Safety data sheet in accordance with 2001/58/EC

Appretan N9211 liq Page 1

Substance key: SXR076300 Revision Date: 17.07.2006

Version : 2 - 4 / EU Date of printing : 18.07.2006

1. Identification of the substance/preparation and company

Trade name
Appretan N9211 liq
Material number: 110864
Use of the substance/preparation.
Industry sector : Textile processing industry
Type of use : Textile finishing
Identification of the company
CLARIANT (France)

70, avenue du Gnral de Gaulle

92058 PARIS LA DEFENSE CEDEX
Telephone no. : +33 1 4696 9600
Information about the substance/preparation
Product Safety Dpt.
tel.: +33 1 46 96 97 82
Emergency telephone number : +33 1 45 42 59 59

2. Composition/information on ingredients
Chemical characterization
Dispersion of an acrylic copolymer

3. Hazards identification
Does not require a hazard warning label, but the normal safety precautions for handling
chemicals must be observed.

4. First aid measures

General information
Remove soiled or soaked clothing immediately
After inhalation
When inhaled remove to fresh air and seek medical aid.
After contact with skin
In case of contact with skin wash off with water.
After contact with eyes
In case of contact with eyes rinse thoroughly with plenty of water and seek medical advice
After ingestion
Call in a physician immediately and show him the Safety Data Sheet.

5. Fire-fighting measures
Safety data sheet in accordance with 2001/58/EC
Appretan N9211 liq Page 2

Substance key: SXR076300 Revision Date: 17.07.2006

Version : 2 - 4 / EU Date of printing : 18.07.2006

Suitable extinguishing media

water mist
carbon dioxide
dry powder
foam
Special hazards from the substance itself, its combustion products or from its vapours
In the event of fire the following can be released:
Carbon dioxide (CO2)
Carbon monoxide (CO)
Special protective equipment for firefighting
Use self-contained breathing apparatus
Wear full protective suit.
Further information
Fire residues must be disposed of in a proper manner

6. Accidental release measures

Personal precautions
Ensure adequate ventilation.
Environmental precautions
Do not allow to enter drains or waterways
Methods for cleaning up/taking up
Cover with absorbent material (eg sand, peat, earth) and then pick it up.
Dispose of contaminated material as prescribed

7. Handling and storage

Advice on safe handling
Ensure adequate ventilation.
It cannot be ruled out, that traces of following substances are present.
Formaldehyde
Local exhaust ventilation.
Advice on protection against fire and explosion
Observe the general rules of industrial fire protection
Requirements for storage rooms and vessels
Keep only in the original container
Further information on storage conditions
Protect against frost. The product after freezing is no longer usuable
Protect from extreme heat and cold
Storage stability
Storage period up to 6 months

8. Exposure controls/personal protection

Hygiene measures
Wash hands before breaks and after work.
Safety data sheet in accordance with 2001/58/EC
Appretan N9211 liq
Substance key: SXR076300
Version : 2 - 4 / EU
Respiratory protection :
Hand protection :
Eye protection :
Body protection :
9. Physical and chemical properties
Form :
Colour :
Odour :
Melting point :
Boiling temperature :
Flash point :
Ignition temperature :
Self-ignition temperature :
Lower explosion limit :
Upper explosion limit :
Vapour pressure :
Density :
Bulk density :
Solubility in water :
pH value :
Octanol/water partition
coefficient (log Pow) :
Viscosity (dynamic) :
10. Stability and reactivity
Thermal decomposition :
Page 3
Revision Date: 17.07.2006
Date of printing : 18.07.2006
Use respiratory protection in case of insufficient exhaust
ventilation or prolonged exposure
Filter A (organic gases and vapours) to standard DIN EN 141
Nitrile rubber gloves.
These types of protective gloves are offered by various
manufacturers. Please note the manufacturers detailed
statements, especially about the minimum thickness and the
minimum breakthrough time. Consider also the particular
working conditions under which the gloves are being used.
safety glasses
see respiratory protection
protective clothing
Liquid
milky white
slight, of acrylate
not determined
approx. 100 C
No flash point upto 100 C.
not determined
Not applicable
not determined
not determined
not determined
1,06 g/cm3 (20 C)
Not applicable
miscible in all proportions
5,0 - 6,5
Method : ISO 1148
Not determined
35 - 65 mPa.s (20 C)
Method : ISO 2555
not determined
Safety data sheet in accordance with 2001/58/EC
Appretan N9211 liq Page 4

Substance key: SXR076300 Revision Date: 17.07.2006

Version : 2 - 4 / EU Date of printing : 18.07.2006

Hazardous decomposition products

Carbon monoxide and carbon dioxide

11. Toxicological information

Acute oral toxicity : LD50 > 2.000 mg/kg (rat)
Method : OECD

Irritant effect on skin : non-irritant (rabbit)

Irritant effect on eyes : non-irritant (rabbit eye)

12. Ecological information

Biodegradability : not determined

Fish toxicity : not determined

Daphnia toxicity : not determined

Algae toxicity : not determined

Chemical oxygen demand 810 g/l

(COD) :

Biochemical oxygen demand 7,5 g/l

(BOD5) :

Remarks
Ecological data are not available
Do not discharge product unmonitored into the environment.

13. Disposal considerations

Product
Disposal in an incineration plant in accordance with the regulations of the local
authorities.
Uncleaned packaging
Packaging that cannot be cleaned should be disposed of as product waste

14. Transport information

ADR not restricted

ADNR not restricted
RID not restricted
IATA not restricted
Safety data sheet in accordance with 2001/58/EC
Appretan N9211 liq Page 5

Substance key: SXR076300 Revision Date: 17.07.2006

Version : 2 - 4 / EU Date of printing : 18.07.2006

IMDG not restricted

15. Regulatory information

Labelling in accordance with EC-Directives
hazard warning labelling not compulsory
Does not require a hazard warning label, but the normal safety precautions for handling of
chemicals must be observed.

16. Other information

See product leaflet
This product is manufactured using a nonylphenol ethoxylate. Observe the requirements of Directive
2003/53/EC of 18 June 2003, the 26th Amendment of Directive 76/769/EEC (relating to restrictions
on the marketing and use of certain dangerous substances and preparations) and the
corresponding national legislation implementing this Directive.

Decimal notation: "Thousands" places are identified with a dot (example: 2.000 mg/kg means
"two thousand mg/kg"). Decimal places are identified with a comma (example: 1,35 g/cm3).

The data are based on the current state of our knowledge, and are intended to describe the
product with regard to the requirements of safety. The data should not be taken to imply any
guarantee of a particular or general specification. It is the responsibility of the user of the
product to ensure to his satisfaction that the product is suitable for the intended purpose and
method of use. We do not accept responsibility for any harm caused by the use of this
information. In all cases, our general conditions of sale apply.