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Physical properties
Group 1 2 3 4 5 6 7
Formula of oxide Na2O MgO Al2O3 SiO2 P4O10 SO2 Cl2O
Tm (K) 1548 3125 2345 1883 573 200 253
State at 298K (s) (s) (s) (s) (s) (g) (g)
Conductivity of
+ + +
molten oxide
Structure and giant giant giant giant simple simple simple
bonding ionic ionic ionic molecular molecular molecular molecular
SO2 A gas which dissolves readily in water to produce a colourless acidic solution.
Explanations
1. Reactions of sodium oxide and magnesium oxide with water
Hydrated ions are formed when ionic compounds dissolve in water.
If the ionic radius is small and the charge on the ion is high, hydrolysis also occurs.
When sodium oxide and magnesium oxide dissolve in water, the small highly charged oxide ions
strongly attract water molecules, so after hydration there is hydrolysis to produce hydroxide ions:
However, silica does react with hydroxide: SiO2(s) + 2OH (aq) SiO2-
3 (aq) + H2O(l)
SiO2-
3 is the silicate(IV) ion. This reaction is responsible for glass stoppers getting stuck in reagent
bottles containing sodium hydroxide solution.
Sulphur dioxide and sulphur trioxide consist of simple molecules. Both react with water to produce
acids: