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Silica, quartz
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Class D2A
What are the most important things to know about silica in an emergency?
Emergency Overview: Colourless crystals. Odourless. Will not burn. VERY TOXIC. Prolonged or repeated exposure causes damage to
lungs. CANCER HAZARD. May cause cancer, if inhaled.
Skin Contact: Quickly and gently blot or brush away excess chemical. Wash gently and thoroughly with lukewarm, gently flowing water and
non-abrasive soap for 5 minutes.
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Eye Contact: Quickly and gently blot or brush chemical off the face. Immediately flush the contaminated eye(s) with lukewarm, gently flowing
water for 5 minutes, while holding the eyelid(s) open. If irritation or pain persists, see a doctor.
Ingestion: Have victim rinse mouth with water. Call a Poison Centre or doctor if the victim feels unwell.
First Aid Comments: If exposed or concerned, see a doctor for medical advice. All first aid procedures should be periodically reviewed by a
doctor familiar with the chemical and its conditions of use in the workplace.
Note to Physicians: Some jurisdictions specifically regulate an ingredient of this product and require a complete medical surveillance
program. Specific information should be sought from the appropriate government agency in your jurisdiction.
Suitable Extinguishing Media: Not combustible. Use extinguishing agent suitable for surrounding fire.
Specific Hazards Arising from the Chemical: None known. Not known to generate any hazardous decomposition products in a fire.
Methods for Containment and Clean-up: Avoid dry sweeping. If necessary, use a dust suppressant such as water. Do not use compressed
air for clean-up. Collect using shovel/scoop or approved HEPA vacuum and place in a suitable container for disposal.
What handling and storage practices should be used when working with silica?
Handling: Before handling, it is important that all engineering controls are operating and that protective equipment requirements and personal
hygiene measures are being followed. Only trained personnel should work with this product. Immediately report leaks, spills or failures of the
safety equipment (e.g. ventilation system). Avoid generating dusts. Prevent accidental contact with incompatible chemicals.
Storage: Keep amount in storage to a minimum. Empty containers may contain hazardous residue. Store separately. Keep closed. Store in
an area that is: separate from incompatible materials.
Exposure Guideline Comments: TLV = Threshold Limit Value. TWA = Time-Weighted Average. A2 = Suspected human carcinogen.
What Personal Protective Equipment (PPE) is needed when working with silica?
Eye/Face Protection: Safety goggles suitable for dust protection.
Respiratory Protection:
Up to 0.5 mg/m3:
(APF = 10) Any particulate respirator equipped with an N95, R95, or P95 filter (including N95, R95, and P95 filtering facepieces) except
quarter-mask respirators. The following filters may also be used: N99, R99, P99, N100, R100, P100.
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APF = Assigned Protection Factor
Recommendations apply only to National Institute for Occupational Safety and Health (NIOSH) approved respirators. Refer to the NIOSH
Pocket Guide to Chemical Hazards (https://www.cdc.gov/niosh/npg/default.html) for more information.
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Date modified:
2017-06-29
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