate
Glycol dibromide Ethylene dibromide
Glycol dichloride Ethylene dichloride
Glycol ethylene ether 1,4-Dioxane
Glycol monoethyl ether Ethylene glycol ethyl ether

Glycol monoethyl ether acetate Ethylene glycol ethyl ether
acetate
Glycol monomethyl ether Ethylene glycol methyl
ether
Glycyl alcohol Glycerine
333
To Find Look Up
Grain alcohol Ethyl alcohol
Groundnut oil Peanut oil
L-Gulitol Sorbitol
Gum camphor Camphor oil
Gum spirits Turpentine
Gum turpentine Turpentine

H
Halon 122 Dichlorodifluoromethane
Hard wax Paraffin wax
HEA 2-Hydroxyethyl acrylate
Heavy industrial fuel oil Bunker C
Heavy oil Creosote, coal tar
n-Heptane Heptane
n-Heptylethylene 1-Nonene
Heptyl hydride Heptane
Hexahydroaniline Cyclohexylamine
Hexahydroazepine Hexamethyleneimine
Hexahydrobenzene Cyclohexane
Hexahydrophenol Cyclohexanol
Hexamethylene Cyclohexane
Hexanaphthene Cyclohexane
Hexane n-Hexane
1,2,3,4,5,6-Hexanehexol Sorbitol
Hexanes Hexane, iso- or n- isomers
1-Hexanol Hexanol
n-Hexanol Hexanol
Hexanols Hexanol
Hexone Methyl isobutyl ketone

sec-Hexyl acetate Methyl amyl acetate
Hexyl alcohol Hexanol
n-Hexyl alcohol Hexanol
sec-Hexyl alcohol Ethyl butanol
Hexyl hydride n-Hexane

High-strength hydrogen peroxide Hydrogen peroxide
334
To Find Look Up
High temperature coal tar Coal tar

Hight solvent naphtha Coal tar naphtha solvent
Hioxyl Hydrogen peroxide
HaN Ammonia, anhydrous

Homopiperidine Hexamethyleneimine
Hoof oil Neatsfoot oil
Household ammonia Ammoni~ solutions
Hydracrylic acid, beta-lactone beta-Propiolactone
Hydracrylonitrile Ethylene cyanohydrin

Hydrochloric ether Ethyl chloride
Hydrocyanic ether Propionitrile
Hydrogencarboxylic acid Formic acid
Hydrogen chloride Hydrochloric acid
Hydrogen dioxide Hydrogen peroxide

Hydrogen nitrate Nitric acid (56 to 68%)
Hydrogen nitrate Nitric acid (95%)
Hydroperoxide Hydrogen peroxide
2-Hydroxethylamine Ethanolamine
beta-Hydroxethylamine Ethanolamine
Hydroxybenzene Phenol
1-Hydroxybutane n-Butyl alcohol
2-Hydroxybutane sec-Butyl alcohol
1-H ydroxy-2-cyanoethane Ethylene cyanohydrin
Hydroxycyclohexane Cyclohexanol
bis[2-(2-Hydroxyethoxy)- Tetraethylene glycol
ethyl]ether
beta-Hydroxyethyl acrylate 2-Hydroxyethyl acrylate
bis(H ydrox yeth yl)amine Diethanolamine
bis(2-Hydroxyethyl)amine Diethanolamine
bis(2-Hydroxyethyl)ether Diethylene glycol
Hydroxyethylethylenediamine Aminoethylethanolamine
N-B-Hydroxyethylethylene- Aminoethylethanolamine
diamine
335
To Find Look Up
N-Hydroxyethyl-1,2- Aminoethylethanolamine
ethylenediamine
2-Hydroxyethyl 2-propenoate 2-Hydroxyethyl acrylate
1-Hydroxyhexane Hexanol
alpha-Hydroxyisobutronitrile Acetone cyanohydrin
alpha-Hydroxyisobutyronitrile Acetone cyanohydrin

Hydroxymethyl benzene Cresols
2-Hydroxymethylfuran- Furfuryl alcohol
4-Hydroxy-4-methyl-2-pentone Diacetone alcohol
4-Hydroxy-4-methyl pentanone-2 Diacetone alcohol
1-Hydroxymethylpropane iso-Butyl alcohol

2-Hydroxy-2- Acetone cyanohydrin
methylpropanenitrile
2-Hydroxynitrobenzene o-Nitrophenol
3-Hydroxypropanenitrile Ethylene cyanohydrin
3-Hydroxypropionitrile Ethylene cyanohydrin

beta-Hydroxypropionitrile Ethylene cyanohydrin
2-Hydroxypropylamine iso-Propanolamine
3-Hydroxypropylamine Propanolamine
Hydroxytoluene Cresols
alpha-Hydroxytoluene Benzyl alcohol

2-Hydroxytriethylamine Diethylethanolamine
Hypochlorite, solutions Sodium hypochlorite
solution
I
IBA iso-Butyl alcohol
Illuminating oil Kerosene
2,2' -Iminobisethanol Diethanolamine
2,2'-Iminodiethanol Diethanolamine
1,1'Iminodi2propanol Diisopropanolamine
Impure camphor Camphor oil
Inedible tallow Tallow
IPA iso-Propyl alcohol
iso- Omit prefix and look up
compound
336
To Find Look Up
Isoacetophenone Isophorone
Isoamyl acetate iso-Amyl acetate
Isoamyl ethanoate iso-Amyl acetate
Isoamyl hydride iso-Pentane
I ,3-Isobenzofuandione Phthalic anhydride
Isobutanal iso-Butyraldehyde
Isobutanol iso-Butyl alcohol
Isobutenyl methyl ketone Mesityl oxide
Isobuty I acetate iso-Buty I acetate
Isobutyl acrylate iso-Butyl acrylate
Isobutyl alcohol iso-Butyl alcohol

Isobutylaldehyde iso-Butyraldehyde
Isobutylamine iso-Butylamine
mono-Isobutylamine iso-Butylamine
Isobutyl methyl carbinol Methylamyl alcohol
Isobutyl methyl ketone Methyl isobutyl ketone

Isobutyl methyl methanol Methylamyl alcohol
Isobutyl-2-propenoate iso-Butyl acrylate
Isobutyraldehyde iso-Butyraldehyde
Isobutyric aldehyde iso-Butyraldehyde
Isodecaldehyde, mixed isomers iso-Decaldehyde

Isodecyl acrylate iso-Decyl acrylate
Isodecy I propenoate iso-Decyl acrylate
Isonitropropane 2-Nitropropane
Isooctanol iso-Octyl alcohol
Isooctyl alcohol iso-Octyl alcohol

Isopentane iso-Pentane
Isopentyl acetate iso-Amyl acetate
Isopropanol iso-Propyl alcohol
Isopropanolamine iso-Propanolamine
Isopropene cyanide Methacrylonitrile

Isopropenylbenzene alpha-Methylstyrene
2-Isopropoxypropane iso-Propyl ether
Isopropyl acetate iso-Propyl acetate
Isopropylacetone Methyl isobutyl ketone
337
To Flad Look Up
Isopropyl alcohol iso-Propyl alcohol
lsopropylamine iso-Propylamine
Isopropyl benzene Cumene
lsopropylcarbinol iso-Butyl alcohol
Isopropyl ester of acetic acid iso-Propyl acetate
Isopropyl ether iso-Propyl ether

lsopropylideneacetone Mesityl oxide
4-lsopropyl-1-methyl benzene p-Cymene
lsopropyltoluene p-Cymene
4-lsopropyl toluene p-Cymene
p-Isopropyltoluene p~ymene
lsotridecanol Tridecanol
Isotridecyl alcohol Tridecanol
Isotron Freon
Isovaleral iso-V aleraldehyde
Isovaleraldehyde iso-V aleraldehyde

Isovaleric aldehyde iso-V aleraldehyde
Isovalerone Diisobutyl ketone
J
Javelle water Sodium hypochlorite
solution
Judean pitch Asphalt
K
Katchung oil Peanut oil
Kerosine Kerosene
Ketohexamethylene Cyclohexanone
2-Ketohexamethylenimine Caprolactam solution

Ketone propane Acetone
beta-keto-Propane Acetone
L
Laurylbenzene Dodecylbenzene
Lead tetraethyl Motor fuel anti-knock
compounds
338
To Find Look Up
Lead tetramethyl Motor fuel anti-knock
compounds
LH2 Hydrogen (liquefied)

Light camphor oil Camphor oil
Light naphtha Naphtha: VM & P
Light oil Benzene, Toluene, Xylene
mixtures
Ligroin (in U.S.A.) Mineral spirits, or naphthas

Liquid ammonia Ammonia, anhydrous
Liquid bleach Sodium hypochlorite
solution
Liquid camphor Camphor oil
Liquid hydrogen Hydrogen (liquefied)
Liquid oxygen Oxygen (liquefied)

Liquid pitch oil Creosote, coal tar
Liquid rosin Tall oil
LNG Liquefied natural gas
LOX Oxygen (liquefied)
LPG Liquefied petroleum gas

Lye Caustic potash solution or
Caustic soda solution
M
MAAc Methyl amyl acetate
MAN Methacrylonitrile
MAOH Methylamyl alcohol
MAPP Gas Methyl acetylene-Propadiene
mixture
Marsh gas Methane

MCA Chloroacetic acid
MCB Chlorobenzene
MDI Diphenylmethane
diisocyanate
MEA, 70% Ethylamine solution

MEK Methyl ethyl ketone
339
To Find Look Up
MEP 2-Methyl-5-ethylpyridine
Metaphosphoric acid Phosphoric acid
Metaxylene m-Xylene
Methacetonic acid Propionic acid

Methacide Toluene
Methacrylate monomer Methyl methacrylate
alpha-Methacrylic acid Methacrylic acid
Methacrylic acid, butyl ester Butyl methacrylate
Methacrylic acid, ethyl ester Ethyl methacrylate

Methacrylic acid, methyl ester Methyl methacrylate
Methanal solution Formaldehyde solutions
Methanamine, N-methyl- Dimethylamine
Methanamine, N-methyl- Dimethylamine solution,
40%
Methanamine, N-methyl- Dimethylamine solution,

50%
Methane, bromo- Methyl bromide
Methane carboxylic acid Acetic acid
Methane, chloro- Methyl chloride
Methane, dichlorodifluoro- Dichlorodifluoromethane
Methane, refrigerated liquid or Liquefied natural gas

Natural gas, refrigerated liquid
Methane, tetrachloro- Carbon tetrachloride
Methane, trichloro Chloroform
Methanoic acid Formic acid
Methanol Methyl alcohol

Metheny! trichloride Chloroform
2-Methoxyethanol Ethylene glycol methyl
ether
2-(2-Methoxyethoxy)ethanol Diethylene glycol methyl
ether
2-[2-(2-Methoxyethoxy)- Methoxy triglycol

ethoxy]ethanol
Methyl acetaldehyde Propionaldehyde
Methylacetic acid Propionic acid
340
To Find Look Up
Methylacetic anhydride Propionic anhydride
Methyl acetylene-allene mixture Methyl acetylene-Propadiene

mixture
beta-Methylacrolein Crotonaldehyde
2-Methylacrylic acid Methacrylic acid
2-Methyl acetonitrile Acetone cyanohydrin
Methylbenzene Toluene
Methylbenzol Toluene
alpha-Methylbivinyl 1,3-Pentadiene
cis-Pentadiene- I ,3 1,3-Pentadiene
trans-Pentadiene- I ,3 1,3-Pentadiene
beta-Methylbivinyl Isoprene
I -Methylbutadiene 1,3-Pentadiene
2-Methy 1- I, 3-butadiene Isoprene
3-Methyl- I ,3-butadiene Isoprene
3-Methylbutanal iso-V aleraldehyde
2-Methylbutane iso-Pentane
3-Methyl- I -butanol acetate iso-Amyl acetate
Methyl iso-butenyl ketone Mesityl oxide
Methyl iso-butyl carbinol acetate Methyl amyl acetate
Methyl iso-butyl carbinyl acetate Methyl amyl acetate
2-Methylbutyl ethanoate iso-Amyl acetate

3-Methyl butyraldehyde iso-V aleraldehyde
Methyl carbinol Ethyl alcohol
Methyl Carbitol Diethylene glycol methyl
ether
Methyl Cellosolve Ethylene glycol methyl

ether
Methyl chloroform 1,1,1-Trich1oroethane
Methyl cyanide Acetonitrile
Methylene bichloride Dichloromethane
Methylene bis(4-phenyl Diphenylmethane
isocyanate) diisocyanate
341
To Find Look Up
Methylene bis-phenylisocyanate Diphenylmethane

diisocyanate
Methylene chloride Dichloromethane
Methylene dichloride Dichloromethane
Methylene oxide Formaldehyde solutions
Methylethene Propylene
Methylethyl aniline 2-Methyl-6-ethylaniline
( 1-Methylethyl)benzene Cumene
Methyl ethyl carbinol sec-Butyl alcohol
Methylethylene Propylene
Methylethylmethane n-Butane
N -( 1-Methylethyl)-2-propanamine Diisopropylamine
6-Methyl-1-heptanol iso-Octyl alcohol
Methyl hydride Methane
Methyl hydroxide Methyl alcohol
Methylisoamyl acetate Methyl amyl acetate

Methyl isobutenyl ketone Mesityl oxide
Methyl iso-butyl carbinol Methylamyl alcohol
Methylisopropylbenzene p-Cymene
1-Methyl-4-isopropylbenzene p-Cymene
Methyl methacrylate monomer, Methyl methacrylate

inh.
N-Methylmethanamine Dimethylamine
N-Methyl methanamine, 40% Dimethylamine solution,
40%
N-Methyl methanamine, 50% Dimethylamine solution,
50%
Methylmethane Ethane
Methyl methanoate Methyl formate
Methyl alpha-methacrylate Methyl methacrylate
Methyl-2-methyl propenoate Methyl methacrylate
2-Methyl nitrobenzene o-Nitrotoluene
Methyloxirane Propylene oxide

Methyl oxitol Ethylene glycol methyl
ether
342
To Find Look Up
2-Methyl pentane iso-Hexane

2-Methyl-2,4-pentanediol Hexylene glycol
4-Methyl-2-pentanol Methylamyl alcohol
4-Methyl-2-pentanol acetate Methyl amyl acetate

4-Methyl-2-pentanone Methyl isobutyl ketone
4-Methyl-3-penten-2-one Mesityl oxide
4-Methyl-2-pentyl acetate Methyl amyl acetate
2-Methyl-2-petanol-4-one Diacetone alcohol
Methylphenol (2-, 3- or 4-) Cresols

1-Methyl-1-phenylethylene alpha-Methylstyrene
2-Methylpropanal iso-Butyraldehyde
2-Methyl-2-propanamine tert-Butylamine
2-Methyl-1-propanol iso-Butyl alcohol
2-Methyl-2-propanol tert-Butyl alcohol

2-Methylpropenic acid Methacrylic acid
Methyl propenoate Methyl acrylate
Methyl 2-propenoate Methyl acrylate
2-Methylpropenoic acid Methacrylic acid
2-Methylpropenoic acid Methyl methacrylate

1-Meth ylpropy !acetate sec-Butyl acetate
2-Methylpropyl acetate iso-Butyl acetate
2-Methyl-1-propyl acetate iso-Butyl acetate
2-Methyl-1-propyl acrylate iso-Butyl acrylate
!-Methyl propylamine sec-Butylamine

2-Methylpropylamine iso-Butylamine
N-(2-Methyl propyl)amine Diisobutylamine
N,N-bis(2-Methylpropyl)amine Diisobutylamine
Methyl propyl benzene p-Cymene
beta-Methylpropyl ethanoate iso-Butyl acetate

Methylstyrene Vinyltoluene
para-Methylstyrene Vinyltoluene
Methyltrimethylene glycol 1,3-Butylene glycol
MIBC Methylamyl alcohol
MIBK Methyl isobutyl ketone
343
To Find Look Up
MIC Methylamyl alcohol
MIK Methyl isobutyl ketone
Mineral oil Crude oil
Mineral pitch Asphalt
Mineral spirits Naphtha: Stoddard solvent

MIPA iso-Propanolamine
Mixed octyl nitrates 2-Ethyl hexyl nitrate
Monobromomethane Methyl bromide
Mono-n-butylamine n-Butylamine
Monochloroacetic acid Chloroacetic acid

Monochlorobenzene Chlorobenzene
Monochlorodifluoromethane Chlorodifluoromethane
Monochloroethane Ethyl chloride
Monochloroethene Vinyl chloride
Monochloroethylene Vinyl chloride

Monoethanolamine Ethanolamine
Monoethylamine Ethylamine
Monoethylamine solution, 70% Ethylamine solution
Monoethylene glycol Ethylene glycol
Monohydroxybenzene Phenol
Monoisopropanolamine iso-Propanolamine
Monoisopropylamine iso-Propylamine
Monomethyl amine Methylamine solution
Mononitrobenzene Nitrobenzene
Monopropylamine Propylamine
Morbicid Formaldehyde solutions
Motor spirit Gasoline, motor
MTBE Methyl tert-butyl ether
Muriatic acid Hydrochloric acid
Muriatic ether Ethyl chloride

Myricycl cerotate Carnauba wax
N
Naphtha Coal tar naphtha solvent
Naphtha Mineral spirits
344
To Find Look Up
Naphthaline Naphthalene
Naphtha, petroleum Naphtha: VM & P
Naphthene Naphthalene
Natural gas Methane

NBA n-Butyl alcohol
Necatorina Carbon tetrachloride
Neolid Caster oil
2,2' ,2"-Nitrilotriethanol Triethanolamine
Nitrobenzol Nitrobenzene
o-Nitrochlorobenzene o-Chloronitrobenzene
2-Nitrophenol o-Nitrophenol
2-Nitropropane 2-Nitropropane
Nitropropanes 2-Nitropropane
sec-Nitropropane 2-Nitropropane
2-Nitrotoluene o-Nitrotoluene
o-Nitrotoluol o-Nitrotoluene
1-Nonane Nonane
n-Nonane Nonane
sec-Nonyl alcohol Diisobutyl carbinol

Nonylcarbinol n-Decyl alcohol
1-Nonylene 1-Nonene
Normal heptane Heptane
Normal hexane n-Hexane
Normal pentane Pentane

Norvalamine n-Butylamine
2-NP 2-Nitropropane
0
Octanol 2-Ethyl hexanol
Octanol iso-Octyl alcohol
iso-Octanol iso-Octyl alcohol
Octoil Dioctyl phthalate
Octyl acrylate 2-Ethylhexyl acrylate
Octyl alcohol 2-Ethyl hexanol

Octyl nitrates 2-Ethyl hexyl nitrate
345
To Find Look Up
Oil of mirbane Nitrobenzene
Oil of Palma Christi Caster oil
Oil of turpentine Turpentine
Oil of vitriol Sulfuric acid

Oleftant gas Ethylene
Olefin C-13 1-Tridecene
ONP o-Nitrophenol
Orthodichlorobenzene a-Dichlorobenzene
Orthonitrotoluene o-Nitrotoluene
Orthophosphoric acid Phosphoric acid
Orthoxylene a-Xylene
3-0xa- I ,5-pentanediol Diethylene glycol
2-0xetanone beta-Propiolactone
Oxirane Ethylene oxide
Oxirane, (chloromethyl)- Epichlorohydrin
2-0xohexamethylenirnine Caprolactam solution
Oxooctyl alcohol iso-Octyl alcohol
Oxotridecyl alcohol Tridecanol
Oxybenzene Phenol
I, I'-Oxybis[butaneI n-Butyl ether
I, I'-Oxybis[2-chloroethaneI 2,2' -Dichloroethyl ether
I ,I'-Oxybisethane Ethyl ether
2,2'-Oxybisethanol Diethylene glycol
2,2'0xybis[propaneI iso-Propyl ether

2,2'-0xydiethanol Diethylene glycol
1,1'-Oxydi-2-propanol Dipropylene glycol
Oxytoluenes Cresols
p
Painters naphtha Naphtha: VM & P
PAN Phthalic anhydride
PAP! Polymethylene polyphenyl
isocyanate
Paraceta!dehyde Paraldehyde
Paraffin Paraffin wax
346
To Find Look Up
Paraffin jelly Petrolatum

Paraffin scale Paraffin wax
Paraxylene p-Xylene
Pear oil iso-Amyl acetate
Pentanal n-Valeraldehyde
Pentanedial Glutaraldehyde solution
I ,5-Pentanedial Glutaraldehyde solution
n-Pentane Pentane
1-Pentanol n-Amyl alcohol
Pentalin Pentachloroethane
Pentyl alcohol n-Amyl alcohol
Pentylcarbinol Hexanol
sec-Pentylcarbinol Ethyl butanol
Perchlorethylene Perchloroethylene
Perchloromethane Carbon tetrachloride

Peroxide Hydrogen peroxide
Petroleum oil Diesel oil
Petrohol iso-Propyl alcohol
Petrol Gasoline, motor
Petrolatum jelly Petrolatum

Petroleum Crude oil
Petroleum alsphalt Asphalt
Petroleum crude oil Crude oil
Petroleum gases, liquefied Liquefied petroleum gas
Petroleum jelly Petrolatum

Petroleum pitch Asphalt
Petroleum solvent Naphthas
Petroleum solvent Naphtha: Stoddard solvent
Petroleum solvent Naphtha: VM & P
Petroleum spirits Mineral spirits

Petroleum wax Paraffin wax
Phene Benzene
Phenic acid Phenol
Phenol, 2,4-dichloro- 2,4-Dichlorophenol
347
To Find Look Up
Phenylamine Aniline
Phenyl carbinol Benzyl alcohol
Phenyl chloride Chlorobenzene
1-Phenyldodecane Dodecylbenzene
Phenylethane Ethylbenzene
Phenyl ether-biphenyl mixture Diphenyl-Diphenyl ether

mixture
Phenylethylene Styrene monomer
Phenyl hydride Benzene
Phenyl hydroxide Phenol
Phenylic acid _phenol

Phenylmethane Toluene
Phenyl methyl alcohol Benzyl alcohol
2-Phenyl propane Cumene
Phenyl propylene alpha-Methylstyrene
meta-Phosphoric acid Phosphoric acid

ortho-Phosphoric acid Phosphoric acid
Phosphoric acid, tris(methyl- Tricresyl phosphate
phenyl)ester
Phthalandione Phtlalic anhydride
Phthalic acid anhydride Phthalic anhydride

Phthalic acid, benzyl butyl ether Butyl benzyl phthalate
Phthalic acid, bis(2- Dioctyl phthalate
ethylhexyl)ester
Pimelic ketone Cyclohexanone
Piperylene 1,3-Pentadiene
Polybutylene Polybutene
Polyisobutene Polybutene
Polyisobutylene Polybutene
Polyisobutylene; plastics, resins & Polybutene
waxes
Potassium hydroxide Caustic potash solution

Potassium hydroxide solution Caustic potash solution
Propadiene-methyl acetylene Methyl acetylene-Propadiene
mixture mixture
348
To Find Look Up
Propanal Propionaldehyde
1-Propanamine Propylamine
2-Propanamine iso-Propylamine
1-Propanamine, 2-methyl- Diisobutylamine
1-Propanamine, N-propyl- Di-n-propylamine
Propanecarboxylic acid n-Butyric acid
Propane-Butane mixtures Liquefied petroleum gas

Propane, 1-chloro-2,3-epoxy Epichlorohydrin
Propane, I ,2-dichloro- 1,2-Dichloropropane
Propanenitrile Propionitrile
Propanenitrile, 2-hydroxy-2- Acetone cyanohydrin
methyl
Propane, nitrow 2-Nitropropane

Propane, 2,2' -oxybis[2-chloro 2,2' -Dichloroisopropyl ether
I ,2,3-Propanetriol Glycerine
Propanoic acid Propionic acid
Propanoic acid anhydride Propionic anhydride
Propanoic anhydride Propionic anhydride

Propanol n-Propyl alcohol
!-Propanol n-Propyl alcohol
2-Propanol iso-Propyl alcohol
3-Propanolamine Propanolamine
!-Propanol, 3-amino- Propanolamine

Propanolide beta-Propiolactone
n-Propanol n-Propyl alcohol
Propanone Acetone
2-Propanone Acetone
Propellant 12 Dichlorodifluoromethane
Propellant 22 Chlorodifluoromethane
Propenamide Acrylamide solution
2-Propenamide Acrylamide solution
Propene Propylene
!-Propene, 1,3-dichloro- 1,3-Dichloropropene

Propenenitrile Acrylonitrile
349
To Find Look Up
2-Propenenitrile Acrylonitrile
2-Propenenitrile, 2-methyl- Methacrylonitrile
Propene oxide Propylene oxide
2-Propenic acid Acrylic acid

Propenioic acid, 2-methylene Methacrylic acid
Propenoic acid Acrylic acid
2-Propenoic acid Acrylic acid
2-Propenoic acid, butyl ester n-Butyl acrylate
2-Propenoic acid, ethyl ester Ethyl acrylate

2-Propenoic acid methyl ester Methyl acrylate
2-Propenoic acid, 2-methyl-, ethyl Ethyl methacrylate
ester
2-Propenoic acid, 2-methyl-, Methyl methacrylate
methyl ester
Propenol Allyl alcohol

1-Propenol-3 Allyl alcohol
1-Propen-3-ol Allyl alcohol
2-Propenol Allyl alcohol
2-Propen-1-ol Allyl alcohol
Propenyl alcohol Allyl alcohol

Propionic aldehyde Propionaldehyde
Propionic nitrile Propionitrile
beta-Propionolactone beta-Propiolactone
Propionyl oxide Propionic anhydride
Propylacetate n-Propyl acetate

2-Propyl acetate iso-Propyl acetate
sec-Propyl acetate iso-Propyl acetate
Propyl alcohol n-Propyl alcohol
Propyl alcohol normal n-Propyl alcohol
sec-Propyl alcohol iso-Propyl alcohol

Propyl aldehyde Propionaldehyde
n-Propylamine Propylamine
mono-n-Propylamine Propylamine
Propyl carbinol n-Butyl alcohol
350
To Find Look Up
n-Propyl carbinol n-Butyl alcohol

Propylene aldehyde Crotonaldehyde
Propylene chloride 1,2-Dichloropropane
Propylene dichloride 1,2-Dichloropropane
Propylene tetramer Dodecene
Propylformic acid n-Butyric acid

Propyl hydride Propane
Propylic alcohol n-Propyl alcohol
Propylic aldehyde Propionaldehyde
iso-Propylideneacetone Mesityl oxide
Propyne-allene mixture Methyl acetylene-Propadiene

mixture
Protium Hydrogen (liquefied)
Pseudohexyl alcohol Ethyl butanol
Pyroacetic ether Acetone
Pyrofax Liquefied petroleum gas

Pyromucic aldehyde Furfural
Pyroxylic spirit Methyl alcohol
Pyrrolylene Butadiene
R
Range oil Kerosene
Red fuming nitric acid Nitric acid (95%)
Refined solvent naphtha Naphtha: VM & P
Refrigerant 12 Dichlorodifluoromethane
Refrigerant 22 Chlorodifluoromethane
Refrigerant gases Freon, or

Chlorodifluoromethane, or
Dichloroditluoromethane
Residual fuel oil no. 6 Bunker C
Resin oil Rosin oil
Retinol Rosin oil

Ricinus oil Caster oil
Rock oil Crude oil
Rosinol Rosin oil
Rubbing alcohol iso-Propyl alcohol
351
To Find Look Up
s
Santicizer 160 Butyl benzyl phthalate
SBA sec-Butyl alcohol
Secondary light oil Benzene, Toluene, Xylene
mixtures
Seneca oil Crude oil
Soda chloric acid, sodium salt Sodium chlorate solution

Soda lye Caustic soda solution
Sodium bichromate Sodium dichromate solution
Sodium bichromate solution Sodium dichromate solution
Sodium bisulfide Sodium hydrosulfide
solution
Sodium hydrogen sulfide Sodium hydrosulfide

solution
Sodium hydroxide Caustic soda solution
Sodium hydroxide solution Caustic soda solution
Sodium hypochlorite Sodium hypochlorite
solution
Sodium mercaptan Sodium hydrosulfide
solution
Sodium sulfhydrate Sodium hydrosulfide

solution
Solar nitrogen solution Urea-Ammonium nitrate
solution
Solvent ether Ethyl ether
Solvent naphtha Naphthas
Solvent naphtha Naphtha: VM & P

Sorbicolan Sorbitol
Sorbit Sorbitol
Sorbo Sorbitol
SorboI Sorbitol
Sorbostyl Sorbitol
Soyabean oil Soybean oil
Soy oil Soybean oil
Spirit of Hartshorn Ammonia solutions
352
To Find Look Up
Spirits of turpentine Turpentine
Spotting sol vent Naphtha: Stoddard solvent

Steam distilled turpentine Turpentine
Stoddard solvent Naphtha: Stoddard solvent
Styrene Styrene monomer
Styrol Styrene monomer
Styrolene Styrene monomer

Sulfate turpentine Turpentine
Sulfate wood turpentine Turpentine
Sulfur Sulfur, molten
Sulfur dioxide, liquefied Sulfur dioxide
Sulfuric acid, diethyl ester Diethyl sulfate

Sulfuric acid, fuming Oleum
Sulfuric chlorohydrin Chlorosulfonic acid
Sulfuric ether Ethyl ether
Sulfurous anhydride Sulfur dioxide
Sulfurous oxide Sulfur dioxide

Sulphur Sulfur, molten
Superoxol Hydrogen peroxide
Sweet oil Olive oil
T
Talleol Tall oil
Tallo! Tall oil
Tallow oil Tallow
Tangantangan oil Caster oil
Tar Coal tar
Tar acids Cresols

Tar camphor Naphthalene
Tar, liquid Coal tar
Tar oil Creosote, coal tar
Tars liquid Asphalt
TBA tert-Butyl alcohol

beta-T I, 1,2-Trichloroethane
1,1,1-TCE I, I, 1-Trichloroethane
353
To Find Look Up
1,1,2-TCE 1,1,2-Trichloroethane
TCP Tricresyl phosphate
TDI Toluene diisocyanate

TEA Triethanolamine
TEO Tetraethylene glycol
TEO Triethylene glycol
TEL Motor fuel anti-knock
compounds
Telone 1,3-Dichloropropene
TEN Triethylamine
TETA Triethylenetetramine
Tetrachlorethene Perchloroethylene
Tetrachlorethylene Perchloroethylene
Tetrachloroethane 1,1,2,2-Tetrachloroethane
sym-Tetrachloroethane 1,1,2,2-Tetrachloroethane
Tetrachloroethylene Perchloroethylene
Tetrachloromethane Carbon tetrachloride
Tetraethyllead compounds Motor fuel anti-knock
compounds
Tetrahydro-4, 7-methanoindene Dicyclopentadiene

1,2,3,4-Tetrahydronaphthalene Tetrahydronaphthalene
Tetrahydro-1,4-oxazine Morpholine
Tetrahydro-2H-1,4-oxazine Morpholine
Tetrahydro-p-oxazine Morpholine
Tetralin Tetrahydronaphthalene
Tetraline Tetrahydronaphthalene
Tetramethylene cyanide Adiponitrile
Tetramethylene oxide Tetrahydrofuran
Tetramethyllead compounds Motor fuel anti-knock
compounds
Tetramp Tetrahydronaphthalene
Tetranap Tetrahydronaphthalene
Tetrapropylene Dodecene
THF Tetrahydrofuran
354
To Find Look Up
TML Motor fuel anti-knock
compounds
TOCP Tricresyl phosphate

2,4-Tolamine Toluenediamine
2,4-Toluenediamine Toluenediamine
4-m-Toluenediamine Toluenediamine
m-Toluenediamine Toluenediamine
2,4-Toluene diisocyanate Toluene diisocyanate

Toluene-2,4-diisocyanate Toluene diisocyanate
Toluene, orthonitro- o-Nitrotoluene
2,4-Tolulene diisocyanate Toluene diisocyanate
Toluol (o-, m-, p-) Cresols
Toluol Toluene
Tolylethylene Vinyltoluene
Tolylenediamine Toluenediamine
2,4-Tolylenediamine Toluenediamine
m-Tolylenediamine Toluenediamine
2,4-Tolylene diisocyanate Toluene diisocyanate

m-Tolylene diisocyanate Toluene diisocyanate
Tolylphosphate Tricresyl phosphate
Treacle Molasses
Tri Trichloroethylene
Trichlorobenzenes, liquid 1,2, 4-Trichlorobenzene

unsym-Trichlorobenzene 1,2, 4-Trichlorobenzene
1,2,4-Trichlorobenzol 1,2,4-Trichlorobenzene
Trichloroethene Trichloroethylene
Trichlorohydrin 1,2,3-Trichloropropane
Trichloromethane Chloroform
Trichloropropane 1,2,3-Trichloropropane
beta-Trichlorethane 1,1,2-Trichloroethane
Tricresol Cresols
1-Tridecanol Tridecanol
Tridecyl alcohol Tridecanol

Trien Triethylenetetramine
JSS
To Find Look Up
1,3,5-Triethylbenzene Triethylbenzene
sym-Triethylbenzene Triethylbenzene
Triethylene glycol ethyl ether Ethoxy triglycol
Triethylene glycol methyl ether Methoxy triglycol

Triethylolamine Triethanolamine
Triglycol Triethylene glycol
Triglycol ethyl ether Ethoxy triglycol
Triglycol monoethyl ether Ethoxy triglycol
Tri(hydroxyethyl)amine Triethanolamine
Tri(2-hydroxyethyl)amine Triethanolamine
Trihydroxypropane Glycerine
1,2,3-Trihydroxypropane Glycerine
Trihydroxytriethylamine Triethanolamine
Trimethylaminomethane tert-Butylamine
Trimethyl carbinol tert-Butyl alcohol
3,5,5-Trimethyl-2-cyclohexene-1- Isophorone
one
Trimethylheptanols iso-Decaldehyde
2,4,4-Trimethyl pentene-1 Diisobutylene

2,4,4-Trimethyl pentene-2 Diisobutylene
Trimethyl pentene Diisobutylene
Trimethyltrimethylene glycol Hexylene glycol
alpha, alpha, alpha'-Trimethyl- Hexylene glycol
trimethylene glycol
2,4,6-Trimethyl-1,3,5-trioxane Paraldehyde
Tri-o-cresyl phosphate Tricresyl phosphate
Tri-o-tolyl phosphate Tricresyl phosphate
1,3,5-Trioxane, 2,4,6-trimethyi- Paraldehyde
3,6,9-Trioxaundecanol, 11-diol Tetraethylene glycol
Tris(hydroxyethyl)amine Triethanolamine
Tritolyl phosphate Tricresyl phosphate
Trolamine Triethanolamine
Turkey-red oil (sulfated caster Caster oil
oil)
Turpentine substitute Mineral spirits
3S6
To Find Look Up
Turps Turpentine
u
UAN-Nitrogen solution Urea-Ammonium nitrate
solution
UAN solution Urea-Ammonium nitrate
solution
Ucon Freon
Ucon 12 Dichlorodifluoromethane
Undecylethylene 1-Tridecene
v
Valera! n-V aleraldehyde
Valeraldehyde Valeraldehyde, iso- or n-
isomers
V aleric aldehyde n-Valeraldehyde
Valerone Diisobutyl ketone
YAM Vinyl acetate

Varnish makers' & painters' Naphtha: VM & P
naphtha
Vaseline Petrolatum
VC Vinyl chloride
VCL Vinyl chloride

VCM Vinyl chloride
Vinamar Vinyl ethyl ether
Vinegar acid Acetic acid
Vinegar naphtha Ethyl acetate
Vinyl acetate monomer Vinyl acetate

Vinyl A monomer Vinyl acetate
Vinylbenzene Styrene monomer
Vinyl carbinol Allyl alcohol
Vinyl chloride monomer Vinyl chloride
Vinyl C monomer Vinyl chloride

Vinyl cyanide Acrylonitrile
Vinyl ethylene Butadiene
357
To Find Look Up
Vinyl trichloride 1,1,2-Trichloroethane
Vinyl formic acid Acrylic acid
VyAc Vinyl acetate
w
Wash oil Creosote, coal tar
Whale sperm oil Sperm oil
White camphor oil Camphor oil
White fuming nitric acid Nitric acid (95%)
White phosphoric acid Phosphoric acid
White phosphorus ..Phosphorus (white)

White spirits Naphtha: Stoddard solvent
White tar Naphthalene
Wood alcohol Methyl alcohol
Wood spirit Methyl alcohol
Wood turpentine Turpentine

WP Phosphorus (white)
X
meta-Xylene m-Xylene
ortho-Xylene o-Xylene
para-Xylene p-Xylene
Xylol Xylene
y
Yellow petrolatum Petrolatum
Yellow phosphorus Phosphorus (white)
z
Zinc dihexyldithiophosphate Zinc dialkyldithiophosphate
Zinc dihexylphosphorodithioate Zinc dialkyldithiophosphate
358
APPENDIXES
A. Compatibility Information, 46 CFR !50- Subpart A......... 360

B. Medical Kit Information - Cyanide-like cargoes;
Carcinogens listed in the Guide........................................ 408
C. List of Oils - Appendix I, MARPOL 73/78;
Composition of Common Petroleum Products................ 410
D. Conversion Factors................................................................ 412
E. Temperature Conversion ....................................................... 417
359
APPENDIX A
COMPATIBILITY INFORMATION
In this seventh edition, chemical compatibility is covered by a gen-

eral discussion and summary of 46 CFR 150 Subpart A followed by 46
CFR 150 in essentially its entirety. If necessary, current information
may be obtained by calling 202-267-1577 or writing to Commandant
(G-MTH-1), Washington, D.C. 20593-0001.
General Discussion_
a. Introduction-The accidental mtxmg of one chemical product
with another inside a cargo tank or pipe may result in a vigorous chem-
ical reaction. Binary combinations that generate significant heat or
produce gas can be very hazardous to personnel and property. The pur-
pose of the Compatibility Guide is to indicate, in chart form, combina-
tions believed to be dangerous. Based on information provided by the
National Academy of Sciences, the Guide represents the latest data
available to the Coast Guard on chemical compatibility. Extensive use
was made of direct e:.<perimental evidence obtained under contract to
the NAS and Coast Guard.
b. Definition of a Hazardous Reaction-As a first approximation, a
binary mixture is considered hazardous when the products are mixed
under specified conditions and the temperature rise exceeds 25"C or a
gas is evolved. In rare cases the reaction of two components (even
though non-hazardous, from temperature or pressure considerations)
may produce a product which is significantly more flammable or toxic
than the original materials. Although no examples of such a reaction
are known at this time, they would be considered hazardous.
c. Chart Format-In reviewing the binary test results and previous
charts, it was evident that there were different degrees of reactivity
among the various products. Many of them are relatively non-reactive
(aromatic hydrocarbons, paraffins) while others form hazardous combi-
nations with many groups (inorganic acids).
The compatibility chart (refer to Figure 1 in 46 CFR 150) is separated
into two sections, group I through group 22 are Reactive groups, and
group 30 through group 43 are Cargo groups. Left unassigned and
available for future expansion are groups 23 through 29 and those past
43. Reactive groups contain products which are chemically the most re-
active; dangerous combinaiions may result between members of differ-
ent Reactive groups and between members of Reactive and Cargo
360
groups. Products assigned to Cargo groups, however, are much less re-
active and dangerous combinations can be formed only with members
of certain Reactive groups. Cargo groups do not react hazardously
with one another. Because of these differences in reactivity, a signifi-
cant part of the usual two-dimensional chart has been eliminated.
d. Using the Guide-The following procedure explains how the
Guide should be used to find compatibility information:
(I) Determine the group numbers of the two chemicals by refer-
ring to the alphabetical listing of products and their corresponding
groups (Table I of 46 CPR 150). Many chemicals are listed under their
parent names and, unless otherwise indicated, isomers or mixtures of
isomers for a particular product are assigned to the same group. For
example, to find the group number for Isobutyl alcohol, look under the
parent name Butyl alcohol. Similarly, the group number for para-
Xylene is found under the entry Xylene. If a chemical cannot be found
in this listing, contact the Coast Guard for a group determination.
(2) If both group numbers do not fall between 30 and 43 inclu-
sive, locate on the chart one of the numbers on the left (Cargo groups)
and the other across the top (Reactive groups). Note that if one of the
group numbers is between 30 and 43 it must be located on the left side.
Proceed across the page until the appropriate Reactive group column is
intersected. The box formed by the intersection will indicate one of the
following:
(a) blank-The two products are considered compatible.
(b) "X"-The two products are not considered compatible.
(c) a letter other than an "X"-Differences (deviations) in re-
activity are present among the group members-refer to the listing fol-
lowing the chart to find whether the products in question are included
in the deviations. Unless the combination is specifically covered on this
page, it may be considered compatible.
Examples:
Combination Groups Compatible?

Butyraldehyde/ Acetic acid 19/4 yes
Allyl alcohol/Toluene diisocyanate 2 15/12 no
Decene/Ethylbenzene 30/32 yes
Ethanolamine/Acetone 8/18 yes
Ammonia/Dimethytformamide 6/10 no
361
e. Exceptions to the Guide-The hazard ratings in the chart are
based largely upon direct experimental data using in most cases one of
the most reactive members of the group. Combinations of other group
members may display considerably less reactivity. For this reason, an
experimental procedure (refer to Appendix III, 46 CFR 150) has been
developed which allows a shipper to test two particular products he be-
lieves non-hazardous although an "X" appears in the chart for their
corresponding groups. A data sheet is also supplied and should be com-
pleted and returned to the Coast Guard for evaluation. If the combina-
tion is not found to be dangerously reactive, an exception will be
issued.
46 CFR PART 150-COMPATIBIUTY OF CARGOES
Subpart A-Compatibility of Cargoes
Sec.
150.105 OMB control numbers assigned pursuant to the Paperwork
Reduction Act.
150.110 Applicability.
150.115 Definitions.
150.120 Definition of incompatible cargoes.
150.130 Loading a cargo on vessels carrying cargoes with which it is
incompatible.
150.140 Cargoes not listed in Table I or II.
150.150 Exceptions to the compatibility chart.
150.160 Carrying a cargo as an exception to the compatibility chart.
150.170 Right of appeal.
FIGURE I-COMPATIBILITY CHART
TABLE I-ALPHABETICAL LIST OF CARGOES
TABLE II-GROUPING OF CARGOES
APPENDIX I-EXCEPTIONS TO THE CHART
APPENDIX II-EXPLANATION OF FIGURE I
APPENDIX III-TESTING PROCEDURES FOR DETERMINING EXCEPTIONS
TO THE CHART
APPENDIX IV-DATA SHEET
Subpart A-Compatibility of Cargoes

150.105 OMB control numbers assigned pursuant to the Paperwork
Reduction Act.
(a) Purpose. This section collects and displays the control numbers
assigned to information collection and recordkeeping requirements in
this subchapter by the Office of Management and Budget (OMB) pursu-
ant to the Paperwork Reduction Act of 1980 (44 U.S.C. 3501 et seq.).
362
The Coast Guard intends that this section comply with the require-
ments of 44 U.S.C. 3507(1) which requires that agencies display a cur-
rent control number assigned by the Director of the OMB for each ap-
proved agency information collection requirement.
(b) Display.
46 CFR part or section where

identified or described Current OMB control No.
150.01-15 2115-0016
153.5 2115-0016
153.905 2115-0089
153.910 2115-0089
153.968 2115-0089
Part 154 2115-0113
154.12 2115-0016
150.110 Applicability.
This subpart prescribes rules for identifying incompatible hazard-
ous materials and rules for carrying these materials in bulk as cargo in
permanently attached tanks or in tanks that are loaded or discharged
while aboard the vessel. The rules apply to all vessels subject to 46
U.S.C. 391a.
150.115 Definitions.
As used in this subpart: "Hazardous material" means:
(a) A flammable liquid as defined in 30.10-22 or a combustible
liquid as defined in 30.10-15 of this chapter;
(b) A material listed in Table 151.05, Table I of Part 153, or Table
4 of Part 154 of this chapter; or
(c) A liquid, liquefied gas, or compressed gas listed in 49 CFR
172.101.
"Person in charge" means the master of a self-prope1led vessel, or

the person in charge of a barge.
150.120 Definition of incompatible cargoes.
Except as described in I 50.150, a cargo of hazardous material is
incompatible with another cargo listed in Table I if the chemical groups
of the two cargoes have an "X" where their columns intersect in
363
Figure I and are not shown as exceptions in Appendix I. (See also
150.140.)
150.130 Loading a cargo on vessels carrying cargoes with which it is
incompatible.
Except as described in !50.160, the person in charge of a vessel
shall ensure that the containment system for a cargo that is a hazardous
material meets the following requirements:
(a) The containment system must separate the hazardous material
or its residue from any cargo in table I with which it is incompatible by
two barriers such as formed by a:
(I) Cofferdam;
(2) Empty tank;

(3) Void space;
(4) Cargo handling space;
(5) Tank containing a compatible cargo; or
(6) Piping tunnel.
(b) In this subpart, isolation across a cruciform joint is equivalent
to isolation by two barriers.
(c) The containment system for the hazardous material must not
have a piping or venting system that connects to a containment system
carrying a cargo with which the hazardous material is incompatible.
Any such piping or venting system must have been separated from the
containment system carrying the incompatible cargo by:
(I) Removing a valve or spool piece and blanking otT the exposed
pipe ends, or
(2) Installing two spectacle flanges in series with a means of detect-
ing leakage into the pipe between the spectacle flanges.
150.140 Cargoes not listed in Table I or II.
A cargo of hazardous material not listed in Table I or II must be

handled as if incompatible with all other cargoes until the Commandant
(G-MTH) (tel. no. (202) 267-1577) assigns the hazardous material to a
compatibility group. (Table I lists cargoes alphabetically while Table II
lists cargoes by compatibility group).
364
150.150 Exceptions to the compatibility chart.
The Commandant (G-MTH) authorizes, on a case by case basis,
exceptions to the rules in this subpart under the following conditions:
(a) When two cargoes shown to be incompatible in Figure I meet
the standards for a compatible pair in Appendix III, or
{b) When two cargoes shown to be compatible in Figure I meet
the standards for an incompatible pair in Appendix III.
Appendix I contains cargoes which have been found to be excep-
tions to Figure I, the Compatibility Chart.
150.160 Carrying a cargo as an exception to the compatibility chart.
The Operator of a vessel having on board a cargo carried as an
exception under I 50.1 SO but not listed in Appendix I, Exceptions to
the Chart, shall make sure that:
(a) The Commandant (G-MTH) has authorized by letter or mes-
sage the cargo pair as an exception to the compatibility chart; and
{b) A copy of the letter or message is on the vessel.
150.170 Right of appeal.
Any person directly affected by a decision or action taken under
this part, by or on behalf of the Coast Guard, may appeal therefrom in
accordance with subpart 1.03 of this chapter.
365
Figure I -Compatibility Chart
BILLING COOE 491o-14-C X: Incompatible Groups
366
Table 1-Aipbabetical List of Cargoes
Chemical name Group CHRIS Related CHRIS codes
No. code
Acetaldehyde.................................... 19 AAD
Acetic acid ....................................... . '4 AAC
Acetic anhydride ............................. . ll ACA
Acetone ..................................... . , 18 ACT
Acetone cyanohydrin ..................... . 1, zo ACY
Acetonitrile ..................................... . 37 ATN
Acetophenone ................................. . 18 ACP
Acetyl tributyl citrate ..................... . 34
Acrolein ........................................... . '19 ARL
Acrylamide solution ........................ . 10 AAM
Acrylic acid ..................................... . '4 ACR
Acrylonitrile .................................... . '15 ACN
Acrylonitrile-Styrene copolymer
dispersion in Polyether polyol ... . 20 ALE
Adiponitrile ...................................... . 37 ADN
Alcohols (Cl3 and above) ............. .. 20 AL Y TDN/TfN/PDC
Alcoholic beverages ........................ . 20
Alcohol polyethoxylates ................. . 20 APK/APL
Alcohol polyethoxylates,
secondary ..................................... . 20 AEA/AEB
Alkyl acrylate-Vinyl pyridine
copolymer in Toluene ................ .. 32 AAP
Alkyl(C9- Cl7) benzenes ............... . 32 AKB DBZ/UDB/DDBfTRBffDB
Alkylbenzenesulfonic acid .............. . ' 'O ABS
Alkylbenzenesulfonic acid, sodium
salt solutions ................................ . 33 ABT
Alkyl phthalates .............................. . 34
Allyl akohol ................................... . '15 ALA
Allyl chloride ................................. .. 15 ALC
Aluminium chloride, Hydrochloric
acid solution ............................... .. 0 AHS
Aluminum sulfate solution .............. . '43 ASX ALM
2-(2-Aminoethoxy)ethanol .............. . 8 AEX
Aminoethyldiethanolamine,
Aminoethylethanolamine
solution ......................................... . 8
Aminoethylethanolamine ................ . 8 AEE
N-Aminoethylpiperazine ........ . 7 AEP
2-Amino-2-hydroxymethyl-1,3-
propanediol solution .................... . 43 AHL
2-Amino-2-methyl-1-propanol ....... .. 8 APR
Ammonia, anhydrous ...................... . 6 AMA
Ammonium bisulfite solution ........ .. '43 ABX ASU
Ammonium hydrogen phosphate
solution ......................................... . 0
Ammonium hydroxide (28% or
less Ammonia) ............................. . 6 AMH
367
Table 1-Aipbabetical Ust of Cargoes-Continued
Chemical name Group CHRIS Related CHRIS coda
No. code
1
Ammonium nitrate solution............. 0 ANR AMN
Ammonium nitrate, Urea solution
(containing Ammonia) ................ . 6 UAS
Ammonium nitrate, Urea solution
(not containing Ammonia) .......... . 43 ANU
Ammonium polyphosphate
solution ......................................... . 43 ANS/APP
Ammonium sulfate solution ............ . 43 AME AMS
Ammonium sulfide solution ........... . 5 ASS ASF
Ammonium thiocyanate,
Ammonium thiosulfate solution .. 0 ACS
Ammonium thiosulfate solution ..... . 43 ATV ATF
Amyl acetate.................................... . 34 AEC IAT/AMLIAAS/AYA
Amyl alcohol ................................... . 20 AAI IAA/AAN/ASE/APM
Amylene ........................................... . 30 AMZ PTX!PTE
Amyl methyl ketone ....................... . 18 AMK
Amyl tallate ..................................... . 34
Aniline .............................................. . 9 ANL
Anthracene oil (Coal tar fraction),
see Coal tar .................................. .. 33 AHO COR
Asphalt ............................................ .. 33 ASP ACU
Asphalt blending stocks, roofers
flux ................................................ . 33 ARF
Asphalt blending stocks, straight
run residue ................................... . 33 ASR
Aviation alkylates............................ . 33 AVA GAY
Behenyl alcohol ............................... . 20
Benzene ............................................ . 32 BNZ
Benzene hydrocarbon mixtures
(having 10% Benzene or more) .. 32 BHB
BenzenesuJfonyl chloride ................ . ''O BSC
Benzene, Toluene, Xylene
mixtures ........................................ . 32 BTX
Benzene tricarboxylic acid, trioctyl
ester .............................................. . 34
Benzylacetate ................................... . 34 BZE
Benzyl alcohol ................................ .. 21 BAL
Benzy1 chloride ............................... . 36 BCL
Brake fluid base mixtures .............. .. 20 BFX
Butadiene ........................................ .. 30 BDI
Butadiene, Butylene mixtures
(cont. Acetylenes) ....................... . 30 BBM
Butane ............................................. .. 31 BMX IBT/BUT
Butene ............................................. . 30 IBL/BTN
Butene oligomer .............................. .. 30 BOL
Butyl acetate ................................... .. 34 BAX IBA!BCN/BTA/BYA
Butyl acrylate .................................. . 14 BAR BAI!BTC
368
Table 1-Alpbabetical List of Cargoes-Continued
Chemical name Group CHRIS Related CHRIS coc1o1
No. code
Butyl alcohol ................................... . '20 IAL/BAN/BAS/BAT
Butylamine ....................................... . 7 BTY IAM!BAM/BTL/BUA
Butylbenzene ................................... . 32 BBE
Butyl benzyl phthalate .................... . 34 BPH
n-Butyl butyrate ............................. .. 34 BUB
Butylene ........................................... . 30 BTN IBL
Butylene glycol .............................. .. '20 BUG
Butylene oxide ................................. . 16 BTO
Butyl ether ....................................... . 41 BTE
Butyl formate ................................... . 34 BFI/BFN
iso-Butyl isobutyrate ...................... .. 34 BIB
Butyl heptyl ketone ......................... . 18 BHK
Butyl methacrylate .......................... . 14 BMH BMI/BMN
Butyl methacrylate, Decyl
methacrylate, Cetyl-Eicosyl
methacrylate mixture .................. . 14 DER
Butyl phenol, Formaldehyde resin
in Xylene ..................................... .. 32
Butyl toluene ................................... . 32 BUE
Butyraldehyde ................................. . 19 BAE BAD/BTR/BFA
Butyric acid ..................................... . 4 BRA IBR
gamma-Butyrolactone ..................... . 1, :lQ BLA
Calcium bromide solution .............. .. 43 CBM
Calcium bromide, Zinc bromide
solution see Drilling brine
(containing Zinc salts) ................ .. 43 DZB
Calcium chloride solution ............... . 43 ccs CLC
Calcium hypochlorite solutions ..... . 5 CHZ/CHU/CHY
Calcium naphthenate in Mineral
oil ...................................... . 34 CNM
Calcium nitrate, Magnesium
nitrate, Potassium chloride
solution ................................ . 34
Calcium sulfonate, Calcium
carbonate, Hydrocarbon solvent
mixture ......................................... . 33
Camphor oil ..................................... . 18 CPO
Caprolactam solution ...................... . 22 CLS
Carbolic oil ...................................... . 21 CBO
Carbon black base .......................... .. 33
Carbon disulfide .. 38 CBB
Carbon tetrachloride ...................... .. 36 CBT
Cashew nut shell oil (untreated) .... . 4 OCN
Caustic potash solution .................. .. s CPS
Caustic soda solution ...................... . s css
Cetyl-Eicosyl methacrylate
mixture ........................................ . 14 CEM
369
Table 1-Aiphabetical List of Cargoes-Continued
Cbemlc:al IUUIIe Group CHRIS Related CHRIS codel
No. eode
Chlorinated paraffins (CIO- Cl3).. . 36 CLH
Chlorinated paraffins (Cl4- C17).. . 36
Chlorine ........................................... . 'O CLX
Chloroacetic acid solution .............. . 4 CHM CHUMCA
Chlorobenzene ................................ .. 36 CRB
Chlorodifluoromethane .................. .. 36 MCF
ChJorofonn ...................................... . 36 CRF
Chlorohydrins .................................. . 17 CHO
4-Chloro-2-methylphenoxyacetic
acid, Dimethylamine salt
solution ......................................... . 9 COM
Chloronitrobenzene see o-
Nitrochlorobenzene ..................... . CNO
Chloropropionic acid ...................... . 4 CPM CLA/CLP
Chlorosulfonic acid ........................ .. 'O CSA
Chlorotoluene .................................. . 36 CHI CTM/CTO/CRN
Choline chloride solutions ............. .. 20 ceo
Coal tar ........................................... .. 33 COR ocr
Coal tar pitch ................................... . 33 CTP
Coconut oil, fatty acid .................... . 34 CFA
Com syrup ....................................... . 43 CSY
Cottonseed oil, fatty acid ............... . 34 CFY
Creosote .......................................... .. '21 ccr CCW/CWO
Cresols ............................................. .. 21 CRS CRL/CSL/CSO
Cresylate spent caustic ................... .. s esc
Cresylic acid ................................... .. 21 CRY
Cresylic acid, sodium salt solution . s esc
Crotonaldehyde ............................... . '19 erA
Cumene ............................................ . 32 CUM
Cycloaliphatic resins ...................... .. 31
1,5,9-Cyclododecatriene ................ .. 30 CYT
Cycloheptane ................................... . 31 CYE
Cyclohexane .................................... . 31 CHX
Cyclohexane oxidation product
acid water.................................... .. 4
Cyclohexanol ................................... . 20 CHN
Cyclohexanone ............................... .. 18 CCH
Cyclohexanone, Cydohexanol
mixtures ....................................... .. '18 CYX
Cyclohexyl acetate .......................... . 34 eve
Cyclohexylamine ............................ .. 7 CHA
1,3..Cyclopentadiene dimer ............ .. 30 CPO
Cyclopentadiene polymers ............. . 30 CPO
Cyclopentadiene, Styrene, Benzene
mixtures ........................................ . 30 CSB
Cyclopentane ................................... . 31 CYP
Cyclopentene ................................... . 30 CPE
370
Table 1-Alphabetical List of Cargoes-Continued
Chemical name Group CHRIS Related CHRIS c:odes
No. code
Cymene ........................................... . 32 CMP
Decahydronaphthalene ................... . 33 DHN
Decaldehyde .................................... . 19 IDA/DAL
Decane ............................................. . 31 DDC PFN
Decanoic acid .................................. . 4 DCO
Decene ............................................. . 30 DCE
Decyl acrylate ................................. . 14 DAT !AI/DAR
Decyl alcohol .................................. . '20 DAX ISA!DAN
Decylbenzene .................................. . 32 DBZ AKB
Dextrose solution ............................ . 43 DTS
Diacetone alcohol ........................... . '20 DAA
Dialkyl(CIO- C14) benzenes .......... . 32 DAB
Dialkyi(C7- C13) phthalates ......... . 34 DAH DHP/DIE/DOP/DIF/DTP/
DUP
Diammonium salt of Zinc EDTA
solution ......................................... . 43 DSZ
Dibutylamine ................................... . 7 DBA
Dibutyl phthalate ............................ . 34 DPA
Dichlorobenzene ............................. . 36 DBX DBM/DBO/DBP
Dichlorodifluoromethane ............... . 36 DCF
1, 1-Dichloroethane .......................... . 36 DCH
2,2'-Dichloroethyl ether ................. . 41 DEE
2,2'-Dichloroisopropyl ether .......... . 36 DC!
Dichloromethane ............................. . 36 DCM
2,4-Dichlorophenol ......................... . 21 DCP
2,4-Dichlorophenoxyacetic acid,
Diethanolamine salt solution ....... 43 DDE
Dimethylamine salt solution ...... .. 1, 20 DAD DDA!DSX
T riisopropanolamine salt
solution ......................................... . '43 DTI
Dichloropropane ............................. . 36 DPX DPB/DPP/DPC/DPL
1,3-Dichloropropene ....................... . 15 DPS DPU/DPF
Dichloropropene,
Dichloropropane mixtures .......... . 15 DMX
2,2-Dichloropropionic acid ........... .. 4 DCN
Dicyclopentadiene ........................... . 30 DPT
Didecyl dimethyl ammonium
chloride, Ethanol mixture
solution ......................................... . 43 DDX
Diethanolamine ................................ . 8 DEA
Diethanolamine salt of 2.4-
Dichlorophenoxyacetic acid
solution ......................................... . 43 DDE
Diethylamine ................................... . 7 DEN
Diethylaminoethanol ....................... . 8 DAE
371
Table 1-Aiphabetlcal List of Cargoes-Continued
Cbemieal aame Group CHRIS Related CHRIS eodeo
No. code
2,6-Diethylaniline ............................. 9 DMN
Diethylbenzene ................................. 32 DEB
Diethylene glycol ............................. 40 DEG
Diethylene glycol butyl ether ......... 40 DME
Diethylene glycol butyl ether
acetate ............................................ 34 DEM
Diethylene glycol dibutyl ether ...... 40 DIG
Diethylene glycol ethyl ether ......... 40 DOE
Diethylene glycol ethyl ether
acetate ............................................ 34 DGA
Diethylene glycol methyl ether ...... 40 DGM
Diethylene glycol methyl ether
acetate ............................................ 34 DGR
Diethylene glycol phenyl ether ...... 40 DGP
Diethylene glycol phthalate ............ 34 DOL
Diethylenetriamine ........................... '7 DET
Diethylethanolamine ........................ 8 DAE
Diethyl ether .................................... 41 EET
Di(2-ethylhexyl)adipate .................. 34 DEH
Di-(2-ethylhexyl)phosphoric acid ... DEP
Di-(2-ethylhexyl)phthalate ............... 34 DIE DIO/DOP/DAH
Diethyl phthalate.............................. 34 DPH
Diethyl sulfate .................................. 34 DSU
Diglycidyl ether of Bisphenol A .... 41 BDE BPA
Diglycidyl ether of Bisphenol F ..... 41 DGF
Diheptyl phthalate ........................... 34 DHP
Di-n-hexyl adipate ............................ 34 DHA
Diisobutylamine ................................ 7 DBU
Diisobutyl carbinol ........................... 20 DBC
Diisobutylene .................................... 30 DBL
Diisobutyl ketone ............................. 18 DIK
Diisobutyl phthalate ......................... 34 DIT
Diisodecyl phthalate ........................ 34 DID
Diisononyl adipate ........................... 34 DNY
Diisononyl phthalate ........................ 34 DIN
Diisooctyl phthalate ......................... 34 DIO
Diisopropanolamine ......................... 8 DIP
Diisopropylamine ............................. 7 DIA
Diisopropylbenzene .......................... 32 DIX
Diisopropyl naphthalene .................. 32 DII
N,N-Dimethylacetamide .................. 10 DAC
N,N-Dimethylacetamide solution ... 10 DLS
Dimethyl adipate ............................... 34 DLA
Dimethylamine ................................. 7 DMA
Dimethylamine solution ................... 7 DMG/DMY/DMC
372
No. code
Dimethylamine salt of 4-Chloro-2-
methylphenoxyacetic acid
solution.......................................... 9 CDM
Dimethylamine salt of 2,4-
solution.......................... 1 2
0 DAD DDA/DSX
2,6-Dimethylaniline ................. 9 DMM
Dimethylcyclicsiloxane
hydrolyzate .................................. . 34
N,N-Dimethylcyclohexylamine ..... . 7 DXN
Dimethylethanolamine .................... . 8 DMB
Dimethylformamide ....................... . 10 DMF
Dimethyl furan .......................... . 41
Dimethyl glutarate .......... . 34 DGT
Dimethyl hydrogen phosphite ....... . '34 DPI
Dimethyl naphthalene sulfonic
acid, sodium salt solution ............ . , 34 DNS
Dimethyloctanoic acid .................... . 4 DMO
Dimethyl phthalate ......................... . 34 DTL
Dimethylpolysiloxane ..................... . 34 DMP
2,2-Dimethylpropane-1,3-diol ......... . 20 DDI
Dimethyl succinate ......................... . 34 DSE
Dinitrotoluene ................. . 42 DNM DTI/Di'L/DNU
Dinonyl phthalate ........................... . 34 DIF DAH
Dioctyl phthalate ........................... . 34 DOP DAH
1,4-Dioxane ..................................... . 41 DOX
Dipentene .......................... . 30 DPN
Diphenyl ......................................... . 32 DIL
Diphenyl, Diphenyl ether mixture. 33 DDO DTH
Diphenyl ether ................................ . 41 DPE
Diphenyl ether, Diphenyl phenyl
ether mixture ................................ . 41 DOB
Diphenylmethane diisocyanate ...... . 12 DPM
Diphenylol propane-
Epichlorohydrin resins ................ . 'O DPR
Di-n-Propylamine ............................ . 7 DNA
Dipropylene glycol ......................... . 40 DPG
Dipropylene glycol dibenzoate ...... . 34 DGY
Dipropylene glycol methyl ether .. . 40 DPY
Distillates, flashed feed stocks ........ . 33 DFF
Distillates, straight run .................... . 33 DSR
Ditridecyl phthalate ........................ . 34 DTP DAH
Diundecyl phthalate ........................ . 34 DUP DAH
Dodecane ......................................... . 31 DOC PFN
Dodecanol ........................................ . 20 DDN LAL
Dodecene ......................................... . 30 DOZ DDC/DOD
373
Chemical name
2-Dodecenylsuccinic acid,
Group
No. .....
CHRIS Related CHRIS <Gdes
dipotassium salt solution.............. 34

Dodecylamine, Tetradecylamine
mixture.......................................... 27 DTA
Dodecyl alcohol............................... 20 DDN/LAL
Dodecylbenzene ............................... 32 DDB AKB
Dodecylbenzenesulfonic acid.......... 20 DSA
Dodecyl diphenyl ether
disulfonate solution....................... 43 DOS
Dodecyl methacrylate..................... 14 DDM
Dodecyl-Pentadecyl methacrylate
mixtures......................................... 14 DDP
Dodecyl phenol................................ 21 DOL
Drilling brine (containing Calcium,
Potassium or Sodium salts).......... 43 DRB
Drilling brine (containing Zinc
salts)............................................... 43 DZB
Drilling mud (low toxicity) (if
flammable or combustible)............ 33 DRM
Drilling mud (low toxicity) (if non-
flammable or non-combustible)..... 43 DRM
Epichlorohydrin ............................... 17 EPC
Epoxy resin....................................... 18
Ethane............................................... 31 ETH
Ethanolamine.................................... 8 MEA
2-Ethoxyethanol............................... 20 EEO
2-Ethoxyethyl acetate...................... 34 EEA
Ethoxylated alcohols, Cll-C15....... 20 EOD/ENP/EOP/EOT/ETD
Ethoxy triglycol............................... 40 ETG
Ethyl acetate..................................... 34 ETA
Ethyl acetoacetate............................ 34 EAA
Ethyl acrylate................................... 14 EAC
Ethyl alcohol.................................... 2 20 EAL
Ethylamine........................................ 27 EAM
Ethylamine solution ......................... 7 EAN
Ethyl amyl ketone............................ 18 EAK ELK
Ethylbenzene .................................... 32 ETB
Ethyl butanol.................................... 20 EDT
N-Ethyl-n-butylamine ...................... 7 EBA
Ethyl butyrate.................................. 34 EBR
Ethyl chloride................................... 36 ECL
Ethyl chlorothioformate .................. z0 ECT
N-Ethylcyclohexylamine ................. 7 ECC
Ethylene............................................ 30 ETL
Ethylene chlorohydrin...................... 20 ECH
Ethylene cyanohydrin ..................... 20 ETC
Ethylenediamine............................... 27 EDA EMX
374
No. code
Ethylenediaminetetracetic acid,
tetrasodium salt solution ............. . 43 EDS
Ethylene dibromide ......................... . 36 EDB
Ethylene dichloride ........................ . '36 EDC
Ethylene glycol .................... . '20 EGL
Ethylene glycol acetate .................. . 34 EGO
Ethylene glycol butyl ether .......... . 40 EGM
Ethylene glycol tert-butyl ether ... .. 40
Ethylene glycol butyl ether
acetate ........................................... . 34 EMA
Ethylene glycol diacetate ............... . 34 EGY
Ethylene glycol dibutyl ether .. . 40 EGB
Ethylene glycol ethyl ether ........... .. 40 EGE
Ethylene glycol ethyl ether acetate 34 EGA
Ethylene glycol isopropyl ether .. .. 40 EGI
Ethylene glycol methyl ether ....... .. 40 EME
Ethylene glycol methyl ether
acetate ............................... . 34 EGT
Ethylene glycol phenyl ether ......... . 40 EPE
Ethylene glycol phenyl ether,
Diethylene glycol phenyl ether
mixture .............................. . 40 EDX
Ethylene glycol propyl ether ....... .. 40 EGP
Ethylene oxide ................................. . 'O EOX
Ethylene oxide, Propylene oxide
mixture ....................................... .. 16 EPM
Ethylene-Vinyl acetate copolymer
emulsion .......................... . 43
Ethyl ether ...... .. 41 EET
Ethyl-3-ethoxypropionate 34 EEP
2-Ethylhexaldehyde ................ . 19 EHA
2-Ethylhexanoic acid . 4 EHO
2-Ethylhexanol ......... .. 20 EHX
2-Ethylhexyl acrylate .................... . 14 EAI
2-Ethylhexylamine 7 EHM
Ethyl hexyl phthalate .. .. 34 EHE
Ethyl hexyl tallate ......................... .. 34 EHT
Ethylidene norbornene ........ .. '30 ENB
Ethyl methacrylate .......................... . 14 ETM
Z-Ethyl-6-methyl-N-( I' -methyi-Z-
methoxyethyl)aniline ....... . 9 EEM
o-Ethyl phenol ................ .. 21 EPL
Ethyl propionate ............................ .. 34 EPR
2-Ethyl-3-propylacrolein ................. . '19 EPA
Ethyl toluene ................................... . 32 ETE
Fatty acids (saturated, C13 and
above) ................................... . 34
375
Chemical name Group CHRIS Related CHRIS <Odes
No. code
Fatty acid amides ..................... . 33
Ferric chloride solution ........... . FCS FCL
Ferric hydroxyethylethylene-
diaminetriacetic acid, trisodium
salt solution .................................. . '43 FHX STA
Ferric nitrate, Nitric acid solution .. 3 FNN
Fish solubles (H!Oter based fish meal
extracts) ......................................... . 43 FSO
Formaldehyde, Methanol mixtures. '19 MTM
Fonnaldehyde solution ................... . '19 FMS
Fonnamide ....................................... . 10 FAM
Fannie acid ...................................... . '4 FMA
Fructose solution ............................. . 43
Fumaric adduct of Rosin, water
dispersion ........................ . 43 FAR
Furfural ............................................ . 19 FFA
Furfuryl alcohol .............................. . '20 FAL
Gas oil, cracked ............................... . 33 GOC
Gasoline blending stock, alkylates .. 33 OAK
Gasoline blending stock,
refonnates ..................................... . 33 GRF
Gasolines:
Automotive (not over 4.23 grams
lead per gal).............................. 33 GAT
Aviation (not over 4.86 grams
lead per gal)............................... 33 GAY AVA
Casinghead (natura/).................... 33 GCS
Polymer......................................... 33 GPL
Straight run.......................... 33 GSR
Glutaraldehyde solution .................. 19 GTA
Glycerine ......................................... . '20 OCR
Glycerol polya1koxylate ................. . 34
Glyceryl triacetate .......................... . 34
Gylcidyl ester of tridecylacetic
acid ............................................... . 34 GLT
Glycidyl ester of Versatic acid ...... . 34 GLT
Glycol diacetate .............................. . 34
Glycols, Resins, and Solvents
mixture.......................................... 33
Glyoxal solutions.............................. 19 GOS
Heptane............................................. 31 HMX HPI/HPT
n-Heptanoic acid.............................. 4 HEP
Heptanol............................................ 20 HTX HTN
Heptene ............................................. 30 HPX HTE
Heptyl acetate................................... 34 HPE
Herbicide (CI5-H22-N02-CI) ......... 33 MCO
Hexamethylenediamine solution ..... 1 HMC HMD
376
Chemical name Group CHRIS Related CHRIS codea
No. code
Hexamethylenetetramine. 7 HMT
Hexamethylenetetramine solutions. 7 HTS
Hexamethylenimine .............. . 7 HMI
Hexane ............... . '31 HXS IHA/HXA
Hexanoic acid 4 HXO
Hexanol ........................... . 20 HXN
Hexene ................ . 30 HEX HXE/HXT
Hexyl acetate .......................... .. 34 HAE HSA
Hexylene glycol .. . 20 HXG
Hydrochloric acid ..................... .. HCL
Hydrochloric acid, spent ....... . HCS
Hydrofluorosilicic acid .......... . HFS
Hydrogen peroxide solutions ... 'O HPN/HPS/HPO
2-Hydroxyethyl acrylate ...... 1, 2Q HAl
N
(H ydrox yeth yl)ethylenediamine-
triacetic acid, trisodium salt
solution........................................ 43 HET
2-H ydroxy-4-( meth ylthio)butanoic
acid ................................... . 4 HBA
Isophorone ........ .. .................. .. '18 !PH
lsophorone diamine ......................... . 7 !PI
Isophorone diisocyanate ................. . 12 IPD
Isoprene ........................................... . 30 IPR
Isopropylbenzene ......................... . 32 CUM
Jet fuels:
]~! ...................................... . 33 JPO
JP-3 ........................ . 33 JPT
JP-4 ....................... . 33 JPF
JP-5 .......................... . 33 JPV
JP-8.. 33 JPE
Kaolin clay slurry 43
Kerosene.......................... 33 KRS
Ketone residue.... 18
Kraft black liquor........................ 5 KPL
Kraft pulping liquors (Black,
Green, or White) ....... ................... 5 KPL
Lactonitrile solution......... 37 LNI
Latex, liquid synthetic.... 43 LLS LTX
Lauric acid........... 34 LRA
Lignin liquor.................... 43
Magnesium chloride solution ... 1, 2Q
Magnesium nonyl phenol sulfide .. .. 33

Magnesium sulfonate ....................... . 34 MSE MAS
Maleic anhydride ............................ . II MLA
Maleic anhydride copolymer ........ .. 33
377
No. code
Mercaptobenzothiazol, sodium salt
solution ......................................... . 5 SMB
Mesityl oxide ................................... . '18 MSO
Metam sodium solution ................... . 7 MSS SMD
Methacrylic acid .............................. . 4 MAD
Methacrylonitrile ............................. . 15 MET
Methane............................................ . 31 MTH
3-Methoxy-1-butanol ....................... . 20
3-Methoxybutyl acetate .................. . 34 MOA
1-Methoxy-2-propyl acetate ........... . 34 MPO
Methoxy triglycol ........................... . 40 MTG
Methyl acetate ................................. . 34 MIT
Methyl acetoacetate ........................ . 34 MAE
Methyl acetylene, Propadiene
mixture ......................................... . 30 MAP
Methyl acrylate ............................... . 14 MAM
Methyl alcohol ................................ . '20 MAL
Methylamine .................................... . 7 MTA
Methylamine solutions .................... . 7 MSZ
Methyl amyl acetate ....................... . 34 MAC
Methyl amyl alcohol ....................... . 20 MAA
Methyl amyl ketone ........................ . 18 MAK
Methyl bromide ............................... . 36 MTB
Methyl butenol ............................... .. 20 MBL
Methyl butyl ketone ....................... .. 18 MBK
Methyl tert-butyl ether .................. .. '41 MBE
Methylbutynol ................................. . 20 MBY
3-Methyl butyraldehyde ................ .. 19
Methyl butyrate ............................... . 34 MBU
Methyl chloride ............................... . 36 MTC
Methylcyclohexane ......................... . 31 MCY
Methylcyclopentadiene dimer ........ . 30 MCK
Methyl diethanolamine .................. .. 8 MDE MAB
4,4'-Methylene dianiline (43% or
less), Polymethylene
polyphenylamine, o-
Dichlorobenzene mixtures .......... . 9 MDB
2-Methyl-6-ethylaniline ,.................. . 9 MEN
Methyl ethyl ketone ........................ . '18 MEK
2-Methyl-5-ethylpyridine ............... .. 9 MEP
Methyl formal.. ................................ . 41 MTF
Methyl fonnate ............................... .. 34 MFM
Methyl heptyl ketone ..................... .. 18 MHK
2-Methyl-2-hydroxy-3-butyne ........ . . 20 MHB
Methyl isoamyl ketone .................. ,. 18 MAK
Methyl isobutyl carbinol ............... .. 20 MIC
Methyl isobutyl ketone ................... . '18 MIK
378
Table 1-Aipbabetical List of Cargoes-Continued
No. code
Methyl methacrylate, .. , .............. , .. . 14 MMM
3-Methyl-3-methoxybutanol , .. , .. , .. 20
3-Methyl-3-methoxybutyl acetate .. . 34
Methyl naphthalene, ............... , .... .. 32 MNA
Methylolureas, .. , .. ,., ... , ............... ,. 19 MUS
2-Methyl pentane ............................. . 31 IHA
2-Methyl-1-pentene ...... , ................. . 30 MPN
4-Methyl-1-pentene ......................... . 30 MTN
Methyl pyridine ................................ . 9 MPR/MPE/MPF
N-Methyl-2-pyrrolidone ................ .. 9 MPY
Methyl salicylate ............................. . 34 MES
alpha-Methylstyrene ....................... .. 30 MSR
Metolachlor ..................................... . 34 MCO
Mineral spirits .................................. . 33 MNS
Molasses .............................. , ........... . 20
Molasses residue .............................. . 0
Monochlorodifluoromethane .......... . 36 MCF
Morpholine ...................................... . '1 MPL
Motor fuel antiknock compounds
containing lead alkyls ................. .. 'O MFA
Myrcene ........................................... . 30 MRE
Naphtha:
Coal tar solvent .......................... .. 33 NCT
Cracking fraction ......................... . '33
Petroleum ..................................... . 33 PTN
Solvent ....................... ,.......... ., ..... . 33 NSV
Stoddard solvent .......................... . 33 NSS
Varnish Makers' and Painters' .. .. 33 NVM
Naphthalene .................................... .. 32 NTM
Naphthalene sulfonic acid-
formaldehyde copolymer,
sodium salt solution ..................... . 0 NFS
Naphthalene sulfonic acid, sodium
salt solution ................................. .. 34 NSA
Naphthenic acid ............................. .. 4 NTI
Naphthenic acid, sodium salt
solution ........................................ .. 43 NTS
Neodecanoic acid ........................... .. 4 NEA
Nitrating acid ................................... . 'O NIA
Nitric acid (70% or less) ............... .. 3 NCD
Nitric acid (greater than 70%) ...... .. 'O NAC
Nitrobenzene .................................... . 42 NTB
o-Nitrochlorobenzene .................... .. 42 CNO CNP
Nitroethane ...................................... . 42 NTE
o-Nitrophenol .................................. . 1, 20 NTP NIP/NPH
Nitropropane ................................... . 42 NPM NPN/NPP
Nitropropane, Nitroethane mixture 42 NNM
379
Ctemical aame Group CHRIS Related CHRIS eodea
No. code
Nitrotoluene...................................... 42 NIT NIE/NIT/NTR
Nonane.............................................. 31 NAX NAN
Nonanoic acid................................... 4 NNA NAI/NIN
Nonene.............................................. 30 NON NNE
2 NNI/NNN
Nonyl alcohol................................... 20 NNS
Nonyl methacrylate......................... 14 NMA
Nonyl phenol.................................... 21 NNP
Nonyl phenol (ethoxylated) ............ 40 NPE
Nonyl phenol poly(4-
12)ethoxylates ............................... 40 NPE
Nonyl phenol sulfide solution......... 33 NPS
Noxious Liquid Substance, n.o.s.
(NLS's).......................................... 0
1-0ctadeccnc .................................... 30
Octadecenoamide ............................. 10 ODD
Octane............................................... 31 OAX 100/0AN
Octanoic acid.................................... 4 OAY OAA
Octene ............................................... 30 OTX OTE
Octyl alcohol (Octanol)................... '20 ocx IOA/OTA
Octyl aldehyde................................. 19 OAL IOC/OLX
Octyl decyl adipate .......................... 34 ODA
Octyl epoxytallate ............................ 34 OET
Octyl nitrate...................................... 2 34 ONE
Octyl phenol..................................... 21
Oil, edible'
Babassu.......................................... 34 OBB
Castor............................................ 34 OCA
Coconut......................................... 2 34
occ
Com............................................... 34 oco
Cottonseed .................................... 34 ocs
Fish................................................ 2 34 OFS
Lard............................................... 34 OLD
Olive.............................................. 34 OOL
2
Palm............................................... 34 OPM
Palm kernel................................... 34 OPO
Peanut............................................ 34 OPN
Rapeseed....................................... 34 ORP
R.ice bran....................................... 34 ORB
Salllower ....................................... 34 OSF
Soya bean...................................... 34 OSB
Sunflower seed ............................. 34 OSN
Tucum........................................... 34 OTC
Vegetable ...................................... 34 OVG
Oil, fuel,
No. l ............................................ c. 33 OON
No. 1-D......................................... 33 OOD
No.2.............................................. 33 OTW
380
Table 1-Alphabetlcal List of Cargoes-Continued
Chemical name Group CHRIS Related CHRIS codeo
No. code
No. 2-D......................................... 33 OTD
No.4.............................................. 33 OFR
No. 5.............................................. 33 OFV
No. 6.............................................. 33 osx
Oil, mise:
Absorption.................................... 33 OAS
Aliphatic........................................ 33
Aromatic....................................... 33
Clarified......................................... 33 OCF
Coal............................................... 33
Coconut oi1, fatty acid methyl
ester............................................ 34 OCM
Cotton seed oil, fatty acid ........... 34 CFY
Crude............................................. 33 OIL
Diesel............................................. 33 ODS
Heartcut distillate......................... 33
Linseed.......................................... 33 OLS
Lubricating.................................... 33 OLB
Mineral.......................................... 33 OMN
Mineral seal................................... 33 OMS
Motor............................................. 33 OMT
Neatsfoot ....................................... 33 ONF
Oiticica .......................................... 34 001
Palm oil, fatty acid methyl ester. 34 OPE
Palm oil, methyl ester, see Palm
oil, fatty acid methyl ester....... 34 OPE
Penetrating.................................... 33 OPT
Pine................................................ 33 OPI
Range............................................. 33 ORO
Residual......................................... 33
Resin ............................................ .. 33 ORS
Resinous petroleum .................... .. 33
Road ............................................. . 33 ORD
Rosin ............................................. . 33 ORN
Seal ............................................... . 34
Soapstock ..................................... . 34 OIS
Soybean (epoxidized) ................. .. 40 EVO
Sperm .......................................... .. 33 OSP
Spindle .......................................... . 33 OSD
Spray ............................................ . 33 OSY
Tall ............................................... . 34 OTL
Tall, fatty acid ............................. . '34 TOF
Tanner's ........................................ . 33 OTN
Transformer ................................. . 33 OTF
Tung ............................................. . 34 OTG
Turbine ........................................ .. 33 OTB
White (mineral) ............................ . 33
381
Chemical Dame Group CHRIS Related CHRIS codes
No. code
Olefin mixtures ................................ . 30 OFX/OFY
alpha-Olefins (C6 - C18) mixtures .. 30 OAM
alpha-Olefins (Cl3 and above) ...... .. 30
Oleic acid ......................................... . 34 OLA
Oleum ............................................... . 1, :zo OLM
Oxyalkylated alkyl phenol
formaldehyde ............................... . 33
Palm kernel oil, fatty acid .............. . 34 PNO
Palm kernel oil, fatty acid methyl
ester .............................................. . 34 PNF
Palm stearin ..................................... . 34 PMS
n-Paraffins (CIO C20) ................... . 31 PFN DCC/DOC/TRD
Paraldehyde .................................... .. 19 PDH
Pentachloroethane .......................... .. 36 PCE
Pentadecanol ................................... .. 20 PDC
1,3-Pentadiene ................................. .. 30 PDE PDN
Pentaethylenehexamine,
Tetraethylenepentamine mixture. 7 PEP
Pentane ............................................. . 31 PTY IPT/PTA
Pentene ............................................. . 30 PTX PTE
Pentene, Miscellaneous
hydrocarbon mixture ................... . '30
3-Pentenenitrile ............................... .. 37 PNT
Pentyl aldehyde ............................... . 19
Perchloroethylene ........................... . 36 PER
Petrolatum ....................................... . 33 PTL
Phenol .............................................. . 21 PHN
1-Phenyl-l-xylyl ethane ................. .. 32 PXE
Phosphoric acid ............................... . PAC
Phosphorus ...................................... . 'O PPW /PPR/PPB
Phthalic anhydride ......................... .. 11 PAN
Pinene ............................................... . 30 PIN
Pine oil ............................................. . 33 OPI
Polyalkenyl succinic anhydride
amine............................................. 33
Polyalkylene glycols, Polyalkylene
glycol monoalkyl ethers
mixtures ....................................... .. 40 PPX
Polyalkyl(C18. C22) acrylate in
Xylene ......................................... .. 14 PIX
Polyalkylene oxide polyol ............. .. 20 PAO
Polybutadiene, hydroxyl
terminated ................................... .. 20
Polybutene ..................................... :.. 30 PLB
Polydimethylsiloxane ...................... . 34
Polyethylene glycol ....................... .. 40
382
No. code
Polyethylene glycol dimethyl
ether............................................... 40
Polyethylene glycol monoalkyl
ether............................................... 40 PEE
Polyethylene polyamines ................. 27 PEB
Polyferric sulfate solution................ 34 PSS
Polyglycerol ..................................... 20 GCR
Polymethylene polyphenyl
isocyanate ..................................... . 12 PPI
Polymethylsiloxane ........................ . 34
Poly(20)oxyethylene sorbitan
monooleate ................................... . 34 PSM
Polypropylene ................................. . 30 PLP
Polypropylene glycol. ..................... . 40 PGC
Polypropylene glycol methyl ether 40 PGM
Polysiloxane .......................... . 34
Potassium hydroxide solution ........ . 'S CPS
Potassium oleate ............................. . 34 POE
Propane .......................................... . 31 PRP
Propanolamine ................................. . 8 PAX MPA/PLA
Propionaldehyde ............................. . 19 PAD
Propionic acid ................................. . 4 PNA
Propionic anhydride........................ . II PAH
Propionitrile .................................. . 37 PCN
nPropoxypropanol ......................... . 40 PXP
Propyl acetate .................... . 34 lAC/PAT
Propyl alcohol ................................. . '20 IPA/PAL
Propylamine ..................................... . 7 IPP/PRAll PO
Propylbenzene ............... . 32 PBZ
iso-Propylcyclohexane ................... . 31 IPX
Propylene ........................ . 30 PPL
Propylene-butylene copolymer ...... . 30 PBP
Propylene dimer .............................. . 30 PDR
Propylene glycol ............................. . '20 PPG
Propylene glycol monoalkyl ether. 40 POE PME/PGY
Propylene glycol ethyl ether ......... . 40 PGY POE
Propylene glycol methyl ether ...... . 40 PME POE
Propylene oxide .............................. . 16 POX
Propylene tetramer ......................... . 30 P1T
Propylene trimer ............................. . 30 PTR
Propyl ether ..................................... . 41 IPE/PRE
Pseudocumene ................................. . 32 TME/TRE
Pyridine ............................................ . 9 PRD
Pyridine bases .................................. . 9 PRB
Rosin oil ........................................... . 33 ORN
Rosin soap (disproportionated)
solution ......................................... . 43 RSP
383
Table 1-Aiphabetlcal List of Cargoes-Continued
Chemloaloame Group CHRIS Related CHRIS coda
No. eode
Rum .................................................. . 20
Salicylaldehyde ................................ . 19 SAL
Sewage sludge ................................. . 43
Sodium acetate solution .................. . 34 SAN
Sodium alkyl sulfonate solution ..... . 43 ssu
Sodium aluminate solution ............. . 5 SAU
Sodium benzoate solution ............... . 34 SBN
Sodium borohydride, Sodium
hydroxide solution ....................... . 5 SBX SBH/SBI
Sodium carbonate solutions ............ . 5 SCE
Sodium chlorate solution ................ . ''O SDD SDC
Sodium cyanide solution ................ .. 5 scs SCN
Sodium dichromate solution........... . ''O SDL SCR
Sodium dimethyl naphthalene
sulfonate solution ......................... . 2 34 DNS
Sodium hydrogen sulfide, Sodium
carbonate solution ....................... . 'O sss
Sodium hydrogen sulfite solution .. . 43 SHX
Sodium hydrosulfide solution ........ . '5 SHR
Sodium hydrosulfide, Ammonium
sulfide solution ............................. . '5 SSA
Sodium hydroxide solution ............ . '5 css
Sodium hypochlorite solution ........ . 5 SHP SHC
Sodium 2-mercaptobenzothiazol
solution ......................................... . SMB
Sodium naphthalene sulfonate
solution ........................................ .. 34 SNS
Sodium nitrite solution .................. .. 5 SNI SNT
Sodium polyacrylate solution ........ .. '43
Sodium salt of Ferric hydro-
xyethylethylenediaminetriacetic
acid solution ................................. . 43 STA FHX
Sodium silicate solution................... 2
43 SSN sse
Sodium sulfide, Hydrosulfide
solution ..... .... ... .... .... .... .... .... ..... ... .. 1, 2 0 SSH/SSI/SSJ
Sodium thiocyanate solution........... t. 2 0 STS SCY
Sorbitol solutions.............................. 20 SBT
Stearic acid ....................................... 34 SRA
Styrene.............................................. 30 STY STX
Sulfolane ........................................... 39 SFL
Sulfur................................................. 1 o sxx
Sulfuric acid...................................... 2 2 SPA
Sulfuric acid, spent........................... 2 SAC
Tall oil............................................... 34 OTL
Tall oil soap (disproportionated) .
solution.......................................... 43 TOS
Tallow............................................... 2 34 TLO
384
Table 1-Aiphabetical List of Cargoes-Continued
No. eode
Tallow fatty acid ............................. . '34 TFD
Tallow fatty alcohol ....................... . 20 TFA
Tallow nitrile ................................... . 37
l, 1,2,2-Tetrachloroethane ............... . 36 TEC
Tetradecanol .................................... . 20 TTN
Tetradecene ..................................... . 30 TTD
Tetradecylbenzene .......................... . 32 TDB AKB
Tetraethylene glycol ....................... . 40 TTO
Tetraethylenepentamine .................. . 7 TTP
Tetrahydrofuran ............................. .. 41 THF
Tetrahydronaphthalene ................... . 32 THN
I ,2,3,5-Tetramethylbenzene ........... .. 32 TTB
Tetrasodium salt of EDTA
solution ......................................... . 43 EDS
Titanium tetrachloride..................... 2 TTT
Toluene............................................. 32 TOL
Toluenediamine ................................ 9 TDA
Toluene diisocyanate ....................... 12 TDI
o-Toluidine........................................ 9 TLI
Triarylphosphate .............................. 34
Tributyl phosphate........................... 34 TBP
1,2,4-Trichlorobenzene .................... 36 TCB
1,1,1-Trichloroethane....................... 2 36
TCE
I, 1,2-Trichloroethane....................... 36 TCM
Trichloroethylene............................. 2 36 TCL
1,2,3-Trichloropropane .................... 36 TCN
I, I ,2-Trichloro-1,2,2-
trifluoroethane .............................. 36 TTF
Tricresyl phosphate.......................... 34 TCO/TCP
Tridecane .......................................... 31 TRD PFN
Tridecanol......................................... 20 TDN
Tridecene .......................................... 30 TDC
Tridecylbenzene ............................... 32 TRB AKB
Triethanolamine................................ 28 TEA
Triethylamine................................... 7 TEN
Triethylbenzene................................ 32 TEB
Triethylene glycol............................ 40 TEO
Triethylene glycol butyl ether....... 40
Triethylene glycol butyl ether
mixture .......................................... 40
Triethylene glycol di-(2-
ethylbutyrate) ............................... . 34 TOD
Triethylene glycol ether mixture .. .. 40
Triethylene glycol ethyl ether ....... . 40 TOE
Triethylenetetramine ....................... . '7 TET
Triethyl phosphate ........................ .. 34 TPS
Triethyl phosphite ......................... .. '34 TPI
385
Chemlealnome
Triisobutylene .................................. .
Triisooctyl trimellitate ................... ..
Group
No.
30
34
.....
CHRIS
TIB
Related CHRIS codes
Triisopropanolamine ....................... . 8 TIP

Triisopropanolamine salt of 2,4-
solution ......................................... . 43 DTI
Trimethylacetic acid ....................... . 4 TAA
Trimethylbenzene ............................ . 32 TRE TME/TMB/TMD
Trimethylhexamethylenediamine
(2,2,4- and 2,4,4-) ......................... . 7 THA
Trimethylhexamethylene
diisocyanate (2,2,4- and 2,4,4-) .... 12 THI
Trimethylol propane
polyethoxylate ............................. . 20 TPR
2,2,4-Trimethyl pentanediol-1,3-
diisobutyrate................................. . 34
2,2,4-Trimethyl-1,3-pentanediol-1-
isobutyrate .................................... . 34 TMP
2,2,4-Trimethy1-3-pentano1-1-
isobutyrate .................................... . 34
Trimethyl phosphite ........................ . '34 TPP
Tripropylene .................................... . 30
Tripropylene glycol ........................ . 40 TGC
Tripropylene glycol methyl ether .. 40 TOM
Trisodium nitrilotriacetate .............. . 34
Trixy1eny1 phosphate ...................... . 34 TRP
Turpentine ........................................ . 30 TPT
Undecanoic acid ............................. .. 4 UDA
Undecanol ........................................ . 20 UND
Undecene ......................................... . 30 UDC
Undecyl alcohol .............................. . 20 UND
Undecylbenzene ............................. .. 32 UDB AKB
Urea, Ammonium mono- and di-
hydrogen phosphate, Potassium
chloride solution .......................... . 0 UPX
Urea. Ammonium nitrate solution
(containing Ammonia) ............... .. 6 UAS
Urea, Ammonium nitrate solution
(not containing Ammonia) .......... . 43 ANU
Urea. Ammonium phosphate
solution ......................................... . 43 UAP
V aleraldehyde .................................. . 19 IV A/V AL/V AK
Vanillin black liquor ....................... . 5 VBL
Vegetable protein solution ............ .. 43
Vinyl acetate ...................................... 13 VAM
Vinyl acetate-Fumarate copolymer 34
Vinyl chloride ................................. . 35 VCM
386
Chemical name
Vinyl ethyl ether ............................. .

Group
No.
13
.....
CHRIS
VEE
Related CHRIS codes
Vinylidene chloride ......................... . 35 VCI

Vinyl neodecanate ........................... . 13 VND
VinyltoJuene .................................... . 13 VNT
Waxes: .............................................. . WAX
Carnauba ...................................... . 34 WCA
Paraffin ......................................... . 31 WPF
White spirit (low (15-20%)
aromatic) ..................................... .. 33 WSL WSP
Xylene .............................................. . 32 XLX XLM/XLO/XLP
Xylenols ........................................... . 21 XYL
Zinc bromide, Calcium bromide
solution see Drilling brine
(containing Zinc salts) ................. . 43 DZB
1
Because of very high reactivity or unusual conditions of carriage or potential compat-
ibility problems, this product is not assigned to a specific group in the Compatibility
Chart. For additional compatibility information, contact Commandant (G-MTH), U.S.
Coast Guard, 2100 Second Street, SW., Washington, D.C. 20593--0001. Telephone (202)
267-1577.
2
See Appendix !-Exceptions to the Chart.
387
Table II-Grouping of Cargoes
0. Unusi1111ed Cargoes Urea, Ammonium mono- and di-
Acetone cyanohydrin 1 2 hydrogen phosphate, Potassium
Alkylbenzenesulfonic acid 1. 2 chloride solution
Aluminium chloride, Hydrochloric 1. Non-Oxidizing Mineral Acids
acid solution 1 Di-(2-ethylhexyl)phosphoric acid
Ammonium hydrogen phosphate Ferric chloride solution
solution 1 Hydrochloric acid
Ammonium nitrate solution 1 Hydrochloric acid, spent
Ammonium thiocyanate, Ammonium HydrofluorosiJicic acid
thiosulfate solution 1 Phosphoric acid
Benzenesulfonyl chloride t. 2 2. Sulfuric Acids
gamma-Butyrolactone t. 2 Sulfuric acid 2
Chlorine 1 Sulfuric acid, spent
Chlorosulfonic acid 1 Titanium tetrachloride
2,4-Dichlorophenoxyacetic acid, 3. Nitric Acid
Dimethylamine salt solution t. 2 Ferric nitrate, Nitric acid solution
Dimethylamine salt of 2,4- Nitric acid (70% or less)
Dichlorophenoxyacetic acid 4. Organic Adds
solution t.z Acetic acid 2
Diphenylol propane-Epichlorohydrin Acrylic acid 2
1
resins Butyric acid
Dodecylbenzenesulfonic acid 12 Cashew nut shell oil (untreated)
Ethyl chlorothioformate t. 2 Chloroacetic acid solution
Ethylene oxide 1 Chloropropionic acid
2-Hydroxyethyl acrylate L 2 Cyclohexane oxidation product acid
Magnesium chloride solution 1 2 water
Molasses residue 1 Decanoic acid
Motor fuel antiknock compounds 2,2-Dichloropropionic acid
containing Lead alkyls 1 2,2-Dimethyloctanoic acid
Naphthalene sulfonic acid- 2-Ethylhexanoic acid
formaldehyde copolymer, sodium Formic acid 2
salt solution 1 n-Heptanoic acid
Nitrating acid 1 Hexanoic acid
Nitric acid (greater than 70%) 1 2-Hydroxy-4-(methylthio)butanoic
o-Nitrophenol 1 2 acid
Noxious Liquid Substance, n.o.s. Methacrylic acid
(NLS's) ' Naphthen.c acid
Oleum 1. 2 Neodecanoic acid
Phosphorus 1 Nonanoic acid
Sodium chlorate solution 1. 2 Octanoic acid
Sodium dichromate solution 1. 2 Propionic acid
Sodium hydrogen sulfide, Sodium Trimethylacetic acid
carbonate solution 1. 2 Undecanoic acid
Sodium sulfide, Hydrosulfide 5. Caustics
solution 1 2 Ammonium sulfide solution
1 2
Sodium thiocyanate solution Calcium hypochlorite solutions
Sulfur 1 Caustic potash solution 2
Caustic soda solution 2
Cresylate spent caustic
388
Cresylic acid, sodium salt solution Hexamethylenetetramine solutions
Kraft black liquor Hexamethylenimine
Kraft pulping liquors Isophorone diamine
Mercaptobenzothiazol, sodium salt Metam sodium solution
solution Methylamine
Potassium hydroxide solution 2 Methylamine solutions
Sodium aluminate solution Morpholine 2
Sodium borohydride, Sodium Pentaethylenehexamine,
hydroxide solution Tetraethylenepentamine mixture
Sodium carbonate solutions Polyethylene polyamines 2
Sodium cyanide solution Propylamine
Sodium hydrosulfide solution 2 Tetraethylenepentamine
Sodium hydrosulfide, Ammonium Triethylamine
sulfide solution 2 Triethylenetetramine 2
Sodium hydroxide solution 2 Trimethylhexamethylene diamine
Sodium hypochlorite solution (2,2,4- and 2,4,4-)
Sodium 2-mercaptobenzothiazol 8. Alkanolamines
solution 2-(2-Aminoethoxy)ethanol
Sodium nitrite solution Aminoethyldiethanolamine,
Vanillin black liquor Aminoethylethanolamine solution
6. Ammonia Aminoethylethanolamine
Ammonia, anhydrous 2-Amino-2-methyl-1-propanol
Ammonium hydroxide (28% or less Diethanolamine
Ammonia) Diethylaminoethanol
Ammonium nitrate, Urea solution Diethylethanolamine
(containing Ammonia) Diisopropanolamine
Urea, Ammonium nitrate solution Dimethylethanolamine
(containing Ammonia) Ethanolamine
7. Aliphatic Amines Propanolamine
N-Aminoethylpiperarine Triethanolamine 2
Butylamine Triisopropanolamine
Cyclohexylamine 9. Aromatic Amioes
Dibutylamine Aniline
Diethylamine 2 4-Chloro-2-methylphenoxyacetic
Diethylenetriamine acid, Dimethylamine salt solution
Diisobutylamine 2,6-Diethylaniline
Diisopropylamine Dimethylamine salt of 4-Chloro-2-
Dimethylamine methylphenoxyacetic acid solution
Dimethylamine solution 2,6-Dimethylaniline
N,N-Dimethylcyclohexylamine 2-Ethyl-6-methyl-N-( I'-methyl-2-
Di-n-propylamine methoxyethyl)aniline
Dodecylamine, Tetradecylamine 4,4'-Methylene dianiline (43% or
mixture 2 less), Polymethylene
Ethylamine 2 polyphenylamine, a-
Ethylamine solution Dichlorobenzene mixtures
N-Ethyl-n-butylamine 2-Methyl-6-ethyl aniline
N-Ethyl cyclohexylamine 2-Methyl-5-ethyl pyridine
Ethylenediamine 2 Methyl pyridine
2-Ethyl hexylamine 3-Methylpyridine
Hexamethylenediamine solution N-Methyl pyrrolidone
Hexamethylenetetramine Pyridine
389
Pyridine bases 1,3-Dichloropropene
Toluenediamine Dichloropropene, Dichloropropane
p-Toluidine mixtures
10. Amides Methacrylonitrile
Acrylamide solution 16. Alkylene Oxides
N,N-Dimethylacetamide Butylene oxide
N,N-Dimethylacetamide solution Ethylene oxide, Propylene oxide
Dimethylformamide mixtures
Formamide Propylene oxide
Octadecenoan11de 17. Epichlorohydrin
11. Organic Anhydrides Chlorohydrins
Acetic anhydride Epichlorohydrin
Maleic anhydride 18. Ketones
Phthalic anhydride Acetone 2
Propionic anhydride Acetophenone
Isocyanates Amyl methyl ketone
Diphenylmethane diisocyanate Butyl heptyl ketone
lsophorone diisocyanate Camphor oil
Polymethylene polyphenyl Cyclohexanone
isocyanate Cyclohexanone, Cyclohexanol
Toluene diisocyanate mixtures 2
Trimethylhexamethylene Diisobutyl ketone
diisocyanate (2,2,4- and 2,4,4-) Ethyl amyl ketone
13. Vinyl Acetate Epoxy resin
Vinyl acetate Ketone residue
Vinyl ethyl ether Isophorone 2
Vinyl neodecanate Mesityl oxide 2
Vinyl toluene Methyl amyl ketone
14. Acrylates Methyl butyl ketone
Butyl acrylate Methyl butyl ketone
Butyl methacrylate Methyl diethanolamine
Butyl methacrylate, Decyl Methyl ethyl ketone 2
methacrylate, Cetyl-Eicosyl Methyl heptyl ketone
methacrylate mixture Methyl isoamyl ketone
Cetyl-Eicosyl methacrylate mixture Methyl isobutyl ketone 2
Decyl acrylate 19. Aldehydes
Dodecyl methacrylate Acetaldehyde
Dodecyl-Pentadecyl methacrylate Acrolein 2
mixture Butyraldehyde
Ethyl acrylate Crotonaldehyde 2
2-Ethylhexyl acrylate Decaldehyde
Ethyl methacrylate Ethylhexaldehyde
Methyl acrylate 2-Ethyl-3-propylacrolein 2
Methyl methacrylate Formaldehyde, Methanol mixtures '
Nonyl methacrylate Formaldehyde solution 2
Polyalkyl(CIS- C22) acrylate in Furfural

Xylene Glutaraldehyde solution
15. Substituted Allyls Glyoxal solutions
Acrylonitrile 2 3-Methyl butyraldehyde
Allyl alcohol 2 Methylolureas
Allyl chloride Octyl aldehyde
390
Paraldehyde Polybutadiene, hydroxyl terminated
Pentyl aldehyde Polyglycerol
Propionaldehyde Propyl alcohol 2
Salicylaldehyde Propylene glycol 2
Valeraldehyde Rum
211. Aleobols, Glycols Sorbitol solutions
Acrylonitrile-Styrene copolymer Tallow fatty alcohol
dispersion in Polyether polyol Tetradecanol
Alcoholic beverages Tridecanol
Alcohol polyethoxylates Trimethylol propane polyethoxylate
Alcohol polyethoxylates, secondary Undecanol
Alcohols (C13 and above) Undecyl alcohol
Amyl alcohol 21. Pbeools, Creools
Behenyl alcohol Benzyl alcohol
Brake fluid base mixtures Carbolic oil
Butyl alcohol 2 Creosote 2
Butylene glycol 2 Cresols
Choline chloride solutions Cresylic acid
Cyclohexanol 2,4-Dichlorophenol
Decyl alcohol 2 Dodecyl phenol
Diacetone alcohol 2 o-Ethylphenol
Diisobutyl carbinol Nonyl phenol
2,2-Dimethylpropane-1,3-diol Octyl phenol
Dodecanol Phenol
Dodecyl alcohol Xylenols
Ethoxylated alcohols, Cti-CIS 22. Caprolactam Solution~
2-Ethoxyethanol Caprolactam solution
Ethyl alcohol 2 :13 - :19. Unualped
Ethyl butanol 30. Oleftas
Ethylene chlorohydrin Amylene
Ethylene cyanohydrin Butadiene
Ethylene glycol 2 Butadiene, Butylene mixtures (cont.
2-Ethylhexanol Acetylenes)
Furfuryl alcohol 2 Butene
Glycerine 2 Butene oligomer
Heptanol Butylene
Hexanol I ,S,9-Cyclododecatriene
Hexylene glycol 1,3-Cyclopentadiene dimer
3-Methoxy-1-butanol Cyclopentadiene polymers
Methyl alcohol 2 Cyclopentadiene, Styrene, Benzene
Methyl amyl alcohol mixture
Methyl butenol Cyclopentene
Methylbutynol Decene
2-Methyl-2-hydroxy-3-butyne Dicyclopenladiene
Methyl isobutyl carbinol Diisobutylene
3-Methyl-3-methoxybutanol Dipentene
Molasses Dodecene
Nonyl alcohol 2 Ethylene
Octyl alcohol 2 Ethylidene norbornene 2
Pentadecanol 1-Heptene
Polyalkylene oxide polyol Hexene
391
Isoprene Propane
Methyl acetylene, Propadiene iso Propylcyclohexane
mixture Tridecane
Methylcyclopentadiene dimer Waxes:
2Methyllpentene ParafTm
4-Methyllpentene 32. Aromatic: Hydrocarbou
alphaMethyl styrene Alkyl acrylate Vinyl pyridine
Myrcene copolymer in Toluene
Nonene Alkyl(C9 Cl7) benzenes
I..Qctadccene Benzene
Octene Benzene hydrocarbon mixtures
Olefm mixtures (having 10% Benzene or more)
alpha..Qlefins (C6 CIS) mixtures Benzene, Toluene, Xylene mixtures
alpha..Qlefins (Cl3 and above) Butylbenzene
1,3Pentadiene Butyl phenol, Formaldehyde resin in
Pentene Xylene
Pentene, Miscellaneous hydrocarbon Butyl toluene
mixture 1 Cumene
Pinene Cymene
Poly butene Decylbenzene
Polypropylene Dialkyl(CIO- C14) benzenes
Propylene Diethylbenzene
Propylene-butylene copolymer Diisopropylbenzene
Propylene dimer Diisopropyl naphthalene
Propylene tetramer Diphenyl
Propylene trimer Dodecylbenzene
Styrene Ethylbenzene
Tetradecene Ethyl toluene
Tridecene Isopropyl benzene
Triisobutylene Methyl naphthalene
Tripropylene Naphthalene
Turpentine lPhenyllxylyl ethane
Undecene Propylbenzene
31. l'anlliDI Pseudocumene
Butane Tetradecylbenzene
Cycloaliphatic resins Tetrahydronaphthalene
Cycloheptane l,2,3,STetramethylbenzene
Cyclohexane Toluene
Cyclopentane Tridecylbenzene
Decane Triethylbenzene
Dodecane Trimethylbenzene
Ethane Undecylbenzene
Heptane Xylene
Hexane 1 33. Mllcellall..., Hydroelrbon Mixtures
Methane Alkylbenzenesulfonic acid, sodium
Methylcyclohexane salt solutions
2-Methyl pentane Asphalt blending stocks, roofen flux
Nonane Asphalt blending stocks, straight run
Octane residue
n-Paraffins (CIO C20) Aviation alkylates
Pentane
392
Calcuim sulfonate, Calcium No.5
carbonate, Hydrocarbon solvent No.6
mixture Oil, mise:
Carbon black base Absorption
Coal tar Aliphatic
Coal tar pitch Aromatic
Decahydronaphthalene Clarified
Diphenyl, Diphenyl ether Coal
Distillates, flashed feed stocks Crude
Distillates, straight run Diesel
Drilling mud (low toxicity) (if Heartcut distillate
flammable or combustible) Linseed
Fatty acid amides Lubricating
Gas oil, cracked Mineral
Gasoline blending stock, alkylates Mineral seal
Gasoline blending stock, reformates Motor
Gasolines: Neatsfoot
Automotive (no/ over 4.23 grams Penetrating
lead per gal.) Pine
Aviation (not over 4.86 grams Range
lead per gal.) Resin
Casinghead (natural) Resinous petroleum
Polymer Rosin
Straight run Sperm
Glycols, Resins, and Solvents Spindle
mixture Spray
Herbicide (Cl5-H22-N02-Cl) Tanner's
Jet Fuels: Turbine
JP-1 White (mineral)
JP-3 Residual
JP-4 Road
JP-5 Transformer
JP-8 Oxyalkylated alkyl phenol
Kerosene formaJdehyde
Magnesium nonyl phenol sulfide Petrolatum
Maleic anhydride copolymer Pine oil
Mineral spirits Polyalkenyl succinic anhydride
Naphtha: amine
Coal tar solvent White spirit (low (15-20%) aromatic)
Cracking fraction 2 34. Ellen
Petroleum Acetyl tributyl citrate
Solvent Alkyl phtbalates
Stoddard solvent Amyl acetate
Varnish Makers' and Painters' Amyl tallate
Nonyl phenolsulfide solution Ben2e11e tricarboxylic acid trioctyl
Oil, fUel: ester
No.1 Benzyl acetate
No. 1-D Butyl acetate
No.2 Butyl benzyl phthalate
No. 2-D n-Butyl butyrate
No.4 Butyl formate
393
iso-Butyl isobutyrate Ethyl hexyl phthalate
Calcium naphthenate in Mineral oil Ethyl hexyl tallate
Calcium nitrate, Magnesium nitrate, Ethyl propionate
Potassium chloride solution Ethyl propionate
Coconut oil, fatty acid Fatty acids (saturated, Cl3 and
Cottonseed oil, fatty acid above)
Cyclohexyl acetate Glycerol polyalkoxylate
Dialkyl(C7- Cl3) phthalates Glyceryl triacetate
Dibutyl phthalate Gylcidyl ester of tridecylacetic acid
Diethylene glycol butyl ether acetate Glycidyl ester of Versatic acid
Diethylene glycol ethyl ether acetate Glycol diacetate
Diethylene glycol methyl ether Heptyl acetate
acetate Hexyl acetate
Diethylene glycol phthalate Lauric acid
Di-(2-ethylhexyl)adipate Magnesium sulfonate
Di-(2-dthylhexyl)phthalate 3-Methoxybutyl acetate
Diethyl phthalate 1-Methoxy-2-propyl acetate
Diethyl sulfate Methyl acetate
Diheptyl phthalate Methyl acetoacetate
Di-n-hexyl adipate Methyl amyl acetate
Diisobutyl phthalate Methyl butyrate
Diisodecyl phthalate Methyl formate
Diisononyl adipate 3-Methyl-3-methoxybutyl acetate
Diisononyl phthalate Methyl salicylate
Diisooctyl phthalate Metolachlor
Dimethyl adipate Naphthalene sulfonic acid, sodium
Dimethylcyclicsiloxane hydrolyzate salt solution (40% or less)
Dimethyl glutarate Octyl decyl adipate
Dimethyl hydrogen phosphite 2 Octyl epoxytallate
Dimethyl naphthalene sulfonic acid, Octyl nitrate 2
sodium salt solution 2 Oil, edible,
Dimethyl phthalate Babassu
Dimethyl polysiloxane Castor
Dimethyl succinate Coconut 2
Dinonyl phthalate Corn
Dioctyl phthalate Cotton seed
Dipropylene glycol dibenzoate Fish 2
Ditridecyl phthalate Lard
2-Dodecenylsuccinic acid, Olive
dipotassium salt solution Palm 2
Diundecyl phthalate Palm kernel
2-Ethoxyethyl acetate Peanut
Ethyl acetate Rapeseed
Ethyl acetoacetate Rice bran
Ethyl butyrate Safflower
Ethylene glycol acetate Soya bean
Ethylene glycol butyl ether acetate Sunflower
Ethylene glycol diacetate Sunflower seed
Ethylene glycol ethyl ether acetate Tucum
Ethylene glycol methyl ether acetate Vegetable
Ethyl-3-ethoxypropionate
394
Oil, mise: Waxes:
Coconut oil, fatty acid methyl Carnauba
ester 35, Vinyl Halides
Cotton seed oil, fatty acid Vinyl chloride
Palm oil, fatty acid methyl ester Vinylidene chloride
Palm oil, methyl ester 36. Halogenated Hydrocarbons
Soapstock Benzyl chloride
Tall Carbon tetrachloride
Tall, fatty acid 2 Chlorinated paraffins (ClO- C13)
Tung Chlorinated paraffins (Cl4- C17)
Oleic acid Chlorobenzene
Palm kernel oil, fatty acid Chlorodifluoromethane
Palm kernel oil, fatty acid methyl Chloroform
ester Chlorotoluene
Palm stearin Dichlorobenzene
Polydimethylsiloxane Dichlorodifluoromethane
Polyferric sulfate solution I, 1-Dichloroethane
Polymethylsiloxane 2,2'-Dichloroisopropyl ether
Poly(20)oxyethylene sorbitan Dichloromethane
monooleate Dichloropropane
Polysiloxane Ethyl chloride
Potassium oleate Ethylene dibromide
Propyl acetate Ethylene dichloride 2
Sodium acetate solution Methyl bromide
Sodium benzoate solution Methyl chloride
Sodium dimethyl naphthalene Monochlorodifluoromethane
sulfonate solution 2 Pentachloroethane
Sodium naphthalene sulfonate Perchloroethylene
solution 1,1 ,2,2-Tetrachloroethane
Stearic acid 1,2,4-Trichlorobenzene
Tall oil 1,1,1-Trichloroethane 2
Tallow 2 1, 1,2-Trichloroethane
Tallow fatty acid 2 Trichloroethylene 2
Triarylphosphate 1,2,3-Trichloropropane
Tributyl phosphate I, I ,2-Trichloro-1,2,2-trifluoroethane
Tricresyl phosphate 37. Nitriles
Triethylene glycol di-(2- Acetonitrile
ethylbutyrate) Adiponitrile
Triethyl phosphate Lactonitrile solution
Triethyl phosphite 2 3-Pentenenitrile
Triisooctyl trimellitate 2 Propionitrile
2,2,4-Trimethyl pentanediol-1,3- Tallow nitrile
diisobutyrate 38. Carbon Disulfide
2,2,4-T rimeth y1-1 ,3-pentanediol-1-
Carbon disulfide
isobutyrate
39. Sulfolane
2,2,4-Trimethyl-3-pentanol-1-
Sulfolane
isobutyrate
40. Glycol Ethers
Trimethyl phosphite 2
Diethylene glycol
Trisodium nitrilotriacetate
Diethylene glycol butyl ether
Trixylenyl phosphate
Diethylene glycol dibutyl ether
Vinyl acetate-Fumarate copolymer
Diethylene glycol ethyl ether
395
Diethylene glycol methyl ether Ethyl ether
Diethylene glycol phenyl ether Methyl-tert-butyl ether 2
Dipropylene glycol Methyl formal
Dipropylene glycol methyl ether Propyl ether
Ethoxy triglycol Tetrahydrofuran
Ethylene glycol tert-butyl ether 42. Nitrocompounds
Ethylene glycol butyl ether Dinitrotoluene
Ethylene glycol dibutyl ether Nitrobenzene
Ethylene glycol ethyl ether o-Nitrochlorobenzene
Ethylene glycol isopropyl ether Nitroethane
Ethylene glycol methyl ether Nitropropane
Ethylene glycol phenyl ether Nitropropane, Nitroethane mixture
Ethylene glycol phenyl ether, Nitrotoluene
Diethylene glycol phenyl ether 43. Mistellaaeous Water Solutions
mixture Aluminum sulfate solution 2
Ethylene glycol propyl ether 2-Amino-2-hydroxymethyl-1,3-
Methoxy triglycol propanediol solution
Nonyl phenol (ethoxylated) Ammonium bisulfite solution 2
Nonyl phenol poly(4-12)ethoxylates Ammonium nitrate, Urea solution
Oil, mise: (not containing Ammonia)
Soybean (epoxidized) Ammonium polyphosphate solution
Polyalkylene glycols, Polyalkylene Ammonium sulfate solution
glycol monoalkyl ethers mixtures Ammonium thiosulfate solution
Polyethylene glycols Calcium bromide solution
Polyethylene glycol dimethyl ether Calcium chloride solution
Polyethylene glycol monoalkyl ether Corn syrup
Polypropylene glycol methyl ether Dextrose solution
Polypropylene glycols Diammonium salt of Zinc EDT A
n-Propoxypropanol solution
Propylene glycol monoalkyl ether 2,4-Dichlorophenoxyacetic acid,
Propylene glycol ethyl ether Diethanolamine salt solution
Propylene glycol methyl ether 2,4-Dichlorophenoxyacetic acid,
Tetraethylene glycol Triisopropanolamine salt solution
Triethylene glycol
Triethylene glycol butyl ether Didecyl dimethyl ammonium
Triethylene glycol butyl ether chloride, Ethanol mixture solution
mixture Diethanolamine salt of 2,4-
Triethylene glycol ether mixture Dichlorophenoxyacetic acid
Triethylene glycol ethyl ether solution
Tripropylene glycol Dodecyl diphenyl ether disulfonate
Tripropylene glycol methyl ether solution
41. Etben Drilling brine (containing Calcium,
Butyl ether Potassium, or Sodium salts)
2,2'-Dichloroethyl ether Drilling brine (containing Zinc salts)
Digylcidyl ether of Bisphenol A Drilling mud Oow toxicity) (if non-
Diglycidyl ether of Bisphenol F flammable or non-combustible)
Dimethyl furan Ethylenediaminetetracetic acid,
1,4-Dioxane tetrasodium salt solution
Diphenyl ether Ethylene-Vinyl acetate copolymer
Diphenyl ether, Diphenyl phenyl emulsion
ether mixture
396
Ferric hydroxyethylethylenediamine Tall oil soap (disproportionated)
triacetic acid, trisodium salt solution
solution 1 Tetrasodium salt of EDTA solution
Fish solubles (water based ftsh meal Triisopropanolamine salt of 2,4-
extracts) Dichlorophenoxyacetic acid
Fructose solution solution
Fumaric adduct of Rosin, water Urea, Ammonium nitrate solution
dispersion (not containing Ammonia)
N(Hydroxyethyl)ethylene diamine Urea, Ammonium phosphate solution
triacetic acid, trisodium salt Vegetable protein solution
solution (hydrolysed)
Kaolin clay s1urry
Latex, liquid synthetic
Lignin liquor Footnotes to Table II
Naphthenic acid, sodium salt solution 1 Because of very high reactivity or un-
Rosin soap (disproportionated) usual conditions of carriage or potential

solution compatibility problems, this product is not
Sewage sludge, treated assigned to a specific group in the Com-
Sodium alkyl sulfonate solution patibility Chart. For additiona1 compat-
Sodium hydrogen sulfite solution ibility information, contact Commandant
Sodium polyacrylate solution 2 (G-MTH) , U.S. Coast Guard, 2100
Sodium salt of Ferric Second Street, SW., Washington, D.C.
hydroxyethy]ethylenediamine 20593-0001. Telephone (202) 267-1577.
triacetic acid solution 2 See Appendix 1-Exceptions to the
Sodium silicate solution 2 Chart.
Appendix I-Exceptions to the Chart

(a). The binary combinations listed below have been tested as pre-
scribed in Appendix III and found not to be dangerously reactive.
These combinations are exceptions to the Compatibility Chart (Figure
I) and may be stowed in adjacent tanks.
Member of reactive group Compatible with
Acetone (t8) Diethylenetriamine (7)

Acetone cyanohydrin (0) Acetic acid (4)
Acrylonitrile (15) Triethanolamine (8)
1,3-Butylene glycol (20) Morpholine (7)
1,4-Butylene glycol (20) Ethylamine (7)
Triethanolamine (8)
Caustic potash, 50% or less (5) Ethyl alcohol (20)
Ethylene glycol (20)
Isopropyl alcohol (20)
Methyl alcohol (20)
iso-Octyl alcohol (20)
397
Member of reactive group Compatible with
Caustic soda, 50% or less (5) Butyl alcohol (20)

tart-Butyl alcohol, Methanol mixtures
Decyl alcohol (20)
Diacetone alcohol (20)
Diethylene glycol (40)
Ethyl alcohol (20)
Ethyl alcohol (40%, whiskey) (20)
Ethylene glycol, Diethylene glycol mixture
(20)
Ethyl hexanol (Octyl alcohol) (20)
Methyl alcohol (20)
Nonyl alcohol (20)
Propyl alcohol (20)
Propylene glycol (20)
Sodium chlorate (0)
iso-Tridecanol (20)
Dodecyl and Tetradecylamine mixture (7) Tall oil, fatty acid (34)
Ethylenediamine (7) Butyl alcohol (20)
tart-Butyl alcohol (20)
Butylene glycol (20)
Creosote (21)
Diethylene glycol (40)
Ethyl alcohol (20)
Ethyl hexanol (20)
Glycerine (20)
lsononyl alcohol (20)
lsophorone (18)
Methyl butyl ketone (18)
Methyl iso-butyt ketone (18)
Methyl ethyl ketone (18)
Propyl alcohol (20)
Propylene glycol (20)
Oleum (0) Hexane (31)
Dichloromethane (36)
Perchloroethylene (36)
1,2-Propylene glycol (20) Diethylenetriamine (7)
Polyethylene potyamines (7)
Triethylenetetramine (7)
Sulfuric acid (2) Coconut oil (34)
Coconut oil acid (34)
Palm oil (34)
Tallow (34)
Sulfuric acid, 98% or less (2) Choice white grease tallow (34)
398
(b). The binary combinations listed below have been determined to
be dangerously reactive, based on either data obtained in the literature
or on laboratory testing which has been carried out in accordance with
procedures prescribed in Appendix III. These combinations are excep-
tions to the Compatibility Chart (Figure I) and may not be stowed in
adjacent tanks.
Acetone cyanohydrin (0) is not compatible with Groups 1-12, 16, 17,
and 22.
Acrolein (19) is not compatible with Group I, Non-Oxidizing Miner-
al Acids.
Acrylic acid (4) is not compatible with Group 9, Aromatic Amines.
Alkylbenzenesulfonic acid (0) is not compatible with Groups 1-3, 5-9,
15, 16, 18, 19, 30, 34, 37, and strong oxidizers.
Allyl alcohol (15) is not compatible with Group 12, Isocyanates.
Aluminum sulfate solution (43) is not compatible with Groups 5-11.
Ammonium bisulfite solution (43) is not compatible with Groups I, 3,
4, and 5.
Benzenesulfonyl chloride (0) is not compatible with Groups 5-7 and
43.
gamma-Butyrolactone (0) is not compatible with Groups 1-9.
Crotonaldehyde (19) is not compatible with Group I, Non-Oxidizing
Mineral Acids.
Cyclohexanone, Cyclohexanol mixture ( 18) is not compatible with
Group 12, Isocyanates.
2,4-Dichlorophenoxyacetic acid, Dimethylamine salt solution (0) is
not compatible with Groups 1-5, II, 12, and 16.
2,4-Dichlorophenoxyacetic acid, Triisopropanolamine salt solution
(43) is not compatible with Group 3, Nitric Acid.
Dimethyl hydrogen phosphite (34) is not compatible with Groups
and 4.
Dimethyl naphthalene sulfonic acid, sodium salt solution (34) is not
compatible with Group 12, Formaldehyde, and strong oxidizing
agents.
Dodecylbenzenesulfonic acid (0) is not compatible with oxidizing
agents and Groups I, 2, 3, 5, 6, 7, 8, 9, 15, 16, 18, 19, 30, 34, and 37.
399
Ethyl chlorothioformate (0) is not compatible with Groups 5, 6, 7, 8,
and 9.
Ethylenediamine (7) is not compatible with Ethylene dichloride (36).
Ethylene dichloride (36) is not compatible with Ethylenediamine (7).
Ethylidene norbomene (30) is not compatible with Groups 1-3 and 5-
8.
2-Ethyl-3-propylacrolein (19) is not compatible with Group 1, Non-
Oxidizing Mineral Acids.
Ferric hydroxyethylethylenediamine triacetic acid, Sodium salt solu-
tion (43) is not compatible with Group 3, Nitric acid.
Fish oil (34) is not compatible with Sulfuric acid (2).
Formaldehyde (over 50%) in Methyl alcohol (over 30%) (19) is not
compatible with Group 12, Jsocyanates.
Formic acid (4) is not compatible with Furfural alcohol (20).
Furfuryl alcohol (20) is not compatible with Group 1, Non-Oxidizing
Mineral Acids and Formic acid (4).
2-Hydroxyethyl acrylate is not compatible with Groups 2, 3, 5-8, and
12.
Isophorone ( 18) is not compatible with Group 8, Alkanolamines.
Magnesium chloride solution (0) is not compatible with Groups 2, 3,
5, 6, and 12.
Mesityl oxide (18) is not compatible with Group 8, Alkanolamines.
Methyl tert-butyl ether (41) is not compatible with Group 1, Non-
oxidizing Mineral Acids.
Naphtha, cracking fraction (33) is not compatible with strong acids,
caustics or oxidizing agents.
o-Nitrophenol (0) is not compatible with Groups 2, 3, and 5-10.
Octyl nitrates (all isomers) (34) is not compatible with Group I, Non-
oxidizing Mineral Acids.
Oleum (0) is not compatible with Sulfuric acid (2) and 1,1,1-Trichlor-
oethane (36).
Pentene, Miscellaneous hydrocarbon ntixtures (30) are not compatible
with strong acids or oxidizing agents.
400
o Sodium chlorate solution (50% or less) (0) is not compatible with
Groups 1-3, 5, 7, 8, 10, 12, 13, 17, and 20.
o Sodium dichromate solution (70% or less) (0) is not compatible with
Groups 1-3, 5, 7, 8, 10, 12, 13, 17, and 20.
0 Sodium dimethyl naphthalene sulfonate solution (34) is not compati-
ble with Group 12, Formaldehyde and strong oxidizing agents.
o Sodium hydrogen sulfide, Sodium carbonate solution (0) is not com-
patible with Groups 6 (Ammonia) and 7 (Aliphatic amines).
o Sodium hydrosulfide (5) is not compatible with Groups 6 (Ammonia)
and 7 (Aliphatic amines).
o Sodium hydrosulfide, Ammonium sulfide solution (5) is not compati-
ble with Groups 6 (Ammonia) and 7 (Aliphatic amines).
0 Sodium polyacrylate solution (43) is not compatible with Group 3,
Nitric Acid.
o Sodium salt of Ferric hydroxyethylethylenediamine triacetic acid so-
lution (43) is not compatible with Group 3, Nitric acid.
0 Sodium silicate solution (43) is not compatible with Group 3, Nitric
Acid.
o Sodium sulfide, hydrosulfide solution (0) is not compatible with
Groups 6 (Ammonia) and 7 (Aliphatic amines).
o Sodium thiocyanate (56% or less) (0) is not compatible with Groups
1-4.
0 Sulfuric acid (2) is not compatible with Fish oil (34), or Oleum (0).
o Tallow fatty acid (34) is not compatible with Group 5, Caustics.
o 1,1, !-Trichloroethane (36) is not compatible with Oleum (0).
o Trichloroethylene (36) is not compatible with Group 5, Caustics.
0 Triethyl phosphite (34) is not compatible with Groups I and 4.
o Trimethyl phosphite (34) is not compatible with Groups I and 4.
Appendix II-Explanation of Figure I

Definition of a hazardous reaction-As a first approximation, a mix-
ture of two cargoes is considered hazardous when, under specified con-
dition, the temperature rise of the mixture exceeds 25"C or a gas is
evolved. It is possible for the reaction of two cargoes to produce a
product that is significantly more flammable or toxic than the original
401
cargoes even though the reaction is non-hazardous from temperature or
pressure considerations, although no examples of such a reaction are
known at this time.
Chart format- There are different degrees of reactivity among the
various cargoes. Many of them are relatively non~reactive: For exam-
ple, aromatic hydrocarbons or paraffins. Others will form hazardous
combinations with many groups: For example, the inorganic acids.
The cargo groups in the compatibility chart are separated into two
categories: I through 22 are "Reactive Groups" and 30 through 43 are
"Cargo Groups". Left unassigned and available for future expansion are
groups 23 through 29 and those past 43. Reactive Groups contain prod-
ucts which are chemically the most reactive; dangerous combinations
may result between members of different Reactive Groups and between
members of Reactive Groups and Cargo Groups. Products assigned to
Cargo Groups, however, are much less reactive; dangerous combina-
tions involving these can be formed only with members of certain Re-
active Groups. Cargo Groups do not react hazardously with one an-
other.
Using the Compatibility Chart- The following procedure explains
how the compatibility chart should be used to find compatibility info-
matico:
(I) Determine the group numbers of the two cargoes by referring

to the alphabetical listing of cargoes and the corresponding groups
(Table I). Many cargoes are listed under their parent names; unless oth-
erwise indicated, isomers or mixtures of isomers of a particular cargo
are assigned to the same group. For example, to find the group number
for Isobutyl Alcohol, look under the parent name Butyl Alcohol. Simi-
larly, the group number for para-Xylene is found under the entry
Xylene. If a cargo cannot be found in this listing, contact the Coast
Guard for a group determination (see 150.140).
(2) If both group numbers are between 30 and 43 inclusive, the
products are compatible and the chart need not be used.
(3) If both group numbers do not fall between 30 and 43 inclusive,
locate one of the numbers on the left of the chart (Cargo Groups) and
the other across the top (Reactive Groups). (Note that if a group
number is between 30 and 43, it can only be found on the left side of
the chart.) The box formed by the intersection of the column and row
containing the two numbers will contain one of the following:
(a) Blank-The two cargoes are compatible.
402
(b) "X"-The two cargoes are not compatible.
(Note that reactivity may vary among the group members. Refer
to Table I or Table II to find whether the products in question are ref-
erenced by a footnote which indicates that exceptions exist and are
listed in Appendix I. Unless the combination is specifically mentioned in
Appendix I, it is compatible.)
Examples
Combination Groups Compatible
Butyraldehyde/ Acetic Acid 19/4 Yes

Allyl Alcohoi/Toluene Diisocyanate 15/12 No
Decene/Ethy1 Benzene 30/32 Yes
Ethanolamine/ Acetone 8/18 Yes
Ammonia/Dimethylformamide 6/10 No
Appendix III-Testing Procedures for Determining Exceptions to the

Chart
Experimental Procedure for Evaluating Binary Chemical Reactivity
General safety precautions-Chemical reactivity tests have, by their
nature, serious potential for injuring the experimenter or destroying
equipment. The experimenter should I) have knowledge of the magni-
tude of the reactivity to be expected, 2) use adequate facilities and pro-
tective equipment to prevent injury from splatter of materials or release
of fumes, and 3) start on a small scale so that unexpected reactions can
be safely contained. All tests should be performed in a well-ventilated
laboratory hood provided with shields.
Testing chemicals other than liquids- The procedure outlined below
was developed for chemicals which are liquids at ambient temperatures.
If one or both chemicals are normally shipped at elevated temperatures,
the same procedure may be followed except the chemicals are tested at
their respective shipping temperatures and the oil bath in Step 3 is
maintained at a level 25'C above the higher temperature. This informa-
tion is then indicated on the data sheet. If one of the chemicals is a gas
at ambient temperatures, consult the Coast Guard for additional instruc-
tions before proceeding with the compatibility test.
Step 1
Objective-To determine if the test chemicals react violently and
present a safety hazard in further tests.
403
Procedure-Place 0.5 ml of one (A) of the test chemicals in a
25 X 150 mm test tube. Clamp the test tube to a stand behind a safety
shield (in a hood). Carefully add from a dropper 0.5 ml of the other
substance (B). Shake to induce mixing. If no immediate reaction occurs,
retain the mixture for at least 10 minutes to check for a delayed reac-
tion.
Results-If a violent reaction occurs, such as sputtering, boiling of
reactants or release of fumes, record the results on the Data Sheet (Ap-
pendix IV) and do not proceed to Step 2. If no reaction or a minor
reaction occurs, proceed to Step 2.
Step 2
Objective-To determine the heat of reaction of two chemicals on
mixing under specified conditions.
Procedure-These separate mixes of the proposed binary combina-
tion will be tested. These are 2 ml : 18 ml, 10 ml : 10 ml, and
18 ml : 2 ml, respectively, to result in a final mixture of about 20 ml in
each case.
A reference-junctioned thermocouple is prepared by inserting two
lengths of 20 gauge or finer iron-constantan or chromelalumel duplex
thermocouple wire into glass capilary sheaths. The common wire of
each probe is joined, while the other wire of each is connected to a
strip-chart recorder. The thermocouple probe which produces a nega-
tive pen deflection upon warming is the reference junction and is
placed in a test tube of water at ambient laboratory temprature. The
other probe is placed near the bottom of a Dewar flask of about 300 ml
capacity, such that the thermocouple will be below the surface of the
test mixture. The Dewar flask is equipped with a magnetic stirrer
having a stirring bar coated with an inert material such as a flourinated
hydrocarbon.
Start the temperature recorder and stirrer. Deliver the test chemi
cals to the Dewar Flask simultaneously from separate graduated sy-
ringes. If an exothermic reaction occurs, continue the test until the
maximum temperature is reached and begins to subside. If no apparent
reaction occurs, continue the test for at least 30 minutes to check for a
delayed reaction. Stop agitation and observe the mixture at five-minute
intervals to determine if the mixture is miscible, if gases are evolved, or
if other visible changes occur. In the interest of safety, a mirror can be
used for these observations. Repeat the above test for the other mixture
combinations.
Results-Record the results in the appropriate places on the Data
Sheet. If no reaction occurs or if the temperature rise is less than 25'C,
404
proceed to Step 3. If the observed temperature rise exceeds 25c or
gases are evolved, do not proceed to Step 3.
Step 3
Objective-To determine if exothermic reactions occur at tempera-
tures up to 50C
Procedure-If a non-hazardous reaction occurred in Step 2, the
ratio of chemicals which resulted in the greatest temperature rise will
be tested. Fresh chemicals will be used with a total volume for this test
of about 10 ml (a ratio of I ml : 9 ml, 5 ml : 5 ml, or 9 ml : I ml). If no
reaction was observed in Step 2, use a ratio of 5 ml : 5 mi. Using the
thermocouple prepared for Step 2, insert the reference probe into a
25 X 150 mm test tube containing 10 ml of water. Place the other probe
into an empty test tube. Start the temperature recorder and add the two
chemicals of the combination, one at a time, to the empty test tube.
Lower the two test tubes into an oil bath maintained at 50rc. Hold
the samples in the oil bath until the maximum temperature differential is
recorded, and in all cases at least 15 minutes. Observe the test mixture
to determine if gases are evolved or if other visible changes occur.
Follow prescribed safety precautions.
Results-Record the maximum differential temperature measured,
the time required to reach this temperature, and any other observations
in the proper space on the Data Sheet.
Send a copy of the Data Sheet for each binary chemical mixture
tested to: Commandant (G-MTH), U.S. Coast Guard, Washington, DC
20593-0001.
405
Appendix IV-Dala Sheet
CHEMICAL REACTIVITY TEST DATA
Chemicals:
Synonyms:
------------------ ------------------
Formula:
Description of Products: A B
Manufacturer
Sample Source
Composition (by weight %)
Inhibitors or Stabilizers
Deviations from Prescribed Method

(Including special equipment)
Step Number 1
Products miscible? ----------------------08888 evolved?-------------------
Olher Observations:
Step Number 2
AlB Ratio: 2118 10/10 1812
Initial Temperature
Maximum .6. T
Time to reach Max. Tamp.
Products miscible?
Gases evolved?
Olhor lll>servallons
Size of Dewar Flask (Inside measurement) Wld1h - - - - - - mm Height - - - - - - mm
406
StepNumbef3
AlB Ratio:
Oil a.th Temperature

Maximum t1. T
nme to reach Max. Temp.

Gases evolved?
Other Observations
Date of Teat
Submitting Organization:
Test Data Approved By:
BILLING CODE 4811>-14-C
407
APPENDIX B
MEDICAL KIT INFORMATION
Cyanide-like cargoes
The kit described below should be readily available for use by a doctor
or other person specially trained in it use when the following cargoes
handled:
Acetone cyanohydrin
Acetonitrile
Acrylonitrile
Adiponitrile
Ethylene cyanohydrin
Methacrylonitrile
Propionitrile
Toluene diisocyanate
Medical Kit
12 pearls of amyl nitrite
I sterile syringe, 10 cc.
I sterile syringe, 50 cc.
2 ampules of sodium nitrite (10 cc., 3% solution)
2 ampules of sodium thiosulfate (50 cc., 25% solution)
Inhalation DO NOT DELAY!
Break an amyl nitrite pearl in a cloth and hold it lightly under the
nose of the victim (but away from the person giving first aid) for about
15 seconds. Repeat five times at about 15 second intervals.
Follow further instructions found with the kit.
408
APPENDIX B
CARCINOGENS
The following is a list of carcinogens, either known or suspected, for

which data are given in this Guide:
Acetaldehyde Dioctyl phthalate

Acrylamide Epichlorohydrin
Acrylonitrile Ethyl acrylate
Allyl chloride Ethylene dibromide
Aniline Ethylene dichloride
Benzene Ethylene oxide
Benzene, Toluene, Xylene Ethyl methacrylate (a teratogen)
Formaldehyde
mixtures
Methyl bromide
Benzyl chloride
Methyl chloride
Butadiene
2-Nitropropane
Carbon tetrachloride
Perchloroethylene
Chlorodifluoromethane beta-Propiolactone
crude Chlorohydrins Propylene oxide
Chloroform Styrene
Coal tar I, I ,2,2-Tetrachloroethane
Coal tar naphtha I, I ,2-Trichloroethane
Cresols 2,4-Toluenediamine
Crotonaldehyde Toluene diisocyanate
I ,4- Dioxane Trichloroethylene
Dichloromethane Vinyl chloride
1,3-Dichloropropene Vinylidene chloride
By analogy to epichlorohydrin.
This list has been compiled from those published hy the Interna-
tional Agency for Research on Cancer (IARC) Supplement 7, the Na.
tiona! Toxicology Program (NTP) Fifth Annual Report on CarcinOfieiiS,
1989, and the American Conference of Governmental Industrial Hy-
gienists (ACGIH) Threshold Limit Values for Chemical Substances and
Physical Agents in the Work Environment, 1989-1990.
409
APPENDIX C
MARPOL 73/78
LIST OF OILS
Asphalt solutions Gas Oil

Blending Stocks Cracked
Roofers Flux Gasoline Blending Stocks
Straight Run Residue Alkylates - fuel
Oils Reformates
Clarified Polymer -fuel
Crude Oil Gasolines
Mixtures containing crude oil Casinghead (natural)
Diesel Oil Automotive
Fuel Oil No.4 Aviation
Fuel Oil No.5 Straight Run
Fuel Oil No.6 Fuel Oil No.I (Kerosene)
Residual Fuel Oil Fuel Oil No.I-D
Road Oil Fuel Oil No.2
Transformer Oil Fuel Oil No.2-D
Aromatic Oil (excluding Jet Fuels
vegetable oil) JP-1 (Kerosene)
Lubricating Oils and Blending JP-3
Stocks JP-4
Mineral Oil JP-5 (Kerosene, Heavy)
Motor Oil Turbo Fuel
Penetrating Oil Kerosene
Spindle Oil Mineral Spirit
Turbine Oil Naphtha
Distlllstes Solvent
Straight Run Petroleum
Flashed Feed Stocks Heartcut Distillate Oil
The list of oils shall not necessarily be considered as comprehensive.
410
Composition of Common Petroleum Products - General Paramo Formula CnH2n+2
Number of Carbon Atoms c, C: c_, c. C! c. c, Ca C Coo Cu Co2 Cn c,. c,, Co C" c .. Co9 C'" Cl
Boiling !"oint of Nonnal c -162 --89 --42 -0.5 +36 69 98 126 lSI 174 196 216 235 253 270 287 302 316 329 343
Paraffin at one atmo:sphere "F -259 -127 --44 +31 97 !56 209 258 303 345 384 421 4S6 488 519 548 575 601 625 649
Liquif!Cd Natural Gas (LNG) 1---i

Liquifled Petroleum Gas (LPG) 1---1
I
Guolw
VMicP Naphtha
e 1---1
Mincnl Spirits
Kerolcnt, Diesel F1tel n

""'00
Wu
l.ullrk:alinl Oil
._ .... I--
I--
~ 901.1' medlme cw ~
APPENDIX D
CONVERSION FACTORS
Metric Units Used In Part 153
Parameter Metric (SI unit)

Abbrevia- Equivalent to English
tion or common metric
FO<ce ................... Newton ........................................ N ................... 0.225 lbs.

Length................. Meter ........................................... m................... 39.37 in.
Centimeter .................................. em................. .3937 in.
Pressure .............. Pascal .......................................... Pa ................. 1.450x1otbs/in2 .
Kilo-Pascal (1,000 Pascals) ...... kPa ............... 0.1451bs/in'.
Kilo-Pascal .................................. kPa ............... 1.02X10" 2 kg/cm 2 .
do ............................................. kPa ............... 1X10' Nim'.
Temperature ....... Degree Celsius ........................... 'C .................. 5/9 ('F-32).
Viscosity .............. milli~Pascal second .................... mPa.sec ....... 1.0 centipoise.
Volume ................ Cubic meter ................................ m' ................. 264 gallons (gal).
do ............................................. m3 ................. 35.3ft3 .
"RULE OF THUMB"
Specific gravity of water:

fresh= 1.00
salt = 1.025 (approx.)
VISCOSITY
Centistokes X density (grams per mi.) = centipoises

Kinematic viscosity X density = absolute viscosity
DENSITY
Pound per gal. (U.S.) at 2oc =specific gravity at 2012oc X 8.32162

Pound per gal. (U.S.)= 0.119 826 grams per mi.
412
APPENDIXD
CONVERSION FACfORS
Miscellaneous Conversion Facton
Given this, multiply by this, to get this.
atmosphere (atm) 760 mm Hg (at O"C)

29.92 in. Hg (at O"C)
33.899 ft H.O (at 4"C)
1.0333 kg!em 2
14.69 lb/in. 2
1.0133 bar
101.3 kPa
bar 0.987 atm

750 mm Hg (at O"C)
14.5 lb/in. 2
100 kPa
barrel (U.S. liq.) (bbl) 26.229 gal (Brit)

31.5 gal (U.S.)
119.237 I
4.2109 ft 3
barrel, petroleum 42 gal (U.S.)
foot, H.O (at 4"C) 0.0295 atm

0.883 in. Hg (at O"C)
2.2419 em Hg (at O"C)
0.4335 lb/in. 2
304.79 kg/m 2
foot 0.02832 m
28.316 I
7.4805 gal (U.S.)
6.2288 gal (Brit)
gallon, U.S. (gal) 0.8327 gal (Brit)

128 oz (U.S. liq.)
8 pt (U.S. 1iq.)
4 qt (U.S. liq.)
413
APPENDIXD
CONVERSION FACI'ORS
Given this, multiply by this, to get this.
gallon, U.S. cont. 3.785

0.1337 ft 3
8.328 lb fresh H.O (fresh
water at 60"F)
8.336 lb fresh H.O (fresh
water at 4"C)
0.0317 bbl (U.S. liq.)
0.0238 bbl (petroleum)
gallon, British 1.2009 gal (U.S.)

4.546 I
160 oz (Brit liq.)
0.16054 ft 3
10 lb H.O (at 60"F)
gallon/minute (U.S.) 8.0208 ft 3 /hr

0.06309 I/sec
gram (g) 0.001 kg

0.0353 oz (avoir.)
0.0022 lb
gram/liter (g/1) I 000 ppm

0.008345 lb/gal (U.S.)
0.0624 lb/ft 3
kilogram/meter 0.07356 mm Hg (at O"C)

(kg/m") 0.00142 lb/in. 2
0.000097 atm
0.20482 lb/ft 2
kilogram/meter 0.06243 lb/ft 3

(kg/m 3 )
kilopascal (kPa) 0.1450377 4 lb/in. 2
liter (I) O.D35 ft 3
414
APPENDIXD
CONVERSION FACI'ORS
Given this, multiply by Ibis, to get Ibis.
liter cont. 0.001 m

0.2642 gal (U.S.)
0.21998 gal (Brit)
1.0567 qt (U.S. liq.)
0.8799 qt (Brit liq.)
liters/min (1/min) 0.035316 ft 3 /min

0.264179 gal (U.S.)/min
meter 3 (m 3 ) 35.315 ft3
264.172 gal (U.S.)

2I9.969 gal (Brit)
1000 I
millimeter Hg 0.001316 atm

(at oq 0.001333 bar
1.3595 g/cm 2
O.OI93 lb/in.
I torr
ounce 28.35 g
(avoirdupois)(oz)
ounce (U.S. liq.) 29.5737 cc

0.0296 I
0.032 qt
ounce (Brit liq.) 28.413 cc
pint (U.S. liq.) 473.176 cc

0.473163
0.5 qt
pound (Ib) 453.5924 g

0.45359 kg
16 oz (avdp)
415
APPENDIXD
CONVERSION FACfORS
Glveu this, multiply by this, to get this.
pound/in. (lb/in. 2 ) 51.715 mm Hg (at O'C)

703.07 kg/m 2
0.068046 atm
0.06895 bar
70.307 glcm
6.894757 kPa
pound/foot (lb/ft 3 ) 0.01602 glee

16.018 kglm 3
quart (liquid) 946.353 cc

0.94633 I
0.25 gal (U.S.)
ton (short) 907.1847 kg

2000 lb (avdp)
0.89286 ton (long)
0.9072 tonne (metric)
ton (long) 1016.047 kg

2240 1b (avdp)
1.12 ton (short)
1.01605 ton (metric)
tonne (metric) 1000 kg

2204.62 lb (avdp)
1.1023 ton (short)
0.98421 ton (long)
torr 0.001316 atm

1.0 mm Hg (at O'C)
416
APPENDIX E
TEMPERATURE CONVERSION TABLE
('C X %) + 32 = 'F ('F - 32) X % = 'C
To convert To COD'Yert To convert

To"F From To"C To"F From To"C To"F From To c
-40.0 -40 -40.0 26.6 -3 -19.4 93.2 34 1.1
-38.2 -39 -39.4 28.4 -2 -18.9 95.0 35 1.7
-36.4 -38 -38.9 30.2 -I -18.3 96.8 36 2.2
-34.6 -37 -38.3 32.0 0 -17.8 98.6 37 2.8
-32.8 -36 -37.8 33.8 I -17.2 100.4 38 3.3
-31.0 -35 -37.2 35.6 2 -16.7 102.2 39 3.9
-29.2 -34 -36.7 37.4 3 -16.1 104.0 40 4.4
-27.4 -33 -36.1 39.2 4 -15.6 105.8 41 5.0
-25.6 -32 -35.6 41.0 5 -15.0 107.6 42 5.6
-23.8 -31 -35.0 42.8 6 -14.4 109.4 43 6.1
-22.0 -30 -34.4 44.6 7 -13.9 111.2 44 6.7
-20.2 -29 -33.9 46.4 8 -13.3 113.0 45 7.2
-18.4 -28 -33.3 48.2 9 -12.8 114.8 46 7.8
-16.6 -27 -32.8 50.0 10 -12.2 116.6 47 8.3
-14.8 -26 -32.2 51.8 II -11.7 118.4 48 8.9
-13.0 -25 -31.7 53.6 12 -11.1 120.2 49 9.4
-11.2 -24 -31.1 55.4 13 -10.6 122.0 so 10.0
-9.4 -23 -30.6 57.2 14 -10.0 123.8 51 10.6
-7.6 -22 -30.0 59.0 15 -9.4 125.6 52 11.1
-5.8 -21 -29.4 60.8 16 -8.9 127.4 53 11.7
-4.0 -20 -28.9 62.6 17 -8.3 129.2 54 12.2
-2.2 -19 -28.3 64.4 18 -7.8 131.0 55 12.8
-0.4 -18 -27.8 66.2 19 -7.2 132.8 56 13.3
1.4 -17 -27.2 68.0 20 -6.7 134.6 57 13.9
3.2 -16 -26.7 69.8 21 -6.1 136.4 58 14.4
5.0 -15 -26.1 71.6 22 -5.6 138.2 59 15.0
6.8 -14 -25.6 73.4 23 -5.0 140.0 60 15.6
8.6 -13 -25.0 75.2 24 -4.4 141.8 61 16.1
10.4 -12 -24.4 77.0 25 -3.9 143.6 62 16.7
12.2 -II -23.9 78.8 26 -3.3 145.4 63 17.2
14.0 -10 -23.3 80.6 27 -2.8 147.2 64 17.8
15.8 -9 -22.8 82.4 28 -2.2 149.0 65 18.3
17.6 -8 -22.2 84.2 29 -1.7 150.8 66 18.9
19.4 -7 -21.7 86.0 30 -1.1 152.6 67 19.4
21.2 -6 -21.1 87.8 31 -0.6 154.4 68 20.0
23.0 -5 -20.6 89.6 32 0.0 156.2 69 20.6
24.8 -4 -20.0 91.4 33 0.6 158.0 70 21.1
417
APPENDIXE
("C X %) + 32 = "F ("F - 32) X % = "C
To coaert To c:onYert To convert

To p From To"C To p From To c To oF From To oc
159.8 71 21.7 226.4 108 42.2 293.0 145 62.8
161.6 72 22.2 228.2 109 42.8 294.8 146 63.3
163.4 73 22.8 230.0 110 43.3 296.6 147 63.9
165.2 14 23.3 231.8 111 43.9 298.4 148 64.4
167.0 15 23.9 233.6 112 44.4 300.2 149 65.0
168.8 76 24.4 235.4 113 45.0 302.0 150 65.6
170.6 77 25.0 237.2 114 45.6 303.8 151 66.1
172.4 78 25.6 239.0 115 46.1 305.6 152 66.7
174.2 79 26.1 240.8 116 46.7 307.4 153 67.2
176.0 80 26.7 242.6 117 47.2 309.2 154 67.8
177.8 81 27.2 244.4 118 47.8 311.0 155 68.3
179.6 82 27.8 246.2 119 48.3 312.8 156 68.9
181.4 83 28.3 248.0 120 48.9 314.6 157 69.4
183.2 84 28.9 249.8 121 49.4 316.4 158 70.0
185.0 85 29.4 251.6 122 50.0 318.2 159 70.6
186.8 86 30.0 253.4 123 50.6 320.0 160 71.1
188.6 87 30.6 255.2 124 51.1 321.8 161 71.7
190.4 88 31.1 257.0 125 51.7 323.6 162 72.2
192.2 89 31.7 258.8 126 52.2 325.4 163 72.8
194.0 90 32.2 260.6 127 52.8 327.2 164 73.3
195.8 91 32.8 262.4 128 53.3 329.0 165 73.9
197.6 92 33.3 264.2 129 53.9 330.8 166 74.4
199.4 93 33.9 266.0 130 54.4 332.6 167 75.0
201.2 94 34.4 267.8 131 55.0 334.4 168 75.6
203.0 95 35.0 269.6 132 55.6 336.2 169 76.1
204.8 96 35.6 271.4 133 56.1 338.0 170 76.7
206.6 97 36.1 273.2 134 56.7 339.8 171 77.2
208.4 98 36.7 275.0 135 57.2 341.6 172 77.8
210.2 99 37.2 276.8 136 57.8 343.4 173 78.3
212.0 100 37.8 278.6 137 58.3 345.2 174 78.9
213.8 101 38.3 280.4 138 58.9 347.0 175 79.4
215.6 102 38.9 282.2 139 59.4 348.8 176 80.0
217.4 103 39.4 284.0 140 60.0 350.6 177 80.6
219.2 104 40.0 285.8 141 60.6 352.4 178 81.1
221.0 105 40.6 287.6 142 61.1 354.2 179 81.7
222.8 106 41.1 289.4 143 61.7 356.0 180 82.2
224.6 107 41.7 291.2 144 62.2 357.8 181 82.8
418
APPENDIXE
('C X %) + 32 = 'F ('F - 32) X % = 'C
To convert To convert To convert

To 'F From To c To'F From To c To'F From To c
359.6 182 83.3 410.0 210 98.9 460.4 238 114.4
361.4 183 83.9 411.8 211 99.4 462.2 239 115.0
363.2 184 84.4 413.6 212 100.0 464.0 240 115.6
365.0 185 85.0 415.4 213 100.6 465.8 241 116.1
366.8 186 85.6 417.2 214 101.1 467.6 242 116.7
368.6 187 86.1 419.0 215 101.7 469.4 243 117.2
370.4 188 86.7 420.8 216 102.2 471.2 244 117.8
372.2 189 87.2 422.6 217 102.8 473.0 245 118.3
374.0 190 87.8 424.4 218 103.3 474.8 246 118.9
476.6 247 119.4
375.8 191 88.3 426.2 219 103.9
478.4 248 120.0
377.6 192 88.9 428.0 220 104.4
480.2 249 120.6
379.4 193 89.4 429.8 221 105.0
482.0 250 121.1
381.2 194 90.0 431.6 222 105.6
483.8 251 121.7
383.0 195 90.6 433.4 223 106.1
485.6 252 122.2
384.8 196 91.1 435.2 224 106.7 122.8
487.4 253
386.6 197 91.7 437.0 225 107.2 489.2 254 123.3
388.4 198 92.2 438.8 226 107.8 491.0 255 123.9
390.2 199 92.8 440.6 227 108.3 492.8 256 124.4
392.0 200 93.3 442.4 228 108.9 494.6 257 125.0
393.8 201 93.9 444.2 229 109.4 496.4 258 125.6
395.6 202 94.4 446.0 230 110.0 498.2 259 126.1
397.4 203 95.0 447.8 231 110.6 500.0 260 126.7
399.2 204 95.6 449.6 232 111.1 501.8 261 127.2
401.0 205 96.1 451.4 233 111.7 503.6 262 127.8
402.8 206 96.7 453.2 234 112.2 505.4 263 128.3
404.6 207 97.2 455.0 235 112.8 507.2 264 128.9
406.4 208 97.8 456.8 236 113.3 509.0 265 129.4
408.2 209 98.3 458.6 237 113.9
t< U.S. GOVERNMENT PRINTING OFFICE: 1981-299-483
419

Chemical Data Guide Book

Hochgeladen von

Dokumentinformationen

Copyright

Verfügbare Formate

Dieses Dokument teilen

Dokument teilen oder einbetten

Freigabeoptionen

Stufen Sie dieses Dokument als nützlich ein?

Sind diese Inhalte unangemessen?

Copyright:

Verfügbare Formate

Chemical Data Guide Book

Hochgeladen von

Copyright:

Verfügbare Formate

U.S.

Chemical Data Guide

Subj: Chemical Data Guide for Bulk Shipment By Water

1. PURPOSE. This manual has been prepared to assist Coast

2. DIRECTIVES AFFECTED. The Chemical Data Guide for Bulk

3. CHANGE. Recommendations, comments, additional data and

DISn..lllmON SDL No. 12 9

For sale by the Superintendent of Documentll, U.S. Govemment Printing Office

Commandant Instruction MI6616.6A ................................................. .

A. Compatibility Information, 46 CFR !50-Subpart A......... 360

The U.S. Coast Guard is vitally concerned with safety at sea. In

The % by weight will be given when the solubility is of particu-

In case of a large-scale chemical fire aboard a vessel, it is proba

Flammable liquids having specific gravities greater than that of

Generally, foam is a good extinguishing agent for fires in flam-

Chemicals that cause a slight smarting of the eyes or respiratory

4 Severely hazardous chemicals usually having threshold limits

The values listed are those assigned by the Occupational Safety

The equilibrium concentration of a gas which can be produced

cone. (ppm) = vapor pressure in mm Hg X 1300.

The Chemical Hazards Response Information System (CHRIS) is

Continuously manned Communications Center.

Contact points with other Government Agencies for access to

Formula-Simplified structural formula

Vapor Pressure 20"C (68"F) (mmHg) ..

FIRE & EXPLOSION HAZARD DATA

Flash Point CFJ .. Open cup unless otherwise noted.

HEALTH HAZARD DATA

SPILL OR LEAK PROCEDURE

If 1plll oceuu, WI the Nati011al RtsponM Center, 100-424-8802.

Appearance-Odor-Colorless hqu1d; pungent suffocat1ng

odor; lru1ty odor when diluted.

Vapor Pressure 200C (68'F) (mmHgJ. _I&_

FIRE & EXPLOSION HAZARD DATA

HEALTH HAZARD DATA

Compatibility-Material: Negligible corros1on to m1ld steel May d1ssolve rubber.

Cargo: Group 1g of compallbill\y chart.

SPILL OR LEAK PROCEDURE

If a spill occun, call the National Response Center, 800-424-8802.

CHRIS Code ...

Vapor Preuure lO'C (68'F) (mmHI) .. ___l1.L

f1RE 4 EXPLOSION HAZARD DATA

Flull PtNDt ('FJ .. 110

HEALTH HAZARD DATA

Short EJ:ponre Toleraaee--40 ppm lor 5 minutes.

SPILL OR LEAK PROCEDURE

FIRE It EXPLOSION HAZARD DATA

Flub Point ('F) .. 121 (CC)

HEALm HAZARD DATA

Sbort bp~M~w-e Toleruee-Less than 40 ppm for 5 minutes.

Carte: Group 11 of compatibility chart.

SPILL OR LEAK PROCEDURE

FIRE .t EXPLOSION HAZARD DATA

Flub Point ('FJ .. 15

HEALTH HAZARD DATA

CompatlbUity-Materlal: Will dissolve many plastics and rubber.

SPILL OR LEAK PROCEDURE

If a 1pill ocam, call tlae National R~ Center,I00-4:z 111102.

Appear ... ~or-Cotorless to straw colored liquid;

Vapor Pressure 20'C (68'FJ (mmHg). ____Q.L_

FIRE & EXPWSION HAZARD DATA

Flub Point (" FJ . 165 (cc)

HEALTH HAZARD DATA

Symptom-Headache, dizziness, nausea; blueness of lips and fingernails.