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Example
Solution:
a) Finding AF:
a = 3.5
Thus,
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MECH 330: APPLIED THERMODYNAMICS II LECTURE 32
Mair
AF = AF
Mfuel
28.97
= (19.99 )
30.07
kg air
= 19.26
kg fuel
pv = y v ptotal
3mol
= 100kPa
(2 + 3 + 0.7 + 15.79)mol
CO2 H2O O2 N2
3
= (100)
21.94
= 13.96kPa
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MECH 330: APPLIED THERMODYNAMICS II LECTURE 32
Combustion Products
Depend upon:
Temperature
Pressure
Mixing
% Theoretical air
Example
Text Problem 13.6
b) AF and AF
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MECH 330: APPLIED THERMODYNAMICS II LECTURE 32
Solution:
H: 2.8 = 2 = 1.4
Thus,
Balancing Os:
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MECH 330: APPLIED THERMODYNAMICS II LECTURE 32
Thus,
1.74(1 + 3.76)
AF =
1
kmol air
= 8.25
kmol fuel
MCH4 MCO MO2 M N2
Mair
AF = AF
Mfuel
28.97
= 8.25
19.831
kg air
= 12.05
kg fuel
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MECH 330: APPLIED THERMODYNAMICS II LECTURE 32
Pref = 1 atm
Enthalpy of Formation hf
C CO2
Tref, Pref Tref, Pref
O2
Qcv
332
MECH 330: APPLIED THERMODYNAMICS II LECTURE 32
On a molar basis:
QCV n nO
hCO2 = + C hC + 2 hO2
nCO2 nCO2 nCO2
QCV
= + hC + hO2
nCO2
0 0
C and O2 are stable elements at the standard
state. Thus, hC = hO2 = 0
Therefore,
-393,520 kJ/kmol of CO2 formed
Q (the value in table A25)
hCO2 = CV
nCO2
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MECH 330: APPLIED THERMODYNAMICS II LECTURE 32
(
h (T , p ) = hf + h (T , p ) h (Tref , pref ) )
OR Table A25
h (T , p ) = hf + h A23 or A2/A3
for example
CaHb at Tf
Air at Ta Combustion
products at Tf
Wcv
b b b
Ca Hb + a + (O2 + 3.76N2 ) aCO2 + H2O + a + 3.76N2
4 2 4
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MECH 330: APPLIED THERMODYNAMICS II LECTURE 32
QCV WCV b b
= ahCO2 + hH2O + a + 3.76hN2
nf nf 2 4
b b
hf a+ hO2 + a + 3.76hN2
4 4
i.e.
QCV WCV
= hproducts hreactants
nf nf
= hp hr
h = hf + h (Tp ) h (Tr e f )
h = hf + h (Ta ) h (Tr e f )
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MECH 330: APPLIED THERMODYNAMICS II LECTURE 32
QCV WCV b
nf
nf
(
= a hf + h
CO2 2
) hf + h+
H 2O
( )
0
b
+ a+
4
3.76 hf + h
N2
( hf + h ) ( ) f
b 0
a+
4
(
hf + h
O2
)
0
b
+ a+
4
3.76 hf + h
N2
( )
Or more simply:
QCV WCV
nf
nf
=
P
(
ne hf + h ) e
R
(
ni hf + h ) i
336