Beruflich Dokumente
Kultur Dokumente
This section contains 30 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONLY ONE is correct.
31. Which of the following compounds is a weaker acid as compared to benzoic acid?
Cl NO2
(1) (2)
COOH COOH
CH3 SO3H
(3) (4)
COOH COOH
NO2 CN CH3
(1) (2) (3) (4)
Arrange these compounds in decreasing order of their basicity:
(1) 1 > 2 > 3 > 4 (2) 2 > 3 > 1 > 4
(3) 4 > 1 > 3 > 2 (4) 4 > 1 > 2 > 3
CENTERS : MUMBAI /DELHI /AKOLA /LUCKNOW / NASHIK /PUNE /NAGPUR / BOKARO /DUBAI # 11
PART AITS - 2 CHEMISTRY (MAIN)
(1) (2)
H OH H OH
CH3 OH
CH3 OH
H OH CH3
H
(3) (4)
H OH
H CH3
CH3
OH
34. The major product expected from the monobromination of phenyl benzoate is
Br Br
(3) (4)
CENTERS : MUMBAI /DELHI /AKOLA /LUCKNOW / NASHIK /PUNE /NAGPUR / BOKARO /DUBAI # 12
PART AITS - 2 CHEMISTRY (MAIN)
36. An aromatic compound A(C7H8O) gives following tests with the given reagents
Na metal
Positive
FeCl3 (neutral)
A(C7H8O) Negative
Lucas reagent
Positive
Anhydrous
Identify 'A' ZnCl /HCl
CH2 OH OCH3
(1) (2)
OH OH
CH3
(3) (4)
CH3
CENTERS : MUMBAI /DELHI /AKOLA /LUCKNOW / NASHIK /PUNE /NAGPUR / BOKARO /DUBAI # 13
PART AITS - 2 CHEMISTRY (MAIN)
38. In the Cannizzaro reaction, the intermediate that will be the best hydride donor is
H H
O
C C
O O
(1) (2) O
CH3O
H H
O O
C C
OH O
(3) (4)
O2N
CENTERS : MUMBAI /DELHI /AKOLA /LUCKNOW / NASHIK /PUNE /NAGPUR / BOKARO /DUBAI # 14
PART AITS - 2 CHEMISTRY (MAIN)
Ph
The structure of product is
I Cl
(1) H Ph (2) H Ph
EtO H I H
Ph Ph
I Cl
(3) Ph H (4) H Ph
EtO H H I
Ph Ph
COOH CH2COOH
(1) CH2 (2)
COOH CH2COOH
CH2COOH
CH2COOH CH2
(3) CH2 (4)
CH2
CH2COOH CH2COOH
CENTERS : MUMBAI /DELHI /AKOLA /LUCKNOW / NASHIK /PUNE /NAGPUR / BOKARO /DUBAI # 15
PART AITS - 2 CHEMISTRY (MAIN)
H D
H H D D
42. Rate of electrophilic aromatic substitution in case of and is same for which
H H D D
H D
of the following reactions?
(1) Sulphonation (2) Iodination
(3) Friedal Crafts ethylation (4) All of these
OsO
4 ( A)
OH OH
OH H
(1) (2) OH
H
OH OH
H H
(3) H (4) H
OH H
CENTERS : MUMBAI /DELHI /AKOLA /LUCKNOW / NASHIK /PUNE /NAGPUR / BOKARO /DUBAI # 16
PART AITS - 2 CHEMISTRY (MAIN)
CH3 N2 CH2
H3C CH2
LiAlH4
(A). A is
46. H3C O (Major product)
CH3
(3) CH3COH (4) No reaction
CH3
47. The rate law for the following intramolecular Cannizzaro reaction will be
O O OH O
Ph C C H OH
Ph CH C O
O O O O
2
(1) rate = k[PhCCH] [OH ] (2) rate = k[PhCCH]2[OH]
O O O O
(3) rate = k[PhCCH][OH ] (4) rate = k[PhCCH]2 [OH]2
CENTERS : MUMBAI /DELHI /AKOLA /LUCKNOW / NASHIK /PUNE /NAGPUR / BOKARO /DUBAI # 17
PART AITS - 2 CHEMISTRY (MAIN)
(1) (2)
CH(OCH3)2 CH(OH)2
OH
(3) (4)
CHO CHO
CENTERS : MUMBAI /DELHI /AKOLA /LUCKNOW / NASHIK /PUNE /NAGPUR / BOKARO /DUBAI # 18
PART AITS - 2 CHEMISTRY (MAIN)
Ph ..
50. C=N on treatment with acid followed by hydrolysis yields
CH3 OH
O O
NH2 COH
(1) CH3COH and (2) and CH3CH2NH2
O
O
CH2NH2 CH2COH and CH3NH2
(3) and HCOH (4)
51.
HI (2 equiv.)
O CH3 one of the product observed is
heat
OH
(1) (2) HO CH3
OH
I
(3) (4) I
CENTERS : MUMBAI /DELHI /AKOLA /LUCKNOW / NASHIK /PUNE /NAGPUR / BOKARO /DUBAI # 19
PART AITS - 2 CHEMISTRY (MAIN)
53. Phenol gives 2,4,6-tribromophenol when treated with bromine in aqueous solution but only o and
pbromophenol in CCl4 solution because
(1) in aqueous solution, phenol exists in equilibrium with phenoxide ion, which has more activating
effect.
(2) in CCl4 solution, phenol exists in equilibrium with phenoxide ion which has more activating
effect.
(3) in CCl4, the electrophilicity of Br2 increases.
(4) in CCl4, the other positions of benzene rings are blocked by the solvent.
54. A compound (A) has molecular formula C2Cl3OH. It reduces Fehlings solution and on oxidation
gives a monocarboxylic acid (B). (A) is obtained by action of Cl2 on ethyl alcohol. (A) is:
(1) Chloral (2) Chloroform
(3) Westrosol (4) Chloro acetic acid
CENTERS : MUMBAI /DELHI /AKOLA /LUCKNOW / NASHIK /PUNE /NAGPUR / BOKARO /DUBAI # 20
PART AITS - 2 CHEMISTRY (MAIN)
R
HCN NH3 Hydrolysis
55. C=O (A) (B) (C)
R
Compound (C) in the above reaction is:
(1) hydroxy acid (2) amino acid
(3) amino alkanol (4) amino hydroxy acid
57. An unsaturated hydrocarbon on ozonolysis gives one mole each of formaldehyde, acetaldehyde and
methylglyoxal. The structure of hydrocarbon is
(1) CH2 = CHCH=CHCH3 (2) CH3CH = CHCH = CHCH3
(3) CH2 = CHC(CH3)=CHCH3 (4) CH2 = C(CH3)C(CH3) = CHCH3
60. Ammonia gas evolved on treatment of 0.30 g of an organic compound for the estimation of nitrogen
was passed in 100 mL of 0.1 M sulphuric acid. The excess of acid required 20 mL of 0.5 M sodium
hydroxide solution for complete neutralization. The organic compound is
(1) thiourea (2) benzamide (3) urea (4) acetamide
CENTERS : MUMBAI /DELHI /AKOLA /LUCKNOW / NASHIK /PUNE /NAGPUR / BOKARO /DUBAI # 21