EDT 03
01.The plasma temperature of Sun is measured
by Dopplers effect the change in wavelength is
detected by using instrument known as
(A) Diffraction grating (B) polarizer
(C) prism (D) Solar cell
02. The change in wavelength of light during
passage from air to glass if refractive index of
glass with respect to air is 1.5 and frequency of
light in turpentine is 4 x 1013Hz and speed of
light in air is 3 x 108m/s
(A)7500A (B)5000A
(C)1500A (D)2500A
03.A parallel beam of light is incident on a glass
slab with glancing angle 45o if the refractive
index of glass slab is 1.5 then the ratio of width
of beam of glass to that in air is
(A)1.633 (B)27/3
(C)37/3 (D) 0.707
04. In the expression of Dopplers effect for light
Vr
1 c
we have = the term Vr vibrations parallel to page of paper and 2
2
Vr
1
c 10. Brewsters law is not applicable for
indicates
(A) velocity of red light which indicate red shift
(B) relative velocity of source and observer
(C) radial component of velocity of source w.r.to
observer
(D) relative velocity of yellow light
05. According to Dopplers effect for light when
Vr < < < c then by simplifying = [ 1(Vr/c)] (B) congruence of triangle
' Vr (C) definition of trigonometric functions
you get and is equal to because
c
(A) of theory of relativity
(B) of fact that speed of light is universal
constant
(C) light is affected by gravity
(D) frequency of light remain same
06. Identify incorrect statement.
(A) blue shift means increase in frequency
(B) red shift means source is moving away
(C) red shift is used for visible light only
(D) Polaroid is used in LCD screen
07. Tourmaline is
(A) name of property which measure
transparency
(B) is name of crystal which is Dichronic crystal
(C) is a line normal to timeline or Greenwich line
(D) name of medium also known as ether
08. The phenomenon of polarization confirmed
that
(A)light wave are transverse in nature
(B)light waves are longitudinal in nature
(C)light is stream of photon
(D)light consist of electric and magnetic field
09. The light indicated by figure 1 and 2
represent
(1) (2)
(A) 1 represent plane polarized light with
vibrations perpendicular to page of paper and 2
PPL with vibrations parallel to plane of paper
(B) 1 represent plane polarized light with
vibrations parallel to page of paper and 2 plane
polarized light with vibrations parallel to plane
of paper
(C) 1 represent plane polarized light with
vibrations perpendicular to page of paper and 2
represents light which is un polarized
(D) 1 represent plane polarized light with
represent un polarized light
(A) polished metallic surfaces
(B) convex glass surface
(C) if reflected and refracted ray are not normal
(D) Tourmaline crystal
11. While proving Snells law by Huygenss
principle we use
(A) similarity of triangles
(D) construction of spherical wave front
12. According to Newton the different colors of
light are because of
(A) different wavelengths
(B) colors of corpuscles
(C) different size of corpuscles
(D) prism held between the white light
13. According to Huygens the wave front is
nothing but
(A) part of medium where none of the particle
have same phase
(B) part of medium which carries energy in a
direction perpendicular to surface
(C) a sphere which is expanding
(D) a plane at a distance from focus of convex
lens
 14. The initial form of light according to light. If the refractive index of water is 4/3 then
Huygens was the refractive index of glass is
(A) energy which travel as longitudinal wave (A) 5/4 (B) 1.5
(B) electromagnetic wave (C) 5/3 (D)16/15
(C) energy which travel as transverse wave 24.If AB is incident wave front which is incident at
(D) white light consisting of seven colors an angle i & CD is refracted wave front refracted at
15. If refractive index of a medium is 3 then its angle r from a medium of refractive index M then
angle of polarization the ratio of CD & AB is
(A) will not be defined (B) will be 60o (A) M (B) 1/M
(C) will be 30 o (D) is 90o (C) cos(i)/cos(r) (D) cos(r)/cos(i)
16.Velocity of light in glass whose refractive
index with respect to air is 1.5 is 2 x 108 m/s and 25.Which one of the following phenomenon is
in certain liquid velocity of light found to be 2.5 not explained by Huygens construction of
x 108 m/s. Refractive index of liquid with wavefront?
respect to air is (A) refraction (B) reflection
(A) 0.64 (B) 0.80 (C) 1.20 (D)1.44 (C) diffraction (D) origin of
17.When unpolarised light is incident on spectrum
reflecting surface at Polarizing angle then out of 26.When unpolarised light traveling in air is
reflected and refracted rays incident at an angle of 60O on a transparent
(A) both are polarized material, the reflected light is completely
(B) neither is polarized polarized. Find the velocity of the refracted ray
(C) reflected is polarized inside the material.
(D) refracted is polarized (A) 3 x 108 m/s (B) 3 3 x 108 m/s
18.If is refractive index of medium & c is (C) 2.5 x 108 m/s (D) 1.33 x 108 m/s
velocity of light in air, then according to 27.Light form distant star will be reaching on
Huygens theory, the distance travelled in time earths surface in the form of
t by a secondary wavelets through the medium (A) spherical wave front
(A) ct. (B) t/c (B) plane wave front
(C) ct/ (D) c/ t. (C) cylindrical wave front
19.A beam of light is incident at the polarizing (D) all of these
angle on an air glass interface. If a & g be the 28. According to wave theory, different colors of
wavelengths of light in air & glass respectively, light is due to
then g that equals (A) different wavelengths of light waves
(A) a cot (B) a tan (B) different frequencies of light waves
(C) a cos (D) a sin (C) different amplitudes of light waves
20.The critical angle of certain medium is (D) none of these
sin1(3/5). The polarizing angle of the medium is 29.To explain propagation of light concept of
(A) sin1(4/5) (B) tan1(5/3) luminiferous ether was introduced by
1
(C) tan (3/4) (D) tan1(4/3) (A) Newton (B) Huygen
21.A ray of light of frequency 4 x 105Hz is (C) Maxwell (D) Planck
refracted through glass of RI 1.5. If c = 3 x 108 30.Which of the following does not support the
m/sec in air, the percentage change in the wave nature of light?
wavelength from air to glass is - (A) Interference
(A) 50% (B) 25% (C) 20% (D) 33% (B) Diffraction
22.According to Newtons corpuscular theory (C) Polarization
velocity of light in water will be ______ than (D)Photoelectric effect
velocity of light in air. 31.The refractive index of a certain glass is 1.5 for
(A) either less or more (B) more light whose wavelength in vacuum is 6000 . The
(C) equal to (D) less wavelength of this light when it passes through the
23.A glass slab of thickness 4 cm contains the glass is
same number of waves as 5 cm of water. When (A) 4000 (B) 6000
both are traversed by the same monochromatic (C) 9000 (D) 15000
32. When a ray of light passes from air medium to 43. A plane wave front AB is incident at glancing
denser medium then the refractive index is angle and after refracting at it becomes CD
(A) relative refractive index then the ratio of AB and CD is
(B) absolute refractive index cos sin
(C) dispersion (A) (B)
cos sin
(D) none of these
cos sin
33.A perpendicular drawn to the wave front in the (C) (D)
direction of propagation of light is cos cos
(A) wave normal (B) ray of light 44.The refractive index of water is 1.33. The speed
(C) arc of circle (D) chord of circle of light in water is
34.The rays of light corresponding to spherical (A) 1.33 x 108 m/s (B) 2.25 x 108 m/s
wave front are (C) 3 x 10 m/s
8 (D) 4 x 108 m/s
(A) converging in nature (B) diverging in nature 45.A ray of light passes from vacuum to a
(C) parallel in nature (D) coaxial medium of R.I m the angle of incidence is found
35. A light wave has a frequency of 4 x 1014 Hz & a to be twice the angle of refraction. Then the
wavelength of 5 x 10-7 m in a medium. The angle of incidence is
refractive index of the medium is (A) 2sin-1m (B) Cos-1m
(A) 1.5 (B) 1.33 (C) 1.0 (D) 0.66 m m
(C) cos-1 (D) 2 cos-1
2 2
36. A ray of light incidents on a plane mirror at an
angle of 30O. The deviation produced in the ray is 46. According to Planks theory of light the
(A) 30O (B) 60O (C) 90O (D)120O frequency of light is equal to
37. The phenomenon of change in path of ray of (A) ratio of planks constant and momentum
light when it passes from one medium to another (B) ratio of energy of light and planks constant
medium is (C)product of planks constant and energy of
(A) reflection of light (B) refraction of light light
(C) interference of light (D) diffraction of light (D) ratio of wavelength and speed of light.
38.The refractive index of water is 4/3 & that of 47. When a diver looking up through the water
glass slab is 5/3. The critical angle for the ray of sees the outside world contain in a circular
light tending to go from water to glass is horizon. If refractive index of water is 1.414 and
(A) sin-1(4/5) (B) sin-1(5/4) diver is 3m below the surface then radius of the
(C) sin (1/2)
-1 (D) sin-1(2/1) circle will be
39.The wavelength of green light in air & in glass is (A) 3m (B) 36/7m
5300 & 3533 . The refractive index of glass is (C) 9/7m (D) 4.242m
(A) 1 (B) 1.5 (C) 2 (D) 2.4 48. A beam of light covers a distance of 900
40. A beam of light is partially reflected & partially meter in air in 3 s. Find the distance it will
refracted from a surface. The angle between the cover in water of absolute refractive index 4/3
reflected & refracted light is 90O. The angle of in 8 s is
refraction is 30O. The angle of incidence must be (A)1400m (B)180m
(A) 50O (B) 60O (C)1800m (D)900 m
(C) 75 O (D) 78O 49. When a ray of light traveling from A to
41. If ij represents refractive index, when a light medium B the number of waves in 8cm length of
ray goes from medium i to medium j, then the A is same as the number of waves in 5cm length
product 21 x 32 x 43 is equal to of B then refractive index A n B is
(A) 31 (B) 32 (A) 0.62 (B) 1.6 (C) 1.5 (D) 1.33
(C) 41 (D) 42 50. If wave normal are normal to reflecting
42. When light passes from one medium to other surface then angle of incidence is
medium then its wavelength decreases & the (A) 90o (B) 0o (C) 45o (D) 60o
frequency of light 51. Which of the following is correct w.r.t. SN2
mechanism?
(A) decreases
(A) It is unimolecular reaction
(B) increases
(B) It is first order reaction
(C) remains same
(C) Rate of reaction [Substrate] [Nucleophile]
(D) may increase or decrease (D) 3O Alkyl halides react through SN1
52. Which of the following produces ethyl cyanide (C) R-I > R-Cl > R-Br > R-F(D) R-F > R-I > R-Br > R-Cl
when reacted with ethyl bromide? 63. Which of the following is correct w.r.t. SN2
(A) HCN (B) AgCN mechanism?
(C) KCN (D) R CN (A) It proceeds through the formation of
53. Propene reacts with HBr in the absence of carbocation
peroxide; the main product obtained has which of (B) The rate of reaction depends upon the attack
the following as its position isomer? of nucleophile on carbocation
(A) 1- Bromopropane (B) 2 Bromo propane (C) The energy profile has one peak
(C) Isobromopropane (D) Both (B) and (C) (D) Inversion and retention of configuration, both
54. What is the major product of the reaction of take place
chloromethane, chloroethane and sodium in dry 64. Consider the following carbocations :
and pure ether?

(A) CH3 CH3 (B) CH3 CH2 CH2 CH3 (I) C 6 H 5 C H 2 (II) C6 H 5 CH 2 C H 2
(C) CH3 CH2 CH3 (D) CH3 CH = CH2

55. The major product in the reaction of 2- (III) C6 H 5 C H CH 3 (IV) C 6 H 5 C CH 3 2

bromobutane with alcoholic KOH is : (A) II < I < III < IV (B) II < III < I < IV
(A) but-1-ene (B) prop-1-ene (C) III < I < II < IV (D) IV < III < I < II
(C) cis-but-2-ene (D) trans-but-2-ene
56. Grignard reagent is prepared in ether and not 65. Which is correct w.r.t. plane polarized light?
in water or alcohol because : (A) It is a monochromatic light
(A) it dissolves in alcohol and water (B) It has vibrations only in one plane
(B) it becomes inactive in alcohol and water (C) It is used to know the optical activity of a
(C) it reacts with alcohol or water to form compound
hydrocarbon (D) All of the above
(D) its reactivity increases in ether 66. Which of the following is used as refrigerant?
(A) CCl2F2 (B) CCl2Br2
57. The functional group of secondary alkyl halides (C) CCl2I2 (D) Both (B) and (C)
is ---- 67. Which order is correct w.r.t. boiling point?
(A) CH3 CH2 CH2 Cl > CH3 CH2 Cl > CH3 Cl
CX (B) CH3 CH2 CH2 Cl < CH3 CH2 Cl < CH3 Cl
(A) =CHX (B)
(C) CH3 CH2 Cl > CH3 Cl > CH3 CH2 CH2 - Cl
(C) CH2X (D) CHX
(D) CH3 CH2Cl > CH3 CH2 CH2 - Cl > CH3 Cl
58. The reactivity of alkyl halides towards SN2
68. An optically active alkyl halide undergoes SN2
reaction is
reaction. The product will show :
(A) 3O > 2O > 1O (B) 3O > 1O > 2O
O O O (A) 100% inversion
(C) 2 > 3 > 1 (D) 1O > 2O > 3O
(B) 50% inversion and 50% retention
(C) 100% retention
59. A racemic mixture is optically inactive because
(D) 25% inversion and 75% retention
of
69. Optical rotation of a compound does not
(A) internal compensation
depend upon
(B) external compensation
(A) number of molecules of compound in solution
(C) absence of chiral C-atom (D) unpredictable
(B) concentration of solution
60. Which one is not correct w.r.t. SN1 mechanism?
(C) wavelength of the light used
(A) It proceeds through the formation of
(D) temperature of solution
carbocation
70. Which type of structural isomerism do alkyl
(B) The rate of reaction depends upon the attack
halides not show?
of nucleophile on carbocation
(A) Chain isomerism (B)Position isomerism
(C) The energy profile has one peak
(C) Metamerism (D) Both (A) and (B)
(D) Inversion and retention of configuration, both
71. Which statement is not correct w.r.t. SN1
take place
mechanism?
61. The shape of methyl carbanion is :
(A) It is unimolecular reaction
(A) trigonal planar (B) pyramidal
(B) It is first order reaction
(C) tetrahedral (D) linear
(C) Rate of reaction [Substrate] [Nucleophile]
(D) 3O Alkyl halides react through SN1
62. The reactivity order of halides for dehydro-
72. ____ is having highest nucleophilicity?
halogenation is :
(A)F- (B)OH- (C)CH3- (D)NH2-
(A) R-F > R-Cl > R-Br > R-I(B) R-I > R-Br > R-Cl > R-F
73. The instrument used to measure the optical 82. Which of the following is observed in ethylene
activity of a compound is : molecule?
(A) lactometer (B) stalagmometer (A) Electromeric effect (B) Inductive effect
(C) polarimeter (D) Optometer (C) Homolytic fission (D) Both B and C
74. Which of the following compound undergoes 83. CH 3 CH 2 Br X HOH
KCN
Y ,
SN1 reaction faster? alc.
Cl CH2Cl
then Y is :
(A) acetic acid (B) propionic acid
Cl

(C) butyric acid (D) formic acid

84. II
Cl R 3C Br

I
R 3 C ........ Br R 3C
(A) (B) (C) (D)

OH
75.Among the following which compound R3 C OH
III
undergoes hydrolysis most readily with aq. NaOH
to furnish the corresponding hydroxyl derivative? Which one is the fastest step?
(A) I (B) II
NO2 (C) III (D) depends on the nature of R group
85. Haloform is represented as :
O2N Cl
O2N Cl (A)
Cl
CH3X (B) CH2X2 (C) CHX3 (D) CX4
Me2N Cl
86. Which of the following is a primary halide?
(A) Isopropyl iodide (B) sec-Butyl chloride
NO2
(C) tert-Butyl bromide (D) Neohexyl chloride
(A) (B) (C) (D)
87. 1-Chloro-2-methylpropane + KOH (aq) X +
KCl. Identify X:
76. A solution of a substance did not show optical
(A) 1-methylpropene (B) 1-propene
rotation in polarimeter. Which of the following is
(C) 2-methylpropan-2-ol (D) 2-methyl-1-propanol
expected to be correct for the substance?
88. SN2 reaction is favoured by :
(A) It may be a racemic mixture
(A) high conc. of nucleophile (B) non-polar solvent
(B) It may be a meso compound
(C)Both A and B (D) polar solvent
(C) It may not have chiral C-atom
89. A compound with molecular formula C7H16
(D) Any of these may be possible
shows optical isomerism, the compound will be :
77. Due to resonance the C-X bond in aryl halides
(A) 2, 3-dimethylpentane (B) 2, 2-
possess?
dimethylpentane
(A)partial double bond character
(C) 2-methylheptane (D) none of the above
(B)single bond character
90. An organic compound A(C4H9Cl) on reaction
(C)more stability (D)more conjugation
with Na/diethyl ether gives a hydrocarbon which
78. If there is no rotation of plane polarized light
on monochlorination gives only one monochloro
by a compound in a specific solvent, thought to be
derivative, then A is :
chiral, it may mean that:
(A) t-butyl chloride (B) sec. butyl chloride
(A) the compound is certainly a chiral
(C) isobutyl chloride (D) n-butyl chloride
(B) the compound is certainly meso
91. Diphenyl can be obtained by__
(C) there is no compound in solvent
(A)2 eq. bromobenzene when reacts in presence of
(D) the compound may be racemic mixture
Na.
79. Which is optically active?
(B)two phenyl rings couples in presence of Na.
(A) CH2Cl2 (B) CHCl3
(C)reaction of benzene with phenol.
(C) Meso tartaric acid (D) Glyceraldehyde
(D) all of the above
80. Which of the following when attached to
92. A similarity between optical & geometrical
carbon will help to form carbanion?
isomerism is that :
(A) Hydrogen (B) Magnesium
(A) each forms equal no. of isomers for a given
(C) both (A) and (B) (D) Chlorine
compound
81. In alkaline hydrolysis of a tertiary halide by
(B) if in a compound one is present, so is the other
aqueous alkali, if the concentration of alkali is
(C) both are included in stereoisomerism
doubled, then the rate of reaction :
(D) they have no similarity
(A) will be doubled (B) will be halved
93. A chiral compound is :
(C) will remain constant (D) cannot say
(A) 2, 3, 4-trimethylhexane (B) n-hexane
(C) methane (D) n-butane
 PCl5 Na
94. X Y n Butane .
X and Y are respectively :
(A) ethyl chloride, ethyl alcohol
(B) ethyl alcohol, ethyl chloride
(C) methyl chloride, methyl alcohol
(D) both (A) and (B)
95. Which of the following will have a meso isomer
also?
(A) 2-Chlorobutane
(B) 2, 3-Dichloropentane
(C) 2-Hydroxypropanoic acid
(D) 2, 3-Dichlorobutane
96. Tertiary alkyl halides are practically inert to
substitution by SN2 mechanism because of :
(A) insolubility (B) instability
(C) inductive effect (D) steric hindrance
97. Which of the following is least reactive in
nucleophilic substitution reaction?
(A) CH2 = CH - Cl (B) CH3 CH2 - Cl
(C) CH2 = CH CH2 - Cl (D) (CH3)3C - Cl
98. Which of the following reactions will yield
2, 2-dibromopropane?
(A) CH3 C CH + 2HBr
(B) CH3 CH = CH Br + HBr
(C) CH CH + 2HBr
(D) CH3 CH = CH2 + HBr
99. Elimination of hydrogen and bromine from
2-bromobutane results in the formation of :
(A) predominantly but-2-yne
(B) predominantly but-1-ene
(C) predominantly but-2-ene
(D) equimolar mixture of B and C
100. Which of the following is the most stable
carbocation?
(A) Isopropyl (B) sec-Butyl
(C) tert-Butyl (D) Neohexyl