Beruflich Dokumente
Kultur Dokumente
HALOGENS
Many Standards
Standard Application Requirement Test Description
MIL-DTL-24643C Cables, Electric, Low Smoke Halogen-Free, For Shipboard All materials shall be halogen-free and have no more halogen content of cable jacket or fillers shall be determined byXRF or analytically following
(1 October 2009) Use than 0.2 % halogen content. an inspection and analyses of the chemical composition of all ingredients
General used.
Halogen-Free
ICEA T-33-655-1994 Guide for Low Smoke, Halogen-Free Polymeric Cable ..materials having less than 0.2% weight of any halogen halogen content of the cable jacket or fillers shall be determined XRF or analytically
Jackets following an inspection and analyses of the chemical composition of all ingredients
used.
UL 44, Clause 5.14.8.4 Standard For Safety For Thermoset-Insulated Wires and 20% by weight of halogen acid gas Halogen Acid Gas Emission
Cables
TUV Pfg 1169/08.2007 Cables for use in photovoltaic-systems Qualitative F, Cl, & Br Qualitative Colormetric Test.
Halogen-free PV Cable Tests on Gases evolved During Combustion of Materials from Cables Part 1 Apparatus &
Determination of the degree of acidity of gases for materials by measuring pH and
Annex B (Test of absence of halogen) indicates conductivity
Insulation and Sheath shall pass the requirement as
follows Determination of the amount of halogen gas (not suitable for zero-halogen determination,
see below)
Low Smoke
Determined by IEC 61034-2 test method
PVC Fallout (Phthalates - plasticizers, Lead & Cadmium heat stabilizer or colorant)
Green Movement /LEED Green Building Initiative & Precautionary Principle (Its bad in
one area so ban it in all areas)
Why is LSHF Important?
Some industry claims:
Halogenated materials, when ignited generate smoke that can be corrosive with the potential to
damage electronics.
Applications where corrosion potential is of particular concern include communications
data centers, Emergency call centers, phone switching stations, etc.
Cables containing halogens also produce significantly higher levels of carbon monoxide (CO) gas
during combustion.
What's a Halogen?
Halogens impart are used to improve flame retardant properties of polymeric materials used in wire & cable.
Fluorine
Chlorine
Bromine
Iodine
Astatine
Primary Halogen Sources in Polymeric Materials
Resins (e.g. PVC, FEP, CPE)
Additives
Flame Retardants (e.g. brominated compounds)
Mineral fillers (e.g. fluorine in silica/glass)
Color Concentrates
Common Flame Retardants used in Non-Hal Applications
Metal Hydroxides
Aluminum TriHydrate (ATH)
Magnesium Hydroxide
Others
Polyesters
Polyamides (e.g. Nylon)
Polystyrene (Not used in W&C)
Polycarbonate (Not used in W&C)
Etc.
New Industry Standards
UL 2885, Standard for acid gas, acidity and conductivity of combusted material
and assessment of Halogens dated 02-12-2015. (Based on IEC 62821-1, -2 &
-3;
IEC 62821-1; Electric Cables Halogen Free, Low Smoke Thermoplastic-
Insulated and Sheathed Cables of Rated Voltages up to and Including
450/750V Part 1: General Requirements
IEC 62821-2; Electric Cables Halogen Free, Low Smoke Thermoplastic-
Insulated and Sheathed Cables of Rated Voltages up to and Including
450/750V Part 2: Test Methods
IEC 62821-3; Electric Cables Halogen Free, Low Smoke Thermoplastic-
Insulated and Sheathed Cables of Rated Voltages up to and Including
450/750V Part 3: Flexible Cables (Cords)
UL 2885 Halogen Free (HF)
Four step test protocol to determined HF content for cable components,
i.e. insulation, fillers, jacket, tapes, etc.:
ULs new optional -LSHF or -HF cable mark applicable for all Listed and Recognized cables.
Type OFNR-LSHF, CMR-LSHF, etc.
Questions?
Thank You!!