Chemical Bonding: Work Book Exercises

7/5/2017 Scribd
SSP34 CH-1
CHEMICAL BONDING
Work Book Exercises

Reasoning
1. Arrange the gaseous hydrogen halides in order of decreasing dipole moment and
explain it.
1. HF HCl HBr HI
The electronegativitiy of halogen decrease from F to I which decreases the value of .
2. Arrange methyl halides in increasing dipole moment CH3F, CH3Cl, CH3Br, CH3I and give
explanation.
2. CH3I CH3Br CH3F CH3Cl
The order generally follows decrease in electronegativity of halogens. But CH 3F is

having lesser than CH3Cl because C F bond distance is much smaller than C Cl,
which tends to decrease the value of even though F is more electronegativity than Cl.
3. Give molecular orbital electronic structure for (a) C2; (b) N2; (c) NO; (d) CN; (e) O 2.
3. a) C2 ((12e ) 1s2 , * 1s2 , 2s2 , * 2s2 ,

2p 2y
2p 2z
b) N2 ((14e ) 1s2 , * 1s2 , 2s2 , * 2s2

2p2y 2p2x
2p 2z
c) CN (14e) similar to nitrogen
d) O2 (16e ) 1s2 , * 1s2 , 2s2 , * 2s2
2
2p2y * 2p1y
* 2s , 2p2x
2p2z * 2p1z
4. Give the bond order for each in question 3.
no. of e- in bond molecular orbital-no. of e-in anti-bonding molecular orbital

4. B.O =
2
FIITJEE
SSP34 CH-2
8 4
a) C2 B.O. 2
2
10 4
b) N2 B.O. 3
2
10 5
c) NO B.O. 2.5
2
10 4
d) CN B.O. 3
2
10 6
e) O2 B.O. 2
2
5. Why dipole moment of CHCl3 is less than that of CH 2Cl2.
H Cl H Cl
H Cl Cl Cl
Net moment Net moment
In CH2Cl2 all bond moment reinforce each other while in CHCl 3 the bond moment of one
of Cl apposes the net moment of the other two. This is also supposed by experimental
values of dipole moment CH3Cl 1.00 CH 2Cl2 1.60 .
True or False
1. All molecules with polar bonds have dipole moment.
1. False
2. AgCl is more covalent than KCl.

https://www.scribd.com/embeds/34940127/content?start_page=1&view_mode=scroll&access_key=key-53mpIO3cEgRqtbdru4Yc 1/52
7/5/2017 Scribd
2. AgCl is more covalent than KCl.
2. True
3. The H N H bond angle in NH 3 is greater than H As H bond angle in AsH3.
3. True
4. The bond order of O22, F2 and Li2 species is same
4. True
5. BaSO4 is in soluble because solvation energy is more than that lattice energy.
5. False
FIITJEE
SSP34 CH-3
6. I3 has linear structure however one of the iodine atom undergoes sp3d hybridisation.
6. True
7. Intramolecular hydrogen bonding decreases the solubility of compound in water.
7. True
8. The metallic bonds are directional in nature.
8. False
9. Higher change and smaller size order a cation toughly polarising.
9. True
10. LiF is less ionic than LiI.
10. False
Fill in the blanks
1. Of the compounds BeO, MgO and BaaO ____________ is more ionic.
1. BaO
2. In P4O10, the no. of oxygen atoms bonded to each phosphorus atom is ____________
2. 4
3. Out of N2, N2+, O2, O2+, ____________ is diamagnetic.
3. N2
4. The angle between two covalent bonds is maximum ____________ (CH 4, NH3, H2O).
4. CH4
5. The hybridization of P in PCl4+ is ____________ and the geometry is ____________.
5. sp3, tetrahedral
6. The dipole moment of CH 3OH is ____________ than that of CH3OH.
6. more
7. Comparatively low melting point and insolubility in water of AlCl 3 is explained by

____________ rule.
7. Fajans
FIITJEE
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
7/5/2017 Scribd
Show me more about this topic

1 of 82
View on Scribd
Back to document
Skip carousel
document
IONIC EQUILLIBRIUM FOR IIT-JEE ENTRANCE TEST by S.K.sinha See Chemistry Animations at http://openchemistry.in
document
How to identify geometrical isomers by S.K.sinha See Chemistry Animations at sinhalab.com

document
Resonance GOC
document
Set of 50 obj in General Organic Chemistry by S.K.sinha http://www.openchemistry.in

document
Resonance GOC 2
document
coordination theory
document
Basic Inorganic Nomenclature FOR IIT-JEE ENTRANCE TEST by S.K.sinha See Chemistry Animations at sinhalab.com
document
IIT JEE -2013 CHEMISTRY "BORON FAMILY"

document
Chemistry for IIT Preparation

document
7/5/2017 Scribd
General Organic Chemistry for IIT
document
PERIODIC TABLE & PERIODICITY-NEET

document
Unique Approach of Problem Solving in Isomerism by S.K.sinha http://www.openchemistry.in

document
Chem Quest
document
Organic Nomenclature http://openchemistry.in/

document
IIT JEE Inorganic Chemistry Study material.pdf

document
How to find no of structural isomers by S.K.sinha See Chemistry Animations at http://www.openchemistry.in

document
Short Tricks of Maths for Iit-jee

document
900 inorganic questions for IIT JEE ADVANCED

document
PRACTICAL ORGANIC CHEMISTRY FOR IIT-JEE ENTRANCE TEST by S.K.sinha See Chemistry Animations at sinhalab.com
document
Amine IIT JEE Organic Chemistry

document
Numerical Chemistry
document
Mechanics for IIT-JEE/AIEEE/AIPMT by Sanjay Pandey

document
UNSTABLE FUNCTIONAL GROUPS IN ORGANIC by S.K.sinha See Chemistry Animations at sinhalab.com

document
ELECTRONIC EFFECTS & APPLICATIONS JEE (MAIN)

document
Maths+quest
document
The Peason --Inorganic Chemistry

document
BANSAL CLASSES METALLURGY

document
carbonyl_post
document
PHYSICS STUDY MATERIAL FOR CLASS-XI

document
chemistry tips for IIT preparation
Skip carousel
document
chem notes.pdf
document
Atlas of Stereochemistry
document
Slow steaming in marine ships

document
Marine Technical - study Notes

document
Fwg Start Up
document
Electrical Must Know

document
Fwg Start Up
document
Fuel Gas Re Circulation

document
Shaft Alignment Procedure

document
Casting Process
document
7/5/2017 Scribd
document
Metal Casting Full Lecture Notes

document
Fluid Mechanics 1 Notes

document
Manufacturing Processes
document
IIT physics -- Magnatism formula sheet

document
Heat transfer formula sheet

document
Current electricity formula sheet

document
Graphs and Equations

document
General Organic Chemistry for IIT

document
Mind Maps
document
TIPS Physical Chem

document
mcq--goc
document
Resonance GOC
document
Resonance GOC 2
document
Mechanical Vibration solved examples

Chemical Bonding: Work Book Exercises

Hochgeladen von

Dokumentinformationen

Originaltitel

Copyright

Verfügbare Formate

Dieses Dokument teilen

Dokument teilen oder einbetten

Freigabeoptionen

Stufen Sie dieses Dokument als nützlich ein?

Sind diese Inhalte unangemessen?

Copyright:

Verfügbare Formate

Chemical Bonding: Work Book Exercises

Hochgeladen von

Copyright:

Verfügbare Formate

7/5/2017 Scribd

Work Book Exercises

The electronegativitiy of halogen decrease from F to I which decreases the value of .

2. CH3I CH3Br CH3F CH3Cl

The order generally follows decrease in electronegativity of halogens. But CH 3F is

3. a) C2 ((12e ) 1s2 , * 1s2 , 2s2 , * 2s2 ,

b) N2 ((14e ) 1s2 , * 1s2 , 2s2 , * 2s2

c) CN (14e) similar to nitrogen

d) O2 (16e ) 1s2 , * 1s2 , 2s2 , * 2s2

4. Give the bond order for each in question 3.

no. of e- in bond molecular orbital-no. of e-in anti-bonding molecular orbital

5. Why dipole moment of CHCl3 is less than that of CH 2Cl2.

Net moment Net moment

values of dipole moment CH3Cl 1.00 CH 2Cl2 1.60 .

1. All molecules with polar bonds have dipole moment.

2. AgCl is more covalent than KCl.

3. The H N H bond angle in NH 3 is greater than H As H bond angle in AsH3.

4. The bond order of O22, F2 and Li2 species is same

7. Intramolecular hydrogen bonding decreases the solubility of compound in water.

8. The metallic bonds are directional in nature.

9. Higher change and smaller size order a cation toughly polarising.

10. LiF is less ionic than LiI.

Fill in the blanks

1. Of the compounds BeO, MgO and BaaO ____________ is more ionic.

3. Out of N2, N2+, O2, O2+, ____________ is diamagnetic.

5. The hybridization of P in PCl4+ is ____________ and the geometry is ____________.

6. The dipole moment of CH 3OH is ____________ than that of CH3OH.

7. Comparatively low melting point and insolubility in water of AlCl 3 is explained by

Show me more about this topic

How to identify geometrical isomers by S.K.sinha See Chemistry Animations at sinhalab.com

Set of 50 obj in General Organic Chemistry by S.K.sinha http://www.openchemistry.in

IIT JEE -2013 CHEMISTRY "BORON FAMILY"

Chemistry for IIT Preparation

PERIODIC TABLE & PERIODICITY-NEET

Unique Approach of Problem Solving in Isomerism by S.K.sinha http://www.openchemistry.in

Organic Nomenclature http://openchemistry.in/

IIT JEE Inorganic Chemistry Study material.pdf

How to find no of structural isomers by S.K.sinha See Chemistry Animations at http://www.openchemistry.in

Short Tricks of Maths for Iit-jee

900 inorganic questions for IIT JEE ADVANCED

Amine IIT JEE Organic Chemistry

Mechanics for IIT-JEE/AIEEE/AIPMT by Sanjay Pandey

UNSTABLE FUNCTIONAL GROUPS IN ORGANIC by S.K.sinha See Chemistry Animations at sinhalab.com

ELECTRONIC EFFECTS & APPLICATIONS JEE (MAIN)

The Peason --Inorganic Chemistry

BANSAL CLASSES METALLURGY

PHYSICS STUDY MATERIAL FOR CLASS-XI

chemistry tips for IIT preparation

Slow steaming in marine ships

Marine Technical - study Notes

Electrical Must Know

Fuel Gas Re Circulation

Shaft Alignment Procedure

Metal Casting Full Lecture Notes

Fluid Mechanics 1 Notes

IIT physics -- Magnatism formula sheet

Heat transfer formula sheet

Current electricity formula sheet

Graphs and Equations

General Organic Chemistry for IIT

TIPS Physical Chem

Mechanical Vibration solved examples

Das könnte Ihnen auch gefallen

5. The hybridization of P in PCl4+ is and the geometry is .