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Example lV
A1:oordlinig; io tno flFiG., `E5 sn :am ili is aa. smile ]_:>;r<:>pyinne
:str =--an1 Whicil comosponds to the: oomloilnation of tile
L3 prodinct. the C2 sa'tllialics, and tlio C3 saiitraies as (as
:sliow'n in collnnns ii.. l.. and .'I in 'iaole 2f). This iepr :senis ino
yieiil and oonnposinon. of tile @indio puropylczno purodlilci.. The
Carlisle propy'ienc: produoi oompiiss about 95 voi-9&5 _piopy
lleno ami may oe ns sil Without; adiiitiionai _processing :as
chemical girado piopqyjlello.
Example v
As shown :in Enafnple l. tile Cf pnodlnei stream (oolutrnn.
l.. oi Tabis: 221i) has tine iiilowing; 1:omposition:
Aooortli~1ag io tho lFlGr.. Iii.. iilis is tine oomqposiiion. oi nireain
1:5555 Wilicli is passed. 11o ihr: buien@y separation zone 122,22', io
provid e a buneno--i slieann 174 havin g; a purity o :aiaont 9i)
wt-#525.
Eixample: 'Vi
ilrthnr to Example 1'.. i111: pioqgiylcine sircnan in 'iaille 2
(cciuinn Il) will prodnlo : aivoni 445.8 isiliigg/hr of diisinpiiopy
letnor (lliiii) when passe-,il 'to line histy etnoriiication none
:Iliill as silown in ihr: FiG. 31.
Wie: claim:
l.. .A proc :ss foi tno prodnciion of ligjnt oioiins irom a.
hyilroeaihon gas foedstnzanl. conngxrisill1g; ineiinme and.
etliiane. said _process compi . ing:
a) passing said fosilstroam in 1:1omininaiion with a Water
sli :ann io a :syrlgiais production nono to prodilc a a
syintlnsxsis gas stnscam and lnassing; sain synihosis pas
stream to a carbon oxido oollvfzrsion :zzone io 1::nndu o: a
omdle oxygonati: siroarn oonnplisixlgl liisihanoi, dim
othyl oi'her and insel oil;
h) passing at, loasi .a jpoiiion of tile milde: oxygislnato siroain
in` tile pieseno: oi' a, iiiluioint to an oleiin pirod~ootion :Lone
ooniaiming; a sinali poro non-vzzzoolitin catalyst inaving a
poire sim: iozs.: 1 tiian about :El Angsnroms to proiluoe: a ligirt 15.5i
ola-:iin slr :am consisting; osscntizaily of iight oioins
having S2: 11o 4 cannon atoms per inloiooillr: andi Watelz,
fi? ,'7 i 4,1562
112:10
o) pag.1 " ng :said ligirt olleiin slieann to n :so rraiion :Lone to
purowide a oonnixilnil liglnt oleiin stream ooinlnisinig;
ot'hjyilene, lnrolnylono , :mil lnvinylonc: andi `a waaier
lay-product stieain and. netnilluing; al: least a _poition oi
saidl simio; ihy--prmi~ilct snreann to [Movido said 'wanen
str :am and :ai least za portion of said iliinoni.
.il Tile process of ciainn 'i wheiein said small pore
a
11on--Izzooliiic catalyst oomqnriso: 1 inetxal alunninopllospinato
molecular sievo lizaving :an einpinioal ohenaical composition
on an anhydrous 'hass ozsiplfiesisifil by tile ioilowinig; iioxnmia:
Wineroin iiiJ is z 1 :mieial sciootodl :from tine gionp oansistiing of
silica , inagnesiunn, zinc, iron, oohnit, iniclnl, inanqggan ase,
ciiromiluim Iand lnixiures ihereoi, x is ine mole " orion oi El..
and is al; 1 asi 0.10015, jy is tile inoie inaction of Al :und is at
ioasi (lili. zz; is tho mole ii'aetion oi i anni is at: least 0.01 and.
:ai-yi# - _
il'. Tho piooi `s oi' claim. 2L Wilerlizin sailjl inctxa'l aluutnino--
phospilate:` moleelnlar sieno crctrniprisiss a SAJEO strllotlire.
4. The: process of olainn 135 Whiein saiuil JEMJPGI stiulciilne:
oolnprisos a EhiiOl- 4- :snmoi'urol
El. This pro lainn 155 Whorein sain JELSLP'II) snnncinne
oolnpl?isos. a SAiCll--Il i :stiuciure
o. The proooss Iof claim. i Wlneroin saiirl cannon oxidle
o(inversion :zone conxpiisos a lnetlianoi piani..
'7. This piocnss of claim i wliomin :said omrle oxygenaie
siroam, oonnplises Water.
IEL A. process ior the: prminoiion oi llghi oioifn from a
Ihjy'rlrocaihon gaas i'ooilstieain ooinlttising; :rnoihane and
etliane, sind process oo[uprising:
a) pnssilng; :said ieotlstroam in i:omihination wiih a 'Wailea
sli :am to a syngaas production. no ne -to lgtrocluo: a
synthosi`~s gaas : , oinpiisingg hydrogen `andi .a oarhlon
35
oixidio and. passing; said synthesis gas s n1 io a inetlia
no1 piani to produce a, smile inetiianoi s'troam compris
ing nnii'hanol,y light; ends, Wahn?, :and :hasni . ; and
h) passing; saiil crlnio mothanol. Siloam. in Itho prosonce of
a rliiilent 'to an oxygorlato i::inversion :sono containing a,
401
SAiO :analyst: soiooted. from 1in: group oonsisiing of
Eiiifi--Eifi- `andi SALPtO-Ilf to pionlncf: a. ligin: oleiin prod
ilct; cornpii~sillg iiily'ieno.. lnnnpjfiene,` lniltylcno, anni
watci;
c) :sopanaiing said. liglii oloiin producir io lriovido :a
by--pliodnot w.' , e. ' .,tlealn, .an etiiylolne prodnot, a pro
py'ione pronunci, andi a 'huiylene pica'luci; and.
di) roinlzninig; at haast: a poliioin of :said lly"--}a1n:~jll11:i Water
s'trlizann. to said s'yngggas prodiletilon :sone io provide: a
portion oi said wanen stream and at le: stl a portion of
said. dilueni.
i. A proc ior tine prodno'tion oi .liigiit oleiins `?onn a
inyilnooar'bon gas ieedsneanr comprising; :motliane and
etlnane, said proc SSS czolnpiising
a) passin g saldi foerlstr :am >in oomioimaiion with. a irsi
waaier siroaurn, io .a sjylnggas pimiunotiion :sono io prodnioo a
syinnihosis gas stream and. passillil said synliiosis gas
suream io an cnryiggenaie ionnniion :sono` 'to puronlnce `an
oixy'gonato pi'oiluci 1 main oonlpiising; `all ioasi one: of
150' inetiianoi or diinoiln'yl, etnia;
h) _passiut at isasi a lgnoiion of tlio mrjy'geniaie piodlnot:
:sireann in tno presence: of a dilute-nt io an oioifn 'pnodno
iion :Lorne: eoniaiiiing `a SALEN() oatnaijyst. selnoteii ir
having, i! 11o 4 eanbon atoms per :molecu~io and a. sooondl
wanna sinziaunr.,